CN108884575A - Rust preventive oil composition - Google Patents
Rust preventive oil composition Download PDFInfo
- Publication number
- CN108884575A CN108884575A CN201780020968.2A CN201780020968A CN108884575A CN 108884575 A CN108884575 A CN 108884575A CN 201780020968 A CN201780020968 A CN 201780020968A CN 108884575 A CN108884575 A CN 108884575A
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- ingredient
- carbon atom
- atom number
- oil composition
- acid
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- 239000000203 mixture Substances 0.000 title claims abstract description 101
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title abstract description 14
- 230000003449 preventive effect Effects 0.000 title abstract 3
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 109
- 239000003921 oil Substances 0.000 claims abstract description 94
- -1 imidazoline compound Chemical class 0.000 claims abstract description 85
- 150000002148 esters Chemical class 0.000 claims abstract description 43
- 150000003839 salts Chemical class 0.000 claims abstract description 41
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 21
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 15
- 239000010452 phosphate Substances 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 229940097789 heavy mineral oil Drugs 0.000 claims abstract description 12
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 239000004615 ingredient Substances 0.000 claims description 328
- 150000001875 compounds Chemical class 0.000 claims description 56
- 125000000217 alkyl group Chemical group 0.000 claims description 46
- 125000003342 alkenyl group Chemical group 0.000 claims description 25
- 239000000126 substance Substances 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 17
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 16
- 239000013556 antirust agent Substances 0.000 claims description 13
- 229940059904 light mineral oil Drugs 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 12
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 11
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims description 11
- 239000012530 fluid Substances 0.000 claims description 10
- 229920005862 polyol Polymers 0.000 claims description 8
- 150000003077 polyols Chemical class 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 229920001083 polybutene Polymers 0.000 claims description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 6
- 125000001118 alkylidene group Chemical group 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 150000003949 imides Chemical class 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 125000004450 alkenylene group Chemical group 0.000 claims description 2
- 150000003505 terpenes Chemical class 0.000 claims description 2
- 235000007586 terpenes Nutrition 0.000 claims description 2
- RMZIOVJHUJAAEY-UHFFFAOYSA-N Allyl butyrate Chemical group CCCC(=O)OCC=C RMZIOVJHUJAAEY-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 45
- 238000000034 method Methods 0.000 abstract description 19
- 239000002480 mineral oil Substances 0.000 abstract description 13
- 235000010446 mineral oil Nutrition 0.000 abstract description 13
- 125000001931 aliphatic group Chemical group 0.000 abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 10
- 150000005846 sugar alcohols Polymers 0.000 abstract description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N dihydromaleimide Natural products O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000002516 radical scavenger Substances 0.000 abstract 1
- 229960002317 succinimide Drugs 0.000 abstract 1
- 150000001721 carbon Chemical group 0.000 description 79
- 235000019198 oils Nutrition 0.000 description 78
- 239000002585 base Substances 0.000 description 61
- 238000005238 degreasing Methods 0.000 description 24
- 239000007769 metal material Substances 0.000 description 23
- 229910052751 metal Inorganic materials 0.000 description 19
- 239000002184 metal Substances 0.000 description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 15
- 239000001993 wax Substances 0.000 description 14
- 150000007524 organic acids Chemical class 0.000 description 13
- 150000007530 organic bases Chemical class 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 150000001412 amines Chemical class 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 11
- 125000004122 cyclic group Chemical group 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- RJWUMFHQJJBBOD-UHFFFAOYSA-N 2-methylheptadecane Chemical compound CCCCCCCCCCCCCCCC(C)C RJWUMFHQJJBBOD-UHFFFAOYSA-N 0.000 description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 125000005037 alkyl phenyl group Chemical group 0.000 description 7
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 230000007935 neutral effect Effects 0.000 description 7
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 6
- 229920001748 polybutylene Polymers 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 6
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Natural products NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 6
- RJDVGKCBHFINOK-UHFFFAOYSA-N tris(2-methylphenoxy)-sulfanylidene-$l^{5}-phosphane Chemical compound CC1=CC=CC=C1OP(=S)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C RJDVGKCBHFINOK-UHFFFAOYSA-N 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
- 239000005642 Oleic acid Substances 0.000 description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 125000002877 alkyl aryl group Chemical group 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 150000004985 diamines Chemical class 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 235000019197 fats Nutrition 0.000 description 5
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical class C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- SNIFAVVHRQZYGO-LUAWRHEFSA-N (z)-tetradec-5-ene Chemical compound CCCCCCCC\C=C/CCCC SNIFAVVHRQZYGO-LUAWRHEFSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 229920002367 Polyisobutene Polymers 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 4
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 4
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- CTDXHTXAABMUIW-QBFSEMIESA-N (z)-hexadec-6-ene Chemical compound CCCCCCCCC\C=C/CCCCC CTDXHTXAABMUIW-QBFSEMIESA-N 0.000 description 3
- HPDAWHPYUNZJMN-QBFSEMIESA-N (z)-octadec-6-ene Chemical compound CCCCCCCCCCC\C=C/CCCCC HPDAWHPYUNZJMN-QBFSEMIESA-N 0.000 description 3
- XEIYDTUADLFFTM-CLFYSBASSA-N (z)-tetradec-4-ene Chemical compound CCCCCCCCC\C=C/CCC XEIYDTUADLFFTM-CLFYSBASSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- VKPSKYDESGTTFR-UHFFFAOYSA-N 2,2,4,6,6-pentamethylheptane Chemical compound CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 3
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000002199 base oil Substances 0.000 description 3
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000008601 oleoresin Substances 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 150000008301 phosphite esters Chemical class 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 3
- 125000005065 undecenyl group Chemical group C(=CCCCCCCCCC)* 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- WZUNUACWCJJERC-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)(CO)CO WZUNUACWCJJERC-UHFFFAOYSA-N 0.000 description 2
- QNDGQRJVVZJMJO-UHFFFAOYSA-N 2-(2-undecyl-4,5-dihydroimidazol-1-yl)ethanol Chemical class CCCCCCCCCCCC1=NCCN1CCO QNDGQRJVVZJMJO-UHFFFAOYSA-N 0.000 description 2
- LJKDOMVGKKPJBH-UHFFFAOYSA-N 2-ethylhexyl dihydrogen phosphate Chemical group CCCCC(CC)COP(O)(O)=O LJKDOMVGKKPJBH-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- ZUDFHYZUQCNUJF-UHFFFAOYSA-N 2-thiophen-2-yl-1,3-thiazolidine-4-carboxylic acid Chemical compound N1C(C(=O)O)CSC1C1=CC=CS1 ZUDFHYZUQCNUJF-UHFFFAOYSA-N 0.000 description 2
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- PWLXTFFHCFWCGG-UHFFFAOYSA-N Heneicosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCCC(O)=O PWLXTFFHCFWCGG-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 235000021319 Palmitoleic acid Nutrition 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- NKSZWBYBTXAALC-WRBBJXAJSA-N [2-(hydroxymethyl)-2-[[(z)-octadec-9-enoyl]oxymethyl]butyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CC)(CO)COC(=O)CCCCCCC\C=C/CCCCCCCC NKSZWBYBTXAALC-WRBBJXAJSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
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- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- YWWVWXASSLXJHU-WAYWQWQTSA-N myristoleic acid Chemical compound CCCC\C=C/CCCCCCCC(O)=O YWWVWXASSLXJHU-WAYWQWQTSA-N 0.000 description 1
- DDQBWEOPDZBVJW-KTKRTIGZSA-N n'-[(z)-octadec-9-enyl]ethane-1,2-diamine Chemical compound CCCCCCCC\C=C/CCCCCCCCNCCN DDQBWEOPDZBVJW-KTKRTIGZSA-N 0.000 description 1
- QCENGKPIBJNODL-UHFFFAOYSA-N n'-dodecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCNCCN QCENGKPIBJNODL-UHFFFAOYSA-N 0.000 description 1
- XMMDVXFQGOEOKH-UHFFFAOYSA-N n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCNCCCN XMMDVXFQGOEOKH-UHFFFAOYSA-N 0.000 description 1
- SLEYAGWXAGXUAS-UHFFFAOYSA-N n'-hexadecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCCCNCCN SLEYAGWXAGXUAS-UHFFFAOYSA-N 0.000 description 1
- LMTSQIZQTFBYRL-UHFFFAOYSA-N n'-octadecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCCCCCNCCN LMTSQIZQTFBYRL-UHFFFAOYSA-N 0.000 description 1
- UTPUPJKKYXJFPX-UHFFFAOYSA-N n'-octylethane-1,2-diamine Chemical compound CCCCCCCCNCCN UTPUPJKKYXJFPX-UHFFFAOYSA-N 0.000 description 1
- KPZNJYFFUWANHA-UHFFFAOYSA-N n'-octylpropane-1,3-diamine Chemical compound CCCCCCCCNCCCN KPZNJYFFUWANHA-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- WYAKJXQRALMWPB-UHFFFAOYSA-N nonyl dihydrogen phosphate Chemical compound CCCCCCCCCOP(O)(O)=O WYAKJXQRALMWPB-UHFFFAOYSA-N 0.000 description 1
- 239000001702 nutmeg Substances 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229940097411 palm acid Drugs 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- KJOMYNHMBRNCNY-UHFFFAOYSA-N pentane-1,1-diamine Chemical compound CCCCC(N)N KJOMYNHMBRNCNY-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- RFPMGSKVEAUNMZ-UHFFFAOYSA-N pentylidene Chemical group [CH2+]CCC[CH-] RFPMGSKVEAUNMZ-UHFFFAOYSA-N 0.000 description 1
- CNVZJPUDSLNTQU-SEYXRHQNSA-N petroselinic acid Chemical compound CCCCCCCCCCC\C=C/CCCCC(O)=O CNVZJPUDSLNTQU-SEYXRHQNSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229960003424 phenylacetic acid Drugs 0.000 description 1
- 239000003279 phenylacetic acid Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- VGUALMPOPCFXCA-UHFFFAOYSA-N phosphoric acid tridecane Chemical compound OP(O)(O)=O.CCCCCCCCCCCCC.CCCCCCCCCCCCC.CCCCCCCCCCCCC VGUALMPOPCFXCA-UHFFFAOYSA-N 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- NNNVXFKZMRGJPM-KHPPLWFESA-N sapienic acid Chemical compound CCCCCCCCC\C=C/CCCCC(O)=O NNNVXFKZMRGJPM-KHPPLWFESA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000005480 straight-chain fatty acid group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940066771 systemic antihistamines piperazine derivative Drugs 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- ALKGSOOKRJKXMF-UHFFFAOYSA-N tetradecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCCCOP(O)O ALKGSOOKRJKXMF-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 235000021081 unsaturated fats Nutrition 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/142—Esters of phosphorous acids with hydroxyalkyl compounds without further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/143—Esters of phosphorous acids with unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/18—Esters of thiophosphoric acids with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
A rust preventive oil composition which can achieve good water removability, rust prevention and water separability and comprises at least 1 water scavenger (A) selected from the following components (A1) - (A4) and organic salts thereof, at least 1 rust preventive (B) selected from the following components (B1) - (B6) and has a kinematic viscosity at 40 ℃ of 20mm2Light mineral oil (C) having a kinematic viscosity of 80mm at 40 DEG and a viscosity of less than s2A heavy mineral oil (D) of at least s; (A1) the method comprises the following steps An imidazoline compound having an aliphatic hydrocarbon group having 10 to 24 carbon atoms; (A2) the method comprises the following steps A phosphate ester compound having a total carbon number of 8 to 40 in an aliphatic hydrocarbon group; (A3) the method comprises the following steps A phosphorothioate compound having a total carbon number of 8 to 40 in the aliphatic hydrocarbon group; (A4) the method comprises the following steps A diamine compound having 8 to 40 total carbon atoms in the aliphatic hydrocarbon group; (B1) the method comprises the following steps A sulfonate having an average of 1 sulfo group and having all carbon atoms of 23 or more; (B2) the method comprises the following steps Partial esters of polyhydric alcohols; (B3) the method comprises the following steps Number ofA polymer having a mean molecular weight of 600 to 5000; (B4) the method comprises the following steps A resin having a number average molecular weight of 400 to 3500; (B5) the method comprises the following steps A wax; (B6) the method comprises the following steps A succinimide compound.
