CN108863019A - Oil-base mud and oil patch resource utilization system and method - Google Patents
Oil-base mud and oil patch resource utilization system and method Download PDFInfo
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- CN108863019A CN108863019A CN201810664283.8A CN201810664283A CN108863019A CN 108863019 A CN108863019 A CN 108863019A CN 201810664283 A CN201810664283 A CN 201810664283A CN 108863019 A CN108863019 A CN 108863019A
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- oil
- thermal desorption
- base mud
- patch
- water
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- 238000000034 method Methods 0.000 title claims abstract description 51
- 238000003795 desorption Methods 0.000 claims abstract description 95
- 239000004568 cement Substances 0.000 claims abstract description 40
- 238000012545 processing Methods 0.000 claims abstract description 29
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 230000002195 synergetic effect Effects 0.000 claims abstract description 17
- 238000005496 tempering Methods 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims description 104
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- 238000007599 discharging Methods 0.000 claims description 37
- 239000007789 gas Substances 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 22
- 239000010802 sludge Substances 0.000 claims description 18
- 239000002283 diesel fuel Substances 0.000 claims description 15
- 238000005553 drilling Methods 0.000 claims description 15
- 238000002485 combustion reaction Methods 0.000 claims description 13
- 239000006148 magnetic separator Substances 0.000 claims description 13
- 239000007921 spray Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 238000012546 transfer Methods 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 238000004458 analytical method Methods 0.000 claims description 6
- 239000010426 asphalt Substances 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000011435 rock Substances 0.000 claims description 6
- 238000005070 sampling Methods 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 5
- 238000004064 recycling Methods 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 150000007516 brønsted-lowry acids Chemical class 0.000 claims description 3
- 150000007528 brønsted-lowry bases Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000921 elemental analysis Methods 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000003345 natural gas Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 238000007790 scraping Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 230000001629 suppression Effects 0.000 claims description 3
- 235000019504 cigarettes Nutrition 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 235000019198 oils Nutrition 0.000 description 72
- 239000000047 product Substances 0.000 description 21
- 239000003209 petroleum derivative Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 235000019476 oil-water mixture Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/18—Treatment of sludge; Devices therefor by thermal conditioning
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/001—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals for sludges or waste products from water treatment installations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1033—Oil well production fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Treatment Of Sludge (AREA)
Abstract
The invention discloses a kind of oil-base mud and oil patch resource utilization system and methods, it includes mixing tempering system, thermal desorption system and cement kiln synergic processing system, mixing tempering system, thermal desorption system and cement kiln synergic processing system are utilized simultaneously, successively oil patch resource is recycled and handled, changing rejected material to useful resource is recycled, it economizes on resources, reduces environmental pollution.
Description
Technical field
The present invention relates to resource and environment technical field, especially oil-base mud and oil patch resource utilization system and
Method.
Background technique
After well drilling detritus refers to that subsurface rock is crushed by drill bit in Process of Oil Well Drilling, it is brought on ground with drilling fluid
Rock fragment, using in oil-base mud drilling process, drilling well oil-base mud takes a large amount of oil patch, oil gas field out of out of well
The discarded oil-base mud and oil patch generated in drilling process is to mainly contain the heavy metal ion such as petroleum hydrocarbon and barium, lead, zinc
And its hazardous waste of compound, harmfulness is larger, if not being subject to purified treatment, it will very to generations such as soil, water resources
Big pollution.With the development of society, sound and environmental consciousness the raising of legal system, to the discarded oil base generated in drilling process
Mud and oil patch progress are innoxious, resource utilization is extremely urgent.For discarded oil-base mud and oil patch, state at present
The mode for inside mostly using small-sized rotary kiln incineration disposition then to fill, the disposal facility small investment, construction are fast.But due to abandoned oil
Base mud and oil patch are not inconsistent the kiln standard that is incorporated into, and burn kiln temperature usually at 600 DEG C or so, cannot will not only have in this way
Machine object thoroughly destroys by fire, and be easy to cause kiln inner product skin, and disposal efficiency and disposition effect are all extremely low, not thorough due to burning
Bottom generates in flue gas and contains large amount of organic, and vent gas treatment is not easy up to standard;Simultaneously because in discarded oil-base mud and oil patch
Also possess many calorific values, burning can waste energy directly in cement kiln;The residue generated is burned through detecting petroleum hydrocarbon content
Generally all 3% or more, new standard of landfill requirement cannot be reached, if do not fill after further treatment and directly will cause it is new
Secondary pollution.
