CN108904323A - A kind of compound with unique wire-drawing effect and its application in cosmetics - Google Patents
A kind of compound with unique wire-drawing effect and its application in cosmetics Download PDFInfo
- Publication number
- CN108904323A CN108904323A CN201810878410.4A CN201810878410A CN108904323A CN 108904323 A CN108904323 A CN 108904323A CN 201810878410 A CN201810878410 A CN 201810878410A CN 108904323 A CN108904323 A CN 108904323A
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- CN
- China
- Prior art keywords
- compound
- drawing effect
- polyethylene glycol
- unique wire
- copolymer
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of compound with unique wire-drawing effect and its applications in cosmetics, and by weight percentage, which contains polyethylene glycol, Sodium Polyacrylate, at least two in macromolecular polysaccharide.The polyethylene glycol that the present invention passes through addition certain content, the macromolecular polysaccharide of certain content and/or the acrylic copolymer of certain content are compounded, the compound being prepared, it adds it in cosmetics, cosmetics spreadability on the skin, resistance to ionic can be significantly improved, and improves the viscosity of product well and uses soft and smooth sense, and bring a kind of unique wire-drawing effect, the texture of product is promoted, while not increasing the glutinous soapy feeling of product again.
Description
Technical field
The present invention relates to field of biotechnology, in particular to a kind of compound with unique wire-drawing effect and its making up
Application in product.
Background technique
Skin is the maximum organ of human body, is followed successively by epidermis, corium and subcutaneous tissue from outside to inside.Epidermis be skin most
One layer of outside includes cuticula, hyaline layer, stratum granulosum, stratum spinosum epidermidis and basal layer.Wherein, in skin epidermis cuticula
Surface have one layer of lipid generated by the sebum, the horn cell that are secreted in skin sebum gland and be secreted in sweat gland
Sweat and smegma grease, the tunic that is formed in skin surface, referred to as sebum film are merged with certain proportion.
The commercially available product overwhelming majority for having certain viscosity contains acrylic compounds rheology control agent, the substance can by with alkali
Property substance neutralization reaction occurs, open the molecule of curling to achieving the effect that be obviously improved product viscosity because of electric repulsion.But
The network that product containing the substance usually shows as when skin surface is smeared collapses rapidly, it is too strong and sprawl to change talent for swimming
The disadvantages of property is poor.The reason of generating such phenomenon is related with sebum film described above, because existing in the sweat in sebum film
A large amount of electrolyte has neutralized electric repulsion needed for the substance promotes viscosity, so that the viscosity structure of system is destroyed, so that disappearing
The skin sense that the person of expense obtains a paintingization water discontinuous equal difference when using product is experienced.
Summary of the invention
In order to solve the above technical problems, the primary purpose of the present invention is that providing a kind of with the compound of unique wire-drawing effect
Object, the compound can be obviously improved the spreadability of product, viscosity that is resistance to ionic and promoting product well.
The compound with unique wire-drawing effect of the present invention, by weight percentage, which contains poly- second
Glycol, Sodium Polyacrylate, at least two in macromolecular polysaccharide.
It is preferably based on the total weight of compound, the additive amount of the polyethylene glycol is 0 ~ 5wt%, and the acrylic compounds are total
The additive amount of polymers is 0 ~ 1.5wt%, and the additive amount of the macromolecular polysaccharide is 0 ~ 0.5wt%.
Preferably, the polyethylene glycol：Acrylic copolymer：The compounding weight ratio of macromolecular polysaccharide is（15-30）：
（2-5）：1；The polyethylene glycol：The compounding weight ratio of macromolecular polysaccharide is（20~35）：1.
Wherein, the polyethylene glycol is selected from PEG-240/HDI copolymer pair ~ -20 ether of decyl tetradecyl alcohol polyethers, poly- second two
One or more of alcohol -90M, PEG-150 distearate.
Wherein, the acrylic copolymer is selected from sodium acrylate/sodium acryloyldimethyl taurate copolymers, acrylic acid
（Ester）Analog copolymer sodium, acrylic acid（Ester）Class/C10-30 alkylol acrylamide acid esters cross-linked polymer, acrylamide dimethyl ox sulphur
One or more of sour ammonium/VP copolymer.
Wherein, the macromolecular polysaccharide is selected from one or more of cellulose, xanthan gum, Arabic gum, hyaluronic acid；
Wherein, the cellulose is selected from one or more of hydroxyethyl cellulose, hydroxypropyl cellulose.
The invention also discloses application of the above-mentioned compound with unique wire-drawing effect in cosmetics.
