CN108911395A - A kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation - Google Patents

A kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation Download PDF

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Publication number
CN108911395A
CN108911395A CN201810809796.3A CN201810809796A CN108911395A CN 108911395 A CN108911395 A CN 108911395A CN 201810809796 A CN201810809796 A CN 201810809796A CN 108911395 A CN108911395 A CN 108911395A
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China
Prior art keywords
water
pipe
organic waste
gas
methyl
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Withdrawn
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CN201810809796.3A
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Chinese (zh)
Inventor
梁峙
梁骁
马捷
张猛
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Xuzhou Tengrui Intelligent Equipment Co Ltd
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Xuzhou Tengrui Intelligent Equipment Co Ltd
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Priority to CN201810809796.3A priority Critical patent/CN108911395A/en
Publication of CN108911395A publication Critical patent/CN108911395A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B2101/00Type of solid waste
    • B09B2101/02Gases or liquids enclosed in discarded articles, e.g. aerosol cans or cooling systems of refrigerators
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of agricultural organic waste comprehensive utilization devices for camplotheca acuminata plantation, wherein promotion column precipitator includes in equipment:Microwave susceptor, electromagnetic coil, inductance, capacitor, reflection convex lens, pipelined channel, microwave tube, microwave tube protective cover;It is equipped with microwave tube protective cover on microwave susceptor top, is waterproof construction, is equipped with inside microwave tube protective cover, electromagnetic coil, inductance, capacitor, reflection convex lens, microwave tube, the wherein mutual conducting wire connection of electromagnetic coil, inductance, capacitor, microwave tube;It is equipped with reflection convex lens in microwave tube lower part, reflects convex lens stainless steel mirror material;Promote column precipitator up and down;The pipelined channel, which is located at, to be promoted between column precipitator shell and microwave tube protective cover.A kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation of the present invention, the plant automation degree is high, stable and reliable operation, convenient later maintenance.

Description

A kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation
Technical field
The invention belongs to agricultural organic waste comprehensive utilization device fields, and in particular to a kind of agriculture for camplotheca acuminata plantation Industry organic waste comprehensive utilization device.
Background technique
Camplotheca acuminata is perennial woody plant, and wide adaptability, resistance is stronger, and fibrous root is flourishing, and stalk is sturdy, nutritive value It is high.But when Camptotheca acuminata seedlings are cultivated, need the soilless cultivation raw material of high nutrition.Thick protein, crude fibre in corn stover dry matter Equal size is very rich, is often used as soilless cultivation raw material.Due to corn have grow it is vigorous, yield per unit area is high, Regeneration power is strong, can multi-harvest the features such as, therefore, as can basing oneself upon various regions resource, make full use of rural areas in our country agriculture abundant Crop material and livestock and poultry dropping source research and develop environment-friendly type cultivation matrix needed for camplotheca acuminata planting process, must can bring huge society Meeting, economy and ecological benefits.The present invention uses animal manure and crop material for raw material, adjusts by the way that dealing with earthworm and formula are preferred It is allowed to be used for the soilless cultivation of Camptotheca acuminata seedlings as environment-friendly type organic substrate, to solve agricultural and rural environmental pollution, development Organic agriculture, reduction production cost, raising camplotheca acuminata quality etc. provide technical support.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of comprehensive benefits of the agricultural organic waste for camplotheca acuminata plantation With device, including:Discharge port 21-1, auger 21-2, separating sieve 21-3 crush motor 21-4, feed hopper 21-5, pulverization roller 21- 6, dust removing tube 21-7, dispersion plate 21-8, blanking tube 21-9, horizontal push plate 21-10, push plate crankshaft 21-11, blanking amount controller 21-12, blanking slideway 21-13, chemicals dosing plant 21-14, mixing chamber 21-15, can not fragmenting bulk export 21-16, outside water of compaction Comb 21-17;
Feed hopper 21-5 positioned at top is passed through with blanking tube 21-9, blanking slideway 21-13, mixing chamber 21-15, discharge port 21-1 Logical, the lower part feed hopper 21-5 is equipped with pulverization roller 21-6, and pulverization roller 21-6 quantity is 2, arranged opposite, 2 pulverization roller 21-6 with Outside crushes motor 21-4 mechanical connection;The lower part pulverization roller 21-6 is equipped with dispersion plate 21-8, is equipped with level in the middle part of dispersion plate 21-8 Axis, dispersion plate 21-8 swing along trunnion axis, and the surface dispersion plate 21-8 is equipped with a large amount of through-holes;The lower part dispersion plate 21-8, which is equipped with, to be divided It is equipped with horizontal push plate 21-10 on the left of choosing sieve 21-3, separating sieve 21-3, horizontal push plate 21-10 passes through push plate crankshaft 21-11 and motor Connection;Being equipped on the right side of separating sieve 21-3 can not fragmenting bulk outlet 21-16;The lower part separating sieve 21-3 is equipped with blanking amount controller 21-12;Blanking amount controller 21-12 is horizontal push-pull configuration, and blanking amount controller 21-12 controls blanking velocity;Discharge quantity control The lower part device 21-12 processed is equipped with blanking slideway 21-13, and the lower part blanking slideway 21-13 is equipped with mixing chamber 21-15, mixing chamber 21-15 It is connected to chemicals dosing plant 21-14;The lower part mixing chamber 21-15 is equipped with auger 21-2, and the lower part of the auger 21-2 other end is equipped with discharging Mouth 21-1;The outer comb 21-17 of water of compaction is located at auger 21-2 bottom side;
The outer comb 21-17 of water of compaction is connected to cesspool 1;
Discharge port 21-1 is connected to organic waste pressurizing unit 22.
Further, this section is the explanation to heretofore described chemicals dosing plant 21-14 structure.Chemicals dosing plant 21-14 packet It includes:Drug-feeding tube 21-14-1, peep hole 21-14-2, drug discharging tube 21-14-3, DC electric field cathode 21-14-4, agitating shaft 21-14- 5, DC electric field anode 21-14-6;
The chemicals dosing plant 21-14 housings close structure, the agitating shaft 21-14-5 in portion disposed thereon pass through gear and external electrical Machine connection, the lower part agitating shaft 21-14-5 are equipped with impeller;It is equipped with drug-feeding tube 21-14-1 in chemicals dosing plant 21-14 shell side, into The top pencil 21-14-1 is equipped with DC electric field anode 21-14-6, and DC electric field anode 21-14-6 is inserted into chemicals dosing plant 21-14 Enclosure interior;It is equipped with drug discharging tube 21-14-3 in the chemicals dosing plant 21-14 shell other side, the top drug discharging tube 21-14-3 is equipped with direct current Electric field cathode 21-14-4, DC electric field cathode 21-14-4 are inserted into chemicals dosing plant 21-14 enclosure interior;DC electric field cathode 21- 14-4 is connect with outside DC electric field anode 21-14-6 with DC power supply;Peep hole is equipped in chemicals dosing plant 21-14 shell side 21-14-2。
Further, this section is the explanation to heretofore described 22 structure of organic waste pressurizing unit.Organic waste Object pressurizing unit 22 includes:Extruder loading hopper 22-1 squeezes capstan winch 22-2, counter-force pallet 22-3, expressed water comb 22-4, Sluicing pipe 22-5 squeezes water collecting tank 22-6, counter-force supporting plate 22-7, organic waste discharge outlet 22-8, lower compression water comb 22-9, capstan winch motor 22-10;
Extruder loading hopper 22-1 positioned at top, its underpart are equipped with counter-force pallet 22-3, counter-force pallet 22-3 concave, center Hatch frame, counter-force pallet 22-3 quantity are 2;The counter-force side pallet 22-3 is equipped with expressed water comb 22-4;Expressed water comb 22-4 is connected to the extruding water collecting tank 22-6 of lower part, is squeezed water collecting tank 22-6 and is connected to lower compression water comb 22-9;Instead It is equipped at power pallet 22-3 king and squeezes capstan winch 22-2, run through 2 counter-force pallet 22-3 up and down, squeeze capstan winch 22-2 It is mechanically connected with external capstan winch motor 22-10;Squeeze the bottom capstan winch 22-2 be equipped with counter-force supporting plate 22-7, be inclined design, Rectangle, surface are equipped with a large amount of through-holes, and the counter-force side supporting plate 22-7 is equipped with organic waste discharge outlet 22-8;Counter-force supporting plate 22- 7 bottoms are equipped with lower compression water comb 22-9;Sluicing pipe 22-5 is equipped on the extruder top loading hopper 22-1;
Lower compression water comb 22-9 is connected to cesspool 1.
Further, this section is the explanation to heretofore described water of compaction after-treatment system structure.Water of compaction post-processing System includes:Cesspool 1, reaction tower 2, anaerobic pond 3, drainage tube 4, grid 5, filler 6, aerobic tank 7, air blower 8, blender 9, control cabinet 10;
2 side of reaction tower is equipped with cesspool 1, and the other side is equipped with anaerobic pond 3, cesspool 1 and anaerobic pond 3 by pipeline with Reaction tower 2 connects;The control cabinet 10 is located at 2 front side of reaction tower;The 3 top both ends of anaerobic pond are equipped with blender 9, blender 9 altogether there are two, blender 9 is controlled by conducting wire and control cabinet 10 to be connected;3 side of anaerobic pond is equipped with drainage tube 4, drainage tube 4 quantity are not less than 12, and wherein 4 one end of drainage tube and anaerobic pond 3 penetrate through, and the other end and aerobic tank 7 penetrate through;The air blower 8 Positioned at 7 bottom both ends of aerobic tank, 8 quantity of air blower is two, and air blower 8 and aerobic tank 7 penetrate through;It is set inside the aerobic tank 7 There is filler 6;The grid 5 is located at 7 inner tip of aerobic tank, and grid 5 is fixedly connected with aerobic tank 7.
