CN108892907A - A kind of high-strength plastic flitch - Google Patents

A kind of high-strength plastic flitch Download PDF

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Publication number
CN108892907A
CN108892907A CN201810639371.2A CN201810639371A CN108892907A CN 108892907 A CN108892907 A CN 108892907A CN 201810639371 A CN201810639371 A CN 201810639371A CN 108892907 A CN108892907 A CN 108892907A
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China
Prior art keywords
parts
mixture
polyethylene
added
nano
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Pending
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CN201810639371.2A
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Chinese (zh)
Inventor
不公告发明人
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Foshan Chancheng Ju Yi Plastic Factory
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Foshan Chancheng Ju Yi Plastic Factory
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Priority to CN201810639371.2A priority Critical patent/CN108892907A/en
Publication of CN108892907A publication Critical patent/CN108892907A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C08L31/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of high-strength plastic flitch, plastic plate component includes 10-30 parts of polyvinyl acetate, 10-20 parts of polyethylene, alkalization 7-14 parts of stalk fibre powder, 5-15 parts of flyash, 1-3 parts of nano-titanium dioxide, 2-6 parts of nanometer calcium carbonate, 5-10 parts of silicon powder, 3-9 parts of ESCALOL 567,4-10 parts of polyethylene wax in parts by weight, production method of the present invention is simple, low manufacture cost, plastic plate obtained has excellent wear-resisting, shock resistance, fire-retardant, sound insulation performance, long service life.

