CN108912999A - A kind of anti-ultraviolet paint preparation method that adhesive force is strong - Google Patents
A kind of anti-ultraviolet paint preparation method that adhesive force is strong Download PDFInfo
- Publication number
- CN108912999A CN108912999A CN201810952267.9A CN201810952267A CN108912999A CN 108912999 A CN108912999 A CN 108912999A CN 201810952267 A CN201810952267 A CN 201810952267A CN 108912999 A CN108912999 A CN 108912999A
- Authority
- CN
- China
- Prior art keywords
- parts
- zeolite
- adhesive force
- added
- paint preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
- C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention discloses a kind of anti-ultraviolet paint preparation method that adhesive force is strong, the coating of preparation ultraviolet light shielding rate with higher, uvioresistant effect is preferable, the adhesive force of its coating is stronger simultaneously, and not easily to fall off and cracking can prolong the service life, filler is uniformly dispersed in coating, has good stability.Zeolite passes through step（1）Operation processing after, sufficiently open its duct, increase its specific surface area, enhance absorption property, and then enhance the adhesive force of coating, prevent from cracking and fall off；Zeolite is handled using methyl methacrylate, CuPc, sodium alginate, diatomite, CuPc immerses zeolite interior, it is fixed in zeolite gap, diatomite is attached to zeolite surface using methyl methacrylate, sodium alginate, each component synergistic effect, the ultraviolet resistance of zeolite is not only increased, coating adhesion is improved, improves the dispersibility of filler.
Description
Technical field
The invention belongs to technical field of paint preparation, especially a kind of anti-ultraviolet paint preparation method that adhesive force is strong.
Background technique
Plastics are one of indispensable materials in people's life, are brought great convenience to people's lives.Often
In the plastic products of outdoor application, usually colour fading, cracking, dusting, embrittlement etc. can be generated because of the irradiation of solar ultraviolet and asked
Topic, seriously affects its service life, so, having the coating of anti-ultraviolet function in surface of plastic products coating is that solution is above-mentioned
The effective ways of problem.
However, during preparing anti-ultraviolet paint, not good enough, bad dispersibility that there is also ultraviolet ray preventing effects is filled out
Expect the problems such as easy to reunite, unstable, film is easy to fall off.
Summary of the invention
In view of the above-mentioned problems, the present invention is intended to provide a kind of coating system that ultraviolet ray preventing effect is preferable, coating adhesion is strong
Preparation Method.
The invention is realized by the following technical scheme：
The strong anti-ultraviolet paint preparation method of a kind of adhesive force according to claim 1, which is characterized in that including following
Step：
（1）5-10 part zeolite in parts by weight is put into the citric acid solution of its 10-20 times of volume, 5- is ultrasonically treated
It is transferred in vapor tight tank after 10min, adjusting hermetically sealed can temperature is 2-5 DEG C, and pressure -0.8~-0.9MPa handles 30-40min, then
Adjusting hermetically sealed can temperature is 80-89 DEG C, pressure 0.2-0.3MPa, handles 30-40min, and cooling bleeds off pressure, then filters, will boil
Stone is put into the sodium hydroxide solution of 10-20 times of its volume, is transferred in hermetically sealed can after being ultrasonically treated 5-10min, and above-mentioned behaviour is repeated
Make, gained zeolite is finally washed with deionized, and is put into 110-120 DEG C of vacuum oven dry；
（2）By step（1）Gained zeolite is added in the modification liquid of 10-20 times of its volume, and the temperature of heating holding modification liquid is
It 45-50 DEG C, after stirring 20-30min at 500-600rpm, is transferred in 70-80 DEG C of vacuum oven, be evacuated to-
0.09~-0.1MPa places 3-5h, then cooling to take out, and filters, washs, dry, obtains modified zeolite；
（3）By step（2）Gained modified zeolite is added in the titanium tetrachloride solution of 20-30 times of its volume, is then added 2-3 parts
Nano ceric oxide, 0.5-1 part silane coupling agent, are dispersed with stirring 20-30min at 40-50 DEG C, 700-800rpm, then sharp
Adjusting its pH value with sodium hydroxide solution is 7.0-8.0, is warming up to 90-98 DEG C, is stirred to react 10- at 400-600rpm
13h, cooling, centrifugation, filters and dries at 90-100 DEG C；
（4）30-40 parts of polyester polyol and 70-80 parts of diisocyanate are added in three-necked flask, are mixed evenly, are risen
1-2 parts of citric acids are added to 80-87 DEG C in temperature, and 5-10 parts of chain extenders, 10-30 parts of polyester are added thereto after reacting 2.5-3.5h
Polyalcohol, deionized water, step（3）Gains, the reaction was continued 30-50min to obtain the final product.