Description
Technical field
The present invention relates to anticorrosive oil compositions.
Background technique
The metal material formed by metals such as iron is during manufacturing step or after product factory, in order to prevent in metal watch
Face generates rust, spot, it is however generally that is coated with antirust oil in metal surface.On the other hand, metal material is carried out using processing oil
The various processing such as cutting, compacting, in addition, also being cleaned sometimes using cleaning solution in the fabrication process.
Antirust oil carries out overlay film to metal material surface sometimes after carrying out various processing or cleaning etc. to metal material.
In the case where processing oil, cleaning solution etc. are water-based substance, processing oil, cleaning solution become reason and generate rust in order to prevent, prevent
Rust oil needs to carry out overlay film to metal surface after removing processing oil, cleaning solution from metal surface.
Therefore, when overlay film antirust oil rear using water-based working fluid etc., usually coating is removed except aqueous excellent finish
After moisture, it is coated with the excellent antirust oil of rust-preventing characteristic on the metal surface.It should be noted that referring to that additive enters in metal except aqueous
Get on the performance removed water between the water and metal adhered on surface, from metal surface.As aqueous excellent finish is removed, such as such as
It is recorded in patent document 1 such, it is known that comprising nonaqueous solvents and include cationic active agent or higher amines or its carboxylate
Deng surfactant water-displacement agent.
In addition, coating has also been attempted and omits except aqueous excellent finish etc. and removes moisture removal in order to simplify step
Step.At this point, antirust oil requires not only to make rust-preventing characteristic under exposed environments, also requires to make to reach good except aqueous.To provide this
For the purpose of the antirust oil of sample, developed in the past containing low viscosity mineral oil, high viscosity mineral oil, fatty acid amine salt, ester and flesh ammonia
The antirust oil of the antirust agent such as acid type compound (referring for example to patent document 2).
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 8-60191 bulletin
Patent document 2：Japanese Unexamined Patent Publication 2013-199670 bulletin.
Summary of the invention
Subject to be solved by the invention
But the additive (antirust agent) for assigning except aqueous additive (deicer) and for assigning rust-preventing characteristic passes through
It is adsorbed in metal surface, assigns and removes aqueous, rust-preventing characteristic.Therefore, it takes into account to realize except aqueous and rust-preventing characteristic, if by deicer
It is matched in antirust oil with both antirust agent, it may be considered that they are in metal surface competitive Adsorption, it is however generally that, it is difficult to it realizes
It takes into account except aqueous and rust-preventing characteristic.
For example, even if in the case where anticorrosive oil composition disclosed in patent document 2, it is believed that fatty acid amine salt hair
The effect of deicer is waved, cooperation both deicer and antirust agent are difficult to sufficiently improve the rust-preventing characteristic under exposed environments.
Further, when anticorrosive oil composition being coated on metal material, such as metal material is impregnated in antirust oil group
The moisture being attached on metal material surface when closing in object, but impregnating is mixed into anticorrosive oil composition sometimes.Therefore, in order to will mix
Enter the water in anticorrosive oil composition and separate removal from anticorrosive oil composition, needs practical water to separate anticorrosive oil composition
Property.
The present invention carries out in view of the foregoing, problem of the present invention is that, provide can make except aqueous, rust-preventing characteristic,
Reach good anticorrosive oil composition with water separable performance.
Means for solving the problems
It is that the inventors of the present invention are furtherd investigate the result is that discovery, by anticorrosive oil composition, in addition to light mineral oil and
Except heavy mineral oil, specific deicer and specific antirust agent is also applied in combination, can the above subject, so as to complete with
Under the present invention.That is, the present invention provides [1] below and [2].
[1] anticorrosive oil composition, it includes：
At least one kind of deicer (A) in following (A1) ~ (A4) ingredient and their organic salt,
At least one kind of antirust agent (B) in following (B1) ~ (B6) ingredient,
40 DEG C of kinematic viscosity are 20mm2/ s light mineral oil below (C) and
40 DEG C of kinematic viscosity are 80mm2The heavy mineral oil (D) of/s or more,
(A1)：Imidazolinium compounds with the aliphatic alkyl that carbon atom number is 10 ~ 24
(A2)：The phosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A3)：The thiophosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A4)：The diamine compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(B1)：The sulfonate that whole carbon atom numbers of average 1 sulfo group are 23 or more
(B2)：Polyol partial esters
(B3)：The polymer that number-average molecular weight is 600 ~ 5000
(B4)：The resin that number-average molecular weight is 400 ~ 3500
(B5)：Wax
(B6)：Succimide compound.
[2] manufacturing method of anticorrosive oil composition, will be in following (A1) ~ (A4) ingredient and their organic salt extremely
Few a kind of deicer (A),
At least one kind of antirust agent (B) in following (B1) ~ (B6) ingredient,
40 DEG C of kinematic viscosity are 20mm2/ s light mineral oil below (C) and
40 DEG C of kinematic viscosity are 80mm2The heavy mineral oil (D) of/s or more is cooperated, and anticorrosive oil composition is obtained；
(A1)：Imidazolinium compounds with the aliphatic alkyl that carbon atom number is 10 ~ 24
(A2)：The phosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A3)：The thiophosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A4)：The diamine compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(B1)：The sulfonate that whole carbon atom numbers of average 1 sulfo group are 23 or more
(B2)：Polyol partial esters
(B3)：The polymer that number-average molecular weight is 600 ~ 5000
(B4)：The resin that number-average molecular weight is 400 ~ 3500
(B5)：Wax
(B6)：Succimide compound.
The effect of invention
In the present invention, providing can make water removal property, rust-preventing characteristic and water separable performance reach good anticorrosive oil composition.
Specific embodiment
Hereinafter, being illustrated for the present invention using embodiment.
Anticorrosive oil composition involved in an embodiment of the invention includes selected from following (A1) ~ (A4) ingredient and it
Organic salt at least one kind of deicer (A), at least one kind of antirust agent (B) in following (B1) ~ (B6) ingredient, 40 DEG C
Kinematic viscosity is 20mm2/ s light mineral oil below (C) and 40 DEG C of kinematic viscosity are 80mm2The heavy mineral oil of/s or more
(D)；
(A1)：Imidazolinium compounds with the aliphatic alkyl that carbon atom number is 10 ~ 24
(A2)：The phosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A3)：The thiophosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A4)：The diamine compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(B1)：The sulfonate that whole carbon atom numbers of average 1 sulfo group are 23 or more
(B2)：Polyol partial esters
(B3)：The polymer that number-average molecular weight is 600 ~ 5000
(B4)：The resin that number-average molecular weight is 400 ~ 3500
(B5)：Wax
(B6)：Succimide compound.
In the anticorrosive oil composition of present embodiment, except both aqueous and rust-preventing characteristics reach good, but if without above-mentioned
(A), (B), any one in (D) ingredient, then except in aqueous and rust-preventing characteristic any performance it is poor.It should be noted that anticorrosive oil composition is such as
Fruit removes aqueous reduction, then can not sufficiently go to remove water from metal material when anticorrosive oil composition being coated on metal material, have
When be unable to fully antirust.In addition, if being free of (C) ingredient, then stability of solution is deteriorated, or becomes to the impregnability of metal material
Difference.
In addition, the anticorrosive oil composition of present embodiment can be such that water separates by containing above-mentioned (A), (B), (D) ingredient
Property reaches good.It should be noted that having various working fluids, alkaline cleaner etc., but this as the moisture for being attached to metal material surface
The anticorrosive oil composition of embodiment, which passes through, contains (A), (B), (D) ingredient, is not only easy to make to common working fluid but also right
The water separable performance of the aqueous solution of the alkalinity such as alkaline cleaner also reaches good.
Further, the anticorrosive oil composition of present embodiment is also easy to reach degreasing well, but by making degreasing
Become good, can easily by metal material surface the anticorrosive oil composition of overlay film fall off.
< deicer (A) >
As deicer (A), using one kind or two or more in above-mentioned (A1) ~ (A4) ingredient and their organic salt.On
It states (A1) ~ (A4) ingredient and passes through the aliphatic alkyl with size to a certain degree, so as to improve anticorrosive oil composition
Except aqueous without damaging rust-preventing characteristic.Hereinafter, (A1) ~ (A4) ingredient is described in more detail.
[(A1) ingredient]
As (A1) if it is 10 ~ 24 aliphatic alkyl that the imidazolinium compounds of ingredient, which has carbon atom number, but if the rouge
The carbon atom number of fat race alkyl is lower than 10, then removes aqueous reduction, and further also water separable performance reduces sometimes.On the other hand, (A1)
If the above-mentioned carbon atom number of ingredient is greater than 24, it is difficult to industrial acquisition.
From the above point of view, the carbon atom number of above-mentioned aliphatic alkyl is preferably 10 ~ 22, more preferably 11 ~ 20.
In addition, the imidazolinium compounds as (A1) ingredient can specifically enumerate following formula (1) compound represented.
[chemical formula 1]
In formula (1), R1Indicate that carbon atom number is 10 ~ 24 aliphatic alkyl；R2Indicate that optionally the carbon atom number with hydroxyl is 1
~ 4 alkyl or hydrogen atom.