Summary of the invention
The purpose of the present invention is to overcome the shortcomings of the existing technology, provides a kind of oil-base mud and oil patch recycling benefit
With system and method, using mixing tempering system, thermal desorption system and cement kiln synergic processing system, to oil patch resource into
Row recycling and processing, changing rejected material to useful resource is recycled, is economized on resources, is reduced environmental pollution.
The purpose of the present invention is achieved through the following technical solutions:Oil-base mud and oil patch resource utilization system,
It includes mixing tempering system, thermal desorption system and cement kiln synergic processing system;
The mixing tempering system includes storage tank, blender, vibrating screen, magnetic separator, dewaterer, temporary storing bin and discharging machine, institute
Storage tank, blender, vibrating screen, magnetic separator, dewaterer, temporary storing bin and discharging machine is stated to be sequentially connected;
The thermal desorption system includes greasy filth pond, thermal desorption furnace, parsing gas condenser, oil water separator, diesel oil tank, cesspool
And residue pool, the discharging product of the mixing tempering system discharging machine are put into greasy filth pond, the greasy filth pond passes through feeding device
It is connect with thermal desorption room, the thermal desorption furnace includes thermal desorption chamber and combustion chamber, and the thermal desorption room is connected by pipeline and parsed
Gas condenser, the thermal desorption room are connect with residue pool again, the parsing gas condenser by pipeline respectively with oil water separator,
The connection of alkaline process spray column, the oil water separator are connect with cesspool, diesel oil tank respectively again by pipeline, and the cesspool is logical
Piping connects greasy filth pond, and the alkaline process spray column is connect by pipeline with combustion chamber;
The cement kiln synergic processing system includes storage silo, screw discharging machine, hydraulic sludge pump and dry method clinker production cement
The thermal desorption product of kiln, the thermal desorption system production is admitted to storage silo, and the storage silo is connected with a broken arch balladeur train, described
Broken arch balladeur train is connected with screw discharging machine, and the screw discharging machine is connected with hydraulic sludge pump, the hydraulic sludge pump and dry method
Clinker produces cement kiln and is connected.
It preferably, further include rainwater collection pool in the thermal desorption system, the rainwater collection pool is de- by pipeline and heat
Attached chamber is connected, and a water injecting pump is provided on the pipeline.
Preferably, the thermal desorption room is connect by a chain transfer hopper with residue pool.
Preferably, screw(-type) feeder is provided between the screw discharging machine and hydraulic sludge pump.
A kind of utilization method based on oil-base mud and oil patch resource utilization system, the method mainly include with
Lower step:S1, first to oil-base mud and oil patch sampling analysis, predominantly detect the heat of oil-base mud and oil patch sample
Value, pH value, moisture, ash content, elemental analysis and viscosity;
S2, basis are to oil-base mud and oil patch sampling analysis as a result, pretreating scheme is formulated, by oil-base mud and containing oil rock
Bits and the unclassified stores in the pretreating scheme of formulation carry out mixing quenched mixing in tempering system, the unclassified stores includes
Emulsion, organic solvent, bronsted lowry acids and bases bronsted lowry, for changing calorific value, pH value, moisture, the ash content, member of oil-base mud and oil patch sample
Plain ingredient and viscosity, until oil-base mud and oil patch meet cement kiln and enter kiln index;
S3, the discharging product formed in S2 through hybrid modulation treatment process is put into thermal desorption system, and carries out thermal desorption processing,
Calorific value is reduced, the additional diesel oil generated of thermal desorption processing send shale gas drilling platforms to be recycled, for configuring oil base drilling fluid;
S4, the thermal desorption product formed in S3 through thermal desorption treatment process feeding cement kiln synergic processing system is carried out at collaboration
It sets.
Preferably, the quenched process of mixing in the S2 mainly includes sending oil-base mud, oil patch and unclassified stores
Enter blender, after blender stirs, sieved using vibrating screen, the mixture after screening enters magnetic separator together, will be oily
Separating in base mud and oil patch containing magnetic metal impurity, oil-base mud and oil patch reach cement kiln and enter kiln index
Afterwards, it by dewaterer dehydration, enters back into after temporary storing bin is kept in and forms discharging product by discharging machine.
Preferably, described to be cleaned containing magnetic metal impurity with asphalt felt by what magnetic separator was isolated, after the use
Asphalt felt recycling be used for thermal desorption treatment process.
