CN108865496B

CN108865496B - Environment-friendly pollution-free multifunctional hand-injury-free cleaning agent

Info

Publication number: CN108865496B
Application number: CN201810878079.6A
Authority: CN
Inventors: 王文举
Original assignee: Guangdong Zhancheng Yanchuang Technology Co ltd
Current assignee: Guangdong Longxing Tianxia Technology Co ltd
Priority date: 2018-08-03
Filing date: 2018-08-03
Publication date: 2021-02-12
Anticipated expiration: 2038-08-03
Also published as: CN108865496A

Abstract

The invention provides an environment-friendly pollution-free multifunctional hand-injury-free cleaning agent, which is prepared from the following raw materials: the component A comprises: natural sea salt, natural sea soda, a surfactant, gramineous sterol, cycloartenol, an oxidant, nano coral calcium powder and sodium citrate; and B component: radix Stemonae extract, cortex Phellodendri extract, Raphani semen extract, and herba Artemisiae Scopariae extract; and C, component C: flos Lonicerae extract, fructus Gleditsiae Abnormalis extract, fructus Cnidii extract, rhizoma Polygoni Cuspidati extract and Aloe extract; and (D) component: an alkaloid. 2. The multifunctional cleaning agent without hurting hands provided by the invention can easily cope with heavy oil stains in a kitchen; the oil stain can be quickly decomposed, and the decomposed oil stain is adsorbed and conveniently removed; and meanwhile, the hands are not injured.

Description

Environment-friendly pollution-free multifunctional hand-injury-free cleaning agent

Technical Field

The invention relates to a cleaning agent, in particular to a cleaning agent without hurting hands.

Background

In the real life, due to the daily accumulation in the life process, the sanitary conditions in kitchens such as families, hotels, restaurants and the like have a plurality of dead corners, and each corner has dirt which is difficult to remove, so that the dirt accumulated throughout the year is not strong in decontamination effect only by a common cleaning agent, and is difficult to realize quick and thorough cleaning.

Since commercially available fruits, vegetables, dried fruits and the like contain abundant nutritional ingredients, the food is indispensable to human life. At present, people not only eat a large number of varieties of fruits and vegetables, but also consume a large amount of fruits, vegetables, dried fruits, dried vegetables, edible fungi and the like every day. Therefore, the planting of fruits, vegetables and the like can bring great economic benefits to farmers. However, due to the large-area cultivation of fruits and vegetables, farmers usually use a large amount of pesticides to control the occurrence of plant diseases and insect pests, and simultaneously, due to the abuse of the pesticides and the harvesting of the fruits and vegetables before reaching the safe period after the pesticide application, a large amount of pesticides are left on the surfaces of the fruits and vegetables. Since these residual pesticides have low water solubility and cannot be washed with clean water, they are sometimes poisoned by pesticides when eaten on such fruits and vegetables, and thus have a great social impact.

The invention provides an environment-friendly pollution-free multifunctional cleaning agent without hurting hands.

Disclosure of Invention

The invention provides an environment-friendly pollution-free multifunctional hand-injury-free cleaning agent, which is prepared from the following raw materials:

the component A comprises: natural sea salt, natural sea soda, a surfactant, gramineous sterol, cycloartenol, an oxidant, nano coral calcium powder and sodium citrate;

and B component: radix Stemonae extract, cortex Phellodendri extract, Raphani semen extract, and herba Artemisiae Scopariae extract;

and C, component C: flos Lonicerae extract, fructus Gleditsiae Abnormalis extract, fructus Cnidii extract, rhizoma Polygoni Cuspidati extract and Aloe extract;

and (D) component: an alkaloid.

As an embodiment of the present invention, the surfactant is a nonionic surfactant and an ionic surfactant in a weight ratio of 1: 2, or a mixture thereof.

In one embodiment of the invention, the nano coral calcium powder is polysaccharide-modified coral calcium powder.

In one embodiment of the present invention, the polysaccharide is pectin.

As an embodiment of the present invention, the alkaloid is selected from one or more of pyridines, pyrrolidines, tropanes, and xanthines.

As an embodiment of the present invention, the alkaloid is selected from one or more of piperine, conidine, trigonelline, arecoline, tetrahydronicotinic acid, pilocarpine, laburnine, nicotine, sparteine, punicine, guline, erythroguline, atropine, cocaine, ecgonine, scopolamine, caffeine, theobromine, and theophylline.

As an embodiment of the present invention, the preparation method of the honeysuckle extract comprises:

s01, selecting 5 parts of honeysuckle, adding 25 parts of distilled water, decocting for 40 minutes, and taking decoction; then concentrating the decoction to 1/3 parts, slowly adding 20% lime milk until the pH value is 10, and centrifuging to obtain a precipitate;

s02 grinding the precipitate and 2 times of ethanol into slurry, then adding 55% sulfuric acid dropwise under stirring until the pH value is 3, then stirring thoroughly, centrifuging, and taking the acid water solution;

s03 taking the acid water solution, adjusting the pH value to 6 with concentrated alkali, then recovering ethanol, drying under reduced pressure, and taking the crude extract;

s04, dissolving the crude extract in 10 times of centrifugal water and 20 times of hydroalcoholic, and adjusting the pH value to 2 by hydrochloric acid; then filtering with egg white membrane to obtain filtrate;

s05 extracting the filtrate with ethyl acetate for several times, and collecting ethyl acetate solution; then filtering to obtain filtrate;

s06 concentrating the filtrate, adding chloroform, collecting solid, and drying under reduced pressure to obtain flos Lonicerae extract.

