CN108949325A - It is a kind of with reducing machine oil and the automobile engine lubricating oil of fuel consumption function and preparation method thereof simultaneously - Google Patents

It is a kind of with reducing machine oil and the automobile engine lubricating oil of fuel consumption function and preparation method thereof simultaneously Download PDF

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CN108949325A
CN108949325A CN201810942434.1A CN201810942434A CN108949325A CN 108949325 A CN108949325 A CN 108949325A CN 201810942434 A CN201810942434 A CN 201810942434A CN 108949325 A CN108949325 A CN 108949325A
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oil
fuel consumption
lubricating oil
automobile engine
engine
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CN108949325B (en
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蔡洪涛
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • C10M2203/065Well-defined aromatic compounds used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/54Fuel economy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/72Extended drain
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/255Gasoline engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

It is a kind of with reducing the automobile engine lubricating oil of machine oil and fuel consumption function simultaneously, it includes: a kind of standard compound additive by API formula certification, a kind of pour-point depressant authenticating recipe requirements, a kind of viscosity index improver authenticating recipe requirements, the base oil of two to three kinds of certification recipe requirements, a kind of alkylnaphthalene synthetic base oil, a kind of organic polymer friction improver;These described materials are deployed into product oil by lubricating oil standard production procedure;The product oil physical and chemical index of these materials allotment meets API appropriate level requirement, and wherein the 100 of product oil DEG C kinematic viscosity reaches the medium value requirement on the upper side in viscosity grade.The engine oil mixed with the present invention is compared with the standard recipe engine oil authenticated by API, in addition to the quality standard for reaching API, shear stability also with higher is good and lower coefficient of friction, has while reducing the function of Lubricant of Automobile Engine and fuel consumption, furthermore oil drain interval is extended.

Description

It is a kind of with reducing the automobile engine lubricating oil of machine oil and fuel consumption function simultaneously And preparation method thereof
Technical field
The present invention relates to technical field of lubricating oil, have the function of more particularly to one kind while reducing machine oil and fuel consumption Automobile engine lubricating oil and preparation method thereof.
Background technique
Automobile engine lubricating oil, abbreviation engine oil, primary lubricant cylinder and piston ring, air inlet and exhaust valve, snail The effects of it is secondary to take turns the components friction such as booster, crankshaft and camshaft bearing, plays wear-resistant, sealing, cooling, antirust, peace and quiet, damping. It is 100 DEG C of kinematic viscosity that engine oil, which has a most important index, and abbreviation KV100, it is to measure frictional resistance in oil product Main indicator, the high-temperature viscosity grade of oil product is exactly to distinguish by KV100.The viscosity of oil product directly determines its wear-resistant profit Sliding effect, sealing effect and engine interior energy consumption.The viscosity of oil product is higher, and bearing capacity is stronger, wear-resistant protection is better, sealing Effect is better, but engine interior energy consumption is higher;The viscosity of oil product is lower, and bearing capacity is smaller, wear-resistant effect is poorer, sealing effect Fruit is poorer, but engine interior energy consumption is lower.The sealing effect of engine oil is related to consumption of lubricating oil, and engine interior energy consumption is straight Connecing influences vehicle fuel consumption.Sealing performance is better, and consumption of lubricating oil is lower;Sealing performance is poorer, and consumption of lubricating oil is bigger.Engine Internal energy consumption is higher, and vehicle fuel consumption is bigger;Engine interior energy consumption is lower, and vehicle fuel consumption is smaller.In this way, engine The consumption of the viscosity practical consumption for directly affecting automobile engine oil and fuel oil of oil.This is a pair of contradictory body, improves engine oil Viscosity can reduce consumption of lubricating oil, but increase fuel consumption.
