CN108896349A - A method of the monitoring contaminated degree of fully-loaded stream - Google Patents

A method of the monitoring contaminated degree of fully-loaded stream Download PDF

Info

Publication number
CN108896349A
CN108896349A CN201810792495.4A CN201810792495A CN108896349A CN 108896349 A CN108896349 A CN 108896349A CN 201810792495 A CN201810792495 A CN 201810792495A CN 108896349 A CN108896349 A CN 108896349A
Authority
CN
China
Prior art keywords
water
fully
monitoring
empty van
contaminated degree
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810792495.4A
Other languages
Chinese (zh)
Inventor
李建英
杨芳
李旋
王玉洁
张晓丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810792495.4A priority Critical patent/CN108896349A/en
Publication of CN108896349A publication Critical patent/CN108896349A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/10Devices for withdrawing samples in the liquid or fluent state
    • G01N1/14Suction devices, e.g. pumps; Ejector devices
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/28Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/38Diluting, dispersing or mixing samples
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/28Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/44Sample treatment involving radiation, e.g. heat
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/10Devices for withdrawing samples in the liquid or fluent state
    • G01N1/14Suction devices, e.g. pumps; Ejector devices
    • G01N2001/1418Depression, aspiration

Abstract

The invention discloses a kind of methods for monitoring the contaminated degree of fully-loaded stream comprising following steps:S1, prepare water tank:Air pump is opened to vacuumize sealing empty van;S2, it fetches water:It extend into the depth of underwater with drinking-water pipe lower end, carries out selecting different sampling depths, successively opens the first valve, carry out extraction water sample;After the completion of S3, extraction, the first valve is closed, then opens stirring motor, is stirred 1-2 minutes, stirring motor is closed, turns off air pump, then makes sealing empty van inner return-air be restored to normal pressure state, opens third valve, be sampled from probe tube;S4, detection water sample:According to the scale on transparent glass graduated cylinder, different amounts of water sample is chosen, and is sent to water quality detection laboratory after the water sample that different depth takes out is mixed in proportion and carries out oxygen demand detection.The present invention acquires the water sample of the different water levels in river, can take out rationally in proportion (ratio that this ratio is different water levels height and total water layer) and mix and homogeneous water sample is made, and detect to this water sample, detection data is more acurrate.