Description

A kind of high-strength plastic flitch
Technical field
The present invention relates to plastic plate manufacture technology field, specially a kind of high-strength plastic flitch.
Background technique
Plastic plate is exactly to be made into plate with plastics, and plastics are the high-molecular compound of synthesis, can freely change body sample Formula.Plastics are the materials using raw material monomer to synthesize or condensation reaction is polymerized, by synthetic resin and filler, plasticizer, The additives such as stabilizer, lubricant, colorant composition, its main component is synthetic resin.
Current plastics board manufacturing method is complicated, and cost of manufacture is high, and current plastic plate compression strength and shock resistance Performance is poor.
Summary of the invention
The purpose of the present invention is to provide a kind of high-strength plastic flitch, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides the following technical solutions：A kind of high-strength plastic flitch, plastic plate component is by weight Amount number includes 10-30 parts of polyvinyl acetate, 10-20 parts of polyethylene, alkalization 7-14 parts of stalk fibre powder, flyash 5-15 Part, 1-3 parts of nano-titanium dioxide, 2-6 parts of nanometer calcium carbonate, 5-10 parts of silicon powder, ESCALOL 567 3-9 Part, 4-10 parts of polyethylene wax.
Preferably, the preferred composition proportion of plastic plate component includes 20 parts of polyvinyl acetate, 15 parts of polyethylene, alkalization straw 10 parts of stalk fiber powder, 10 parts of flyash, 2 parts of nano-titanium dioxide, 4 parts of nanometer calcium carbonate, 8 parts of silicon powder, 2- hydroxyl -4- methoxy 6 parts of base benzophenone, 7 parts of polyethylene wax.
Preferably, production method includes the following steps：
A, it is added in agitator tank and stirs at low speed after mixing polyvinyl acetate, polyethylene, alkalization stalk fibre powder, whipping process Middle addition ESCALOL 567, polyethylene wax continue to obtain mixture A after stirring 20min；
B, it by flyash, nano-titanium dioxide, nanometer calcium carbonate, silicon powder, is added in grinder and grinds after mixing, the time is 10min obtains mixture B；
C, mixture B is added in mixture A, after being sufficiently mixed at normal temperature, obtains mixture C；
D, mixture C is added in sheet-forming machine and is formed to get plastic plate is arrived.
Compared with prior art, the beneficial effects of the invention are as follows：Production method of the present invention is simple, low manufacture cost, is made Plastic plate have excellent wear-resisting, shock resistance, fire-retardant, sound insulation performance, long service life；Wherein, it is added in the present invention Nano-titanium dioxide, nanometer calcium carbonate, silicon powder can be improved the flame retardant property and compression strength of plastic plate；The 2- hydroxyl of addition Base -4- methoxy benzophenone, polyethylene wax, can be improved the shock resistance of plastic plate；In addition, the production that the present invention uses Method can ensure the uniformity of plate.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The present invention provides the following technical solutions：A kind of high-strength plastic flitch, plastic plate component include poly- second in parts by weight 10-30 parts of vinyl acetate, 10-20 parts of polyethylene, alkalization 7-14 parts of stalk fibre powder, 5-15 parts of flyash, nano-titanium dioxide 1-3 parts, 2-6 parts of nanometer calcium carbonate, 5-10 parts of silicon powder, 3-9 parts of ESCALOL 567, polyethylene wax 4-10 Part.
Embodiment one：
Plastic plate component includes 10 parts of polyvinyl acetate, 10 parts of polyethylene, alkalization 7 parts of stalk fibre powder, powder in parts by weight 5 parts of coal ash, 2 parts of nanometer calcium carbonate, 5 parts of silicon powder, 3 parts of ESCALOL 567, gathers 1 part of nano-titanium dioxide 4 parts of ethylene waxes.
The production method of the present embodiment includes the following steps：
A, it is added in agitator tank and stirs at low speed after mixing polyvinyl acetate, polyethylene, alkalization stalk fibre powder, whipping process Middle addition ESCALOL 567, polyethylene wax continue to obtain mixture A after stirring 20min；
B, it by flyash, nano-titanium dioxide, nanometer calcium carbonate, silicon powder, is added in grinder and grinds after mixing, the time is 10min obtains mixture B；
C, mixture B is added in mixture A, after being sufficiently mixed at normal temperature, obtains mixture C；
D, mixture C is added in sheet-forming machine and is formed to get plastic plate is arrived.
Embodiment two：
Plastic plate component includes 30 parts of polyvinyl acetate, 20 parts of polyethylene, alkalization 14 parts of stalk fibre powder, powder in parts by weight 15 parts of coal ash, 3 parts of nano-titanium dioxide, 6 parts of nanometer calcium carbonate, 10 parts of silicon powder, 9 parts of ESCALOL 567, 10 parts of polyethylene wax.
The production method of the present embodiment includes the following steps：
A, it is added in agitator tank and stirs at low speed after mixing polyvinyl acetate, polyethylene, alkalization stalk fibre powder, whipping process Middle addition ESCALOL 567, polyethylene wax continue to obtain mixture A after stirring 20min；
B, it by flyash, nano-titanium dioxide, nanometer calcium carbonate, silicon powder, is added in grinder and grinds after mixing, the time is 10min obtains mixture B；
C, mixture B is added in mixture A, after being sufficiently mixed at normal temperature, obtains mixture C；
D, mixture C is added in sheet-forming machine and is formed to get plastic plate is arrived.
Embodiment three：
Plastic plate component includes 15 parts of polyvinyl acetate, 12 parts of polyethylene, alkalization 9 parts of stalk fibre powder, powder in parts by weight 7 parts of coal ash, 3 parts of nanometer calcium carbonate, 7 parts of silicon powder, 4 parts of ESCALOL 567, gathers 2 parts of nano-titanium dioxide 5 parts of ethylene waxes.
The production method of the present embodiment includes the following steps：
A, it is added in agitator tank and stirs at low speed after mixing polyvinyl acetate, polyethylene, alkalization stalk fibre powder, whipping process Middle addition ESCALOL 567, polyethylene wax continue to obtain mixture A after stirring 20min；
B, it by flyash, nano-titanium dioxide, nanometer calcium carbonate, silicon powder, is added in grinder and grinds after mixing, the time is 10min obtains mixture B；
C, mixture B is added in mixture A, after being sufficiently mixed at normal temperature, obtains mixture C；
D, mixture C is added in sheet-forming machine and is formed to get plastic plate is arrived.
Example IV：
Plastic plate component includes 25 parts of polyvinyl acetate, 18 parts of polyethylene, alkalization 12 parts of stalk fibre powder, powder in parts by weight 13 parts of coal ash, 3 parts of nano-titanium dioxide, 5 parts of nanometer calcium carbonate, 8 parts of silicon powder, 8 parts of ESCALOL 567, 9 parts of polyethylene wax.
The production method of the present embodiment includes the following steps：
A, it is added in agitator tank and stirs at low speed after mixing polyvinyl acetate, polyethylene, alkalization stalk fibre powder, whipping process Middle addition ESCALOL 567, polyethylene wax continue to obtain mixture A after stirring 20min；
B, it by flyash, nano-titanium dioxide, nanometer calcium carbonate, silicon powder, is added in grinder and grinds after mixing, the time is 10min obtains mixture B；
C, mixture B is added in mixture A, after being sufficiently mixed at normal temperature, obtains mixture C；
D, mixture C is added in sheet-forming machine and is formed to get plastic plate is arrived.
Embodiment five：
Plastic plate component includes 20 parts of polyvinyl acetate, 15 parts of polyethylene, alkalization 10 parts of stalk fibre powder, powder in parts by weight 10 parts of coal ash, 2 parts of nano-titanium dioxide, 4 parts of nanometer calcium carbonate, 8 parts of silicon powder, 6 parts of ESCALOL 567, 7 parts of polyethylene wax.
The production method of the present embodiment includes the following steps：
A, it is added in agitator tank and stirs at low speed after mixing polyvinyl acetate, polyethylene, alkalization stalk fibre powder, whipping process Middle addition ESCALOL 567, polyethylene wax continue to obtain mixture A after stirring 20min；
B, it by flyash, nano-titanium dioxide, nanometer calcium carbonate, silicon powder, is added in grinder and grinds after mixing, the time is 10min obtains mixture B；
C, mixture B is added in mixture A, after being sufficiently mixed at normal temperature, obtains mixture C；
D, mixture C is added in sheet-forming machine and is formed to get plastic plate is arrived.
Experimental example：
It is tested for the property using plastic plate made from various embodiments of the present invention, obtains data such as following table：
Compression strength（MPA） Impact strength（MPA）
Embodiment one 85 120
Embodiment two 82 125
Embodiment three 84 120
Example IV 86 122
Embodiment five 90 128
Production method of the present invention is simple, low manufacture cost, and plastic plate obtained has excellent wear-resisting, shock resistance, fire-retardant, sound insulation Performance, long service life；Wherein, nano-titanium dioxide, nanometer calcium carbonate, the silicon powder added in the present invention, can be improved The flame retardant property and compression strength of plastic plate；ESCALOL 567, the polyethylene wax of addition, can be improved modeling The shock resistance of flitch；In addition, the production method that the present invention uses can ensure the uniformity of plate.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (3)