Further, this section is the explanation to heretofore described 1 structure of cesspool.Cesspool 1 includes:Mud discharging pipe 1-1, COD detector 1-2, bilge discharge pipe 1-3 promote column precipitator 1-4, wave agitation plate 1-5, buffer subsystem 1-6, polyaluminum sulfate System 1-7, sewage inlet pipe 1-8 is added in aluminium;
Sewage inlet pipe 1-8 positioned at top, its underpart are equipped with polyaluminium sulfate and system 1-7 are added, and wherein polyaluminium sulfate adds Entering system 1-7 includes water pump, ring pipe, shower nozzle, and the quantity of ring pipe is 3, and ring pipe lower part is equipped with a large amount of spray heads, ring Shape pipe is connected to spray head;The lower part system 1-7 is added in polyaluminium sulfate and is equipped with buffer subsystem 1-6, buffer subsystem 1-6 multilayer, screen distance 2cm~4cm;The lower part buffer subsystem 1-6 is equipped with wave agitation plate 1-5, and the wave agitation section plate 1-5 is W type, and quantity is 20, point Two groups, wave agitation plate 1-5 spacing 20cm~40cm, all wave agitation plate 1-5 are connect with external crankshaft, and external motor drives Wave agitation plate 1-5 low speed horizontal pan inside crankshaft promotion;The wave agitation lower part plate 1-5 be equipped with promote column precipitator 1-4, Quantity is 15, is vertically arranged;Bilge discharge pipe 1-3 is equipped in the lower part column precipitator 1-4;It is arranged in 1 bottom of cesspool equipped with sludge Put pipe 1-1;
The cesspool 1 is located inside water of compaction after-treatment system.
Further, this section is to the heretofore described explanation for promoting column precipitator 1-4 structure.Promote column precipitator 1-4 packet It includes:Microwave susceptor 1-4-1, electromagnetic coil 1-4-2, inductance 1-4-3, capacitor 1-4-4 reflect convex lens 1-4-5, pipelined channel 1- 4- 6, microwave tube 1-4-7, microwave tube protective cover 1-4-8;It is equipped with microwave tube protective cover 1-4-8 on the top microwave susceptor 1-4-1, It is waterproof construction, is equipped with inside microwave tube protective cover 1-4-8, electromagnetic coil 1-4-2, inductance 1-4-3, capacitor 1-4-4, anti- Convex lens 1-4-5, microwave tube 1-4-7 are penetrated, wherein electromagnetic coil 1-4-2, inductance 1-4-3, capacitor 1-4-4, microwave tube 1-4-7 Mutual conducting wire connection;It is equipped with reflection convex lens 1-4-5 in the lower part microwave tube 1-4-7, reflects convex lens 1-4-5 stainless steel mirror material; Promote column precipitator 1-4 up and down;The pipelined channel 1-4-6, which is located at, promotes column precipitator 1-4 shell and microwave tube protective cover 1- Between 4-8;
Further, this section is the explanation to heretofore described 2 structure of reaction tower.The reaction tower 2 includes:Aspiration pump 2-1, Emission-control equipment 2-2, sewage pump 2-3, sewage pipe 2-4, reaction chamber 2-5, tracheae 2-6, outlet pipe 2-7, exhaust pipe 2-8;Institute It states reaction chamber 2-5 bottom side and is equipped with emission-control equipment 2-2 and sewage pump 2-3, wherein emission-control equipment 2-2 and reaction chamber It is penetrated through between 2-5 by tracheae 2-6;Sewage pipe 2-4 is equipped on the sewage pump 2-3, sewage pipe 2-4 shape is handstand U-typed; The side the emission-control equipment 2-2 is equipped with aspiration pump 2-1, and aspiration pump 2-1 is penetrated through by pipeline and emission-control equipment 2-2, Wherein exhaust pipe 2-8 is equipped on aspiration pump 2-1;The top reaction chamber 2-5 side is equipped with outlet pipe 2-7, outlet pipe 2-7 and anti- Room 2-5 is answered to penetrate through;The aspiration pump 2-1 and sewage pump 2-3 passes through conducting wire and is connected with the control of control cabinet 10.
Further, this section is the explanation to heretofore described emission-control equipment 2-2 structure.Emission-control equipment 2- 2 include:Exhaust inlet pipe 2-2-1, washs sparge pipe 2-2-2, purified gas outlet pipe 2-2-3, adsorbent equipment 2-2-4, and washing water goes out Pipe 2-2-5;Emission-control equipment 2-2 enclosed construction;Purified gas outlet pipe 2-2-3 positioned at top, its underpart are equipped with washing water spray Pipe 2-2-2 is provided with a large amount of through-holes for ring structure, its underpart;It washs the lower part sparge pipe 2-2-2 and is equipped with adsorbent equipment 2-2-4, Adsorbent equipment 2-2-4 honeycomb structure;The lower part adsorbent equipment 2-2-4 is equipped with exhaust inlet pipe 2-2-1, exhaust inlet pipe 2-2-1 Upper end is equipped with umbrella gas outlet;The bottom emission-control equipment 2-2 is equipped with washing water outlet pipe 2-2-5;The emission-control equipment 2-2 Inside reaction tower 2.
Further, this section is the explanation to heretofore described reaction chamber 2-5 structure.The reaction chamber 2-5 includes:Point Flow tube 2-5-1, spray head 2-5-2, partition 2-5-3, water outlet 2-5-4, gas chamber 2-5-5 collect air column 2-5-6;
The reaction chamber 2-5 inner bottom is equipped with isocon 2-5-1, is equipped with spray head 2-5-2, spray head 2-5-2 on isocon 2-5-1 Quantity is 6;The reaction chamber 2-5 inner tip is equipped with gas chamber 2-5-5, and wherein the bottom end gas chamber 2-5-5 is equipped with collection air column 2-5- 6, collection air column 2-5-6 quantity is not less than 10, and collection air column 2-5-6 and gas chamber 2-5-5 are penetrated through;Run through on the collection air column 2-5-6 There are partition 2-5-3, partition 2-5-3 mono- to be divided into two layers, is fixedly connected inside partition 2-5-3 and reaction chamber 2-5;The water outlet 2-5-4 is located at reaction chamber 2-5 top side, and water outlet 2-5-4 is welded and fixed with outlet pipe 2-7.
Further, this section is the explanation to heretofore described collection air column 2-5-6 structure.The collection air column 2-5-6 packet It includes:Gas outlet 2-5-6-1, catalyst jet pipe 2-5-6-2, steam jet 2-5-6-3, organic matter adsorbent material 2-5-6-4, water row Pipe 2-5-6-5 is put, air column partition 2-5-6-6, air inlet 2-5-6-7, detection hole 2-5-6-8 are collected;
Positioned at the gas outlet 2-5-6-1 on top, uncovered structure, treated, and gas is discharged from gas outlet 2-5-6-1;The catalysis Agent jet pipe 2-5-6-2 is located at the gas outlet lower part 2-5-6-1, the two spacing 20cm~40cm, and the top catalyst jet pipe 2-5-6-2 is set There is valve, valve and supervisor connect, and supervisor lower part connects multiple branch pipes, and the quantity of branch pipe is 2~8, and the end of branch pipe is equipped with Spray head, spray head spray into catalyst in collection air column 2-5-6, and catalyst promotes the degradation of organic matter in gas;The steam jet 2-5-6-3 is located at the lower part catalyst jet pipe 2-5-6-2, the two spacing 20cm~40cm, steam jet 2-5-6-3 circular hollow knot Structure, steam jet 2-5-6-3 and external steam supervisor connect, and main steam header is equipped with valve, the lower part cyclic annular steam jet 2-5-6-3 Equipped with lotus spray-head, the two is communicated, and lotus spray-head sprays high-temperature steam, and high-temperature steam promotes catalyst to react with organic matter;Institute It states organic matter adsorbent material 2-5-6-4 and is located at the lower part steam jet 2-5-6-3, the two spacing 20cm~40cm, organic matter absorption The cellular porous reticular structure of material 2-5-6-4, organic matter adsorbent material 2-5-6-4 are that multilayer is laid out, interlamellar spacing 2cm~4cm, Organic matter adsorbent material 2-5-6-4 adsorbs organic matter in exhaust gas;The collection air column partition 2-5-6-6 is located in collection air column 2-5-6 Portion and bottom, quantity be 2, collect air column partition 2-5-6-6 stainless steel material, surface be equipped with a large amount of through-hole, collection air column every The side plate 2-5-6-6 is equipped with water discharge spout 2-5-6-5, for condensed water, excessive catalyst to be collected reprocessing;The collection air column The bottom 2-5-6 is equipped with air inlet 2-5-6-7, and exhaust gas enters from there;Collect and be equipped with detection hole 2-5-6-8 in the middle part of air column 2-5-6, uses In overhaul of the equipments.
