CN108914651A - One kind being used for transfer printing paper of pure cotton cloth colorant and its production technology - Google Patents
One kind being used for transfer printing paper of pure cotton cloth colorant and its production technology Download PDFInfo
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- CN108914651A CN108914651A CN201810579662.7A CN201810579662A CN108914651A CN 108914651 A CN108914651 A CN 108914651A CN 201810579662 A CN201810579662 A CN 201810579662A CN 108914651 A CN108914651 A CN 108914651A
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- China
- Prior art keywords
- transfer printing
- printing paper
- cotton cloth
- pure cotton
- agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
Abstract
The invention discloses one kind to be used for transfer printing paper of pure cotton cloth colorant, including following mass fraction component：Active deep blue, reactive brilliant blue, anhydrous sodium sulphate, levelling agent, antishifting agent.The invention also discloses the production technologies of the colorant, include the following steps：（1）Cold water is added in dye vat；（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；（3）After heating up for the first time, it is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains；（4）Adjusting PH with alkaline agent is alkalinity；(5) continue to heat up and maintain, after carry out to color.The present invention has the characteristics of lovely luster, dye-uptake is high, and printed mark is clear, and fastness is good, Environmental Safety.
Description
Technical field
The invention belongs to fabric paper fields, in particular to a kind of to be used for transfer printing paper of pure cotton cloth colorant and its life
Production. art.
Background technique
Currently, there was only the transfer printing substantially unshaped of the transfer printing of woven dacron and high-grade pure cotton cloth in the market, it is main
Reason is wanted to be the flower-shape on paper can be made to be transferred on cotton currently without ideal thickening agent, it is not fresh with coloured light
It is gorgeous, the defects of dye uptake is low, and printed mark is unintelligible, and fastness is poor.
Reactive dye form it can with fiber when in use since it uses parent dye, concatenating group and active group composition
Firm Covalent bonding together, and have a series of incomparable feature of other cellulose fibre dyestuffs, it is established as fine
The development of cellulose fiber dyestuff and the status for using emphasis, in terms of highlightedly showing following four：
(1) reactive dye are to replace prohibitive dye and other types of fibers element dyestuff such as sulfur dye, azoic dyes and reduction
One of the optimal selection of dyestuff etc..
(2) reactive dye can obtain the high-caliber strong performance of items with economic dyeing and simple dying operation
Especially wet fastness.
(3) chromatography of reactive dye it is wide, it is bright in colour, have excellent performance, strong applicability, form and aspect and performance substantially with city
Requirement of the field to fiber and dress material is adapted.
(4) reactive dye are suitable for the needs of the printing and dyeing such as new cellulosic product such as Lyocell fiber.
But the technical problem underlying of reactive dye has at following 4 points：
(1) utilization rate is not high enough, and generally 60% ~ 70%, a large amount of coloured sewage are generated, for coloration more than thousands of times, COD value is general
In 0.8 ten thousand ~ 30,000 ppm, the COD value of density wastewater will be more than 50,000 ppm.
(2) in order to inhibit the charge of fiber surface, when reactive dye use, need to consume considerable amount of electrolyte, both increase
Labor intensity, and the chlorine ion concentration in waste water is caused to be up to ten thousand ppm more than 10, it is useless to substantially increase improvement reactive dyeing
The difficulty of water.
(3) color fastness is not able to satisfy market demands, such as sweat day light fastness, fastness to wet rubbing and azo-type orchil
With light fastness etc. of the azo-type blue dye in light color.
(4) dark color of vulcanization vulcanization material and reducing dye etc. can be replaced of less types.
Summary of the invention
The present invention provides a kind of colorants and its production technology for pure cotton fabric transfer printing paper, have color
Bright-coloured, dye-uptake is high, and printed mark is clear, and fastness is good, and raffinate COD concentration is lower（Between 0.2 ten thousand ~ 0.8 ten thousand ppm）, simultaneous
Has the characteristics of Environmental Safety.
