CN108884406A - Lubricating oil composition and metal working method - Google Patents
Lubricating oil composition and metal working method Download PDFInfo
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- CN108884406A CN108884406A CN201780020495.6A CN201780020495A CN108884406A CN 108884406 A CN108884406 A CN 108884406A CN 201780020495 A CN201780020495 A CN 201780020495A CN 108884406 A CN108884406 A CN 108884406A
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- lubricant oil
- ingredient
- oil composite
- composite
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- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 21
- 238000005555 metalworking Methods 0.000 title claims description 9
- 239000010687 lubricating oil Substances 0.000 title abstract description 11
- 239000002199 base oil Substances 0.000 claims abstract description 23
- 239000004711 α-olefin Substances 0.000 claims abstract description 20
- 239000002131 composite material Substances 0.000 claims description 145
- 239000003921 oil Substances 0.000 claims description 121
- 239000000314 lubricant Substances 0.000 claims description 110
- 239000004615 ingredient Substances 0.000 claims description 61
- 239000011248 coating agent Substances 0.000 claims description 47
- 238000000576 coating method Methods 0.000 claims description 47
- 229910052799 carbon Inorganic materials 0.000 claims description 35
- -1 alkane hydrocarbon Chemical class 0.000 claims description 23
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000003963 antioxidant agent Substances 0.000 claims description 18
- 150000001412 amines Chemical class 0.000 claims description 16
- 230000003078 antioxidant effect Effects 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 12
- 108010077895 Sarcosine Proteins 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229940043230 sarcosine Drugs 0.000 claims description 11
- 150000002314 glycerols Chemical class 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 229910000838 Al alloy Inorganic materials 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 3
- 238000005461 lubrication Methods 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 description 30
- 125000003342 alkenyl group Chemical group 0.000 description 28
- 150000001721 carbon Chemical group 0.000 description 27
- 235000019441 ethanol Nutrition 0.000 description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 235000006708 antioxidants Nutrition 0.000 description 17
- 239000000654 additive Substances 0.000 description 12
- 230000000996 additive effect Effects 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 12
- 238000001035 drying Methods 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 8
- 239000002480 mineral oil Substances 0.000 description 8
- 235000010446 mineral oil Nutrition 0.000 description 8
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical class OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
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- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
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- 230000000052 comparative effect Effects 0.000 description 6
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 6
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 5
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 5
- 239000002530 phenolic antioxidant Substances 0.000 description 5
- 125000005466 alkylenyl group Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- VSMOENVRRABVKN-UHFFFAOYSA-N oct-1-en-3-ol Chemical compound CCCCCC(O)C=C VSMOENVRRABVKN-UHFFFAOYSA-N 0.000 description 4
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- 229940095068 tetradecene Drugs 0.000 description 4
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 3
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 3
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- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 3
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- 229940035422 diphenylamine Drugs 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
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- VQOXUMQBYILCKR-UHFFFAOYSA-N 1-Tridecene Chemical group CCCCCCCCCCCC=C VQOXUMQBYILCKR-UHFFFAOYSA-N 0.000 description 2
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical class CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
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- 150000007513 acids Chemical class 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- DGXRZJSPDXZJFG-UHFFFAOYSA-N docosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCCCC(O)=O DGXRZJSPDXZJFG-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
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- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
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- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 description 1
- MGHPNCMVUAKAIE-UHFFFAOYSA-N diphenylmethanamine Chemical compound C=1C=CC=CC=1C(N)C1=CC=CC=C1 MGHPNCMVUAKAIE-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 229940108623 eicosenoic acid Drugs 0.000 description 1
- BITHHVVYSMSWAG-UHFFFAOYSA-N eicosenoic acid Natural products CCCCCCCCC=CCCCCCCCCCC(O)=O BITHHVVYSMSWAG-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 125000005187 nonenyl group Chemical group C(=CCCCCCCC)* 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LHTVMBMETNGEAN-UHFFFAOYSA-N pent-1-en-1-ol Chemical compound CCCC=CO LHTVMBMETNGEAN-UHFFFAOYSA-N 0.000 description 1
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
- 125000004344 phenylpropyl group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OSFBJERFMQCEQY-UHFFFAOYSA-N propylidene Chemical group [CH]CC OSFBJERFMQCEQY-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 208000011117 substance-related disease Diseases 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- POOSGDOYLQNASK-UHFFFAOYSA-N tetracosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC POOSGDOYLQNASK-UHFFFAOYSA-N 0.000 description 1
- IBYFOBGPNPINBU-UHFFFAOYSA-N tetradecenoic acid Natural products CCCCCCCCCCCC=CC(O)=O IBYFOBGPNPINBU-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- IBYFOBGPNPINBU-OUKQBFOZSA-N trans-2-tetradecenoic acid Chemical compound CCCCCCCCCCC\C=C\C(O)=O IBYFOBGPNPINBU-OUKQBFOZSA-N 0.000 description 1
- LKOVPWSSZFDYPG-WUKNDPDISA-N trans-octadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCC\C=C\C(O)=O LKOVPWSSZFDYPG-WUKNDPDISA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- BZVJOYBTLHNRDW-UHFFFAOYSA-N triphenylmethanamine Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(N)C1=CC=CC=C1 BZVJOYBTLHNRDW-UHFFFAOYSA-N 0.000 description 1
- 125000005065 undecenyl group Chemical group C(=CCCCCCCCCC)* 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/06—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/02—Well-defined hydrocarbons
- C10M105/04—Well-defined hydrocarbons aliphatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M127/00—Lubricating compositions characterised by the additive being a non- macromolecular hydrocarbon
- C10M127/02—Lubricating compositions characterised by the additive being a non- macromolecular hydrocarbon well-defined aliphatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/08—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least 2 hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
- C10M129/70—Esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
Provided is a lubricating oil composition containing a base oil (A), an N-acylsarcosine (B), and an α -olefin (C).
