CN108892210A - A kind of electrolytic cell for seawater desalination mixing capacitor - Google Patents

A kind of electrolytic cell for seawater desalination mixing capacitor Download PDF

Info

Publication number
CN108892210A
CN108892210A CN201810793122.9A CN201810793122A CN108892210A CN 108892210 A CN108892210 A CN 108892210A CN 201810793122 A CN201810793122 A CN 201810793122A CN 108892210 A CN108892210 A CN 108892210A
Authority
CN
China
Prior art keywords
electrolytic cell
seawater desalination
ontology
electrode
mixing capacitor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810793122.9A
Other languages
Chinese (zh)
Inventor
丹媛媛
冯伟超
滕腾
沙春帆
顾雷香
葛骊超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu University of Science and Technology
Original Assignee
Jiangsu University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu University of Science and Technology filed Critical Jiangsu University of Science and Technology
Priority to CN201810793122.9A priority Critical patent/CN108892210A/en
Publication of CN108892210A publication Critical patent/CN108892210A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices

Abstract

The invention discloses a kind of electrolytic cells for seawater desalination mixing capacitor, including electrolytic cell ontology, set on the top cover of electrolytic cell ontology upper end and set on the intrinsic electrode assembly of the electrolytic cell;Several partitions are equipped in the electrolytic cell ontology in parallel, several partitions are connected with one end with electrolytic cell inner body wall side, and the other end mutually is staggered to form S type channel from the electrolytic cell inner body wall other side, and several electrode assemblies are isolated by partition.Electrolytic cell inner space is divided into multi-section point, increases the quantity for the electrode that can be placed, enhance the effect of seawater desalination, saved space, reduce cost by the S-type water flow of electrolytic cell of the invention, internal partition;In addition, electrode assembly structure is simple, and it is easy to operate, completely cut off between electrode by megohmite insulant and to the simple fixation that electrode carries out, is convenient for preventing the short circuit of electrode while the replacement of electrode.

