CN108935502A - A kind of mixed herbicide and its application containing proxazuron-methyl, penoxsuam and bentazone - Google Patents

A kind of mixed herbicide and its application containing proxazuron-methyl, penoxsuam and bentazone Download PDF

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Publication number
CN108935502A
CN108935502A CN201810862227.5A CN201810862227A CN108935502A CN 108935502 A CN108935502 A CN 108935502A CN 201810862227 A CN201810862227 A CN 201810862227A CN 108935502 A CN108935502 A CN 108935502A
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China
Prior art keywords
penoxsuam
methyl
proxazuron
bentazone
mixed herbicide
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CN201810862227.5A
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Chinese (zh)
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CN108935502B (en
Inventor
朱怀铜
汪云强
张传奇
梅洪玲
夏葵
吴文静
黄永灿
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ANHUI YOUNGSUN PESTICIDES Co Ltd
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ANHUI YOUNGSUN PESTICIDES Co Ltd
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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Abstract

The present invention provides a kind of mixed herbicide containing proxazuron-methyl, penoxsuam and bentazone and its application;Active constituent is made of proxazuron-methyl, penoxsuam and bentazone, and the weight ratio of the proxazuron-methyl, penoxsuam and bentazone is 1-40:1-20:1-100;It can be used for broadleaf weeds, gramineae weed and the prevention and treatment of nutgrass flatsedge.