Description
Technical field
The present invention relates to lubricant oil composite and use the method for metal working of the lubricant oil composite.
Background technique
Carry out the metals such as contraction processing, the bending machining of metal or the nonferrous metal such as its alloy, particularly aluminum or aluminum alloy
When processing, the lubricant oil composite of intermetallic composite coating is used.
To the lubricant oil composite of intermetallic composite coating, as basic performance, it is desirable that excellent intermetallic composite coating.That is, by golden
When the lubricant oil composite of category poor in processability is used for intermetallic composite coating, it is easy to produce generation seizure, bending in such as contraction processing and adds
The failure of rupture etc occurs in work.
As the lubricant oil composite of intermetallic composite coating, for the purpose of improving intermetallic composite coating, carry out various
Research and motion.
For example, disclosing in the base oil in mineral oil and synthetic oil with specified amount in patent document 1 comprising having
The glycerol derivatives of specific structure and the intermetallic composite coating lubricant oil composite of oiliness improver.
In addition, it is defined for disclosing in the kinematic viscosity at mineral oil and synthetic oil and 40 DEG C in patent document 2
Intermetallic composite coating lubricant oil composite in the base oil of range with specified amount comprising the glycerol derivatives with specific structure.
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2008-088428 bulletin
Patent document 2：Japanese Unexamined Patent Publication 2013-177515 bulletin.
Summary of the invention
Subject to be solved by the invention
However, even if in the lubricant oil composite described in patent document 1 and 2, although having metal good to a certain degree to add
Work, but require to further improve the lubricant oil composite of intermetallic composite coating.
The object of the present invention is to provide the lubricant oil composite with excellent intermetallic composite coating and use the lubrication
The method for metal working of fluid composition.
Means for solving the problems
The inventors discovered that the lubricant oil composite that N- acyl group sarcosine and alpha-olefin is applied in combination is able to solve the above subject,
So as to complete the present invention.
That is, the present invention provides following [1] ~ [2].
[1] lubricant oil composite contains base oil (A), N- acyl group sarcosine (B) and alpha-olefin (C).
[2] method for metal working carries out intermetallic composite coating using lubricant oil composite described in above-mentioned [1].
The effect of invention
Lubricant oil composite of the invention has excellent intermetallic composite coating, with lubricant oil composite is useful as intermetallic composite coating
's.
Specific embodiment
[lubricant oil composite]
Lubricant oil composite of the invention contains base oil (A), N- acyl group sarcosine (B) and alpha-olefin (C).
In lubricant oil composite of the invention, by combination contain ingredient (B) and ingredient (C), with exclusive use it is each at
The case where dividing is compared, and the improvement effect of intermetallic composite coating is synergistically played.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of further increasing intermetallic composite coating, make
Content ratio for ingredient (B) relative to 100 mass parts of ingredient (C), more than preferably 0.030 mass parts, more preferably 0.050 matter
It more than amount part, is more preferably 0.060 mass parts or more, further preferably 0.070 mass parts or more, is still more preferably
More than 0.100 mass parts, more than particularly preferably 0.300 mass parts.
In addition, from the viewpoint of being made the good lubricant oil composite of drying property, as ingredient (B) relative to ingredient
(C) the content ratio of 100 mass parts, preferably 60 below the mass, more preferably 30 below the mass, more preferably 10 mass parts
It below, is more preferably 7 below the mass, still more preferably for 5 below the mass, particularly preferably 2 below the mass.
In the lubricant oil composite of one embodiment of the present invention, the total content of ingredient (A), (B) and (C) is with the lubricating oil
Meter is preferably 70 mass % or more, is more preferably 75 mass % or more, is further excellent on the basis of the total amount (100 mass %) of composition
It is selected as 80 mass % or more, is still more preferably 85 mass % or more, particularly preferably 90 mass % or more, in addition, being usually
100 mass % or less, preferably 99.99 mass % or less.
The lubricant oil composite of one embodiment of the present invention is from the viewpoint of further increasing intermetallic composite coating, preferably also
Contain the oiliness improver selected from one or more of glycerol derivatives, unary alcohol, amine, fatty acid and fatty acid ester
(D)。
In addition, the lubricant oil composite of one embodiment of the present invention preferably contains from the viewpoint of improving antioxygenic property
There is antioxidant (E).
It should be noted that the lubricant oil composite of one embodiment of the present invention is not damaging in effective scope of the invention, also
Other additive for lubricant other than ingredient (B) ~ (E) can be contained.
In the lubricant oil composite of one embodiment of the present invention, the total content of ingredient (A), (B), (C), (D) and (E) with
On the basis of the total amount (100 mass %) of the lubricant oil composite meter be preferably 75 ~ 100 mass %, more preferably 80 ~ 100 mass %,
It further preferably 85 ~ 100 mass %, is still more preferably 90 ~ 100 mass %, particularly preferably 95 ~ 100 mass %.
Hereinafter, being illustrated for the details for each ingredient for including in lubricant oil composite of the invention.
< ingredient (A)：Base oil >
Base oil (A) used in the present invention can be any one in mineral oil and synthetic oil, furthermore, it is possible to for combination
Use the miscella of more than two kinds in mineral oil and synthetic oil.
As mineral oil, it can be cited for example that by crude oil such as alkane hydrocarbon system crude oil, intermediate base system crude oil, cycloalkanes hydrocarbon system crude oil
Carry out reduced crude obtained from air-distillation；Distillate oil obtained from these reduced crudes are evaporated under reduced pressure；This is evaporated
Fuel-displaced implementation solvent deasphalting, solvent extraction, be hydrocracked, solvent dewaxing, catalytic dewaxing, in the refinement treatments such as hydrofinishing
Mineral oil obtained from more than one processing；By to wax (GTL wax (the Gas To Liquids using manufactures such as fischer tropsch process
WAX, natural gas synthetic wax)) carry out mineral oil wax obtained from isomerization etc..