In formula (1), R1Alkyl, alkenyl, unsaturated fatty hydrocarbons base with 2 ~ 3 double bonds etc. can be enumerated, wherein excellent
It is selected as alkyl, alkenyl.R1Can be straight-chain, branched, it is possible to have cyclic structure, specifically, can enumerate decyl,
Isodecyl, undecyl, lauryl, Permethyl 99A base, tridecyl, myristyl, different myristyl, pentadecyl, palm
Base, heptadecyl, isocetyl, stearyl, isooctadecane base, nonadecyl, eicosyl, behenyl base, undecenyl,
Cis- -4- tetradecene base, cis- -5- tetradecene base, cis- -9- tetradecene base, cis- -6- hexadecene base, palm
Oleyl, cis- -6- octadecene base, oleyl, trans- -9- octadecene base, cis- -11- octadecene base, anti-form-1 1-
Octadecene base, sub-oleyl etc..
R2Optionally with hydroxyl carbon atom number be 1 ~ 4 alkyl can be branch or straight chain.In addition, having hydroxyl
When, hydroxyl is usually 1, specifically, hydroxy alkyl can be enumerated.As R2More detailed concrete example, hydrogen can be enumerated
Atom, methyl, ethyl, propyl, isopropyl, butyl, isobutyl group, sec-butyl, tert-butyl, hydroxymethyl, 1- hydroxyethyl, 2- hydroxyl
Base ethyl, 1- hydroxypropyl, 2- hydroxypropyl, 3- hydroxypropyl, 1- hydroxybutyl, 2- hydroxybutyl, 3- hydroxybutyl, 4- hydroxyl
Base butyl etc., among these, preferably 2- hydroxyethyl.
As imidazolinium compounds, preferably R2For the alkyl or alkenyl -2- hydroxyethyl imidazolines chemical combination of 2- hydroxyethyl
Object.
In addition, R1Preferably carbon atom number be 10 ~ 22 aliphatic alkyl, more preferably carbon atom number be 11 ~ 20 rouge
Fat race alkyl.Further, R1Preferably straight chain.
As the concrete example of suitable imidazolinium compounds, undecyl -2- hydroxyethyl imidazolines, oily alkene can be enumerated
Base -2- hydroxyethyl imidazolines etc. can also further enumerate the R such as tall oil -2- hydroxyethyl imidazolines1It is mixed comprising a variety of
Close object etc..Among these, most preferably undecyl -2- hydroxyethyl imidazolines.
(A1) ingredient can be used singly or in combination of two or more.
[(A2) ingredient]
In phosphate based compound as (A2) ingredient, the total carbon atom number of the aliphatic alkyl for including in a molecule is 8 ~
40.If the total carbon atom number is lower than 8 or is greater than 40, rust-preventing characteristic is likely to decrease except performances such as aqueous, water separable performances.From
From the perspective of keeping various performances better, above-mentioned total carbon atom number is preferably 10 ~ 38, more preferably 12 ~ 36.
In addition, it is 8 or more aliphatic alkyl that phosphate based compound, which preferably has carbon atom number, more preferably have carbon former
The aliphatic alkyl that subnumber is 8 ~ 24, the aliphatic alkyl for being more preferably 10 ~ 18 with carbon atom number.By with such rouge
Fat race alkyl, phosphate based compound are easy to play above-mentioned various performances.
Above-mentioned aliphatic alkyl can enumerate alkyl, alkenyl, unsaturated fatty hydrocarbons base with 2 ~ 3 double bonds etc.,
In, preferably alkyl, alkenyl.
In addition, phosphate based compound can be phosphate, or phosphite ester.
As phosphate, specifically, following formula (2) compound represented can be enumerated.
(R3O-)nP(=O)(-OH)3-n (2)
In formula (2), n indicates 1 or 2, R3Indicate aliphatic alkyl, the R in a molecule3Total carbon atom number be 8 ~ 40.N is 2
When, R3Can be mutually the same, it can also be different.
In formula (2), R3Alkyl, alkenyl, unsaturated fatty hydrocarbons base with 2 ~ 3 double bonds etc. can be enumerated, wherein excellent
It is selected as alkyl, alkenyl.R3It can be straight-chain or branched, it is possible to have cyclic structure, preferably straight-chain or branched.
Each R3It is 10 ~ 18 that usual carbon atom number, which is 1 ~ 24, preferably carbon atom number is 8 ~ 24, more preferable carbon atom number.In addition, n is preferably
1。
It should be noted that formula (2) compound represented is also referred to as so-called phosphate ester acid.
As R3Preferred concrete example, can enumerate octyl, 2- ethylhexyl, nonyl, isononyl, decyl, isodecyl,
Undecyl, lauryl, Permethyl 99A base, tridecyl, myristyl, different myristyl, pentadecyl, palmityl, 17
Alkyl, isocetyl, stearyl, isooctadecane base, nonadecyl, eicosyl, behenyl base, undecenyl, cis- -4-
Tetradecene base, cis- -5- tetradecene base, cis- -9- tetradecene base, cis- -6- hexadecene base, palm oleyl,
Cis- -6- octadecene base, oleyl, trans- -9- octadecene base, cis- -11- octadecene base, 18 carbon of anti-form-1 1-
Alkenyl etc..
As formula (2) compound represented, more preferably n is 1 and R3The alkyl or carbon atom for being 8 ~ 24 for carbon atom number
Number for 8 ~ 24 alkenyl compound, as specifically suitable compound, can enumerate phosphoric acid 2- ethylhexyl, octyl phosphate,
The different nonyl ester of phosphoric acid, phosphoric acid nonyl ester, isodecyl ester, phosphoric acid last of the ten Heavenly stems ester, lauryl phosphate, phosphoric acid tridecane base ester, phosphoric acid nutmeg
Base ester, phosphoric acid palm base ester, phosphoric acid stearyl, phosphoric acid oleyl ester, phosphoric acid isooctadecane base ester, the anti-oleyl ester of phosphoric acid
Deng particularly preferably phosphoric acid 2- ethylhexyl, phosphoric acid oleyl ester.
In addition, as phosphite ester, specifically, following formula (3) compound represented can be enumerated.
(R4O-)mP(-OH)3-m (3)
In formula (3), m indicates 1 or 2, R4Indicate aliphatic alkyl, the R in a molecule4Total carbon atom number be 8 ~ 40.M is 2
When, R4Can be mutually the same, it can also be different.
In formula (3), R4Alkyl, alkenyl, unsaturated fatty hydrocarbons base with 2 ~ 3 double bonds etc. can be enumerated, wherein excellent
It is selected as alkyl, alkenyl.R4It can be straight-chain or branched, it is possible to have cyclic structure, preferably straight-chain or branched.
Usual R4Carbon atom number be 1 ~ 24, preferably carbon atom number is 8 ~ 24, more preferable carbon atom number is 12 ~ 18.In addition, m is preferably
2。
It should be noted that formula (3) compound represented is also referred to as so-called acid phosphite ester.
As R4Preferred concrete example, above-mentioned R can be enumerated3In each functional group for enumerating.
As formula (3) compound represented, preferably m is 2 and R4For carbon atom number be 8 ~ 24 alkyl or carbon atom number
For the compound of 8 ~ 24 alkenyl, specifically, phosphorous acid two (2- ethylhexyl) ester, dioctyl phosphite, Asia can be enumerated
Phosphoric acid dinonyl, two nonyl ester of phosphorous acid, phosphorous acid diisodecyl ester, didecyl phosphite, phosphorous acid dilauryl ester, phosphorous acid
Two (tridecyl) esters, phosphorous acid myristyl ester, two palm base ester of phosphorous acid, phosphorous acid distearyl base ester, phosphorous acid two
Oleyl ester etc..Wherein particularly, particularly preferably two oleyl ester of phosphorous acid, phosphorous acid dilauryl ester.
(A2) ingredient can be used singly or in combination of two or more.
[(A3) ingredient]
In thiophosphate based compound as (A3) ingredient, the total carbon atom number for the aliphatic alkyl for including in a molecule
It is 8 ~ 40.If the total carbon atom number is lower than 8, become inadequate except aqueous etc..In addition, if be greater than 40, then rust-preventing characteristic etc.
Performance is likely to decrease.From the viewpoint of keeping various performances better, above-mentioned total carbon atom number is preferably 12 ~ 38, more preferably
It is 20 ~ 36.
Above-mentioned aliphatic alkyl can enumerate alkyl, alkenyl, unsaturated fatty hydrocarbons base with 2 ~ 3 double bonds etc.,
In, preferably alkyl, alkenyl.
In addition, thiophosphate based compound can be thiophosphate, or thiophosphite, preferably sulphur
Substituted phosphate.
As thiophosphate, specifically, following formula (4) compound represented can be enumerated.
S=P(-OR5)(-OR5)(-OR5) (4)
(in formula (4), R5For alkyl, the total carbon atom number of aliphatic alkyl is 8 ~ 40；Multiple R5Can it is mutually the same, can also be with
It is different).
As R5, specifically, alkyl, alkenyl, alkylaryl, the unsaturated fat with 2 ~ 3 double bonds can be enumerated
Race's alkyl etc..Alkyl, alkenyl, with 2 ~ 3 double bonds unsaturated fatty hydrocarbons base and alkylaryl in alkyl can be straight
Chain, or branched can also have cyclic structure, preferably any one in straight or branched.
In addition, the R as alkyl, alkenyl or the unsaturated fatty hydrocarbons base with 2 ~ 3 double bonds5Usual carbon atom number
It is 8 ~ 24, more preferable carbon atom number for 1 ~ 24, preferably carbon atom number is 10 ~ 18.
On the other hand, R5When for alkylaryl, the usual carbon atom number of alkyl in alkylaryl is 1 ~ 18, preferred carbon atom
It is 8 ~ 10 that number, which is 8 ~ 12, particularly preferred carbon atom number,.
In addition, as R5Functional group, it is above-mentioned among, preferably alkylaryl, particularly preferably alkyl phenyl.
As R5Specific functional group, can enumerate octyl, 2- ethylhexyl, nonyl, isononyl, decyl, isodecyl,
Undecyl, lauryl, tridecyl, myristyl, pentadecyl, palmityl, heptadecyl, stearyl, palm oleyl,
Oleyl, octyl phenyl, 2- ethylhexyl phenyl, nonyl phenyl, isononyl phenyl, decyl phenyl, isodecyl phenyl, hendecane
Base phenyl etc..
As the compound of preferred (A3) ingredient, three (alkyl phenyls) that the carbon atom number of alkyl is 8 ~ 10 can be enumerated
Thiophosphate, specifically, tri o cresyl thiophosphate (octyl phenyl) ester, tri o cresyl thiophosphate (2- ethylhexyl phenyl) can be enumerated
Ester, tri o cresyl thiophosphate (nonyl phenyl) ester, tri o cresyl thiophosphate (isononyl phenyl) ester, tri o cresyl thiophosphate (decyl phenyl) ester, sulphur
For tricresyl phosphate (isodecyl phenyl) ester, tri o cresyl thiophosphate (alkyl phenyl) ester, (wherein, alkyl is the alkyl that carbon atom number is 8 ~ 10
Mixture) etc..
