CN108942631A - ULTRASONIC COMPLEX vibropolish equipment - Google Patents
ULTRASONIC COMPLEX vibropolish equipment Download PDFInfo
- Publication number
- CN108942631A CN108942631A CN201810730330.4A CN201810730330A CN108942631A CN 108942631 A CN108942631 A CN 108942631A CN 201810730330 A CN201810730330 A CN 201810730330A CN 108942631 A CN108942631 A CN 108942631A
- Authority
- CN
- China
- Prior art keywords
- main shaft
- polishing
- clamping
- shaft
- polishing trough
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B31/00—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor
- B24B31/003—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor whereby the workpieces are mounted on a holder and are immersed in the abrasive material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B31/00—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor
- B24B31/06—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor involving oscillating or vibrating containers
- B24B31/064—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor involving oscillating or vibrating containers the workpieces being fitted on a support
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B31/00—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor
- B24B31/12—Accessories; Protective equipment or safety devices; Installations for exhaustion of dust or for sound absorption specially adapted for machines covered by group B24B31/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B31/00—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor
- B24B31/12—Accessories; Protective equipment or safety devices; Installations for exhaustion of dust or for sound absorption specially adapted for machines covered by group B24B31/00
- B24B31/14—Abrading-bodies specially designed for tumbling apparatus, e.g. abrading-balls
Abstract
Including pedestal and the column being set on the base polishing groove mechanism is arranged in pedestal upper surface, being provided on column can be along the clamping workpiece mechanism that column moves up and down in ULTRASONIC COMPLEX vibropolish equipment of the present invention;The rabbling mechanism that groove mechanism includes polishing trough and is arranged in polishing trough is polished, clamping workpiece mechanism includes clip claw mechanism and the clamping jaw vibrating mechanism being connected with clip claw mechanism;Refined abrasive is contained in polishing trough;Clamping workpiece mechanism can be moved down along column, and clip claw mechanism clamping is polished part and protrudes into polishing trough to be vibrated under the driving of clamping jaw vibrating mechanism, and rabbling mechanism stirs refined abrasive and polishes to part is polished;Several ultrasonic oscillators are arranged in bottom in polishing trough.Abrasive suspension rotation and supersonic generator make abrasive suspension generate longitudinal high-frequency vibration to realize the processing to workpiece inside the longitudinally reciprocal vibration of workpiece to be processed high speed of the present invention, polishing trough, the retrofit of realization that can be economic to workpiece surface.
Description
Technical field
The invention mainly relates to surface finish work fields, and in particular to a kind of ULTRASONIC COMPLEX vibropolish equipment.
Background technique
In order to realize the efficient polishing of workpiece and to the application and expansion of ULTRASONIC COMPLEX vibropolish technology, one kind is devised
ULTRASONIC COMPLEX vibropolish equipment.For this field, have the ultrasonic polishing equipment of exploitation, but these polissoir volumes
Greatly, build process is complicated, and the ULTRASONIC COMPLEX free abrasive polissoir of thumping majority does not carry out the mixing part of abrasive material
Design.
Summary of the invention
The purpose of the present invention is to provide a kind of ULTRASONIC COMPLEX vibropolish equipment, it is big to solve existing polissoir volume,
The problem that build process is complicated and machining accuracy is not high.
In order to achieve the above object, technical scheme is as follows:
A kind of ULTRASONIC COMPLEX vibropolish equipment is arranged in pedestal upper surface and throws including pedestal and the column being set on the base
Light groove mechanism, being provided on column can be along the clamping workpiece mechanism that column moves up and down;Polishing groove mechanism includes polishing trough and sets
The rabbling mechanism in polishing trough is set, clamping workpiece mechanism includes clip claw mechanism and the clamping jaw bobbing machine being connected with clip claw mechanism
Structure;Refined abrasive is contained in polishing trough;Clamping workpiece mechanism is moved down along column, and clip claw mechanism clamping is polished part and protrudes into throwing
It is thrown by the driving vibration of clamping jaw vibrating mechanism, rabbling mechanism stirring refined abrasive and/or compound abrasive to part is polished in light slot
Light;Several ultrasonic oscillators are arranged in bottom in polishing trough.
Further, rabbling mechanism includes stirring motor, retarder, shaft coupling, transmission shaft, agitating shaft, rolling bearing, stirs
Mix axis fixture nut, agitating shaft and agitating shaft blade;The output shaft of stirring motor is connect with retarder, the connection of retarder output end
Shaft coupling, shaft coupling connect one end of transmission shaft, and the other end of transmission shaft is connected by rolling bearing with agitating shaft fixture nut
Several agitating shafts are respectively provided with agitating shaft blade on each agitating shaft.
