CN108929801A - 一种基于非离子活性剂的除油剂及其制备方法 - Google Patents

一种基于非离子活性剂的除油剂及其制备方法 Download PDF

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CN108929801A
CN108929801A CN201810846044.4A CN201810846044A CN108929801A CN 108929801 A CN108929801 A CN 108929801A CN 201810846044 A CN201810846044 A CN 201810846044A CN 108929801 A CN108929801 A CN 108929801A
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degreaser
tween
polyoxyethylene ether
mixed liquor
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欧阳波
肖勇
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Guangzhou Sen Environmental Protection Technology Co Ltd
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Abstract

本发明公开了一种基于非离子活性剂的除油剂及其制备方法,包括以下原料：溶剂，烷基酚聚氧乙烯醚，高碳脂肪醇聚氧乙烯醚，脂肪酸甲酯乙氧基化物，吐温‑20，聚二甲基硅氧烷，碳酸钠，乙酸钠，六亚甲基四胺，氨基三甲亚基膦酸，柠檬酸，辛苯昔醇，十二烷基苯磺酸钠，N‑十二烷基二甲胺，壬基酚聚氧乙烯醚，磷酸三丁酯，松香酸，酒石酸，异丙醇，酵素，分散剂和缓蚀剂；本发明还提出了除油剂的制备方法；本发明通过在除油剂中添加烷基酚聚氧乙烯醚、高碳脂肪醇聚氧乙烯醚和脂肪酸甲酯乙氧基化物非离子活性剂为原料，使得制备的除油剂的除油效果好，除油效率高，而且除油迅速彻底。

Description

一种基于非离子活性剂的除油剂及其制备方法
技术领域
本发明涉及除油剂生产技术领域，尤其涉及一种基于非离子活性剂的除油剂及其制备方法。
背景技术
除油剂是以水基质的有机与无机化学品组成的复杂混合物，是利用"乳化""皂化"原理而研制的新型工业除油剂。在金属加工、食品、纺织、交通、船舶、建筑、电器、医药、化工等工业领域都有广泛的用途，虽然清洗的表面基质不尽相同，但清洗目的是一致的，都是恢复基质表面的洁净度及保持基质表面的完整性。现有的除油剂在除油过程中大量含油废液的出现，如果不及时处理，油污仍然停留在基质的表面。因此，我们提出了一种基于非离子活性剂的除油剂及其制备方法用于解决上述问题。
发明内容
本发明的目的是为了解决现有技术中存在除油剂在除油过程中大量含油废液的出现，如果不及时处理，油污仍然停留在基质的表面的缺点，而提出的一种基于非离子活性剂的除油剂及其制备方法。
一种基于非离子活性剂的除油剂，包括以下重量份的原料：溶剂42-49份，烷基酚聚氧乙烯醚10-14份，高碳脂肪醇聚氧乙烯醚12-15份，脂肪酸甲酯乙氧基化物11-15份，吐温-20 1-3份，聚二甲基硅氧烷1-2份，碳酸钠0.2-0.6份，乙酸钠0.1-0.4份，六亚甲基四胺0.3-0.5份，氨基三甲亚基膦酸1-2份，柠檬酸0.5-0.8份，辛苯昔醇0.3-0.5份，十二烷基苯磺酸钠3-4份，N-十二烷基二甲胺1-3份，壬基酚聚氧乙烯醚0.2-0.5份，磷酸三丁酯0.1-0.4份，松香酸1-3份，酒石酸0.6-0.8份，异丙醇6-9份，酵素4-5份，分散剂0.6-0.9份和缓蚀剂2-5份。