Preferably, the thermal desorption processing in the S3 mainly includes the following steps that:S31, by S2 treated discharging produce
Product are sent into the thermal desorption chamber in thermal desorption furnace by feeder equipment;
S32, oil-base mud and oil patch are intracavitary in thermal desorption, are heated indirectly under anaerobic condition, and temperature is gradually increasing, and is added
After hot 5h, temperature rises to 120 DEG C, and the vapor in oil-base mud and oil patch is evaporated;
S33, in the intracavitary oil-base mud of thermal desorption and oil patch under anaerobic condition continuous heating, heat 16h after, temperature
360 DEG C are risen to, the oils in oil-base mud and oil patch is evaporated;
S34, the water being successively evaporated and oil are drawn into parsing gas condenser, are cooled down indirectly using water, and then water and oil are logical
Oil water separator is crossed, the oil isolated is sent to diesel oil tank by pipeline and stored, and isolated water is back to greasy filth by cesspool
Discharging product mix in pond and S2, fixed gas is by HCL, the water in alkaline process spray column removal fixed gas after condenser system
Solidifying lower vapor, then it is delivered to combustion chamber processing;
S35, after the oils in oil-base mud and oil patch evaporates, temperature can from 260 DEG C fall after rise to 310 DEG C, then
The indoor combustion of natural gas of burning is closed, when the indoor oil-base mud of thermal desorption and oil patch naturally cool to 180 DEG C, rain
Water in water collecting pit spray water dust suppression cooling 15min by water injecting pump into thermal desorption room;
S36, when the indoor oil-base mud of thermal desorption and oil patch temperature are lower than 100 DEG C, thermal desorption room is opened, using scraping blade
Residue is scraped into chain transfer hopper, residue is delivered in residue pool by chain transfer hopper;
S37, thermal desorption product is carried out dehydrating and formed to residue in residue pool, and the diesel oil that thermal desorption goes out send shale pneumatic drill
Well platform loop uses configuration oil base drilling fluid.
Preferably, the cement kiln synergic processing in the S4, mainly includes the following steps:
S41, the thermal desorption product for needing to carry out cement kiln synergic processing are first placed into storage silo and temporarily put;
Product in S42, storage silo is admitted to screw discharging machine by the broken arch balladeur train of storage silo lower part, using screw feeder
Machine is sent to hydraulic sludge pump, and then under the action of sludge pump, product is admitted to the tail kiln cigarette of dry method clinker production cement kiln
Room is finally fed in the rotary kiln of cement kiln and burns together with cement slurry.
Preferably, the ignition temperature of the cement kiln is 1500 DEG C ~ 1700 DEG C.
The present invention has the following advantages that:(1)A kind of oil-base mud provided by the invention and oil patch resource utilization system
System and method return oil patch resource using mixing tempering system, thermal desorption system and cement kiln synergic processing system
It receives and handles, changing rejected material to useful resource is recycled, is economized on resources, environmental pollution is reduced;(2)The present invention is used to after quenched
Oil-base mud and oil patch carry out thermal desorption processing, can recycle the diesel oil that desorption generates, while reducing calorific value, this
Sample avoids wasting extra energy;(3)After mixing quenched, thermal desorption processing, so that oil-base mud and oil patch exist
The disposal efficiency and disposition effect of cement kiln improve, and burning is more thorough, and vent gas treatment is more easily up to standard.
Detailed description of the invention
Fig. 1 is mixing tempering system schematic diagram of the invention;
Fig. 2 is the thermal desorption system schematic diagram in the method for the present invention;
Fig. 3 is the cement kiln synergic processing schematic diagram in the method for the present invention.
Specific embodiment
The present invention will be further described with reference to the accompanying drawing, but protection scope of the present invention is not limited to following institute
It states.