Description

A kind of electrolytic cell for seawater desalination mixing capacitor
Technical field
The invention belongs to electrolytic cell field more particularly to a kind of electrolytic cells for seawater desalination mixing capacitor.
Background technique
There are many tellurian water, however fresh water reserves only account for the 2.53% of global total water, and the mankind can directly utilize Water only account for 0.26% or so of total Water on the earth.With world economy and industrial expansion, the continuous growth of population and ring Border pollution is got worse, and the demand of freshwater resources is growing day by day.How seawater to be desalinated worldwide increasingly It attracts attention.The method for being traditionally used for sea water desalination at present has the methods of the way of distillation, hyperfiltration and electroosmose process, however by In energy consumption height, the disadvantages of secondary pollution is generated, these methods are difficult to be promoted, until the appearance of capacitive deionization technology, makes It is seen that realization low power consuming, the hope of pollution-free sea water desalination.
Therefore, now needing one kind being capable of electrolysis at low cost and more effectively being desalinized seawater using capacitive deionization technology Pond.
Summary of the invention
Goal of the invention:The object of the present invention is to provide it is a kind of it is at low cost and easy to operate, can effectively carry out seawater desalination Electrolytic cell.
Technical solution:The present invention is used for the electrolytic cell of seawater desalination mixing capacitor, including electrolytic cell ontology, is set to electrolytic cell The top cover of ontology upper end and be set to the intrinsic electrode assembly of the electrolytic cell;In the electrolytic cell ontology in parallel be equipped with it is several every Plate, several partitions are connected with one end with electrolytic cell inner body wall side, and the other end mutually interlocks from the electrolytic cell inner body wall other side Setting forms S type channel, and several electrode assemblies are isolated by partition.
Furtherly, electrolytic cell ontology internal partition is mutually from electrolytic cell inner body wall 25~30mm of the other side.Electrolytic cell ontology Body diagonal at be respectively equipped with inlet and outlet, wherein water inlet is set to the lower end of electrolytic cell ontology, and water outlet is set to The upper end of electrolytic cell ontology.Top cover circumferentially offers the groove to fasten with electrolytic cell ontology.
It further says, electrode assembly includes two fixed plates and cathode and anode between the fixed plate, the cathode It is equipped with the first copper sheet between its adjacent fixed plate, the second copper sheet is equipped between anode and its adjacent fixed plate.Top cover is equipped with The aperture being pierced by for first copper sheet and the second copper sheet.The thickness ratio of two fixed plates can be 1:2~2.5.
Furtherly, the first washer, spacer block and second packing ring can be also successively arranged between cathode and anode.Cathode and anode Upper cladding is equipped with amberplex.
Beneficial effect:Compared with prior art, remarkable advantage of the invention is:The S-type water flow of the electrolytic cell, it is internal every Electrolytic cell inner space is divided into multi-section point by plate, is increased the quantity for the electrode that can be placed, is enhanced the effect of seawater desalination, more Supernumerary segment about space, reduces cost;It is easy to operate in addition, electrode assembly structure is simple, between electrode by megohmite insulant isolation and To the simple fixation that electrode carries out, it is convenient for preventing the short circuit of electrode while the replacement of electrode.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of electrolytic cell of the present invention;
Fig. 2 is the structural schematic diagram of electrode assembly of the present invention;
Fig. 3 is the structural schematic diagram of top cover of the present invention.
Specific embodiment
Technical solution of the present invention is described in further detail below with reference to embodiment.
The present invention is used for the electrolytic cell of seawater desalination mixing capacitor, including electrolytic cell ontology 1, is set to the electrolytic cell ontology 1 On top cover 2, the circumferential edge of top cover 2 opens up fluted, is fastened by the groove and electrolytic cell ontology 1, to form sealing Body structure.Several partitions 3 are equipped in electrolytic cell ontology 1 in parallel, as shown in Figure 1, this several partition 3 is with one end and electrolytic cell 1 inner wall side of ontology is connected, and mode of the other end mutually from 1 25~30mm of the inner wall other side of electrolytic cell ontology is staggered, thus So that forming S type channel in electrolytic cell ontology 1, that is, form the water flow of S type.It is equipped with several electrode assemblies in electrolytic cell ontology 1, leads to Partition 3 is crossed to be separated by.Such as when partition 3 is 3, then it is divided into 4 inner spaces in electrolytic cell ontology 1, and the electrolytic cell 4 electrode assemblies can be placed in ontology 1.Electrode assembly includes that thickness ratio is 1:2~2.5 two fixed plates 6 and to be set to this two solid Cathode 7 and anode 8 between fixed board 6, wherein cathode 7 and its correspond to and be equipped with the first copper sheet 9,8 He of anode between adjacent fixed plate 6 It is equipped with the second copper sheet 10 between corresponding to adjacent fixed plate 6, and the first washer 12, spacer block 13 are also successively arranged between cathode 7 and anode 8 With second packing ring 14, amberplex is equipped with as shown in Fig. 2, also coating on cathode 7 and anode 8.Corresponding, top cover 2 is equipped with For the aperture 11 that first copper sheet 9 and the second copper sheet 10 are pierced by, as shown in figure 3, so that the first copper sheet 9 and the second copper sheet 10 can be connected with power supply.
Water inlet 4 and water outlet 5 are respectively equipped at the body diagonal of electrolytic cell ontology 1, wherein water inlet 4 is set to electrolytic cell The lower end of ontology 1, water outlet 5 are set to the upper end of electrolytic cell ontology 1.Cathode 7 can be sodium manganese oxide electrode, and anode 8 can be work Property carbon resistance rod.All parts are connected by electrode assembly by insulating materials screw.
Working principle:Firstly, electrode assembly is placed in electrolytic cell ontology 1, top cover 2 powers on;Then, will Rubber tube is inserted into water inlet 4, and right end connects peristaltic pump, metabisulfite solution is pressed into water inlet 4 using peristaltic pump, and by continuous Work, water outlet 5 will be pressed by electrolysis, the metabisulfite solution after desalination, it is same to use to achieve the effect that seawater desalination Rubber tube entangles water outlet 5, and left end is inserted into beaker, the solution after picking up desalination.

