CN108947428A - A kind of control method of gangue spontaneous combustion - Google Patents
A kind of control method of gangue spontaneous combustion Download PDFInfo
- Publication number
- CN108947428A CN108947428A CN201810766684.4A CN201810766684A CN108947428A CN 108947428 A CN108947428 A CN 108947428A CN 201810766684 A CN201810766684 A CN 201810766684A CN 108947428 A CN108947428 A CN 108947428A
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- Prior art keywords
- gangue
- layer
- spontaneous combustion
- flyash
- building
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- 238000002485 combustion reaction Methods 0.000 title claims abstract description 22
- 230000002269 spontaneous effect Effects 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000010881 fly ash Substances 0.000 claims abstract description 33
- 239000002893 slag Substances 0.000 claims abstract description 23
- 239000003245 coal Substances 0.000 claims abstract description 19
- 239000004567 concrete Substances 0.000 claims abstract description 17
- 238000011160 research Methods 0.000 claims abstract description 15
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 14
- 238000000465 moulding Methods 0.000 claims abstract description 10
- 239000004746 geotextile Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 13
- 229910052602 gypsum Inorganic materials 0.000 claims description 9
- 239000010440 gypsum Substances 0.000 claims description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 7
- 239000000920 calcium hydroxide Substances 0.000 claims description 7
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 230000002194 synthesizing effect Effects 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000012827 research and development Methods 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 abstract description 7
- 239000002910 solid waste Substances 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 4
- 239000000428 dust Substances 0.000 abstract description 3
- 238000005067 remediation Methods 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 description 6
- 239000004568 cement Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000005065 mining Methods 0.000 description 4
- 239000011150 reinforced concrete Substances 0.000 description 4
- 239000005997 Calcium carbide Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/08—Flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/12—Waste materials; Refuse from quarries, mining or the like
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04G—SCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
- E04G21/00—Preparing, conveying, or working-up building materials or building elements in situ; Other devices or measures for constructional work
- E04G21/02—Conveying or working-up concrete or similar masses able to be heaped or cast
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Architecture (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Mining & Mineral Resources (AREA)
- Combustion & Propulsion (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a kind of control methods of gangue spontaneous combustion, comprising the following steps: 1. remove the combustible in gangue;2. gangue+flyash+efficient the flyash excitant of carbide slag+independent research, is proportionally mixed;It is placed 3. stirring evenly, is fabricated to coal gangue concrete;4. carrying out building for template, poured after the completion of building with coal gangue concrete;5. carrying out placement layer by layer as needed, reinforcing bar is assigned to carry out the fixation between each layer between every layer;6. being laid with geotextiles carries out reinforcing wall;7. pair building built carries out shape beautification, such as moulding and greening.The advantages of the present invention over the prior art are that: intensity is high, anti- soda acid corrodes, air can effectively be completely cut off, the necessary condition of the gangues spontaneous combustion such as rainwater, thoroughly solve the spontaneous combustion of gangue, the problems such as fugitive dust, is truly realized and administers Industrial Solid Waste with Industrial Solid Waste, has great significance to China's mine environmental remediation.
Description
Technical field
The present invention relates to gangue process field, in particular to a kind of control methods of gangue spontaneous combustion.
Background technique
Gangue is the solid waste of discharge during coal mining and dressing of coal by washing, a large amount of due to containing in spoil
The rush such as pyrite and coal fire combustible, are accumulated for a long time, spontaneous combustion often occur in the case where environmental condition is suitable for, and produce
The toxic and harmful gas such as raw a large amount of SO2, CO, H2S, CO2, seriously affect the environment in mining area and the safety of people's lives and properties.
The prior art is big to the processing one side control expense of gangue, on the other hand generates secondary pollution, and success rate to environment
It is low, it on the other hand not can effectively solve surface strength and soda acid erosion problem, cannot effectively completely cut off air, the gangues such as rainwater are certainly
The necessary condition of combustion.
Summary of the invention
The technical problem to be solved by the present invention is to gangue spontaneous combustion can be effectively prevent by providing one kind in view of the above problems
Method.
In order to solve the above technical problems, technical solution provided by the invention are as follows: a kind of control method of gangue spontaneous combustion, packet
Include following steps:
1. removing the combustible in gangue;
2. gangue+flyash+efficient the flyash excitant of carbide slag+independent research, is proportionally mixed;
It is placed 3. stirring evenly, is fabricated to coal gangue concrete;
4. carrying out building for template, poured after the completion of building with coal gangue concrete;
5. carrying out placement layer by layer as needed, reinforcing bar is assigned to carry out the fixation between each layer between every layer;
6. being laid with geotextiles carries out reinforcing wall;
7. pair building built carries out shape beautification, such as moulding and greening.
The advantages of the present invention over the prior art are that: the gangue+flyash+efficient fine coal of carbide slag+independent research
Grey exciting agent, synthesizing new environmental protection non-reinforced concrete intensity is high, and anti-soda acid corrodes, and can effectively completely cut off air, the gangues such as rainwater
The necessary condition of spontaneous combustion carries out cofferdam to existing gangue slag muck using gangue environmental protection non-reinforced concrete, covers, moulding is green
The problems such as change etc., the thoroughly spontaneous combustion of solution gangue, fugitive dust, while science solves flyash, the Industrial Solid Wastes such as carbide slag
Environmentally friendly handling problems, be truly realized with Industrial Solid Waste administer Industrial Solid Waste, have great significance to China's mine environmental remediation.
