CN108892933A - It is a kind of for manufacturing the material of degradable bionic fish bait - Google Patents
It is a kind of for manufacturing the material of degradable bionic fish bait Download PDFInfo
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- CN108892933A CN108892933A CN201810630264.3A CN201810630264A CN108892933A CN 108892933 A CN108892933 A CN 108892933A CN 201810630264 A CN201810630264 A CN 201810630264A CN 108892933 A CN108892933 A CN 108892933A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Fodder In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
The invention discloses a kind of for manufacturing the material of degradable bionic fish bait, is made of following substance：Polydactyl acid, toughener, nanometer calcium carbonate, phagostimulant, pigment, antioxidant, ultraviolet absorbing agent, lubricant.The reasonably combined plurality of raw materials ingredient of the present invention, the enhancing for effectively realizing material property improves, significantly improve temperature tolerance, the machinability of material, and mechanical strength characteristics, and then realize bionic fish bait life-time dilatation and the enhancing using quality, the great market competitiveness and application value.
Description
Technical field
The invention belongs to bionic fish bait working process technical fields, and in particular to one kind is for manufacturing degradable bionic fish bait
Material.
Background technique
It is well known that fishing with the raising of people's economic level as the deep happiness by modern people of an outdoor activities
Love.Fishing has Biomimetic Fish true to nature, shrimp, worm and other effects with bionic fish bait prepared by plastics, while can be used for a long time, without changing
The features such as bait, is widely used in the fan that fishes.However common plastics bionic fish bait is mostly with nondegradable plastics system
It is standby to form, such as use PVC, PE, PC, ABS plastics.The bionic fish bait of this kind of plastics preparation, which once falls off, falls into ocean, up to a hundred
Year can not all degrade, and can cause great harm to marine organisms and ecological environment.Polylactic acid（PLA）It is to be formed sediment by being extracted in plant
Powder, the fermented biodegradated polymer materal at lactic acid, being further polymerized, polylactic acid have excellent molding processibility
Energy.With poly-lactic acid material prepare bionic fish bait fall off fall into ocean when, can under the microbial action of nature completely
It is degraded to H2O and CO2, any harm will not be brought to the marine eco-environment.But poly-lactic acid material brittleness is big, thermo-labile（55℃
Deform）, not modified to be unfavorable for processing and forming.
Patent CN104497509A provides a kind of bionic fish bait that can be degraded, and is made of poly-lactic acid material, in order to mention
The toughness of high poly-lactic acid material, while polycaprolactone and TPEE thermoplastic elastomer (TPE) are also added in material.This method production
On the one hand bionic fish bait can make that the production cost increases due to added with this biodegradation material of polycaprolactone, on the other hand can be because
The complete biodegradable characteristic of polylactic acid is destroyed added with TPEE thermoplastic elastomer (TPE).
Summary of the invention
The purpose of the present invention is being directed to existing problem, provide a kind of for manufacturing the material of degradable bionic fish bait.
The present invention is achieved by the following technical solutions：
It is a kind of for manufacturing the material of degradable bionic fish bait, be made of the substance of following parts by weight：
100 ~ 110 parts of polydactyl acids, 8 ~ 12 parts of toughener, 3 ~ 5 parts of nanometer calcium carbonates, 0.5 ~ 1.5 part of phagostimulant, 1 ~ 2 part of face
Material, 0.2 ~ 0.4 part of antioxidant, 0.1 ~ 0.3 part of ultraviolet absorbing agent, 0.5 ~ 0.8 part of lubricant.
Preferably, it is made of the substance of following parts by weight：
105 parts of polydactyl acids, 10 parts of toughener, 4 parts of nanometer calcium carbonates, 1 part of phagostimulant, 1.5 parts of pigment, 0.3 part it is anti-oxidant
Agent, 0.2 part of ultraviolet absorbing agent, 0.7 part of lubricant.
Further, the toughener is methyl methacrylate-butadiene-styrene copolymer.
Further, the grain diameter of the nanometer calcium carbonate is 20 ~ 60nm.
Further, the phagostimulant be allicin, vanillic aldehyde, cumarin it is one or more.
Further, the antioxidant is antioxidant 1010.
Further, the ultraviolet absorbing agent is ultraviolet absorbent UV-531.
Further, the lubricant is polyethylene wax.
