CN108912440A - A kind of uvioresistant antimicrobial composite material - Google Patents

A kind of uvioresistant antimicrobial composite material Download PDF

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Publication number
CN108912440A
CN108912440A CN201810520943.5A CN201810520943A CN108912440A CN 108912440 A CN108912440 A CN 108912440A CN 201810520943 A CN201810520943 A CN 201810520943A CN 108912440 A CN108912440 A CN 108912440A
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Prior art keywords
parts
nano
uvioresistant
composite material
diatomite
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CN201810520943.5A
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Chinese (zh)
Inventor
李东霖
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Anhui Shuntong Packaging Material Co Ltd
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Anhui Shuntong Packaging Material Co Ltd
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Priority to CN201810520943.5A priority Critical patent/CN108912440A/en
Publication of CN108912440A publication Critical patent/CN108912440A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

Abstract

The invention discloses a kind of uvioresistant antimicrobial composite materials, are made of raw material from the following weight:30-45 parts of low density polyethylene (LDPE), 10-15 parts of Nano silica sol, 10-15 parts of butadiene rubber, 5-9 parts of nanometer TPU powder, 2-8 parts of nano modification diatomite, 3-8 parts of nano silica, 2-6 parts of plant amylum, 1-5 parts of bamboo fibre, 3-7 parts of ultraviolet absorbing agent, 3-6 parts of antibacterial filler, 1-3 parts of antioxidant, 2-5 parts of heat stabilizer, 2-5 parts of plasticizer, 1-4 parts of compatilizer.Zinc oxide, boron oxide, tellurium dioxide are creatively added in antibacterial filler of the invention, so that composite material obtained has the advantages that good mechanical properties, corrosion-resistant, electric conductivity is superior, ductility is good;Contain zeolite with carrying silver in antibacterial filler, it is safe and non-toxic, antimicrobial efficiency is higher;The ultraviolet absorbing agent of addition, so that composite material has good anti-ultraviolet property.