Description

A kind of mixed herbicide containing proxazuron-methyl, penoxsuam and bentazone and its Using
Technical field
The invention belongs to pesticide fields, and in particular to a kind of mixing containing proxazuron-methyl, penoxsuam and bentazone Herbicide and its application.
Background technique
Proxazuron-methyl is pyrimidine radicals sulfonylurea herbicide developed by Japan Sumitomo Chemical, although with other sulfonylureas The mechanism of action of class herbicide is identical, is acetolactate synthestase (ALS) inhibitor, but it fights the miscellaneous of sulfonylurea herbicide Grass has good preventive effect, is mainly used for paddy field and prevents and kill off grass family and broadleaf weeds.The product dosage is low, to certain known sulphonyl The weeds that carbamide herbicides generate resistance have good preventive effect.Penoxsuam category triazolopyrimidine sulfonamides herbicide, can Barnyard grass, semen euphorbiae and annual sedge weed effectively are prevented and kill off, and effective to numerous broadleaf weeds, such as the raw different stamen flower in natural pond, carp Intestines, sesbania, ring flower, Monochoria vaginalis etc..Bentazone is the selective herbicide after seedling of contact killing type, can be used for rice, wheat, big The various crops Tanaka such as beans, corn, pea prevents and kill off broadleaf weeds and sedge weed.
Compounding between herbicide not only can solve the problem that pesticide single dose toxicity is big, effect is poor, but also less investment, R&D cycle It is short, and it is used interchangeably the generation for capableing of retarding action object drug resistance between different pesticides, it is imitated with ideal use Fruit, therefore the compounding of pesticide is current research focus in the field of pesticide between different role mechanism.Patent document (CN103271065A) Herbicidal combinations that effective component is proxazuron-methyl and bentazone are disclosed;Patent document (CN106172457A) Herbicidal combinations of proxazuron-methyl and penoxsuam are disclosed;Patent document (CN105519549A) Disclose the Herbicidal combinations of penoxsuam and bentazone.It proxazuron-methyl, penoxsuam and does not go out in the prior art Careless pine compounding ternary weeding composition.
Summary of the invention
The purpose of the present invention is to provide a kind of component is reasonable, drug cost is low, is not likely to produce the herbicide group of drug resistance Close object, to paddy field, wheatland grass family, broadleaf weeds, nutgrass flatsedge have preferable control efficiency, to slow down Weed Resistance, reduce Drug dosage etc. has positive effect.
The present invention provides following technical scheme
A kind of mixed herbicide containing proxazuron-methyl, penoxsuam and bentazone, active constituent by proxazuron-methyl, Penoxsuam and bentazone composition, the weight ratio of the proxazuron-methyl, penoxsuam and bentazone are 1-40:1- 20:1-100。
The weight ratio of mixed herbicide of the present invention, the proxazuron-methyl, penoxsuam and bentazone is 1-10:1-5:20-100.The weight ratio of the preferred proxazuron-methyl, penoxsuam and bentazone is 5:1:100.
Proxazuron-methyl described in mixed herbicide of the present invention, penoxsuam and bentazone are in the composition Total weight percentage composition is 1-95%.The preferred proxazuron-methyl, penoxsuam and bentazone in the composition total Weight percentage is 25-65%.
The present composition can be prepared into adaptation dosage form, preferred dosage form wettable powder with agriculturally acceptable auxiliary combination Agent dispersible has one of suspending agent, suspending agent, granule, missible oil, microemulsion, aqueous emulsion, water dispersible granules etc..It is wettable Property pulvis, missible oil, suspending agent, oil-suspending agent, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules etc..It is of the present invention Auxiliary agent includes emulsifier, dispersing agent, wetting agent, binder, disintegrating agent, thickener, stabilizer, antifreezing agent, defoaming agent filler etc.. It is selected from the common auxiliary material in this field.
Mixed herbicide of the present invention is used for the purposes of management of weeds.It is preferred for paddy field, wheatland grass family, wealthy Leaf weeds and nutgrass flatsedge, for example, it is barnyard grass, semen euphorbiae, wild avena sativa, Monochoria vaginalis, clearvers, Chinese celery, herba setariae viridis, purslane, herba digitariae, different Type nutgrass flatsedge, water amaranth, bog pondweed etc..
The present invention obtains following advantageous effects:
Composition of the present invention uses the active ingredient combinations of three kinds of different role mechanism, can effectively reduce weeds The generation of drug resistance expands degrass spectrum;Can prevent and kill off simultaneously barnyard grass, semen euphorbiae, Monochoria vaginalis, difformed galingale herb, Monochoria vaginalis, water amaranth, Bog pondweed etc..
Herbicidal combinations of the present invention have significant synergies, and Herbicidal combinations field of the present invention is anti- Effect is higher compared to the field efficacy of single dose, binary composition, can effectively reduce the administration dosage of active constituent, reduces environment Pollution.
Specific embodiment
Below with reference to embodiment, specific embodiments of the present invention will be described in detail, it is to be understood that guarantor of the invention Shield range is not limited by the specific implementation.
Embodiment 1: 28% proxazuron-methyl penoxsuam bentazone aqueous emulsion
Embodiment 2: 35% proxazuron-methyl penoxsuam bentazone suspending agent
Embodiment 3: 60% proxazuron-methyl penoxsuam bentazone wettable powder
Embodiment 4: 53% proxazuron-methyl penoxsuam bentazone water dispersible granules
Biological test one: proxazuron-methyl, penoxsuam and bentazone are to barnyard grass indoor toxicity test.
Test method: selection grows consistent weeds barnyard grass and is colonized, and does cauline leaf process, and water drenching is after blade is dry Carry out cauline leaf spraying treatment.After processing 30 days, fresh weight is measured, calculates preventive effect.
Herbicide associated form is evaluated according to Colby method.Evaluation criterion: as E ﹣ E0 > 10%, it is expressed as synergistic effect; As ﹣ 10%≤E ﹣ E0≤10%, summation action is shown as;As E ﹣ E0 < ﹣ 10%, antagonism is shown as.
1 proxazuron-methyl of table, penoxsuam and bentazone compounding are to barnyard grass indoor toxicity test
As seen from the above table, proxazuron-methyl, penoxsuam and bentazone compounding have apparent synergistic effect to barnyard grass, Three kinds of substances, which are applied in combination, can be effectively reduced Pesticide use dosage.
Biological test two: proxazuron-methyl, penoxsuam and bentazone compounding are to paddy field weed field efficacy.
Subjects: barnyard grass, semen euphorbiae, Monochoria vaginalis, difformed galingale herb, Monochoria vaginalis, water amaranth, bog pondweed etc..
Test medicine: embodiment 1-4 medicament and comparison medicament
Test method: according to experimental plot area, having weighed medicament, and be watered and be diluted, and weeds are in the 2-3 leaf phase, It is carried out cauline leaf 1 time by spraying using backpack sprayer, fresh weight preventive effect after investigation 30 days, and the activity of weeding of more various medicaments.It is anti- Imitate (%)=[(clear water control group weeds fresh weight-processing group weeds fresh weight)/clear water group weeds fresh weight] * 100%.
2 proxazuron-methyl of table, penoxsuam and bentazone compounding are to paddy field weed field efficacy
As seen from the above table, compared with single dose, proxazuron-methyl, penoxsuam and bentazone compounding application, which can expand, to be removed Grass spectrum, and its control efficiency to weeds can be significantly improved, it has significant synergies, can effectively lower applying for pesticide With dosage, reduce environmental pollution;And field observation is to crop safety.
The above is only a preferred embodiment of the present invention, to those skilled in the art, this hair is not being departed from It under the premise of bright raw material, can be suitably modified, these are improved also within protection scope of the present invention.