These mineral oil may be used singly or in combination of two or more.
As synthetic oil, it can be cited for example that alpha-olefin homo or alpha olefin copolymer (such as ethene-alpha-olefin is total
The carbon atom numbers such as polymers be 8 ~ 14 alpha olefin copolymer) etc. poly alpha olefins system synthetic oil；The alkanes such as normal paraffin hydrocarbons, isoparaffin
Hydrocarbon system synthetic oil；Polyol ester, dibasic acid ester (such as glutaric acid two (tridecyl) ester etc.), tribasic ester (such as inclined benzene three
Formic acid 2- ethylhexyl), the esters system synthetic oil such as phosphate；The ethers such as polyphenylene oxide system synthetic oil；Polyalkylene glycol；Alkylbenzene；
Alkylnaphthalene；Synthetic oil as obtained from carrying out isomerization to the wax (GTL wax) using manufactures such as fischer tropsch process etc..
These synthetic oils may be used singly or in combination of two or more.
As base oil used in one embodiment of the present invention (A), from the sight for the drying property for improving lubricant oil composite
Point sets out, and preferably comprises synthetic oil, more preferably includes alkane hydrocarbon system synthetic oil, further preferably together comprising normal paraffin hydrocarbons and different
Alkane.
From the above point of view, base of the content ratio of the synthetic oil in base oil (A) to include in lubricant oil composite
Meter is preferably 50 ~ 100 mass %, is more preferably 70 ~ 100 mass %, is further excellent on the basis of the total amount (100 mass %) of plinth oil (A)
It is selected as 80 ~ 100 mass %, is still more preferably 90 ~ 100 mass %, particularly preferably 100 mass %.
In addition, from the above point of view, the content ratio of the alkane hydrocarbon system synthetic oil in base oil (A) is with lubricating oil composition
Meter is preferably 50 ~ 100 mass %, more preferably 70 ~ 100 matter on the basis of the total amount (100 mass %) for the base oil (A) for including in object
It measures %, further preferably 80 ~ 100 mass %, be still more preferably 90 ~ 100 mass %, particularly preferably 100 mass %.
Based on kinematic viscosity at 40 DEG C of oily (A), preferably 0.5 ~ 10mm2/ s, more preferably 0.75 ~ 5mm2/s、
Further preferably 1 ~ 3mm2/s。
As long as the kinematic viscosity is 0.5mm2/ s or more can then further increase intermetallic composite coating.
As long as in addition, the kinematic viscosity is 10mm2/ s hereinafter, then while being able to maintain that excellent intermetallic composite coating,
Treatability also becomes good.
It should be noted that the kinematic viscosity at 40 DEG C refers to according to JIS K2283 in this specification：The value of 2000 measurements.
In addition, from the viewpoint of preparation improves the lubricant oil composite of intermetallic composite coating, as of the invention one
Base oil used in mode (A) is preferably difficult to due to volatility height by according to JIS K2283：2000 measuring method and
Calculate the base oil of the kinematic viscosity and viscosity index (VI) at 100 DEG C.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of making greasy property become good, ingredient
(A) content counts preferably 65 mass % or more, more preferably 70 on the basis of the total amount (100 mass %) of the lubricant oil composite
It quality % or more, further preferably 75 mass % or more, is still more preferably 80 mass % or more.
In addition, from ensuring the content of ingredient (B) and (C), the viewpoint of the excellent lubricant oil composite of intermetallic composite coating being made
Set out, the content of ingredient (A) counted on the basis of the total amount (100 mass %) of the lubricant oil composite preferably 89 mass % or less,
More preferably 88 mass % or less, further preferably 85 mass % or less.
< ingredient (B)：N- acyl group sarcosine >
Lubricant oil composite of the invention contains N- acyl group sarcosine (B).
It should be noted that ingredient (B) may be used singly or in combination of two or more.
As N- acyl group sarcosine (B), preferably the following general formula (b) compound represented.
[changing 1]
。
In above-mentioned general formula (b), R indicates that the alkyl that carbon atom number is 2 ~ 30, the naphthenic base that carbon atom number is 3 ~ 30 or carbon are former
The alkenyl that subnumber is 3 ~ 30.
It should be noted that among these, as R, preferably carbon atom number be 2 ~ 30 alkyl or carbon atom number be 3 ~ 30
Alkenyl.
As the abovementioned alkyl that can be elected to be R, it can be cited for example that ethyl, propyl, butyl, amyl, hexyl, heptyl, pungent
Base, nonyl, decyl, undecyl, dodecyl, tridecyl, myristyl, cetyl, octadecyl, lignocerane
Base, cerul etc..
It should be noted that the alkyl can be straight chained alkyl, or branched alkyl, preferably straight chained alkyl.
Carbon atom number as the alkyl is preferably 2 ~ 30, more preferably 5 ~ 26, further preferably 8 ~ 24, more into
One step is preferably 12 ~ 20.
As the above-mentioned naphthenic base that can be elected to be R, it can be cited for example that cyclopropyl, cyclobutyl, cyclopenta, cyclohexyl, ring
Heptyl, cyclooctyl, adamantyl etc..
It should be noted that the naphthenic base can be replaced by the alkyl that carbon atom number is 1 ~ 10 (preferably 1 ~ 4).
As the carbon atom number (also including the carbon atom number of the alkyl by alkyl-substituted naphthenic base) of the naphthenic base, preferably
It is 3 ~ 30, more preferably 5 ~ 26, be more preferably 5 ~ 20, is still more preferably 6 ~ 15.
As the above-mentioned alkenyl that can be elected to be R, it can be cited for example that acrylic, cyclobutenyl, pentenyl, hexenyl, heptene
Base, octenyl, nonenyl, decene base, undecenyl, dodecenyl succinic, tridecylene base, tetradecene base, hexadecene
Base, octadecene base (oleyl), tetracosa carbon alkenyl, cerotene base etc..