Further, Z-direction motor, Z-direction displacement synchronous belt wheel A, Z-direction displacement synchronous belt wheel B, Z-direction position are set in column
Move synchronous belt, screw rod and pair of nut;Output axis connection the Z-direction displacement synchronous belt wheel B, Z-direction displacement synchronous belt wheel B of Z-direction motor
By Z-direction displacement synchronous band connection Z-direction displacement synchronous belt wheel A, Z-direction displacement synchronous belt wheel A connection wire rod, screw thread is matched on screw rod
Pair of nut is closed, is fixedly connected with clamping workpiece mechanism on pair of nut.
Further, clip claw mechanism includes cylinder body, clamp body head, fixture connecting rod and collet;If being arranged on clamp body head
Collet is arranged in the end of the fixture connecting rod that dry root is made up of more piece organ, every fixture connecting rod;Clamping jaw vibrating mechanism packet
Include spindle motor, main shaft synchronous pulley B, main shaft synchronous belt, main shaft synchronous pulley A, main shaft, taper shank, crankshaft, connecting rod and piston;
The output axis connection main shaft synchronous pulley B, main shaft synchronous pulley B of spindle motor passes through the synchronous band connection main shaft synchronous pulley of main shaft
A, main shaft synchronous pulley A connection main shaft, main shaft connect crankshaft by taper shank, and crankshaft connects connecting rod, and the end of connecting rod passes through piston
Pin connection piston, piston are arranged in the cylinder body of clip claw mechanism.
Further, clamping jaw vibrating mechanism is mounted in spindle box, and spindle box is fixedly connected with pair of nut, is set on the outside of crankshaft
Sliding bearing is set, sliding bearing is mounted on main shaft chamber interior wall.
Further, main shaft synchronous pulley A connection pneumatic element.
Further, ultrasonic oscillator setting number is two, three, four or six, they are arranged at equal intervals throws
Bottom in light slot.
Further, polishing trough is the cylindrical structure of upper end opening.
Further, refined abrasive includes abrasive material and mixed solution, and abrasive material includes aluminum oxide powder, silica
Powder, titanium dioxide powder, bortz powder, carborundum powder, silicon nitride powder, brown iron oxide, white alundum powder and boron carbide powder one
Kind or it is a variety of, mixed solution include water, glycerine, cyclohexane, alcohol, carbon tetrachloride, kerosene, glyceride and respectively it is corresponding
It is one or more.
The invention has the advantages that
The present invention uses main body of the fluid as polishing, and adds corresponding high speed machine vibration and ultrasonic vibration to work
Part applies corresponding polishing force, and the abrasive material selected in the present invention is more fine, therefore surface forming effect is better,
Precision can reach micrometer level;The horizontal rotation of complex vibration and lapping liquid in the present invention can form stable work vibration
, allow the lapping liquid with a kind of relatively stable velocity shock workpiece surface, realizes the mesh processed for surface fine
's;Ultrasonic wave is added in the present invention as one of vibration source, and ultrasonic activation has certain cleaning capacity, it can be to work
The pollutant on part surface is cleaned, and is conducive to being uniformly distributed for lapping liquid, can form higher working efficiency.
Detailed description of the invention
Fig. 1 is overall structure diagram of the invention;
Fig. 2 is the structural schematic diagram of rabbling mechanism of the present invention;
Fig. 3 is the structural schematic diagram of Z-direction displacement mechanism of the present invention;
Fig. 4 is the structural schematic diagram of clamping jaw vibrating mechanism of the present invention;
In figure, 1- pedestal, 2- column, 3- polish groove mechanism, 4- clamping workpiece mechanism, 5- stirring motor, 6- retarder, 7- shaft coupling
Device, 8- transmission shaft, 9- stabilizer blade, 10- rolling bearing, 11- agitating shaft fixture nut, 12- agitating shaft, 13- agitating shaft blade, 14-Z
To motor, 15-Z to displacement synchronous belt wheel A, 16-Z to displacement synchronous belt wheel B, 17-Z to displacement synchronous band, 18- screw rod, 19- spiral shell
Female pair, 20- cylinder body, 21- clamp body head, 22- fixture connecting rod, 23- collet, 24- spindle motor, 25- main shaft synchronous pulley B,
26- main shaft synchronous belt, 27- main shaft synchronous pulley A, 28- main shaft, 29- taper shank, 30- crankshaft, 31- connecting rod, 32- piston, 33- are living
Plug pin, 34- spindle box, 35- sliding bearing, 36- pneumatic element, 37- ultrasonic oscillator.