优选的，所述除油剂的原料包括以下重量份：溶剂45份，烷基酚聚氧乙烯醚12份，高碳脂肪醇聚氧乙烯醚13份，脂肪酸甲酯乙氧基化物13份，吐温-20 2份，聚二甲基硅氧烷1份，碳酸钠0.4份，乙酸钠0.3份，六亚甲基四胺0.4份，氨基三甲亚基膦酸2份，柠檬酸0.7份，辛苯昔醇0.4份，十二烷基苯磺酸钠4份，N-十二烷基二甲胺2份，壬基酚聚氧乙烯醚0.3份，磷酸三丁酯0.2份，松香酸2份，酒石酸0.7份，异丙醇8份，酵素5份，分散剂0.7份和缓蚀剂3份。
优选的，所述溶剂为乙二醇/水溶液，且乙二醇和水在溶剂中的比例为4:6。
优选的，所述分散剂为硬脂酸丁酯、乙烯－丙烯酸共聚物、乙烯－醋酸乙烯共聚物和硬脂酸钡中的一种。
优选的，所述缓蚀剂为硅酸盐、钼酸盐、聚磷酸盐、锌盐琉基苯并噻唑、苯并三唑和磺化木质素中的一种。
本发明还提出了一种基于非离子活性剂的除油剂的制备方法，包括以下步骤：
S1、按照比例称取以上重量份的原料；
S2、将上述原料充分混合，并使用搅拌机搅拌均匀后得到混合液，将混合液使用氢氧化钠溶液调节其pH值，直至混合液呈透明状态；
S3、将混合液静置30分钟后过滤，将滤液分装即为除油剂。
优选的，所述混合液使用氢氧化钠溶液调节其pH值的温度为32℃-34℃，氢氧化钠溶液的质量浓度为5％-8％。
本发明的有益效果是：
1、本发明，通过在除油剂中添加烷基酚聚氧乙烯醚、高碳脂肪醇聚氧乙烯醚和脂肪酸甲酯乙氧基化物非离子活性剂为原料，使得制备的除油剂的除油效果好，除油效率高，而且除油迅速彻底。
2、本发明，通过使用酵素为除油剂中的添加物，使得制备的除油剂不仅具备除油效果，而且在将基质表面的油污除去后还可以分解油污，避免了油污在出去后不及时清理会再次覆基在基质的表面。
具体实施方式
下面结合具体实施例对本发明作进一步解说。
实施例一：一种基于非离子活性剂的除油剂，包括以下重量份的原料：溶剂42份(乙二醇/水溶液，且乙二醇和水在溶剂中的比例为4:6)，烷基酚聚氧乙烯醚10份，高碳脂肪醇聚氧乙烯醚12份，脂肪酸甲酯乙氧基化物11份，吐温-20 1份，聚二甲基硅氧烷1份，碳酸钠0.2份，乙酸钠0.1份，六亚甲基四胺0.3份，氨基三甲亚基膦酸1份，柠檬酸0.5份，辛苯昔醇0.3份，十二烷基苯磺酸钠3份，N-十二烷基二甲胺1份，壬基酚聚氧乙烯醚0.2份，磷酸三丁酯0.1份，松香酸1份，酒石酸0.6份，异丙醇6份，酵素4份，硬脂酸丁酯0.6份和硅酸盐2份；
制备方法包括以下步骤：
S1、按照比例称取以上重量份的原料；
S2、将上述原料充分混合，并使用搅拌机搅拌均匀后得到混合液，将混合液使用氢氧化钠溶液调节其pH值(混合液使用氢氧化钠溶液调节其pH值的温度为32℃，氢氧化钠溶液的质量浓度为5％)，直至混合液呈透明状态；
S3、将混合液静置30分钟后过滤，将滤液分装即为除油剂。
实施例二：一种基于非离子活性剂的除油剂，包括以下重量份的原料：溶剂43份(乙二醇/水溶液，且乙二醇和水在溶剂中的比例为4:6)，烷基酚聚氧乙烯醚11份，高碳脂肪醇聚氧乙烯醚13份，脂肪酸甲酯乙氧基化物12份，吐温-20 2份，聚二甲基硅氧烷1份，碳酸钠0.3份，乙酸钠0.2份，六亚甲基四胺0.4份，氨基三甲亚基膦酸1份，柠檬酸0.6份，辛苯昔醇0.4份，十二烷基苯磺酸钠3份，N-十二烷基二甲胺2份，壬基酚聚氧乙烯醚0.3份，磷酸三丁酯0.2份，松香酸2份，酒石酸0.7份，异丙醇7份，酵素4份，乙烯－醋酸乙烯共聚物0.7份和聚磷酸盐3份；
制备方法包括以下步骤：