It should be noted that the alkenyl can be straight-chain alkenyl, or branched-chain alkenyl, preferably straight-chain alkenyl.
As the carbon atom number of the alkenyl, preferably 3 ~ 30, more preferably 5 ~ 26, further preferably 8 ~ 24, more into one
Step preferably 12 ~ 20.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of further increasing intermetallic composite coating, at
(B) is divided to preferably comprise selected from the following general formula (b-1) compound represented (B1) and the following general formula (b-2) compound represented (B2)
One or more of.
[changing 2]
。
In above-mentioned general formula (b-1), the integer that m is 1 ~ 29, preferably 4 ~ 25, more preferably 7 ~ 23, further preferably 11 ~
19。
As specific compound (B1), various alkylsarcosines can be enumerated, specifically, N- lauroyl can be enumerated
Base sarcosine (m=11 in formula (b-1)), N- myristoy sarcosine (m=13 in formula (b-1)), N- palmityl flesh ammonia
Sour (m=14 in formula (b-1)) etc..
In addition, in above-mentioned general formula (b-2), p and q are each independently 0 or more integer.Wherein, p+q is 0 ~ 27, preferably
It is 2 ~ 23, more preferably 5 ~ 21, further preferably 9 ~ 17.
As specific compound (B2), various alkenyl sarcosines can be enumerated, specifically, N- oleyl can be enumerated
Sarcosine (p=q=7 in formula (b-2)) etc..
From the viewpoint of further increasing intermetallic composite coating, compound (B1) and compound (B2) in ingredient (B)
It amounts to content ratio and counts preferably 70 ~ 100 on the basis of the total amount (100 mass %) for the ingredient (B) for including in lubricant oil composite
Quality %, more preferably 80 ~ 100 mass %, further preferably 90 ~ 100 mass %, still more preferably for 95 ~ 100 mass %,
Particularly preferably 100 mass %.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of improving intermetallic composite coating, ingredient (B)
Content is counted preferably 0.001 mass % or more on the basis of the total amount (100 mass %) of the lubricant oil composite, is more preferably
It 0.005 mass % or more, further preferably 0.01 mass % or more, is still more preferably 0.02 mass % or more, particularly preferably
For 0.03 mass % or more.
In addition, the content of ingredient (B) is from the viewpoint of being made the good lubricant oil composite of drying property with the lubricating oil
Meter is preferably 9 mass % or less, is more preferably 4 mass % or less, is further preferred on the basis of the total amount (100 mass %) of composition
For 1.5 mass % or less, be still more preferably 0.9 mass % or less, particularly preferably 0.6 mass % or less.
< ingredient (C)：Alpha-olefin >
Lubricant oil composite of the invention contains alpha-olefin (C).
It should be noted that ingredient (C) may be used singly or in combination of two or more.
As the carbon atom number of alpha-olefin (C), from the viewpoint of improving intermetallic composite coating, preferably 8 or more, more preferably
It is 10 or more, further preferably 12 or more, in addition, from the viewpoint of improving drying property, preferably 20 or less, be more preferably
16 or less, it is more preferably 15 or less, is still more preferably 14 or less.
As alpha-olefin (C), the linear alkene that there is double bond in end can be enumerated, specifically, the 1- last of the ten Heavenly stems can be enumerated
Alkene, 1- endecatylene, 1- dodecylene, 1- tridecylene, tetradecene, 1- pentadecane alkene, cetene, 17 carbon of 1-
Alkene, 1- octadecene etc..
It should be noted that in the lubricant oil composite of one embodiment of the present invention, it is dry from also being improved together with intermetallic composite coating
From the perspective of dry property, ingredient (C) preferably comprises the alpha-olefin (C1) that carbon atom number is 12 ~ 14.
From the above point of view, the content ratio as the ingredient (C1) in ingredient (C), to include in lubricant oil composite
Ingredient (C) total amount (100 mass %) on the basis of meter be preferably 70 ~ 100 mass %, more preferably 80 ~ 100 mass %, further
It preferably 90 ~ 100 mass %, is still more preferably 95 ~ 100 mass %, particularly preferably 100 mass %.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of improving intermetallic composite coating, ingredient (C)
Content counts preferably 10 mass % or more, more preferably 11 mass % on the basis of the total amount (100 mass %) of the lubricant oil composite
It above, is more preferably 12 mass % or more.
In addition, the content of ingredient (C) is from the viewpoint of being made the good lubricant oil composite of drying property with the lubricating oil
Meter is preferably 20 mass % or less, is more preferably 18 mass % or less, is further excellent on the basis of the total amount (100 mass %) of composition
It is selected as 17 mass % or less.
< ingredient (D)：Oiliness improver >
The lubricant oil composite of one embodiment of the present invention preferably also contains from the viewpoint of further increasing intermetallic composite coating
Oiliness improver (D) selected from one or more of glycerol derivatives, unary alcohol, amine, fatty acid and fatty acid ester.
It should be noted that ingredient (D) may be used singly or in combination of two or more.
(glycerol derivatives)
As glycerol derivatives, preferably the following general formula (d) compound represented.
[changing 3]
。
In aforementioned formula (d), R1Indicate alkyl, alkenyl or aryl alkyl, preferably alkyl or alkenyl.
R2And R3Each independently represent hydrogen atom or methyl, preferably hydrogen atom.
A1And A2The alkylidene that carbon atom number is 2 ~ 4, preferably ethylidene or propylidene are each independently represented, more preferably
For ethylidene.
X and y each independently represents 0 or more number, x+y be average addition molal quantity and indicate 0 ~ 5 number, preferably 0.
Z indicates 0 ~ 2 integer, from the viewpoint of further increasing intermetallic composite coating, preferably 0 or 1, more preferably 1.
It should be noted that as R can be elected to be1Alkyl and alkenyl carbon atom number, preferably 8 ~ 22, more preferably 10 ~
It 20, is more preferably 12 ~ 18.