As an embodiment of the present invention, the torilidis fructus extract is prepared by the following steps:

(1) selecting 1 part of fruit coarse powder, adding 15 times of ethanol, uniformly dividing into three parts, soaking for 2 hours respectively, combining three parts of alcohol solution, then concentrating under reduced pressure to 1 part of alcohol solution, and taking a water layer;

(2) standing the water layer, solidifying, adding a small amount of ethanol, thermally dissolving, standing for crystallization, and taking out crystals;

(3) recrystallizing the crystal in the step (2) for multiple times by using absolute ethyl alcohol to obtain a block crystal;

(4) and (4) adding 10 parts of ethanol, 20 parts of distilled water and 3 parts of silk fibroin into the blocky crystal prepared in the step (3), uniformly stirring, filtering and drying to obtain the fructus cnidii extract.

As an embodiment of the present invention, the component B and the component C are coated with sustained-release films, respectively.

As an embodiment of the invention, the slow release film is modified rhamnose.

Has the advantages that:

1. the multifunctional non-hand-injury cleaning agent provided by the invention can inhibit bacteria and quickly remove pesticide residues and fruit wax; but also can avoid the rapid loss and damage of the water of the fruits after being cleaned;

2. the multifunctional cleaning agent without hurting hands provided by the invention can easily cope with heavy oil stains in a kitchen; the oil stain can be quickly decomposed, and the decomposed oil stain is adsorbed and is convenient to remove; and meanwhile, the hands are not injured.

Detailed Description

For purposes of the following detailed description, it is to be understood that the invention may assume various alternative variations and step sequences, except where expressly specified to the contrary. Moreover, other than in any operating examples, or where otherwise indicated, all numbers expressing, for example, quantities of ingredients used in the specification and claims are to be understood as being modified in all instances by the term "about". Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties to be obtained by the present invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.

Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements.

Moreover, it should be understood that any numerical range recited herein is intended to include all sub-ranges subsumed therein. For example, a range of "1 to 10" is intended to include all sub-ranges between (and including) the recited minimum value of 1 and the recited maximum value of 10, i.e., having a minimum value equal to or greater than 1 and a maximum value of equal to or less than 10.

and (D) component: an alkaloid.

Component A

Natural sea salt

In the invention, the natural sea salt is prepared by introducing sea water into a salt pan, and naturally drying and crystallizing the sea water through solarization and evaporation; natural sea salt contains more potassium than ordinary edible salt, but has similar contents of other minerals such as sodium, phosphorus and calcium.

In the present invention, the natural sea salt is purchased from san salt co ltd, lazhou.

Natural sea alkali

In the invention, the natural marine alkali is natural alkali, salt minerals obtained by evaporating products in a salt lake sedimentary zone are hydrated sodium bicarbonate and mainly come from alkali lakes and solid alkali ores; the main chemical components of the fertilizer are minerals such as sodium carbonate and sodium bicarbonate. It is in the form of fibrous or columnar block, gray or yellowish white or colorless.

Surface active agent

In the invention, the surfactant is a nonionic surfactant and an anionic surfactant according to a weight ratio of 1: 2, or a mixture thereof.

Nonionic surfactant: the nonionic surfactant is a polyoxyethylene nonionic surfactant; a polyoxyethylene-type nonionic surfactant which is a product of addition reaction of ethylene oxide with a compound containing active hydrogen; the active hydrogen atom is-OH, -COOH, -NH₂and-CONH₂Etc. in the radical.

As an embodiment of the present invention, the nonionic surfactant is selected from one or more of tween-20, tween-60 and tween-80.

Anionic surfactant: the anionic surfactant is sodium dodecyl benzene sulfonate.

Gramineous sterols

In the invention, the gramineous sterol is one of phytosterols, and is 4-methyl sterol phytosterol.

Cycloartenol

In the invention, the cycloartenol is one of phytosterols, and is one of 4, 4' -dimethyl sterols.

Oxidizing agent

In the present invention, the oxidizing agent is an inorganic peroxide.

In the invention, the inorganic peroxide is selected from one or more of sodium peroxide, potassium peroxide, calcium peroxide, magnesium peroxide and zinc peroxide.

As an embodiment of the present invention, the inorganic peroxide is calcium peroxide.

Nano coral calcium powder

Coral calcium is a daily nutritional supplement, and is coral sand prepared by weathering and naturally decomposing live coral. It contains very high concentrations of calcareous, major and trace minerals, also known as marine diamonds because of their abundant mineral content.

The nano coral calcium powder is prepared by grinding coral calcium to a nano level, and then performing polysaccharide modification on the nano coral calcium powder; the polysaccharide is pectin.