S1、按照比例称取以上重量份的原料；
S2、将上述原料充分混合，并使用搅拌机搅拌均匀后得到混合液，将混合液使用氢氧化钠溶液调节其pH值(混合液使用氢氧化钠溶液调节其pH值的温度为32℃，氢氧化钠溶液的质量浓度为6％)，直至混合液呈透明状态；
S3、将混合液静置30分钟后过滤，将滤液分装即为除油剂。
实施三：一种基于非离子活性剂的除油剂，包括以下重量份的原料：溶剂45份(乙二醇/水溶液，且乙二醇和水在溶剂中的比例为4:6)，烷基酚聚氧乙烯醚12份，高碳脂肪醇聚氧乙烯醚13份，脂肪酸甲酯乙氧基化物13份，吐温-20 2份，聚二甲基硅氧烷1份，碳酸钠0.4份，乙酸钠0.3份，六亚甲基四胺0.4份，氨基三甲亚基膦酸2份，柠檬酸0.7份，辛苯昔醇0.4份，十二烷基苯磺酸钠4份，N-十二烷基二甲胺2份，壬基酚聚氧乙烯醚0.3份，磷酸三丁酯0.2份，松香酸2份，酒石酸0.7份，异丙醇8份，酵素5份，乙烯－醋酸乙烯共聚物0.7份和苯并三唑3份；
制备方法包括以下步骤：
S1、按照比例称取以上重量份的原料；
S2、将上述原料充分混合，并使用搅拌机搅拌均匀后得到混合液，将混合液使用氢氧化钠溶液调节其pH值(混合液使用氢氧化钠溶液调节其pH值的温度为33℃，氢氧化钠溶液的质量浓度为7％)，直至混合液呈透明状态；
S3、将混合液静置30分钟后过滤，将滤液分装即为除油剂。
实施例四：一种基于非离子活性剂的除油剂，包括以下重量份的原料：溶剂46份(乙二醇/水溶液，且乙二醇和水在溶剂中的比例为4:6)，烷基酚聚氧乙烯醚13份，高碳脂肪醇聚氧乙烯醚14份，脂肪酸甲酯乙氧基化物14份，吐温-20 3份，聚二甲基硅氧烷1份，碳酸钠0.5份，乙酸钠0.3份，六亚甲基四胺0.4份，氨基三甲亚基膦酸2份，柠檬酸0.7份，辛苯昔醇0.4份，十二烷基苯磺酸钠4份，N-十二烷基二甲胺3份，壬基酚聚氧乙烯醚0.4份，磷酸三丁酯0.3份，松香酸3份，酒石酸0.8份，异丙醇8份，酵素4份，硬脂酸钡0.9份和磺化木质素4份；
制备方法包括以下步骤：
S1、按照比例称取以上重量份的原料；
S2、将上述原料充分混合，并使用搅拌机搅拌均匀后得到混合液，将混合液使用氢氧化钠溶液调节其pH值(混合液使用氢氧化钠溶液调节其pH值的温度为34℃，氢氧化钠溶液的质量浓度为8％)，直至混合液呈透明状态；
S3、将混合液静置30分钟后过滤，将滤液分装即为除油剂。
实施例五：一种基于非离子活性剂的除油剂，包括以下重量份的原料：溶剂49份(乙二醇/水溶液，且乙二醇和水在溶剂中的比例为4:6)，烷基酚聚氧乙烯醚14份，高碳脂肪醇聚氧乙烯醚15份，脂肪酸甲酯乙氧基化物15份，吐温-20 3份，聚二甲基硅氧烷2份，碳酸钠0.6份，乙酸钠0.4份，六亚甲基四胺0.5份，氨基三甲亚基膦酸2份，柠檬酸0.8份，辛苯昔醇0.5份，十二烷基苯磺酸钠4份，N-十二烷基二甲胺3份，壬基酚聚氧乙烯醚0.5份，磷酸三丁酯0.4份，松香酸3份，酒石酸0.8份，异丙醇9份，酵素5份，乙烯－醋酸乙烯共聚物0.9份和磺化木质素5份；
制备方法包括以下步骤：
S1、按照比例称取以上重量份的原料；
S2、将上述原料充分混合，并使用搅拌机搅拌均匀后得到混合液，将混合液使用氢氧化钠溶液调节其pH值(混合液使用氢氧化钠溶液调节其pH值的温度为34℃，氢氧化钠溶液的质量浓度为8％)，直至混合液呈透明状态；
S3、将混合液静置30分钟后过滤，将滤液分装即为除油剂。
选取含油量为280mg/L的污水5L，并将其等分为5份，将实施例一，实施例二，实施例三，实施例四和实施例五制成的除油剂各取50ml分别添加到5等份的污水中，搅拌24h后，测量污水中的含油量，测量结果如下：