(A3) ingredient can be used singly or in combination of two or more.
[(A4) ingredient]
The total carbon atom number for the aliphatic alkyl that diamine compound as (A4) ingredient includes in a molecule is 8 ~ 40.Such as
The fruit total carbon atom number is lower than 8 or is greater than 40, then rust-preventing characteristic, be likely to decrease except performances such as aqueous, water separable performances.From making
From the perspective of dissolubility in mineral oil reaches good, above-mentioned total carbon atom number is preferably 8 ~ 30, further from make with plus
From the perspective of the separation property of work liquid reaches good, above-mentioned carbon atom number is more preferably 18 ~ 30.
(A4) aliphatic alkyl possessed by ingredient can be in the aliphatic alkyl of 1 valence or the aliphatic alkyl of divalent
Both one, preferably comprise.
As the aliphatic alkyl of 1 valence, alkyl, alkenyl, the unsaturated fatty hydrocarbons base with 2 ~ 3 double bonds can be enumerated
Deng, wherein preferably alkyl, alkenyl.
As the aliphatic alkyl of divalent, the unsaturation of alkylidene, alkenylene, divalent with 2 ~ 3 double bonds can be enumerated
Aliphatic alkyl etc., wherein preferably alkyl, alkenyl.It should be noted that so-called alkylidene further includes alkylidene radical herein.
As diamine compound, specifically, following formula (5) compound represented can be enumerated.
R6-NH-R7-NH2 (5)
(in formula (5), R6The alkyl or alkenyl for being 1 ~ 39 for carbon atom number, R7The alkylidene or sub- alkene for being 1 ~ 39 for carbon atom number
Base, R6And R7Total carbon atom number be 8 ~ 40).
R6And R7Total carbon atom number making the dissolubility in mineral oil reach good, preferably 8
~ 30, further more preferably 18 ~ 30 from the viewpoint of making to reach good with the separation property of working fluid.
R6Carbon atom number be preferably 2 ~ 35, more preferably 15 ~ 25.R6It can be straight-chain, branched, it is possible to have
Cyclic structure, specifically, decyl, isodecyl, undecyl, lauryl, Permethyl 99A base, tridecyl, meat can be enumerated
Myristyl, different myristyl, pentadecyl, palmityl, heptadecyl, isocetyl, stearyl, isooctadecane base, 19
Alkyl, eicosyl, behenyl base, undecenyl, cis- -4- tetradecene base, cis- -5- tetradecene base, cis- -9- ten
Four carbene bases, cis- -6- hexadecene base, palm oleyl, cis- -6- octadecene base, oleyl, 18 carbon of trans- -9-
Alkenyl, cis- -11- octadecene base, anti-form-1 1- octadecene base, sub-oleyl etc..
R7Carbon atom number be preferably 1 ~ 6, more preferably 2 ~ 5.R7It can be straight-chain, branched, it is possible to have cyclic annular
Structure, specifically, can enumerate methylene, ethylidene, ethidine, trimethylene, propylidene, isopropylidene, tetramethylene,
Butylidene, isobutylene, pentylidene, hexa-methylene, hexylidene etc..
As the concrete example of formula (6) compound represented, can enumerate N- octyl ethylenediamine, N- dodecyl ethylenediamine,
The monosubstituted second of N- such as N- cetyl ethylenediamine, N- octadecyl ethylenediamine, N- oleyl ethylenediamine, N- tallow alkyl ethylenediamine
Diamines；N- octyl trimethylene diamine, N- dodecyl trimethylene diamine, N- cetyl trimethylene diamine, N- 18
Alkyl trimethylene diamine, N- oleyl trimethylene diamine, N- Cocoalkyl trimethylene diamine, three methylene of N- tallow alkyl
The monosubstituted trimethylene diamines of N- such as base diamines, N- hardening tallow alkyl trimethylene diamine；N- lauryl butanediamine, N- six are sub-
The monosubstituted butanediamine of N- such as butyl diamines, N- octadecyl butanediamine, N- tallow alkyl butanediamine, N- Cocoalkyl butanediamine
Deng.It should be noted that among these diamine compounds, " Cocoalkyl ... diamines ", " tallow alkyl ... diamines ", " hardening ox
Rouge alkyl ... diamines " refers to that the diamine compound is to be manufactured by coconut oil, coconut oil fat, tallow etc. by well known means
The substance of the saturated or unsaturated aliphatic hydrocarbon residue for the range that carbon atom number is 8 ~ 20 accounts for the mixing of the amine of its main component
Object (mixed alkyl amine).
(A4) ingredient can be used singly or in combination of two or more.
[organic salt]
As organic salt used in (A) ingredient, the organic salt (A1- formed by (A1) ingredient and (A2) ingredient can be enumerated
A2), the organic salt (A4-A2) that is formed by (A4) ingredient and (A2) ingredient, by above-mentioned (A1) ingredient and other than (A2) ingredient
Organic acid (E1) formed organic salt (A1-E1), formed by (A4) ingredient and organic acid (E1) organic salt (A4-E1), on
State the organic salt (A2-E2) etc. that (A2) ingredient is formed with the organic base (E2) other than above-mentioned (A1) ingredient and (A4) ingredient.
The forming method of organic salt is not particularly limited, can be by (A1) ingredient and (A2) ingredient, (A4) ingredient and (A2)
Ingredient, (A1) ingredient and organic acid (E1), (A2) ingredient and organic base (E2) or (A4) ingredient and organic acid (E1) are pre-formed
Organic salt, and the organic salt is matched in anticorrosive oil composition.Alternatively, can by (A1) ingredient and (A2) ingredient, (A4) at
Divide and (A2) ingredient, (A1) ingredient and organic acid (E1), (A2) ingredient and organic base (E2) or (A4) ingredient and organic acid (E1)
It is individually matched in composition, and forms organic salt in the composition.
It should be noted that by above-mentioned (A1) ingredient and (A2) components matching in composition when, usually in anticorrosive oil composition
In comprising the organic salt (A1-A2) that is formed by (A1) ingredient and (A2) ingredient, but (A1) ingredient, one in (A2) ingredient at this time
Machine salt can be formed without and be present in anticorrosive oil composition by dividing.It should be noted that the following description is various, (A1) ingredient is stated
When with the combination of (A2) ingredient, they can partly or entirely form organic salt in anticorrosive oil composition, can also be formed without
Machine salt.Similarly, in the composition cooperation (A4) ingredient and (A2) ingredient, (A1) ingredient and organic salt (E1), (A2) ingredient and
When organic base (E2) or (A4) ingredient and organic acid (E1), a part in (A1) ingredient, (A2) ingredient or (A4) ingredient can also
To be formed without machine salt.
As organic acid (E1), various carboxylic acids can be enumerated.As the carbochain of carboxylic acid, can preferably enumerate carbon atom number is
8 ~ 24 carbochain can more preferably enumerate the carbochain that carbon atom number is 10 ~ 20.
The carbochain of carboxylic acid can be straight-chain or branched, it is possible to have cyclic structure.In addition, as the specific of carboxylic acid
Example, can enumerate aliphatic monocarboxylic acid, aliphatic dicarboxylic acid, the half ester of aliphatic dicarboxylic acid, aromatic monocarboxylate, aromatics dicarboxyl
Acid, the partial esterification object of the polyacid with 3 or more carboxyls and polyacid, unsaturated aliphatic carboxylic acid polymerized fatty acid
Deng, among these, preferably aliphatic monocarboxylic acid, aliphatic dicarboxylic acid, the half ester of aliphatic dicarboxylic acid, aromatic monocarboxylate.
More specifically, as aliphatic monocarboxylic acid, octanoic acid, n-nonanoic acid, octanoic acid, neodecanoic acid, hendecanoic acid, the moon can be enumerated
Cinnamic acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitinic acid, stearic acid, palmitoleic acid, oleic acid etc., as aliphatic dicarboxyl
Acid can enumerate succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, decanedioic acid, heneicosanedioic acid, dodecane
Diacid, tetracosandioic acid, octadecane diacid, cyclohexane cyclohexanedimethanodibasic, hexahydrotoluene dioctyl phthalate etc..Further, as aliphatic
The half ester of dicarboxylic acids can enumerate 1 in aforementioned aliphatic dicarboxylic acid the substance being esterified, alkyl or alkenyl succinic acid
Half ester etc..Further, as aromatic monocarboxylate, toluic acid, naphthoic acid, methyl naphthoic acid, phenylacetic acid etc. can be enumerated, is made
For aromatic dicarboxylic acid, terephthalic acid (TPA), M-phthalic acid, phthalic acid, naphthalenedicarboxylic acid, biphenyl dicarboxylic acid etc. can be enumerated.
In addition, can enumerate as polymerized fatty acid by polymerized fatty obtained from the polymerization of the unsaturated aliphatics carboxylic acid such as ricinoleic acid
Acid etc..Among these, preferably oleic acid, toluic acid, dodecanedioic acid, alkyl or alkenyl succinic acid half ester, neodecanoic acid, castor-oil plant
The polymerized fatty acid of oleic acid.
Carboxylic acid can be used singly or in combination of two or more.
As organic base (E2), various amine can be enumerated.Amine as organic base (E2) can be primary amine, secondary amine and tertiary amine
In any one, preferably primary amine.The total carbon atom number of amine is preferably that 8 ~ 20, more preferable carbon atom number is 8 ~ 18.In addition, the amine can
General formula NR is used to enumerateEIt indicates, REAmong 1 ~ 3 be alkyl, the substance remaining as hydrogen atom.Alkyl can be straight-chain, branch
Chain, it is possible to have cyclic structure.It should be noted that alkyl can preferably enumerate alkyl or alkenyl.It should be noted that the carbon of alkyl
As long as atomicity is 1 ~ 20, preferably 8 ~ 18.
In addition, the preferred concrete example as amine, can enumerate octyl amine, nonyl amine, decyl amine, lauryl amine, Pork and beans
Cool base amine, palmityl amine, stearic amine, oleyl amine etc., wherein more preferably octyl amine, oleyl amine.
Amine can be used singly or in combination of two or more.
As (A) ingredient, as long as using a kind or 2 kinds in above-mentioned (A1) ~ (A4) ingredient or their organic salt
It is above.But, it is preferable to use being selected from least 1 in (A1) ingredient, (A2) ingredient and their organic salt among these
Kind, more preferably using at least one kind of in (A1) ingredient and their organic salt.In present embodiment, by using (A1)
Ingredient, make rust-preventing characteristic, except it is aqueous reach good while, be easy that degreasing, water separable performance etc. is made also to reach good.
< antirust agent (B) >
As antirust agent (B), using one kind or two or more in above-mentioned (B1) ~ (B6) ingredient.