In the invention, the preparation method of the polysaccharide modified nano coral calcium powder comprises the following steps:

1. dripping a small amount of deionized water into the nano coral calcium powder at room temperature, and uniformly dispersing the nano coral calcium powder after ultrasonic oscillation treatment;

2. dispersing polysaccharide in water solution to prepare polysaccharide solution with the concentration of 3%;

3. gradually dropping the polysaccharide solution into the nano coral calcium powder slurry obtained in the step 1 under the ultrasonic condition, continuing ultrasonic treatment for 10 minutes after the dropping is finished, freezing the mixed solution at-80 ℃ for 12 hours, and freeze-drying to obtain the polysaccharide modified nano coral calcium powder.

Wherein the weight ratio of the polysaccharide to the nano coral calcium powder is 1: 2.

citric acid sodium salt

The alias sodium citrate is an organic compound and is white to colorless crystal in appearance. No odor, and cool, salty and spicy taste. The air-conditioning agent is stable in normal temperature and air, has slight solubility in wet air, and generates a weathering phenomenon in hot air. Heating to 150 deg.C to lose the crystal water. Easily soluble in water, soluble in glycerol, insoluble in alcohols and other organic solvents, pyrolyzed, slightly deliquesced in humid environment, and slightly weathered in hot air.

B component

In the invention, the component B is stemona extract, phellodendron extract, radish seed extract and oriental wormwood extract, and the component B is coated by a slow release film.

The slow release film is modified rhamnose, and the modified rhamnose is polyvinyl alcohol modified rhamnose.

In the invention, the preparation method of the component B comprises the following steps:

1. dissolving 1.5g of rhamnose in 100mL of 2% acetic acid aqueous solution, and stirring and dissolving by using a magnetic stirrer; 1g of polyvinyl alcohol is dissolved in 30mL of water and heated to be dissolved; the rhamnose and the polyvinyl alcohol solution are stirred and mixed evenly, water bath is carried out at 50 ℃ for 48h, 40mL of mixed solution is added with 1.6-2.8g of 200-mesh silica gel and then poured into a glass plate, and the mixture is evaporated at room temperature to form a film. And immersing the obtained dried membrane into 2mol/L sodium hydroxide solution, and dissolving silica gel in water bath at 50 ℃ for 2h to obtain the rhamnose/polyvinyl alcohol. The excess sodium hydroxide was neutralized with 5% acetic acid, rinsed to neutrality with deionized water, and dried in a dry box.

2. Mixing radix Stemonae extract, cortex Phellodendri extract, Raphani semen extract, and herba Artemisiae Scopariae extract to obtain extract mixture;

3. and (2) mixing 10g of the rhamnose/polyvinyl alcohol prepared in the step (1) with 80g of distilled water, adding 6g of the extract mixture at room temperature, uniformly stirring, performing ultrasonic treatment for 30min to uniformly mix, and performing spray drying at the inlet temperature of 175 ℃, the feed flow rate of 3mL/min, the nozzle head diameter of 0.7mm and the nozzle cleaning for 2 times/min to obtain a component B.

Radix Stemonae extract and cortex Phellodendri extract

Stemona is also known as Boraginaceae and pediculosis drug, and is a plant of Stemonaceae. Radix Stemonae is a perennial herb, and spindle fleshy root tuber grows underground, and other things climb up the upper part of the stem. Oval leaves, 2-4 trochanteric nodes. In early spring, light green flowers are bloomed, and flower stalks are attached to the main veins of the leaves, like flowers growing from the leaves.

Radix Stemonae is rich in a large amount of alkaloids, and root contains stemonine, tuberostemonine, stilinine, subestemonine, and stemonine oxide; it also contains sugar 2.32%, lipid 0.84%, protein 9.25%, ash 12.1%, and acetic acid, formic acid, malic acid, succinic acid, oxalic acid, etc.

Cortex Phellodendri contains alkaloids such as berberine, jateorhizine, magnoflorine, phellodendrine, N-methyl hordenine, tetrandrine, dauricine, etc.; and further contains obacunone, obacunlactone, dictamnolide, obacunone acid, green fluorescent acid, 7-dehydrostigmasterol, beta-sitosterol, and campesterol. The cortex Melaleucae Leucadendrae contains berberine, jateorhizine, phellodendrine and N-methyl hordenine. Wood also contains berberine. The fresh leaves contain phellodendrin, dehydrophellodendrin, dehydroisocoryzanin, and isocoryzanin. The dried leaves contain hyperin and no phellodendron glycosides.

In the invention, the extraction method of the stemona root extract and the phellodendron bark extract comprises the following steps:

1. selecting 1 part of radix stemonae and 1 part of phellodendron amurense bark, cleaning, drying, grinding, adding 10 parts of lime milk, uniformly stirring, putting into a percolation cylinder, soaking for 6 hours by using lime water, taking a percolate, adding 120% of the volume of the percolate, adding a citric acid saturated aqueous solution, stirring, standing overnight, filtering and taking a precipitate;

2. dissolving the precipitate with hot water, filtering, and collecting filtrate to obtain radix Stemonae extract and cortex Phellodendri extract crude product;

3. dissolving the crude product in boiling water, and filtering while hot to obtain radix Stemonae extract and cortex Phellodendri extract.