With the development of auto manufacturing technology and the upgrading of motor vehicle emission environmental regulation, the operating condition of engine is increasingly Harshness needs matched engine oil.The standard of China's automobile engine oil is formulated according to API standard, API using Formula certification licensing system.It is mainly researched and developed by internationally famous lube oil additive company by the formula of API certification, lubricating oil system It makes quotient and is produced by it by the standard recipe of API certification, to meet the standard requirements of API.But this has caused another problem, addition The formula that agent company provides is standard condition-new car and specific operating condition by the condition of certification, what engine oil designed Viscosity configuration is smaller.The vehicle of actual motion is because distance travelled is different, vehicle material is different, working condition is different, starts mechanism Manufacturing accuracy is different, and engine respectively rubs, and secondary wear condition is different, gap is different, is difficult to use additive in same viscosity grade The low viscous formula of company solves the lubrication of various automobile engines.The result is that using this standard recipe oil product to most of vehicle Appearance engine oil pressure is low, consumption of lubricating oil is big (being most with the Europe such as Audi, benz, BMW, Passat system's vehicle), engine noise is big, The problems such as oil life is short, engine failure is frequent etc..In consideration of it, some lubricating oil manufacturers are on the basis using standard recipe On solved these problems by improving Engine Oil Viscosity, but following generate that engine fuel consumption is excessive, vehicle is dynamic Power decline is not suitable with the new problems such as new car and the preferable vehicle of vehicle condition.
There are some additives for lubricating oil in the prior art, reduces lubricating oil by the way of adding nano particle Coefficient of friction, but nano particle is immiscible with lubricating oil, and additive capacity causes greatly very much ash content to be higher than engine oil standard, and And high expensive, it loses more than gain.Therefore, it is high to there is consumption of lubricating oil height, fuel consumption in existing automobile engine oil in use Problem is able to solve there is presently no lubricant formula in the prior art while reducing consumption of lubricating oil and engine fuel consumption The problem of.
Summary of the invention
In view of this, the present invention provides a kind of with the automobile engine profit for reducing machine oil and fuel consumption function simultaneously Lubricating oil and preparation method thereof, can under the premise of meeting automotive engine lubrication requirement and meanwhile solve engine oil consumption it is high, Engine fuel consumes high problem, and extends the service life of engine oil and engine, thus more suitable for practical.
In order to reach above-mentioned first purpose, the vapour provided by the invention having while reducing machine oil and fuel consumption function The technical solution of car engine lubricating oil is as follows:
It is a kind of with reducing the automobile engine lubricating oil of machine oil and fuel consumption function simultaneously, which is characterized in that including Raw material based on quality percentage below: compound additive, the pour-point depressant of 0.3-0.5% certification recipe requirements, dosage are no more than 9% The viscosity index improvers of certification recipe requirements, the 60-75% certification base oil of recipe requirements, 5-10% alkylnaphthalene synthetic base oil, 0.3%~1.0% organic polymer friction improver, wherein the compound additive is the standard by API formula certification Compound additive, dosage are the required additive amount of certification formula, remaining raw material is according to the dosage of compound additive in respective institute It states selection, the product oil physical and chemical index mixed in percentage range and meets API appropriate level requirement, wherein the 100 of product oil DEG C kinematic viscosity reaches the medium value requirement on the upper side in viscosity grade.
In raw material in automobile engine lubricating oil of the invention, compound additive should be gated to be formulated with API and be authenticated Standard compound additive, as composite gasoline and engine oil additive (adjust gasoline engine oil) Afton Chemical Corp. HiTEC 9490 or HiTEC 11100 or the P6660 of Run Yinglian company etc., dosage are 10.1wt.%~13.5wt.%: or diesel engine oil is compound adds Add the D3494 of agent (adjust diesel engine oil) Run Yinglian company, the HiTEC 1255 of Afton Chemical Corp., dosage be 13.2wt.%~ 16.2wt.%.Correspondingly, pour-point depressant, viscosity index improver, base oil then should be using the models of certification recipe requirements, as pour-point depressant is Polymethacrylates or vinylacetate/fumarate co-polymer;Viscosity index improver is distributed olefin copolymer or hydrogen Change styrene isoprene;Base oil is that II class is hydrocracked that paraffin base oil, III class are secondary to be hydrocracked isomerization dewaxing stone Two to three kinds in cerul base oil or IV class polyalphaolefin synthetic base oil.
Select through standard compound additive, pour-point depressant, viscosity index improver, the base oil of API formula certification is to reach hair Motivation oil quality standard minimum requirements.
Further, the product oil physical and chemical index mixed meets API appropriate level requirement, wherein product oil 100 DEG C of kinematic viscosity reach the medium value requirement on the upper side in viscosity grade, are the sealings in order to ensure oil product in hot operation Effect reduces consumption of lubricating oil.