Description

A kind of uvioresistant antimicrobial composite material
Technical field
The present invention relates to polymeric material field, specifically a kind of uvioresistant antimicrobial composite material.
Background technique
Composite material is to be passed through by two or more material of different nature either physically or chemically, in macroscopically group At a kind of material with new capability, a variety of materials learn from other's strong points to offset one's weaknesses in performance, generate coordinating effect, make the comprehensive of composite material It closes performance and meets different demands better than each component.
Present composite material uvioresistant anti-microbial property needs further improve.
Summary of the invention
The purpose of the present invention is to provide a kind of uvioresistant antimicrobial composite materials, to solve to propose in above-mentioned background technique The problem of.
To achieve the above object, the present invention provides the following technical solutions:
A kind of uvioresistant antimicrobial composite material, is made of raw material from the following weight:
30-45 parts of low density polyethylene (LDPE), 10-15 parts of Nano silica sol, 10-15 parts of butadiene rubber, nanometer TPU powder 5-9 Part, 2-8 parts of nano modification diatomite, 3-8 parts of nano silica, 2-6 parts of plant amylum, 1-5 parts of bamboo fibre, ultraviolet radiation absorption 3-7 parts of agent, 3-6 parts of antibacterial filler, 1-3 parts of antioxidant, 2-5 parts of heat stabilizer, 2-5 parts of plasticizer, 1-4 parts of compatilizer.
A kind of uvioresistant antimicrobial composite material, is made of raw material from the following weight:
30 parts of low density polyethylene (LDPE), 10 parts of Nano silica sol, 10 5 parts of part, nanometer TPU powder of butadiene rubber, nano modification 2 parts of diatomite, 3 parts of nano silica, 2 parts of plant amylum, 1 part of bamboo fibre, 3 parts of ultraviolet absorbing agent, 3 parts of antibacterial filler, 1 part of antioxidant, 2 parts of heat stabilizer, 2 parts of plasticizer, 1 part of compatilizer.
A kind of uvioresistant antimicrobial composite material, is made of raw material from the following weight:
45 parts of low density polyethylene (LDPE), 15 parts of Nano silica sol, 15 9 parts of part, nanometer TPU powder of butadiene rubber, nano modification 8 parts of diatomite, 8 parts of nano silica, 6 parts of plant amylum, 5 parts of bamboo fibre, 7 parts of ultraviolet absorbing agent, 6 parts of antibacterial filler, 3 parts of antioxidant, 5 parts of heat stabilizer, 5 parts of plasticizer, 4 parts of compatilizer.
A kind of uvioresistant antimicrobial composite material, is made of raw material from the following weight:
38 parts of low density polyethylene (LDPE), 13 parts of Nano silica sol, 13 7 parts of part, nanometer TPU powder of butadiene rubber, nano modification 5 parts of diatomite, 6 parts of nano silica, 4 parts of plant amylum, 3 parts of bamboo fibre, 5 parts of ultraviolet absorbing agent, 4 parts of antibacterial filler, 2 parts of antioxidant, 4 parts of heat stabilizer, 4 parts of plasticizer, 3 parts of compatilizer.
Preferably, the nano modification diatomite is made of raw material from the following weight:10-20 parts of sodium based diatomite, benzene 25-33 parts of acrylic emulsion, 5-9 parts of para-aminobenzoate, appropriate deionized water.
The preparation method of the nano modification diatomite is as follows:
1) sodium based diatomite and appropriate amount of deionized water are made into suspension, first high-speed stirred 30 minutes at room temperature, heating Sodium based diatomite complete swelling is dispersed to 55 DEG C of high-speed stirreds;
2) para-aminobenzoate is added thereto again, is warming up to 80-88 DEG C, stirs 60-75 minutes, then cooling, pumping Filter, be dried in vacuo, grinding and to obtain nano diatomite;
3) nano diatomite and appropriate amount of deionized water are configured to suspension, specially first high-speed stirred 30- at room temperature 40 minutes, then heat to 50 DEG C, ultrasonic vibration 10 minutes, then styrene-acrylic emulsion is added dropwise, 30 DEG C are adjusted the temperature to, 1- is dispersed with stirring 2 hours, then ultrasound 10 minutes, then through cooling, suction filtration, vacuum drying, grind up to nano modification diatomite.
Preferably, the antibacterial filler is made from the following raw materials in parts by weight:2-5 parts of zeolite with carrying silver, attapulgite 1-5 Part, 5-8 parts of carbon fiber, 4-10 parts of graphene, 3-8 parts of soybean oil, 2-4 parts of zinc oxide, 3-6 parts of boron oxide, tellurium dioxide 3-6 Part.
Preferably, the heat stabilizer is calcium zinc class composite thermal stabilizer.
The plasticizer is glycerol or propylene glycol.
Preferably, the compatilizer is maleic anhydride graft type compatilizer.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention cooperates nano silica solution, butadiene rubber, nanometer TPU powder, makes using low density polyethylene (LDPE) as major ingredient It obtains product and has cold-resistant, wear-resisting scratch-resistant, shock resistance, ageing-resistant, uvioresistant, weather-proof, corrosion-resistant, high-barrier excellent performance; A certain amount of butadiene rubber is added, so that composite material cold resistance obtained, wearability, elasticity, ageing-resistant performance are good;Antibacterial is filled out Zinc oxide, boron oxide, tellurium dioxide are creatively added in material so that composite material obtained have good mechanical properties, Advantage corrosion-resistant, electric conductivity is superior, ductility is good;Contain zeolite with carrying silver, safe and non-toxic, antimicrobial efficiency in antibacterial filler It is higher;The ultraviolet absorbing agent of addition, so that composite material has good anti-ultraviolet property.
Specific embodiment
Embodiment 1
A kind of uvioresistant antimicrobial composite material, is made of raw material from the following weight:
30 parts of low density polyethylene (LDPE), 10 parts of Nano silica sol, 10 5 parts of part, nanometer TPU powder of butadiene rubber, nano modification 2 parts of diatomite, 3 parts of nano silica, 2 parts of plant amylum, 1 part of bamboo fibre, 3 parts of ultraviolet absorbing agent, 3 parts of antibacterial filler, 1 part of antioxidant, 2 parts of heat stabilizer, 2 parts of plasticizer, 1 part of compatilizer.