Specific embodiment
To facilitate the understanding of the present invention, a more comprehensive description of the invention is given in the following sections with reference to the relevant attached drawings.In attached drawing
Give presently preferred embodiments of the present invention.But the invention can be realized in many different forms, however it is not limited to this paper institute
The embodiment of description.On the contrary, purpose of providing these embodiments is keeps the understanding to the disclosure more thorough
Comprehensively.
It should be noted that it can directly on the other element when element is referred to as " being fixed on " another element
Or there may also be elements placed in the middle.When an element is considered as " connection " another element, it, which can be, is directly connected to
To another element or it may be simultaneously present centering elements.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases
Any and all combinations of the listed item of pass.
A kind of Fig. 1-ULTRASONIC COMPLEX vibropolish equipment shown in Fig. 4 is participated in, including pedestal 1 and is arranged on pedestal 1
Polishing groove mechanism 3 is arranged in 1 upper surface of pedestal in column 2, and being provided on column 2 can be along the clamping workpiece machine that column 2 moves up and down
Structure 4;Polishing groove mechanism 3 includes polishing trough and the rabbling mechanism being arranged in polishing trough, and clamping workpiece mechanism 4 includes clip claw mechanism
The clamping jaw vibrating mechanism being connected with clip claw mechanism;Refined abrasive is contained in polishing trough;Clamping workpiece mechanism 4 can along column 2 to
Lower movement, clip claw mechanism clamping is polished part and protrudes into polishing trough to be vibrated under the driving of clamping jaw vibrating mechanism, rabbling mechanism stirring
Refined abrasive is polished to part is polished;Several ultrasonic oscillators 37 are arranged in bottom in polishing trough.
Rabbling mechanism includes stirring motor 5, retarder 6, shaft coupling 7, transmission shaft 8, rolling bearing 10, the fixed spiral shell of agitating shaft
Mother 11, agitating shaft 12 and agitating shaft blade 13;The output shaft of stirring motor 5 is connect with retarder 6, the connection of 6 output end of retarder
Shaft coupling 7, shaft coupling 7 connect one end of transmission shaft 8, and the other end of transmission shaft 8 passes through rolling bearing 10 and the fixed spiral shell of agitating shaft
Mother 11 connects several agitating shafts 12, is respectively provided with agitating shaft blade 13 on each agitating shaft 12.
Z-direction motor 14, Z-direction displacement synchronous belt wheel A15, Z-direction displacement synchronous belt wheel B16, Z-direction displacement are set in column 2
Synchronous belt 17, screw rod 18 and pair of nut 19;The output axis connection Z-direction displacement synchronous belt wheel B16 of Z-direction motor 14, Z-direction displacement synchronous
Belt wheel B16 connects Z-direction displacement synchronous belt wheel A15, Z-direction displacement synchronous belt wheel A15 connection wire rod by Z-direction displacement synchronous band 17
18, pair of nut 19 is threadedly engaged on screw rod 18, and clamping workpiece mechanism 4, the above composition Z-direction displacement machine are fixedly connected on pair of nut 19
Structure.
Clip claw mechanism includes cylinder body 20, clamp body head 21, fixture connecting rod 22 and collet 23;If being arranged on clamp body head 21
Collet 23 is arranged in the end of dry root fixture connecting rod 22, every fixture connecting rod 22;Clamping jaw vibrating mechanism include spindle motor 24,
Main shaft synchronous pulley B25, main shaft synchronous belt 26, main shaft synchronous pulley A27, main shaft 28, taper shank 29, crankshaft 30, connecting rod 31 and work
Plug 32;Output axis connection main shaft the synchronous pulley B25, main shaft synchronous pulley B25 of spindle motor 24 are connected by main shaft synchronous belt 26
Main shaft synchronous pulley A27, main shaft synchronous pulley A27 connection main shaft 28 are met, main shaft 28 connects crankshaft 30, crankshaft 30 by taper shank 29
Connecting rod 31 is connected, the end of connecting rod 31 connects piston 21 by piston pin 33, and piston 21 is arranged in the cylinder body 20 of clip claw mechanism.
Clamping jaw vibrating mechanism is mounted in spindle box 34, and spindle box 34 is fixedly connected with pair of nut 19, setting on the outside of crankshaft
Sliding bearing 35, sliding bearing 35 are mounted on 34 inner wall of spindle box.
Main shaft synchronous pulley A27 connection pneumatic element 36.