Description

A method of the monitoring contaminated degree of fully-loaded stream
Technical field
The invention belongs to the river pollution degree in environmental protection to monitor art field, be specifically related to a kind of monitoring fully-loaded stream The method of contaminated degree.
Background technique
Increasingly with the continuous development of industrialization and people's living standard, either industrial waste or sanitary waste It is more, and significant portion therein is directly discharged in river without environmentally friendlyization processing, thus leads to the dirt in river Dye.
In order to monitor the contaminated degree in river, data supporting is provided for the prevention and treatment of river pollution, often in the prior art Using following technical scheme:
Chinese patent application 201110046575.3 discloses a kind of method of diagnosing river pollution in real time comprising:River Flow pollution diagnosis platform, pollution level evaluation module, pollution cause diagnostic module, blowdown scheme optimization module, computation model pipe Manage module and database management module;When completing a pollution diagnosis engineering, this method executes according to the following steps:A. start river Flow pollution diagnosis platform;B., basic parameter is set;C. river pollution scale evaluation is carried out;D. river pollution cause diagnosis is carried out; E. contaminating enterprises' blowdown scheme optimization is carried out;F. result output is carried out.Realize the method equipment include:Flowmeter, GPS core Piece, solubility detector, singlechip group at remote terminal.The technical solution realizes the reality of river pollution degree and pollution cause When diagnose, input water correction target or pollution level reduce target after also produce the optimization side of contaminating enterprises' blowdown along the river Case is good for the environment department's real-time monitoring river pollution situation, carries out Discussion On Measures of Rivers Pollution Treatment to the ill, and science carries out emission reduction planning.
But the technical solution uses numerous modules, structure is complicated, and different modules has the risk of data distortion, It is easy to cause the inaccuracy to the monitoring of river pollution degree.
Chinese patent application 201710664120.5 is disclosed a kind of observed based on water quality of river and calculates that upstream enters river pollution The method of flux, key step include 1) Outlet Section water quality process observation data collection;2) River Water Quality Process computation model Building;3) River Water Quality Process associated model constructs;4) enter river pollution flux optimization to calculate.This method uses lower reaches of river section Water concentration process observation data realize the high-precision estimation into river pollution flux, avoid using root in conventional method It estimates according to Land use data into the uncertain excessive problem of river pollution flux.
But the method that above-mentioned observation calculates that upstream enters river pollution flux is using the method calculated, during reckoning It needs by a large amount of intermediate computations;It is well known that the intermediate data being related in calculating process is more, result data deviation is got over Greatly, thus lead to final result data inaccuracy, be difficult really to react the contaminated situation in river.
On the other hand, since current China's vegetation deterioration is serious, there are more fully-loaded stream, the river water of fully-loaded stream It due to the difference of depth, is influenced by buoyancy, gravity or flowing, the substance contained in water body is different, and water body is caused to be layered, and produces Raw multiple water layers;It is above-mentioned in the prior art to the contaminated degree in river when monitoring the contaminated degree of fully-loaded stream Technical solution cannot exclude the influence of silt and water body layering in fully-loaded stream, thus can not accurately monitor contaminated The case where water body in river contaminated degree.
Had shown that through a large amount of research of applicant, by COD can monitor fully-loaded stream it is contaminated Degree.
COD is chemically to measure to consume the suitable of oxygen when organic matter is aoxidized by strong oxidizer in water sample Amount, to indicate the number of Organic substance in water amount.Water sample under certain condition, with reproducibility object in the water sample of oxidizing units volume The amount of oxidant consumed by matter be index, be converted to per unit volume water sample be all oxidized after, the milligram of the oxygen needed Number, is indicated with mg/L, to reflect the degree polluted in water by reducing substances.
Summary of the invention
The purpose of the present invention is to provide a kind of methods for monitoring the contaminated degree of fully-loaded stream, to solve above-mentioned background Structure is complicated for the technical solution in the prior art proposed in technology, and different modules has the risk of data distortion, is easy to lead Cause the inaccuracy monitored to river pollution degree;Technical solution in the prior art can not rule out silt in fully-loaded stream simultaneously And water body is layered the technical issues of monitoring to river pollution degree.
To achieve the above object, present invention employs following technical solutions:
A method of the monitoring contaminated degree of fully-loaded stream, this approach includes the following steps:
S1, prepare water tank:Sealing empty van is vacuumized using aspiration pump, excludes air to river monitoring data It influences;
S2, it fetches water:Drinking-water pipe lower end is extend into the depth needed in the river water surface, selects different samplings deep Degree, successively opens the first valve, carries out extraction water sample;
S3, stirring sampling:After the completion of extraction, the first valve is closed, opens stirring motor, after mixing time T, closes stirring Motor turns off air pump, so that sealing empty van inner return-air is restored to normal atmosphere pressure condition, third valve is opened, from probe tube In be sampled;
S4, sample presentation detection:The water sample obtained in step S3 is passed through into rapid-digestion spectrophotometric in water quality detection laboratory Method carries out contaminated degree detecting.
Preferably, the contaminated degree of the rapid-digestion spectrophotometry water sample uses following steps:
S41, water sample is divided by two classes according to sediment content, sediment content is less than or equal to 4 × 10-3The water sample and silt of g/mL Content is greater than 4 × 10-3The water sample of g/mL;
S42, sediment content are less than or equal to 4 × 10-3The water sample of g/mL directly with COD digestion device and COD spectrophotometer come Directly measure the COD value of the water sample;
S43, sediment content are greater than 4 × 10-3The water sample of g/mL carries out silt separation to water sample with centrifuge;Sediment content Greater than 4 × 10-3The water sample of g/mL takes supernatant COD digestion device and COD spectrophotometer come directly after centrifuge separates Measure COD value;
S44, by the COD value banknotes-system measured in step S42 and S43 at table, obtain the contaminated degree of fully-loaded stream.
Preferably, the depth is the depth downward from river surface.
Preferably, in step s 2, river water is pumped into sealing empty van using atmospheric pressure and carries out extraction water sample.
Preferably, before step S 4, repeat step S1-S3, the river water of different depth is carried out separately sampled;And It is sent to water quality detection laboratory after the water sample that different depth takes out is mixed in proportion in step s 4 and carries out oxygen demand detection, To obtain fully-loaded stream pollution level data.