As shown in Figure 1, Figure 2 and Figure 3, oil-base mud and oil patch resource utilization system, it includes mixing quenched system
System, thermal desorption system and cement kiln synergic processing system;
The mixing tempering system includes storage tank, blender, vibrating screen, magnetic separator, dewaterer, temporary storing bin and discharging machine, institute
Storage tank, blender, vibrating screen, magnetic separator, dewaterer, temporary storing bin and discharging machine is stated to be sequentially connected;
The thermal desorption system includes greasy filth pond, thermal desorption furnace, parsing gas condenser, oil water separator, diesel oil tank, cesspool
And residue pool, the discharging product of the mixing tempering system discharging machine are put into greasy filth pond, the greasy filth pond passes through feeding device
It is connect with thermal desorption room, the thermal desorption furnace includes thermal desorption chamber and combustion chamber, and the thermal desorption room is connected by pipeline and parsed
Gas condenser, the thermal desorption room are connect with residue pool again, the parsing gas condenser by pipeline respectively with oil water separator,
The connection of alkaline process spray column, the oil water separator are connect with cesspool, diesel oil tank respectively again by pipeline, and the cesspool is logical
Piping connects greasy filth pond, and the alkaline process spray column is connect by pipeline with combustion chamber;
The cement kiln synergic processing system includes storage silo, screw discharging machine, hydraulic sludge pump and dry method clinker production cement
The thermal desorption product of kiln, the thermal desorption system production is admitted to storage silo, and the storage silo is connected with a broken arch balladeur train, described
Broken arch balladeur train is connected with screw discharging machine, and the screw discharging machine is connected with hydraulic sludge pump, the hydraulic sludge pump and dry method
Clinker produces cement kiln and is connected.
It preferably, further include rainwater collection pool in the thermal desorption system, the rainwater collection pool is de- by pipeline and heat
Attached chamber is connected, and a water injecting pump is provided on the pipeline.
Preferably, the thermal desorption room is connect by a chain transfer hopper with residue pool.
Preferably, screw(-type) feeder is provided between the screw discharging machine and hydraulic sludge pump.
A kind of utilization method method based on oil-base mud and oil patch resource utilization system, the method are mainly wrapped
Include following steps:
S1, first to oil-base mud and oil patch sampling analysis, predominantly detect oil-base mud and oil patch sample calorific value,
PH value, moisture, ash content, elemental analysis and viscosity.
S2, basis are to oil-base mud and oil patch sampling analysis as a result, formulation pretreating scheme, by oil-base mud and contains
Oil rock bits are put into the unclassified stores in the pretreating scheme of formulation and mix tempering system, its in the pretreating scheme of formulation
His material includes emulsion, organic solvent, bronsted lowry acids and bases bronsted lowry, and oil-base mud, oil patch and unclassified stores pass through different feeding ports
It is sent into blender, unclassified stores initially enters storage tank by the first feeding port and enter back into blender, then oil-cut mud and contains
Oil rock bits are close to enter blender from the second feeding port, and cement kiln is reached after blender stirs and enters kiln index(Such as table 1)Afterwards,
It is sieved using vibrating screen, the fines after screening is sent into magnetic separator further through conveyer, by magnetic separator by magnetic contained in material
Property metal impurities separate, the magnetic metal impurity separated can be taken out after being cleaned with asphalt felt, asphalt felt recycling can
To be handled for thermal desorption, by the oil-base mud filtered out and oil patch of magnetic separator by dewaterer dehydration, temporary storing bin
It is temporary, then discharge to form product by discharging machine, the water deviate from dewaterer can be back in storage tank and mix with unclassified stores.
S3, it will be first placed into greasy filth pond through the processed oil-base mud of hybrid modulation and oil patch product in S2, passed through
Feeding device is admitted to the thermal desorption chamber in thermal desorption furnace, and thermal desorption chamber has gas lock, intracavitary to escape substantially without gas, oil base mud
Slurry and oil patch product are intracavitary in thermal desorption, are heated indirectly under anaerobic condition, and temperature is gradually increasing, and after heating 5h, heat is de-
Attached indoor temperature rises to 120 DEG C, and the vapor in oil-base mud and oil patch is evaporated at this time;Continuous heating is about again
After 16h, temperature rises to 360 DEG C, and the oils in oil-base mud and oil patch is evaporated at this time;It evaporates in oils
Afterwards, temperature can be fallen after rise from 360 DEG C to 310 DEG C, be then shut off the combustion of natural gas of combustion chamber, the indoor slag natural cooling of thermal desorption
When to 180 DEG C, the water in rainwater collection pool is cooled down about 15min by water injecting pump dust suppression of spray water into thermal desorption room at this time, is sprayed water
Amount control does not play fugitive dust when residue is come out of the stove without waste water water clock yet, and the moisture content for the residue that discharges is 15%.When residue temperature is lower than
At 100 DEG C, thermal desorption room is opened, is scraped residue into chain transfer hopper using scraping blade, residue is delivered to residual by chain transfer hopper
Storage in slag bath, residue moisture content about 15% are in mud cake shape, are packed into transfer hopper, and transfer hopper is conveyed residue using chain mode
To residue pool.Successively desorption forms resolution gas out from greasy filth for water and petroleum hydrocarbon(Petroleum hydrocarbon+vapor)It is drawn into resolution gas
In condenser system, cooled down indirectly using water.The liquid oil water mixture to cool down(Oil quality accounting about 80%, water accounting is about
20%)Enter oil water separator by pipeline, the oil of separation is stored using pipeline to the diesel oil tank of visualization laying;Point
From water enter cesspool, enter back into greasy filth pond, after being mixed with oil base landwaste, into thermal desorption room in handled again.Through
Cross the fixed gas after condenser system in pipeline(Predominantly C4 petroleum hydrocarbon below, based on methane)It is removed by alkaline process spray column
HCL, the lower vapor of condensation etc. in fixed gas, then it is delivered to combustion chambers burn processing.At oil-base mud and oil patch thermal desorption
The residue obtained after reason forms thermal desorption product by dehydration, and the diesel oil generated is added in thermal desorption treatment process and is sent
Configuration oil base drilling fluid is recycled to shale gas drilling platforms.