Further, step（1）The citric acid solution mass fraction is 10-15%.
Further, step（1）The sodium hydroxide solution mass fraction is 5-10%.
Further, step（1）The ultrasound condition is 100-120Hz.
Further, step（2）Each ingredient and its corresponding parts by weight are in the modification liquid：15-20 parts of methacrylic acids
Methyl esters, 1-2 part CuPc, 1-2 parts of sodium alginates, 3-5 parts of diatomite, 30-50 parts of deionized waters, the diatomite pass through 350-
360 DEG C of calcination processing.
Further, step（2）The drying temperature is 60-80 DEG C.
Further, step（2）The titanium tetrachloride solution concentration is 0.5-0.8mol/L.
Beneficial effects of the present invention：Coating ultraviolet light shielding rate with higher prepared by the present invention, uvioresistant effect
Preferably, while the adhesive force of its coating is stronger, and not easily to fall off and cracking can prolong the service life, and filler is uniformly dispersed in coating,
It has good stability.Zeolite passes through step（1）Operation processing after, sufficiently open its duct, increase its specific surface area, enhancing is inhaled
Attached performance, and then enhance the adhesive force of coating, prevent from cracking and fall off；Utilize methyl methacrylate, CuPc, alginic acid
Sodium, diatomite handle zeolite, and CuPc immerses zeolite interior, are fixed in zeolite gap, and diatomite utilizes methyl-prop
E pioic acid methyl ester, sodium alginate are attached to zeolite surface, and each component synergistic effect not only increases the ultraviolet resistance of zeolite,
Coating adhesion is improved, the dispersibility of filler is improved；Finally in zeolite surface load nano-titanium dioxide and ceria, the two
Synergistic effect, improves its agglomeration, meanwhile, further enhance uvioresistant effect.
Specific embodiment
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
The strong anti-ultraviolet paint preparation method of a kind of adhesive force according to claim 1, which is characterized in that including following
Step：
（1）5 parts of zeolites in parts by weight are put into the citric acid solution of its 10 times of volumes, are transferred to after ultrasonic treatment 5min close
It closes in tank, adjusting hermetically sealed can temperature is 2 DEG C, pressure -0.8MPa, handles 30min, and then adjusting hermetically sealed can temperature is 80 DEG C, pressure
Power is 0.2MPa, handles 30min, and cooling bleeds off pressure, then filters, zeolite is put into the sodium hydroxide solution of 10 times of its volume,
It is transferred in hermetically sealed can after ultrasonic treatment 5min, repeats aforesaid operations, gained zeolite is finally washed with deionized, and be put into 110
DEG C vacuum oven in it is dry；
（2）By step（1）Gained zeolite is added in the modification liquid of 10 times of its volume, and it is 45 that heating, which keeps the temperature of modification liquid,
DEG C, it after stirring 20min at 500 rpm, is transferred in 70 DEG C of vacuum oven, is evacuated to -0.09MPa, place 3h, so
It is cooling afterwards to take out, it filters, washs, it is dry, obtain modified zeolite；
（3）By step（2）Gained modified zeolite is added in the titanium tetrachloride solution of 20 times of its volume, and 2 parts of nanometers are then added
Ceria, 0.5 part of silane coupling agent, are dispersed with stirring 20min at 40 DEG C, 700rpm, then utilize sodium hydroxide solution tune
Saving its pH value is 7.0, is warming up to 90 DEG C, and 10h is stirred to react at 400rpm, and cooling, centrifugation is filtered and dried at 90 DEG C；
（4）30 parts of polyester polyol and 70 parts of diisocyanate are added in three-necked flask, is mixed evenly, is warming up to 80
DEG C, 1 part of citric acid is added, 5 parts of chain extenders, 10 parts of polyester polyol, deionized water, steps are added thereto after reacting 2.5h
（3）Gains, the reaction was continued 30min to obtain the final product.