Claims (9)

1. a kind of electrolytic cell for seawater desalination mixing capacitor, it is characterised in that:Including electrolytic cell ontology (1), it is set to electrolysis The top cover (2) of pond ontology (1) upper end and several electrode assemblies being set in the electrolytic cell ontology (1);The electrolytic cell ontology (1) Inside be equipped with several partitions (3) in parallel, several partitions (3) are connected with one end with electrolytic cell ontology (1) inner wall side, other end phase from Electrolytic cell ontology (1) inner wall other side is staggered to form S type channel, is separated by between several electrode assemblies by partition (3) From.
2. the electrolytic cell according to claim 1 for seawater desalination mixing capacitor, it is characterised in that:The partition (3) Mutually from electrolytic cell ontology (1) 25~60mm of the inner wall other side.
3. the electrolytic cell according to claim 1 for seawater desalination mixing capacitor, it is characterised in that:The electrolytic cell sheet Water inlet (4) and water outlet (5) are respectively equipped at the body diagonal of body (1), wherein water inlet (4) is set to electrolytic cell ontology (1) Lower end, water outlet (5) be set to electrolytic cell ontology (1) upper end.
4. the electrolytic cell according to claim 1 for seawater desalination mixing capacitor, it is characterised in that:The top cover (2) Circumferentially offer the groove to fasten with electrolytic cell ontology (1).
5. the electrolytic cell according to claim 1 for seawater desalination mixing capacitor, it is characterised in that:The electrode assembly Including two fixed plates (6) and the cathode (7) and anode (8) that are set between two fixed plates (6), the cathode (7) and its adjacent consolidate The first copper sheet (9) are equipped between fixed board (6), are equipped with the second copper sheet (10) between anode (8) and its adjacent fixed plate (6).
6. the electrolytic cell according to claim 5 for seawater desalination mixing capacitor, it is characterised in that:Top cover is set on (2) There is the aperture (11) being pierced by for first copper sheet (9) and the second copper sheet (10).
7. the electrolytic cell according to claim 5 for seawater desalination mixing capacitor, it is characterised in that:The cathode (7) The first washer (12), spacer block (13) and second packing ring (14) are also successively arranged between anode (8).
8. the electrolytic cell according to claim 7 for seawater desalination mixing capacitor, it is characterised in that:The cathode (7) Amberplex is equipped with cladding on anode (8).
9. the electrolytic cell according to claim 5 for seawater desalination mixing capacitor, it is characterised in that:Two fixed plate (6) thickness ratio is 1:2~2.5.
CN201810793122.9A 2018-07-18 2018-07-18 A kind of electrolytic cell for seawater desalination mixing capacitor Pending CN108892210A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810793122.9A CN108892210A (en) 2018-07-18 2018-07-18 A kind of electrolytic cell for seawater desalination mixing capacitor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810793122.9A CN108892210A (en) 2018-07-18 2018-07-18 A kind of electrolytic cell for seawater desalination mixing capacitor

Publications (1)

Publication Number Publication Date
CN108892210A true CN108892210A (en) 2018-11-27

Family

ID=64350911

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810793122.9A Pending CN108892210A (en) 2018-07-18 2018-07-18 A kind of electrolytic cell for seawater desalination mixing capacitor

Country Status (1)

Country Link
CN (1) CN108892210A (en)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2190829A1 (en) * 1994-05-20 1995-12-07 Joseph C. Farmer Method and apparatus for capacitive deionization and electrochemical purification and regeneration of electrodes
US6309532B1 (en) * 1994-05-20 2001-10-30 Regents Of The University Of California Method and apparatus for capacitive deionization and electrochemical purification and regeneration of electrodes
CN101518748A (en) * 2008-02-29 2009-09-02 三星电子株式会社 Deionization apparatus and method of manufacturing the same
KR20100089251A (en) * 2009-02-03 2010-08-12 한국과학기술원 Capacitive deionization device, method for capacitively deionizing, and desalination apparatus, wastewater treatment apparatus using the same
CN103668305A (en) * 2014-01-02 2014-03-26 哈尔滨工业大学 Guide-plate microbial electrolysis cell embedded with multi-electrode system and use method thereof
CN105541020A (en) * 2015-12-31 2016-05-04 武汉科技大学 CDI (Capacitive Deionization) based compound type constructed wetland desalination system
CN106006872A (en) * 2016-07-01 2016-10-12 宁波市川宁环保科技有限公司 Clamping-groove-type multistage-series capacitive deionization device
CN106865701A (en) * 2017-02-20 2017-06-20 江苏科技大学 A kind of electrolytic cell for seawater desalination mixing electric capacity
CN206858235U (en) * 2017-06-13 2018-01-09 郭洪飞 A kind of open capacitive deionization desalter

