CN108951147A - Using the method for Biocomposite material improvement fiber - Google Patents

Using the method for Biocomposite material improvement fiber Download PDF

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Publication number
CN108951147A
CN108951147A CN201810780277.9A CN201810780277A CN108951147A CN 108951147 A CN108951147 A CN 108951147A CN 201810780277 A CN201810780277 A CN 201810780277A CN 108951147 A CN108951147 A CN 108951147A
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China
Prior art keywords
water
liquid
extra large
fiber
composite material
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CN201810780277.9A
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Chinese (zh)
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江志清
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Individual
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Individual
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Priority to CN201810780277.9A priority Critical patent/CN108951147A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

A method of fiber being improved using Biocomposite material, feature includes standby with biologic compound amylose liquid: the materials ratio of biologic compound amylose liquid is water 96%, chitosan oligosaccharide 2.4%, chitosan 1.6%;Chitosan oligosaccharide, chitosan are put into the suitable quantity of water of room temperature and is stirred evenly;Standby to match extra large polysaccharide composite material liquid: the materials ratio of extra large polysaccharide composite material liquid is water 97%, extra large glycan 3%;It is spare by being stirred evenly in the suitable quantity of water of extra large glycan investment room temperature;Biologic compound amylose liquid is grown leaching and is arranged: growing leaching fiber 150 minutes, dehydration, drying with the biologic compound amylose liquid of step 1;It is compound that extra large polysaccharide composite material liquid grows leaching: it is grown soak fiber 120 minutes that step 3 obtains with the extra large polysaccharide composite material liquid of step 2 again, dehydration, drying.It solves biologic compound amylose fiber, and the problem of being easy degradation chitosan is dyed using acid, is that traditional natural fiber, staple fibre are transformed into the splendid method of healthcare function fiber.