In the invention, the conventional stemona root extract and the phellodendron bark extract are extracted separately, and simultaneously, the basic substance is added after lime milk is added in the conventional extraction, and excessive organic acid is added in the invention, so that hydrochloric acid can be added in the later period for pH adjustment, thereby obtaining the alkaloids of the stemona root extract and the phellodendron bark extract, such as magnoflorine, phellodendrine and the like except berberine and stemonine, and avoiding excessive substance loss.

Radish seed extract

Radish seed, name of traditional Chinese medicine. Is dried mature seed of radish of Brassicaceae. Harvesting plants in summer when the fruits are ripe, drying in the sun, rubbing out the seeds, removing impurities, and drying in the sun.

The chemical components of the seed comprise fatty oil and volatile oil. The volatile oil contains methyl mercaptan, etc. The fatty oil contains high content of erucic acid, linoleic acid, linolenic acid, erucic acid glyceride, etc. Also contains antibacterial substance called sulforaphane.

In the present invention, the preparation method of the radish seed extract refers to the preparation method of patent CN 103830305A.

Herba Artemisiae Scopariae extract

Contains volatile oil, wherein the oil contains carvone, p-cymene, limonene, perillene, alpha-phellandrene, thymol, alpha-, beta-pinene, terpineol-4, verbenazone, naphthalene and arylmethylacetophenone, and the other contains incarvillin, p-hydroxyacetophenone and chlorogenic acid. And capillary artemisia chromone and 6, 7-dimethoxy coumarin.

In the invention, the preparation method of the artemisia capillaris extract comprises the following steps:

1. selecting 10 parts of oriental wormwood, decocting the oriental wormwood in water for 4 hours, and filtering the decoction to obtain a water extract;

2. then concentrating the water extract to 1/4 volume, and extracting with chloroform;

3. selecting chloroform extract, extracting with 5% sodium bicarbonate and 2% sodium hydroxide, respectively, selecting sodium hydroxide extract, acidifying with hydrochloric acid, and extracting with chloroform;

4. selecting chloroform extract, recovering chloroform, subjecting the acidic part to polyamide column chromatography, and gradient eluting with ethanol (with concentration of 30%, 50% and 80% respectively);

5. selecting 80% ethanol eluate, heating to volatilize ethanol, extracting with diethyl ether, recovering diethyl ether extractive solution, and recovering diethyl ether to obtain white solid.

C component

In the present invention, the component C comprises honeysuckle extract, saponin extract, cnidium monnieri extract, polygonum cuspidatum extract and aloe extract.

In the invention, the component C is coated by a slow release film.

In the invention, the preparation method of the component C comprises the following steps:

2. Mixing flos Lonicerae extract, fructus Gleditsiae Abnormalis extract, fructus Cnidii extract, rhizoma Polygoni Cuspidati extract and Aloe extract to obtain extract mixture;

3. and (2) mixing 10g of the rhamnose/polyvinyl alcohol prepared in the step (1) with 80g of distilled water, adding 6g of the extract mixture at room temperature, uniformly stirring, performing ultrasonic treatment for 30min to uniformly mix, and performing spray drying at the inlet temperature of 175 ℃, the feed flow rate of 3mL/min, the nozzle head diameter of 0.7mm and the nozzle cleaning for 2 times/min to obtain a component C.

Honeysuckle extract

Honeysuckle, known as honeysuckle. The honeysuckle flower contains the following components: luteolin, inositol and saponin. They can separate chlorogenic acid and isochlorogenic acid, and are the main effective components of flos Lonicerae with antibacterial effect.

In the invention, the preparation method of the honeysuckle extract comprises the following steps:

1. selecting 5 parts of honeysuckle, adding 25 parts of distilled water, decocting for 40 minutes, and taking decoction; then, after the decoction is concentrated to 1/3 parts, 20 percent of lime milk is slowly added until the pH value is 10, and the precipitate is obtained by centrifugation;

2. grinding the precipitate and 2 times of ethanol into slurry, then dropwise adding 55% sulfuric acid under stirring until the pH value is 3, then fully stirring, centrifuging, and taking an acid-water solution;

3. taking the acid water solution, adjusting the pH value to 6 by using concentrated alkali, then recovering ethanol, and drying under reduced pressure to obtain a crude extract;

4. dissolving the crude extract in 10 times of centrifugal water and 20 times of hydroalcoholic, and adjusting the pH value to 2 by using hydrochloric acid; then filtering with egg white membrane, and collecting filtrate;

5. extracting the filtrate with ethyl acetate for several times, and collecting ethyl acetate solution; then filtering to obtain filtrate;

6. concentrating the filtrate, adding chloroform, collecting solid, and drying under reduced pressure to obtain flos Lonicerae extract.

The honeysuckle extract has the allergen characteristic, and the crude extract is dissolved in 10 times of centrifugal water and 20 times of hydroalcoholic in the preparation process, so that the allergen condition of the honeysuckle extract can be improved.

Chinese honeylocust fruit extract

Chinese honeylocust fruit, also known as Chinese honeylocust tree, is one of the unique tree species of Gleditsia of Caesalpiniaceae, grows vigorously, is a male and female variant, and has strong pod-bearing ability.

The component of fructus Gleditsiae Abnormalis comprises saponin B-G of Gleditsia sinensis, palmitic acid, stearic acid, oleic acid, Stigmasterol, sitosterol, and nonacosane.