Further, the preparation method of the polydactyl acid includes the following steps：
（1）By terephthalic acid (TPA) and ethylene glycol according to molar ratio 1:1.2 ~ 1.6, which carry out mixing, puts into reaction kettle, and heating is kept
Temperature in reaction kettle is 190 ~ 220 DEG C, when being stirred continuously processing 50% or more degree to be esterified, then puts into it into reaction kettle
The modified solution of interior substance gross mass 25 ~ 30% when continuing stir process 90% or more degree to be esterified, is added antimony oxide and urges
Agent, and the temperature in reaction kettle is risen into 280 ~ 310 DEG C, while vacuumize process, taken out after 1.5 ~ 2h mixture is spare；
The modified solution by following parts by weight material composition：4 ~ 7 parts of ethyl orthosilicates, 15 ~ 20 parts of deionized waters, 30 ~ 35 parts of nothings
Water-ethanol, 0.1 ~ 0.2 part of ammonium hydroxide, 3 ~ 5 parts of corn fiber gums, 1 ~ 2 part of chitosan；
（2）By step（1）Mixture obtained is put into extruder, and extruding pelletization is carried out, after the completion up to polydactyl acid.
Further, nitrogen environment is remained before vacuumize process in the reaction kettle.
The present invention provides a kind of raw material of novel bionic fish bait manufacture, effectively improve existing poly-lactic acid material
Big, thermo-labile, not easy to be processed etc. the problem of brittleness is added to a kind of special polydactyl acid ingredient wherein preparing, be by
It is polylactic acid modified to form, its performance is changed, whole quality is enhanced.In the modification to polylactic acid, in its polymerization forming
It is added to modified solution in the process and is modified processing, this modified solution can generate nanometer silicon dioxide particle under the high temperature conditions
Ingredient, in the polymerization generating process of polylactic acid, effectively fixation grafts on polymer molecular chain nanometer silicon dioxide particle,
The enhancing to characteristics such as polylactic acid entirety heatproof, intensity is realized, the addition energy of corn fiber gum and chitosan in modified solution
It is enough further to promote the fixed stability of nanometer silicon dioxide particle grafting, the quality of material is finally improved well.
The present invention has the following advantages that compared with prior art：
The reasonably combined plurality of raw materials ingredient of the present invention, the enhancing for effectively realizing material property improve, hence it is evident that improve material
Temperature tolerance, machinability and the mechanical strength characteristics of material, and then realize bionic fish bait life-time dilatation and use quality
Enhancing, the great market competitiveness and application value.
Specific embodiment
Embodiment 1
It is a kind of for manufacturing the material of degradable bionic fish bait, be made of the substance of following parts by weight：
100 parts of polydactyl acids, 8 parts of toughener, 3 parts of nanometer calcium carbonates, 0.5 part of phagostimulant, 1 part of pigment, 0.2 part it is anti-oxidant
Agent, 0.1 part of ultraviolet absorbing agent, 0.5 part of lubricant.
Further, the toughener is methyl methacrylate-butadiene-styrene copolymer.
Further, the grain diameter of the nanometer calcium carbonate is 20 ~ 60nm.
Further, the phagostimulant is allicin.
Further, the antioxidant is antioxidant 1010.
Further, the ultraviolet absorbing agent is ultraviolet absorbent UV-531.
Further, the lubricant is polyethylene wax.
Further, the preparation method of the polydactyl acid includes the following steps：
（1）By terephthalic acid (TPA) and ethylene glycol according to molar ratio 1:1.2, which carry out mixing, puts into reaction kettle, and heating keeps reaction
Temperature in kettle is 190 DEG C, is stirred continuously when handling 50% or more degree to be esterified, then to put into reaction kettle substance in it total
When continuing stir process 90% or more degree to be esterified, antimony oxide catalyst is added, and will be anti-in the modified solution of quality 25%
Answer the temperature in kettle to rise to 280 DEG C, while vacuumize process, taken out after 1.5h mixture is spare；The modified solution is by such as
The material composition of lower parts by weight：4 parts of ethyl orthosilicates, 15 parts of deionized waters, 30 parts of dehydrated alcohols, 0.1 part of ammonium hydroxide, 3 parts of corns
Viscose, 1 part of chitosan；
（2）By step（1）Mixture obtained is put into extruder, and extruding pelletization is carried out, after the completion up to polydactyl acid.
Further, nitrogen environment is remained before vacuumize process in the reaction kettle.
Embodiment 2
It is a kind of for manufacturing the material of degradable bionic fish bait, be made of the substance of following parts by weight：
105 parts of polydactyl acids, 10 parts of toughener, 4 parts of nanometer calcium carbonates, 1 part of phagostimulant, 1.5 parts of pigment, 0.3 part it is anti-oxidant
Agent, 0.2 part of ultraviolet absorbing agent, 0.7 part of lubricant.
Further, the toughener is methyl methacrylate-butadiene-styrene copolymer.
Further, the grain diameter of the nanometer calcium carbonate is 20 ~ 60nm.
Further, the phagostimulant is vanillic aldehyde.
Further, the antioxidant is antioxidant 1010.
