CN108905287A - One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green - Google Patents

One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green Download PDF

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Publication number
CN108905287A
CN108905287A CN201810958294.7A CN201810958294A CN108905287A CN 108905287 A CN108905287 A CN 108905287A CN 201810958294 A CN201810958294 A CN 201810958294A CN 108905287 A CN108905287 A CN 108905287A
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CN
China
Prior art keywords
loading pipe
sieve plate
section
flesh
malachite green
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Pending
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CN201810958294.7A
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Chinese (zh)
Inventor
黄艳荧
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Foshan University
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Foshan University
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Priority to CN201810958294.7A priority Critical patent/CN108905287A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/14Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to the introduction of the feed to the apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/18Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
    • B01D15/1864Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns using two or more columns
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/02Food
    • G01N33/12Meat; Fish

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention discloses one kind for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, it include tube body, the bottom of the tube body is provided with extracting tube group, the bottom of the extracting tube group is provided with outlet tube, the extracting tube group includes no less than one loading pipe, the loading pipe is to be detachably connected with the tube body, the loading pipe is to be detachably connected with the outlet tube, upper sieve plate and lower sieve plate are provided in the loading pipe, the lower sieve plate is connected by a snap in the loading pipe, the upper sieve plate is set to the top of the lower sieve plate, the present invention can be according to the difference of flesh of fish sample, extraction times are different, it can freely arrange in pairs or groups and assemble multiple loading pipes, it is more flexible and convenient when use.