[(B1) ingredient]
As (B1) ingredient, the sulfonate that whole carbon atom numbers using average 1 sulfo group are 23 or more.If average 1 sulphur
Whole carbon atom numbers of base are lower than 23, then are difficult to make to reach good except aqueous, rust-preventing characteristic.Whole carbon atoms of average 1 sulfo group
Several quantity from the viewpoint of being improved with good balance except aqueous, rust-preventing characteristic etc., preferably 23 ~ 40, more preferably 25 ~
35。
Sulfonate as (B1) ingredient is the metal salt of various sulfonic acid.
The sulfonic acid of sulfonate preferably has alkyl phenyl structure (that is, Alkyl-Ph-SO3 -(Alkyl indicates alkyl, Ph
Indicate phenyl ring)), the sulfonic acid of alkylnaphthalene based structures, more preferably there are alkylnaphthalene based structures.That is, as sulfonic acid, more preferably alkyl
Benzene sulfonic acid, alkyl naphthalene sulfonic acid, further preferably alkyl naphthalene sulfonic acid.It should be noted that being bonded to naphthalene skeleton in alkylnaphthalene based structures
The quantity of alkyl be usually 1, but may be 2 or more.Similarly, in alkyl phenyl structure, it is bonded to benzene skeleton
The quantity of alkyl is usually 1, but may be 2 or more.
Sulfonic acid except aqueous by being easy to become excellent, the moisture of further anticorrosive oil composition with alkylnaphthalene based structures
It is easy to become good from property.
In addition, as metal used in sulfonate lithium, sodium, magnesium, zinc, calcium, barium, preferably calcium, barium can be enumerated, more
Preferably calcium.By using calcium, barium, it is easy to become excellent except aqueous.
It can be neutral sulfonate as sulfonate, or alkaline sulfonate can also be overbased sulfonates,
In order to enable reach well with the adaptability of the packaging materials such as rust-preventing film, preferably neutral sulfonate.
The base number of neutral sulfonate is lower than 30mgKOH/g.In addition, the base number of alkalinity or overbased sulfonates does not limit especially
System, preferably 200mgKOH/g or less, more preferably 30 ~ 150mgKOH/g, further preferably 30 ~ 100mgKOH/g.
It should be noted that whole carbon atom numbers of each sulfo group refer to the sulfo group (RSO in (B1) ingredient3) respectively contain it is complete
The average value of portion's carbon atom number (that is, carbon atom number of R).
(B1) ingredient can be used singly or in combination of two or more.
[(B2) ingredient]
As (B2) ingredient, polyol partial esters are used.Partial ester refer at least one of the hydroxyl in polyalcohol or more be not esterified and
The directly remaining ester in the form of hydroxyl.In the case where full ester is formed without hydroxyl, ester removes aqueous reduction.
As the concrete example of polyol partial esters, trimethylolpropane, pentaerythrite or sorbitan can be enumerated
Partial ester, from the viewpoint of except aqueous, water separable performance, the preferably partial ester of trimethylolpropane, pentaerythrite.
As partial ester, the esterified monoesters of preferably 1 hydroxyl, 2 esterified diester of hydroxyl.
In addition, the alcohol for partial ester can be used singly or in combination of two or more.
If be more particularly described, it is used as partial ester, can be enumerated selected from trimethylolpropane, pentaerythrite or dehydration mountain
The ester that the fatty acid that polyalcohol and carbon atom number in pears sugar alcohol are 8 ~ 24 is formed.Fatty acid is monocarboxylic acid, can be saturated fat
Fat acid or unsaturated fatty acid, furthermore can be straight-chain fatty acid or branched fatty acid.The carbon atom number of fatty acid is from anti-
More preferably 10 ~ 24, further preferably 12 ~ 18 from the perspective of rust property.
As specific fatty acid, it can be cited for example that octanoic acid, 2 ethyl hexanoic acid, n-nonanoic acid, isononanoic acid, capric acid, isodecyl it is sour,
Hendecanoic acid, lauric acid, different lauric acid, tridecanoic acid, myristic acid, different myristic acid, pentadecanoic acid, palmitinic acid, different palm
Acid, stearic acid, isostearic acid, arachidic acid, behenic acid, undecenoic acid, cis- -4- tetradecenoic acid, cis- -5- tetradecene
Acid, cis-9-tetradecenoate, cis-6-hexadecenoic acid, palmitoleic acid, cis--petroselinic acid, oleic acid, it is trans--
9- octadecenoic acid, cis--vaccenic acid, anti-form-1 1- octadecenoic acid etc., among these, preferably oleic acid.
Fatty acid can be used singly or in combination of two or more.
As the suitable concrete example of polyol partial esters, trimethylolpropane monolaurate, trihydroxy methyl third can be enumerated
Alkane list myristinate, trimethylolpropane monopalmitate, trimethylolpropane monostearate, trimethylolpropane list oil
The trimethylolpropanes monoesters such as acid esters；Pentaerythritol monolaurate, pentaerythrite list myristinate, pentaerythrite list palm
The pentaerythrites monoesters such as acid esters, pentaerythritol monostearate, pentaerythritol monooleate；Sorbitan mono laurate
Ester, span 40, sorbitan monostearate, takes off sorbitan list myristinate
The anhydrosorbitol monoesters such as water sorbitol monooleate；Trimethylolpropane dilaurate, two meat of trimethylolpropane
Myristate, trimethylolpropane dipalmitate, trimethylolpropane distearate, trimethylolpropane dioleate etc.
Trimethylolpropane diester；Pentaerythrite dilaurate, two myristinate of pentaerythrite, pentaerythrite dipalmitate,
The pentaerythritol diesters such as pentaerythritol stearate, pentaerythrite dioleate；Sorbitan dilaurate, dehydration
Two myristinate of D-sorbite, sorbitan dipalmitate, dehydrated sorbitol distearate, Sorbitan
Sorbitans diester such as alcohol dioleate etc., among these, particularly preferably trimethylolpropane dioleate, Ji Wusi
Alcohol monoleate.
[(B3) ingredient]
As (B3) ingredient, the polymer for the use of number-average molecular weight being 600 ~ 5000.It should be noted that so-called poly- in (B3) ingredient
It closes object and refers to the substance without ring structure.
If number-average molecular weight is lower than 600, the film thickness formed on the metal surface is thinning, and rust-preventing characteristic is easily reduced.This
Outside, if it is greater than 5000, then degreasing reduces, it is difficult to remove the anticorrosive oil composition of overlay film on the metal surface.
From these viewpoints, above-mentioned number-average molecular weight is preferably 600 ~ 4000, more preferably 710 ~ 3000.
It should be noted that the number-average molecular weight of (B3) ingredient and aftermentioned (B4) ingredient passes through in a manner of shown in aftermentioned embodiment
GPC method is found out in terms of polystyrene conversion.
As polymer used in (B3) ingredient, can enumerate selected from polybutene, polyisobutene, poly-methyl methacrylate
It is one kind or two or more in ester (PMMA) and their derivative.Among these, from being easy that various performances is made to reach good sight
Point sets out, preferably polybutene.
As polybutene, object obtained from being polymerize the various butylene such as butene-1, butene-2, isobutene can be enumerated
Matter.In addition, substance obtained from being polymerize isobutene can be enumerated as polyisobutene.Further, as polybutene and
The derivative of polyisobutene can be enumerated and carry out substance obtained from adding hydrogen to them.
It should be noted that polybutene and each leisure of polyisobutene can have on a small quantity in the range of not impacting to its character
The structural unit for being originated from the monomer other than butylene and isobutene of (such as 20 mass % or less of entire infrastructure unit).
It is substance obtained from being polymerize methyl methacrylate as polymethyl methacrylate.In addition, conduct
The derivative of polymethyl methacrylate can be enumerated by methyl methacrylate and other than methyl methacrylate
Substance obtained from vinyl monomer is polymerize, at this point, the structural unit for generally originating from methyl methacrylate is formed mainly
Ingredient (for example, 70 mass % or more of entire infrastructure unit).
(B3) ingredient can be used singly or in combination of two or more.
[(B4) ingredient]
As (B4) ingredient, the resin for the use of number-average molecular weight being 400 ~ 3500.If the number-average molecular weight of resin is lower than 400,
It is then unable to fully improve rust-preventing characteristic.In addition, if being greater than 3500, then degreasing is deteriorated, and is easy to happen and is difficult to from metal material
The defects of removing the anticorrosive oil composition of overlay film.
The number-average molecular weight of above-mentioned (B4) ingredient is more preferably 450 ~ 2000, further preferably 500 ~ 1500.Passing through will
Molecular weight is set as within the scope of these, is easy that rust-preventing characteristic and degreasing is made to reach better.
The resin of referred to as (B4) ingredient refers to the substance with ring structure.In addition, (B4) ingredient can specifically be enumerated
Petropols, terpene resin etc., among these, preferably Petropols.(B4) ingredient is by being easy to improve with cyclic structure
Rust-preventing characteristic.
As Petropols, preferably hydrogenated petroleum resin, can compatibly enumerate for example to bicyclopentadiene and aromatics
The copolymer of compound carries out substance obtained from adding hydrogen.Hydrogenated petroleum resin can be part hydrogenated petroleum resin, complete hydrogen
Any one in fossil oleoresin, preferably part hydrogenated petroleum resin.
(B4) ingredient can be used singly or in combination of two or more.
[(B5) ingredient]
As (B5) ingredient, wax is used.Wax preferably its fusing point is 30 ~ 80 DEG C.By the way that fusing point is set as 30 DEG C or more, it is easy to make to prevent
Rust property becomes good.In addition, by being set as 80 DEG C hereinafter, low-temperature stability becomes well, to be easy to produce wax and lack at analyzing etc.
It falls into.The fusing point of wax is preferably 35 ~ 65 DEG C, more preferably 40 ~ 55 DEG C.
It is preferably oxidized wax from the viewpoint of rust-preventing characteristic, from degreasing, smelly using paraffin wax, oxidized wax as wax
From the perspective of gas, preferably paraffin wax.
Oxidized wax uses substance obtained from for example being aoxidized paraffin wax.Oxidized wax such as its acid value be 10 ~
It 200, is preferably 20 ~ 100, more preferably 30 ~ 80.It should be noted that acid value refers to by based on JIS K 2501:2003 current potential
Poor method and the value measured.In addition, the fusing point of wax is based on JIS K0064：The value of 2014 measurements.
(B5) ingredient can be used singly or in combination of two or more.
[(B6) ingredient]
As (B6) ingredient, succimide compound is used.
As the succimide compound for being used as (B6) ingredient, it can be cited for example that the monotype with 1 imide
Succimide compound, the succimide compound of dimorphism with 2 or more imides etc..Among these,
From the viewpoint of being improved with good balance except aqueous, rust-preventing characteristic, stoste stability etc., the preferably succimide of monotype
Compound.
As the succimide compound of monotype, it is preferably selected from allyl butyrate imide compound and its derivative
At least one kind of, more preferably following formula (6) compound represented.