As an improvement, the efficient flyash excitant ingredient of independent research is as follows by quality:
Carbide slag 7-11g, saltcake 9-16g, desulfurized gypsum 33-51g, calcium hydroxide 15-22g, sodium hydroxide 6-13g, sulfuric acid
Sodium 12-17g is the ratio of main component synthesizing efficient flyash excitant each component.
As an improvement, the self-service efficient flyash excitant of research and development needs to stand a period of time progress instead after water is added
It answers.
Specific embodiment
The present invention in the specific implementation, a kind of control method of gangue spontaneous combustion, comprising the following steps:
A kind of control method of gangue spontaneous combustion, comprising the following steps:
1. removing the combustible in gangue;
2. gangue+flyash+efficient the flyash excitant of carbide slag+independent research, is proportionally mixed;
It is placed 3. stirring evenly, is fabricated to coal gangue concrete;
4. carrying out building for template, poured after the completion of building with coal gangue concrete;
5. carrying out placement layer by layer as needed, reinforcing bar is assigned to carry out the fixation between each layer between every layer;
6. being laid with geotextiles carries out reinforcing wall;
7. pair building built carries out shape beautification, such as moulding and greening.
Effectively mining slag can be recycled, save a large amount of material resources and waste disposal expense, by work
Industry waste material is transformed into the building of progress protective construction after available resources, kills two birds with one stone, and saves the functional work such as cofferdam
The problem of waste of resource of Cheng Jianzhu.
The efficient flyash excitant ingredient of independent research is as follows by quality:
Carbide slag 7-11g, desulfurized gypsum 33-51g, calcium hydroxide 15-22g, sodium hydroxide 6-13g, sodium sulphate 12-17g are
The ratio of main component synthesizing efficient flyash excitant each component.
It needs to stand after the efficient flyash excitant addition water of self-service research and development and be reacted for a period of time.
Using coal gangue as raw material, it gathers materials on the spot, gangue is administered at site operation, scene, during improving mine environment, no
Secondary pollution is generated, does not consume any resource.Gangue+flyash+efficient the flyash excitant of carbide slag+independent research closes
High at novel environment friendly non-reinforced concrete intensity, anti-soda acid corrodes, and can effectively completely cut off air, the necessary item of the gangues spontaneous combustion such as rainwater
Part carries out cofferdam, covering, moulding, greening etc., thoroughly solution to existing gangue slag muck using gangue environmental protection non-reinforced concrete
The problems such as spontaneous combustion of gangue, fugitive dust, improves mining area ecological environment.
Calcium carbide waste slag cement has the enterprise of numerous maturations at home, and proprietary cement producing line digestion calcium carbide is useless
Slag.Slurry concentration is concentrated to by 5%-8% by 35%, sand pump using concentration basin and is sent into hopper, after point removing a part of supernatant
It is configured to cement slurry with sandstone, clay slip, then send calcined by rotary kiln cement.The differentiation of desulfurization gypsum powder and general land plaster
Be, desulfurization gypsum powder has renewable, and granularity is small, stable components, and objectionable impurities content is few, it is with high purity the features such as, more ring
It protects, it is ensured that the gelatification of gypsum, main material of the calcium hydroxide as concrete, when sodium hydroxide accelerates to chemically react
Between, sodium sulphate is used for reinforcing after concrete setting, and the selection of entire concrete material is more environmentally-friendly, and use is all adopted
Ore wastes, reproduction after being mixed avoid expense and labour consumed by waste disposal, also reduce the row of pollutant
It puts, the effect of environmental protection can be played.
Embodiment:
A kind of embodiment one: control method of gangue spontaneous combustion, comprising the following steps:
1. removing the combustible in gangue;
2. gangue+flyash+efficient the flyash excitant of carbide slag+independent research, is proportionally mixed;
It is placed 3. stirring evenly, is fabricated to coal gangue concrete;
4. carrying out building for template, poured after the completion of building with coal gangue concrete;
5. carrying out placement layer by layer as needed, reinforcing bar is assigned to carry out the fixation between each layer between every layer;
6. being laid with geotextiles carries out reinforcing wall;
7. pair building built carries out shape beautification, such as moulding and greening, carry out planting soil in geotextiles, after adding water curing
Greening is planted in soil layer.
The efficient flyash excitant ingredient of independent research is as follows by quality:
Carbide slag 7g, desulfurized gypsum 33g, calcium hydroxide 15g, sodium hydroxide 6g, sodium sulphate 12g are main component synthesizing efficient
The ratio of flyash excitant each component.