由上述的测量结果可知，本发明提出的一种基于非离子活性剂的除油剂的除油率达90％以上，出油效果好，而且实施例三维本发明的最佳实施例。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种基于非离子活性剂的除油剂，其特征在于，包括以下重量份的原料：溶剂42-49份，烷基酚聚氧乙烯醚10-14份，高碳脂肪醇聚氧乙烯醚12-15份，脂肪酸甲酯乙氧基化物11-15份，吐温-201-3份，聚二甲基硅氧烷1-2份，碳酸钠0.2-0.6份，乙酸钠0.1-0.4份，六亚甲基四胺0.3-0.5份，氨基三甲亚基膦酸1-2份，柠檬酸0.5-0.8份，辛苯昔醇0.3-0.5份，十二烷基苯磺酸钠3-4份，N-十二烷基二甲胺1-3份，壬基酚聚氧乙烯醚0.2-0.5份，磷酸三丁酯0.1-0.4份，松香酸1-3份，酒石酸0.6-0.8份，异丙醇6-9份，酵素4-5份，分散剂0.6-0.9份和缓蚀剂2-5份。
2.根据权利要求1所述的一种基于非离子活性剂的除油剂，其特征在于，所述除油剂的原料包括以下重量份：溶剂45份，烷基酚聚氧乙烯醚12份，高碳脂肪醇聚氧乙烯醚13份，脂肪酸甲酯乙氧基化物13份，吐温-20 2份，聚二甲基硅氧烷1份，碳酸钠0.4份，乙酸钠0.3份，六亚甲基四胺0.4份，氨基三甲亚基膦酸2份，柠檬酸0.7份，辛苯昔醇0.4份，十二烷基苯磺酸钠4份，N-十二烷基二甲胺2份，壬基酚聚氧乙烯醚0.3份，磷酸三丁酯0.2份，松香酸2份，酒石酸0.7份，异丙醇8份，酵素5份，分散剂0.7份和缓蚀剂3份。
3.根据权利要求1所述的一种基于非离子活性剂的除油剂，其特征在于，所述溶剂为乙二醇/水溶液，且乙二醇和水在溶剂中的比例为4:6。
4.根据权利要求1所述的一种基于非离子活性剂的除油剂，其特征在于，所述分散剂为硬脂酸丁酯、乙烯－丙烯酸共聚物、乙烯－醋酸乙烯共聚物和硬脂酸钡中的一种。
5.根据权利要求1所述的一种基于非离子活性剂的除油剂，其特征在于，所述缓蚀剂为硅酸盐、钼酸盐、聚磷酸盐、锌盐琉基苯并噻唑、苯并三唑和磺化木质素中的一种。
6.一种基于非离子活性剂的除油剂的制备方法，其特征在于，包括以下步骤：
S1、按照比例称取以上重量份的原料；
S2、将上述原料充分混合，并使用搅拌机搅拌均匀后得到混合液，将混合液使用氢氧化钠溶液调节其pH值，直至混合液呈透明状态；
S3、将混合液静置30分钟后过滤，将滤液分装即为除油剂。
7.根据权利要求6所述的一种基于非离子活性剂的除油剂的制备方法，其特征在于,所述混合液使用氢氧化钠溶液调节其pH值的温度为32℃-34℃，氢氧化钠溶液的质量浓度为5％-8％。
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CN110129120A (zh) * 2019-05-20 2019-08-16 王盛良 一种节能减排型发动机免拆清洁活化修复剂及其制备方法
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CN104073374A (zh) * 2014-07-12 2014-10-01 张慧玲 一种地板高效清洁剂
CN104450298A (zh) * 2014-09-26 2015-03-25 苏州长盛机电有限公司 重油污机械部件清洁剂及其制备方法
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CN110129120A (zh) * 2019-05-20 2019-08-16 王盛良 一种节能减排型发动机免拆清洁活化修复剂及其制备方法
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