[chemical formula 2]
In formula (6), R8Expression number-average molecular weight is 100 or more and 5,000 alkenyl below, R9Indicate that carbon atom number is 2 ~ 5
Alkylidene, r indicate 1 or more and 10 integers below.
R8Number-average molecular weight from the viewpoint of making rust-preventing characteristic reach excellent, be 100 or more, more preferably 150 or more.
In addition, R8Number-average molecular weight from the viewpoint of making degreasing reach excellent, be 5,000 or less.
R8As long as number-average molecular weight is that 100 or more and 5,000 alkenyl below is then not particularly limited, can enumerate poly-
Cyclobutenyl, polyisobutenyl, the alkenyl comprising polymer such as ethylene-propylene copolymers.Among these, from being easy to make various performances
It is preferably polybutylene-based from the perspective of reaching good.As polybutylene-based, can enumerate 1- butylene, 2- butylene, isobutene
Substance obtained from being polymerize etc. various butylene.In addition, as polyisobutenyl, can enumerate isobutene is polymerize and
Obtained substance.It should be noted that polybutylene-based and each leisure of polyisobutenyl can be in the range of not impacting to its character
The structure for being originated from the monomer other than butylene and isobutene with a small amount of (such as 20 mass % or less of entire infrastructure unit)
Unit.
As R9Shown in alkylidene, ethylidene, propylidene, butylidene, pentylidene etc. can be enumerated, it is excellent among these
It is selected as ethylidene.
R is preferably 2 or more and 5 or less, more preferably 3 or more and 4 or less.If r is 1 or more, favorable dispersibility, such as
Fruit r is 10 hereinafter, then also good to the dissolubility of base oil.
Allyl butyrate imide compound usually can be as making obtained from the reacting of polyolefin and maleic anhydride
Enetutanedioic acid anhydride is reacted with polyamines and is manufactured.
As the olefinic monomer for forming aforementioned polyolefins, the α-that can be 2 ~ 8 by one or two or more kinds of carbon atom numbers
Olefin uses, and can compatibly use the mixture of isobutene and 1- butylene.
In addition, the single diamines such as ethylenediamine, propane diamine, butanediamine, pentanediamine can be enumerated as aforementioned polyamines；Two
Ethylenetriamine, trien, tetren, penten, two (methyl ethylidene) triamines, two butylidenes
The polyalkylene polyamines such as triamine, three butylidene tetramines, five pentylidene hexamines；Bridged piperazine derivatives such as aminoethylpiperazine etc..
The nitrogen content of aforementioned succimide compound is improved from good balance except the viewpoint of aqueous, rust-preventing characteristic etc. goes out
Hair, preferably 0.5 ~ 5.0 mass %, from the viewpoint of improve monomer except aqueous, more preferably 1.0 ~ 4.5 mass %, from
To with (A) ingredient except from the perspective of aqueous synergy, further preferably 1.4 ~ 4.0 mass %.
It is one kind or two or more in above-mentioned (B1) ~ (B6) ingredient using being selected from as (B) ingredient, as (B) ingredient
And, it is preferable to use at least both (B2) ingredient and (B3) ingredient when using two or more.At this point, (A) ingredient is as described above, only
Will be to be at least one kind of in (A1) ~ (A4) ingredient and its organic salt, preferably at least use (A1) ingredient or its is organic
Salt.
In addition it is also preferred that being applied in combination with (B2) ingredient and (B5) ingredient.At this point, (A) ingredient preferably at least uses
(A1) ingredient or its organic salt.With (B2) ingredient and when being applied in combination of (B5) ingredient, (B6) ingredient can be further combined.
Use both (B2) ingredient and (B3) ingredient when, more preferably be selected from (B2) ingredient, (B3) ingredient, (B1) ingredient,
(B4) at least one kind of in ingredient and (B5) ingredient is applied in combination.As specific combination, can enumerate (B1) ingredient, (B2) at
Divide, the combination of (B3) ingredient and (B5) ingredient；(B2) combination of ingredient, (B3) ingredient and (B5) ingredient；(B2) ingredient, (B3)
The combination of ingredient and (B4) ingredient.It certainly, can be for using only the mode of (B2) and (B3) as (B) ingredient.
By the way that (B) ingredient is applied in combination with these, it is easy that rust-preventing characteristic is made to reach better.
It further, further preferably include the mode of (B1) ingredient, for example, can only make as (B) ingredient as (B) ingredient
With (B1) ingredient.At this point, (A) ingredient preferably at least uses (A1) ingredient or its organic salt.But as (B) ingredient, in selection
It, can be selected from the ingredient other than (B1) ingredient when stating a kind in 6 kinds of (B1) ~ (B6) ingredient.
Also, as the suitable concrete example of (A) ingredient and the combination of (B) ingredient, (I) below ~ (XII) can be enumerated.
(I)：(A) ingredient be it is at least one kind of in (A1) ingredient and above-mentioned organic salt (A1-E1), and (B) ingredient be (B1) at
Divide, the combination of (B2) ingredient, (B3) ingredient and (B5) ingredient
(II)：(A) ingredient is the combination of (A1) ingredient and (A2) ingredient, and (B) ingredient is (B1) ingredient, (B2) ingredient, (B3)
The combination of ingredient and (B5) ingredient
(III)：(A) ingredient be it is at least one kind of in (A2) ingredient and organic salt (A2-E2), and (B) ingredient be (B1) at
Divide, the combination of (B2) ingredient, (B3) ingredient and (B5) ingredient
(IV)：(A) ingredient is (A3) ingredient, and (B) ingredient is (B1) ingredient, (B2) ingredient, (B3) ingredient and (B5) ingredient
Combination
(V)：(A) ingredient is (A1) ingredient, and (B) ingredient is the combination of (B2), (B3) and (B5) ingredient
(VI)：(A) ingredient is (A1) ingredient, and (B) ingredient is (B2) ingredient, (B3) ingredient and (B4) ingredient
(VII)：(A) ingredient is (A1) ingredient, and (B) ingredient is the combination of (B2) ingredient, (B3) ingredient and (B5) ingredient
(VIII)：(A) ingredient is (A1) ingredient, and (B) ingredient is the combination of (B2) and (B3) ingredient
(IX) (A) ingredient is (A1) ingredient, and (B) ingredient is (B1) ingredient
(X) (A) ingredient is at least one kind of in organic salt (A1-E1), and (B) ingredient is (B2) ingredient and (B5) ingredient
Combination.
(XI) (A) ingredient is at least one kind of in (A1) ingredient and above-mentioned organic salt (A1-E1), and (B) ingredient is
(B2) combination of ingredient, (B5) ingredient and (B6) ingredient
(XII) (A) ingredient is at least one kind of in (A4) ingredient and above-mentioned organic salt (A4-E1), and (B) ingredient is (B2)
The combination of ingredient, (B5) ingredient and (B6) ingredient.
< (C) and (D) ingredient >
40 DEG C of kinematic viscosity of the light mineral oil as (C) ingredient are 20mm2/ s or less.If 40 DEG C of kinematic viscosity are greater than
20mm2/ s, then anticorrosive oil composition reduces the impregnability of metal material sometimes, is unable to fully to form overlay film sometimes.In addition, molten
Solution property becomes inadequate, and generates the defects of each ingredient being matched in anticorrosive oil composition is insoluble sometimes.
40 DEG C of kinematic viscosity of light mineral oil are preferably 0.5 ~ 10mm2/ s, further preferably 1 ~ 8mm2/s。
In addition, 40 DEG C of kinematic viscosity for being used as the heavy mineral oil of (D) ingredient are 80mm2/ s or more.If 40 DEG C of movements
Viscosity is lower than 80mm2The defects of/s is then difficult to be suitably formed overlay film, and generation is unable to maintain that rust-preventing characteristic.
In addition, 40 DEG C of kinematic viscosity of (D) ingredient are preferably 800mm2/ s or less.By being set as 800mm2/ s is hereinafter, degreasing
Property become good, be easy to remove anticorrosive oil composition from metal material.
From the viewpoint of making degreasing and rust-preventing characteristic reach good with good balance, 40 DEG C of movements of heavy mineral oil
Viscosity is preferably 100 ~ 550mm2/ s, further for making degreasing reach excellent, more preferably 120 ~ 240mm2/ s, in order to make
Rust-preventing characteristic reaches excellent, more preferably 300 ~ 500mm2/s。
Above-mentioned light mineral oil and heavy mineral oil can be enumerated to crude oil is carried out air-distillation and obtain reduced crude
And fraction obtained from being evaporated under reduced pressure gained reduced crude carries out solvent deasphalting, solvent extraction, is hydrocracked, solvent
Dewaxing, catalytic dewaxing, hydrofinishing etc. one or more of processing and the mineral oil etc. that is refining to obtain.
(content of (A) ~ (D) ingredient)
Anticorrosive oil composition is counted on the basis of total composition, preferably comprises above-mentioned (A) ingredient, 1 ~ 40 matter of 0.01 ~ 10 mass %
Measure (D) ingredient of (B) ingredient of %, (C) ingredient of 50 mass % or more, 1 ~ 40 mass %.By by the content of (A) and (B) ingredient
It is set as in above range, is easy to make the rust-preventing characteristic of anticorrosive oil composition and reaches good except aqueous.In addition, passing through (C) ingredient
Content be set as 50 mass % or more, the dissolubility for each ingredient being matched in composition can be made to reach good.Further, lead to
It crosses (D) at being divided into above range, degreasing is also improved while making rust-preventing characteristic reach good.
It should be noted that as (A) ingredient, when using two or more in 4 kinds of above-mentioned (A1) ~ (A4) ingredient, it is also preferred that into
Row is adjusted so that the total content of (A) ingredient reaches above range.It is also the same such for (B) ingredient.
The preferred content of (A) ingredient in anticorrosive oil composition is calculated as 0.05 ~ 8 matter on the basis of total composition
Measure %.By in range that content is set as to such, being easy that both rust-preventing characteristic and water separable performance is made to reach better.In addition, (A)
The content of the total composition benchmark of ingredient is in order to make to reach excellent with the separation property of water, further preferably 0.1 ~ 6 mass %.
It further, is still more preferably 0.3 ~ 1 mass % in order to make to reach excellent with the separation property of water and aqueous alkali.
As described above, it is preferably 1 ~ 40 mass % that the content of (B) ingredient, which amounts to, but the respective content of (B1) ~ (B6) ingredient
Preferred scope is different according to used ingredient.
When using (B1) ingredient, the content of (B1) ingredient also contains other to improve water separable performance with good balance
Ingredient counts preferably 1 ~ 20 mass % on the basis of total composition.In addition, the above-mentioned content of (B1) ingredient is in order to improve degreasing
Property and rust-preventing characteristic, more preferably 3 ~ 10 mass %.