The alkyl can be straight chained alkyl, or branched alkyl.
In addition, the alkenyl may be straight-chain alkenyl, or branched-chain alkenyl.
As R can be elected to be1Alkyl and alkenyl, can enumerate above-mentioned as the R that can be elected to be in aforementioned formula (b)
Alkyl and alkenyl and carbon atom number is 8 ~ 22 among the group enumerated alkyl and alkenyl.
As R can be elected to be1Aryl alkyl carbon atom number, preferably 7 ~ 20, more preferably 7 ~ 18, further preferably
It is 7 ~ 16.
As R can be elected to be1Aryl alkyl, it can be cited for example that benzyl, phenethyl, phenyl propyl, tolyl first
Base, tolylethyl, xylyl methyl, xylyl ethyl etc..
Among glycerol derivatives as ingredient (D), from the viewpoint of further increasing intermetallic composite coating, more preferably
For the following general formula (d-1) compound represented.
[changing 4]
(in aforementioned formula (d-1), R1aIndicate the alkyl that carbon atom number is 12 ~ 18 or the alkenyl that carbon atom number is 12 ~ 18；z1
Indicate 0 or 1, preferably 1).
(unary alcohol)
It can be straight-chain as unary alcohol, preferably unitary aliphatic saturated alcohols and unitary aliphatic unsaturated alcohol, it can also
Think branched.
As the carbon atom number of unary alcohol, preferably 8 ~ 22, more preferably 10 ~ 20, further preferably 12 ~ 18.
As unitary aliphatic saturated alcohols, it can be cited for example that octanol (octanol), decyl alcohol, dodecanol (laruyl alcohol), ten
Four alkanols (myristyl alcohol), hexadecanol (cetanol, cetanol), octadecanol (stearyl alcohol) etc., among these, preferably
Dodecanol (laruyl alcohol).
As unitary aliphatic unsaturated alcohol, it can be cited for example that matsutake alcohol, decenol, lanolin alcohol, tetradecene
Alcohol, hexadecenol, oleyl alcohol (oleyl alcohol, oleyl alcohol) etc., among these, preferably oleyl alcohol (oleyl alcohol, oily alkene
Base alcohol).
(amine)
As amine, secondary amine and the following general formula shown in primary amine, the following general formula shown in the following general formula (i) (ii) can be enumerated
(iii) quaternary amine shown in.
[changing 5]
。
In above-mentioned general formula (i) ~ (iii), R11~R13It is each independently alkyl, alkenyl or aryl alkyl, preferably alkyl
Or alkenyl, more preferably alkenyl.
As R can be elected to be11~R13Alkyl and alkenyl carbon atom number, preferably 8 ~ 22, more preferably 10 ~ 20, into
One step is preferably 12 ~ 18.
The alkyl can be straight chained alkyl, or branched alkyl.
In addition, the alkenyl may be straight-chain alkenyl, or branched-chain alkenyl.
It should be noted that as R can be elected to be11~R13Alkyl and alkenyl, can enumerate before above-mentioned conduct can be elected to be
State the alkyl and alkenyl and carbon atom number is 8 ~ 22 among the group enumerated alkyl and alkenyl of the R in general formula (b).
As R can be elected to be11~R13Aryl alkyl carbon atom number, preferably 7 ~ 20, more preferably 7 ~ 18, further
Preferably 7 ~ 16.
As R can be elected to be11~R13Aryl alkyl, can enumerate above-mentioned as the R that can be elected to be in aforementioned formula (d)1
Aryl alkyl and the group that illustrates.
As primary amine shown in aforementioned formula (i), it can be cited for example that octyl amine, lauryl amine, stearic amine, oleyl
The primary aliphatic amine such as amine；Benzyl amine etc..
As secondary amine shown in aforementioned formula (ii), it can be cited for example that dioctylamine, dilauryl amine, distearyl
The secondary aliphatic amines such as amine, two oleyl amine；Benzhydryl amine etc..
As quaternary amine shown in aforementioned formula (iii), it can be cited for example that trioctylphosphine amine, three lauryl amines, three stearyls
The seasons aliphatic amine such as amine, three oleyl amine；Trityl amine etc..
It is more preferably aforementioned logical as amine, preferably primary amine shown in aforementioned formula (i) in one embodiment of the present invention
R in formula (i)11For the primary aliphatic amine of alkyl or alkenyl, further preferably oleyl amine.
(fatty acid)
As fatty acid, it can be cited for example that palmitinic acid, stearic acid, isostearic acid, hydroxy stearic acid, dimeric dibasic acid, oleic acid, two
The saturated fatty acids such as ten alkanoic acids or unsaturated fatty acid.
As the carbon atom number of fatty acid, preferably 8 ~ 30, more preferably 10 ~ 24, further preferably 12 ~ 22.
(fatty acid ester)
As fatty acid ester, aliphatic that the aliphatic carboxylic acid and carbon atom number for being preferably 6 ~ 22 by carbon atom number are 1 ~ 18
The ester that alcohol is formed.
Aforementioned aliphatic carboxylic acid can be monoacid, or polyacid more than binary acid, furthermore, it is possible to for saturation
With any one in unsaturation.Further, it is possible to be straight-chain, it is possible to have branch.
As the aliphatic carboxylic acid, it can be cited for example that octanoic acid, capric acid, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, ten
Eight alkanoic acids, hydroxyoctadecanoic acid, arachic acid, octenoic acid, decylenic acid, dodecenoic acid, tetradecenoic acid, gaidic acid,
Octadecenoic acid, kamalolenic acid, eicosenoic acid, suberic acid, decanedioic acid, dodecanedioic acid, tetracosandioic acid, 16
Docosandioic acid, octadecane diacid, eicosane diacid, octendioic acid, decenedioic acid, decene dicarboxylic acid, tetracosendioic acid, 16
Carbene diacid, octadecene diacid, octadecene dicarboxylic acid etc..