Further, step（1）The citric acid solution mass fraction is 10%.
Further, step（1）The sodium hydroxide solution mass fraction is 5%.
Further, step（1）The ultrasound condition is 100Hz.
Further, step（2）Each ingredient and its corresponding parts by weight are in the modification liquid：15 parts of methyl methacrylates
Ester, 1 part of CuPc, 1 part of sodium alginate, 3 parts of diatomite, 30 parts of deionized waters, the diatomite pass through at 350 DEG C of calcining
Reason.
Further, step（2）The drying temperature is 60 DEG C.
Further, step（2）The titanium tetrachloride solution concentration is 0.5mol/L.
Embodiment 2
The strong anti-ultraviolet paint preparation method of a kind of adhesive force according to claim 1, which is characterized in that including following
Step：
（1）8 parts of zeolites in parts by weight are put into the citric acid solution of its 15 times of volumes, are transferred to after ultrasonic treatment 7min close
It closes in tank, adjusting hermetically sealed can temperature is 3 DEG C, pressure -0.85MPa, handles 35min, and then adjusting hermetically sealed can temperature is 85 DEG C, pressure
Power is 0.25MPa, handles 35min, and cooling bleeds off pressure, then filters, zeolite is put into the sodium hydroxide solution of 15 times of its volume,
It is transferred in hermetically sealed can after ultrasonic treatment 8min, repeats aforesaid operations, gained zeolite is finally washed with deionized, and be put into 115
DEG C vacuum oven in it is dry；
（2）By step（1）Gained zeolite is added in the modification liquid of 15 times of its volume, and it is 47 that heating, which keeps the temperature of modification liquid,
DEG C, it after stirring 25min at 550rpm, is transferred in 75 DEG C of vacuum oven, is evacuated to -0.095MPa, place 4h, so
It is cooling afterwards to take out, it filters, washs, it is dry, obtain modified zeolite；
（3）By step（2）Gained modified zeolite is added in the titanium tetrachloride solution of 25 times of its volume, and 3 parts of nanometers are then added
Ceria, 0.6 part of silane coupling agent, are dispersed with stirring 25min at 45 DEG C, 750rpm, then utilize sodium hydroxide solution tune
Saving its pH value is 8.0, is warming up to 93 DEG C, is stirred to react 12h at 500 rpm, and cooling, centrifugation is filtered and dried at 95 DEG C；
（4）35 parts of polyester polyol and 75 parts of diisocyanate are added in three-necked flask, is mixed evenly, is warming up to 85
DEG C, 2 parts of citric acids are added, 7 parts of chain extenders, 20 parts of polyester polyol, deionized water, steps are added thereto after reacting 3h（3）
Gains, the reaction was continued 40min to obtain the final product.
Further, step（1）The citric acid solution mass fraction is 12%.
Further, step（1）The sodium hydroxide solution mass fraction is 8%.
Further, step（1）The ultrasound condition is 110Hz.
Further, step（2）Each ingredient and its corresponding parts by weight are in the modification liquid：18 parts of methyl methacrylates
Ester, 2 parts of CuPcs, 2 parts of sodium alginates, 4 parts of diatomite, 40 parts of deionized waters, the diatomite pass through at 355 DEG C of calcining
Reason.
Further, step（2）The drying temperature is 70 DEG C.
Further, step（2）The titanium tetrachloride solution concentration is 0.7mol/L.