When using (B2) ingredient, the content of (B2) ingredient is in order to while making degreasing reach good, also with good
Balance contains other compositions, and preferably 2 ~ 30 mass % are counted on the basis of total composition.(B2) content of ingredient is in order to ensure
Degreasing is set to reach better while good rust-preventing characteristic, more preferably 10 ~ 25 mass %.
When using (B3) ingredient, the content of (B3) ingredient while ensuring good rust-preventing characteristic in order to make degreasing good
It is good, preferably 1 ~ 30 mass % is counted on the basis of total composition, in order to also contain other compositions with good balance, more preferably
For 3 ~ 15 mass %.
When using (B4) ingredient, the content of (B4) ingredient while ensuring good rust-preventing characteristic in order to make degreasing good
It is good, preferably 0.5 ~ 30 mass % is counted on the basis of total composition, it is more excellent in order to also contain other compositions with good balance
It is selected as 1 ~ 20 mass %.
When using (B5) ingredient, the content of (B5) ingredient is from the viewpoint of making low-temperature stability reach better, with group
Meter is preferably 0.5 ~ 15 mass % on the basis of closing object total amount, from the viewpoint of also making degreasing reach good, more preferably 1 ~ 10
Quality %.
When using (B6) ingredient, the content of (B6) ingredient while ensuring good rust-preventing characteristic in order to make degreasing good
It is good, preferably 1 ~ 30 mass % is counted on the basis of total composition, in order to also contain other compositions with good balance, more preferably
For 3 ~ 15 mass %.
In further present embodiment, as (B) ingredient, two or more in 6 kinds of above-mentioned (B1) ~ (B6) ingredient is used
When (such as (B1) ingredient and (B2) ingredient, (B1) ingredient and (B2) ingredient and (B3) ingredient etc.), particularly preferably by (B1) ~
(B6) the respective content of ingredient be adjusted in above-mentioned respective preferred range or more preferable range in while, by (B) at
The total content divided is adjusted in preferred range (that is, 1 ~ 40 mass %).By adjusting for such amount, it is easy to play (B)
The function of each ingredient of ingredient is easy that rust-preventing characteristic is made to reach good.
In addition, the content of (D) ingredient is preferably 1 ~ 40 mass % as described above, more preferably 2.5 ~ 30 mass %, into one
Step is preferably 5 ~ 20 mass %.In addition, the content of (C) ingredient as described above be preferably 50 mass % or more, formed (A), (B),
(D) surplus of ingredient and aftermentioned other compositions.
(other compositions)
In addition, anticorrosive oil composition in the range of not damaging the purpose of the present invention, can contain in addition to above-mentioned (A) ~ (D) ingredient
Except ingredient (other compositions).Specifically, the base oil other than (C), (D) ingredient can be enumerated, in addition to above-mentioned
(A), the additive except (B) ingredient.
As the base oil other than (C) and (D) ingredient, it can be cited for example that 40 DEG C with light mineral oil (C)
The mineral oil of 40 DEG C of kinematic viscosity between kinematic viscosity and 40 DEG C of kinematic viscosity of heavy mineral oil (D).Such mineral oil
Also in the same manner as above-mentioned light mineral oil and heavy mineral oil, it is able to use the mineral oil for having carried out above-mentioned various refinement treatments.
In addition, antioxidant, inerting agent etc. can be enumerated as the additive other than above-mentioned (A), (B) ingredient.Make
For antioxidant, the phenolic antioxidants such as 2,6- DI-tert-butylphenol compounds, 2,6- di-t-butyl-paracresol, alkylation can be used
The amine antioxidants such as diphenylamine, phenyl-α-naphthylamine.
As inerting agent, it can be cited for example that benzotriazole, thiadiazoles and their derivative etc..
The respective content of other compositions in anticorrosive oil composition counted on the basis of total composition preferably 20 mass % with
Under, more preferably 0.1 ~ 10 mass % range.
The application method > of < anticorrosive oil composition
Anticorrosive oil composition is coated on the surface of metal material and uses.Anticorrosive oil composition is led to and being coated on metal surface
Often overlay film is formed on the surface of metal material.Coating can and metal material is impregnated in anticorrosive oil composition into
Row, can also be carried out and blowing attached anticorrosive oil composition or other various coating process to metal material, preferably pass through dipping
And carry out.
In addition, metal material is preferably processed using water-based working fluid, or after being cleaned by alkaline cleaner etc.,
Anticorrosive oil composition is coated on metal material surface.
Above-mentioned anticorrosive oil composition other than rust-preventing characteristic except aqueous also excellent, therefore in water-based working fluid, cleaning solution
When being coated in the state of remaining on the surface of metal material, working fluid, cleaning solution can be removed from the surface of metal material
And form overlay film.
It should be noted that the use of the metal of anticorrosive oil composition being preferably pure iron, steel, cast steel, steel alloy, carbon steel, cast iron, casting
The iron-containing metal such as iron, but can be used for other metals.
The anticorrosive oil composition of present embodiment is not particularly limited, such as antirust before antirust, factory between step.
The manufacturing method > of < anticorrosive oil composition
In the manufacturing method of anticorrosive oil composition involved in an embodiment of the invention, above-mentioned (A1) ~ (A4) will be selected from
Ingredient and at least one kind of deicer (A) in their organic salt, at least one kind of antirust agent in above-mentioned (B1) ~ (B6) ingredient
(B), 40 DEG C of kinematic viscosity are 20mm2/ s light mineral oil below (C) and 40 DEG C of kinematic viscosity are 80mm2The heavy of/s or more
Mineral oil (D) is cooperated, and anticorrosive oil composition is obtained.
It should be noted that other than above-mentioned (A) ~ (D) ingredient, other compositions can also be cooperated in this manufacturing method.
In this method, use level and other details and the above-mentioned content and other of above-mentioned (A) ~ (D) and other his ingredients
Details are identical, and the description thereof will be omitted.
It should be noted that can be formed with as described above when containing organic salt about (A) ingredient, in anticorrosive oil composition
Cooperate after machine salt, can also be respectively cooperating with above-mentioned (A1) and (A2) ingredient, (A4) ingredient and (A2) ingredient, (A1) ingredient with it is organic
Sour (E1), (A2) ingredient and organic base (E2) or (A4) ingredient and organic acid (E1), form organic in anticorrosive oil composition
Salt.
Embodiment
Hereinafter, be further elaborated with the present invention by embodiment, but the present invention not due to these examples by any limit
It is fixed.
Measuring method in the present invention, evaluation method is as follows described.
(1) kinematic viscosity
According to JIS K2283-2000, the value measured using glass system capillary viscosimeter.
(2) base number
Base number is the value measured according to JIS K-2501-2003 by perchloric acid method.
(3) number-average molecular weight
The number-average molecular weight of each ingredient in the HLC-8220 type of Dong ソ ー Co. Ltd. system by installing Dong ソ ー column：
2+G2000H-XL1 roots of TSKgelGMH-XL, in detector：Refractive index detector, measuring temperature：40 DEG C, mobile phase：Tetrahydro
Furans, flow velocity：1.0ml/ minutes, measure under conditions of concentration 1.0mg/ml, found out by standard polystyren conversion.
(4) exposure test (exposure rust-preventing characteristic) under eaves
Commercially available SPCC-SD is impregnated in test oil and after skimming oil 24 hours, exposure test under eaves is implemented.For each examination
It tests, the state after being evaluated 10 days by evaluation criteria below, after 14 days, after 20 days, after 40 days.It should be noted that test number
Implement for 3.
A：Rustless, B：Become rusty area < 5%, C：Become rusty area >=5%.
In addition, as overall merit, determining according to benchmark below for 3 tests.
AAA：5,AAB：4,ABB：3,BBB：2, C includes 1 or more：1.
(5) water substituting test (except aqueous)
With JIS K2246：2007 6.29 regulation similarly, by commercially available SPCC-SB abrasive sheet (pre-treatment A240, lappingout
A100), prepare test film.Lift after the test film is impregnated in water, confirmation grinding part is covered with water.The case where repelling water
Under abandon test film.Into the 500mL beaker that joined test oil 70mL, the test film being covered with water is added, in the oil up and down
Oscillating moves (1 time/second).Time (second) until near water is completely fallen off by visual observation is measured as water displacement number of seconds, according to below
Evaluation criteria evaluation is except aqueous.
A：6 seconds or less, B：Greater than 6 seconds and it is lower than 8 seconds, C：8 seconds or more.
(6) degreasing is tested
After being impregnated in test oil by SPCC-SD and skim oil 24 hours, the dipping of shake in 15 seconds is carried out by degreaser, then, is led to
It crosses dipping water and wash within 15 seconds, water wetting areas of the confirmation dipping water to after lifting.Aforementioned shake dipping is repeated extremely
Confirm the operation of water wetting areas, the degreasing time until water wetting areas reaches 100% is measured, according to evaluation base below
Standard is evaluated.Degreaser is set as commercially available alkaline cleaner (pH is 11 ~ 13) by degreasing condition, under 40 DEG C of temperature, without mixing
It carries out.
A：60 seconds or less, B：Greater than 60 seconds.
(7) water separable performance is tested
Oily (20mL) will be tested and water system working fluid (20mL) is added in the bottle of 50mL, up and down after oscillation 5 seconds, measured to being separated into
Time only is determined according to evaluation criteria below.It should be noted that as water system working fluid, in order to study at the scene
Water separable performance, use water or as alkaline cleaner water-soluble cleaning oil (trade name " ダ フ ニ ー W ク リ ー ナ ー CM ", out
The emerging production Co. Ltd. system of light, 5 mass % dilutions) it is evaluated.
A：Lower than 120 seconds, B：120 seconds more than or lower than 180 seconds, C：180 seconds or more.
[embodiment 1 ~ 44, comparative example 1 ~ 8]
According to the proportion recorded in table 1 ~ 4, anticorrosive oil composition is prepared, the exposure rust-preventing characteristic of each anticorrosive oil composition is evaluated, removes
Aqueous, degreasing and water separable performance.
[table 1]
[table 2]
[table 3]
[table 4]
Carbon atom number in each table of ※ is as described below.
(A1) ingredient：The carbon atom number of aliphatic alkyl possessed by imidazolinium compounds
(A2), (A3) ingredient：The total carbon of aliphatic alkyl possessed by phosphate based compound or thiophosphate based compound
Atomicity
(A4) ingredient：The total carbon atom number for the aliphatic alkyl for including in one molecule
(B1) ingredient：Whole carbon atom numbers of average 1 sulfo group in sulfonate
That Details as Follows is described for each compound in each table of ※.