In order to achieve the above objectives, concrete scheme of the invention is as follows：
One kind being used for transfer printing paper of pure cotton cloth colorant, including following mass fraction component：
The deep blue 55-65% of activity；
Reactive brilliant blue 15-25%；
Anhydrous sodium sulphate 8-15%；
Levelling agent 2-6 %；
Antishifting agent 2-7 %；
Preferably,
For transfer printing paper of pure cotton cloth colorant, including following mass fraction component：
Activity deep blue 60%；
Reactive brilliant blue 20%；
Anhydrous sodium sulphate 12%；
4 % of levelling agent；
Antishifting agent 4%；
A kind of production technology for transfer printing paper of pure cotton cloth colorant, includes the following steps：
（1）Cold water is added in dye vat；
（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；
（3）After heating up for the first time, it is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains；
（4）Adjusting PH with alkaline agent is alkalinity；
(5) continue to heat up and maintain, after carry out to color.
The step（1）In cold water temperature be 10-15 DEG C.
The step（4）Intermediate value Ph is 10.5-11.5.
The step（3）Heating for the first time is 25-40 DEG C.
The step（3）It holds time as 8-15min.
The step（5）Continuing heating is 50-60 DEG C.
The step（5）It holds time as 20-30min.
The alkaline agent is sodium hydroxide, in potassium hydroxide, ammonium hydroxide, sodium carbonate, sodium phosphate, sodium orthosilicate, sodium metasilicate
It is one or more.
The present invention for reactive dye to azo-type blue dye dyeing when fastness difference defect, provided with two steps heat up
Toner, to promote active deep blue, the deep blue upper dye power to cashmere of activity, to promote color fastness.Further, since activity is deep blue
Affinity is poor, and dyestuff generates migration phenomenon with moisture movement when drying, causes processing cloth color difference, and anti-migration is arranged in the present invention
The stability of agent promotion coloured light.
The present invention is further elaborated below by way of specific embodiment.
Specific embodiment
The purchaser of following raw material：
The deep blue P5B of activity is purchased from Jiangsu Chemical Co., Ltd. of dolantin section.
Reactive brilliant blue P3R is purchased from Jiangsu Chemical Co., Ltd. of dolantin section.
Anhydrous sodium sulphate is purchased from Shaoxing Salt Company.
Levelling agent is purchased from Jiangsu Hai'an Petrochemical Plant.
Antishifting agent is the copolymer of acrylic acid and propylene phthalein amine, is purchased from Dongguan Jiahong Silicone Technology Co., Ltd..
Embodiment 1
One kind being used for transfer printing paper of pure cotton cloth colorant, including following mass fraction component：
The deep blue P5R 55% of activity；
Reactive brilliant blue P3R 25%；
Anhydrous sodium sulphate 10%；
5 % of levelling agent；
5 % of antishifting agent；
A kind of production technology for transfer printing paper of pure cotton cloth colorant, includes the following steps：
（1）10 DEG C of cold water is added in dye vat；
（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；
（3）25 DEG C are warming up to for the first time, is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains 8min；
（4）Adjusting PH with alkaline agent sodium hydroxide is 10.5；
(5) 50 DEG C are continuously heating to and maintains 20min, after carry out to color, dyeing, measure dye-uptake be 93%, raffinate COD concentration
For 0.6 ten thousand ppm.50 DEG C of soaping fastnesses are 4 grades, crock fastness：It is 5 grades of unlubricated friction, wet to rub 4 grades.
Embodiment 2
One kind being used for transfer printing paper of pure cotton cloth colorant, including following mass fraction component：
The deep blue P5R 60% of activity；
Reactive brilliant blue P3R 25%；
Anhydrous sodium sulphate 10%；
3 % of levelling agent；
2 % of antishifting agent；
A kind of production technology for transfer printing paper of pure cotton cloth colorant, includes the following steps：
（1）12 DEG C of cold water is added in dye vat；
（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；
（3）30 DEG C are warming up to for the first time, is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains 10min；
（4）Adjusting PH with alkaline agent ammonium hydroxide is 11；
(5) 55 DEG C are continuously heating to and maintains 25min, after carry out to color, dyeing, measure dye-uptake be 94%, raffinate COD concentration
For 0.3 ten thousand ppm.50 DEG C of soaping fastnesses are 5 grades, crock fastness：It is 4 grades of unlubricated friction, wet to rub 4 grades.