Embodiment 3
The strong anti-ultraviolet paint preparation method of a kind of adhesive force according to claim 1, which is characterized in that including following
Step：
（1）10 parts of zeolites in parts by weight are put into the citric acid solution of its 20 times of volumes, are transferred to after being ultrasonically treated 10min
In vapor tight tank, adjusting hermetically sealed can temperature is 5 DEG C, pressure -0.9MPa, handles 40min, and then adjusting hermetically sealed can temperature is 89 DEG C,
Pressure is 0.3MPa, handles 40min, and cooling bleeds off pressure, then filters, zeolite is put into the sodium hydroxide solution of 20 times of its volume
In, it is transferred in hermetically sealed can after being ultrasonically treated 10min, repeats aforesaid operations, gained zeolite is finally washed with deionized, and be put into
It is dry in 120 DEG C of vacuum oven；
（2）By step（1）Gained zeolite is added in the modification liquid of 20 times of its volume, and it is 50 that heating, which keeps the temperature of modification liquid,
DEG C, it after stirring 30min at 600 rpm, is transferred in 80 DEG C of vacuum oven, is evacuated to -0.1MPa, place 5h, then
It is cooling to take out, it filters, washs, it is dry, obtain modified zeolite；
（3）By step（2）Gained modified zeolite is added in the titanium tetrachloride solution of 30 times of its volume, and 3 parts of nanometers are then added
Ceria, 1 part of silane coupling agent, are dispersed with stirring 30min at 50 DEG C, 800rpm, are then adjusted using sodium hydroxide solution
Its pH value is 8.0, is warming up to 98 DEG C, is stirred to react 13h at 600 rpm, and cooling, centrifugation is filtered and dried at 100 DEG C；
（4）40 parts of polyester polyol and 80 parts of diisocyanate are added in three-necked flask, is mixed evenly, is warming up to 87
DEG C, 2 parts of citric acids are added, 10 parts of chain extenders, 30 parts of polyester polyol, deionized water, steps are added thereto after reacting 3.5h
（3）Gains, the reaction was continued 50min to obtain the final product.
Further, step（1）The citric acid solution mass fraction is 15%.
Further, step（1）The sodium hydroxide solution mass fraction is 10%.
Further, step（1）The ultrasound condition is 120Hz.
Further, step（2）Each ingredient and its corresponding parts by weight are in the modification liquid：20 parts of methyl methacrylates
Ester, 2 parts of CuPcs, 2 parts of sodium alginates, 5 parts of diatomite, 50 parts of deionized waters, the diatomite pass through at 360 DEG C of calcining
Reason.
Further, step（2）The drying temperature is 80 DEG C.
Further, step（2）The titanium tetrachloride solution concentration is 0.8mol/L.
Comparative example 1
Step is omitted compared to embodiment 2 in this comparative example（1）Processing to zeolite, method and step in addition to this are equal
It is identical.
Comparative example 2
Step is omitted compared to embodiment 2 in this comparative example（2）The addition of CuPc in modification liquid, side in addition to this
Method step is all the same.
Comparative example 3
Step is omitted compared to embodiment 2 in this comparative example（2）The addition of diatomite in modification liquid, side in addition to this
Method step is all the same.
Comparative example 4
The addition of nano ceric oxide is omitted compared to embodiment 2 in this comparative example, and method and step in addition to this is homogeneous
Together.
Comparative example 5
The addition of titanium tetrachloride is omitted compared to embodiment 2 in this comparative example, and method and step in addition to this is all the same.
Performance test：
Coating obtained by each group embodiment and comparative example is coated on transparent plastic sheet, is solidified, its purple is then tested
Outside line transmitance, adhesive force and dispersibility, wherein dispersibility test is that coating obtained by each group embodiment and comparative example exists
At 25 DEG C, after humidity is 25% lower placement 10h, the dispersibility of filler is detected, test result is as shown in table 1：
Table 1
As can be seen from Table 1, coating prepared by the present invention ultraviolet light shielding rate with higher, uvioresistant effect is preferable, together
When its coating adhesive force it is stronger, it is not easily to fall off and cracking, can prolong the service life, filler is uniformly dispersed in coating, stability
Well.