(B1) ingredient
Neutral calcium sulfonate 1：It include alkylnaphthalene based structures in sulfonic group
Parlkaline calcium sulfonate：It include alkylnaphthalene based structures, base number 50mgKOH/g in sulfonic group
Neutral barium sulfonate：It include alkylnaphthalene based structures in sulfonic group
Neutral calcium sulfonate 2：It include alkyl phenyl structure in sulfonic group
Neutral calcium sulfonate 3：Sulfonic group includes alkyl phenyl structure
(B3) ingredient
Polybutene 1：Number-average molecular weight (Mn) 710
Polybutene 2：Number-average molecular weight (Mn) 1200
PMMA：Number-average molecular weight (Mn) 2500
Butene low polymers：Number-average molecular weight (Mn) 560
(B4) ingredient
Petropols 1：Substance obtained from adding hydrogen is carried out to the copolymer of bicyclopentadiene and aromatic compounds, part hydrogenates stone
Oleoresin, number-average molecular weight (Mn) 710
Petropols 2：Substance obtained from adding hydrogen is carried out to the copolymer of bicyclopentadiene and aromatic compounds, part hydrogenates stone
Oleoresin, number-average molecular weight (Mn) 500
(B5) ingredient
Oxidized wax：45 DEG C of fusing point, acid value 60
Paraffin wax：49 DEG C of fusing point
(B6) ingredient
Polybutylene-based succimide：Acid value 1.0mgKOH/g, base number 44.0mgKOH/g, nitrogen content 3.5 mass % are polybutylene-based
Number-average molecular weight (Mn) 950
Alkenyl succimide：Acid value 14.2mgKOH/g, base number 40.5mgKOH/g, 1.8 mass % of nitrogen content
(C) ingredient
Mineral oil 1：40 DEG C of kinematic viscosity 5mm2/s
(D) ingredient
Mineral oil 2：40 DEG C of kinematic viscosity 150mm2/s
Mineral oil 3：40 DEG C of kinematic viscosity 450mm2/s
Other additives：Antioxidant, inerting agent.
As shown in above embodiment 1 ~ 44, by containing defined (A) ~ (D) ingredient in anticorrosive oil composition,
It can make rust-preventing characteristic, except aqueous, degreasing and water separable performance reach good.
On the other hand, in comparative example 1 ~ 3, anticorrosive oil composition is without any in (A) ingredient, (B) ingredient, (C) ingredient
Person, therefore rust-preventing characteristic can not be made, except at least either in aqueous reaches good.In addition, in comparative example 4, as (A) ingredient
Using the small imidazolinium compounds of the carbon atom number of aliphatic alkyl, therefore can not make to reach good except aqueous, further moisture
It is also reduced from property.In comparative example 5, (A3) ingredient without aliphatic alkyl is used as (A) ingredient, therefore can not make to prevent
Rust property reaches good except aqueous.
Further, in comparative example 6 ~ 8, (B1) ingredient for using whole carbon atom numbers of each sulfo group few, as full ester
(B2) ingredient and small (B3) ingredient of molecular weight, therefore rust-preventing characteristic can not be made, except at least either in aqueous reaches good.
Claims (14)
1. anticorrosive oil composition, it includes：
At least one kind of deicer (A) in following (A1) ~ (A4) ingredient and their organic salt,
At least one kind of antirust agent (B) in following (B1) ~ (B6) ingredient,
40 DEG C of kinematic viscosity are 20mm2/ s light mineral oil below (C) and
40 DEG C of kinematic viscosity are 80mm2The heavy mineral oil (D) of/s or more；
(A1)：Imidazolinium compounds with the aliphatic alkyl that carbon atom number is 10 ~ 24
(A2)：The phosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A3)：The thiophosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A4)：The diamine compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(B1)：The sulfonate that whole carbon atom numbers of average 1 sulfo group are 23 or more
(B2)：Polyol partial esters
(B3)：The polymer that number-average molecular weight is 600 ~ 5000
(B4)：The resin that number-average molecular weight is 400 ~ 3500
(B5)：Wax
(B6)：Succimide compound.
2. anticorrosive oil composition according to claim 1, wherein (A1) ingredient is following formula (1) compound represented,
[chemical formula 1]
In formula (1), R1Indicate that carbon atom number is 10 ~ 24 aliphatic alkyl, R2Indicate optionally with hydroxyl carbon atom number be 1 ~
4 alkyl or hydrogen atom.
3. anticorrosive oil composition according to claim 1 or 2, wherein (A2) ingredient is to change shown in following formula (2)
It is at least one kind of in conjunction object and following formula (3) compound represented,
(R3O-)nP(=O)(-OH)3-n (2)
In formula (2), n indicates 1 or 2, R3Indicate aliphatic alkyl, the R in a molecule3Total carbon atom number reach 8 ~ 40；N is 2
When, R3Can it is mutually the same, can also be different；
(R4O-)mP(-OH)3-m (3)
In formula (3), m indicates 1 or 2, R4Indicate aliphatic alkyl, the R in a molecule4Total carbon atom number reach 8 ~ 40；M is 2
When, R4Can it is mutually the same, can also be different.
4. anticorrosive oil composition described according to claim 1 ~ any one of 3, wherein (A3) ingredient is selected from following formula (4)
It is at least one kind of in compound represented,
S=P(-OR5)(-OR5)(-OR5) (4)
In formula (4), R5For alkyl, so that the total carbon atom number of aliphatic alkyl reaches 8 ~ 40；Multiple R5Can it is mutually the same,
It can be different.
5. anticorrosive oil composition described according to claim 1 ~ any one of 4, wherein (A4) ingredient is shown in following formula (5)
Compound,
R6-NH-R7-NH2 (5)
In formula (5), R6The alkyl or alkenyl for being 1 ~ 39 for carbon atom number, R7The alkylidene or alkenylene for being 1 ~ 39 for carbon atom number,
R6And R7Total carbon atom number be 8 ~ 40.
6. anticorrosive oil composition described according to claim 1 ~ any one of 5, wherein the sulfonic acid of the sulfonate in (B1) ingredient
With alkylnaphthalene based structures.
7. anticorrosive oil composition described according to claim 1 ~ any one of 6, wherein (B2) ingredient is selected from trihydroxy methyl third
At least one kind of partial ester in alkane, pentaerythrite and sorbitan.
8. anticorrosive oil composition described according to claim 1 ~ any one of 7, wherein (B3) ingredient is selected from polybutene, gathers
It is at least one kind of in isobutene, polymethyl methacrylate and their derivative.
9. anticorrosive oil composition described according to claim 1 ~ any one of 8, wherein (B4) ingredient has ring structure, and
It is at least one kind of in Petropols and terpene resin.
10. anticorrosive oil composition described according to claim 1 ~ any one of 9, wherein (B5) ingredient is that fusing point is 30 ~ 80 DEG C
Wax.
11. anticorrosive oil composition described according to claim 1 ~ any one of 10, wherein (B6) ingredient is selected from allyl butyrate two
It is at least one kind of in acid imide and its derivative.
12. anticorrosive oil composition described according to claim 1 ~ any one of 11, wherein anticorrosive oil composition is total with composition
Counted on the basis of amount, containing 0.1 ~ 10 mass % of (A) ingredient, 1 ~ 40 mass % of (B) ingredient, 50 mass % of (C) ingredient or more and (D) at
Divide 1 ~ 40 mass %.
13. anticorrosive oil composition described according to claim 1 ~ any one of 12, wherein (B) ingredient include (B1) ingredient,
(B2) ingredient and (B3) ingredient or (B2) ingredient and (B5) ingredient.
14. the manufacturing method of anticorrosive oil composition, will be selected from least 1 in following (A1) ~ (A4) ingredient and their organic salt
Kind deicer (A), at least one kind of antirust agent (B) in following (B1) ~ (B6) ingredient, 40 DEG C of kinematic viscosity are 20mm2/ s with
Under light mineral oil (C) and 40 DEG C of kinematic viscosity be 80mm2The heavy mineral oil (D) of/s or more is cooperated, and antirust is obtained
Fluid composition；
(A1)：Imidazolinium compounds with the aliphatic alkyl that carbon atom number is 10 ~ 24
(A2)：The phosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A3)：The thiophosphate based compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(A4)：The diamine compound that the total carbon atom number of aliphatic alkyl is 8 ~ 40
(B1)：The sulfonate that whole carbon atom numbers of average 1 sulfo group are 23 or more
(B2)：Polyol partial esters
(B3)：The polymer that number-average molecular weight is 600 ~ 5000
(B4)：The resin that number-average molecular weight is 400 ~ 3500
(B5)：Wax
(B6)：Succimide compound.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016069743 | 2016-03-30 | ||
| JP2016-069743 | 2016-03-30 | ||
| PCT/JP2017/013251 WO2017170868A1 (en) | 2016-03-30 | 2017-03-30 | Rust preventive oil composition |
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|---|---|
| CN108884575A true CN108884575A (en) | 2018-11-23 |
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| CN201780020968.2A Pending CN108884575A (en) | 2016-03-30 | 2017-03-30 | Rust preventive oil composition |
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|---|---|
| JP (1) | JPWO2017170868A1 (en) |
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| WO (1) | WO2017170868A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112111314A (en) * | 2019-06-21 | 2020-12-22 | 株式会社自动网络技术研究所 | Surface protective agent composition and covered wire with terminal |
| CN113416595A (en) * | 2021-07-14 | 2021-09-21 | 安庆市中创生物工程有限公司 | Method for reducing friction of special anti-wear hydraulic oil for high-pressure plunger pump |
| CN113490769A (en) * | 2019-03-08 | 2021-10-08 | 出光兴产株式会社 | Rust preventive oil composition and method for producing same |
| CN113557323A (en) * | 2019-05-28 | 2021-10-26 | 花王株式会社 | Rust preventive, rust preventive composition, coating film-forming material, coating film, and metal member |
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| CN109371401B (en) * | 2018-12-21 | 2021-03-23 | 陕西省石油化工研究设计院 | Polyoxyethylene ether imidazoline sulfonate corrosion inhibitor and preparation method thereof |
| JP2020143358A (en) * | 2019-03-08 | 2020-09-10 | 出光興産株式会社 | Rust-proof oil composition and its manufacturing method |
| JP7204264B1 (en) * | 2022-01-07 | 2023-01-16 | テック大洋工業株式会社 | Antirust composition and antirust method |
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| CN113490769A (en) * | 2019-03-08 | 2021-10-08 | 出光兴产株式会社 | Rust preventive oil composition and method for producing same |
| CN113557323A (en) * | 2019-05-28 | 2021-10-26 | 花王株式会社 | Rust preventive, rust preventive composition, coating film-forming material, coating film, and metal member |
| CN112111314A (en) * | 2019-06-21 | 2020-12-22 | 株式会社自动网络技术研究所 | Surface protective agent composition and covered wire with terminal |
| CN113416595A (en) * | 2021-07-14 | 2021-09-21 | 安庆市中创生物工程有限公司 | Method for reducing friction of special anti-wear hydraulic oil for high-pressure plunger pump |
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| Publication number | Publication date |
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| JPWO2017170868A1 (en) | 2019-02-14 |
| WO2017170868A1 (en) | 2017-10-05 |
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