Further, the ultraviolet absorbing agent is ultraviolet absorbent UV-531.
Further, the lubricant is polyethylene wax.
Further, the preparation method of the polydactyl acid includes the following steps：
（1）By terephthalic acid (TPA) and ethylene glycol according to molar ratio 1:1.4, which carry out mixing, puts into reaction kettle, and heating keeps reaction
Temperature in kettle is 200 DEG C, is stirred continuously when handling 50% or more degree to be esterified, then to put into reaction kettle substance in it total
When continuing stir process 90% or more degree to be esterified, antimony oxide catalyst is added, and will be anti-in the modified solution of quality 28%
Answer the temperature in kettle to rise to 300 DEG C, while vacuumize process, taken out after 1.8h mixture is spare；The modified solution is by such as
The material composition of lower parts by weight：6 parts of ethyl orthosilicates, 17 parts of deionized waters, 32 parts of dehydrated alcohols, 0.15 part of ammonium hydroxide, 4 parts of corns
Viscose, 1.5 parts of chitosans；
（2）By step（1）Mixture obtained is put into extruder, and extruding pelletization is carried out, after the completion up to polydactyl acid.
Further, nitrogen environment is remained before vacuumize process in the reaction kettle.
Embodiment 3
It is a kind of for manufacturing the material of degradable bionic fish bait, be made of the substance of following parts by weight：
110 parts of polydactyl acids, 12 parts of toughener, 5 parts of nanometer calcium carbonates, 1.5 parts of phagostimulants, 2 parts of pigment, 0.4 part it is anti-oxidant
Agent, 0.3 part of ultraviolet absorbing agent, 0.8 part of lubricant.
Further, the toughener is methyl methacrylate-butadiene-styrene copolymer.
Further, the grain diameter of the nanometer calcium carbonate is 20 ~ 60nm.
Further, the phagostimulant is cumarin.
Further, the antioxidant is antioxidant 1010.
Further, the ultraviolet absorbing agent is ultraviolet absorbent UV-531.
Further, the lubricant is polyethylene wax.
Further, the preparation method of the polydactyl acid includes the following steps：
（1）By terephthalic acid (TPA) and ethylene glycol according to molar ratio 1:1.6, which carry out mixing, puts into reaction kettle, and heating keeps reaction
Temperature in kettle is 220 DEG C, is stirred continuously when handling 50% or more degree to be esterified, then to put into reaction kettle substance in it total
When continuing stir process 90% or more degree to be esterified, antimony oxide catalyst is added, and will be anti-in the modified solution of quality 30%
Answer the temperature in kettle to rise to 310 DEG C, while vacuumize process, taken out after 2h mixture is spare；The modified solution is by as follows
The material composition of parts by weight：7 parts of ethyl orthosilicates, 20 parts of deionized waters, 35 parts of dehydrated alcohols, 0.2 part of ammonium hydroxide, 5 parts of corn fibres
Tie up glue, 2 parts of chitosans；
（2）By step（1）Mixture obtained is put into extruder, and extruding pelletization is carried out, after the completion up to polydactyl acid.
Further, nitrogen environment is remained before vacuumize process in the reaction kettle.
Comparative example 1
This comparative example 1 compared with Example 2, in the preparation process of polydactyl acid, eliminates the jade in modified solution
Rice viscose and constituent of chitosan, method and step in addition to this are all the same.
Comparative example 2
This comparative example 2 compared with Example 2, in the preparation process of polydactyl acid, is changed with nano silica substitution
Property solution, addition amount be modified solution gross mass 15%, method and step in addition to this is all the same.
Comparative example 3
This comparative example 3 compared with Example 2, with etc. mass parts common polylactic acid substituting modification polylactic acid ingredient, remove this
Outer method and step is all the same.
In order to compare effect of the present invention, to above-described embodiment 2, comparative example 1, comparative example 2, comparative example 3
Corresponding material obtained is tested for the property, and specific correlation data is as shown in table 1 below：
Table 1
Note：Impact strength described in upper table 1 is rushed using the k-5033 type of Dongguan Yuan Ke detecting instrument Co., Ltd production
Testing machine is hit to be measured according to GB/T1843-2008 standard；The tensile strength is to utilize Jinan resistance to and test limited
The WDW-10C universal testing machine of company's production is measured by GB/T1040-2006 standard.
The comprehensive performance of the material of the bionic fish bait made from the method for the present invention it can be seen from upper table 1 is obviously improved, pole
Has application value.
Claims (10)
1. a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that be made of the substance of following parts by weight：
100 ~ 110 parts of polydactyl acids, 8 ~ 12 parts of toughener, 3 ~ 5 parts of nanometer calcium carbonates, 0.5 ~ 1.5 part of phagostimulant, 1 ~ 2 part of face
Material, 0.2 ~ 0.4 part of antioxidant, 0.1 ~ 0.3 part of ultraviolet absorbing agent, 0.5 ~ 0.8 part of lubricant.