Description

One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green
Technical field
The present invention relates to a kind of extraction equipments, more particularly to one kind is for measuring the remaining solid phase extraction of flesh of fish Malachite Green Take column.
Background technique
Malachite green is widely used in preventing and treating the saprolegniasis of all kinds of aquatic livestocks, branchiomycosis and unguiculus parasitosis etc., But malachite green and its metabolite high residue easily in aquatic products body easily cause carcinogenic, teratogenesis and mutagenesis etc. after people is edible Phenomenon, general Solid Phase Extraction is using following operation:Activation-loading-elution-elution is needed in actual extraction to sample The number of extraction will according to the actual situation depending on, different samples in order to extract malachite green, to required for sample extract Number would also vary from, and original extraction column is due to the architectural characteristic of its own, each extraction column can extraction times according to The construction of its own and determine, when use, is inflexible, and adds filler and be also more troublesome, and practical operation can be very inconvenient.
Summary of the invention
The technical problem to be solved by the present invention is to:It needs a kind of for measuring the remaining Solid Phase Extraction of flesh of fish Malachite Green Column can freely set its extraction times according to the difference of sample, not limited by the structure of extraction column script.
The solution that the present invention solves its technical problem is:One kind is for measuring the remaining solid phase of flesh of fish Malachite Green Extraction column includes tube body, and the bottom of the tube body is provided with extracting tube group, and the bottom of the extracting tube group is provided with out liquid Pipe, the extracting tube group include no less than one loading pipe, and the loading pipe is to be detachably connected with the tube body, institute It is to be detachably connected that loading pipe, which is stated, with the outlet tube, and upper sieve plate and lower sieve plate, the lower sieve are provided in the loading pipe Plate is connected by a snap in the loading pipe, and the upper sieve plate is set to the top of the lower sieve plate.
The present invention provides one kind for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, includes tube body, bottom It is provided with extracting tube group, the bottom of extracting tube group is provided with outlet tube, and extracting tube group includes no less than one loading pipe, fills out Expects pipe is to be detachably connected with tube body, and loading pipe is to be detachably connected with outlet tube, is provided with upper sieve plate in each loading pipe With lower sieve plate, lower sieve plate is connected by a snap in loading pipe, can be easy to disassemble, and upper sieve plate is set to the top of lower sieve plate, In actual mechanical process, need to be added the difference of the number of plies of filler, settable difference number in extraction process according to different samples The loading pipe of amount can place one in a loading pipe to solve the problems, such as repeatedly to extract between upper sieve plate and lower sieve plate Packing layer such as needs three kinds of filler extractions three times, then is connected as an extracting tube group using three loading pipes, when use more Add flexibly, therefore, an extracting tube is divided into multistage by the present invention, and integral disassembly, assembly is convenient, can be increased according to different needs and be assembled Different loading pipes, thus meet the requirement for needing extraction times different when measuring malachite green vestigial to flesh of fish sample, and It can facilitate and filler is cleaned, directly disassemble loading pipe segmentation, be cleaned compared with traditional extracting tube more quick It is convenient.
As a further improvement of the above technical scheme, the loading pipe includes sequentially connected upper fixation from top to bottom Section, contraction section, lower fixed section, the outer diameter of the contraction section from top to bottom gradually taper up.
As a further improvement of the above technical scheme, the loading pipe is provided with several, fixed section interior Peripheral wall is provided with internal thread segment, and the periphery wall of the lower fixed section is provided with external thread section, the internal thread segment and the outer spiral shell Line section, which corresponds, to be cooperatively connected.
As a further improvement of the above technical scheme, the lower, outer perimeter wall of the tube body is provided with external thread section, described The internal perisporium of upper fixed section is provided with internal thread segment, and the external thread section and the internal thread segment, which cooperate, to be connected.
As a further improvement of the above technical scheme, the top internal perisporium of the outlet tube is provided with internal thread segment, institute The periphery wall for stating lower fixed section is provided with external thread section, and the internal thread segment and the external screw thread, which cooperate, to be connected.
As a further improvement of the above technical scheme, the periphery wall of the lower sieve plate is evenly arranged with several card slots, The position that the loading pipe corresponds to the card slot is provided with fixture block, and the fixture block and the card slot, which correspond, to be cooperatively connected.
As a further improvement of the above technical scheme, piston rod is provided in the tube body.
Beneficial effect using above-mentioned further scheme is:Integrated operation is more flexible and convenient, between every pipe connection not It is more preferable to be easy airtightness, it is not easy to leakage problem occur.
Detailed description of the invention
To describe the technical solutions in the embodiments of the present invention more clearly, make required in being described below to embodiment Attached drawing is briefly described.Obviously, described attached drawing is a part of the embodiments of the present invention, rather than is all implemented Example, those skilled in the art without creative efforts, can also be obtained according to these attached drawings other designs Scheme and attached drawing.
Fig. 1 is whole interior structural schematic diagram of the invention.
In figure:It is fixed under sieve plate, the upper fixed section of 5-, 6- contraction section, 7- under 1- tube body, 2- outlet tube, 3- upper sieve plate, 4- Section, 8- piston rod.
Specific embodiment