Further, the partition 2-5-3 is formed by high molecular material pressing mold, the constituent and manufacture of partition 2-5-3 Process is as follows:
One, partition 2-5-3 constituent:
According to parts by weight, 19~89 parts of benzoic acid of 4- (3- formoxyl -1H- indoles -5- base), 4- (2- (amino methyl) -4- nitre Base phenyl) 129~206 parts of piperazine -1- carboxylic acid tert-butyl ester, 2- cyano -2- (1,2- dihydro -2- Yang Dai quinoxaline -3- base) acetic acid 67~147 parts of ethyl ester, 140~180 parts of methyl acetate of 2- [4- (2- acetyl bromide) -3- methylphenoxy], 3- (5- formoxyl Furans -2- base) 78~176 parts of -4- methyl benzoic acid, [2- [2- (2,5- dihydro -2,5- dioxo -1H- pyrroles -1- base) ethoxy Base] ethyl] carbamic acid 1,221~296 parts of 1- dimethylethyl esters, concentration is 5- [(the chloro- 1H- pyrrole of 4- of 57ppm~87ppm Azoles -1- base) methyl] 155~243 parts of -2- formic acid, 37~80 parts of propionic acid of 3- (1,3,5- trimethyl -1H- pyrazoles -4- base), N- [2- [4- [(methyl sulphonyl) amino] phenyl] ethyl] carbamic acid 1,127~188 parts of 1- dimethylethyl esters, crosslinking agent 129 ~196 parts, 221~334 parts of carboxylate methyl ester of -1H- pyrazoles -5- of -4- nitro of 1- ((ethoxy carbonyl) methyl), 3- (5- acetyl Base -2- thiophene) 218~281 parts of methyl benzoate, 2- (n- methyl-1 H- pyrazoles -1- carboxylic acid amides) ethyl methylcarbamic acid uncle 87~169 parts of butyl ester;
The crosslinking agent is 4- (4- hydroxyphenoxy) ethyl butyrate, 3,4- dihydroxypiperdine -1- benzyl carboxylate, 2- (3- amyl) Any one in dimethyl malenate;
Two, the manufacturing process of partition 2-5-3, comprises the steps of:
Step 1:2755~3655 parts of ultrapure water that conductivity is 5.33 μ of μ S/cm~8.23 S/cm, starting are added in a kettle Blender in reaction kettle, revolving speed are 76rpm~131rpm, start heat pump, reactor temperature is made to rise to 77 DEG C~129 ℃;Sequentially add 4- (3- formoxyl -1H- indoles -5- base) benzoic acid, 4- (2- (amino methyl) -4- nitrobenzophenone) piperazine - 1- carboxylic acid tert-butyl ester, 2- cyano -2- (1,2- dihydro -2- Yang Dai quinoxaline -3- base) ethyl acetate, stir and adjust pH value and be 5.8~7.7, agitator speed is adjusted to 141rpm~233rpm, temperature is 115 DEG C~169 DEG C, and chemical reaction 21~33 is small When;
Step 2:Take 2- [4- (2- acetyl bromide) -3- methylphenoxy] methyl acetate, 3- (5- formylfuran -2- base) -4- Methyl benzoic acid is crushed, and powder diameter is 1050~1250 mesh;[2- [2- (2,5- dihydro -2,5- dioxo -1H- is added Pyrroles -1- base) ethyoxyl] ethyl] carbamic acid 1,1- dimethylethyl esters be uniformly mixed, be laid in pallet, tiling with a thickness of 29mm~45mm uses the alpha ray irradiation 135~225 that dosage is 6.9MeV~9.1MeV for 8.9kGy~12.8kGy, energy Minute and the same dose of β x ray irradiation xs 135~225 minutes;
Step 3:The mixed-powder handled through step 2 is added in 5- [(the chloro- 1H- pyrazol-1-yl of 4-) methyl] -2- formic acid, is added Enter reaction kettle, agitator speed is 137rpm~182rpm, and temperature is 132 DEG C~201 DEG C, and booster air pump makes the pressure of reaction kettle Reach 1.03MPa~2.27MPa, keeps this state response 15~27 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure 1.14MPa~1.81MPa, heat preservation stand 17~25 hours;Agitator speed is promoted to 221rpm~269rpm, simultaneous reactions kettle Pressure release is to 0MPa;Sequentially add 3- (1,3,5- trimethyl -1H- pyrazoles -4- base) propionic acid, N- [2- [4- [(methyl sulphonyl) ammonia Base] phenyl] ethyl] carbamic acid 1, after 1- dimethylethyl esters are completely dissolved, crosslinking agent is added and is stirred, heat preservation stands 19 ~29 hours;
Step 4:When agitator speed is 233rpm~298rpm, 1- ((ethoxy carbonyl) methyl) -4- nitro-is sequentially added 1H- pyrazoles -5- carboxylate methyl ester, 3- (5- acetyl group -2- thiophene) methyl benzoate and 2- (n- methyl-1 H- pyrazoles -1- carboxylic acyl Amine) the ethyl methylcarbamic acid tert-butyl ester, reactor pressure is promoted, 2.60MPa~4.1MPa is reached, temperature is 188 DEG C ~253 DEG C, polymerization reaction 25~35 hours;Reacting kettle inner pressure is down to 0MPa after the reaction was completed, is cooled to 29 DEG C~33 DEG C, Discharging, entering molding press can be prepared by partition 2-5-3.
A kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation of the present invention, the plant automation Degree is high, stable and reliable operation, convenient later maintenance;The device treatment effeciency is high, reduces labor intensity, while to dirt The exhaust gas generated in water treatment procedure carries out concentration purification filtering, avoids the pollution to air.
Detailed description of the invention
Fig. 1 is that a kind of heretofore described agricultural organic waste comprehensive utilization device structure for camplotheca acuminata plantation is shown It is intended to.
Fig. 2 is heretofore described chemicals dosing plant 21-14 structural schematic diagram.
Fig. 3 is heretofore described 22 structural schematic diagram of organic waste pressurizing unit.
Fig. 4 is heretofore described water of compaction after-treatment system structural schematic diagram.
Fig. 5 is heretofore described 1 structural schematic diagram of cesspool.
Fig. 6 is heretofore described promotion column precipitator 1-4 structural schematic diagram.
Fig. 7 is heretofore described 2 structural schematic diagram of reaction tower.
Fig. 8 is heretofore described emission-control equipment 2-2 structural schematic diagram.
Fig. 9 is heretofore described reaction chamber 2-5 structural schematic diagram.
Figure 10 is heretofore described collection air column 2-5-6 schematic diagram.
Figure 11 is that heretofore described partition 2-5-3 fatigue strength changes over time figure.
Specific embodiment
It is comprehensive to a kind of agricultural organic waste for camplotheca acuminata plantation provided by the invention with reference to the accompanying drawings and examples Conjunction is further described using device.
As shown in Figure 1, being a kind of heretofore described agricultural organic waste comprehensive utilization dress for camplotheca acuminata plantation Set structural schematic diagram.As seen from the figure, including:Discharge port 21-1, auger 21-2, separating sieve 21-3 crush motor 21-4, charging Struggle against 21-5, pulverization roller 21-6, dust removing tube 21-7, dispersion plate 21-8, blanking tube 21-9, horizontal push plate 21-10, push plate crankshaft 21- 11, blanking amount controller 21-12, blanking slideway 21-13, chemicals dosing plant 21-14, mixing chamber 21-15 can not fragmenting bulk outlets 21-16, the outer comb 21-17 of water of compaction;
Feed hopper 21-5 positioned at top is passed through with blanking tube 21-9, blanking slideway 21-13, mixing chamber 21-15, discharge port 21-1 Logical, the lower part feed hopper 21-5 is equipped with pulverization roller 21-6, and pulverization roller 21-6 quantity is 2, arranged opposite, 2 pulverization roller 21-6 with Outside crushes motor 21-4 mechanical connection;The lower part pulverization roller 21-6 is equipped with dispersion plate 21-8, is equipped with level in the middle part of dispersion plate 21-8 Axis, dispersion plate 21-8 swing along trunnion axis, and the surface dispersion plate 21-8 is equipped with a large amount of through-holes;The lower part dispersion plate 21-8, which is equipped with, to be divided It is equipped with horizontal push plate 21-10 on the left of choosing sieve 21-3, separating sieve 21-3, horizontal push plate 21-10 passes through push plate crankshaft 21-11 and motor Connection;Being equipped on the right side of separating sieve 21-3 can not fragmenting bulk outlet 21-16;The lower part separating sieve 21-3 is equipped with blanking amount controller 21-12;Blanking amount controller 21-12 is horizontal push-pull configuration, and blanking amount controller 21-12 controls blanking velocity;Discharge quantity control The lower part device 21-12 processed is equipped with blanking slideway 21-13, and the lower part blanking slideway 21-13 is equipped with mixing chamber 21-15, mixing chamber 21-15 It is connected to chemicals dosing plant 21-14;The lower part mixing chamber 21-15 is equipped with auger 21-2, and the lower part of the auger 21-2 other end is equipped with discharging Mouth 21-1;The outer comb 21-17 of water of compaction is located at auger 21-2 bottom side;
The outer comb 21-17 of water of compaction is connected to cesspool 1.
As shown in Fig. 2, being heretofore described chemicals dosing plant 21-14 structural schematic diagram.As seen from the figure, chemicals dosing plant 21-14 includes:Drug-feeding tube 21-14-1, peep hole 21-14-2, drug discharging tube 21-14-3, DC electric field cathode 21-14-4, stirring Axis 21-14-5, DC electric field anode 21-14-6;
The chemicals dosing plant 21-14 housings close structure, the agitating shaft 21-14-5 in portion disposed thereon pass through gear and external electrical Machine connection, the lower part agitating shaft 21-14-5 are equipped with impeller;It is equipped with drug-feeding tube 21-14-1 in chemicals dosing plant 21-14 shell side, into The top pencil 21-14-1 is equipped with DC electric field anode 21-14-6, and DC electric field anode 21-14-6 is inserted into chemicals dosing plant 21-14 Enclosure interior;It is equipped with drug discharging tube 21-14-3 in the chemicals dosing plant 21-14 shell other side, the top drug discharging tube 21-14-3 is equipped with direct current Electric field cathode 21-14-4, DC electric field cathode 21-14-4 are inserted into chemicals dosing plant 21-14 enclosure interior;DC electric field cathode 21- 14-4 is connect with outside DC electric field anode 21-14-6 with DC power supply;Peep hole is equipped in chemicals dosing plant 21-14 shell side 21-14-2。
As shown in figure 3, being heretofore described 22 structural schematic diagram of organic waste pressurizing unit.As seen from the figure, Organic waste pressurizing unit 22 includes:Extruder loading hopper 22-1 squeezes capstan winch 22-2, counter-force pallet 22-3, expressed water Comb 22-4, sluicing pipe 22-5, squeeze water collecting tank 22-6, counter-force supporting plate 22-7, organic waste discharge outlet 22-8, and lower part is squeezed Press water comb 22-9, capstan winch motor 22-10;
Extruder loading hopper 22-1 positioned at top, its underpart are equipped with counter-force pallet 22-3, counter-force pallet 22-3 concave, center Hatch frame, counter-force pallet 22-3 quantity are 2;The counter-force side pallet 22-3 is equipped with expressed water comb 22-4;Expressed water comb 22-4 is connected to the extruding water collecting tank 22-6 of lower part, is squeezed water collecting tank 22-6 and is connected to lower compression water comb 22-9;Instead It is equipped at power pallet 22-3 king and squeezes capstan winch 22-2, run through 2 counter-force pallet 22-3 up and down, squeeze capstan winch 22-2 It is mechanically connected with external capstan winch motor 22-10;Squeeze the bottom capstan winch 22-2 be equipped with counter-force supporting plate 22-7, be inclined design, Rectangle, surface are equipped with a large amount of through-holes, and the counter-force side supporting plate 22-7 is equipped with organic waste discharge outlet 22-8;Counter-force supporting plate 22- 7 bottoms are equipped with lower compression water comb 22-9;Sluicing pipe 22-5 is equipped on the extruder top loading hopper 22-1;
Lower compression water comb 22-9 is connected to cesspool 1.