Embodiment 3
One kind being used for transfer printing paper of pure cotton cloth colorant, including following mass fraction component：
The deep blue P5R 65% of activity；
Reactive brilliant blue P3R 15%；
Anhydrous sodium sulphate 8%；
6 % of levelling agent；
Antishifting agent 6%；
A kind of production technology for transfer printing paper of pure cotton cloth colorant, includes the following steps：
（1）15 DEG C of cold water is added in dye vat；
（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；
（3）40 DEG C are warming up to for the first time, is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains 15min；
（4）Adjusting PH with alkaline agent sodium carbonate is 11.5；
(5) 60 DEG C are continuously heating to and maintains 30min, after carry out to color, dyeing, measure dye-uptake be 95%, raffinate COD concentration
For 0.2 ten thousand ppm.50 DEG C of soaping fastnesses are 5 grades, crock fastness：It is 5 grades of unlubricated friction, wet to rub 4 grades.
Embodiment 4
One kind being used for transfer printing paper of pure cotton cloth colorant, including following mass fraction component：
The deep blue P5R 60% of activity；
Reactive brilliant blue P3R 20%；
Anhydrous sodium sulphate 10%；
4 % of levelling agent；
6 % of antishifting agent；
A kind of production technology for transfer printing paper of pure cotton cloth colorant, includes the following steps：
（1）15 DEG C of cold water is added in dye vat；
（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；
（3）40 DEG C are warming up to for the first time, is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains 15min；
（4）Adjusting PH with alkaline agent sodium phosphate is 11；
(5) 55 DEG C are continuously heating to and maintains 25min, after carry out to color, dyeing, measure dye-uptake be 94%, raffinate COD concentration
For 0.25 ten thousand ppm.50 DEG C of soaping fastnesses are 4 grades, crock fastness：It is 5 grades of unlubricated friction, wet to rub 4 grades.
Embodiment 5
One kind being used for transfer printing paper of pure cotton cloth colorant, including following mass fraction component：
The deep blue P5R 60% of activity；
Reactive brilliant blue P3R 20%；
Anhydrous sodium sulphate 12%；
4 % of levelling agent；
Antishifting agent 4%；
A kind of production technology for transfer printing paper of pure cotton cloth colorant, includes the following steps：
（1）12 DEG C of cold water is added in dye vat；
（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；
（3）35 DEG C are warming up to for the first time, is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains 12min；
（4）Adjusting PH with alkaline agent sodium orthosilicate is 11.5；
(5) 55 DEG C are continuously heating to and maintains 25min, after carry out to color, dyeing, measure dye-uptake be 96%, raffinate COD concentration
For 0.2 ten thousand ppm.50 DEG C of soaping fastnesses are 5 grades, crock fastness：It is 5 grades of unlubricated friction, wet to rub 4 grades.
Above specific embodiment is only the preferred embodiment of this creation, all in this wound not to limit this creation
Any modification, equivalent substitution, improvement and etc. done within the spirit and principle of work, should be included in this creation protection scope it
It is interior.
Claims (10)
1. one kind is used for transfer printing paper of pure cotton cloth colorant, which is characterized in that including following mass fraction component：
The deep blue 55-65% of activity；
Reactive brilliant blue 15-25%；
Anhydrous sodium sulphate 8-15%；
Levelling agent 2-6 %；
Antishifting agent 2-7 %.
2. being used for transfer printing paper of pure cotton cloth colorant as described in claim 1, which is characterized in that including following quality point
Array point：
Activity deep blue 60%；
Reactive brilliant blue 20%；
Anhydrous sodium sulphate 12%；
4 % of levelling agent；
Antishifting agent 4%.
