CN108913372A - For safeguarding the detergent and preparation method thereof of gardens drying landscape landscape - Google Patents
For safeguarding the detergent and preparation method thereof of gardens drying landscape landscape Download PDFInfo
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- CN108913372A CN108913372A CN201810952302.7A CN201810952302A CN108913372A CN 108913372 A CN108913372 A CN 108913372A CN 201810952302 A CN201810952302 A CN 201810952302A CN 108913372 A CN108913372 A CN 108913372A
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- landscape
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- detergent
- gardens
- safeguarding
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- 239000003599 detergent Substances 0.000 title claims abstract description 39
- 238000001035 drying Methods 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 238000005253 cladding Methods 0.000 claims abstract description 27
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 claims abstract description 19
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 14
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 14
- -1 neopelex Substances 0.000 claims abstract description 14
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000001509 sodium citrate Substances 0.000 claims abstract description 12
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000002696 manganese Chemical class 0.000 claims abstract description 11
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 10
- 239000000440 bentonite Substances 0.000 claims abstract description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229960001484 edetic acid Drugs 0.000 claims abstract description 10
- 229960002885 histidine Drugs 0.000 claims abstract description 10
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- XZUAPPXGIFNDRA-UHFFFAOYSA-N ethane-1,2-diamine;hydrate Chemical compound O.NCCN XZUAPPXGIFNDRA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000010348 incorporation Methods 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 5
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 3
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 3
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 3
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 3
- 239000011565 manganese chloride Substances 0.000 claims description 3
- 235000002867 manganese chloride Nutrition 0.000 claims description 3
- 229940099607 manganese chloride Drugs 0.000 claims description 3
- 229940099596 manganese sulfate Drugs 0.000 claims description 3
- 239000011702 manganese sulphate Substances 0.000 claims description 3
- 235000007079 manganese sulphate Nutrition 0.000 claims description 3
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 3
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical group [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 230000000857 drug effect Effects 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 10
- 238000012423 maintenance Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000004576 sand Substances 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of for safeguarding the detergent and preparation method thereof of gardens drying landscape landscape, which includes:1)Bentonite, mantoquita, manganese salt, molysite, L-Histidine, ethylenediamine tetra-acetic acid and water are subjected to hydro-thermal reaction to form hydrothermal system;2)Cyclodextrin is added in hydrothermal system and be coated with forming cladding system;3)Polyethylene glycol, neopelex, sodium citrate, streptomysin are added in cladding system and mixed to obtain being used for safeguarding the detergent of gardens drying landscape landscape.The detergent has the characteristics that drug effect is long, dosage is few, environmental-friendly for the maintenance for safeguarding gardens drying landscape landscape, while the preparation method has the advantages that process is simple and raw material is easy to get.
Description
Technical field
The present invention relates to detergents, and in particular, to a kind of for safeguarding the detergent and its system of gardens drying landscape landscape
Preparation Method.
Background technique
Drying landscape landscape is the miniature formula garden landscape built to adapt to Japanese geographical conditions originating from Japan, now more
See small and exquisite, quiet, deep Zen Buddhism's monastery.Drying landscape landscape was both limited without high mountain, hills or by river, lake, pool, the geographical of small stream
System explores it in landscape art design exquisite and careful.Drying landscape signifies the chain of mountains with stone, signifies Hu Hai with white sand,
Water wave is indicated with lines, the landscape hand scroll that a such as pair is left white.In its distinctive ambiance, water is explained because its is anhydrous, because of nothing
Mountain is anhydrous and gains the name.
Drying landscape landscape just needs to carry out daily maintenance from after use, if being the absence of maintenance, then the table of stone, white sand
Face can then generate countless more mosses or other ground floras, so that stone, white sand lose original pattern, in turn
Original design implied meaning so that drying landscape landscape has scattered and disappeared.Although being tieed up at present using some reagents for inhibiting plant growth
Shield, but these reagents or be that environmental pollution is big or be that drug effect is difficult to persistently and then brings to the maintenance of drying landscape landscape
Challenge.
Summary of the invention
The object of the present invention is to provide a kind of for safeguarding the detergent and preparation method thereof of gardens drying landscape landscape, this is clear
Clean dose has the characteristics that drug effect is long, dosage is few, environmental-friendly for the maintenance for safeguarding gardens drying landscape landscape, while the system
Preparation Method has the advantages that process is simple and raw material is easy to get.