As shown in figure 4, being heretofore described water of compaction after-treatment system structural schematic diagram.As seen from the figure, including: Cesspool 1, reaction tower 2, anaerobic pond 3, drainage tube 4, grid 5, filler 6, aerobic tank 7, air blower 8, including:Cesspool 1, instead Answer tower 2, anaerobic pond 3, drainage tube 4, grid 5, filler 6, aerobic tank 7, air blower 8, blender 9, control cabinet 10;
2 side of reaction tower is equipped with cesspool 1, and the other side is equipped with anaerobic pond 3, cesspool 1 and anaerobic pond 3 by pipeline with Reaction tower 2 connects;The control cabinet 10 is located at 2 front side of reaction tower;The 3 top both ends of anaerobic pond are equipped with blender 9, blender 9 altogether there are two, blender 9 is controlled by conducting wire and control cabinet 10 to be connected;3 side of anaerobic pond is equipped with drainage tube 4, drainage tube 4 quantity are not less than 12, and wherein 4 one end of drainage tube and anaerobic pond 3 penetrate through, and the other end and aerobic tank 7 penetrate through;The air blower 8 Positioned at 7 bottom both ends of aerobic tank, 8 quantity of air blower is two, and air blower 8 and aerobic tank 7 penetrate through;It is set inside the aerobic tank 7 There is filler 6;The grid 5 is located at 7 inner tip of aerobic tank, and grid 5 is fixedly connected with aerobic tank 7.
As shown in figure 5, being heretofore described 1 structural schematic diagram of cesspool.As seen from the figure, cesspool 1 includes:It is dirty Mud delivery pipe 1-1, COD detector 1-2, bilge discharge pipe 1-3 promote column precipitator 1-4, wave agitation plate 1-5, buffer subsystem 1-6, System 1-7, sewage inlet pipe 1-8 is added in polyaluminium sulfate;
Sewage inlet pipe 1-8 positioned at top, its underpart are equipped with polyaluminium sulfate and system 1-7 are added, and wherein polyaluminium sulfate adds Entering system 1-7 includes water pump, ring pipe, shower nozzle, and the quantity of ring pipe is 3, and ring pipe lower part is equipped with a large amount of spray heads, ring Shape pipe is connected to spray head;The lower part system 1-7 is added in polyaluminium sulfate and is equipped with buffer subsystem 1-6, buffer subsystem 1-6 multilayer, screen distance 2cm~4cm;The lower part buffer subsystem 1-6 is equipped with wave agitation plate 1-5, and the wave agitation section plate 1-5 is W type, and quantity is 20, point Two groups, wave agitation plate 1-5 spacing 20cm~40cm, all wave agitation plate 1-5 are connect with external crankshaft, and external motor drives Wave agitation plate 1-5 low speed horizontal pan inside crankshaft promotion;The wave agitation lower part plate 1-5 be equipped with promote column precipitator 1-4, Quantity is 15, is vertically arranged;Bilge discharge pipe 1-3 is equipped in the lower part column precipitator 1-4;It is arranged in 1 bottom of cesspool equipped with sludge Put pipe 1-1;The cesspool 1 is located inside water of compaction after-treatment system.
As shown in fig. 6, being heretofore described promotion column precipitator 1-4 structural schematic diagram.As seen from the figure, promote precipitating Column 1-4 includes:Microwave susceptor 1-4-1, electromagnetic coil 1-4-2, inductance 1-4-3, capacitor 1-4-4 reflect convex lens 1-4-5, stream Aquaporin 1-4-6, microwave tube 1-4-7, microwave tube protective cover 1-4-8;Microwave tube protective cover is equipped on the top microwave susceptor 1-4-1 1-4-8 is waterproof construction, is equipped with inside microwave tube protective cover 1-4-8, electromagnetic coil 1-4-2, inductance 1-4-3, capacitor 1- 4-4, convex lens 1-4-5, microwave tube 1-4-7 are reflected, wherein electromagnetic coil 1-4-2, inductance 1-4-3, capacitor 1-4-4, microwave tube The mutual conducting wire connection of 1-4-7;It is equipped with reflection convex lens 1-4-5 in the lower part microwave tube 1-4-7, reflects convex lens 1-4-5 stainless steel mirror Material;Promote column precipitator 1-4 up and down;The pipelined channel 1-4-6, which is located at, promotes column precipitator 1-4 shell and microwave protection of pipe It covers between 1-4-8.
As shown in fig. 7, being heretofore described 2 structural schematic diagram of reaction tower.As seen from the figure, the reaction tower 2 wraps It includes:Aspiration pump 2-1, emission-control equipment 2-2, sewage pump 2-3, sewage pipe 2-4, reaction chamber 2-5, tracheae 2-6, outlet pipe 2-7, Exhaust pipe 2-8;
The reaction chamber 2-5 bottom side be equipped with emission-control equipment 2-2 and sewage pump 2-3, wherein emission-control equipment 2-2 and It is penetrated through between reaction chamber 2-5 by tracheae 2-6;Sewage pipe 2-4 is equipped on the sewage pump 2-3, sewage pipe 2-4 shape is to stand upside down U-typed;The side the emission-control equipment 2-2 is equipped with aspiration pump 2-1, and aspiration pump 2-1 passes through pipeline and emission-control equipment 2- 2 perforations, are wherein equipped with exhaust pipe 2-8 on aspiration pump 2-1;The top reaction chamber 2-5 side is equipped with outlet pipe 2-7, outlet pipe 2-7 and reaction chamber 2-5 is penetrated through;The aspiration pump 2-1 and sewage pump 2-3 passes through conducting wire and is connected with the control of control cabinet 10.
As shown in figure 8, being heretofore described emission-control equipment 2-2 structural schematic diagram.As seen from the figure, at exhaust gas Managing device 2-2 includes:Exhaust inlet pipe 2-2-1 washs sparge pipe 2-2-2, purified gas outlet pipe 2-2-3, adsorbent equipment 2-2-4, Washing water outlet pipe 2-2-5;Emission-control equipment 2-2 enclosed construction;Purified gas outlet pipe 2-2-3 positioned at top, its underpart is equipped with Sparge pipe 2-2-2 is washed, is provided with a large amount of through-holes for ring structure, its underpart;It washs the lower part sparge pipe 2-2-2 and is equipped with absorption dress Set 2-2-4, adsorbent equipment 2-2-4 honeycomb structure;The lower part adsorbent equipment 2-2-4 is equipped with exhaust inlet pipe 2-2-1, gas inlet The upper end pipe 2-2-1 is equipped with umbrella gas outlet;The bottom emission-control equipment 2-2 is equipped with washing water outlet pipe 2-2-5;The exhaust-gas treatment Device 2-2 is located inside reaction tower 2.
As shown in figure 9, being heretofore described reaction chamber 2-5 structural schematic diagram.As seen from the figure, the reaction chamber 2-5 includes:Isocon 2-5-1, spray head 2-5-2, partition 2-5-3, water outlet 2-5-4, gas chamber 2-5-5 collect air column 2-5-6;Institute It states reaction chamber 2-5 inner bottom and is equipped with isocon 2-5-1, be equipped with spray head 2-5-2 on isocon 2-5-1, spray head 2-5-2 quantity is 6;The reaction chamber 2-5 inner tip is equipped with gas chamber 2-5-5, and wherein the bottom end gas chamber 2-5-5 is equipped with collection air column 2-5-6, gas collection Column 2-5-6 quantity is not less than 10, and collection air column 2-5-6 and gas chamber 2-5-5 are penetrated through;Running through on the collection air column 2-5-6 has partition 2-5-3, partition 2-5-3 mono- are divided into two layers, are fixedly connected inside partition 2-5-3 and reaction chamber 2-5;The water outlet 2-5-4 Positioned at reaction chamber 2-5 top side, water outlet 2-5-4 is welded and fixed with outlet pipe 2-7.