Claims (7)
1. a kind of strong anti-ultraviolet paint preparation method of adhesive force according to claim 1, which is characterized in that including with
Lower step：
（1）5-10 part zeolite in parts by weight is put into the citric acid solution of its 10-20 times of volume, 5- is ultrasonically treated
It is transferred in vapor tight tank after 10min, adjusting hermetically sealed can temperature is 2-5 DEG C, and pressure -0.8~-0.9MPa handles 30-40min, then
Adjusting hermetically sealed can temperature is 80-89 DEG C, pressure 0.2-0.3MPa, handles 30-40min, and cooling bleeds off pressure, then filters, will boil
Stone is put into the sodium hydroxide solution of 10-20 times of its volume, is transferred in hermetically sealed can after being ultrasonically treated 5-10min, and above-mentioned behaviour is repeated
Make, gained zeolite is finally washed with deionized, and is put into 110-120 DEG C of vacuum oven dry；
（2）By step（1）Gained zeolite is added in the modification liquid of 10-20 times of its volume, and the temperature of heating holding modification liquid is
It 45-50 DEG C, after stirring 20-30min at 500-600rpm, is transferred in 70-80 DEG C of vacuum oven, be evacuated to-
0.09~-0.1MPa places 3-5h, then cooling to take out, and filters, washs, dry, obtains modified zeolite；
（3）By step（2）Gained modified zeolite is added in the titanium tetrachloride solution of 20-30 times of its volume, is then added 2-3 parts
Nano ceric oxide, 0.5-1 part silane coupling agent, are dispersed with stirring 20-30min at 40-50 DEG C, 700-800rpm, then sharp
Adjusting its pH value with sodium hydroxide solution is 7.0-8.0, is warming up to 90-98 DEG C, is stirred to react 10- at 400-600rpm
13h, cooling, centrifugation, filters and dries at 90-100 DEG C；
（4）30-40 parts of polyester polyol and 70-80 parts of diisocyanate are added in three-necked flask, are mixed evenly, are risen
1-2 parts of citric acids are added to 80-87 DEG C in temperature, and 5-10 parts of chain extenders, 10-30 parts of polyester are added thereto after reacting 2.5-3.5h
Polyalcohol, deionized water, step（3）Gains, the reaction was continued 30-50min to obtain the final product.
2. a kind of strong anti-ultraviolet paint preparation method of adhesive force according to claim 1, which is characterized in that step
（1）The citric acid solution mass fraction is 10-15%.
3. a kind of strong anti-ultraviolet paint preparation method of adhesive force according to claim 1, which is characterized in that step
（1）The sodium hydroxide solution mass fraction is 5-10%.
4. a kind of strong anti-ultraviolet paint preparation method of adhesive force according to claim 1, which is characterized in that step
（1）The ultrasound condition is 100-120Hz.
5. a kind of strong anti-ultraviolet paint preparation method of adhesive force according to claim 1, which is characterized in that step
（2）Each ingredient and its corresponding parts by weight are in the modification liquid：15-20 parts of methyl methacrylates, 1-2 parts of CuPcs, 1-2 parts
Sodium alginate, 3-5 part diatomite, 30-50 parts of deionized waters, the diatomite pass through 350-360 DEG C of calcination processing.
6. a kind of strong anti-ultraviolet paint preparation method of adhesive force according to claim 1, which is characterized in that step
（2）The drying temperature is 60-80 DEG C.