In the present invention, the saponin extract is commercially available.

Fructus Cnidii extract

Cnidium fruit, name of Chinese medicine. Is dried mature fruit of cnidium officinale belonging to family Umbelliferae.

The fruit contains volatile oil 1.3%, and contains pinene, camphene, isobaric borneol ester, and isoborneol as main ingredients. Also contains methoxyl group parsley phenol, osthole, isosaxifrage, bergapten, dihydrocarveol and its angelate, and acetate; origanate, cnidipine, isobutanoyloxydisulenol acetate.

The root contains cnidium lactone, isopimpinellin, imperatorin, xanthotoxol and imperatorin.

Palmitic acid, beta-sitosterol, bergapten, isopimpinellin, xanthotoxol and the like are obtained in addition to 7-methoxy-carvacrol from the fruit alcohol extract. According to the report, the commercial cnidium fruit in China contains 0.20% of columbianactone, angelicin, edible angelicin, bergapten, isopimpinellin, O-acetyl dihydrooroselagin, O-isovaleryl dihydrooroselagin, 3' -isobutyryloxy-O-acetyl dihydrooroselagin and O-isobutyryl dihydrooroselagin. The seed contains bergapten, parsley extract and edible angelicin.

The preparation method of the fructus cnidii extract comprises the following steps:

1. selecting 1 part of fruit coarse powder, adding 15 times of ethanol, uniformly dividing into three parts, soaking for 2 hours respectively, combining three parts of alcohol solution, then concentrating under reduced pressure to 1 part of alcohol solution, and taking a water layer;

2. standing the water layer, solidifying, adding a small amount of ethanol, thermally dissolving, standing for crystallization, and taking out crystals;

3. recrystallizing the crystal obtained in the step 2 for multiple times by using absolute ethyl alcohol to obtain a block crystal;

4. and (3) adding 10 parts of ethanol, 20 parts of distilled water and 3 parts of silk fibroin into the blocky crystal prepared in the step (3), uniformly stirring, filtering and drying to obtain the fructus cnidii extract.

Polygonum cuspidatum extract

Giant knotweed rhizome, name of traditional Chinese medicine. Is dried rhizome and root of Polygonum cuspidatum of Polygonaceae. Collected in spring and autumn, removed fibrous root, cleaned, cut into short segments or thick slices, and dried in the sun. Distributed in northwest, east, center, south and southwest regions. Has effects of promoting diuresis, eliminating jaundice, clearing away heat and toxic materials, dispelling blood stasis, relieving pain, relieving cough, and eliminating phlegm.

The giant knotweed extract contains anthraquinone derivatives, the total amount can reach 2.1010 according to analysis, the free type is taken as the main material, and the combined type content is lower; it also contains astragaloside (resveratrol) and astragaloside (polydatin), and contains tannin and multiple flavonoids. In addition, it contains chrysophanol, physcion, 6-hydroxy aloe-emodin, rhein, isoquercitrin, tigenin, citric acid, malic acid, etc.

In the invention, the preparation method of the giant knotweed extract comprises the following steps:

1. taking 1 part of giant knotweed rhizome coarse powder, then carrying out cold soaking by using ethanol, and then taking an ethanol cold soaking solution; concentrating the ethanol cold extract under reduced pressure to obtain extract;

2. adding distilled water into the extract, and adding CHCl₃Refluxing, and taking water solution;

3. extracting the water solution with EtOAc, filtering to remove precipitate, and collecting EtOAc layer;

4. the EtOAc layer was concentrated under reduced pressure, dissolved in water and then Et₂Extracting with water, and collecting a water layer;

5. treating the water layer with active carbon, adding dropwise piperine solution, standing, and collecting colloidal precipitate;

6. taking colloidal precipitate, adding small amount of MeOH for dissolving, adding water for diluting, and adding CHCl with equal volume₃Collecting a water layer after extracting for a plurality of times;

7. extracting the water layer with EtOAc, collecting the EtOAc layer, dehydrating, and concentrating under reduced pressure to obtain rhizoma Polygoni Cuspidati extract.

Aloe extract

Aloe is a new star of plant integrating edible, medicinal, skin caring and ornamental functions, and its secretion (the main effective component is allin substances such as aloin) has been widely used in medicine and daily chemical products. Aloe vera is used by Chinese folks as a natural drug for beauty, hair care and treatment of skin diseases. Aloe gel has effect in relieving itching of mosquito bite.

In the present invention, the aloe vera extract is commercially available from siennan biotechnology limited.

D component

Alkaloid is a nitrogen-containing basic organic compound existing in nature, and has alkali-like properties, so that the alkaloid is also called pseudo-alkali in the past.

The alkaloids can be pyridine, pyrrolidine, tropane, quinoline, isoquinoline, phenethylamine, tryptamine, ergoline, beta-carboline, vinblastine, marchanzi, xanthine, and aconite.

In a preferred embodiment of the present invention, the alkaloids are nicotine, scopolamine and cytisine in a weight ratio of 2: 1: 1.