It as shown in Figure 10, is heretofore described collection air column 2-5-6 structural schematic diagram.As seen from the figure, the gas collection Column 2-5-6 includes:Gas outlet 2-5-6-1, catalyst jet pipe 2-5-6-2, steam jet 2-5-6-3, organic matter adsorbent material 2- 5-6-4, water discharge spout 2-5-6-5 collect air column partition 2-5-6-6, air inlet 2-5-6-7, detection hole 2-5-6-8;
Positioned at the gas outlet 2-5-6-1 on top, uncovered structure, treated, and gas is discharged from gas outlet 2-5-6-1;The catalysis Agent jet pipe 2-5-6-2 is located at the gas outlet lower part 2-5-6-1, the two spacing 20cm~40cm, and the top catalyst jet pipe 2-5-6-2 is set There is valve, valve and supervisor connect, and supervisor lower part connects multiple branch pipes, and the quantity of branch pipe is 2~8, and the end of branch pipe is equipped with Spray head, spray head spray into catalyst in collection air column 2-5-6, and catalyst promotes the degradation of organic matter in gas;The steam jet 2-5-6-3 is located at the lower part catalyst jet pipe 2-5-6-2, the two spacing 20cm~40cm, steam jet 2-5-6-3 circular hollow knot Structure, steam jet 2-5-6-3 and external steam supervisor connect, and main steam header is equipped with valve, the lower part cyclic annular steam jet 2-5-6-3 Equipped with lotus spray-head, the two is communicated, and lotus spray-head sprays high-temperature steam, and high-temperature steam promotes catalyst to react with organic matter;Institute It states organic matter adsorbent material 2-5-6-4 and is located at the lower part steam jet 2-5-6-3, the two spacing 20cm~40cm, organic matter absorption The cellular porous reticular structure of material 2-5-6-4, organic matter adsorbent material 2-5-6-4 are that multilayer is laid out, interlamellar spacing 2cm~4cm, Organic matter adsorbent material 2-5-6-4 adsorbs organic matter in exhaust gas;The collection air column partition 2-5-6-6 is located in collection air column 2-5-6 Portion and bottom, quantity be 2, collect air column partition 2-5-6-6 stainless steel material, surface be equipped with a large amount of through-hole, collection air column every The side plate 2-5-6-6 is equipped with water discharge spout 2-5-6-5, for condensed water, excessive catalyst to be collected reprocessing;The collection air column The bottom 2-5-6 is equipped with air inlet 2-5-6-7, and exhaust gas enters from there;Collect and be equipped with detection hole 2-5-6-8 in the middle part of air column 2-5-6, uses In overhaul of the equipments.
Following embodiment further illustrates the contents of the present invention, and as partition 2-5-3, it is significant components of the invention, Due to its presence, the service life of integral device is increased, it plays crucial work for the safety of integral device, even running With.For this purpose, by it is following be embodiment, further verify partition 2-5-3 of the present invention, shown be higher than other phases Close the physical characteristic of patent.
Embodiment 1
Partition 2-5-3 of the present invention is manufactured according to the following steps, and according to parts by weight:
Step 1:2755 parts of ultrapure water that conductivity is 5.33 μ S/cm are added in a kettle, start blender in reaction kettle, turn Speed is 76rpm, starts heat pump, reactor temperature is made to rise to 77 DEG C;Sequentially add 4- (3- formoxyl -1H- indoles -5- Base) 19 parts of benzoic acid, 4- (2- (amino methyl) -4- nitrobenzophenone) 129 parts of piperazine -1- carboxylic acid tert-butyl ester, 2- cyano -2- (1, 2- dihydro -2- Yang Dai quinoxaline -3- base) 67 parts of ethyl acetate, stirring and adjusting pH value is 5.8, and agitator speed is adjusted to 141 rpm, temperature are 115 DEG C, are chemically reacted 21 hours;
Step 2:Take 2- [4- (2- acetyl bromide) -3- methylphenoxy] 140 parts of methyl acetate, 3- (5- formylfuran -2- Base) 78 parts of -4- methyl benzoic acid crushed, powder diameter be 1050 mesh;[2- [2- (2,5- dihydro -2,5- dioxo-is added 1H- pyrroles -1- base) ethyoxyl] ethyl] carbamic acid 1,221 parts of 1- dimethylethyl esters are uniformly mixed, and are laid in pallet, put down With a thickness of 29mm, the alpha ray for using dosage to be 6.9MeV for 8.9kGy, energy irradiates 135 minutes and the same dose of β paving X ray irradiation x 135 minutes;
Step 3:The mixed-powder handled through step 2 is dissolved in the 5- [(the chloro- 1H- pyrazol-1-yl of 4-) methyl]-that concentration is 57ppm In 155 parts of 2- formic acid, reaction kettle, agitator speed 137rpm is added, temperature is 132 DEG C, and starting vacuum pump makes reaction kettle Vacuum degree reaches -1.03MPa, keeps this state response 15 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure 1.14 MPa, heat preservation stand 17 hours;Agitator speed is promoted to 221rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3- (1, 3,5- trimethyl -1H- pyrazoles -4- base) 37 parts of propionic acid, N- [2- [4- [(methyl sulphonyl) amino] phenyl] ethyl] carbamic acid After 1,1- 127 parts of dimethylethyl esters are completely dissolved, it is added 129 parts of crosslinking agent and is stirred, so that the hydrophilic parent of reaction kettle solution Oily equilibrium valve is 6.1, and heat preservation stands 19 hours;
Step 4:When agitator speed is 233rpm, 1- ((ethoxy carbonyl) methyl) -4- nitro -1H- pyrazoles-is sequentially added 221 parts of 5- carboxylate methyl ester, 218 parts of 3- (5- acetyl group -2- thiophene) methyl benzoate and 2- (n- methyl-1 H- pyrazoles -1- carboxylic acyl Amine) 87 parts of the ethyl methylcarbamic acid tert-butyl ester, reactor pressure is promoted, 2.60MPa is reached, temperature is 188 DEG C, polymerization Reaction 25 hours;Reacting kettle inner pressure is down to 0MPa after the reaction was completed, is cooled to 29 DEG C, discharging, entering molding press can be prepared by Partition 2-5-3.
The crosslinking agent is 4- (4- hydroxyphenoxy) ethyl butyrate.
Embodiment 2
Partition 2-5-3 of the present invention is manufactured according to the following steps, and according to parts by weight:
Step 1:3205 parts of ultrapure water that conductivity is 6.78 μ S/cm are added in a kettle, start blender in reaction kettle, turn Speed is 103rpm, starts heat pump, reactor temperature is made to rise to 103 DEG C;Sequentially add 4- (3- formoxyl -1H- indoles - 5- yl) 54 parts of benzoic acid, 4- (2- (amino methyl) -4- nitrobenzophenone) 164 parts of piperazine -1- carboxylic acid tert-butyl ester, 2- cyano -2- 107 parts of ethyl acetate of (1,2- dihydro -2- Yang Dai quinoxaline -3- base), stirring and adjusting pH value is 6.8, by agitator speed tune To 187rpm, temperature is 141 DEG C, is chemically reacted 28 hours;
Step 2:Take 2- [4- (2- acetyl bromide) -3- methylphenoxy] 159 parts of methyl acetate, 3- (5- formylfuran -2- Base) 127 parts of -4- methyl benzoic acid crushed, powder diameter be 1150 mesh;[2- [2- (2,5- dihydro -2,5- dioxy is added Generation -1H- pyrroles -1- base) ethyoxyl] ethyl] carbamic acid 1,258 parts of 1- dimethylethyl esters are uniformly mixed, and are laid in pallet Interior, with a thickness of 37mm, the alpha ray for using dosage to be 8.0MeV for 10.9kGy, energy irradiates 180 minutes and same agent for tiling The β x ray irradiation x of amount 180 minutes;
Step 3:The mixed-powder handled through step 2 is dissolved in the 5- [(the chloro- 1H- pyrazol-1-yl of 4-) methyl]-that concentration is 72ppm In 199 parts of 2- formic acid, reaction kettle, agitator speed 158rpm is added, temperature is 167 DEG C, and starting vacuum pump makes reaction kettle Vacuum degree reaches 0.80MPa, keeps this state response 21 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure 1.47 MPa, heat preservation stand 21 hours;Agitator speed is promoted to 237rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3- (1, 3,5- trimethyl -1H- pyrazoles -4- base) 58 parts of propionic acid, N- [2- [4- [(methyl sulphonyl) amino] phenyl] ethyl] carbamic acid After 1,1- 157 parts of dimethylethyl esters are completely dissolved, it is added 161 parts of crosslinking agent and is stirred, so that the hydrophilic parent of reaction kettle solution Oily equilibrium valve is 8.0, and heat preservation stands 24 hours;
Step 4:When agitator speed is 265rpm, 1- ((ethoxy carbonyl) methyl) -4- nitro -1H- pyrazoles-is sequentially added 277 parts of 5- carboxylate methyl ester, 249 parts of 3- (5- acetyl group -2- thiophene) methyl benzoate and 2- (n- methyl-1 H- pyrazoles -1- carboxylic acyl Amine) 128 parts of the ethyl methylcarbamic acid tert-butyl ester, reactor pressure is promoted, 3.53MPa is reached, temperature is 220 DEG C, is gathered Close reaction 30 hours;Reacting kettle inner pressure is down to 0MPa after the reaction was completed, is cooled to 31 DEG C, discharging, entering molding press can make Obtain partition 2-5-3.
The crosslinking agent is 3,4- dihydroxypiperdine -1- benzyl carboxylate.