Preferably, the nano modification diatomite is made of raw material from the following weight:10-20 parts of sodium based diatomite, benzene 25-33 parts of acrylic emulsion, 5-9 parts of para-aminobenzoate, appropriate deionized water.
The preparation method of the nano modification diatomite is as follows:
1) sodium based diatomite and appropriate amount of deionized water are made into suspension, first high-speed stirred 30 minutes at room temperature, heating Sodium based diatomite complete swelling is dispersed to 55 DEG C of high-speed stirreds;
2) para-aminobenzoate is added thereto again, is warming up to 80-88 DEG C, stirs 60-75 minutes, then cooling, pumping Filter, be dried in vacuo, grinding and to obtain nano diatomite;
3) nano diatomite and appropriate amount of deionized water are configured to suspension, specially first high-speed stirred 30- at room temperature 40 minutes, then heat to 50 DEG C, ultrasonic vibration 10 minutes, then styrene-acrylic emulsion is added dropwise, 30 DEG C are adjusted the temperature to, 1- is dispersed with stirring 2 hours, then ultrasound 10 minutes, then through cooling, suction filtration, vacuum drying, grind up to nano modification diatomite.
Preferably, the antibacterial filler is made from the following raw materials in parts by weight:2-5 parts of zeolite with carrying silver, attapulgite 1-5 Part, 5-8 parts of carbon fiber, 4-10 parts of graphene, 3-8 parts of soybean oil, 2-4 parts of zinc oxide, 3-6 parts of boron oxide, tellurium dioxide 3-6 Part.
Preferably, the heat stabilizer is calcium zinc class composite thermal stabilizer.
The plasticizer is glycerol or propylene glycol.
Preferably, the compatilizer is maleic anhydride graft type compatilizer.
Embodiment 2
A kind of uvioresistant antimicrobial composite material, is made of raw material from the following weight:
45 parts of low density polyethylene (LDPE), 15 parts of Nano silica sol, 15 9 parts of part, nanometer TPU powder of butadiene rubber, nano modification 8 parts of diatomite, 8 parts of nano silica, 6 parts of plant amylum, 5 parts of bamboo fibre, 7 parts of ultraviolet absorbing agent, 6 parts of antibacterial filler, 3 parts of antioxidant, 5 parts of heat stabilizer, 5 parts of plasticizer, 4 parts of compatilizer.
Preferably, the nano modification diatomite is made of raw material from the following weight:10-20 parts of sodium based diatomite, benzene 25-33 parts of acrylic emulsion, 5-9 parts of para-aminobenzoate, appropriate deionized water.
The preparation method of the nano modification diatomite is as follows:
1) sodium based diatomite and appropriate amount of deionized water are made into suspension, first high-speed stirred 30 minutes at room temperature, heating Sodium based diatomite complete swelling is dispersed to 55 DEG C of high-speed stirreds;
2) para-aminobenzoate is added thereto again, is warming up to 80-88 DEG C, stirs 60-75 minutes, then cooling, pumping Filter, be dried in vacuo, grinding and to obtain nano diatomite;
3) nano diatomite and appropriate amount of deionized water are configured to suspension, specially first high-speed stirred 30- at room temperature 40 minutes, then heat to 50 DEG C, ultrasonic vibration 10 minutes, then styrene-acrylic emulsion is added dropwise, 30 DEG C are adjusted the temperature to, 1- is dispersed with stirring 2 hours, then ultrasound 10 minutes, then through cooling, suction filtration, vacuum drying, grind up to nano modification diatomite.
Preferably, the antibacterial filler is made from the following raw materials in parts by weight:2-5 parts of zeolite with carrying silver, attapulgite 1-5 Part, 5-8 parts of carbon fiber, 4-10 parts of graphene, 3-8 parts of soybean oil, 2-4 parts of zinc oxide, 3-6 parts of boron oxide, tellurium dioxide 3-6 Part.
Preferably, the heat stabilizer is calcium zinc class composite thermal stabilizer.
The plasticizer is glycerol or propylene glycol.
Preferably, the compatilizer is maleic anhydride graft type compatilizer.
Embodiment 3
A kind of uvioresistant antimicrobial composite material, is made of raw material from the following weight:
38 parts of low density polyethylene (LDPE), 13 parts of Nano silica sol, 13 7 parts of part, nanometer TPU powder of butadiene rubber, nano modification 5 parts of diatomite, 6 parts of nano silica, 4 parts of plant amylum, 3 parts of bamboo fibre, 5 parts of ultraviolet absorbing agent, 4 parts of antibacterial filler, 2 parts of antioxidant, 4 parts of heat stabilizer, 4 parts of plasticizer, 3 parts of compatilizer.
Preferably, the nano modification diatomite is made of raw material from the following weight:10-20 parts of sodium based diatomite, benzene 25-33 parts of acrylic emulsion, 5-9 parts of para-aminobenzoate, appropriate deionized water.
The preparation method of the nano modification diatomite is as follows:
1) sodium based diatomite and appropriate amount of deionized water are made into suspension, first high-speed stirred 30 minutes at room temperature, heating Sodium based diatomite complete swelling is dispersed to 55 DEG C of high-speed stirreds;
2) para-aminobenzoate is added thereto again, is warming up to 80-88 DEG C, stirs 60-75 minutes, then cooling, pumping Filter, be dried in vacuo, grinding and to obtain nano diatomite;
3) nano diatomite and appropriate amount of deionized water are configured to suspension, specially first high-speed stirred 30- at room temperature 40 minutes, then heat to 50 DEG C, ultrasonic vibration 10 minutes, then styrene-acrylic emulsion is added dropwise, 30 DEG C are adjusted the temperature to, 1- is dispersed with stirring 2 hours, then ultrasound 10 minutes, then through cooling, suction filtration, vacuum drying, grind up to nano modification diatomite.
Preferably, the antibacterial filler is made from the following raw materials in parts by weight:2-5 parts of zeolite with carrying silver, attapulgite 1-5 Part, 5-8 parts of carbon fiber, 4-10 parts of graphene, 3-8 parts of soybean oil, 2-4 parts of zinc oxide, 3-6 parts of boron oxide, tellurium dioxide 3-6 Part.
Preferably, the heat stabilizer is calcium zinc class composite thermal stabilizer.
The plasticizer is glycerol or propylene glycol.
Preferably, the compatilizer is maleic anhydride graft type compatilizer.