As an embodiment of the present invention, the weight ratio of the a component, the B component, the C component and the D component is 5: 2: 2: 1.

in the component a, the weight ratio of the natural sea salt, the natural sea soda, the surfactant, the gramineous sterol, the cycloartenol, the oxidant, the nano coral calcium powder and the sodium citrate is 1: 1: 0.5: 0.2: 0.2: 0.01: 1: 0.02.

in one embodiment of the present invention, in the component B, the weight ratio of the stemona root extract, the phellodendron bark extract, the radish seed extract and the artemisia capillaris extract is 1: 1: 1: 1.

in one embodiment of the invention, in the component C, the weight ratio of the honeysuckle extract, the saponin extract, the cnidium monnieri extract, the polygonum cuspidatum extract and the aloe extract is 2: 1: 2: 2: 1.

the mechanism is explained as follows: the multifunctional hand-friendly cleaning agent prepared by the invention is suitable for cleaning vegetables, fruits, rice, eggs, meat and aquatic products, and can remove oil stains in a kitchen. Meanwhile, the natural coral calcium powder and the natural sea alkali are added, so that the oil stain decomposing agent has strong decomposing capacity, can adsorb and wrap decomposed small molecular oil stains, and is convenient to clear in the later period. Meanwhile, the cleaned fruits are covered with a layer of protective film, so that the water loss of the fruits is relieved, and the protective film has excellent protective performance particularly for the apples.

The environment-friendly pollution-free multifunctional hand-injury-free cleaning agent is described in detail with reference to specific embodiments.

Example 1:

the embodiment provides an environment-friendly pollution-free multifunctional hand-injury-free cleaning agent, and the preparation raw materials of the cleaning agent comprise:

and (D) component: an alkaloid.

The weight ratio of the component A to the component B to the component C to the component D is respectively 5: 2: 2: 1.

in the component A, the weight ratio of the natural sea salt, the natural sea alkali, the surfactant, the gramineous sterol, the cycloartenyl alcohol, the oxidant, the nano coral calcium powder and the sodium citrate is 1: 1: 0.5: 0.2: 0.2: 0.01: 1: 0.02.

in the component B, the weight ratio of the stemona root extract to the phellodendron bark extract to the radish seed extract to the oriental wormwood extract is 1: 1: 1: 1.

in the component C, the weight ratio of the honeysuckle extract, the Chinese honeylocust fruit extract, the common cnidium fruit extract, the giant knotweed rhizome extract and the aloe extract is 2: 1: 2: 2: 1.

the surfactant is tween-60 and sodium dodecyl benzene sulfonate according to a weight ratio of 1: 2, or a mixture thereof.

The oxidant is calcium peroxide.

The preparation method of the polysaccharide modified nano coral calcium powder comprises the following steps:

the preparation method of the component B comprises the following steps:

The extraction method of the stemona extract and the phellodendron extract comprises the following steps:

The preparation method of the herba artemisiae capillaris extract comprises the following steps:

The component C comprises flos Lonicerae extract, fructus Gleditsiae Abnormalis extract, fructus Cnidii extract, rhizoma Polygoni Cuspidati extract and Aloe extract.

In the invention, the component C is coated by a slow release film.

The preparation method of the honeysuckle extract comprises the following steps:

The saponin extract is commercially available.

The preparation method of the giant knotweed extract comprises the following steps:

4. the EtOAc layer was concentrated under reduced pressure, dissolved in water and then Et₂O extracting and takingA water layer;

The aloe extract is commercially available

The alkaloid is nicotine, scopolamine and laburnine according to the weight ratio of 2: 1: 1.

Example 2:

and (D) component: an alkaloid.

The oxidant is calcium peroxide.

Wherein the weight ratio of the polysaccharide to the nano coral calcium powder is 1: 1.

the preparation method of the component B comprises the following steps:

In the invention, the component C is coated by a slow release film.

The saponin extract is commercially available.

The aloe extract is commercially available

Example 3: example 3 is a similar embodiment to example 1, except that the weight ratios of the a, B, C and D components are 3: 2: 2: 1.

example 4: example 4 the specific embodiment is the same as example 1 except that the a component is free of sitosterol, cycloartenol.

Example 5: example 5 is a similar embodiment to example 1 except that the component A is free of nano coral calcium powder.

Example 6: the embodiment of example 6 is substantially the same as that of example 1, except that the nano coral calcium powder is not modified.

Example 7: example 7 the embodiment is substantially the same as example 1 except that the plant extract of component B is not coated with a sustained release film.

Example 8: example 8 the embodiment is the same as example 1 except that the plant extract of component C is not coated with a sustained release film.

Example 9: the embodiment of example 9 is substantially the same as that of example 1, except that,

4. dissolving the crude extract in 10 times of water alcohol, and adjusting the pH value to 2 by hydrochloric acid; extracting with ethyl acetate for several times, and collecting ethyl acetate solution; then filtering to obtain filtrate;

5. concentrating the filtrate, adding chloroform, collecting solid, and drying under reduced pressure to obtain flos Lonicerae extract.

Example 10: the embodiment of example 10 is substantially the same as that of example 1, except that,

3. and (3) recrystallizing the crystals obtained in the step (2) for multiple times by using absolute ethyl alcohol to obtain blocky crystals, and drying to obtain the fructus cnidii extract.