Embodiment 3
Partition 2-5-3 of the present invention is manufactured according to the following steps, and according to parts by weight:
Step 1:3655 parts of ultrapure water that conductivity is 8.23 μ S/cm are added in a kettle, start blender in reaction kettle, turn Speed is 131rpm, starts heat pump, reactor temperature is made to rise to 129 DEG C;Sequentially add 4- (3- formoxyl -1H- indoles - 5- yl) 89 parts of benzoic acid, 4- (2- (amino methyl) -4- nitrobenzophenone) 206 parts of piperazine -1- carboxylic acid tert-butyl ester, 2- cyano -2- 147 parts of ethyl acetate of (1,2- dihydro -2- Yang Dai quinoxaline -3- base), stirring and adjusting pH value is 7.7, by agitator speed tune To 233rpm, temperature is 169 DEG C, is chemically reacted 33 hours;
Step 2:Take 2- [4- (2- acetyl bromide) -3- methylphenoxy] 180 parts of methyl acetate, 3- (5- formylfuran -2- Base) 176 parts of -4- methyl benzoic acid crushed, powder diameter be 1241 mesh;[2- [2- (2,5- dihydro -2,5- dioxy is added Generation -1H- pyrroles -1- base) ethyoxyl] ethyl] carbamic acid 1,296 parts of 1- dimethylethyl esters are uniformly mixed, and are laid in pallet Interior, with a thickness of 45mm, the alpha ray for using dosage to be 9.1MeV for 12.8kGy, energy irradiates 225 minutes and same agent for tiling The β x ray irradiation x of amount 225 minutes;
Step 3:The mixed-powder handled through step 2 is dissolved in the 5- [(the chloro- 1H- pyrazol-1-yl of 4-) methyl]-that concentration is 87ppm In 243 parts of 2- formic acid, reaction kettle, agitator speed 182rpm is added, temperature is 201 DEG C, and starting vacuum pump makes reaction kettle Vacuum degree reaches 1.90MPa, keeps this state response 27 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure 1.81 MPa, heat preservation stand 25 hours;Agitator speed is promoted to 269rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3- (1, 3,5- trimethyl -1H- pyrazoles -4- base) 80 parts of propionic acid, N- [2- [4- [(methyl sulphonyl) amino] phenyl] ethyl] carbamic acid After 1,1- 188 parts of dimethylethyl esters are completely dissolved, it is added 196 parts of crosslinking agent and is stirred, so that the hydrophilic parent of reaction kettle solution Oily equilibrium valve is 9.8, and heat preservation stands 28 hours;
Step 4:When agitator speed is 297rpm, 1- ((ethoxy carbonyl) methyl) -4- nitro -1H- pyrazoles-is sequentially added 334 parts of 5- carboxylate methyl ester, 281 parts of 3- (5- acetyl group -2- thiophene) methyl benzoate and 2- (n- methyl-1 H- pyrazoles -1- carboxylic acyl Amine) 169 parts of the ethyl methylcarbamic acid tert-butyl ester, reactor pressure is promoted, 4.1MPa is reached, temperature is 253 DEG C, polymerization Reaction 35 hours;Reacting kettle inner pressure is down to 0MPa after the reaction was completed, is cooled to 33 DEG C, discharging, entering molding press can be prepared by Partition 2-5-3.
The crosslinking agent is 2- (3- amyl) dimethyl malenate.
Reference examples
Reference examples are certain commercially available brand component same as the application partition 2-5-3, are tested for the property test.
Embodiment 4
The partition 2-5-3 and reference examples that Examples 1 to 3 is prepared same component obtained carry out using effect comparison. The two heat distortion temperature, compression strength, Air permenbility, corrosion rate are counted, the results are shown in Table 1.
As seen from Table 1, partition 2-5-3 of the present invention, heat distortion temperature, compression strength, Air permenbility, corrosion rate Etc. indexs be superior to the prior art production product.
In addition, finding out from the statistical chart that heretofore described partition 2-5-3 fatigue strength changes over time, embodiment Partition 2-5-3 used in 1~3, fatigue of materials intensity are substantially better than existing product with using time change degree.

Claims (10)

1. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation, which is characterized in that promote column precipitator (1-4) Including:Microwave susceptor (1-4-1), electromagnetic coil (1-4-2), inductance (1-4-3), capacitor (1-4-4) reflect convex lens (1-4- 5), pipelined channel (1-4-6), microwave tube (1-4-7), microwave tube protective cover (1-4-8);
It is equipped with microwave tube protective cover (1-4-8) on the microwave susceptor top (1-4-1), is waterproof construction, microwave tube protective cover (1- It is 4-8) internal to be equipped with, electromagnetic coil (1-4-2), inductance (1-4-3), capacitor (1-4-4), reflection convex lens (1-4-5), microwave tube (1-4-7), wherein electromagnetic coil (1-4-2), inductance (1-4-3), capacitor (1-4-4), microwave tube (1-4-7) mutually conducting wire connect It connects;It is equipped with reflection convex lens (1-4-5) in the microwave tube lower part (1-4-7), reflects convex lens (1-4-5) stainless steel mirror material;Promote Column precipitator (1-4) is up and down;The pipelined channel (1-4-6), which is located at, promotes column precipitator (1-4) shell and microwave tube protective cover Between (1-4-8);
The promotion column precipitator (1-4) is internal in cesspool (1).
2. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 1, including:Out Material mouth (21-1), auger (21-2), separating sieve (21-3) crush motor (21-4), feed hopper (21-5), pulverization roller (21-6), Dust removing tube (21-7), dispersion plate (21-8), blanking tube (21-9), horizontal push plate (21-10), push plate crankshaft (21-11), discharge quantity Controller (21-12), blanking slideway (21-13), chemicals dosing plant (21-14), mixing chamber (21-15) can not fragmenting bulk outlet (21-16), the outer comb (21-17) of water of compaction;It is characterized in that,
Feed hopper (21-5) positioned at top, with blanking tube (21-9), blanking slideway (21-13), mixing chamber (21-15), discharging Mouthful (21-1) perforation, the feed hopper lower part (21-5) are equipped with pulverization roller (21-6), and pulverization roller (21-6) quantity is 2, arranged opposite, 2 pulverization rollers (21-6) and external crush motor (21-4) are mechanically connected;The pulverization roller lower part (21-6) is equipped with dispersion plate (21-8), Trunnion axis is equipped in the middle part of dispersion plate (21-8), dispersion plate (21-8) swings along trunnion axis, and the surface dispersion plate (21-8) is equipped with A large amount of through-holes;The dispersion plate lower part (21-8) is equipped with separating sieve (21-3), and horizontal push plate (21- is equipped on the left of separating sieve (21-3) 10), horizontal push plate (21-10) is connected to motor by push plate crankshaft (21-11);Being equipped on the right side of separating sieve (21-3) can not crush Bulk exports (21-16);The separating sieve lower part (21-3) is equipped with blanking amount controller (21-12);Blanking amount controller (21-12) is Horizontal push-pull configuration, blanking amount controller (21-12) control blanking velocity;The blanking amount controller lower part (21-12) is equipped with blanking Slideway (21-13), the blanking slideway lower part (21-13) are equipped with mixing chamber (21-15), mixing chamber (21-15) and chemicals dosing plant (21- 14) it is connected to;The mixing chamber lower part (21-15) is equipped with auger (21-2), and the lower part of auger (21-2) other end is equipped with discharge port (21- 1);The outer comb (21-17) of water of compaction is located at auger (21-2) bottom side;
The outer comb (21-17) of water of compaction is connected to cesspool (1);
Discharge port (21-1) is connected to organic waste pressurizing unit (22).
3. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 2, feature It is, chemicals dosing plant (21-14) includes:Drug-feeding tube (21-14-1), peep hole (21-14-2), drug discharging tube (21-14-3), direct current Electric field cathode (21-14-4), agitating shaft (21-14-5), DC electric field anode (21-14-6);
Chemicals dosing plant (21-14) the housings close structure, the agitating shaft (21-14-5) in portion disposed thereon, by gear and outside The connection of portion's motor, the agitating shaft lower part (21-14-5) are equipped with impeller;Drug-feeding tube is equipped in chemicals dosing plant (21-14) shell side (21-14-1), the drug-feeding tube top (21-14-1) are equipped with DC electric field anode (21-14-6), DC electric field anode (21-14-6) It is inserted into chemicals dosing plant (21-14) enclosure interior;It is equipped with drug discharging tube (21-14-3) in chemicals dosing plant (21-14) the shell other side, out The pencil top (21-14-3) is equipped with DC electric field cathode (21-14-4), and DC electric field cathode (21-14-4) is inserted into chemicals dosing plant (21-14) enclosure interior;DC electric field cathode (21-14-4) and the outside DC electric field positive (21-14-6) connect with DC power supply It connects;Peep hole (21-14-2) is equipped in chemicals dosing plant (21-14) shell side;
The chemicals dosing plant (21-14) is in a kind of agricultural organic waste comprehensive utilization device system for camplotheca acuminata plantation Portion.
4. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 3, feature It is, organic waste pressurizing unit (22) includes:Extruder loading hopper (22-1) squeezes capstan winch (22-2), counter-force pallet (22-3), expressed water comb (22-4), sluicing pipe (22-5) squeeze water collecting tank (22-6), counter-force supporting plate (22-7), organic waste Gurry discharge outlet (22-8), lower compression water comb (22-9), capstan winch motor (22-10);
Extruder loading hopper (22-1) positioned at top, its underpart are equipped with counter-force pallet (22-3), and counter-force pallet (22-3) is recessed Type, central opening structure, counter-force pallet (22-3) quantity are 2;The counter-force pallet side (22-3) is equipped with expressed water comb (22- 4);Expressed water comb (22-4) is connected to the extruding water collecting tank (22-6) of lower part, squeezes water collecting tank (22-6) and lower part is squeezed Press water comb (22-9) connection;It is equipped at counter-force pallet (22-3) king and squeezes capstan winch (22-2), run through 2 up and down instead Power pallet (22-3), squeezes capstan winch (22-2) and external capstan winch motor (22-10) is mechanically connected;Squeeze the bottom capstan winch (22-2) It is inclined design, rectangle, surface equipped with a large amount of through-holes, the side counter-force supporting plate (22-7) is set equipped with counter-force supporting plate (22-7) There is organic waste discharge outlet (22-8);The counter-force supporting plate bottom (22-7) is equipped with lower compression water comb (22-9);In extruder The loading hopper top (22-1) is equipped with sluicing pipe (22-5);
The lower compression water comb (22-9) is connected to cesspool (1).
5. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 4, feature It is, water of compaction after-treatment system includes:Cesspool (1), reaction tower (2), anaerobic pond (3), drainage tube (4), grid (5), Filler (6), aerobic tank (7), air blower (8), blender (9), control cabinet (10);
Reaction tower (2) side is equipped with cesspool (1), and the other side is equipped with anaerobic pond (3), and cesspool (1) and anaerobic pond (3) are equal It is connect by pipeline with reaction tower (2);The control cabinet (10) is located on front side of reaction tower (2);Both ends at the top of the anaerobic pond (3) Equipped with blender (9), blender (9) altogether there are two, blender (9), which is controlled by conducting wire with control cabinet (10), to be connected;It is described to detest Oxygen pond (3) side is equipped with drainage tube (4), and drainage tube (4) quantity is not less than 12, wherein drainage tube (4) one end and anaerobic pond (3) Perforation, the other end and aerobic tank (7) penetrate through;The air blower (8) is located at aerobic tank (7) bottom both ends, and air blower (8) quantity is Two, air blower (8) and aerobic tank (7) penetrate through;Filler (6) are equipped with inside the aerobic tank (7);The grid (5) is located at Aerobic tank (7) inner tip, grid (5) are fixedly connected with aerobic tank (7), and aerobic tank (7) side is equipped with outlet pipe;
The cesspool (1) includes:Mud discharging pipe (1-1), COD detector (1-2), bilge discharge pipe (1-3) promote precipitating System (1-7) is added in column (1-4), wave agitation plate (1-5), buffer subsystem (1-6), polyaluminium sulfate, sewage inlet pipe (1-8);
Sewage inlet pipe (1-8) positioned at top, its underpart are equipped with polyaluminium sulfate and system (1-7) are added, wherein polyaluminum sulfate It includes water pump, ring pipe, shower nozzle that system (1-7), which is added, in aluminium, and the quantity of ring pipe is 3, and ring pipe lower part is equipped with a large amount of Spray head, ring pipe are connected to spray head;The system lower part (1-7) is added in polyaluminium sulfate and is equipped with buffer subsystem (1-6), buffer subsystem (1- 6) multilayer, screen distance 2cm~4cm;The buffer subsystem lower part (1-6) is equipped with wave agitation plate (1-5), the section wave agitation plate (1-5) For W type, quantity is 20, be divided to two groups, wave agitation plate (1-5) spacing 20cm~40cm, all wave agitation plates (1-5) with outside The connection of portion's crankshaft, external motor is with wave agitation plate (1-5) low speed horizontal pan inside dynamic crankshaft promotion;In wave agitation plate The lower part (1-5), which is equipped with, promotes column precipitator (1-4), quantity to be 15, be vertically arranged;It is arranged in the column precipitator lower part (1-4) equipped with sewage Outlet pipe (1-3);Mud discharging pipe (1-1) is equipped in cesspool (1) bottom;
The cesspool (1) is located inside water of compaction after-treatment system.
6. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 5, feature It is, the reaction tower (2) includes:Aspiration pump (2-1), emission-control equipment (2-2), sewage pump (2-3), sewage pipe (2-4), Reaction chamber (2-5), tracheae (2-6), outlet pipe (2-7), exhaust pipe (2-8);
Reaction chamber (2-5) bottom side is equipped with emission-control equipment (2-2) and sewage pump (2-3), and wherein exhaust-gas treatment fills It sets and is penetrated through between (2-2) and reaction chamber (2-5) by tracheae (2-6);It is equipped with sewage pipe (2-4) on the sewage pump (2-3), it is dirty Water pipe (2-4) shape is handstand U-typed;The emission-control equipment side (2-2) is equipped with aspiration pump (2-1), aspiration pump (2-1) It is penetrated through by pipeline and emission-control equipment (2-2), is wherein equipped with exhaust pipe (2-8) on aspiration pump (2-1);The reaction chamber The top side (2-5) is equipped with outlet pipe (2-7), and outlet pipe (2-7) and reaction chamber (2-5) are penetrated through;
The aspiration pump (2-1) and sewage pump (2-3) are connected by conducting wire with control cabinet (10) control.
7. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 6, feature It is, emission-control equipment (2-2) includes:Exhaust inlet pipe (2-2-1) washs sparge pipe (2-2-2), purified gas outlet pipe (2- 2-3), adsorbent equipment (2-2-4), washing water outlet pipe (2-2-5);
Emission-control equipment (2-2) enclosed construction;Purified gas outlet pipe (2-2-3) positioned at top, its underpart are equipped with washing water spray It manages (2-2-2), is provided with a large amount of through-holes for ring structure, its underpart;It washs the sparge pipe lower part (2-2-2) and is equipped with adsorbent equipment (2-2-4), adsorbent equipment (2-2-4) honeycomb structure;The adsorbent equipment lower part (2-2-4) is equipped with exhaust inlet pipe (2-2-1), gives up The gas air inlet pipe upper end (2-2-1) is equipped with umbrella gas outlet;The emission-control equipment bottom (2-2) is equipped with washing water outlet pipe (2-2-5);
It is internal that the emission-control equipment (2-2) is located at reaction tower (2).
8. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 7, feature It is, the reaction chamber (2-5) includes:Isocon (2-5-1), spray head (2-5-2), partition (2-5-3), water outlet (2-5-4), Gas chamber (2-5-5) collects air column (2-5-6);
Reaction chamber (2-5) inner bottom is equipped with isocon (2-5-1), is equipped with spray head (2-5-2) on isocon (2-5-1), Spray head (2-5-2) quantity is 6;Reaction chamber (2-5) inner tip is equipped with gas chamber (2-5-5), wherein the bottom gas chamber (2-5-5) End is equipped with collection air column (2-5-6), and collection air column (2-5-6) quantity is not less than 10, and collection air column (2-5-6) is passed through with gas chamber (2-5-5) It is logical;Through having partition (2-5-3) on the collection air column (2-5-6), partition (2-5-3) one is divided into two layers, partition (2-5-3) with It is fixedly connected inside reaction chamber (2-5);The water outlet (2-5-4) is located at reaction chamber (2-5) top side, water outlet (2-5- 4) it is welded and fixed with outlet pipe (2-7).
9. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 8, feature It is, the collection air column (2-5-6) includes:Gas outlet (2-5-6-1), catalyst jet pipe (2-5-6-2), steam jet (2-5- 6-3), organic matter adsorbent material (2-5-6-4), water discharge spout (2-5-6-5) collect air column partition (2-5-6-6), air inlet (2- 5-6-7), detection hole (2-5-6-8);
Positioned at the gas outlet (2-5-6-1) on top, uncovered structure, treated, and gas is discharged from gas outlet (2-5-6-1);It is described Catalyst jet pipe (2-5-6-2) is located at the lower part gas outlet (2-5-6-1), the two spacing 20cm~40cm, catalyst jet pipe (2-5- 6-2) top is equipped with valve, and valve and supervisor connect, and supervisor lower part connects multiple branch pipes, and the quantity of branch pipe is 2~8, branch pipe End be equipped with spray head, spray head by catalyst spray into collection air column (2-5-6) in, catalyst promote gas in organic matter degradation; The steam jet (2-5-6-3) is located at the lower part catalyst jet pipe (2-5-6-2), the two spacing 20cm~40cm, steam jet (2-5-6-3) circular hollow structure, steam jet (2-5-6-3) and external steam supervisor connect, and main steam header is equipped with valve, ring The shape steam jet lower part (2-5-6-3) is equipped with lotus spray-head, and the two communicates, and lotus spray-head sprays high-temperature steam, and high-temperature steam promotees It is reacted into catalyst with organic matter;The organic matter adsorbent material (2-5-6-4) is located at the lower part steam jet (2-5-6-3), and two Person spacing 20cm~40cm, organic matter adsorbent material (2-5-6-4) cellular porous reticular structure, organic matter adsorbent material (2- It 5-6-4) is laid out for multilayer, interlamellar spacing 2cm~4cm, organic matter adsorbent material (2-5-6-4) adsorbs organic matter in exhaust gas;It is described Collect air column partition (2-5-6-6) and be located at collection air column (2-5-6) middle part and bottom, quantity is 2, collects air column partition (2-5-6- 6) stainless steel material, surface are equipped with a large amount of through-hole, and the collection air column partition side (2-5-6-6) is equipped with water discharge spout (2-5-6-5), For condensed water, excessive catalyst to be collected reprocessing;The collection air column bottom (2-5-6) is equipped with air inlet (2-5-6-7), gives up Gas enters from there;Collect and be equipped with detection hole (2-5-6-8) in the middle part of air column (2-5-6), is used for overhaul of the equipments.