It is carried out below with reference to technical effect of the embodiment and attached drawing to design of the invention, specific structure and generation clear Chu is fully described by, to be completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is this hair Bright a part of the embodiment, rather than whole embodiments, based on the embodiment of the present invention, those skilled in the art are not being paid Other embodiments obtained, belong to the scope of protection of the invention under the premise of creative work.In addition, be previously mentioned in text All connection/connection relationships not singly refer to that component directly connects, and referring to can be added deduct according to specific implementation situation by adding Few couple auxiliary, to form more preferably coupling structure.Each technical characteristic in the invention, in not conflicting conflict Under the premise of can be with combination of interactions.
Referring to Fig.1, a kind of for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, it include tube body 1, the pipe The bottom of body 1 is provided with extracting tube group, and the bottom of the extracting tube group is provided with outlet tube 2, and the extracting tube group includes not Loading pipe less than one, the loading pipe are to be detachably connected with the tube body 1, the loading pipe and the outlet tube 2 To be detachably connected, upper sieve plate 3 and lower sieve plate 4 are provided in the loading pipe, the lower sieve plate 4 is connected by a snap in institute It states in loading pipe, the upper sieve plate 3 is set to the top of the lower sieve plate 4.
It is used to measure the remaining solid-phase extraction column of flesh of fish Malachite Green it can be seen from the above, the present invention provides one kind, including There is tube body 1, bottom is provided with extracting tube group, and the bottom of extracting tube group is provided with outlet tube 2, and extracting tube group includes no less than one A loading pipe, loading pipe are to be detachably connected with tube body 1, and loading pipe is to be detachably connected with outlet tube 2, in each loading pipe It is provided with upper sieve plate 3 and lower sieve plate 4, lower sieve plate 4 is connected by a snap in loading pipe, can be easy to disassemble, upper sieve plate 3 is arranged In the top of lower sieve plate 4, in the actual operation process, need to be added the number of plies of filler in extraction process according to different samples Difference, the loading pipe of settable different number, to solve the problems, such as repeatedly to extract, in a loading pipe can upper sieve plate 3 with A packing layer is placed between lower sieve plate 4, is such as needed three kinds of filler extractions three times, is then connected as one using three loading pipes A extracting tube group, when use, are more flexible, and therefore, an extracting tube is divided into multistage by the present invention, and integral disassembly, assembly is convenient, can basis Different needs increase the different loading pipe of assembling, need to extract when to meeting to flesh of fish sample measurement malachite green vestigial secondary The different requirement of number, and can facilitate and filler is cleaned, directly loading pipe segmentation is disassembled, with traditional extracting tube It is more efficient and convenient compared to cleaning.
Be further used as preferred embodiment, the loading pipe include from top to bottom sequentially connected upper fixed section 5, The outer diameter of contraction section 6, lower fixed section 7, the contraction section 6 from top to bottom gradually tapers up, and such structure may make that loading pipe is General structure can be conveniently connected through a screw thread between each loading pipe, it is preferred that upper fixed section 5, contraction section 6, lower fixed section 7 can be an integral molding structure, it is preferred that upper sieve plate 3 and lower sieve plate 4 may be provided in contraction section 6, and solution to be extracted is upper solid Determine in section 5, after being extracted by the packing layer in contraction section 6, solution extracted is flowed into lower fixed section 7.
As a further improvement of the above technical scheme, the loading pipe is provided with several, fixed section 5 interior Peripheral wall is provided with internal thread segment, and the periphery wall of the lower fixed section 7 is provided with external thread section, the internal thread segment and the outer spiral shell Line section, which corresponds, to be cooperatively connected, and therefore, the interconnection between loading pipe can pass through a loading pipe and another loading pipe External thread section and internal thread segment be cooperatively connected, to realize that quick splicing between loading pipe assembles, and loading pipe this When structure setting may make lower section loading pipe and upper section loading pipe to splice, lower section loading pipe is nested into upper section filler bottom of the tube, and It is not the top that upper section loading pipe is nested into lower section loading pipe, there are when hydraulic pressure in loading pipe, water flow is not easily accessed phase In the thread segment mutually cooperated, airtightness is more preferable.
As a further improvement of the above technical scheme, the lower, outer perimeter wall of the tube body 1 is provided with external thread section, described The internal perisporium of upper fixed section 5 is provided with internal thread segment, and the external thread section and the internal thread segment, which cooperate, to be connected, equally , the cooperation of this structure can facilitate the mutual cooperation between loading pipe and tube body 1 to connect.
As a further improvement of the above technical scheme, the top internal perisporium of the outlet tube 2 is provided with internal thread segment, institute The periphery wall for stating lower fixed section 7 is provided with external thread section, and the internal thread segment and the external screw thread, which cooperate, to be connected, equally , the cooperation of this structure can facilitate the mutual cooperation between loading pipe and outlet tube 2 to connect.
As a further improvement of the above technical scheme, the periphery wall of the lower sieve plate 4 is evenly arranged with several card slots, The position that the loading pipe corresponds to the card slot is provided with fixture block, and the fixture block and the card slot, which correspond, to be cooperatively connected, Preferably, fixture block and card slot it is settable there are three, by the cooperation of fixture block and card slot, can facilitate to lower 4 Fast Installation of sieve plate To loading pipe.
As a further improvement of the above technical scheme, it is provided with piston rod 8 in the tube body 1, piston rod 8 can be in tube body 1 top moves up and down, and to pressurizeing in tube body 1, accelerates the process of extraction, it is preferred that optional for the extractant of malachite green With pure water or acetonitrile, quartz sand layer, lead oxide, malachite green molecular imprinting filler etc. also can be selected and be used as filler.
Better embodiment of the invention is illustrated above, but the invention is not limited to the implementation Example, those skilled in the art can also make various equivalent modifications on the premise of without prejudice to spirit of the invention or replace It changes, these equivalent variation or replacement are all included in the scope defined by the claims of the present application.