Preferably, described is after being sampled according to three layers of upper, middle and lower of river in proportion, and every layer of water sample accounts for mixed The one third of water sample after conjunction, the depth on upper layer are a quarter of river total depth, and the depth in middle layer is river total depth One third, remaining is lower layer.
Preferably, described is according to rationally in proportion, which is the ratio of different water levels height and total water layer in proportion Example.
It preferably, in step s 4, to the oxygen demand detection of water sample is detected using rapid-digestion spectrophotometry COD (COD).
For the method using a kind of device for monitoring the contaminated degree of fully-loaded stream, which includes floating work The upper face of platform, water quality detection laboratory, sealing empty van, vertical bar, the floating workbench has built water quality detection experiment Room, the top of the floating workbench are fixedly connected with sealing empty van, and the top of the floating workbench is fixed by the bracket company It is connected to clamp, the inside of the clamp, which is fixedly clamped, is equipped with vertical bar, and the side of the vertical bar is fixed by the connecting rod company It is connected to resilient clip opening, drinking-water pipe is connected in the resilient clip opening, the upper end of the drinking-water pipe is connected to sealing by hose The top of empty van, and the first valve is installed on hose, the inside of the sealing empty van is fixedly installed with transparent glass graduated cylinder, Stirring motor is installed at the top of the sealing empty van.
The lower part of the stirring motor is sequentially connected with agitating shaft, and the lower end of the agitating shaft extends to transparent glass graduated cylinder Interior bottom, be fixedly connected with paddle on the agitating shaft, one end of the hose extends to the upper of transparent glass graduated cylinder The side of side, the sealing empty van is equipped with sealed transparent glass plate, and the side of the transparent glass graduated cylinder is communicated with probe tube, One end of the probe tube is equipped with third valve, the floating workbench through sealed transparent glass plate, and on probe tube Top air pump is installed, the bleeding point of the air pump is connected to by tracheae with the upper end side of sealing empty van.
Preferably, the drinking-water pipe is at least provided with four groups, and the lower end of four groups of drinking-water pipes extend into the depth of underwater Difference, the resilient clip opening are elastoplastic clamping opening.
Preferably, the stirring motor is decelerating motor, and the revolving speed R of stirring motor is 150-320r/min, described to stir Mixing leaf is straight leaf or helical-blade, and the distance between inner wall of paddle and transparent glass graduated cylinder d is not less than 3-5cm.
Preferably, the bottom of the sealing empty van is fixedly connected with supporting leg, and the lower central of the transparent glass graduated cylinder connects It is connected with the scum pipe through sealing empty van, and the second valve is installed on scum pipe.
Preferably, the lower part of the stirring motor is fixedly installed with shock-absorbing motor pedestal, and the shock-absorbing motor pedestal is bullet Property rubber base plate.
Preferably, protrusion is fixedly connected on the upper end side wall of the drinking-water pipe.
Preferably, the surface of the vertical bar offers the scale for fathoming.
Preferably, one end of the hose is arranged at the top 1-2cm of transparent glass graduated cylinder, and the water outlet of hose Port diagonally downward, is extend into transparent glass graduated cylinder.
Preferably, in order to realize being uniformly mixed for water sample, to obtain the contaminated degree of more accurate fully-loaded stream Data, revolving speed R and paddle and the distance between the inner wall of the transparent glass graduated cylinder d of the stirring motor meet with ShiShimonoseki System:
Wherein, β is coefficient of balance, value range 2.46-5.5;Numerical operation is pertained only to herein, is not related to unit fortune It calculates.
Compared with prior art, technical effect and advantage of the invention:
1, the method for the monitoring contaminated degree of fully-loaded stream of the invention, by choosing the water sample of river multilayer water body, The actual conditions of river water can be accurately reflected, it is ensured that the contaminated data in the river obtained are accurate.
2, the method for the monitoring contaminated degree of fully-loaded stream of the invention, by using rapid-digestion spectrophotometry into Row detection COD (COD), and then judge the pollution level of polluted river.
3, the method for the monitoring contaminated degree of fully-loaded stream of the invention, by using multiple groups vertical bar, resilient clip opening And the design of drinking-water pipe, the lower end of multiple groups drinking-water pipe can be in the different water levels of river underwater, be used for different water levels Sampling use, sampling facilitate it is comprehensive so that sampling it is more accurate.
4, the method for the monitoring contaminated degree of fully-loaded stream of the invention, by using sealing empty van and stirring motor Design, is sampled, after sampling, contact of the water sample with air is few, avoids water sample from polluting, while stirring motor can using negative pressure So that water sample keeps uniform state, precipitating is produced after avoiding sampling or floating material, the taken amount for influencing water sample are used in mixed way.
5, the method for the monitoring contaminated degree of fully-loaded stream of the invention, by using the design of transparent glass graduated cylinder, The sampling water of different water levels can take out mixing rationally in proportion (ratio that this ratio is different water levels height and total water layer) And homogeneous water sample being made, and detect to this water sample, detection data is more acurrate.
6, the method for the monitoring contaminated degree of fully-loaded stream of the invention, is examined by using rapid-digestion spectrophotometry The contaminated degree for surveying water sample, solves influence of the silt in fully-loaded stream to testing result, improves the accurate of monitoring Property.
7, the method for the monitoring contaminated degree of fully-loaded stream of the invention, by revolving speed and stirring that stirring motor is arranged The relationship of the distance between the inner wall of leaf and transparent glass graduated cylinder can be realized being uniformly mixed for water sample, more accurate to obtain Fully-loaded stream contaminated level data
Detailed description of the invention
Fig. 1 is a kind of method flow diagram for monitoring the contaminated degree of fully-loaded stream of the present invention;
Fig. 2 is a kind of structural schematic diagram for the device for monitoring the contaminated degree of fully-loaded stream of the present invention;
Fig. 3 is the portion the A enlarged structure signal in a kind of device Fig. 2 for monitoring the contaminated degree of fully-loaded stream of the present invention Figure;
Fig. 4 is the internal structure signal that a kind of device for monitoring the contaminated degree of fully-loaded stream of the present invention seals empty van Figure;
Fig. 5 is a kind of overlooking structure diagram for the device vertical bar for monitoring the contaminated degree of fully-loaded stream of the present invention.
In figure:1 floating workbench, 2 water quality detection laboratories, 3 air pumps, 4 sealing empty vans, 5 first valves, 6 brackets, 7 are erected Straight-bar, 8 clamps, 9 hoses, 10 protrusions, 11 resilient clip openings, 12 drinking-water pipes, 13 connecting rods, 14 tracheaes, 15 stirring motors, 16 subtract It is seismoelectric machine base, 17 transparent glass graduated cylinders, 18 supporting legs, 19 scum pipes, 20 second valves, 21 probe tubes, 22 third valves, 23 close Seal transparency glass plate, 24 paddles, 25 agitating shafts.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Herein Described specific embodiment is only used to explain the present invention, is not intended to limit the present invention.Based on the embodiments of the present invention, Every other embodiment obtained by those of ordinary skill in the art without making creative efforts, belongs to this hair The range of bright protection.