Further, the alkylnaphthalene synthetic base oil is increased in the standard recipe by API formula certification and have Two kinds of critical materials of machine polymer friction improver, the changeable Frotteurism that acts synergistically improve condition of boundary lubrication, reduce Component wear, the coefficient of friction for significantly reducing oil product and frictional resistance improve oil product thermal oxidation stability and shear stability, from And the running resistance of each lubricant housings of engine is reduced under high stick part, reduces vehicle fuel consumption.The alkylnaphthalene synthesis Base oil is high viscosity, low pour point alkylnaphthalene synthetic base oil, such as AN23, AN30.The organic polymer friction improver For organo-molybdenum friction agent or polymer electrolyte organic friction modifiers, Molyvan855, standing grain major company such as Vanderbilt company Perfad 3057 etc..
The present invention has while reducing the automobile engine lubricating oil of machine oil and fuel consumption function and can use with lower section Method preparation: being first added blending kettle for base oil and alkylnaphthalene synthetic base oil, stirs 5 to 10 minutes, adds viscosity index improver stirring 5 To 10 minutes, compound additive, organic friction modifiers stirring 5 to 10 minutes is then added, is eventually adding pour-point depressant stirring 30 To 50 minutes, 55 to 65 DEG C of oil product temperature in blending kettle.
The effect of each raw material, requirement etc. are as follows in the present invention:
Pour-point depressant, effect are to adjust the cryogenic property of oil product.
Viscosity index improver, effect are the viscosity temperature characteristics for improving oil product, improve oil viscosity, deposited by the oil viscosity that viscosity index improver improves It in slitter loss, will increase greasy filth, influence oil product service life, it is few as far as possible to use, it is no more than 9%.
Base oil, for it is high viscous, in glue, it is low it is viscous in two or three of base oil combination, to adjust the high and low temperature of oil product Performance, dosage are not limited by certification formula, but the physical and chemical index of product oil must reach the requirement of API correlation rank after allotment, and 100 DEG C of kinematic viscosity reach the medium value requirement on the upper side in viscosity grade.
Alkylnaphthalene synthetic base oil, specifications and models and dosage are determined according to product oil viscosity grade, are used as much as possible height Viscous oil and large dosage, minimum amount are not less than 5%.The alkylnaphthalene synthetic base oil should have excellent thermal oxide stable Property, shear stability, hydrolytic stability, additive dissolubility and lower evaporation loss and good compatible with sealing material Property.It is to improve the shear stability of oil product in use with the purpose of this material, the high temperature viscosity of oil product is made to keep stablizing, To improve the high temperature lubrication property and sealing performance, reduction consumption of lubricating oil of oil product.Meanwhile this material can also increase compound addition The dissolubility of other materials, plays synergistic effect, can extend machine oil service life in agent and formula.Alkylnaphthalene synthesis basis The defect of oil is that low temperature flow is slightly poor, to be adjusted by base oil.
Organic polymer friction improver is organo-molybdenum friction agent or polymer electrolyte organic friction modifiers, such as CRODA (standing grain The Perfad 3057 produced greatly).This material is free of metal component, does not have shadow to the ash content of product oil, S and P element ingredient It rings, it and the alkylnaphthalene synthetic base oil act synergistically and Frotteurism can be changed, improve condition of boundary lubrication, reduce mill Damage, the coefficient of friction and frictional resistance for significantly reducing oil product, to reduce the fortune of each lubricant housings of engine under high stick part Row resistance reduces vehicle fuel consumption.