A kind of embodiment two: control method of gangue spontaneous combustion, comprising the following steps:
1. removing the combustible in gangue;
2. gangue+flyash+efficient the flyash excitant of carbide slag+independent research, is proportionally mixed;
It is placed 3. stirring evenly, is fabricated to coal gangue concrete;
4. carrying out building for template, poured after the completion of building with coal gangue concrete;
5. carrying out placement layer by layer as needed, reinforcing bar is assigned to carry out the fixation between each layer between every layer;
6. being laid with geotextiles carries out reinforcing wall;
7. pair building built, which carries out shape beautification, is grafted directly to geotextiles using artificial grass such as moulding and greening
On, Result of afforestation is significant.
The efficient flyash excitant ingredient of independent research is as follows by quality:
Carbide slag 11g, desulfurized gypsum 51g, calcium hydroxide 22g, sodium hydroxide 13g, sodium sulphate 17g are that main component synthesis is high
Imitate the ratio of flyash excitant each component.
A kind of embodiment three: control method of gangue spontaneous combustion, comprising the following steps:
1. removing the combustible in gangue;
2. gangue+flyash+efficient the flyash excitant of carbide slag+independent research, is proportionally mixed;
It is placed 3. stirring evenly, is fabricated to coal gangue concrete;
4. carrying out building for template, moulding refers to terraced fields, is poured after the completion of building with coal gangue concrete;
5. being poured as needed, demoulding is carried out after pouring;
6. being laid with geotextiles carries out reinforcing wall;
It is reserved greenbelt at each layer of platform, in slag in such a way that platform is moved back in layering 7. being administered for gangue slag muck
While heap seals, stacking structure the most stable ensure that, meanwhile, the landscape moulding of similar terraced fields is built, opens and controls
Manage the new way of mine environment progress synchronous with beautification and greening.
The efficient flyash excitant ingredient of independent research is as follows by quality:
Carbide slag 11g, desulfurized gypsum 51g, calcium hydroxide 22g, sodium hydroxide 13g, sodium sulphate 17g are that main component synthesis is high
Imitate the ratio of flyash excitant each component.
The present invention and its embodiments have been described above, this description is no restricted, it is illustrated above also only
It is one of embodiments of the present invention, actual structure is not limited to this.All in all if the ordinary skill people of this field
Member is enlightened by it, without departing from the spirit of the invention, is not inventively designed similar to the technical solution
Frame mode and embodiment, be within the scope of protection of the invention.
Claims (3)
1. a kind of control method of gangue spontaneous combustion, it is characterised in that: the following steps are included:
1. removing the combustible in gangue;
2. gangue+flyash+efficient the flyash excitant of carbide slag+independent research, is proportionally mixed;
It is placed 3. stirring evenly, is fabricated to coal gangue concrete;
4. carrying out building for template, poured after the completion of building with coal gangue concrete;
5. carrying out placement layer by layer as needed, reinforcing bar is assigned to carry out the fixation between each layer between every layer;
6. being laid with geotextiles carries out reinforcing wall;
7. pair building built carries out shape beautification, such as moulding and greening.
2. a kind of control method of gangue spontaneous combustion according to claim 1, it is characterised in that: the independent research is efficient
Flyash excitant ingredient is as follows by quality:
Carbide slag 7-11g, desulfurized gypsum 33-51g, calcium hydroxide 15-22g, sodium hydroxide 6-13g, sodium sulphate 12-17g are main
The ratio of ingredient synthesizing efficient flyash excitant each component.
3. a kind of control method of gangue spontaneous combustion according to claim 1, it is characterised in that: the self-service research and development are efficient
It needs to stand after flyash excitant addition water and be reacted for a period of time.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810766684.4A CN108947428A (en) | 2018-07-13 | 2018-07-13 | A kind of control method of gangue spontaneous combustion |
Applications Claiming Priority (1)
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CN201810766684.4A CN108947428A (en) | 2018-07-13 | 2018-07-13 | A kind of control method of gangue spontaneous combustion |
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CN201810766684.4A Pending CN108947428A (en) | 2018-07-13 | 2018-07-13 | A kind of control method of gangue spontaneous combustion |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111233426A (en) * | 2020-03-24 | 2020-06-05 | 内蒙古科技大学 | Novel guniting material for inhibiting spontaneous combustion of gangue dump and application method thereof |
CN111715662A (en) * | 2020-06-19 | 2020-09-29 | 大同煤矿集团有限责任公司 | Spontaneous combustion preventing treatment method for gangue |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104876459A (en) * | 2015-05-15 | 2015-09-02 | 中南大学 | Coal ash activated excitant and high-content high-calcium fly-ash cement |
-
2018
- 2018-07-13 CN CN201810766684.4A patent/CN108947428A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104876459A (en) * | 2015-05-15 | 2015-09-02 | 中南大学 | Coal ash activated excitant and high-content high-calcium fly-ash cement |
Non-Patent Citations (1)
Title |
---|
赵睿: "废石膏改性全废四渣基层路用性能研究" * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111233426A (en) * | 2020-03-24 | 2020-06-05 | 内蒙古科技大学 | Novel guniting material for inhibiting spontaneous combustion of gangue dump and application method thereof |
CN111715662A (en) * | 2020-06-19 | 2020-09-29 | 大同煤矿集团有限责任公司 | Spontaneous combustion preventing treatment method for gangue |
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Application publication date: 20181207 |