Aforementioned aliphatic alcohol can be monohydric alcohol, or polyalcohol, furthermore, it is possible to be any in saturation, unsaturation
Person.Further, it is possible to be straight-chain, or branched.
As the aliphatic alcohol, it can be cited for example that methanol, ethyl alcohol, allyl alcohol, propyl alcohol, butanol, amylalcohol, hexanol, octanol,
Decyl alcohol, dodecanol, tetradecanol, hexadecanol, octadecanol, butenol, pentenol, hexenol, matsutake alcohol, decenol,
Lanolin alcohol, tetradecene alcohol, hexadecenol, oleyl alcohol etc..
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of further increasing intermetallic composite coating, oil
Property agent (D) more preferably one or more of selected from glycerol derivatives, unary alcohol and amine, be further preferably selected from third
One or more of triol derivates and amine.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of further increasing intermetallic composite coating, at
It is preferably 0.001 mass % or more that the content of point (D) count on the basis of the total amount (100 mass %) of the lubricant oil composite, more excellent
It is selected as 0.005 mass % or more, further preferably 0.01 mass % or more, is still more preferably 0.02 mass % or more, especially
Preferably 0.03 mass % or more.
In addition, the content of ingredient (D) is from the viewpoint of being made the good lubricant oil composite of drying property with the lubricating oil
Meter is preferably 5 mass % or less, is more preferably 4 mass % or less, is further preferred on the basis of the total amount (100 mass %) of composition
For 1.5 mass % or less, be still more preferably 0.9 mass % or less, particularly preferably 0.6 mass % or less.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint that the good lubricant oil composite of drying property is made
Set out, ingredient (D) relative to 100 mass parts of ingredient (B) content than preferably 500 below the mass, more preferably 350 mass
Part or less, further preferably 200 below the mass, still more preferably for 150 below the mass.
In addition, ingredient (D) is relative to 100 mass parts of ingredient (B) from the viewpoint of further increasing intermetallic composite coating
Content is than being preferably 5 mass parts or more, being more preferably 10 mass parts or more, further preferably 25 mass parts or more, more into one
Step is preferably 40 mass parts or more.
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint that the good lubricant oil composite of drying property is made
Set out, ingredient (D) relative to 100 mass parts of ingredient (C) content than preferably 30 below the mass, more preferably 20 mass parts
Below, be more preferably 10 below the mass, further preferably 7 below the mass, still more preferably for 5 below the mass,
Particularly preferably 2 below the mass.
In addition, ingredient (D) is relative to 100 mass parts of ingredient (C) from the viewpoint of further increasing intermetallic composite coating
Content than be preferably 0.030 mass parts or more, more preferably more than 0.050 mass parts, more than more preferably 0.060 mass parts,
It is more than further preferably 0.070 mass parts, still more preferably for it is more than 0.100 mass parts, particularly preferably 0.300 mass
Part or more.
< ingredient (E)：Antioxidant >
The lubricant oil composite of one embodiment of the present invention preferably comprises antioxidant from the viewpoint of improving antioxygenic property
(E)。
As antioxidant (E), can be fitted among the well known antioxidant of the previous antioxidant as lubricating oil
When selection arbitrary substance uses, it can be cited for example that amine antioxidant, phenolic antioxidant, sulfur antioxidant, molybdenum system are anti-
Oxidant, phosphorous antioxidant etc..
It should be noted that ingredient (E) may be used singly or in combination of two or more.
As amine antioxidant, it can be cited for example that the alkyl of diphenylamine, the alkyl for being 3 ~ 20 with carbon atom number
Change the diphenyl amine antioxidants such as diphenylamine；There is carbon atom number to be 3 ~ 20 alkane for Alpha-Naphthyl amine, phenyl-α-naphthylamine
Naphthalenes amine antioxidants such as the substituted-phenyl of base-Alpha-Naphthyl amine etc..
As phenolic antioxidant, it can be cited for example that 2,6- DI-tert-butylphenol compounds, 2,6- di-t-butyl -4- methylbenzene
Phenol, 2,6- di-t-butyl -4- ethyl -phenol, the different monooctyl ester of 3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid, 3- (bis- uncle of 3,5-
Butyl -4- hydroxy phenyl) single phenolic antioxidant such as propionic acid stearyl；4,4 '-di-2-ethylhexylphosphine oxides (2,6- di-tert-butyl
Phenol), two phenolic antioxidants such as 2,2 '-methylene-bis(4-ethyl-6-t-butyl phenol)s；Hindered phenolic antioxidant etc..
As sulfur antioxidant, it can be cited for example that 3,3 '-thiodipropionate dilauryls etc..
As molybdenum system antioxidant, it can be cited for example that obtained from molybdenum trioxide and/or molybdic acid are reacted with amine compounds
Molybdenum amine complex etc..
As phosphorous antioxidant, it can be cited for example that phosphite ester etc..
In the lubricant oil composite of one embodiment of the present invention, from the viewpoint of improving antioxygenic property, ingredient (E)
Content is counted preferably 0.001 mass % or more on the basis of the total amount (100 mass %) of the lubricant oil composite, is more preferably
0.005 mass % or more, further preferably 0.01 mass % or more.
In addition, the content of ingredient (E) is from the viewpoint of being made the good lubricant oil composite of drying property with the lubricating oil
Meter is preferably 1 mass % or less, is more preferably 0.8 mass % or less, is further excellent on the basis of the total amount (100 mass %) of composition
It is selected as 0.5 mass % or less.
Other additive for lubricant of < >
The lubricant oil composite of one embodiment of the present invention is not damaging in effective scope of the invention, can also containing in addition at
Divide the additive for lubricant except (B) ~ (E).
As such additive for lubricant, it can be cited for example that extreme pressure agent, abrasion performance agent, antirust agent, metal inerting
Agent, defoaming agent, viscosity index improver, antistatic agent etc..
These various additive for lubricant may be used singly or in combination of two or more.