Claims (7)

1. a kind of mixed herbicide containing proxazuron-methyl, penoxsuam and bentazone, it is characterised in that: active constituent is by third Piperazine Sulfometuron Methyl, penoxsuam and bentazone composition, the weight ratio of the proxazuron-methyl, penoxsuam and bentazone are 1-40:1-20:1-100。
2. mixed herbicide according to claim 1, it is characterised in that: the proxazuron-methyl, penoxsuam and go out The weight ratio of careless pine is 1-10:1-5:20-100.
3. mixed herbicide according to claim 2, it is characterised in that: the proxazuron-methyl, penoxsuam and go out The weight ratio of careless pine is 5:1:100.
4. mixed herbicide according to claim 1 to 3, it is characterised in that: the proxazuron-methyl, penoxsuam and The total weight percentage composition of bentazone in the composition is 1-95%.
5. mixed herbicide according to claim 4, it is characterised in that: the proxazuron-methyl, penoxsuam and go out The total weight percentage composition of careless pine in the composition is 25-65%.
6. mixed herbicide described in -5 according to claim 1, it is characterised in that: combination dosage form can for wettable powder, can It is dispersed with one of suspending agent, suspending agent, granule, missible oil, microemulsion, aqueous emulsion, water dispersible granules etc..
7. mixed herbicide described in -6 is used for the purposes of management of weeds according to claim 1.
CN201810862227.5A 2018-08-01 2018-08-01 Mixed herbicide containing propyrisulfuron, penoxsulam and bentazone and application thereof Active CN108935502B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109699668A (en) * 2019-02-25 2019-05-03 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of ternary weeding composition and its application for paddy field weed

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103271065A (en) * 2013-06-05 2013-09-04 江苏龙灯化学有限公司 Weeding composition
CN104522027A (en) * 2014-12-22 2015-04-22 广东中迅农科股份有限公司 Herbicidal composition containing propyrisulfuron, cyhalofop-butyl and bentazone
CN104823999A (en) * 2015-05-13 2015-08-12 广东中迅农科股份有限公司 Herbicidal composition containing propyrisulfuron, pretilachlor and penoxsulam
CN105519549A (en) * 2010-08-30 2016-04-27 陶氏益农公司 Synergistic herbicidal composition containing penoxsulam and bentazon
CN105532702A (en) * 2015-12-23 2016-05-04 北京燕化永乐生物科技股份有限公司 Weeding composition
CN106172457A (en) * 2015-01-19 2016-12-07 江苏龙灯化学有限公司 A kind of Herbicidal combinations and the method controlling plant strain growth

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105519549A (en) * 2010-08-30 2016-04-27 陶氏益农公司 Synergistic herbicidal composition containing penoxsulam and bentazon
CN103271065A (en) * 2013-06-05 2013-09-04 江苏龙灯化学有限公司 Weeding composition
CN104522027A (en) * 2014-12-22 2015-04-22 广东中迅农科股份有限公司 Herbicidal composition containing propyrisulfuron, cyhalofop-butyl and bentazone
CN106172457A (en) * 2015-01-19 2016-12-07 江苏龙灯化学有限公司 A kind of Herbicidal combinations and the method controlling plant strain growth
CN104823999A (en) * 2015-05-13 2015-08-12 广东中迅农科股份有限公司 Herbicidal composition containing propyrisulfuron, pretilachlor and penoxsulam
CN105532702A (en) * 2015-12-23 2016-05-04 北京燕化永乐生物科技股份有限公司 Weeding composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109699668A (en) * 2019-02-25 2019-05-03 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of ternary weeding composition and its application for paddy field weed

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