The present invention has while reducing the automobile engine lubricating oil of machine oil and fuel consumption function, and physical and chemical index meets The requirement of API appropriate level, wherein the 100 of product oil DEG C kinematic viscosity reaches the medium value requirement on the upper side in viscosity grade, refers to The product oil physical and chemical index of these materials allotment is in the critical field of API, but 100 DEG C of kinematic viscosity of product oil are necessary Reach the medium value requirement on the upper side in viscosity grade,.Such as gasoline engine oil SN 5W40, except physical and chemical index must reach API Outside SN5W40 standard, 100 DEG C of kinematic viscosity reach 14.5mm2/ s or more.Common 100 DEG C of kinematic viscosity grades have 30,40, 50, corresponding 100 DEG C of kinematic viscosity ranges are 9.3-12.5,12.5-16.3,16.3-21.9mm2/ s, present invention provide that corresponding 100 DEG C of kinematic viscosity ranges be 11.0-11.5,14.5-15.5,19.0-19.5mm2/s。
The invention has the benefit that the engine oil mixed with the present invention is sent out with the standard recipe by API certification Motivation oil is compared, in addition to the quality standard for reaching API, high temperature kinematic viscosity also with higher, shear stability is good and compared with Low coefficient of friction, and the synergistic action effect of primary standard formula materials is effectively excited, thus sealing performance is more preferable, friction Resistance is smaller, lubrication protection effect is more preferable, Oil life is longer, has while reducing Lubricant of Automobile Engine and fuel consumption Function, furthermore oil drain interval is extended.It is identical as engine lubricating oil with the product manufacture deployed of the present invention, product at This increase very little, but the scope of application of product and cost performance are increased dramatically.The different product and automobile deployed with the present invention The first charge of oil of factory's configuration, depot specify after-sale service international top-brand oil, API formula Valuation Standard oil to carry out a large amount of peers and started Machine oil compares road performance test with vehicle, test result: with these oil products oil drain interval domestic demand supplement machine oil vehicle as run quickly, BMW, Audi etc. are not supplemented machine oil, and 5% or more vehicle fuel consumption decline, engine oil oil drain interval extends one times or more.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, it is carried out below in conjunction with the embodiment of the present invention clear It describes to Chu, it is clear that described embodiments are some of the embodiments of the present invention, instead of all the embodiments.Based on this hair Embodiment in bright, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
Embodiment one
The five-star composite gasoline and engine oil additive of Infineum company is P6660, has passed through API SN, ACEA A5/ B5, VW501 01/,502 00/,505 00, BMW LL-01, MB 229.3/229.5, Porsche A40 certification, pass through certification Standard recipe and allotment gasoline engine oil SN0W40 survey index such as table one:
Based on above-mentioned standard recipe, increase a kind of high viscosity alkylnaphthalene synthesis base marked as AN23 of NACO production Plinth oil 6% (wt), the organic polymer friction improver 0.5% marked as Perfad 3057 for being further added by a kind of CRODA production (wt), compound additive P6660, pour-point depressant V385 dosage are constant, and control viscosity index improver dosage is not higher than 9% (wt), adjustment basis Oily dosage is until the product physical and chemical index after allotment meets API SN0W40 standard requirements, and 100 DEG C of kinematic viscosity are in 14.5- 15.5mm2Within the scope of/s.Formula adjusted and the gasoline engine oil SN0W40 of allotment survey index such as table two according to the method:
The engine lubricating oil SN0W40 physical and chemical index comparison of above-described standard recipe and inventive formulation allotment is such as Table three:
By three comparing result of table, 100 DEG C of fortune of the gasoline engine oil SN0W40 of inventive formulation and standard recipe allotment Kinetic viscosity increases by 5.07%, and sealing performance is more preferable, and consumption of lubricating oil can reduce;Low-temperature dynamic viscosity CCS decline 11.17%, low temperature Mobility is more preferable;High-temperature high shear viscosity HTHS increases by 8.33%, and high temperature anti-shear ability is stronger;Evaporation loss decline 27.27%, consumption of lubricating oil can reduce;Average friction drop in resistance 40.77%, engine operating is more brisk, and fuel consumption will It reduces;Wear scar diameter decline 23.78%, abrasion reduces, and engine lubrication protection is more preferable.Therefore, have while reducing automobile hair The ability of motivation machine oil and fuel consumption.