Each content of these additive for lubricant is do not damage in effective scope of the invention can be with appropriate adjustment, with profit
Meter is usually 0.001 ~ 10 mass %, is preferably 0.005 ~ 8 mass %, more excellent on the basis of the total amount (100 mass %) of sliding oil composition
It is selected as 0.01 ~ 5 mass %.
(the various physical property of lubricant oil composite)
Kinematic viscosity at 40 DEG C of lubricant oil composite as one embodiment of the present invention, preferably 0.5 ~ 10mm2/ s, more
Preferably 0.75 ~ 5mm2/ s, further preferably 1 ~ 3mm2/s。
If the kinematic viscosity is 0.5mm2/ s or more, then when the lubricant oil composite being used for intermetallic composite coating, formation is filled
Point lubricating film and being easy play the effect for improving processing performance.
In addition, if the kinematic viscosity is 10mm2/ s is hereinafter, then the treatability of the lubricant oil composite is excellent.
Using the lubricant oil composite of one embodiment of the present invention, as being measured under conditions of being recorded in aftermentioned embodiment
Coefficient of friction, preferably shorter than 0.25, more preferably 0.22 or less, more preferably 0.18 or less, further preferably 0.16 with
Under, still more preferably be 0.15 or less.
If the coefficient of friction is lower than 0.25, it can be said that being the excellent lubricant oil composite of intermetallic composite coating.
[manufacturing method of lubricant oil composite]
It as the manufacturing method of lubricant oil composite of the invention, is not particularly limited, it is however preferred to have the side of following step (1)
Method.
Step (1)：To the step of cooperation N- acyl group sarcosine (B) in base oil (A) and alpha-olefin (C).
It should be noted that in step (1), together with ingredient (B) and (C), it can also combine gradation composition (D), (E) and remove
Additive for lubricant except ingredient (B) ~ (E).
It should be noted that ingredient (A) ~ (E) details (being suitble to ingredient, content and content ratio of other compositions etc.) institute as above
It states.
In base oil (A) after the additive for lubricant such as gradation composition (B) and (C), can by well known method into
Row stirs and keeps additive for lubricant evenly dispersed in base oil (A).
[purposes of lubricant oil composite]
Lubricant oil composite of the invention has excellent intermetallic composite coating, therefore is preferred for intermetallic composite coating, is more preferably used for
The intermetallic composite coating of aluminum material or aluminum alloy materials, the further preferably metal for aluminium fin material or aluminum alloy fin material add
Work.
In addition, lubricant oil composite of the invention is more preferably used for aluminum material particularly preferred for the press process of metal
Or the press process of aluminum alloy materials, further preferably it is used for the press process of aluminium fin material or aluminum alloy fin material.
(method for metal working)
Method for metal working of the invention is characterized in that, is added using above-mentioned lubricant oil composite of the invention to carry out metal
Work.
As the intermetallic composite coating, since lubricant oil composite of the invention has excellent intermetallic composite coating, preferably
For the press process of metal, the more preferably press process of aluminum material or aluminum alloy materials, further preferably aluminium fin material
Or the press process of aluminum alloy fin material.
It should be noted that in method for metal working of the invention, using above-mentioned lubricant oil composite of the invention, therefore i.e.
Make under conditions of such as 1.5 or more draw ratio (further for 1.6 or more under conditions of, particularly 1.7 or more condition
Under), also it is able to carry out good processing.
Embodiment
Then, present invention will be further described in detail through examples, but the present invention not due to these examples by any limit
It is fixed.
It should be noted that the kinematic viscosity at 40 DEG C of base oil used in embodiment below is according to JIS K2283：
2000 measurements.
Embodiment 1 ~ 28, comparative example 1 ~ 2
With type shown in table 1 ~ 3 and use level addition base oil and additive for lubricant, lubricant oil composite is prepared respectively.
Base oil described in table 1 ~ 3 used in embodiment and comparative example and additive for lubricant are as shown below.
< base oil >
Ingredient (A)：
Alkane hydrocarbon system synthetic oil (containing normal paraffin hydrocarbons and isoparaffin), 40 DEG C of kinematic viscosity=2.1mm2/ s can not calculate 100
DEG C kinematic viscosity and viscosity index (VI).
< additive for lubricant >
Ingredient (B)：
N- oleyl sarcosine：The compound that p and q in aforementioned formula (b-2) are 7.
Ingredient (C)：
Alpha-olefin (C12-C14)：The alpha-olefin that carbon atom number is 12 ~ 14.
Alpha-olefin (C16-C18)：The alpha-olefin that carbon atom number is 16 ~ 18.
Ingredient (D)：
Oleyl alcohol：The unsaturated alcohol that carbon atom number is 18.
Laruyl alcohol：The saturated alcohols that carbon atom number is 12.
Glycerol derivatives (1)：Two glycerine list oleyl ethers, the R in aforementioned formula (d-1)1aFor oleyl and z1 is
1 compound.
Glycerol derivatives (2)：Single glycerine list oleyl ether, the R in aforementioned formula (d-1)1aFor oleyl and z1 is
0 compound.
Ingredient (E)：
Antioxidant：2,6- di-t-butyl-paracresol.
For the lubricant oil composite prepared in embodiment and comparative example, test below is carried out, evaluates intermetallic composite coating
And drying property.These results are shown in table 1 ~ and 3.
(1) intermetallic composite coating is evaluated：Round-trip dynamic friction test
For the lubricant oil composite prepared in embodiment and comparative example, under experimental condition below, round-trip dynamic friction is used
Abrasiometer (Co., Ltd.'s A & D system, product name " AFT-15M-A ") measures the coefficient of friction of the 200th sliding.The friction
The value of coefficient is smaller, then is properly termed as the more excellent lubricant oil composite of intermetallic composite coating.