To achieve the goals above, the present invention provides a kind of for safeguarding the preparation of the detergent of gardens drying landscape landscape
Method, the preparation method include:
1)Bentonite, mantoquita, manganese salt, molysite, L-Histidine, ethylenediamine tetra-acetic acid and water are subjected to hydro-thermal reaction to form hydro-thermal
System;
2)Cyclodextrin is added in hydrothermal system and be coated with forming cladding system;
3)Polyethylene glycol, neopelex, sodium citrate, streptomysin are added in cladding system and mixed to obtain
To for safeguarding the detergent of gardens drying landscape landscape.
The present invention also provides a kind of for safeguarding the detergent of gardens drying landscape landscape, this is used to safeguard gardens drying landscape
The detergent of landscape is prepared by above-mentioned preparation method.
In the above-mentioned technical solutions, the present invention adsorbs mantoquita, manganese salt, molysite, L- as absorption carrier using bentonite first
The product that histidine, ethylenediamine tetra-acetic acid react, then improves bentonitic dispersibility by the cladding of cyclodextrin, finally adds
The auxiliary agents such as polyethylene glycol, neopelex, sodium citrate, streptomysin further increase the cleaning effect of detergent.?
It in above-mentioned detergent, is reacted or is combined by using the mild raw material of environment, so that the detergent has environment
The feature friendly, drug effect is long, dosage is few;The preparation method has the advantages that process is simple and raw material is easy to get simultaneously.
Other features and advantages of the present invention will the following detailed description will be given in the detailed implementation section.
Specific embodiment
Detailed description of the preferred embodiments below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The present invention provides a kind of for safeguarding the preparation method of the detergent of gardens drying landscape landscape, the preparation method packet
It includes:
1)Bentonite, mantoquita, manganese salt, molysite, L-Histidine, ethylenediamine tetra-acetic acid and water are subjected to hydro-thermal reaction to form hydro-thermal
System;
2)Cyclodextrin is added in hydrothermal system and be coated with forming cladding system;
3)Polyethylene glycol, neopelex, sodium citrate, streptomysin are added in cladding system and mixed to obtain
To for safeguarding the detergent of gardens drying landscape landscape.
In above-mentioned preparation method step 1)In, raw material dosage can select in a wide range, but in order to further mention
The drug effect of high cleaning agent, it is preferable that in step 1)In, bentonite, mantoquita, manganese salt, molysite, L-Histidine, ethylenediamine tetra-acetic acid
Weight ratio with water is 10:0.5-2:0.05-0.15:0.5-1.5:3-5:2-6:200-300.
In above-mentioned preparation method step 1)In, the dosage of hydro-thermal reaction can select in a wide range, but in order into
The drug effect of one step raising detergent, it is preferable that in step 1)In, hydro-thermal reaction meets the following conditions:It is carried out in closed environment,
Reaction temperature is 130-150 DEG C, reaction time 12-24h.
In above-mentioned preparation method step 1)In, the type of each salt can select in a wide range, but in order into one
Step improves the drug effect of detergent, it is preferable that in step 1)In, mantoquita is selected from least one of copper sulphate, copper nitrate and copper chloride;
Manganese salt is selected from least one of manganese chloride, manganese nitrate and manganese sulfate;Molysite in ferric nitrate, iron chloride and ferric sulfate extremely
Few one.
In above-mentioned preparation method step 2)In, the dosage of material can select in a wide range, but in order to further
Improve the drug effect of detergent, it is preferable that in step 2)In, hydrothermal system, cyclodextrin weight ratio be 100:2-5.
In above-mentioned preparation method step 2)In, the actual conditions of cladding can select in a wide range, but in order into
The drug effect of one step raising detergent, it is preferable that in step 2)In, cladding meets the following conditions:It carries out, coats under stirring condition
Temperature is 15-35 DEG C, and the cladding time is 4-6h.
In above-mentioned preparation method step 3)In, the dosage of material can select in a wide range, but in order to further
Improve the drug effect of detergent, it is preferable that in step 3)In, coat system, polyethylene glycol, neopelex, citric acid
Sodium, streptomysin weight ratio be 100:1-2:0.1-0.4:0.08-0.15:0.02-0.05.