3. a kind of production technology for transfer printing paper of pure cotton cloth colorant, it is characterised in that include the following steps：
（1）Cold water is added in dye vat；
（2）Above-mentioned dosage levelling agent, antishifting agent, anhydrous sodium sulphate are added in dye vat；
（3）After heating up for the first time, it is added that above-mentioned dose active is deep blue, and reactive brilliant blue simultaneously maintains；
（4）Adjusting PH with alkaline agent is alkalinity；
(5) continue to heat up and maintain, after carry out to color.
4. a kind of production technology for transfer printing paper of pure cotton cloth colorant as claimed in claim 3, it is characterised in that：
The step（1）In cold water temperature be 10-15 DEG C.
5. a kind of production technology for transfer printing paper of pure cotton cloth colorant as claimed in claim 3, it is characterised in that：
The step（4）Intermediate value Ph is 10.5-11.5.
6. a kind of production technology for transfer printing paper of pure cotton cloth colorant as claimed in claim 3, it is characterised in that：
The step（3）Heating for the first time is 25-40 DEG C.
7. a kind of production technology for transfer printing paper of pure cotton cloth colorant as claimed in claim 3, it is characterised in that：
The step（3）It holds time as 8-15min.
8. a kind of production technology for transfer printing paper of pure cotton cloth colorant as claimed in claim 3, it is characterised in that：
The step（5）Continuing heating is 50-60 DEG C.
9. a kind of production technology for transfer printing paper of pure cotton cloth colorant as claimed in claim 3, it is characterised in that：
The step（5）It holds time as 20-30min.
10. being used for transfer printing paper of pure cotton cloth colorant as claimed in claim 3, it is characterised in that：The alkaline agent is hydrogen
One of sodium oxide molybdena, potassium hydroxide, ammonium hydroxide, sodium carbonate, sodium phosphate, sodium orthosilicate, sodium metasilicate are a variety of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810579662.7A CN108914651A (en) | 2018-06-07 | 2018-06-07 | One kind being used for transfer printing paper of pure cotton cloth colorant and its production technology |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810579662.7A CN108914651A (en) | 2018-06-07 | 2018-06-07 | One kind being used for transfer printing paper of pure cotton cloth colorant and its production technology |
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| Publication Number | Publication Date |
|---|---|
| CN108914651A true CN108914651A (en) | 2018-11-30 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102650097A (en) * | 2011-02-28 | 2012-08-29 | 上海辉誉化工有限公司 | Foam spraying dyeing method adopting reactive dyes |
| CN103540166A (en) * | 2013-11-01 | 2014-01-29 | 上海雅运纺织化工股份有限公司 | Blue active dye composition and application thereof in dyeing fiber |
| CN104710841A (en) * | 2015-02-15 | 2015-06-17 | 江苏德美科化工有限公司 | Red reactive dye composition |
| CN106049110A (en) * | 2016-07-25 | 2016-10-26 | 浙江中昕染整有限公司 | Coffee dyeing method of rabbit wool |
| CN106752076A (en) * | 2016-11-28 | 2017-05-31 | 浙江瑞华化工有限公司 | A kind of blue active dye composition and its production and use |
-
2018
- 2018-06-07 CN CN201810579662.7A patent/CN108914651A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102650097A (en) * | 2011-02-28 | 2012-08-29 | 上海辉誉化工有限公司 | Foam spraying dyeing method adopting reactive dyes |
| CN103540166A (en) * | 2013-11-01 | 2014-01-29 | 上海雅运纺织化工股份有限公司 | Blue active dye composition and application thereof in dyeing fiber |
| CN104710841A (en) * | 2015-02-15 | 2015-06-17 | 江苏德美科化工有限公司 | Red reactive dye composition |
| CN106049110A (en) * | 2016-07-25 | 2016-10-26 | 浙江中昕染整有限公司 | Coffee dyeing method of rabbit wool |
| CN106752076A (en) * | 2016-11-28 | 2017-05-31 | 浙江瑞华化工有限公司 | A kind of blue active dye composition and its production and use |
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Application publication date: 20181130 |