Example 11: the embodiment of example 11 is substantially the same as example 1, except that,

5. treating the water layer with active carbon, dripping caffeine solution, standing, and collecting colloidal precipitate;

Example 12: example 12 is a similar embodiment to example 1, except that the release films of both component C and component B are polyvinyl alcohol.

Performance testing

Pesticide residue testing

1. Distilled water, a commercial detergent and the multifunctional non-injurious hand cleaning agent are selected to respectively clean cowpeas treated according to the national standard, and then the cypermethrin residual rate and the propoxur residual rate of the cowpeas before and after cleaning are detected, wherein the specific test method refers to the standard GB 23200.8-2016.

In the patent, the commercially available detergent is white cat lemon black tea detergent purchased from a supermarket.

Table 1: test results of test 1

According to the test 1, the cypermethrin residue rate and propoxur residue rate of the multifunctional non-hand-injuring cleaning agent provided by the embodiment 1 are the lowest after cowpeas are cleaned, and the multifunctional non-hand-injuring cleaning agent provided by the embodiment 1 has the best effect.

2. For the test method of test 1, the multifunctional non-injurious hand detergent provided in example 1 was used to clean and test apples in the same manner, and the test results are shown in table 2.

Table 2: test results of test 2

Examples	Residual rate of cypermethrin, percent		Residual ratio of propoxur%
				Example 1	0.08	1	0.06
Example 2	0.13	2	0.10
				Example 3	0.21	3	0.19
Example 4	1.76	7	1.65
				Example 5	2.18	12	2.09
Example 6	1.70	6	1.68
				Example 7	1.91	10	1.82
Example 8	1.91	10	1.82
				Example 9	1.79	8	1.76
Example 10	1.85	9	1.76
				Example 11	1.18	4	1.13
Example 12	1.61	5	1.52
				Washing with water	3.06		2.90
Commercial detergent	2.53		2.42

As shown in tests 1 and 2, the effect of the multifunctional hand-injury-free cleaning agent on apples is superior to that of cowpeas.

And (3) testing: the cleaned apples and unwashed apples of test 2 were stored at room temperature at 28 ℃ and 55% humidity. When 20% of the fruit on the surface decayed, the storage time of the fruit was recorded and is reported in table 3.

Table 3: test results of test 3

And (4) testing: and (5) testing the antibacterial performance. Selecting the cowpeas in the test 1, testing the antibacterial performance of each bacterium on the surfaces of the cowpeas in the test 1, and mainly checking the size of an antibacterial ring.

Table 4: test result of test 4

And (5) testing: and (3) testing detergency:

1) preparation of Artificial soil

The formula of the mixed oil comprises: the soil is prepared from beef tallow, lard and vegetable oil according to the mass ratio of 0.5:0.5:1, and 5% of glyceryl monostearate by mass of the total mass of the soil is added, so that the artificial soil is obtained.

Heating the artificial dirt on an electric furnace to 180 ℃, stirring and keeping the temperature for 10min, transferring the beaker to an electromagnetic stirrer for stirring, and naturally cooling to the required temperature for later use. Smearing temperature recommendation reference: when the room temperature is 20 ℃, the oil temperature is required to be 80 ℃; when the room temperature is 25 ℃, the oil temperature is 45 ℃; when the room temperature is lower than 17 ℃ or higher than 27 ℃, the test is not suitable to be carried out, and the test needs to be carried out in an air-conditioned room. If necessary, a vertical type decontamination machine with a freezing device is used.

2) Preparation of soil sheet

A100 cm line was drawn on the slide (110 cm. times.110 cm) to show that smear was confined below this line; the lower edge of the slide was drawn with a 50cm line to show that wiping of excess oil was confined below this line.

3) After the newly purchased glass slide needs to be boiled in water for 15min, the glass slide is washed by clean water until water drops are not hung, and then the glass slide is soaked in acid washing liquor for 1h, rinsed by clean water and washed by distilled water, and then the glass slide is placed in a drying oven for drying and standby.

4) Smearing with dirt

The clean glass slides are put on a weighing rack in groups of four, and are precisely weighed (accurate to 1mg) to m by an analytical balance₀And clamping the weighed glass slides on a slide airing rack one by one, wherein the clamp is clamped above the line of the glass slides, and the slide airing rack is arranged in a enamel plate to be ready for smearing.

And when the oil stain is kept at a determined temperature, the glass slides and the clips are taken down from the film airing rack one by one, the glass slides are immersed into the oil stain by holding the clips to a position (1-2) s below the upper line of 100cm, the glass slides are taken out slowly, and the glass slides are hung back to the original film airing rack to sequentially prepare the oil stain after the dropping speed of the oil stain is slowed down. After the oil stains are solidified, taking down the dirty sheet, wiping off redundant oil stains on the bottom edge and two sides of the lower edge of the dirty sheet within 50cm by using filter paper or absorbent cotton, and wiping the dirty sheet clean by using forceps to clamp the absorbent cotton stained with petroleum ether. After being dried for 4 hours at room temperature, the mixture is accurately weighed to m by an analytical balance on a weighing frame₁. The amount of the dirt on each group of dirt pieces should be guaranteed to be (5 +/-0.5) g.