Embodiment 1
As shown in Figure 1, a kind of method for monitoring the contaminated degree of fully-loaded stream, this approach includes the following steps:
S1, prepare water tank:Sealing empty van is vacuumized using aspiration pump, excludes air to river monitoring data It influences;
S2, it fetches water:Drinking-water pipe lower end is extend into the depth needed in the river water surface, selects different samplings deep Degree, successively opens the first valve, carries out extraction water sample;
S3, stirring sampling:After the completion of extraction, the first valve is closed, opens stirring motor, after mixing time T, closes stirring Motor turns off air pump, so that sealing empty van inner return-air is restored to normal atmosphere pressure condition, third valve is opened, from probe tube In be sampled;
S4, sample presentation detection:The water sample of removal is sent to water quality detection laboratory and carries out oxygen demand detection.
As shown in Figure 2-5, the method is using a kind of device for monitoring the contaminated degree of fully-loaded stream, the device packet Floating workbench 1 is included, the upper face of the floating workbench 1 has built water quality detection laboratory 2, the floating workbench 1 Top be fixedly connected with sealing empty van 4, the top of the floating workbench 1 is fixedly connected with clamp 8 by bracket 6, described The inside of clamp 8, which is fixedly clamped, is equipped with vertical bar 7, and the side of the vertical bar 7 is fixedly connected flexible by connecting rod 13 Clamping opening 11, drinking-water pipe 12 is connected in the resilient clip opening 11, and the upper end of the drinking-water pipe 12 is connected to sealing by hose 9 The top of empty van 4, and the first valve 5 is installed on hose 9, the inside of the sealing empty van 4 is fixedly installed with transparent glass The top of graduated cylinder 17, the sealing empty van 4 is equipped with stirring motor 15.
The lower part of the stirring motor 15 is sequentially connected with agitating shaft 25, and the lower end of the agitating shaft 25 extends to transparent glass The interior bottom of glass graduated cylinder 17 is fixedly connected with paddle 14 on the agitating shaft 25, and one end of the hose 9 extends to transparent The side of the top of glass cylinder 17, the sealing empty van 4 is equipped with sealed transparent glass plate 23, the transparent glass graduated cylinder 17 Side be communicated with probe tube 21, one end of the probe tube 21 is pacified through sealed transparent glass plate 23, and on probe tube 21 Equipped with third valve 22, the top of the floating workbench 1 is equipped with air pump 3, the bleeding point of the air pump 3 by tracheae 14 with Seal the upper end side connection of empty van 4.
The drinking-water pipe 12 is at least provided with four groups, and the lower end of four groups of drinking-water pipes 12 extend into the depth of underwater not Together, the resilient clip opening 11 is elastoplastic clamping opening;The stirring motor 15 is decelerating motor, and the revolving speed of stirring motor 15 is low In 200r/min, the paddle 24 is straight leaf or helical-blade, and the inner wall of 24 distance transparent glass cylinder 17 of paddle is not Less than 3cm;The bottom of the sealing empty van 4 is fixedly connected with supporting leg 18, the lower central connection of the transparent glass graduated cylinder 17 There is the scum pipe 19 through sealing empty van 4, and the second valve 20 is installed on scum pipe 19;The lower part of the stirring motor 15 It is fixedly installed with shock-absorbing motor pedestal 16, the shock-absorbing motor pedestal 16 is elastic rubber pedestal;The upper end of the drinking-water pipe 12 Protrusion 10 is fixedly connected on side wall;The surface of the vertical bar 7 offers the scale for fathoming;The hose 9 One end be arranged at the top 1-2cm of transparent glass graduated cylinder 17, and the water outlet port of hose 9 is diagonally downward, extend into In bright glass cylinder 17.
Working principle:The present invention is by the design of multiple groups vertical bar, resilient clip opening and drinking-water pipe, under multiple groups drinking-water pipe End can be in the different water levels of river underwater, for different water levels sampling use, sampling facilitate it is comprehensive so that sampling It is more accurate;By sealing the design of empty van and stirring motor, it is sampled using negative pressure, after sampling, water sample and air Contact is few, and water sample is avoided to pollute, while stirring motor can make water sample keep uniform state, avoid after sampling production precipitating or Floating material, the taken amount for influencing water sample are used in mixed way;Pass through the design of transparent glass graduated cylinder, the sampling water of different water levels, Ke Yihe Reason in proportion (ratio that this ratio is different water levels height and total water layer), is taken out and mixes and homogeneous water sample is made, and to this water Sample is detected, and detection data is more acurrate.
Embodiment 2
As shown in Figure 1, a kind of method for monitoring the contaminated degree of fully-loaded stream, this approach includes the following steps:
S1, prepare water tank:Sealing empty van is vacuumized using aspiration pump, excludes air to river monitoring data It influences;
S2, it fetches water:Drinking-water pipe lower end is extend into the depth needed in the river water surface, selects different samplings deep Degree, successively opens the first valve, and river water is pumped into sealing empty van using atmospheric pressure and carries out extraction water sample;
S3, stirring sampling:After the completion of extraction, the first valve is closed, opens stirring motor, after mixing time T, closes stirring Motor turns off air pump, so that sealing empty van inner return-air is restored to normal atmosphere pressure condition, third valve is opened, from probe tube In be sampled;
S4, sample presentation detection:The water sample obtained in step S3 is passed through into rapid-digestion spectrophotometric in water quality detection laboratory Method carries out contaminated degree detecting:
The contaminated degree of the rapid-digestion spectrophotometry water sample uses following steps:
S41, water sample is divided by two classes according to sediment content, sediment content is less than or equal to 4 × 10-3The water sample and silt of g/mL Content is greater than 4 × 10-3The water sample of g/mL;
S42, sediment content are less than or equal to 4 × 10-3The water sample of g/mL directly with COD digestion device and COD spectrophotometer come Directly measure the COD value of the water sample;
S43, sediment content are greater than 4 × 10-3The water sample of g/mL carries out silt separation to water sample with centrifuge;Sediment content Greater than 4 × 10-3The water sample of g/mL takes supernatant COD digestion device and COD spectrophotometer come directly after centrifuge separates Measure COD value;
S44, by the COD value banknotes-system measured in step S42 and S43 at table, obtain the contaminated degree of fully-loaded stream.
The depth is the depth downward from river surface.
Before step S 4, repeat step S1-S3, the river water of different depth is carried out separately sampled;And in step Water quality detection laboratory is sent to after mixing the water sample that different depth takes out in proportion in S4 to detect.
Described is after being sampled according to three layers of upper, middle and lower of river in proportion, and every layer of water sample accounts for mixed water The one third of sample, the depth on upper layer are a quarter of river total depth, the depth in middle layer be river total depth three/ One, remaining is lower layer.