Claims (9)

1. a kind of uvioresistant antimicrobial composite material, which is characterized in that be made of raw material from the following weight:
30-45 parts of low density polyethylene (LDPE), 10-15 parts of butadiene rubber, 5-9 parts of nanometer TPU powder, is received 10-15 parts of Nano silica sol Rice 2-8 parts of modification infusorial earth, 3-8 parts of nano silica, 2-6 parts of plant amylum, 1-5 parts of bamboo fibre, ultraviolet absorbing agent 3-7 Part, 3-6 parts of antibacterial filler, 1-3 parts of antioxidant, 2-5 parts of heat stabilizer, 2-5 parts of plasticizer, 1-4 parts of compatilizer.
2. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that by the raw material system of following parts by weight At:
30 parts of low density polyethylene (LDPE), 10 parts of Nano silica sol, 10 5 parts of part, nanometer TPU powder of butadiene rubber, nano modification diatom Native 2 parts, 3 parts of nano silica, 2 parts of plant amylum, 1 part of bamboo fibre, 3 parts of ultraviolet absorbing agent, 3 parts of antibacterial filler, antioxygen 1 part of agent, 2 parts of heat stabilizer, 2 parts of plasticizer, 1 part of compatilizer.
3. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that by the raw material system of following parts by weight At:
45 parts of low density polyethylene (LDPE), 15 parts of Nano silica sol, 15 9 parts of part, nanometer TPU powder of butadiene rubber, nano modification diatom Native 8 parts, 8 parts of nano silica, 6 parts of plant amylum, 5 parts of bamboo fibre, 7 parts of ultraviolet absorbing agent, 6 parts of antibacterial filler, antioxygen 3 parts of agent, 5 parts of heat stabilizer, 5 parts of plasticizer, 4 parts of compatilizer.
4. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that by the raw material system of following parts by weight At:
38 parts of low density polyethylene (LDPE), 13 parts of Nano silica sol, 13 7 parts of part, nanometer TPU powder of butadiene rubber, nano modification diatom Native 5 parts, 6 parts of nano silica, 4 parts of plant amylum, 3 parts of bamboo fibre, 5 parts of ultraviolet absorbing agent, 4 parts of antibacterial filler, antioxygen 2 parts of agent, 4 parts of heat stabilizer, 4 parts of plasticizer, 3 parts of compatilizer.
5. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that the nano modification diatomite by The raw material of following parts by weight is made:10-20 parts of sodium based diatomite, 5-9 parts of para-aminobenzoate, is gone 25-33 parts of styrene-acrylic emulsion Ion appropriate amount of water;
The preparation method of the nano modification diatomite is as follows:
1) sodium based diatomite and appropriate amount of deionized water are made into suspension, first high-speed stirred 30 minutes at room temperature are warming up to 55 DEG C high-speed stirred is dispersed to sodium based diatomite complete swelling;
2) para-aminobenzoate is added thereto again, is warming up to 80-88 DEG C, stirs 60-75 minutes, then cools down, filter, is true Sky is dry, grinds to obtain nano diatomite;
3) nano diatomite and appropriate amount of deionized water are configured to suspension, specially first high-speed stirred 30-40 divides at room temperature Clock, then heats to 50 DEG C, and ultrasonic vibration 10 minutes, then styrene-acrylic emulsion is added dropwise, 30 DEG C are adjusted the temperature to, it is small to be dispersed with stirring 1-2 When, then ultrasound 10 minutes, then through cooling, suction filtration, vacuum drying, grind up to nano modification diatomite.
6. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that the antibacterial filler is by following heavy The raw material of amount part is made:2-5 parts of zeolite with carrying silver, 1-5 parts of attapulgite, 5-8 parts of carbon fiber, 4-10 parts of graphene, soybean oil 3-8 Part, 2-4 parts of zinc oxide, 3-6 parts of boron oxide, 3-6 parts of tellurium dioxide.
7. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that the heat stabilizer is calcium zinc class Composite thermal stabilizer.
8. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that the plasticizer is glycerol or third Glycol.
9. uvioresistant antimicrobial composite material according to claim 1, which is characterized in that the compatilizer is maleic anhydride Graft type compatilizer.
CN201810520943.5A 2018-05-28 2018-05-28 A kind of uvioresistant antimicrobial composite material Withdrawn CN108912440A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971136A (en) * 2019-03-21 2019-07-05 深圳市昱荣环保材料有限公司 A kind of plastic uptake antiultraviolet film and preparation method thereof
CN110776043A (en) * 2019-10-23 2020-02-11 安徽国电能源设备工程有限公司 Preparation method of filter element for removing residual chlorine in water