It is two, three, four or six that number, which is arranged, in ultrasonic oscillator 37, and bottom in polishing trough is arranged in they at equal intervals
Portion.
Polishing trough be upper end opening cylindrical structure.
Fixture connecting rod 22 is made of more joints, and there is stronger pawl to hold ability.
Pedestal is made of cast iron, and there are four stabilizer blades for setting on pedestal 1, it may be convenient to adjust support balance.
Refined abrasive includes abrasive material and mixed solution, and abrasive material includes aluminum oxide powder, silicon dioxide powder, titanium dioxide
Powder, bortz powder, carborundum powder, silicon nitride powder, brown iron oxide, white alundum powder and boron carbide powder it is one or more, mix
Closing solution includes water, glycerine, cyclohexane, alcohol, carbon tetrachloride, kerosene, glyceride and respective corresponding one kind or more
Kind.
The course of work of the invention is described below:
Workpiece to be processed is mounted on collet 23 to this equipment during the work time, is fixedly connected by stop nut, works as completion
After this work, Z-direction motor 14 starts, and drives the movement of 34 Z-direction of spindle box, the direction of motion towards ground, until collet 23 into
Enter at polishing trench bottom one third;In next operation time, the spindle motor 24 positioned at 34 left side of spindle box starts, bent
The connection fastening means of axis 30 is clamped by pneumatic element 36, and crankshaft 30 is rotated, and principle is mainly to utilize taper shank
The clamping of 29 self-locking performance and pneumatic element 36 realizes that 30 other end of crankshaft is positioned and propped up by sliding bearing 35
It holds (selection the reason is that being easily installed and dismantling), connecting rod 31(31 major part of connecting rod is installed on crankshaft 30 and is separated into two parts
To cooperate with crankshaft 30), 31 microcephaly of connecting rod connect with piston 32, and (part company is fixed by piston pin 20 in piston 32
Bar 31 is according to actually cannot interfering phenomenon with piston 32), which carries out reciprocal linear motion in cylinder body 20, folder
First 23 is of reciprocating vibration with the progress of piston 32 Z-direction.In this process, corresponding abrasive material and mixed solution according to processing request according to than
Example is added, and stirring motor 5 starts, and power is transferred to agitating shaft 12 and stirring by retarder 6, shaft coupling 7, transmission shaft 8
Axis blade 13 is realized to the stirring action (uniformity consistency for guaranteeing abrasive material) of refined abrasive, is equipped in polishing trench bottom more
A ultrasonic oscillator 37 is realized and the vibropolish of refined abrasive is acted on, to meet design requirement, completes complex vibration and throws
The fining requirement that light works for workpiece surface.
Use above specific case is illustrated the present invention, is merely used to help understand the present invention, not to limit
The system present invention.For those skilled in the art, according to the thought of the present invention, can also make several simple
It deduces, deform or replaces.
Claims (10)
1. ULTRASONIC COMPLEX vibropolish equipment, it is characterised in that: including pedestal (1) and column (2) on pedestal (1) is set,
In the pedestal (1) upper surface polishing groove mechanism (3) is set, being provided on the column (2) can move up and down along column (2)
Clamping workpiece mechanism (4);The rabbling mechanism that polishing groove mechanism (3) includes polishing trough and is arranged in polishing trough, the work
Part clamping mechanism (4) includes clip claw mechanism and the clamping jaw vibrating mechanism being connected with clip claw mechanism;It is contained in the polishing trough fine
Abrasive material;The clamping workpiece mechanism (4) can move down along column (2), and the clip claw mechanism clamping is polished part and protrudes into polishing
It is vibrated under the driving of clamping jaw vibrating mechanism in slot, the rabbling mechanism stirs the refined abrasive and polishes to part is polished;Institute
It states bottom in polishing trough and several ultrasonic oscillators (37) is set.
2. ULTRASONIC COMPLEX vibropolish equipment according to claim 1, it is characterised in that: the rabbling mechanism includes stirring electricity
Machine (5), retarder (6), shaft coupling (7), transmission (8), rolling bearing (10), agitating shaft fixture nut (11), agitating shaft (12)
With agitating shaft blade (13);The output shaft of the stirring motor (5) is connect with retarder (6), and retarder (6) output end connects
It connects shaft coupling (7), one end of shaft coupling (7) connection transmission shaft (8), the other end of the transmission shaft (8) passes through the axis of rolling
It holds (10) and agitating shaft fixture nut (11) connects several agitating shafts (12), be respectively provided with agitating shaft on each agitating shaft (12)
Blade (13).