Claims (7)

  1. It include tube body (1) 1. one kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, it is characterised in that:Institute The bottom for stating tube body (1) is provided with extracting tube group, and the bottom of the extracting tube group is provided with outlet tube (2), the extracting tube group It include no less than one loading pipe, the loading pipe is to be detachably connected with the tube body (1), the loading pipe and institute Stating outlet tube (2) is to be detachably connected, and upper sieve plate (3) and lower sieve plate (4), the lower sieve plate are provided in the loading pipe (4) it is connected by a snap in the loading pipe, the upper sieve plate (3) is set to the top of the lower sieve plate (4).
  2. 2. according to claim 1 a kind of for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, feature exists In:The loading pipe includes from top to bottom sequentially connected upper fixed section (5), contraction section (6), lower fixed section (7), the receipts The outer diameter of contracting section (6) from top to bottom gradually tapers up.
  3. 3. according to claim 2 a kind of for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, feature exists In:The loading pipe is provided with several, and the internal perisporium of fixed section (5) is provided with internal thread segment, the lower fixed section (7) periphery wall is provided with external thread section, and the internal thread segment and the external thread section, which correspond, to be cooperatively connected.
  4. 4. according to claim 2 a kind of for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, feature exists In:The lower, outer perimeter wall of the tube body (1) is provided with external thread section, and the internal perisporium of fixed section (5) is provided with internal screw thread Section, the external thread section and the internal thread segment, which cooperate, to be connected.
  5. 5. according to claim 2 a kind of for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, feature exists In:The top internal perisporium of the outlet tube (2) is provided with internal thread segment, and the periphery wall of the lower fixed section (7) is provided with outer spiral shell Line section, the internal thread segment and the external screw thread, which cooperate, to be connected.
  6. 6. according to claim 1 a kind of for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, feature exists In:The periphery wall of the lower sieve plate (4) is evenly arranged with several card slots, and the position that the loading pipe corresponds to the card slot is all provided with It is equipped with fixture block, the fixture block and the card slot, which correspond, to be cooperatively connected.
  7. 7. according to claim 1 a kind of for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green, feature exists In:Piston rod (8) are provided in the tube body (1).
CN201810958294.7A 2018-08-22 2018-08-22 One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green Pending CN108905287A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810958294.7A CN108905287A (en) 2018-08-22 2018-08-22 One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green

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Application Number Priority Date Filing Date Title
CN201810958294.7A CN108905287A (en) 2018-08-22 2018-08-22 One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112494992A (en) * 2020-11-02 2021-03-16 河北伊莱莎生物技术有限公司 Dioxin pretreatment purification combined column and preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101879381A (en) * 2005-07-26 2010-11-10 诺华赛公司 The method and apparatus of separating mixture component
CN102974129A (en) * 2012-12-10 2013-03-20 浙江省海洋水产研究所 Multi-stage combined type multi-wall carbon nano tube solid phase extraction column
CN106481817A (en) * 2016-12-12 2017-03-08 苏州楚博生物技术有限公司 Butt sealing assembly for tandem chromatographic column
CN206192956U (en) * 2016-11-21 2017-05-24 天津农学院 Drug residue detects and uses extraction device
CN206450638U (en) * 2016-09-30 2017-08-29 珠海赛隆药业股份有限公司 The GM1 detection chromatographic column of high-purity
CN206556971U (en) * 2017-03-10 2017-10-13 深圳市瑞赛生物技术有限公司 A kind of malachite green molecular engram multilayer solid phase extraction column
CN208852462U (en) * 2018-08-22 2019-05-14 佛山科学技术学院 One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101879381A (en) * 2005-07-26 2010-11-10 诺华赛公司 The method and apparatus of separating mixture component
CN102974129A (en) * 2012-12-10 2013-03-20 浙江省海洋水产研究所 Multi-stage combined type multi-wall carbon nano tube solid phase extraction column
CN206450638U (en) * 2016-09-30 2017-08-29 珠海赛隆药业股份有限公司 The GM1 detection chromatographic column of high-purity
CN206192956U (en) * 2016-11-21 2017-05-24 天津农学院 Drug residue detects and uses extraction device
CN106481817A (en) * 2016-12-12 2017-03-08 苏州楚博生物技术有限公司 Butt sealing assembly for tandem chromatographic column
CN206556971U (en) * 2017-03-10 2017-10-13 深圳市瑞赛生物技术有限公司 A kind of malachite green molecular engram multilayer solid phase extraction column
CN208852462U (en) * 2018-08-22 2019-05-14 佛山科学技术学院 One kind is for measuring the remaining solid-phase extraction column of flesh of fish Malachite Green

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112494992A (en) * 2020-11-02 2021-03-16 河北伊莱莎生物技术有限公司 Dioxin pretreatment purification combined column and preparation method and application thereof

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