Gasoline engine oil SN0W40, the standard recipe deployed on 2010 sections of BMW 730Li vehicles with aforementioned present invention formula The gasoline engine oil SN0W40 of allotment and first charge of oil SN0W40, BMW after-sale service international top-brand oil SN0W40 carry out driving comparison Consumption of lubricating oil, fuel consumption, wear condition and the oil drain interval of different engine oil vehicles are tested in test.Consumption of lubricating oil is Total charging machine oil mass of one oil drain interval releases the difference of oil level at the end of.Fuel consumption is vehicle in one is changed oil The ratio of the total dosage of the gasoline of journey and traveling total kilometrage is average value.By GB/T 8028-2010, " gasoline engine oil changes wear condition Oil index " as defined in method detect metallic element.Oil drain interval recommends mileage by each oil product and refers to GB/T 8028-2010 " vapour Oil machine oil criteria for changing oil " standard progress.Test vehicle is a company business vehicle, and vehicle vehicle condition, operating condition are normal, matches gasoline engine Oily SN0W40, travel route are random.During the test, with BMW brand oil after sale when driving to 5000km because of machine oil lamp report Alert to supplement 1L machine oil, other are not supplemented.Road tests such as table four:
According to table four, by GB/T19055-2003 " automobile engine reliability test method " standard, rated speed is born entirely Machine oil/fuel consumption ratio must not exceed 0.3% when lotus, using the consumption of lubricating oil of above-mentioned four kinds of oil products all in critical field, this Invention formula consumption of lubricating oil is minimum, and 40% is had dropped compared with standard recipe, is the 15% of brand oil.With inventive formulation machine oil Average fuel consumption than having dropped 7.81% with first installation oil, have dropped 11.28% than highest brand oil;Oil drain interval ratio Highest standard recipe machine oil increases 66.67%, is 5 times of first charge of oil.Oily metallic element after the use of inventive formulation machine oil Content value added is minimum, and wear-resistant protective effect is best;100 DEG C of kinematic viscosity variations are minimum, and the anti-shear ability of oil product is most strong.Cause This, the present invention is real in the present embodiment to be had the function of while reducing machine oil and fuel consumption.
Embodiment two
The composite gasoline and engine oil additive HiTEC 11100 of Afton company has passed through API SN, GM dexos1, ILSAC GF-5 certification surveys index such as table one by the standard recipe of certification and the gasoline engine oil SN5W30 of allotment:
Based on above-mentioned standard recipe, increase a kind of high viscosity alkylnaphthalene synthesis base marked as AN23 of NACO production Plinth oil 5% (wt), the organic polymer friction improver 0.5% marked as Perfad 3057 for being further added by a kind of CRODA production (wt), 11100 dosage of compound additive HiTEC is constant, increases pour-point depressant V385 0.2% (wt), and control viscosity index improver dosage is not Higher than 9% (wt), base oil dosage is adjusted until the product physical and chemical index after allotment meets API SN5W30 standard requirements, 100 DEG C kinematic viscosity is in 11.0-11.5mm2Within the scope of/s.The gasoline engine oil SN5W30 of formula and allotment adjusted according to the method Survey index such as table two:
The engine lubricating oil SN5W30 physical and chemical index comparison of above-described standard recipe and inventive formulation allotment is such as Table three:
By three comparing result of table, 100 DEG C of fortune of the gasoline engine oil SN5W30 of inventive formulation and standard recipe allotment Kinetic viscosity increases by 2.46%, and sealing performance is more preferable, and consumption of lubricating oil can reduce;Low-temperature dynamic viscosity CCS decline 12.78%, low temperature Mobility is more preferable;High-temperature high shear viscosity HTHS increases by 9.37%, and high temperature anti-shear ability is stronger;Evaporation loss decline 23.81%, consumption of lubricating oil can reduce;Average friction drop in resistance 37.16%, engine operating is more brisk, and fuel consumption will It reduces;Wear scar diameter decline 24.77%, abrasion reduces, and engine lubrication protection is more preferable.Therefore, have while reducing automobile hair The ability of motivation machine oil and fuel consumption.