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876001A (en) * 2012-09-20 2013-01-16 吴江市天源塑胶有限公司 Anti-aging thermoplastic elastomer
CN105885165A (en) * 2016-04-29 2016-08-24 安徽巢湖南方膜业有限责任公司 Environmentally-friendly shopping paper bag water-proof outer film
CN107011584A (en) * 2017-06-08 2017-08-04 合肥帧讯低温科技有限公司 A kind of low temperature resistant heat-insulating heat-preserving material of antimicrobial form

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876001A (en) * 2012-09-20 2013-01-16 吴江市天源塑胶有限公司 Anti-aging thermoplastic elastomer
CN105885165A (en) * 2016-04-29 2016-08-24 安徽巢湖南方膜业有限责任公司 Environmentally-friendly shopping paper bag water-proof outer film
CN107011584A (en) * 2017-06-08 2017-08-04 合肥帧讯低温科技有限公司 A kind of low temperature resistant heat-insulating heat-preserving material of antimicrobial form

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971136A (en) * 2019-03-21 2019-07-05 深圳市昱荣环保材料有限公司 A kind of plastic uptake antiultraviolet film and preparation method thereof
CN110776043A (en) * 2019-10-23 2020-02-11 安徽国电能源设备工程有限公司 Preparation method of filter element for removing residual chlorine in water
CN110776043B (en) * 2019-10-23 2023-10-31 安徽国电能源设备工程有限公司 Preparation method of filter element for removing residual chlorine in water

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Application publication date: 20181130