(experimental condition)
Ball material：SUJ2, diameter are 1/2 inch
Sliding material：A1050 is without surface treatment
Temperature：35℃
Load-carrying：3kgf
Sliding speed：20mm/s
Sliding distance：40mm
Sample oil mass：It is coated with moistly.
(2) drying property is evaluated：Drying test
In the glass dish for being 51mm to the diameter of measured in advance quality, the lubricating oil group prepared in embodiment and comparative example is acquired
Object 3g is closed, the lid of glass dish is not added, is put into 130 DEG C of thermostat (TABAI corporation, product name " SAFETY OVEN SPH-
The residual mass of lubricant oil composite after 200 ", measurement 45 minutes and after sixty minutes, calculates residual rate (%) by following formula.
[residual rate (%) after 45 minutes or after sixty minutes]=([lubricant oil composite after 45 minutes or after sixty minutes
Residual mass (g)]/[quality (that is, 3g) of the lubricant oil composite before test]) × 100.
[table 1]
。
[table 2]
。
[table 3]
。
According to table 1 ~ 3, the lubricant oil composite that is prepared in embodiment 1 ~ 28 and the lubricating oil composition prepared in comparative example 1 ~ 2
Object is compared, and the result that coefficient of friction is low and intermetallic composite coating is excellent is obtained.
Claims (14)
1. lubricant oil composite contains base oil (A), N- acyl group sarcosine (B) and alpha-olefin (C).
2. lubricant oil composite according to claim 1, wherein base oil (A) includes synthetic oil.
3. lubricant oil composite according to claim 1 or 2, wherein base oil (A) includes alkane hydrocarbon system synthetic oil.
4. lubricant oil composite described according to claim 1 ~ any one of 3, wherein the content of ingredient (B) is with the lubrication
0.001 ~ 9 mass % is calculated as on the basis of the total amount of fluid composition.
5. lubricant oil composite described according to claim 1 ~ any one of 4, wherein the carbon atom number of alpha-olefin (C) be 8 ~
20。
6. lubricant oil composite described according to claim 1 ~ any one of 5, wherein the content of ingredient (C) is with the lubrication
10 ~ 20 mass % are calculated as on the basis of the total amount of fluid composition.
7. lubricant oil composite described according to claim 1 ~ any one of 6, wherein ingredient (B) is relative to ingredient (C) 100
The content ratio of mass parts is 0.030 ~ 60 mass parts.
8. lubricant oil composite described according to claim 1 ~ any one of 7 also includes selected from glycerol derivatives, unitary
The oiliness improver (D) of one or more of alcohols, amine, fatty acid and fatty acid ester.
9. lubricant oil composite according to claim 8, wherein ingredient (D) contains relative to 100 mass parts of ingredient (B)
Amount compares for 500 below the mass.
10. lubricant oil composite according to claim 8 or claim 9, wherein ingredient (D) is relative to 100 mass parts of ingredient (C)
Content ratio be 30 below the mass.
11. lubricant oil composite described according to claim 1 ~ any one of 10 also contains antioxidant (E).
12. lubricant oil composite described according to claim 1 ~ any one of 11, is used for intermetallic composite coating.
13. lubricant oil composite described according to claim 1 ~ any one of 12, it to be used for aluminum material or aluminum alloy materials
Intermetallic composite coating.
14. method for metal working carries out intermetallic composite coating using lubricant oil composite described in any one of claim 1 ~ 13.
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|---|---|---|---|
| JP2016-073055 | 2016-03-31 | ||
| JP2016073055A JP6856296B2 (en) | 2016-03-31 | 2016-03-31 | Lubricating oil composition and metal processing method |
| PCT/JP2017/013133 WO2017170811A1 (en) | 2016-03-31 | 2017-03-30 | Lubrication oil composition and metal working method |
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| CN108884406A true CN108884406A (en) | 2018-11-23 |
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| CN201780020495.6A Pending CN108884406A (en) | 2016-03-31 | 2017-03-30 | Lubricating oil composition and metal working method |
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|---|---|
| JP (1) | JP6856296B2 (en) |
| CN (1) | CN108884406A (en) |
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| JP7364379B2 (en) * | 2019-07-19 | 2023-10-18 | 出光興産株式会社 | Lubricating oil composition, method for producing a lubricating oil composition, and method for lubricating a transmission or reduction gear |
| CN113444559B (en) * | 2021-07-30 | 2023-03-21 | 奎克化学（中国）有限公司 | Battery foil rolling additive and preparation method and application thereof |
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| JP2009221448A (en) * | 2008-03-19 | 2009-10-01 | Nippon Oil Corp | Metal working fluid composition |
| CN102127485A (en) * | 2010-01-12 | 2011-07-20 | Nok克鲁勃株式会社 | Lubricant composition |
| JP2012518046A (en) * | 2009-02-13 | 2012-08-09 | ビーエーエスエフ ソシエタス・ヨーロピア | N-acyl sarcosine composition |
| CN106133124A (en) * | 2014-03-28 | 2016-11-16 | 捷客斯能源株式会社 | Lubricant oil composite |
| CN107109291A (en) * | 2014-12-17 | 2017-08-29 | 国际壳牌研究有限公司 | Alhpa olefin absorption inhibition lubricant compositions, adsorption suppressing method and adsorption inhibitor |
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2016
- 2016-03-31 JP JP2016073055A patent/JP6856296B2/en active Active
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2017
- 2017-03-30 CN CN201780020495.6A patent/CN108884406A/en active Pending
- 2017-03-30 WO PCT/JP2017/013133 patent/WO2017170811A1/en active Application Filing
- 2017-03-30 TW TW106110805A patent/TW201807180A/en unknown
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| CN106133124A (en) * | 2014-03-28 | 2016-11-16 | 捷客斯能源株式会社 | Lubricant oil composite |
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2017179292A (en) | 2017-10-05 |
| WO2017170811A1 (en) | 2017-10-05 |
| TW201807180A (en) | 2018-03-01 |
| JP6856296B2 (en) | 2021-04-07 |
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