As shown in Figure 2-5, the method is using a kind of device for monitoring the contaminated degree of fully-loaded stream, the device packet Floating workbench 1 is included, the upper face of the floating workbench 1 has built water quality detection laboratory 2, the floating workbench 1 Top be fixedly connected with sealing empty van 4, the top of the floating workbench 1 is fixedly connected with clamp 8 by bracket 6, described The inside of clamp 8, which is fixedly clamped, is equipped with vertical bar 7, and the side of the vertical bar 7 is fixedly connected flexible by connecting rod 13 Clamping opening 11, drinking-water pipe 12 is connected in the resilient clip opening 11, and the upper end of the drinking-water pipe 12 is connected to sealing by hose 9 The top of empty van 4, and the first valve 5 is installed on hose 9, the inside of the sealing empty van 4 is fixedly installed with transparent glass The top of graduated cylinder 17, the sealing empty van 4 is equipped with stirring motor 15.
The lower part of the stirring motor 15 is sequentially connected with agitating shaft 25, and the lower end of the agitating shaft 25 extends to transparent glass The interior bottom of glass graduated cylinder 17 is fixedly connected with paddle 14 on the agitating shaft 25, and one end of the hose 9 extends to transparent The side of the top of glass cylinder 17, the sealing empty van 4 is equipped with sealed transparent glass plate 23, the transparent glass graduated cylinder 17 Side be communicated with probe tube 21, one end of the probe tube 21 is pacified through sealed transparent glass plate 23, and on probe tube 21 Equipped with third valve 22, the top of the floating workbench 1 is equipped with air pump 3, the bleeding point of the air pump 3 by tracheae 14 with Seal the upper end side connection of empty van 4.
The drinking-water pipe 12 is at least provided with four groups, and the lower end of four groups of drinking-water pipes 12 extend into the depth of underwater not Together, the resilient clip opening 11 is elastoplastic clamping opening;The stirring motor 15 is decelerating motor, and the revolving speed of stirring motor 15 is low In 200r/min, the paddle 24 is straight leaf or helical-blade, and the inner wall of 24 distance transparent glass cylinder 17 of paddle is not Less than 3cm;The bottom of the sealing empty van 4 is fixedly connected with supporting leg 18, the lower central connection of the transparent glass graduated cylinder 17 There is the scum pipe 19 through sealing empty van 4, and the second valve 20 is installed on scum pipe 19;The lower part of the stirring motor 15 It is fixedly installed with shock-absorbing motor pedestal 16, the shock-absorbing motor pedestal 16 is elastic rubber pedestal;The upper end of the drinking-water pipe 12 Protrusion 10 is fixedly connected on side wall;The surface of the vertical bar 7 offers the scale for fathoming;The hose 9 One end be arranged at the top 1-2cm of transparent glass graduated cylinder 17, and the water outlet port of hose 9 is diagonally downward, extend into In bright glass cylinder 17.
Embodiment 3
As shown in Figure 1, a kind of method for monitoring the contaminated degree of fully-loaded stream, this approach includes the following steps:
S1, prepare water tank:Sealing empty van is vacuumized using aspiration pump, excludes air to river monitoring data It influences;
S2, it fetches water:Drinking-water pipe lower end is extend into the depth needed in the river water surface, selects different samplings deep Degree, successively opens the first valve, and river water is pumped into sealing empty van using atmospheric pressure and carries out extraction water sample;
S3, stirring sampling:After the completion of extraction, the first valve is closed, opens stirring motor, after mixing time T, closes stirring Motor turns off air pump, so that sealing empty van inner return-air is restored to normal atmosphere pressure condition, third valve is opened, from probe tube In be sampled;
S4, sample presentation detection:By the water sample of removal be sent to water quality detection laboratory using rapid-digestion spectrophotometry into Row detection COD (COD) carries out oxygen demand detection.
The depth is the depth downward from river surface.
Before step S 4, repeat step S1-S3, the river water of different depth is carried out separately sampled;And in step It is sent to water quality detection laboratory after mixing the water sample that different depth takes out in proportion in S4 and carries out oxygen demand detection, with much Waste stream pollution level data.
Described is according to rationally in proportion, which is the ratio of different water levels height and total water layer in proportion.
As shown in Figure 2-5, the method is using a kind of device for monitoring the contaminated degree of fully-loaded stream, the device packet Floating workbench 1 is included, the upper face of the floating workbench 1 has built water quality detection laboratory 2, the floating workbench 1 Top be fixedly connected with sealing empty van 4, the top of the floating workbench 1 is fixedly connected with clamp 8 by bracket 6, described The inside of clamp 8, which is fixedly clamped, is equipped with vertical bar 7, and the side of the vertical bar 7 is fixedly connected flexible by connecting rod 13 Clamping opening 11, drinking-water pipe 12 is connected in the resilient clip opening 11, and the upper end of the drinking-water pipe 12 is connected to sealing by hose 9 The top of empty van 4, and the first valve 5 is installed on hose 9, the inside of the sealing empty van 4 is fixedly installed with transparent glass The top of graduated cylinder 17, the sealing empty van 4 is equipped with stirring motor 15.
The lower part of the stirring motor 15 is sequentially connected with agitating shaft 25, and the lower end of the agitating shaft 25 extends to transparent glass The interior bottom of glass graduated cylinder 17 is fixedly connected with paddle 14 on the agitating shaft 25, and one end of the hose 9 extends to transparent The side of the top of glass cylinder 17, the sealing empty van 4 is equipped with sealed transparent glass plate 23, the transparent glass graduated cylinder 17 Side be communicated with probe tube 21, one end of the probe tube 21 is pacified through sealed transparent glass plate 23, and on probe tube 21 Equipped with third valve 22, the top of the floating workbench 1 is equipped with air pump 3, the bleeding point of the air pump 3 by tracheae 14 with Seal the upper end side connection of empty van 4.
The drinking-water pipe 12 is at least provided with four groups, and the lower end of four groups of drinking-water pipes 12 extend into the depth of underwater not Together, the resilient clip opening 11 is elastoplastic clamping opening;The stirring motor 15 is decelerating motor, and the revolving speed of stirring motor 15 is low In 200r/min, the paddle 24 is straight leaf or helical-blade, and the inner wall of 24 distance transparent glass cylinder 17 of paddle is not Less than 3cm;The bottom of the sealing empty van 4 is fixedly connected with supporting leg 18, the lower central connection of the transparent glass graduated cylinder 17 There is the scum pipe 19 through sealing empty van 4, and the second valve 20 is installed on scum pipe 19;The lower part of the stirring motor 15 It is fixedly installed with shock-absorbing motor pedestal 16, the shock-absorbing motor pedestal 16 is elastic rubber pedestal;The upper end of the drinking-water pipe 12 Protrusion 10 is fixedly connected on side wall;The surface of the vertical bar 7 offers the scale for fathoming;The hose 9 One end be arranged at the top 1-2cm of transparent glass graduated cylinder 17, and the water outlet port of hose 9 is diagonally downward, extend into In bright glass cylinder 17.
Preferably, in order to realize being uniformly mixed for water sample, to obtain the contaminated degree of more accurate fully-loaded stream Data, revolving speed R and paddle and the distance between the inner wall of the transparent glass graduated cylinder d of the stirring motor meet with ShiShimonoseki System:
Wherein, β is coefficient of balance, value range 2.46-5.5;Numerical operation is pertained only to herein, is not related to unit fortune It calculates.
Finally it should be noted that:The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (9)

1. a kind of method for monitoring the contaminated degree of fully-loaded stream, it is characterised in that:The method includes the following steps:
S1, prepare water tank:Sealing empty van is vacuumized using aspiration pump, excludes air to the shadow of river monitoring data It rings;
S2, it fetches water:Drinking-water pipe lower end is extend into the depth needed in the river water surface, selects different sampling depths, according to The first valve of secondary opening, carries out extraction water sample;
S3, stirring sampling:After the completion of extraction, the first valve is closed, opens stirring motor, after mixing time T, closes stirring electricity Machine turns off air pump, so that sealing empty van inner return-air is restored to normal atmosphere pressure condition, third valve is opened, from probe tube It is sampled;
S4, sample presentation detection:By the water sample obtained in step S3 water quality detection laboratory by rapid-digestion spectrophotometry into The contaminated degree detecting of row.
2. a kind of method for monitoring the contaminated degree of fully-loaded stream according to claim 1, it is characterised in that:Described Depth is the depth downward from river surface.
3. a kind of method for monitoring the contaminated degree of fully-loaded stream according to claim 1 or 2, it is characterised in that:? In step S2, river water is pumped into sealing empty van using atmospheric pressure and carries out extraction water sample.
4. a kind of method for monitoring the contaminated degree of fully-loaded stream according to claim 1 to 3, it is characterised in that:It is described Method using it is a kind of monitor the contaminated degree of fully-loaded stream device, the device include floating workbench (1), water quality detection Laboratory (2), sealing empty van (4), vertical bar (7), the upper face of floating workbench (1) have built water quality detection experiment Room (2), the top of floating workbench (1) are fixedly connected with sealing empty van (4), and the top of floating workbench (1) is logical It crosses bracket (6) to be fixedly connected with clamp (8), the inside of the clamp (8), which is fixedly clamped, to be equipped with vertical bar (7), described vertical The side of bar (7) is fixedly connected with resilient clip opening (11) by connecting rod (13), is connected with and is drawn water in the resilient clip opening (11) It manages (12), the upper end of the drinking-water pipe (12) is connected to the top of sealing empty van (4) by hose (9), and on hose (9) It is equipped with the first valve (5), the inside of sealing empty van (4) is fixedly installed with transparent glass graduated cylinder (17), and the sealing is empty Stirring motor (15) are installed at the top of case (4).
5. a kind of method for monitoring the contaminated degree of fully-loaded stream according to claim 4, it is characterised in that:It is described to stir Mixing leaf (24) is straight leaf or helical-blade.
6. a kind of method for monitoring the contaminated degree of fully-loaded stream according to claim 4 or 5, it is characterised in that:Institute The bottom for stating sealing empty van (4) is fixedly connected with supporting leg (18), and the lower central of the transparent glass graduated cylinder (17), which is communicated with, passes through It is through at the scum pipe (19) of sealing empty van (4), and the second valve (20) are installed on scum pipe (19).
7. a kind of method of the contaminated degree of monitoring fully-loaded stream according to claim 4-6, it is characterised in that:It is described The lower part of stirring motor (15) is fixedly installed with shock-absorbing motor pedestal (16), and the shock-absorbing motor pedestal (16) is elastic rubber bottom Seat.
8. a kind of method of the contaminated degree of monitoring fully-loaded stream according to claim 4-6, it is characterised in that:It is described Raised (10) are fixedly connected on the upper end side wall of drinking-water pipe (12).
9. a kind of method for monitoring the contaminated degree of fully-loaded stream according to claim 4, it is characterised in that:It is described The surface of vertical bar (7) offers the scale for fathoming.
CN201810792495.4A 2018-07-18 2018-07-18 A method of the monitoring contaminated degree of fully-loaded stream Pending CN108896349A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810792495.4A CN108896349A (en) 2018-07-18 2018-07-18 A method of the monitoring contaminated degree of fully-loaded stream

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810792495.4A CN108896349A (en) 2018-07-18 2018-07-18 A method of the monitoring contaminated degree of fully-loaded stream

Publications (1)

Publication Number Publication Date
CN108896349A true CN108896349A (en) 2018-11-27

Family

ID=64350824

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810792495.4A Pending CN108896349A (en) 2018-07-18 2018-07-18 A method of the monitoring contaminated degree of fully-loaded stream

Country Status (1)

Country Link
CN (1) CN108896349A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110987919A (en) * 2019-12-23 2020-04-10 武汉俊德环保科技发展有限公司 Detection method of heavy metal ions in water
CN111649988A (en) * 2020-07-01 2020-09-11 四川欣洋远锦环保科技有限公司 Intermittent water quality acquisition device for water quality monitoring
CN112326351A (en) * 2020-11-03 2021-02-05 义乌市排水有限公司 Method for monitoring water quality and water quantity of sewage pipeline
CN112665925A (en) * 2021-01-14 2021-04-16 江苏纳盛科技有限公司 Equipment and method for treating turbidity in water
CN113916602A (en) * 2021-12-14 2022-01-11 四川清和科技有限公司 Water quality sampling device
CN114088649A (en) * 2022-01-19 2022-02-25 江苏太川环境科技有限公司 Water quality monitoring device for preventing sample crosstalk and detection method
CN114200095A (en) * 2021-11-09 2022-03-18 卢莹 Water quality detector
CN114705834A (en) * 2022-03-31 2022-07-05 安徽理工大学 Indoor test system for simulating gas lift reverse circulation slurry suspension slag discharge and test method thereof

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201191269Y (en) * 2008-05-18 2009-02-04 锦州华冠环境科技实业公司 Chemical oxygen demand water quality on-line automatic monitoring instrument
CN202648998U (en) * 2012-07-07 2013-01-02 西安洛克仪器设备有限公司 Sediment-containing water automatic monitoring preprocessing device
CN203376184U (en) * 2013-08-14 2014-01-01 中国科学院南京地理与湖泊研究所 Water layering synchronous automatic sampling device
CN203869908U (en) * 2013-12-21 2014-10-08 广东省水利水电科学研究院 Multipoint layered synchronous water sample acquisition device for deep water
CN104596801A (en) * 2015-01-27 2015-05-06 河海大学 River and lake layered synchronous rapid water collection device
CN205749008U (en) * 2016-05-23 2016-11-30 中国环境科学研究院 A kind of multi-cavity Sewage Sampler for sewage detection
CN206177640U (en) * 2016-11-17 2017-05-17 张悦 Environmental monitoring is with dirty water sampler
CN106932297A (en) * 2017-03-13 2017-07-07 北京林业大学 Sediment charge automatic measurement system in a kind of runoff
CN206618597U (en) * 2017-03-21 2017-11-07 福建师范大学 A kind of float type water qi leel layer synchronized sampling unit
CN206818472U (en) * 2017-05-02 2017-12-29 北京市格雷斯普科技开发公司 A kind of layered water sample synchronous sampler
CN206891782U (en) * 2017-06-30 2018-01-16 陕西职业技术学院 A kind of environmental project water sampling apparatus for demonstrating
CN108020443A (en) * 2016-11-02 2018-05-11 郑州富铭环保科技有限公司 A kind of sampling apparatus for water quality online analyzer measure equal proportion mixed sample

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201191269Y (en) * 2008-05-18 2009-02-04 锦州华冠环境科技实业公司 Chemical oxygen demand water quality on-line automatic monitoring instrument
CN202648998U (en) * 2012-07-07 2013-01-02 西安洛克仪器设备有限公司 Sediment-containing water automatic monitoring preprocessing device
CN203376184U (en) * 2013-08-14 2014-01-01 中国科学院南京地理与湖泊研究所 Water layering synchronous automatic sampling device
CN203869908U (en) * 2013-12-21 2014-10-08 广东省水利水电科学研究院 Multipoint layered synchronous water sample acquisition device for deep water
CN104596801A (en) * 2015-01-27 2015-05-06 河海大学 River and lake layered synchronous rapid water collection device
CN205749008U (en) * 2016-05-23 2016-11-30 中国环境科学研究院 A kind of multi-cavity Sewage Sampler for sewage detection
CN108020443A (en) * 2016-11-02 2018-05-11 郑州富铭环保科技有限公司 A kind of sampling apparatus for water quality online analyzer measure equal proportion mixed sample
CN206177640U (en) * 2016-11-17 2017-05-17 张悦 Environmental monitoring is with dirty water sampler
CN106932297A (en) * 2017-03-13 2017-07-07 北京林业大学 Sediment charge automatic measurement system in a kind of runoff
CN206618597U (en) * 2017-03-21 2017-11-07 福建师范大学 A kind of float type water qi leel layer synchronized sampling unit
CN206818472U (en) * 2017-05-02 2017-12-29 北京市格雷斯普科技开发公司 A kind of layered water sample synchronous sampler
CN206891782U (en) * 2017-06-30 2018-01-16 陕西职业技术学院 A kind of environmental project water sampling apparatus for demonstrating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
司毅铭 等: "黄河泥沙对水中有机污染物测定的影响研究", 《人民黄河》 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110987919A (en) * 2019-12-23 2020-04-10 武汉俊德环保科技发展有限公司 Detection method of heavy metal ions in water
CN111649988A (en) * 2020-07-01 2020-09-11 四川欣洋远锦环保科技有限公司 Intermittent water quality acquisition device for water quality monitoring
CN112326351A (en) * 2020-11-03 2021-02-05 义乌市排水有限公司 Method for monitoring water quality and water quantity of sewage pipeline
CN112665925A (en) * 2021-01-14 2021-04-16 江苏纳盛科技有限公司 Equipment and method for treating turbidity in water
CN112665925B (en) * 2021-01-14 2022-08-12 江苏纳盛科技有限公司 Equipment and method for treating turbidity in water
CN114200095A (en) * 2021-11-09 2022-03-18 卢莹 Water quality detector
CN113916602A (en) * 2021-12-14 2022-01-11 四川清和科技有限公司 Water quality sampling device
CN113916602B (en) * 2021-12-14 2022-03-01 四川清和科技有限公司 Water quality sampling device
CN114088649A (en) * 2022-01-19 2022-02-25 江苏太川环境科技有限公司 Water quality monitoring device for preventing sample crosstalk and detection method
CN114705834A (en) * 2022-03-31 2022-07-05 安徽理工大学 Indoor test system for simulating gas lift reverse circulation slurry suspension slag discharge and test method thereof
CN114705834B (en) * 2022-03-31 2023-08-18 安徽理工大学 Simulated gas lift reverse circulation slurry suspension deslagging indoor test system and test method thereof

Similar Documents

Publication Publication Date Title
CN108896349A (en) A method of the monitoring contaminated degree of fully-loaded stream
CN211626990U (en) Visual gasbag sampler of uncovered formula bamboo joint type
CN210604037U (en) Environment detection sampler
CN108195628A (en) A kind of pollution water quality sample devices
CN209311141U (en) Groundwater sampling detection device
CN104677802B (en) Multifunctional linkage device integrating sewage time-sharing sampling and permeation coefficient testing and working method of multifunctional linkage device
CN208193738U (en) A kind of Full Automatic Liquid liquid abstraction instrument analyzed for oils in seawater
CN110568139A (en) Water quality detection device
CN108362845A (en) The intellectualizing system of POPS substances in a kind of detection water
CN102175506B (en) Diluting device used for on-line water quality analysis
CN108132178B (en) Oil field injection water performance evaluation device and evaluation method
CN203350160U (en) permeation coefficient tester for pervious concrete
CN2924521Y (en) Oil total amount on-line monitoring instrument
CN110632267A (en) System and method for continuously measuring high-concentration sewage exceeding application range of online instrument
CN216847051U (en) Urban underground sewage detection sampling device for environmental monitoring
CN211527944U (en) Water quality monitoring preprocessing device and water quality monitoring system
CN213041575U (en) Sampling device for ocean water quality monitoring
CN212180797U (en) Online monitoring system for dissolved gas in oil
CN209992239U (en) Sample collecting device for determining apparent age of seawater by utilizing radioactive krypton isotope
CN204594853U (en) Integrate the multi-functional linkage that sewage timesharing sampling and coefficient of permeability are tested
CN107192786B (en) The enrichment preparation facilities and its method of gas in a kind of water body
CN219302430U (en) Water surface detector for water quality treatment
CN214374707U (en) Novel high chlorine waste water experiment device
CN205786332U (en) A kind of fluoride on-line computing model two valve pinch off type accurate measuring device
CN212904645U (en) Water resource pH value testing arrangement

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20181127