3. ULTRASONIC COMPLEX vibropolish equipment according to claim 1 or claim 2, it is characterised in that: the setting in the column (2)
Z-direction motor (14), Z-direction displacement synchronous belt wheel A(15), Z-direction displacement synchronous belt wheel B(16), Z-direction displacement synchronous band (17), screw rod
(18) and pair of nut (19);The output axis connection Z-direction displacement synchronous belt wheel B(16 of the Z-direction motor (14)), the Z-direction displacement
Synchronous pulley B(16) pass through Z-direction displacement synchronous band (17) connection Z-direction displacement synchronous belt wheel A(15), the Z-direction displacement synchronous band
Take turns A(15) connection wire rod (18), it is threadedly engaged pair of nut (19) on the screw rod (18), is fixedly connected on the pair of nut (19)
The clamping workpiece mechanism (4).
4. ULTRASONIC COMPLEX vibropolish equipment according to claim 3, it is characterised in that: the clip claw mechanism includes cylinder body
(20), clamp body head (21), fixture connecting rod (22) and collet (23);Several fixtures are arranged on the clamp body head (21) to connect
Collet (23) are arranged in the end of extension bar (22), the every fixture connecting rod (22);The clamping jaw vibrating mechanism includes main shaft electricity
Machine (24), main shaft synchronous pulley B(25), main shaft synchronous belt (26), main shaft synchronous pulley A(27), main shaft (28), taper shank (29),
Crankshaft (30), connecting rod (31) and piston (32);The output axis connection main shaft synchronous pulley B(25 of the spindle motor (24)), institute
State main shaft synchronous pulley B(25) main shaft synchronous pulley A(27 is connected by main shaft synchronous belt (26)), the main shaft synchronous pulley A
(27) main shaft (28) are connected, the main shaft (28) connects connecting rod by taper shank (29) connection crankshaft (30), the crankshaft (30)
(31), the end of the connecting rod (31) is arranged by piston pin (33) connection piston (21), the piston (21) in clip claw mechanism
Cylinder body (20) in.
5. ULTRASONIC COMPLEX vibropolish equipment according to claim 4, it is characterised in that: the clamping jaw vibrating mechanism is mounted on
In spindle box (34), the spindle box (34) is fixedly connected with the pair of nut (19), and sliding bearing is arranged on the outside of the crankshaft
(35), the sliding bearing (35) is mounted on spindle box (34) inner wall.
6. ULTRASONIC COMPLEX vibropolish equipment according to claim 5, it is characterised in that: the main shaft synchronous pulley A(27)
It connects pneumatic element (36).
7. ULTRASONIC COMPLEX vibropolish equipment according to claim 6, it is characterised in that: ultrasonic oscillator (37) setting
Number is two, three, four or six, and bottom in polishing trough is arranged in they at equal intervals.
8. ULTRASONIC COMPLEX vibropolish equipment according to claim 7, it is characterised in that: the polishing trough is upper end opening
Cylindrical structure.
9. ULTRASONIC COMPLEX vibropolish equipment according to claim 8, it is characterised in that: the fixture connecting rod (22) is by more
Root joint is constituted.
10. ULTRASONIC COMPLEX vibropolish equipment according to claim 9, it is characterised in that: the refined abrasive includes abrasive material
And mixed solution, the abrasive material include aluminum oxide powder, silicon dioxide powder, titanium dioxide powder, bortz powder, silicon carbide
Powder, silicon nitride powder, brown iron oxide, white alundum powder and boron carbide powder it is one or more, the mixed solution includes water, third
Triol, cyclohexane, alcohol, carbon tetrachloride, kerosene, glyceride and respectively it is corresponding one or more.
Priority Applications (1)
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CN201810730330.4A CN108942631A (en) | 2018-07-05 | 2018-07-05 | ULTRASONIC COMPLEX vibropolish equipment |
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CN201810730330.4A CN108942631A (en) | 2018-07-05 | 2018-07-05 | ULTRASONIC COMPLEX vibropolish equipment |
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CN201810730330.4A Pending CN108942631A (en) | 2018-07-05 | 2018-07-05 | ULTRASONIC COMPLEX vibropolish equipment |
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CN109382709A (en) * | 2018-12-17 | 2019-02-26 | 嘉兴学院 | Sound wave clamps abrasive grain sapphire and magnesium alloy micropore inner surface polishing method and device |
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CN110948398A (en) * | 2019-12-06 | 2020-04-03 | 南京尚吉增材制造研究院有限公司 | Ultrasonic-assisted cavitation abrasive flow finishing method for titanium alloy surface oxide layer |
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