In above-mentioned preparation method step 3)In, mixed condition can select in a wide range, but in order to further
Improve the drug effect of detergent, it is preferable that in step 3)In, mixing meets the following conditions:It is carried out under stirring condition, mixing temperature
It is 15-35 DEG C, incorporation time 40-60min.
The present invention also provides a kind of for safeguarding the detergent of gardens drying landscape landscape, this is used to safeguard gardens drying landscape
The detergent of landscape is prepared by above-mentioned preparation method.
The present invention will be described in detail by way of examples below.
Embodiment 1
1)By bentonite, mantoquita(Copper sulphate), manganese salt(Manganese chloride), molysite(Ferric nitrate), L-Histidine, ethylenediamine tetra-acetic acid and
Water is according to 10:1:0.09:0.9:4:5:250 weight ratio carries out hydro-thermal reaction(It is carried out in closed environment, reaction temperature is
140 DEG C, reaction time 18h)To form hydrothermal system;
2)Cyclodextrin is added in hydrothermal system(Hydrothermal system, cyclodextrin weight ratio be 100:3)It is coated(In stirring
Under the conditions of carry out, temperature of plate be 25 DEG C, the cladding time be 5h)To form cladding system;
3)Polyethylene glycol, neopelex, sodium citrate, streptomysin are added in cladding system(Cladding system is gathered
Ethylene glycol, neopelex, sodium citrate, streptomysin weight ratio be 100:1.5:0.3:0.1:0.03)It is mixed
It closes(It is carried out under stirring condition, mixing temperature is 25 DEG C, incorporation time 50min)To obtain for safeguarding gardens drying landscape scape
The detergent A1 of sight.
Embodiment 2
1)By bentonite, mantoquita(Copper nitrate), manganese salt(Manganese nitrate), molysite(Iron chloride), L-Histidine, ethylenediamine tetra-acetic acid and
Water is according to 10:0.5:0.05:0.5:3:2:200 weight ratio carries out hydro-thermal reaction(It is carried out in closed environment, reaction temperature is
130 DEG C, the reaction time is for 24 hours)To form hydrothermal system;
2)Cyclodextrin is added in hydrothermal system(Hydrothermal system, cyclodextrin weight ratio be 100:2)It is coated(In stirring
Under the conditions of carry out, temperature of plate be 15 DEG C, the cladding time be 6h)To form cladding system;
3)Polyethylene glycol, neopelex, sodium citrate, streptomysin are added in cladding system(Cladding system is gathered
Ethylene glycol, neopelex, sodium citrate, streptomysin weight ratio be 100:1:0.1:0.08:0.02)It is mixed
(It is carried out under stirring condition, mixing temperature is 15 DEG C, incorporation time 60min)To obtain for safeguarding gardens drying landscape landscape
Detergent A2.
Embodiment 3
1)By bentonite, mantoquita(Copper chloride), manganese salt(Manganese sulfate), molysite(Ferric sulfate), L-Histidine, ethylenediamine tetra-acetic acid and
Water is according to 10:2:0.15:1.5:5:6:300 weight ratio carries out hydro-thermal reaction(It is carried out in closed environment, reaction temperature is
150 DEG C, reaction time 12h)To form hydrothermal system;
2)Cyclodextrin is added in hydrothermal system(Hydrothermal system, cyclodextrin weight ratio be 100:5)It is coated(In stirring
Under the conditions of carry out, temperature of plate be 35 DEG C, the cladding time be 4h)To form cladding system;
3)Polyethylene glycol, neopelex, sodium citrate, streptomysin are added in cladding system(Cladding system is gathered
Ethylene glycol, neopelex, sodium citrate, streptomysin weight ratio be 100:2:0.4:0.15:0.05)It is mixed
(It is carried out under stirring condition, mixing temperature is 35 DEG C, incorporation time 40min)To obtain for safeguarding gardens drying landscape landscape
Detergent A3.
Comparative example 1
It carries out obtaining detergent B1 according to the method for embodiment 1, unlike, step 1)Mantoquita is not used.
Comparative example 2
It carries out obtaining detergent B2 according to the method for embodiment 1, unlike, step 1)Manganese salt is not used.