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2190829A1 (en) * 1994-05-20 1995-12-07 Joseph C. Farmer Method and apparatus for capacitive deionization and electrochemical purification and regeneration of electrodes
US6309532B1 (en) * 1994-05-20 2001-10-30 Regents Of The University Of California Method and apparatus for capacitive deionization and electrochemical purification and regeneration of electrodes
CN101518748A (en) * 2008-02-29 2009-09-02 三星电子株式会社 Deionization apparatus and method of manufacturing the same
KR20100089251A (en) * 2009-02-03 2010-08-12 한국과학기술원 Capacitive deionization device, method for capacitively deionizing, and desalination apparatus, wastewater treatment apparatus using the same
CN103668305A (en) * 2014-01-02 2014-03-26 哈尔滨工业大学 Guide-plate microbial electrolysis cell embedded with multi-electrode system and use method thereof
CN105541020A (en) * 2015-12-31 2016-05-04 武汉科技大学 CDI (Capacitive Deionization) based compound type constructed wetland desalination system
CN106006872A (en) * 2016-07-01 2016-10-12 宁波市川宁环保科技有限公司 Clamping-groove-type multistage-series capacitive deionization device
CN106865701A (en) * 2017-02-20 2017-06-20 江苏科技大学 A kind of electrolytic cell for seawater desalination mixing electric capacity
CN206858235U (en) * 2017-06-13 2018-01-09 郭洪飞 A kind of open capacitive deionization desalter

Similar Documents

Publication Publication Date Title
CN102263278B (en) Continuous flow microorganism fuel cell and battery pack for synchronously generating electricity and desalting
Zuo et al. A ten liter stacked microbial desalination cell packed with mixed ion-exchange resins for secondary effluent desalination
CN207645869U (en) A kind of pharmaceutical wastewater apparatus for electrochemical treatment
CN105084633A (en) Eutrophication water body in-situ electromagnetic coupling flocculation precipitation device
CN103936106A (en) Electrochemical synchronous nitrogen and phosphorus removal apparatus and municipal sewage treatment method
CN108892210A (en) A kind of electrolytic cell for seawater desalination mixing capacitor
CN209442984U (en) A kind of microorganism battery system removing kitchen garbage salinity
CN204281413U (en) A kind of two rooms MFC Waste Water Treatment combined with A/O technique
CN106865701B (en) Electrolytic cell for seawater desalination mixed capacitor
CN204982072U (en) Acid etching waste liquid copper recovery device
CN217555865U (en) Multi-channel capacitive desalination device constructed by copper ion redox electrolyte
CN103420459B (en) Hybrid membrane desalination processing device and equipment, and desalination method
CN211620021U (en) Spiral electrolyzed water generator
CN204434733U (en) Electrolyzer
CN104016451A (en) Equipment for double-membrane desalination through synergistic effect of pressure field and electric field and application method
CN202214427U (en) Aluminum reduction cell with plate-shaped diaphragm structure
CN103361673A (en) Titanium cylinder electrolysis machine
CN204625801U (en) A kind of pulsed electrolyzer
CN201933161U (en) Electrolytic bath with diionic membrane structure
CN103496766A (en) High-efficiency and low-energy-consumption type wastewater recycling device and application thereof
CN114212859A (en) Two-stage electrochemical crosslinking electrodialysis desalination treatment system and application thereof
CN205556792U (en) Zero pole span electrolysis trough
CN109704442B (en) Electrode plate structure for seawater acidification device
CN105330094A (en) System for removing antibiotics in surface water through using root secretion reinforced wetland coupling system, and method thereof
CN204080167U (en) A kind of rack plating acidic zinc nickel wire

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181127

RJ01 Rejection of invention patent application after publication