On 2010 sections of general Chevrolet Lova 1.6L vehicles with aforementioned present invention formula deploy gasoline engine oil SN5W30, The gasoline engine oil SN5W30 and first charge of oil SN5W30, general after-sale service brand oil SN5W30 of standard recipe allotment drive a vehicle Comparative test tests consumption of lubricating oil, fuel consumption, wear condition and the oil drain interval of different engine oil vehicles.Machine oil disappears Consumption is that total charging machine oil mass of an oil drain interval releases the difference of oil level at the end of.Fuel consumption is that vehicle is changed at one The ratio of the total dosage of the gasoline of oily mileage and traveling total kilometrage is average value.Wear condition presses GB/T 8028-2010 " gasoline engine Oily criteria for changing oil " as defined in method detect metallic element.Oil drain interval recommends mileage by each oil product and refers to GB/T 8028- 2010 " gasoline engine oil criteria for changing oil " standards carry out.Test vehicle is company's officer's car, and vehicle vehicle condition, operating condition are normal, With gasoline engine oil SN5W30, travel route is random.During test, do not supplemented in an oil drain interval as defined in each oil product Machine oil.Road tests such as table four:
According to table four, by GB/T19055-2003 " automobile engine reliability test method " standard, rated speed is born entirely Machine oil/fuel consumption ratio must not exceed 0.3% when lotus, using the consumption of lubricating oil of above-mentioned four kinds of oil products all in critical field, this Invention formula consumption of lubricating oil is minimum, and 33.33% is had dropped compared with standard recipe.Disappeared with the average fuel of inventive formulation machine oil Loss-rate has dropped 10.87% with standard recipe machine oil;Oil drain interval increases 100% than highest standard recipe machine oil, is just 4 times of charge of oil.Oily metal element content value added is minimum after the use of inventive formulation machine oil, and wear-resistant protective effect is best;100℃ Kinematic viscosity variation is minimum, and the anti-shear ability of oil product is most strong.Therefore, the present invention is real in the present embodiment has while reducing The effect of machine oil and fuel consumption.
Embodiment three
The diesel engine oil compound additive D3494 of Infineum company passed through API CJ-4/CI-4, ACEA E7/E9, The certification such as MB 228.31, MAN3275, Volvo VDS-4 passes through the standard recipe of certification and the diesel engine oil CJ-4 of allotment 10W40 surveys index such as table one:
Based on above-mentioned standard recipe, increase a kind of high viscosity alkylnaphthalene synthesis base marked as AN23 of NACO production Plinth oil 9% (wt), the organic polymer friction improver 0.5% marked as Perfad 3057 for being further added by a kind of CRODA production (wt), compound additive D3494 dosage is constant, and pour-point depressant V385 dosage is adjusted to 0.3% (wt), and control viscosity index improver dosage is not high In 9% (wt), adjusts product physical and chemical index of the base oil dosage after allotment and meets API CJ-4 10W40 standard requirements, 100 DEG C of kinematic viscosity are in 14.5-15.5mm2Within the scope of/s.The diesel engine oil CJ- of formula and allotment adjusted according to the method 4 10W40 survey index such as table two:
The engine lubricating oil CJ-4 10W40 physical and chemical index pair of above-described standard recipe and inventive formulation allotment Such as table three:
By three comparing result of table, the 100 of the diesel engine oil CJ-4 10W40 of inventive formulation and standard recipe allotment DEG C kinematic viscosity increases by 21.36%, and sealing performance is more preferable, and consumption of lubricating oil can reduce;Low-temperature dynamic viscosity CCS decline 25.32%, Low temperature flow is more preferable;High-temperature high shear viscosity HTHS increases by 15.82%, and high temperature anti-shear ability is stronger;Evaporation loss decline 33.88%, consumption of lubricating oil can reduce;Average friction drop in resistance 31.22%, engine operating is more brisk, and fuel consumption will It reduces;Wear scar diameter decline 23.22%, abrasion reduces, and engine lubrication protection is more preferable.Therefore, have while reducing automobile hair The ability of motivation machine oil and fuel consumption.
The diesel engine oil deployed on 2011 sections of Feitian Ou Man, 336 horsepower of six axis logistic car with aforementioned present invention formula CJ-4 10W40, the diesel engine oil CJ-4 10W40 of standard recipe allotment and first charge of oil CH-4 15W40, Feitian Ou Man take after sale Certain brand oil CH-4 15W40 that is engaged in carries out driving comparative test, and test is disappeared with consumption of lubricating oil, the fuel oil of different engine oil vehicles Consumption, wear condition and oil drain interval.Consumption of lubricating oil is that total charging machine oil mass of an oil drain interval releases oil level at the end of Difference.Fuel consumption is ratio of the vehicle in the total dosage of diesel oil of an oil drain interval and traveling total kilometrage, is average value.Mill Damage situation detects metallic element by method as defined in GB/T 7607-2010 " diesel engine oil criteria for changing oil ".Oil drain interval presses each oil Product are recommended mileage and are carried out with reference to GB/T 7607-2010 " diesel engine oil criteria for changing oil " standard.Test vehicle is company's object Vehicle is flowed, vehicle vehicle condition, operating condition are normal, match diesel engine oil CJ-4/CI-4/CH-4 15W40,10W40, travel route is Beijing To Yiwu.During test, machine oil is not supplemented in an oil drain interval as defined in each oil product.Road tests such as table Four:
According to table four, by GB/T19055-2003 " automobile engine reliability test method " standard, rated speed is born entirely Machine oil/fuel consumption ratio must not exceed 0.3% when lotus, using the consumption of lubricating oil of above-mentioned four kinds of oil products all in critical field, this Invention formula consumption of lubricating oil is minimum, has dropped 50% compared with the first charge of oil to behave oneself best.With being averaged for inventive formulation machine oil Fuel consumption ratio has dropped 10.17% with first installation oil, and oil drain interval increases 66.67% than highest standard recipe machine oil, It is 3.3 times of first charge of oil.Oily metal element content value added is minimum after the use of inventive formulation machine oil, and wear-resistant protective effect is most It is good;100 DEG C of kinematic viscosity variations are minimum, and the anti-shear ability of oil product is most strong.Therefore, the present invention is real in the present embodiment has The effect of machine oil and fuel consumption is reduced simultaneously.