Comparative example 3
It carries out obtaining detergent B3 according to the method for embodiment 1, unlike, step 1)Molysite is not used.
Comparative example 4
It carries out obtaining detergent B4 according to the method for embodiment 1, unlike, step 1)Molysite, mantoquita, manganese salt is not used.
Comparative example 5
It carries out obtaining detergent B5 according to the method for embodiment 1, unlike, step 2)Cyclodextrin is not used.
Application examples 1
Above-mentioned detergent is sprayed to stone, the white sand in woods drying landscape landscape;Fountain height is:With 100 squares of woods drying landscape scape
Seeing is standard, and the fountain height of each detergent is 100-200mL;Spring and summer per two weeks sprinkling are primary, fall and winter
Sprinkling in one month is primary.After 1 year, the coverage rate of moss on statistics stone, white sand.
Table 1
The reagent of sprinkling | Coverage rate/% of moss on stone | Coverage rate/% of moss on white sand |
Water | 85.3 | 76.9 |
A1 | 0.9 | 0.3 |
A2 | 1.1 | 0.5 |
A3 | 0.8 | 0.4 |
B1 | 27.2 | 22.6 |
B2 | 25.6 | 20.5 |
B3 | 18.9 | 17.9 |
B4 | 75.9 | 66.7 |
B5 | 12.3 | 8.9 |
The preferred embodiment of the present invention has been described above in detail, still, the tool during present invention is not limited to the embodiments described above
Body details within the scope of the technical concept of the present invention can be with various simple variants of the technical solution of the present invention are made, these letters
Monotropic type all belongs to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case where shield, can be combined in any appropriate way, in order to avoid unnecessary repetition, the present invention to it is various can
No further explanation will be given for the combination of energy.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (9)
1. a kind of for safeguarding the preparation method of the detergent of gardens drying landscape landscape, which is characterized in that the preparation method packet
It includes:
1)Bentonite, mantoquita, manganese salt, molysite, L-Histidine, ethylenediamine tetra-acetic acid and water are subjected to hydro-thermal reaction to form hydro-thermal
System;
2)Cyclodextrin is added in hydrothermal system and be coated with forming cladding system;
3)Polyethylene glycol, neopelex, sodium citrate, streptomysin are added in the cladding system and mixed
To obtain the detergent for safeguarding gardens drying landscape landscape.
2. preparation method according to claim 1, wherein in step 1)In, the bentonite, mantoquita, manganese salt, molysite,
The weight ratio of L-Histidine, ethylenediamine tetra-acetic acid and water is 10:0.5-2:0.05-0.15:0.5-1.5:3-5:2-6:200-
300。
3. preparation method according to claim 1, wherein in step 1)In, the hydro-thermal reaction meets the following conditions:In
It is carried out in closed environment, reaction temperature is 130-150 DEG C, reaction time 12-24h.
4. preparation method according to claim 1, wherein in step 1)In, the mantoquita be selected from copper sulphate, copper nitrate and
At least one of copper chloride;The manganese salt is selected from least one of manganese chloride, manganese nitrate and manganese sulfate;The molysite is selected from nitre
At least one of sour iron, iron chloride and ferric sulfate.
5. preparation method described in any one in -4 according to claim 1, wherein in step 2)In, the hydrothermal system,
The weight ratio of cyclodextrin is 100:2-5.
6. preparation method according to claim 5, wherein in step 2)In, the cladding meets the following conditions:In stirring
Under the conditions of carry out, temperature of plate be 15-35 DEG C, the cladding time be 4-6h.
7. preparation method according to claim 5 or 6, wherein in step 3)In, the cladding system, polyethylene glycol, ten
Dialkyl benzene sulfonic acids sodium, sodium citrate, streptomysin weight ratio be 100:1-2:0.1-0.4:0.08-0.15:0.02-0.05.
8. preparation method according to claim 5 or 6, wherein in step 3)In, the mixing meets the following conditions:In
It is carried out under stirring condition, mixing temperature is 15-35 DEG C, incorporation time 40-60min.
9. a kind of for safeguarding the detergent of gardens drying landscape landscape, which is characterized in that described for safeguarding gardens drying landscape scape
The detergent of sight is prepared by preparation method described in any one of claim 1-8.
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