5) Test procedure

A glass slide of known smear was washed with the same amount of examples 1-10 and a commercial detergent, wiped in one direction along the slide, in one direction,wiping for 10 times, placing the glass slide in clear water, standing for 5 minutes, taking out, drying, and weighing to m₂。

6) The results show that: oil removal rate omega ═ m₁－m₂)/(m₁－m₀)×100％。

In the formula: m is₀-slide mass before smearing, g; m is₁-slide mass after smear, g; m is₂-mass of soiled pieces after washing, g.

TABLE 5 test chart for oil removal rate

Examples	Oil removal rate%
		Example 1	83.2
Example 2	78.1
		Example 3	75.6
Example 4	63.5
		Example 5	43.8
Example 6	71.5
		Example 7	47.9
Example 8	47.8
		Example 9	61.3
Example 10	54.2
		Example 11	74.9
Example 12	72.8
		Commercial detergent	25.5

In the invention, the commercially available detergent is white cat lemon black tea detergent purchased from a supermarket.

And 6, testing: stain redeposition test:

the washed re-smear preparation operation of test 1 was calculated for the smear rate and the re-oil removal rate.

The new dirty sheet preparation operation:

the clean glass slides are put on a weighing rack in groups of four, and are precisely weighed (accurate to 1mg) to m by an analytical balance₀' clamping the weighed glass slides on a slide airing rack one by one, wherein the clamp is clamped above the line of the glass slides, and the slide airing rack is placed in a enamel plate to be ready for smearing.

When the oil stain is kept at a certain temperature, the glass slides and the clips are taken down from the film airing rack one by one, the glass slides are immersed into the oil stain by holding the clips to a position (1-2) s below the upper line of 100cm, the glass slides are taken out slowly, and the glass slides are hung back to the original film airing rack to be aired after the dropping speed of the oil stain is slowed downDirty sheets are prepared on the sheet rack in sequence. After the oil stains are solidified, taking down the dirty sheet, wiping off redundant oil stains on the bottom edge and two sides of the lower edge of the dirty sheet within 50cm by using filter paper or absorbent cotton, and wiping the dirty sheet clean by using forceps to clamp the absorbent cotton stained with petroleum ether. After being dried for 4 hours at room temperature, the mixture is accurately weighed to m by an analytical balance on a weighing frame₁'. At this time, it is not necessary to ensure that the amount of smeared sheets per set is (5. + -. 0.5) g.

Fouling rate (m)₁’-m₀’)/(m₁-m₀)×100％。

At the same time, the newly prepared soiled sheet was subjected to the test procedure of test 1 to obtain a mass m₂’。

Oil removal rate again: ω' ═ m₁’－m₂’)/(m₁’－m₀’)×100％。

TABLE 2 Re-deoiling rate test chart

Examples	Fouling rate,% of	Oil removal rate%
			Example 1	55	91.3
Example 2	61	83.2
			Example 3	63	78.2
Example 4	77	64.3
			Example 5	89	47.9
Example 6	73	70.2
			Example 7	86	47.6
Example 8	86	47.5
			Example 9	79	62.6
Example 10	82	53.1
			Example 11	69	75.9
Example 12	70	74.1
			Commercial detergent	99	25.3

And 7, testing: the detergency performance test is carried out by referring to the requirements of standard GB 9985.

TABLE 3 detergency performance test

The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims

1. The environment-friendly pollution-free multifunctional hand-injury-free cleaning agent is characterized in that the cleaning agent is prepared from the following raw materials:

the nano coral calcium powder is pectin modified coral calcium powder; the weight ratio of the pectin to the nano coral calcium powder is 1: 2;

the surfactant is a nonionic surfactant and an ionic surfactant, and the weight ratio of the nonionic surfactant to the ionic surfactant is 1: 2;

the oxidant is inorganic peroxide;

the weight ratio of the natural sea salt, the natural sea alkali, the surfactant, the gramineous sterol, the cycloartenol, the oxidant, the nano coral calcium powder and the sodium citrate is 1: 1: 0.5: 0.2: 0.2: 0.01: 1: 0.02;

the weight ratio of the stemona root extract to the phellodendron bark extract to the radish seed extract to the oriental wormwood extract is 1: 1: 1: 1;

the weight ratio of the honeysuckle extract to the Chinese honeylocust fruit extract to the fructus cnidii extract to the polygonum cuspidatum extract to the aloe extract is 2: 1: 2: 2: 1;

and (D) component: an alkaloid;

the alkaloid is selected from one or more of pyridine, pyrrolidine, tropane and xanthine;

the component B and the component C are respectively coated by slow release film modified rhamnose;

2. the environmentally friendly, non-polluting, multi-functional, non-injurious hand cleanser of claim 1 wherein the alkaloid is selected from one or more of piperine, carvone, trigonelline, arecoline, tetrahydronicotinic acid, pilocarpine, laburnine, nicotine, sparteine, punicine, gulicine, erythroguline, atropine, cocaine, ecgonine, scopolamine, caffeine, theobromine, and theophylline.

3. The environment-friendly pollution-free multifunctional hand-injury-free cleaning agent as claimed in claim 1, wherein the preparation method of the honeysuckle extract comprises the following steps:

4. The environment-friendly pollution-free multifunctional hand-injury-free cleaning agent as claimed in claim 1, wherein the preparation method of the fructus cnidii extract comprises the following steps: