CN108893009A - A kind of high temperature resistance high heat conduction non-viscous paint and its preparation method and application - Google Patents
A kind of high temperature resistance high heat conduction non-viscous paint and its preparation method and application Download PDFInfo
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- CN108893009A CN108893009A CN201810820755.4A CN201810820755A CN108893009A CN 108893009 A CN108893009 A CN 108893009A CN 201810820755 A CN201810820755 A CN 201810820755A CN 108893009 A CN108893009 A CN 108893009A
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- heat conduction
- agent
- high temperature
- temperature resistance
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- 238000002360 preparation method Methods 0.000 title claims abstract description 18
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- 238000000576 coating method Methods 0.000 claims abstract description 30
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- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910003471 inorganic composite material Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/16—Homopolymers or copolymers of vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K2003/026—Phosphorus
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention proposes a kind of high temperature resistance high heat conduction non-viscous paints, are prepared by weight by following raw material：Aluminum oxide/100-120 parts of red phosphorus modified fluorin resin；50-70 parts of polyphenylene sulfide；Graphene 50-70 powder；30-50 parts of carbon fiber；40-70 parts of polylactic acid；20-30 parts of heat conduction inorganic filler；10-20 parts of coupling agent；20-30 parts of auxiliary agent；The auxiliary agent is made of levelling agent, defoaming agent, film forming agent, antioxidant, preservative and ceramic powder.High temperature resistance high heat conduction non-viscous paint raw material sources prepared by the present invention are wide, and production method is simply controllable, and the coating of preparation is used for a long time under 400-500 DEG C of high temperature, and performance is unaffected, is with a wide range of applications.
Description
Technical field
The present invention relates to high-molecular coating technical fields, and in particular to a kind of high temperature resistance high heat conduction non-viscous paint.
Background technique
Non-viscous paint, so that other materials are difficult to adhere on surface, is produced from it since it has low-down surface tension
Non-stick pan have since the advent of the world to people life bring great convenience.Non-stick pan is divided into aluminum pot, stainless steel according to substrate
Pot, iron pan.The characteristic of aluminum pot is that heat distribution is excellent, and heat-transfer effect is 16 times of stainless-steel pan, and pot body is lighter.But aluminum pot is not easy
Oil smoke is big when cleaning, is more with oil.The characteristic of stainless-steel pan is that heat distribution is bad, is also easy to produce heat build-up point and burning foods.Stainless steel
Pot pot body weight, not easy cleaning, with oil it is more when easily smolder.Iron-enamel pot heat distribution is bad, bottom of being easily burned.This kind of pot not easy cleaning,
Surface is easy breakage, and iron-based material is caused to get rusty.Iron pan heat distribution is bad, is also easy to produce heat build-up point and burning foods, pot body weight, no
Easy cleaning is easily got rusty, and with oil it is more when oil smoke it is big.Therefore, current coating non-stick pan is using aluminium or aluminium alloy as pot
Base, this is because the good heat conductivity of this metalloid.But the direct contacting foodstuff of aluminum products, how much will affect health.But
It is heat build-up point to be easy to cause, to cause to apply since the heat distribution using stainless-steel pan and iron pan as the non-stick pan of substrate is poor
Film rupture and burning foods, greatly reduce the service life of coating.
The non-stick pan of existing market mainstream is all the non-viscous paint for relying on surface and spraying a strata fluorine type resin, by it
The characteristic of strong-hydrophobicity and low-friction coefficient, to realize what food did not glued, it, which is able to satisfy really in people's cooking process, does not occur
Food glue pot requirement, but it there is also many defects.Be first polytetrafluorethylecoatings coatings intensity it is poor, be easy to fall off and
Damage, and can soften in cooking process, wood shovel can only be used, harder food can not be cooked；Meanwhile this non-stick pan
Also acidic food should not be cooked, otherwise will affect the service life of non-stick pan；Furthermore the use temperature one of polytetrafluorethylecoatings coatings
As no more than 250 DEG C, people are difficult to strict control when in use, are easy to damage because of dry combustion method.For polytetrafluorethylecoatings coatings
Non-stick pan also always exists dispute with the presence or absence of harm to human health in use, constantly initiation controversial issue；And once
Non-viscous paint falls off, and will lead to substantially reducing for non-adhesion behavior.
Polyphenylene sulfide (PPS) is a kind of fire resistant resin binder of excellent combination property.Its crystallinity is high, line expansion is
Number is low, at 170 DEG C or less insoluble in any solvent, and has many advantages, such as water imbibition and oil absorption is small, chemical resistance is good.
Chinese patent notification number CN103740192A discloses a kind of fluorine resin coating that graphene is modified, using graphene
The intensity of fluorine resin coating is improved, crocking resistance is significantly increased with the adhesive force of substrate, impact resistance, thermal conductivity,
The coating have it is at low cost, dosage is few, efficacy lasting, easy to use feature.Although disadvantage is that graphene
Addition can be improved into wear-resisting property and thermal conductivity, but high temperature resistant and thermal conductivity still are apparent not enough.
Therefore, need to develop a non-viscous paint required suitable for non-stick pan high temperature resistance high heat conduction to meet modern market
Requirement to the field.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of high temperature resistance high heat conduction non-viscous paint and preparation method thereof
And application passes through aluminum oxide/red phosphorus of addition preparation it is intended that providing a kind of high temperature resistance high heat conduction non-viscous paint
Modified fluorin resin can be used for a long time, performance is not so that coating has extraordinary high temperature resistance under 400-500 DEG C of high temperature
It is impacted；By adding inorganic Heat Conduction Material, so that non-viscous paint good heat conductivity, and have no toxic side effect.
The present invention provides a kind of high temperature resistance high heat conduction non-viscous paint, is prepared by weight by following raw material：
Aluminum oxide/100-120 parts of red phosphorus modified fluorin resin；
50-70 parts of polyphenylene sulfide；
Graphene 50-70 powder；
30-50 parts of carbon fiber；
40-70 parts of polylactic acid；
20-30 parts of heat conduction inorganic filler；
10-20 parts of coupling agent；
20-30 parts of auxiliary agent；
The auxiliary agent is made of levelling agent, defoaming agent, film forming agent, antioxidant, preservative and ceramic powder；
The aluminum oxide/red phosphorus modified fluorin resin is prepared by following methods：
The mixed solvent of dimethylformamide, dimethylbenzene composition is added in reaction kettle, fluororesin is added thereto, heats up
To 100-120 DEG C, a small amount of isobutanol is added as dispersing agent, in magnetic agitation after resin is completely dissolved in stirring 30min
On device it is fully dispersed after, lead to nitrogen protection, silane coupling agent DL171 and aluminum oxide, red phosphorus, insulated and stirred 60- be added
90min, filtering, ethanol washing, 60-70 DEG C vacuum drying to get；
The mass ratio of the fluororesin, aluminum oxide and red phosphorus is 10：(2-4)：(1-2).
As further improvement of the invention, it is prepared by weight by following raw material：
Aluminum oxide/112 parts of red phosphorus modified fluorin resin；
65 parts of polyphenylene sulfide；
61 powder of graphene；
45 parts of carbon fiber；
60 parts of polylactic acid；
27 parts of heat conduction inorganic filler；
15 parts of coupling agent；
24 parts of auxiliary agent.
As further improvement of the invention, non-viscous paint is in 400-500 DEG C of high temperatures.
As further improvement of the invention, coupling agent is selected from one of Aluminate, silane, boric acid ester coupler, excellent
Select silane coupling agent, the silane coupling agent be selected from gamma-aminopropyl-triethoxy-silane, γ-aminopropyltrimethoxysilane,
γ-(β-aminoethyl) aminopropyl trimethoxysilane, γ-(the third oxygen of 2,3- epoxy) propyl trimethoxy silicane, γ-(2,3- ring
The third oxygen of oxygen) propyl-triethoxysilicane, β-(3,4- epoxycyclohexyl) ethyl trimethoxy silane, γ-mercapto propyl trimethoxy
One or more of silane, gamma-mercaptopropyltriethoxysilane.
As further improvement of the invention, auxiliary agent is composed of following raw material according to mass percent：Levelling agent
22%, defoaming agent 13%, film forming agent 15%, antioxidant 15%, preservative 20% and ceramic powder 10%；
It is modified that the levelling agent is selected from polyacrylic acid, carboxymethyl cellulose, dimethyl silicone polymer, silicone oil or polyether polyester
One or more of organosiloxane；
The defoaming agent is selected from silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite
Ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether, dimethyl silicone polymer
One or more of；
The film forming agent be selected from the modified casein of acrylic resin, acrylic resin polyurethane copolymerization resin, polyethylene or
One or more of acrylate modified butadiene resin, polyurethane-modified cellulose nitrate；
The antioxidant be selected from diphenylamines, p-phenylenediamine, dihydroquinoline, 2,6- three-level butyl -4- methylphenol, it is bis- (3,
5- three-level butyl -4- hydroxy phenyl) thioether, four (β-(3,5- three-level butyl -4- hydroxy phenyl) propionic acid) pentaerythritol esters, double ten
Two carbon alcohol esters, bi-myristoleyl, double octadecanol esters, three monooctyl esters, three last of the ten Heavenly stems esters, three (Lauryl Alcohol) esters and three (16 carbon alcohol)
One or more of ester；
The preservative is selected from potassium sorbate, sorbic acid, deoxidation acetic acid, deoxidation sodium acetate, methyl p-hydroxybenzoate, right
Nipagin A, propylparaben, butyl p-hydroxybenzoate, sodium Diacetate, calcium propionate, one in sodium lactate
Kind is several.
As further improvement of the invention, heat conduction inorganic filler is selected from zinc oxide, aluminum oxide, magnesia, dioxy
One or more of SiClx, beryllium oxide, boron nitride, silicon carbide, silicon nitride.
As further improvement of the invention, the fluororesin is selected from polytetrafluoroethylene (PTFE), polytrifluorochloroethylene, polyvinylidene fluoride
One or more of alkene, ethylene-tetrafluoroethylene copolymer, ethylene-chlorotrifluoro-ethylene copolymer, polyvinyl fluoride.
The present invention further protects a kind of preparation method of above-mentioned high temperature resistance high heat conduction non-viscous paint, makes in accordance with the following methods
It is standby：Aluminum oxide/red phosphorus modified fluorin resin, polyphenylene sulfide and polylactic acid is added in organic solvent, ultrasonic disperse machine point
30min is dissipated, it is made to be uniformly dispersed, heat conduction inorganic filler, graphene, carbon fiber and auxiliary agent, re-ultrasonic dispersion 30min is added and adds
Enter coupling agent, magnetic agitation 30min is after being heated to 100 DEG C up to coating finished product.
The present invention further protects a kind of application of above-mentioned high temperature resistance high heat conduction non-viscous paint, and the coating finished product is sprayed
Onto the metal material for having been subjected to degreasing and rust removal, 16-17 μm of the thickness of paint film, room temperature 10 days, up to not after paint film is dry
Adhesive coating layer.
As further improvement of the invention, anti-stick coating hardness is 4HV, and adhesive force is 1 grade.
The present invention has the advantages that：
1. aluminum oxide prepared by the present invention/red phosphorus modified fluorin resin, by inorganic composite materials aluminum oxide/red
The modification of phosphorus can be used for a long time, performance is not so that fluororesin has extraordinary high temperature resistance under 400-500 DEG C of high temperature
It is impacted；
2. the present invention adds inorganic Heat Conduction Material graphene, carbon fiber and heat conduction inorganic filler, so that preparation is not glued
Coating heat transfer performance is good, and has no toxic side effect；
3. raw material sources of the present invention are wide, production method is simply controllable, it is easy to accomplish industrial applications.
Detailed description of the invention
Fig. 1 is the preparation technology figure of high temperature resistance high heat conduction non-viscous paint.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, the embodiment described is the embodiment of part of representative of the invention, rather than whole embodiments, this field are general
Other all embodiments obtained belong to protection of the invention to logical technical staff without making creative work
Range.
The preparation of 1 high temperature resistance high heat conduction non-viscous paint of embodiment
Raw material composition：
Aluminum oxide/100 parts of red phosphorus modified fluorin resin；
50 parts of polyphenylene sulfide；
50 powder of graphene；
30 parts of carbon fiber；
40 parts of polylactic acid；
10 parts of boron nitride, 10 parts of silicon carbide；
10 parts of γ-mercaptopropyl trimethoxysilane；
20 parts of auxiliary agent；
The auxiliary agent is composed of following raw material according to mass percent：Polyether polyester azo polyether polyeste 22%,
Polypropylene glycerol aether 13%, (β-(3, the 5- three-level butyl -4- hydroxy benzenes of acrylic resin polyurethane copolymerization resin 15%, four
Base) propionic acid) pentaerythritol ester 15%, propylparaben 20% and ceramic powder 10%.
Aluminum oxide/red phosphorus modified fluorin resin is prepared by following methods：
The mixed solvent of dimethylformamide, dimethylbenzene composition is added in reaction kettle, 100g fluororesin is added thereto,
100 DEG C are warming up to, a small amount of isobutanol is added as dispersing agent, in magnetic agitation after resin is completely dissolved in stirring 30min
On device it is fully dispersed after, lead to nitrogen protection, be added silane coupling agent DL171 and 20g aluminum oxide, 10g red phosphorus, insulated and stirred
60min, filtering, ethanol washing, 60 DEG C vacuum drying to get.
The preparation of high temperature resistance high heat conduction non-viscous paint：By aluminum oxide/red phosphorus modified fluorin resin, polyphenylene sulfide and poly- cream
Acid is added in organic solvent, and ultrasonic disperse machine disperses 30min, so that it is uniformly dispersed, thermally conductive boron nitride, silicon carbide, stone is added
γ-mercaptopropyl trimethoxysilane, magnetic force after being heated to 100 DEG C is added in black alkene, carbon fiber and auxiliary agent, re-ultrasonic dispersion 30min
30min is stirred up to coating finished product.
The coating finished product is sprayed on the metal material for having been subjected to degreasing and rust removal, 16 μm of the thickness of paint film, room temperature is put
It sets 10 days, up to non-sticking lining after paint film is dry.
The preparation of 2 high temperature resistance high heat conduction non-viscous paint of embodiment
Raw material composition：
Aluminum oxide/120 parts of red phosphorus modified fluorin resin；
70 parts of polyphenylene sulfide；
70 powder of graphene；
50 parts of carbon fiber；
70 parts of polylactic acid；
30 parts of silica；
20 parts of gamma-aminopropyl-triethoxy-silane；
30 parts of auxiliary agent；
The auxiliary agent is composed of following raw material according to mass percent：Polyether polyester azo polyether polyeste 22%,
Polypropylene glycerol aether 13%, polyurethane-modified cellulose nitrate 15%, double octadecanol esters 15%, propylparaben
20% and ceramic powder 10%.
Aluminum oxide/red phosphorus modified fluorin resin is prepared by following methods：
The mixed solvent of dimethylformamide, dimethylbenzene composition is added in reaction kettle, 100g Kynoar is added
Wherein, it is warming up to 120 DEG C, stirs 30min, after Kynoar is completely dissolved, a small amount of isobutanol is added as dispersing agent,
On magnetic stirring apparatus it is fully dispersed after, lead to nitrogen protection, it is red that silane coupling agent DL171 and 40g aluminum oxide, 20g be added
Phosphorus, insulated and stirred 90min, filtering, ethanol washing, 70 DEG C vacuum drying to get.
The preparation of high temperature resistance high heat conduction non-viscous paint：By aluminum oxide/red phosphorus modified fluorin resin, polyphenylene sulfide and poly- cream
Acid is added in organic solvent, ultrasonic disperse machine disperse 30min, so that it is uniformly dispersed, be added thermally conductive silica, graphene,
Gamma-aminopropyl-triethoxy-silane, magnetic agitation after being heated to 100 DEG C is added in carbon fiber and auxiliary agent, re-ultrasonic dispersion 30min
30min is up to coating finished product.
The coating finished product is sprayed on the metal material for having been subjected to degreasing and rust removal, 17 μm of the thickness of paint film, room temperature is put
It sets 10 days, up to non-sticking lining after paint film is dry.
The preparation of 3 high temperature resistance high heat conduction non-viscous paint of embodiment
Raw material composition：
Aluminum oxide/112 parts of red phosphorus modified fluorin resin；
65 parts of polyphenylene sulfide；
61 powder of graphene；
45 parts of carbon fiber；
60 parts of polylactic acid；
12 parts of zinc oxide 15, aluminum oxide；
15 parts of propyl trimethoxy silicane of γ-(the third oxygen of 2,3- epoxy)；
24 parts of auxiliary agent；
The auxiliary agent is composed of following raw material according to mass percent：Polyacrylic acid 22%, silicone emulsion 13%, third
The ester modified butadiene resin 15% of olefin(e) acid, bis- (3,5- three-level butyl -4- hydroxy phenyl) thioethers 15%, potassium sorbate 10%, mountain
Pears acid 10% and ceramic powder 10%.
Aluminum oxide/red phosphorus modified fluorin resin is prepared by following methods：
The mixed solvent of dimethylformamide, dimethylbenzene composition is added in reaction kettle, it is added in 100g tetrafluoroethene
In, 110 DEG C are warming up to, a small amount of isobutanol is added as dispersing agent, in magnetic after tetrafluoroethene is completely dissolved in stirring 30min
On power blender it is fully dispersed after, lead to nitrogen protection, be added silane coupling agent DL171 and 30g aluminum oxide, 15g red phosphorus, protect
Temperature stirring 70min, filtering, ethanol washing, 65 DEG C vacuum drying to get.
The preparation of high temperature resistance high heat conduction non-viscous paint：By aluminum oxide/red phosphorus modified fluorin resin, polyphenylene sulfide and poly- cream
Acid is added in organic solvent, and ultrasonic disperse machine disperses 30min, it is made to be uniformly dispersed, and zinc oxide, aluminum oxide, stone is added
γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, heating is added in black alkene, carbon fiber and auxiliary agent, re-ultrasonic dispersion 30min
Magnetic agitation 30min is after to 100 DEG C up to coating finished product.
The coating finished product is sprayed on the metal material for having been subjected to degreasing and rust removal, 16 μm of the thickness of paint film, room temperature is put
It sets 10 days, up to non-sticking lining after paint film is dry.
Reference examples 1 are prepared according to the method for patent ZL 201610035103.0 " high thermal conductivity high abrasion non-viscous paint " a kind of
(1) preparation of sulfonated polyether-ether-ketone
By 10g polyether-ether-ketone, 10g chlorosulfonic acid is uniformly mixed, and is warming up to 120 DEG C, and after reacting 72h, it is cold to pour into 5 DEG C of 100g
1h is stood in water, makes to be washed with distilled water to washing lotion pH 6~7, obtains sulphur after 50 DEG C of vacuum drying in a vacuum drying oven
Change polyether-ether-ketone.
(2) preparation of non-viscous paint
Silicon carbide 5g, carbon black 5g, dispersing agent 1g, defoaming agent 0.5g, graphene 1g, deionized water 11g, NMP1g are mixed
SPEEK10g, PTFE emulsion 40g, PES resin 20g, thickener prepared by step 1) is added after being ground to required partial size after uniformly
0.5g, AMP-95 (pH adjusting agent) 5g is uniformly mixing to obtain a kind of high thermal conductivity high abrasion non-viscous paint.
(3) it is sprayed into stainless steel ground
Wear-resisting scratch-resistant long-life non-viscous paint is sprayed at the stainless steel surface through blasting treatment, the thickness of coating with spray gun
Control is at 30 μm, and the coating sprayed is through 100 DEG C of dry 40min, then in 410 DEG C of plasticizing 40min.
1 performance test of test case
1-3 of the embodiment of the present invention high temperature resistance high heat conduction non-viscous paint prepared and reference examples 1 are prepared into high thermal conductivity high abrasion
Non-viscous paint is applied to as required on stainless steel ground, and combines commercially available stainless non-stick pan, tests its performance.
Friction and wear behavior is tested with MHK-500A type testing machine, and experimental condition is：Load 312N, speed 2.5m/s, with
Coating by it is completely worn out be standard, (the friction stroke table that abrasion unit film thickness is born is calculated by formula in friction factor
Show)；The adhesive force of coating is measured with Q65-67 type adherometer；The 0153-3K1 type impact resistance of the impact resistant strength of coating
Exerciser measurement；Film flexibility is measured with QTX-1 type flexibility test device；The antistick characteristic of coating is connect by drip method with CA-A type
Feeler meter measures；Vickers hardness is measured with HD-G803-4HV-10Z automatic turret Vickers, within 120kg
The rectangular cone injector of diamond that load and apex angle are 136 ° is pressed into material surface, with the surface area of material impression pit divided by load
Charge values；Thermal conductivity is tested with 1800 Conduction Coefficient Detector Basing of ZH.Unless otherwise indicated, the performance test sample of coating is using spray
The stainless steel ground of sand processing.
Test result is shown in Table 1.
1 each group test result table of table
As seen from the above table, coating obtained by the high temperature resistance high heat conduction non-viscous paint of 1-3 of embodiment of the present invention preparation is compared to control
Example and commercially available non-stick pan coating layer have more preferably high temperature resistant, wear-resisting, high thermal conductivity and mechanical property：Wearability (830-860m/ μ
M), form a film smooth, adhesion 1 grade, impact strength (82-85kgcm), thermal conductivity (1890-1920W/mK) and hardness 4HV.
Therefore, there are preferable market prospects.
Those skilled in the art is not under conditions of departing from the spirit and scope of the present invention that claims determine, also
Various modifications can be carried out to the above content.Therefore the scope of the present invention is not limited in above explanation, but by
The range of claims determines.
Claims (10)
1. a kind of high temperature resistance high heat conduction non-viscous paint, which is characterized in that be prepared by weight by following raw material：
Aluminum oxide/100-120 parts of red phosphorus modified fluorin resin；
50-70 parts of polyphenylene sulfide；
Graphene 50-70 powder；
30-50 parts of carbon fiber；
40-70 parts of polylactic acid；
20-30 parts of heat conduction inorganic filler；
10-20 parts of coupling agent；
20-30 parts of auxiliary agent；
The auxiliary agent is made of levelling agent, defoaming agent, film forming agent, antioxidant, preservative and ceramic powder；
The aluminum oxide/red phosphorus modified fluorin resin is prepared by following methods：
The mixed solvent of dimethylformamide, dimethylbenzene composition is added in reaction kettle, fluororesin is added thereto, is warming up to
100-120 DEG C, a small amount of isobutanol is added as dispersing agent, in magnetic stirring apparatus after resin is completely dissolved in stirring 30min
It is upper it is fully dispersed after, lead to nitrogen protection, silane coupling agent DL171 and aluminum oxide, red phosphorus, insulated and stirred 60- be added
90min, filtering, ethanol washing, 60-70 DEG C vacuum drying to get；
The mass ratio of the fluororesin, aluminum oxide and red phosphorus is 10：(2-4)：(1-2).
2. a kind of high temperature resistance high heat conduction non-viscous paint according to claim 1, which is characterized in that by weight by following raw material
It is prepared：
Aluminum oxide/112 parts of red phosphorus modified fluorin resin；
65 parts of polyphenylene sulfide；
61 powder of graphene；
45 parts of carbon fiber；
60 parts of polylactic acid；
27 parts of heat conduction inorganic filler；
15 parts of coupling agent；
24 parts of auxiliary agent.
3. a kind of high temperature resistance high heat conduction non-viscous paint according to claim 1, which is characterized in that the non-viscous paint is in 400-
500 DEG C of high temperatures.
4. a kind of high temperature resistance high heat conduction non-viscous paint according to claim 1, which is characterized in that the coupling agent is selected from aluminic acid
One of ester, silane, boric acid ester coupler, preferably silane coupling agent, the silane coupling agent are selected from three ethoxy of γ-aminopropyl
Base silane, γ-aminopropyltrimethoxysilane, γ-(β-aminoethyl) aminopropyl trimethoxysilane, γ-(2,3- epoxy third
Oxygen) propyl trimethoxy silicane, γ-(2,3- the third oxygen of epoxy) propyl-triethoxysilicane, β-(3,4- epoxycyclohexyl) ethyl
One or more of trimethoxy silane, γ-mercaptopropyl trimethoxysilane, gamma-mercaptopropyltriethoxysilane.
5. a kind of high temperature resistance high heat conduction non-viscous paint according to claim 1, which is characterized in that the auxiliary agent is by following raw material
It is composed according to mass percent：Levelling agent 22%, defoaming agent 13%, film forming agent 15%, antioxidant 15%, preservative 20%
With ceramic powder 10%；
It is organic that the levelling agent is selected from polyacrylic acid, carboxymethyl cellulose, dimethyl silicone polymer, silicone oil or polyether polyester modification
One or more of siloxanes；
The defoaming agent is selected from silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, gathers
Ethylene oxide polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether, in dimethyl silicone polymer
It is one or more of；
The film forming agent is selected from the modified casein of acrylic resin, acrylic resin polyurethane copolymerization resin, polyethylene or propylene
One or more of acid esters modified butadiene resin, polyurethane-modified cellulose nitrate；
The antioxidant is selected from diphenylamines, p-phenylenediamine, dihydroquinoline, 2,6- three-level butyl -4- methylphenol, bis- (3,5- tri-
Grade butyl -4- hydroxy phenyl) thioether, four (β-(3,5- three-level butyl -4- hydroxy phenyl) propionic acid) pentaerythritol esters, double 12 carbon
In alcohol ester, bi-myristoleyl, double octadecanol esters, three monooctyl esters, three last of the ten Heavenly stems esters, three (Lauryl Alcohol) esters and three (16 carbon alcohol) esters
One or more；
The preservative be selected from potassium sorbate, sorbic acid, deoxidation acetic acid, deoxidation sodium acetate, methyl p-hydroxybenzoate, to hydroxyl
One of ethyl benzoate, propylparaben, butyl p-hydroxybenzoate, sodium Diacetate, calcium propionate, sodium lactate or
It is several.
6. a kind of high temperature resistance high heat conduction non-viscous paint according to claim 1, which is characterized in that the heat conduction inorganic filler choosing
One of autoxidation zinc, aluminum oxide, magnesia, silica, beryllium oxide, boron nitride, silicon carbide, silicon nitride are several
Kind.
7. a kind of high temperature resistance high heat conduction non-viscous paint according to claim 1, which is characterized in that the fluororesin is selected from
Polytetrafluoroethylene (PTFE), polytrifluorochloroethylene, Kynoar, ethylene-tetrafluoroethylene copolymer, ethylene-chlorotrifluoro-ethylene copolymer,
One or more of polyvinyl fluoride.
8. a kind of preparation method of high temperature resistance high heat conduction non-viscous paint described in -7 any claims according to claim 1, special
Sign is, prepares in accordance with the following methods：Aluminum oxide/red phosphorus modified fluorin resin, polyphenylene sulfide and polylactic acid has been added to
In solvent, ultrasonic disperse machine disperses 30min, it is made to be uniformly dispersed, and heat conduction inorganic filler, graphene, carbon fiber is added and helps
Coupling agent is added in agent, re-ultrasonic dispersion 30min, and magnetic agitation 30min is after being heated to 100 DEG C up to coating finished product.
9. a kind of application of high temperature resistance high heat conduction non-viscous paint, feature described in -7 any claims exist according to claim 1
In the coating finished product being sprayed on the metal material for having been subjected to degreasing and rust removal, 16-17 μm of the thickness of paint film, room temperature
10 days, up to non-sticking lining after paint film is dry.
10. a kind of application of high temperature resistance high heat conduction non-viscous paint according to claim 9, which is characterized in that the anti-snearing
Layer hardness is 4HV, and adhesive force is 1 grade.
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| CN109749404A (en) * | 2019-01-12 | 2019-05-14 | 莫爱军 | A kind of high-temperature stability electronic packaging composite material of high heat conductance and preparation method thereof |
| CN109836965A (en) * | 2018-12-27 | 2019-06-04 | 宁波中一石化科技股份有限公司 | Thermostable heat-conductive coating and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003183408A (en) * | 2002-10-22 | 2003-07-03 | Du Pont Mitsui Fluorochem Co Ltd | Fluororesin powder composition for powder processing |
| CN102876040A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | Polyphenylene sulfide composite material and preparation method thereof |
| CN105733376A (en) * | 2016-02-23 | 2016-07-06 | 广东四方威凯新材料有限公司 | Weather-proof, halogen-free, flame-retardant, anti-corrosion and insulating fluorine-carbon coating |
| CN106189561A (en) * | 2016-09-09 | 2016-12-07 | 朱燕华 | A kind of enviroment protective ceramic coating material of faucet |
| CN108178992A (en) * | 2018-01-25 | 2018-06-19 | 宁波蒙曼生物科技有限公司 | A kind of composition for being used to prepare anticorrosive heat insulating automobile adhesive film and preparation method thereof |
-
2018
- 2018-07-24 CN CN201810820755.4A patent/CN108893009B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003183408A (en) * | 2002-10-22 | 2003-07-03 | Du Pont Mitsui Fluorochem Co Ltd | Fluororesin powder composition for powder processing |
| CN102876040A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | Polyphenylene sulfide composite material and preparation method thereof |
| CN105733376A (en) * | 2016-02-23 | 2016-07-06 | 广东四方威凯新材料有限公司 | Weather-proof, halogen-free, flame-retardant, anti-corrosion and insulating fluorine-carbon coating |
| CN106189561A (en) * | 2016-09-09 | 2016-12-07 | 朱燕华 | A kind of enviroment protective ceramic coating material of faucet |
| CN108178992A (en) * | 2018-01-25 | 2018-06-19 | 宁波蒙曼生物科技有限公司 | A kind of composition for being used to prepare anticorrosive heat insulating automobile adhesive film and preparation method thereof |
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| CN109336542A (en) * | 2018-12-12 | 2019-02-15 | 重庆科恒建材集团有限公司 | A kind of heat-conductive coating and preparation method for floor heating module radiating surface |
| CN109336542B (en) * | 2018-12-12 | 2021-06-04 | 重庆科恒建材集团有限公司 | Heat-conducting coating for heat dissipation surface of floor heating module and preparation method thereof |
| CN109836965A (en) * | 2018-12-27 | 2019-06-04 | 宁波中一石化科技股份有限公司 | Thermostable heat-conductive coating and preparation method thereof |
| CN109749404A (en) * | 2019-01-12 | 2019-05-14 | 莫爱军 | A kind of high-temperature stability electronic packaging composite material of high heat conductance and preparation method thereof |
| CN110264863A (en) * | 2019-07-13 | 2019-09-20 | 广州彩邦印刷有限公司 | Wear-resisting label |
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| CN110916512A (en) * | 2019-11-25 | 2020-03-27 | 西安和光明宸科技有限公司 | Antiseized steamer |
| CN110980043A (en) * | 2019-11-25 | 2020-04-10 | 西安和光明宸科技有限公司 | Garbage can |
| CN110903715A (en) * | 2019-12-04 | 2020-03-24 | 齐耐润工业设备（上海）有限公司 | Protective coating for sealing element and preparation method thereof |
| CN114539856A (en) * | 2020-11-27 | 2022-05-27 | 无锡康庭氟塑材料科技有限公司 | Non-stick coating and preparation method and application thereof |
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| CN116285606A (en) * | 2023-01-07 | 2023-06-23 | 河北悠扬时代环保科技有限公司 | Water-based anticorrosive paint for welding points and preparation method thereof |
| CN115975500A (en) * | 2023-03-16 | 2023-04-18 | 浙江德力装备有限公司 | Insulating high-thermal-conductivity anticorrosive coating and preparation method thereof |
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