1. a kind of high-strength plastic flitch, it is characterised in that：Plastic plate component includes polyvinyl acetate 10-30 in parts by weight Part, 10-20 parts of polyethylene, alkalization 7-14 parts of stalk fibre powder, 5-15 parts of flyash, 1-3 parts of nano-titanium dioxide, nano-calcium carbonate 2-6 parts of calcium, 5-10 parts of silicon powder, 3-9 parts of ESCALOL 567,4-10 parts of polyethylene wax.
2. a kind of high-strength plastic flitch according to claim 1, it is characterised in that：The preferred composition proportion of plastic plate component Including 20 parts of polyvinyl acetate, 15 parts of polyethylene, alkalization 10 parts of stalk fibre powder, 10 parts of flyash, nano-titanium dioxide 2 Part, 4 parts of nanometer calcium carbonate, 8 parts of silicon powder, 6 parts of ESCALOL 567,7 parts of polyethylene wax.
3. realizing a kind of production method of high-strength plastic flitch described in claim 1, it is characterised in that：Its production method includes Following steps：
A, it is added in agitator tank and stirs at low speed after mixing polyvinyl acetate, polyethylene, alkalization stalk fibre powder, whipping process Middle addition ESCALOL 567, polyethylene wax continue to obtain mixture A after stirring 20min；
B, it by flyash, nano-titanium dioxide, nanometer calcium carbonate, silicon powder, is added in grinder and grinds after mixing, the time is 10min obtains mixture B；
C, mixture B is added in mixture A, after being sufficiently mixed at normal temperature, obtains mixture C；
D, mixture C is added in sheet-forming machine and is formed to get plastic plate is arrived.
CN201810639371.2A 2018-06-20 2018-06-20 A kind of high-strength plastic flitch Pending CN108892907A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810639371.2A CN108892907A (en) 2018-06-20 2018-06-20 A kind of high-strength plastic flitch

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Application Number Priority Date Filing Date Title
CN201810639371.2A CN108892907A (en) 2018-06-20 2018-06-20 A kind of high-strength plastic flitch

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115197516A (en) * 2022-07-08 2022-10-18 张家港飞腾复合新材料股份有限公司 A2-grade composite board and production process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694523A (en) * 2013-12-11 2014-04-02 南京聚锋新材料有限公司 Composite plastic plate as well as preparation method and application thereof
CN104974408A (en) * 2015-08-03 2015-10-14 金宝丽科技（苏州）有限公司 Nano antimicrobial polyethylene material and preparation method thereof
CN106280160A (en) * 2016-08-17 2017-01-04 安徽兴源塑料包装有限公司 A kind of plastic plate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694523A (en) * 2013-12-11 2014-04-02 南京聚锋新材料有限公司 Composite plastic plate as well as preparation method and application thereof
CN104974408A (en) * 2015-08-03 2015-10-14 金宝丽科技（苏州）有限公司 Nano antimicrobial polyethylene material and preparation method thereof
CN106280160A (en) * 2016-08-17 2017-01-04 安徽兴源塑料包装有限公司 A kind of plastic plate

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
中国室内装饰协会等: "《室内装饰材料实用教程》", 30 September 2006 *
邬素华等: "《高分子材料加工工程专业实验》", 31 July 2013 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115197516A (en) * 2022-07-08 2022-10-18 张家港飞腾复合新材料股份有限公司 A2-grade composite board and production process thereof

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Application publication date: 20181127