It will be understood by those skilled in the art that above embodiments are only exemplary embodiments, without departing substantially from spirit of the invention In the case where range, a variety of variations can be carried out, replaced and changed.

Claims (8)

1. a kind of with reducing the automobile engine lubricating oil of machine oil and fuel consumption function simultaneously, which is characterized in that including with Under raw material based on quality percentage: compound additive, the pour-point depressant of 0.3-0.5% certification recipe requirements, dosage are no more than 9% Authenticate the viscosity index improver of recipe requirements, base oil, the 5-10% alkylnaphthalene of two to three kinds of certification recipe requirements of 60-75% synthesize base Plinth oil, 0.3%~1.0% organic polymer friction improver, wherein the compound additive be pass through API formula certification Standard compound additive, dosage is the required additive amount of certification formula, remaining raw material exists according to the dosage of compound additive Selection in the respective percentage range;The base oil is that II class is hydrocracked that paraffin base oil, III class be secondary plus hydrogen is split Two to three kinds in change isomerization dewaxing paraffin base oil or IV class polyalphaolefin synthetic base oil.
2. the automobile engine lubricating oil according to claim 1 having while reducing machine oil and fuel consumption function, It is characterized in that, the automobile engine lubricating oil being deployed into, 100 DEG C of kinematic viscosity 0W-30,5W-30 grades is formed by the raw material 11.0-11.5mm is not reached2/ s, 0W-40,5W-40,10W-40,15W-40 rank reach 14.5-15.5mm2/ s, 20W-50 grade 19.0-19.5mm is not reached2/s。
3. the automobile engine lubricating oil according to claim 1 having while reducing machine oil and fuel consumption function, It is characterized in that, the compound additive is HiTEC 9490, HiTEC 11100, one in P6660, D3494, HiTEC 1255 Kind.
4. the automobile engine lubricating oil according to claim 1 having while reducing machine oil and fuel consumption function, It is characterized in that, the pour-point depressant is polymethacrylates or vinylacetate/fumarate co-polymer.
5. the automobile engine lubricating oil according to claim 1 having while reducing machine oil and fuel consumption function, It is characterized in that, the viscosity index improver is distributed olefin copolymer or hydrogenated styrene isoprene.
6. the automobile engine lubricating oil according to claim 1 having while reducing machine oil and fuel consumption function, It is characterized in that, the alkylnaphthalene synthetic base oil is AN23 or AN30.
7. the automobile engine lubricating oil according to claim 1 having while reducing machine oil and fuel consumption function, It is characterized in that, the organic friction modifiers are organo-molybdenum friction agent or polymer electrolyte organic friction modifiers.
8. -7 any automotive engine lubrication having while reducing machine oil and fuel consumption function according to claim 1 The preparation method of oil, which is characterized in that blending kettle first is added in base oil and alkylnaphthalene synthetic base oil, is stirred 5 to 10 minutes, It adds viscosity index improver to stir 5 to 10 minutes, compound additive, organic friction modifiers stirring 5 to 10 minutes is then added, finally Pour-point depressant is added to stir 30 to 50 minutes, 55 to 65 DEG C of oil product temperature in blending kettle.
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