Compared with prior art, the present invention having the advantages that：
The present invention passes through the polyethylene glycol of addition certain content, the macromolecular polysaccharide of certain content and/or the propylene of certain content
Acid copolymer is compounded, and the compound being prepared adds it in cosmetics, can significantly improve cosmetics in skin
It is spreadability on skin, resistance to ionic, and improve the viscosity of product well and use soft and smooth sense, and bring a kind of unique wire drawing
Effect promotes the texture of product, while not increasing the glutinous soapy feeling of product again.
Specific embodiment
The present invention is further illustrated below by specific embodiment, but embodiments of the present invention are not by following realities
Apply the limitation of example.
Polyethylene glycol：GT-730：PEG-240/HDI copolymer pair ~ -20 ether of decyl tetradecyl alcohol polyethers, 30% active matter contain
Amount is purchased from Japan chemical company Ai Dike.
WSR-301：Polyethylene glycol -90M is purchased from Dow Chemical Company.
DM150：PEG-150 distearate is purchased from Daoming Chemistry Co., Ltd..
Acrylic copolymer：EG：Sodium acrylate/sodium acryloyldimethyl taurate copolymers, active matter content
37.5%, purchased from match Bicc Public Ltd. Co of France.
U21：Acrylic acid（Ester）Class/C10-30 alkylol acrylamide acid esters cross-linked polymer is purchased from the limited public affairs of U.S. Lu Borun
Department.
AVC：Acrylamide dimethyltaurine ammonium/VP copolymer is purchased from Clariant Chemical Co., Ltd..
Macromolecular polysaccharide：Hydroxyethyl cellulose, hydroxypropyl cellulose：It is purchased from Ya Shilan company.
CGF：Xanthan gum, can company purchased from Si Bikai.
Hyaluronic acid：Purchased from Shandong Fu Ruida company.
Arabic gum：Purchased from TIC Gums company of the U.S..
NaOH：Sodium hydroxide is purchased from Xilong Chemical Co., Ltd.
Citric acid：Citric Acid Mono, purchased from the holding Group Co., Ltd in English pavilion.
Test method：
It is resistance to ionic：By sample it is soft be applied to skin surface, see sample in the continuous state of skin surface, if continuous
State, as spreadability are good, comment 5 points, if sample, which is separated in skin surface like droplet shape, is chosen as 1 point, intermediate state is successively commented
Point.
Spreadability：Sample is coated in skin surface with same dynamics, sees that sample sprawls situation in skin surface, if sample
Product are then that spreadability is good in continuous unremitting smooth sprawl in skin surface, 5 points are commented, if it is discontinuous like droplet to sprawl interruption
It is then bad for spreadability, 1 point is commented, intermediate state successively scores.
Viscosity：It can also be estimated using BROOK FIELD viscosity meter, viscosity lower assessment 1 divides if like watery flowing, if seemingly
Paste does not flow then viscosity height, comments 5 points, intermediate state successively scores.
Soft and smooth sense：Sample is gently rubbed and is applied to skin surface, experiences the silk smooth felling of sample.If no silk smooth felling comments 1 point, if having
Silk smooth felling successively comments 2 ~ 5 points according to it from weak to strong.
Wire-drawing effect：Whether there is wire drawing as judgment criteria when transferring sample using finger, if commenting 1 point without wire drawing, if there is wire drawing
2 ~ 5 points are successively commented from weak to strong according to it.
Glutinous soapy feeling：Sample is gently rubbed and is applied to skin surface, the glutinous soapy feeling smeared and experience sample of slowly looping, if greasy without sticking
Sense comments 5 points, is chosen as 1 point if the glutinous soapy feeling of sample is relatively strong, intermediate state successively scores.
Embodiment 1 ~ 9 and comparative example 1 ~ 5：
It is formulated by shown in table 1,（1）Acrylic copolymer is accurately weighed, is added in deionized water, 5min is impregnated, it is spare；（2）
Macromolecular polysaccharide and/or polyethylene glycol are accurately weighed, is dispersed with glycerol, is stirred, it is spare；（2）Stirring（1）State
Under, it will（2）It is added, being heated to temperature jointly is 70 ~ 75 DEG C, and the NaOH got ready in advance is added under stirring（10% is water-soluble
Liquid）And citric acid（1% aqueous solution）, adjust between pH to 6 ~ 7, continue to stir, being cooled to room temperature to obtain the final product has unique wire-drawing effect
Compound, the results are shown in Table 1 for test performance.