10. a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation according to claim 9, feature It is, the partition (2-5-3) is formed by high molecular material pressing mold;
One, the constituent of partition (2-5-3) is as follows:
According to parts by weight, 19~89 parts of benzoic acid of 4- (3- formoxyl -1H- indoles -5- base), 4- (2- (amino methyl) -4- nitre Base phenyl) 129~206 parts of piperazine -1- carboxylic acid tert-butyl ester, 2- cyano -2- (1,2- dihydro -2- Yang Dai quinoxaline -3- base) acetic acid 67~147 parts of ethyl ester, 140~180 parts of methyl acetate of 2- [4- (2- acetyl bromide) -3- methylphenoxy], 3- (5- formoxyl furan Mutter -2- base) 78~176 parts of -4- methyl benzoic acid, [2- [2- (2,5- dihydro -2,5- dioxo -1H- pyrroles -1- base) ethoxy Base] ethyl] carbamic acid 1,221~296 parts of 1- dimethylethyl esters, concentration is 5- [(the chloro- 1H- pyrrole of 4- of 57ppm~87ppm Azoles -1- base) methyl] 155~243 parts of -2- formic acid, 37~80 parts of propionic acid of 3- (1,3,5- trimethyl -1H- pyrazoles -4- base), N- [2- [4- [(methyl sulphonyl) amino] phenyl] ethyl] carbamic acid 1,127~188 parts of 1- dimethylethyl esters, crosslinking agent 129 ~196 parts, 221~334 parts of carboxylate methyl ester of -1H- pyrazoles -5- of -4- nitro of 1- ((ethoxy carbonyl) methyl), 3- (5- acetyl group - 2- thiophene) 218~281 parts of methyl benzoate, 2- (n- methyl-1 H- pyrazoles -1- carboxylic acid amides) ethyl methylcarbamic acid tert-butyl ester 87~169 parts;
The crosslinking agent is 4- (4- hydroxyphenoxy) ethyl butyrate, 3,4- dihydroxypiperdine -1- benzyl carboxylate, 2- (3- amyl) Any one in dimethyl malenate;
Two, the manufacturing process of partition (2-5-3), comprises the steps of:
Step 1:2755~3655 parts of ultrapure water that conductivity is 5.33 μ of μ S/cm~8.23 S/cm, starting are added in a kettle Blender in reaction kettle, revolving speed are 76rpm~131rpm, start heat pump, reactor temperature is made to rise to 77 DEG C~129 ℃;Sequentially add 4- (3- formoxyl -1H- indoles -5- base) benzoic acid, 4- (2- (amino methyl) -4- nitrobenzophenone) piperazine -1- Carboxylic acid tert-butyl ester, 2- cyano -2- (1,2- dihydro -2- Yang Dai quinoxaline -3- base) ethyl acetate, stirring and adjusting pH value is 5.8 ~7.7, agitator speed is adjusted to 141rpm~233rpm, temperature is 115 DEG C~169 DEG C, is chemically reacted 21~33 hours;
Step 2:Take 2- [4- (2- acetyl bromide) -3- methylphenoxy] methyl acetate, 3- (5- formylfuran -2- base) -4- Methyl benzoic acid is crushed, and powder diameter is 1050~1250 mesh;[2- [2- (2,5- dihydro -2,5- dioxo -1H- is added Pyrroles -1- base) ethyoxyl] ethyl] carbamic acid 1,1- dimethylethyl esters be uniformly mixed, be laid in pallet, tiling with a thickness of 29mm~45mm uses the alpha ray irradiation 135~225 that dosage is 6.9MeV~9.1MeV for 8.9kGy~12.8kGy, energy Minute and the same dose of β x ray irradiation xs 135~225 minutes;
Step 3:The mixed-powder handled through step 2 is added in 5- [(the chloro- 1H- pyrazol-1-yl of 4-) methyl] -2- formic acid, is added Enter reaction kettle, agitator speed is 137rpm~182rpm, and temperature is 132 DEG C~201 DEG C, and booster air pump makes the pressure of reaction kettle Reach 1.03MPa~2.27MPa, keeps this state response 15~27 hours;Pressure release is simultaneously passed through radon gas, makes reacting kettle inner pressure 1.14MPa~1.81MPa, heat preservation stand 17~25 hours;Agitator speed is promoted to 221rpm~269rpm, simultaneous reactions kettle Pressure release is to 0MPa;Sequentially add 3- (1,3,5- trimethyl -1H- pyrazoles -4- base) propionic acid, N- [2- [4- [(methyl sulphonyl) ammonia Base] phenyl] ethyl] carbamic acid 1, after 1- dimethylethyl esters are completely dissolved, crosslinking agent is added and is stirred, heat preservation standing 19~ 29 hours;
Step 4:When agitator speed is 233rpm~298rpm, 1- ((ethoxy carbonyl) methyl) -4- nitro-is sequentially added 1H- pyrazoles -5- carboxylate methyl ester, 3- (5- acetyl group -2- thiophene) methyl benzoate and 2- (n- methyl-1 H- pyrazoles -1- carboxylic acid amides) The ethyl methylcarbamic acid tert-butyl ester promotes reactor pressure, reaches 2.60MPa~4.1MPa, and temperature is 188 DEG C~ 253 DEG C, polymerization reaction 25~35 hours;Reacting kettle inner pressure is down to 0MPa after the reaction was completed, is cooled to 29 DEG C~33 DEG C, out Material, entering molding press can be prepared by partition (2-5-3);
A kind of working method of the agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation, this method includes following Step:
Step 1:In a kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation, organic waste to be processed passes through Feed hopper (21-5) enters, and pulverization roller (21-6) crushes organic waste under the drive for crushing motor (21-4), point (21-8) is fallen apart by crushing organic waste progress homogeneous, dispersion, by separating sieve (21-3) and in blanking amount controller (21- 12) under the premise of controlling blanking velocity, fine powder falls into blanking slideway (21-13) into mixing chamber (21-15);It can not fragmenting bulk By horizontal push plate (21-10) will be unable to fragmenting bulk from can not fragmenting bulk outlet (21-16) discharge;Organic waste fine powder It mixes in mixing chamber (21-15) with the medicament from chemicals dosing plant (21-14), under the stirring action of auger (21-2), realizes The homogeneous of medicament and organic waste fine powder, final organic waste are discharged from discharge port (21-1), squeeze into organic waste Pressure device (22);Water of compaction comb (21-17) outside water of compaction is discharged;The water of compaction of discharge enters cesspool (1);
Step 2:At chemicals dosing plant (21-14), medicament is flowed into from drug-feeding tube (21-14-1), in chemicals dosing plant (21-14) shell Portion, agitating shaft (21-14-5) carry out mixing homogeneous to medicament by internal impeller, while under the action of DC electric field, removal Polar substances, treated, and medicament is finally discharged from drug discharging tube (21-14-3);Operator is right by peep hole (21-14-2) Agent-feeding treatment process is monitored;
Step 3:In organic waste pressurizing unit (22), organic waste enters from extruder loading hopper (22-1), is squeezing Under the combination of extrusion effect for pressing capstan winch (22-2) and counter-force pallet (22-3), moisture in organic waste is squeezed out, expressed water from Expressed water comb (22-4) outflow, into squeezing in water collecting tank (22-6), organic waste continues to fall, and through squeezing capstan winch The combination of extrusion of (22-2) and counter-force supporting plate (22-7) act on, again extrusion dehydration, and water of compaction is from lower compression water comb (22- 9) it is discharged, dry organic waste is discharged from organic waste discharge outlet (22-8);When equipment for washing, clear water is from sluicing pipe (22-5) Outflow is implemented to clean to equipment;
Step 4:In water of compaction after-treatment system, staff puts water of compaction to cesspool (1), and passes through control cabinet (10) Sewage pump (2-3) starting is controlled, treatment sewage is delivered in reaction tower (2);After reaction tower (2) processing, sewage is logical It crosses outlet pipe (2-7) and enters aerobic tank (7) into anaerobic pond (3), then by drainage tube (4), be finally expelled to after the completion of processing Designated position;
Step 5:In cesspool (1), sewage from sewage inlet pipe (1-8) flow into, buffer subsystem (1-6) top and carry out auto polymerization The polyaluminium sulfate contact of system (1-7) is added in aluminum sulfate, and under the facilitation of buffer subsystem (1-6), dirty Organic substance in water is heavy It forms sediment;Meanwhile wave agitation plate (1-5) implements agitation at a slow speed and further promotes the two reaction;Solution continues to fall, and is promoting to precipitate Under the action of column (1-4), organic matter is further settled, and organic waste handles water from sewage from mud discharging pipe (1-1) outlet Discharge pipe (1-3) discharge;COD detector (1-2) monitors reaction process in real time, and feeds back to control centre;
Step 6:Promoting column precipitator (1-4), pending water flows through pipelined channel (1- from promoting the column precipitator top (1-4) to flow into When 4-6), power on, electromagnetic coil (1-4-2), inductance (1-4-3), capacitor (1-4-4) synergy under, microwave It manages (1-4-7) and generates microwave, while stainless steel mirror reflection convex lens (1-4-5) for being located at bottom reflects microwave around, promotees Organic matter is precipitated in water inlet body, realizes that water is separated with organic matter;
Step 7:In reaction tower (2), sewage enter reaction tower (2) it is interior when, sewage pass through isocon (2-5-1) and spray head (2- It 5-2) enters in reaction chamber (2-5), is chemically reacted by anaerobic mud bed effect, while generating bulk gas;In dirt During water reacts, the gas of generation passes through the effect of aspiration pump (2-1), reaches gas chamber (2-5- by collection air column (2-5-6) 5) internal, emission-control equipment (2-2) inside is entered using tracheae (2-6), is discharged finally by exhaust pipe (2-8);
Step 8:At emission-control equipment (2-2), exhaust gas is from entering exhaust inlet pipe (2-2-1), and in exhaust inlet pipe (2-2- 1) under the dispersion umbrella effect of upper end, gas dispersion, when passing through honeycomb sorbent device (2-2-4), with washing sparge pipe (2-2-2) The catharsis of the washing water of ejection, the organic matter in exhaust gas is adsorbed device (2-2-4) absorption or the cleaning of washed water is net, clearly Clean gas is discharged from purified gas outlet pipe (2-2-3), and washing water is discharged from washing water outlet pipe (2-2-5);
Step 9:In collection air column (2-5-6), exhaust gas enters from air inlet (2-5-6-7), in multilayer organic matter adsorbent material (2-5- 6-4) under suction-operated, the organic matter in removing exhaust gas is removed, while with organic matter adsorbent material (2-5-6-4) for carrier, in steam Under the high-temperature steam facilitation that jet pipe (2-5-6-3) sprays, catalyst that exhaust gas and catalyst jet pipe (2-5-6-2) spray into Row reacts, organic matter in gas of degrading;Condensed water and extra catalyst are discharged from the water of collection side air column partition (2-5-6-6) It manages (2-5-6-5) and collects reuse;Treated, and gas is discharged from top gas outlet (2-5-6-1);
Step 10:In water of compaction after-treatment system, when sewage enter anaerobic pond (3) it is internal when, be now placed in anaerobic pond (3) top Blender (9) start under the manipulation of operator, by sewage stir acceleration its purification;When sewage enter it is aerobic When pond (7) is internal, it is located at the content of aerobic tank (7) internal oxygen content sensor real-time monitoring aerobic tank (7) internal oxygen, When oxygen content is lower than its setting value, oxygen content sensor generates electric signal transmission to control cabinet (10), control cabinet (10) Air blower (8) starting is controlled, oxygen injection aerobic tank (7) is internal, guarantee that aerobic tank (7) internal oxygen stable content is being set Near.
CN201810809796.3A 2018-07-23 2018-07-23 A kind of agricultural organic waste comprehensive utilization device for camplotheca acuminata plantation Withdrawn CN108911395A (en)

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