Description

Using the method for Biocomposite material improvement fiber
Technical field
The present invention relates to biological composite fibre technology fields, specifically a kind of to utilize Biocomposite material, will be traditional Natural fiber, staple fibre, the method for being transformed into biological function fiber.
Background technique
With the continuous development of economy and society, natural fiber, staple fibre function limitation be difficult to meet human lives It needs, the research and development of ecological health care function textile obtain the most attention in the whole world, and people are to high-tech functional textile Product are made excessive demands, so that the field market potential is very big.Realize textile product healthcare function, selection and application function material Material is crucial.
Biologic compound amylose, refer to chitosan oligosaccharide 60% and chitosan 40% assembles substance.It has antibacterial, stops blooding, disappears The functions such as scorching, anti-infective, mould proof, promotion wound healing;And containing cationic natural polymers, contain in molecule The amino of positive charge is a kind of polymeric sorbent, has an extremely strong biological immune activity, moisture absorption oxygen flow, deodorization, it is anti-radiation, It eliminates the unusual smell, there is good affinity interaction to human body.Biologic compound amylose is to be applied to the best natural function of field of textiles to protect Strong material.
Extra large polysaccharide composite material refers to a kind of water-soluble biological composite material from extractions such as sea shells.It has Have that special enhancing solidification is decomposed, reaction neutralizes function, it is caking property and stability with super strength, good structural strength, anti- Bacterium eliminates the unusual smell, and the features such as efficient removal formaldehyde.Extra large polysaccharide composite material is new type natural functional material.
Biocomposite material refers to biologic compound amylose and extra large polysaccharide composite material.
Currently, there are mainly two types of the application methods of biologic compound amylose in textile industry: first is that fiber blend method, i.e., With chitin fiber and the blended yarn of cotton fiber;
Second is that viscose rayon additive process is spun viscous containing chitosan that is, to add suitable chitosan when viscose rayon spinning Glue fiber.
The fiber that above two method obtains, during using acid dyeing, acid is easy degradation chitosan, makes fiber function It can substantially reduce, therefore, it is jejune technology, this is also to cause biologic compound amylose widely applied not in textile Basic reason.
Summary of the invention
The present invention is that solution fiber blend method and viscose rayon additive process, the biologic compound amylose fiber of acquisition use acid Dyeing is easy the problem of degradation chitosan, provide it is a kind of using biologic compound amylose material, extra large polysaccharide composite material, after dyeing Traditional fibre implement Biocomposite material transformation, by traditional fibre be modified to ecological health care function chemical fibre dimension method.
The technical scheme is that a method of fiber is improved using Biocomposite material, special character includes,
One, standby to match biologic compound amylose liquid: the materials ratio of biologic compound amylose liquid is water 96%, water-soluble chitosan oligosaccharide 2.4%, water soluble chitosan 1.6%;In proportion by powdery chitosan oligosaccharide, chitosan investment room temperature suitable quantity of water in stir evenly it is standby With;
Two, standby with extra large polysaccharide composite material liquid: the materials ratio of extra large polysaccharide composite material liquid is that water 97%, water-soluble sea are poly- Sugar 3%;It will be stirred evenly in the suitable quantity of water of powdery sea glycan investment room temperature in proportion spare;
Three, biologic compound amylose liquid is grown leaching and is arranged: the biologic compound amylose liquid of fiber step 1 to be processed is grown leaching 150 minutes, dehydration, drying;
Four, it is compound to grow leaching for extra large polysaccharide composite material liquid: growing leaching step 3 with the extra large polysaccharide composite material liquid of step 2 again and obtains Fiber 120 minutes obtained, dehydration, drying.
The solution have the advantages that by adopting the above technical scheme, may be implemented it is a kind of using Biocomposite material to biography The modification method that fiber of uniting is implemented, in implementation process, by the biologic compound amylose containing positive charge and negatively charged sea Polysaccharide composite material forms Biocomposite material condensed material in traditional fibre, a kind of biological mixture matter fiber has been transformed.
The modification method that Biocomposite material provided by the invention implements traditional fibre has selected to apply in textile industry The characteristics of optimal functional material biologic compound amylose, excavation applies new bio functional material sea polysaccharide composite material.Institute With the functional fabric of the obtained fibrous woven of this technology has good ecological health care function.
Biologic compound amylose and extra large polysaccharide composite material, assemble renovation technique by biology, are formed in traditional fibre Colloid condensed material water can't is washed off.Through national authority, department is detected, and hand-washes 200 times and still has functional effect;Functional fabric pile is folded Three layers of test free from extraneous odour and smooth breathing;And traditional folded three layers of test of fabric pile has peculiar smell and breathing is obstructed.
Specific embodiment
Combined with specific embodiments below, the present invention is further described.
Embodiment 1 is implemented to improve using Biocomposite material provided by the invention to staple fibre.
One, standby to match biologic compound amylose liquid, taking pH value is 200 kilograms of the normal-temperature water of 6-7,4.8 public affairs of water-soluble chitosan oligosaccharide Jin, 3.2 kilograms of water soluble chitosan;It is spare by being stirred evenly in powdery chitosan oligosaccharide, chitosan investment water;
Two, standby with extra large polysaccharide composite material liquid, take 200 kilograms of normal-temperature water, water-soluble extra large 6 kilograms of glycan that pH value is 6-7;It will It is stirred evenly in powdery sea glycan investment water spare;
Three, biologic compound amylose liquid is grown leaching and is arranged, and 60 kilograms of staple fibre is put into the biologic compound amylose liquid of step 1 Body grows leaching 150 minutes, dehydration, drying;
Four, extra large polysaccharide composite material liquid taste leaching is compound, then grows leaching step 3 with the extra large polysaccharide composite material liquid of step 2 and obtain 60 kilograms of staple fibres 120 minutes obtained, dehydration, drying.
Embodiment 2 is implemented to improve using Biocomposite material provided by the invention to cotton fiber.
One, standby to match biologic compound amylose liquid, taking pH value is 400 kilograms of the normal-temperature water of 6-7,9.6 public affairs of water-soluble chitosan oligosaccharide Jin, 6.4 kilograms of water soluble chitosan;It is spare by being stirred evenly in powdery chitosan oligosaccharide, chitosan investment water;
Two, standby with extra large polysaccharide composite material liquid, take 400 kilograms of normal-temperature water, water-soluble extra large 12 kilograms of glycan that pH value is 6-7; It is spare by being stirred evenly in powdery sea glycan investment water;
Three, biologic compound amylose liquid is grown leaching and is arranged, and the cotton fiber of 120 kg is put into the biologic compound amylose liquid of step 1 Grow leaching 150 minutes, dehydration, drying;
Four, extra large polysaccharide composite material liquid taste leaching is compound, then grows leaching step 3 with the extra large polysaccharide composite material liquid of step 2 and obtain 120 kg cotton fiber 120 minutes obtained, dehydration, drying.
Embodiment 3 is implemented to improve using Biocomposite material provided by the invention to blend fibre.
One, standby to match biologic compound amylose liquid, taking pH value is 800 kilograms of the normal-temperature water of 6-7,19.2 public affairs of water-soluble chitosan oligosaccharide Jin, 12.8 kilograms of water soluble chitosan;It is spare by being stirred evenly in powdery chitosan oligosaccharide, chitosan investment water;
Two, standby with extra large polysaccharide composite material liquid, take 800 kilograms of normal-temperature water, water-soluble extra large 24 kilograms of glycan that pH value is 6-7; It is spare by being stirred evenly in powdery sea glycan investment water;
Three, biologic compound amylose liquid is grown leaching and is arranged, and 240 kilograms of blend fibre is put into the biologic compound amylose liquid of step 1 Body grows leaching 150 minutes, dehydration, drying;
Four, extra large polysaccharide composite material liquid taste leaching is compound, then grows leaching step 3 with the extra large polysaccharide composite material liquid of step 2 and obtain 240 kilograms of blend fibres 120 minutes obtained, dehydration, drying.