The weight percentage of each component and each the performance test results of 1 embodiment and comparative example of table
The present invention passes through the polyethylene glycol of addition certain content it can be seen from the embodiment and comparative example of table 1, certain content
Macromolecular polysaccharide and/or the acrylic copolymer of certain content are compounded, the compound being prepared, adding it to
In cosmetic, cosmetics spreadability on the skin, resistance to ionic can be significantly improved, and improve the viscosity of product well and make
With soft and smooth sense, and a kind of unique wire-drawing effect is brought, promotes the texture of product, and do not increase the glutinous soapy feeling of product.
Claims (7)
1. a kind of compound with unique wire-drawing effect, which is characterized in that by weight percentage, which contains poly- second
Glycol, Sodium Polyacrylate, at least two in macromolecular polysaccharide.
2. the compound with unique wire-drawing effect according to claim 1, which is characterized in that the gross weight based on compound
Amount, the additive amount of the polyethylene glycol are 0 ~ 5wt%, and the additive amount of the acrylic copolymer is 0 ~ 1.5wt%, described big point
The additive amount of sub- polysaccharide is 0 ~ 0.5wt%.
3. the compound with unique wire-drawing effect according to claim 2, which is characterized in that the polyethylene glycol：Third
Olefin(e) acid analog copolymer：The compounding weight ratio of macromolecular polysaccharide is（15-30）：（2-5）：1；The polyethylene glycol：Macromolecular polysaccharide
Compounding weight ratio be（20~35）：1.
4. the compound with unique wire-drawing effect according to claim 1, which is characterized in that the polyethylene glycol is selected from
PEG-240/HDI copolymer is double--20 ether of decyl tetradecyl alcohol polyethers, polyethylene glycol -90M, in PEG-150 distearate
It is one or more of.
5. the compound with unique wire-drawing effect according to claim 1, which is characterized in that the acrylic copolymer
Object is selected from sodium acrylate/sodium acryloyldimethyl taurate copolymers, acrylic acid（Ester）Analog copolymer sodium, acrylic acid（Ester）Class/
One or more of C10-30 alkylol acrylamide acid esters cross-linked polymer, acrylamide dimethyltaurine ammonium/VP copolymer.
6. the compound with unique wire-drawing effect according to claim 1, which is characterized in that the macromolecular polysaccharide choosing
From one or more of cellulose, xanthan gum, Arabic gum, hyaluronic acid；Wherein, the cellulose is selected from hydroxy ethyl fiber
One or more of element, hydroxypropyl cellulose.
7. application of the compound with unique wire-drawing effect as claimed in any one of claims 1 to 6 in cosmetics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810878410.4A CN108904323A (en) | 2018-08-03 | 2018-08-03 | A kind of compound with unique wire-drawing effect and its application in cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810878410.4A CN108904323A (en) | 2018-08-03 | 2018-08-03 | A kind of compound with unique wire-drawing effect and its application in cosmetics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108904323A true CN108904323A (en) | 2018-11-30 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810878410.4A Pending CN108904323A (en) | 2018-08-03 | 2018-08-03 | A kind of compound with unique wire-drawing effect and its application in cosmetics |
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| CN (1) | CN108904323A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110507594A (en) * | 2019-09-17 | 2019-11-29 | 上海百雀羚生物科技有限公司 | A kind of toner and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102046142A (en) * | 2008-05-30 | 2011-05-04 | 株式会社资生堂 | Oil-in-water type topical agent for skin |
| CN102525844A (en) * | 2012-02-07 | 2012-07-04 | 广东名臣有限公司 | Wiredrawing and shaping composition |
| CN104940044A (en) * | 2015-06-30 | 2015-09-30 | 广州环亚化妆品科技有限公司 | Foundation cream with stable wire-drawing effect and preparation method of foundation cream |
-
2018
- 2018-08-03 CN CN201810878410.4A patent/CN108904323A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102046142A (en) * | 2008-05-30 | 2011-05-04 | 株式会社资生堂 | Oil-in-water type topical agent for skin |
| CN102525844A (en) * | 2012-02-07 | 2012-07-04 | 广东名臣有限公司 | Wiredrawing and shaping composition |
| CN104940044A (en) * | 2015-06-30 | 2015-09-30 | 广州环亚化妆品科技有限公司 | Foundation cream with stable wire-drawing effect and preparation method of foundation cream |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110507594A (en) * | 2019-09-17 | 2019-11-29 | 上海百雀羚生物科技有限公司 | A kind of toner and preparation method thereof |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181130 |