2. according to claim 1 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that by weighing as follows
The substance of amount part is made：
105 parts of polydactyl acids, 10 parts of toughener, 4 parts of nanometer calcium carbonates, 1 part of phagostimulant, 1.5 parts of pigment, 0.3 part it is anti-oxidant
Agent, 0.2 part of ultraviolet absorbing agent, 0.7 part of lubricant.
3. according to claim 1 or 2 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described
Toughener be methyl methacrylate-butadiene-styrene copolymer.
4. according to claim 1 or 2 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described
Nanometer calcium carbonate grain diameter be 20 ~ 60nm.
5. according to claim 1 or 2 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described
Phagostimulant be allicin, vanillic aldehyde, cumarin it is one or more.
6. according to claim 1 or 2 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described
Antioxidant be antioxidant 1010.
7. according to claim 1 or 2 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described
Ultraviolet absorbing agent be ultraviolet absorbent UV-531.
8. according to claim 1 or 2 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described
Lubricant be polyethylene wax.
9. according to claim 1 or 2 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described
The preparation method of polydactyl acid include the following steps：
（1）By terephthalic acid (TPA) and ethylene glycol according to molar ratio 1:1.2 ~ 1.6, which carry out mixing, puts into reaction kettle, and heating is kept
Temperature in reaction kettle is 190 ~ 220 DEG C, when being stirred continuously processing 50% or more degree to be esterified, then puts into it into reaction kettle
The modified solution of interior substance gross mass 25 ~ 30% when continuing stir process 90% or more degree to be esterified, is added antimony oxide and urges
Agent, and the temperature in reaction kettle is risen into 280 ~ 310 DEG C, while vacuumize process, taken out after 1.5 ~ 2h mixture is spare；
The modified solution by following parts by weight material composition：4 ~ 7 parts of ethyl orthosilicates, 15 ~ 20 parts of deionized waters, 30 ~ 35 parts of nothings
Water-ethanol, 0.1 ~ 0.2 part of ammonium hydroxide, 3 ~ 5 parts of corn fiber gums, 1 ~ 2 part of chitosan；
（2）By step（1）Mixture obtained is put into extruder, and extruding pelletization is carried out, after the completion up to polydactyl acid.
10. according to claim 9 a kind of for manufacturing the material of degradable bionic fish bait, which is characterized in that described anti-
It answers in kettle and remains nitrogen environment before vacuumize process.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810630264.3A CN108892933A (en) | 2018-06-19 | 2018-06-19 | It is a kind of for manufacturing the material of degradable bionic fish bait |
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| CN201810630264.3A CN108892933A (en) | 2018-06-19 | 2018-06-19 | It is a kind of for manufacturing the material of degradable bionic fish bait |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111393860A (en) * | 2020-04-30 | 2020-07-10 | 安徽宏飞钓具有限公司 | Quickly degradable bionic bait for sea fishing and production process thereof |
| CN113429716A (en) * | 2021-06-25 | 2021-09-24 | 安徽宏飞钓具有限公司 | Full-biodegradable bionic bait and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005143413A (en) * | 2003-11-17 | 2005-06-09 | Fuji Mold:Kk | Artificial bait using biodegradable resin |
| CN106046722A (en) * | 2016-06-07 | 2016-10-26 | 威海两岸环保新材料科技有限公司 | Fully biodegradable bionic bait and preparation method thereof |
| CN107603191A (en) * | 2017-09-21 | 2018-01-19 | 安徽宏飞钓具有限公司 | A kind of degradable high imitated baits of novel environment friendly |
-
2018
- 2018-06-19 CN CN201810630264.3A patent/CN108892933A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005143413A (en) * | 2003-11-17 | 2005-06-09 | Fuji Mold:Kk | Artificial bait using biodegradable resin |
| CN106046722A (en) * | 2016-06-07 | 2016-10-26 | 威海两岸环保新材料科技有限公司 | Fully biodegradable bionic bait and preparation method thereof |
| CN107603191A (en) * | 2017-09-21 | 2018-01-19 | 安徽宏飞钓具有限公司 | A kind of degradable high imitated baits of novel environment friendly |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111393860A (en) * | 2020-04-30 | 2020-07-10 | 安徽宏飞钓具有限公司 | Quickly degradable bionic bait for sea fishing and production process thereof |
| CN113429716A (en) * | 2021-06-25 | 2021-09-24 | 安徽宏飞钓具有限公司 | Full-biodegradable bionic bait and preparation method thereof |
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Application publication date: 20181127 |