Claims (1)

1. a kind of method using Biocomposite material improvement fiber, feature include:
One, standby to match biologic compound amylose liquid: the materials ratio of biologic compound amylose liquid is water 96%, water-soluble chitosan oligosaccharide 2.4%, water soluble chitosan 1.6%;In proportion by powdery chitosan oligosaccharide, chitosan investment room temperature suitable quantity of water in stir evenly it is standby With;
Two, standby with extra large polysaccharide composite material liquid: the materials ratio of extra large polysaccharide composite material liquid is that water 97%, water-soluble sea are poly- Sugar 3%;It will be stirred evenly in the suitable quantity of water of powdery sea glycan investment room temperature in proportion spare;
Three, biologic compound amylose liquid is grown leaching and is arranged: the biologic compound amylose liquid of fiber step 1 to be processed is grown leaching 150 minutes, dehydration, drying;
Four, it is compound to grow leaching for extra large polysaccharide composite material liquid: growing leaching step 3 with the extra large polysaccharide composite material liquid of step 2 again and obtains Fiber 120 minutes obtained, dehydration, drying.
CN201810780277.9A 2018-07-17 2018-07-17 Using the method for Biocomposite material improvement fiber Pending CN108951147A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810780277.9A CN108951147A (en) 2018-07-17 2018-07-17 Using the method for Biocomposite material improvement fiber

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Application Number Priority Date Filing Date Title
CN201810780277.9A CN108951147A (en) 2018-07-17 2018-07-17 Using the method for Biocomposite material improvement fiber

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CN108951147A true CN108951147A (en) 2018-12-07

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101798756A (en) * 2010-01-06 2010-08-11 东华大学 Method for preparing biomedical material of static self-assembly modified nano fiber
CN102995402A (en) * 2012-11-17 2013-03-27 江志清 Method for solidifying pharmaceutical-grade chitosan oligosaccharide on fabric
CN107268088A (en) * 2017-05-19 2017-10-20 傲丝生态(中国)有限公司 A kind of preparation method of high-performance bamboo fibre

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101798756A (en) * 2010-01-06 2010-08-11 东华大学 Method for preparing biomedical material of static self-assembly modified nano fiber
CN102995402A (en) * 2012-11-17 2013-03-27 江志清 Method for solidifying pharmaceutical-grade chitosan oligosaccharide on fabric
CN107268088A (en) * 2017-05-19 2017-10-20 傲丝生态(中国)有限公司 A kind of preparation method of high-performance bamboo fibre

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王辉等: "生物纤维素及其与多糖共混纤维的结构与性能", 《纺织大学学报》 *

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Application publication date: 20181207

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