7. a kind of strong anti-ultraviolet paint preparation method of adhesive force according to claim 1, which is characterized in that step
（2）The titanium tetrachloride solution concentration is 0.5-0.8mol/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810952267.9A CN108912999A (en) | 2018-08-21 | 2018-08-21 | A kind of anti-ultraviolet paint preparation method that adhesive force is strong |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810952267.9A CN108912999A (en) | 2018-08-21 | 2018-08-21 | A kind of anti-ultraviolet paint preparation method that adhesive force is strong |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108912999A true CN108912999A (en) | 2018-11-30 |
Family
ID=64406335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810952267.9A Withdrawn CN108912999A (en) | 2018-08-21 | 2018-08-21 | A kind of anti-ultraviolet paint preparation method that adhesive force is strong |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108912999A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1621346A (en) * | 2003-11-28 | 2005-06-01 | 上海家化联合股份有限公司 | Molecular sieve based nano composite anti-ultraviolet material, its preparation method and use |
| CN101322944A (en) * | 2008-07-28 | 2008-12-17 | 吉林大学 | Composite photocatalyst prepared from stephanoporate mineral and method thereof |
| CN103849250A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Method used for preparing furniture decorative coating from epidesmine |
| CN103965672A (en) * | 2014-05-19 | 2014-08-06 | 宁波市爱使电器有限公司 | Paint with strong adhesion for cooling surface for LED (light emitting diode) radiator |
-
2018
- 2018-08-21 CN CN201810952267.9A patent/CN108912999A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1621346A (en) * | 2003-11-28 | 2005-06-01 | 上海家化联合股份有限公司 | Molecular sieve based nano composite anti-ultraviolet material, its preparation method and use |
| CN101322944A (en) * | 2008-07-28 | 2008-12-17 | 吉林大学 | Composite photocatalyst prepared from stephanoporate mineral and method thereof |
| CN103849250A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Method used for preparing furniture decorative coating from epidesmine |
| CN103965672A (en) * | 2014-05-19 | 2014-08-06 | 宁波市爱使电器有限公司 | Paint with strong adhesion for cooling surface for LED (light emitting diode) radiator |
Non-Patent Citations (1)
| Title |
|---|
| 商平等: "《环境矿物材料》", 31 January 2008, 化学工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103555005B (en) | Preparation method of modified kaolin used as rubber reinforcing agent | |
| CN110126043B (en) | Preparation method of heat-conduction enhanced phase-change energy-storage wood based on photo-thermal response | |
| CN106752237B (en) | Water-borne heat-insulating slurry and preparation method thereof and water-borne heat-insulating glass coating and preparation method thereof | |
| CN106366892B (en) | A kind of resistance to scratch-type open air powdery paints | |
| CN107629537A (en) | A kind of processing method of pump paint filler | |
| CN107139298A (en) | A kind of manufacture method of bamboo material surface load nano-titanium dioxide material | |
| CN106893131A (en) | A kind of antistatic heat-proof silica gel skin and its manufacture craft | |
| CN108912999A (en) | A kind of anti-ultraviolet paint preparation method that adhesive force is strong | |
| CN106800722A (en) | A kind of ageing-resistant rigid polyvinyl chloride cable material | |
| CN108250475A (en) | A kind of PVDC coating materials with high obstructing performance and preparation method thereof | |
| CN105922414A (en) | Treating agent with air purification function for bamboo-plaited articles and preparation method of treating agent | |
| CN208432064U (en) | A kind of butyronitrile gloves production drying device | |
| CN106833229A (en) | A kind of energy saving and environment friendly insulating moulding coating and preparation method thereof | |
| CN111138698A (en) | Method for preparing cellulose membrane based on chitosan | |
| CN206046025U (en) | A kind of EVOH resin-mades are for process units | |
| CN108342132A (en) | A kind of PVDC coating materials and preparation method thereof with high obstructing performance | |
| CN115229918A (en) | Preparation method of antibacterial transparent wood with solid wood color and texture | |
| CN108165212A (en) | One kind eliminates the unusual smell adhesive | |
| CN107760133A (en) | A kind of preparation method of the organo-mineral complexing coating of nanometer of lanthanum hexaboride collaboration enhancing effect of heat insulation | |
| CN109796913A (en) | A kind of adhesive containing modified Nano bamboo charcoal powder | |
| CN111500028A (en) | High-strength modified PBAT photocatalytic antibacterial film and preparation method thereof | |
| CN105856369A (en) | Shell powder-sodium alginate bamboo-woven product treatment agent and preparation method thereof | |
| CN107474314B (en) | The dedicated titanium dioxide process of plastic material | |
| CN213886854U (en) | Spraying device is used in processing of silica gel goods | |
| CN208824923U (en) | A kind of door-plate varnish-baking device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181130 |
|
| WW01 | Invention patent application withdrawn after publication |