The thermal desorption product that S4, oil-base mud and oil patch are formed after thermal desorption is handled, is stored in storage first
In storage, storage warehouse lower part is equipped with broken arch balladeur train, and thermal desorption product enters screw discharging machine by balladeur train, using screw feeder
Machine is sent to hydraulic sludge pump, then under the action of hydraulic sludge pump, by product by being sent to existing 2500t/d new dry process
Clinker production line kiln tail is calcined together with cement slurry out of kiln tail smoke-box feeding rotary kiln, and the temperature of cement kiln is
1600 DEG C, thermal capacity and thermal inertia are big, and product is calcined in high-temperature region, and harmful components can be decomposed thoroughly, it is ensured that Environmental security.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art
For, under the premise of different disengaging the invention design, various modifications and improvements can be made, these belong to this hair
Bright protection scope.
Claims (10)
1. oil-base mud and oil patch resource utilization system, it is characterised in that:It includes mixing tempering system, thermal desorption system
System and cement kiln synergic processing system;
The mixing tempering system includes storage tank, blender, vibrating screen, magnetic separator, dewaterer, temporary storing bin and discharging machine, institute
Storage tank, blender, vibrating screen, magnetic separator, dewaterer, temporary storing bin and discharging machine is stated to be sequentially connected;
The thermal desorption system includes greasy filth pond, thermal desorption furnace, parsing gas condenser, oil water separator, diesel oil tank, cesspool
And residue pool, the discharging product of the mixing tempering system discharging machine are put into greasy filth pond, the greasy filth pond passes through feeding device
It is connect with thermal desorption room, the thermal desorption furnace includes thermal desorption chamber and combustion chamber, and the thermal desorption room is connected by pipeline and parsed
Gas condenser, the thermal desorption room are connect with residue pool again, the parsing gas condenser by pipeline respectively with oil water separator,
The connection of alkaline process spray column, the oil water separator are connect with cesspool, diesel oil tank respectively again by pipeline, and the cesspool is logical
Piping connects greasy filth pond, and the alkaline process spray column is connect by pipeline with combustion chamber;
The cement kiln synergic processing system includes storage silo, screw discharging machine, hydraulic sludge pump and dry method clinker production cement
The thermal desorption product of kiln, the thermal desorption system production is admitted to storage silo, and the storage silo is connected with a broken arch balladeur train, described
Broken arch balladeur train is connected with screw discharging machine, and the screw discharging machine is connected with hydraulic sludge pump, the hydraulic sludge pump and dry method
Clinker produces cement kiln and is connected.
2. oil-base mud according to claim 1 and oil patch resource utilization system, it is characterised in that:The heat is de-
It further include rainwater collection pool in attached system, the rainwater collection pool is connected by pipeline with thermal desorption chamber, is arranged on the pipeline
There is a water injecting pump.
3. oil-base mud according to claim 1 and oil patch resource utilization system, it is characterised in that:The heat is de-
Alcove is connect by a chain transfer hopper with residue pool.
4. oil-base mud according to claim 1 and oil patch resource utilization system, it is characterised in that:The spiral
Screw(-type) feeder is provided between unloader and hydraulic sludge pump.
5. a kind of utilization method based on oil-base mud described in claim 1 and oil patch resource utilization system, special
Sign is:The method mainly includes the following steps that:S1, first to oil-base mud and oil patch sampling analysis, predominantly detect
The calorific value of oil-base mud and oil patch sample, pH value, moisture, ash content, elemental analysis and viscosity;
S2, basis are to oil-base mud and oil patch sampling analysis as a result, pretreating scheme is formulated, by oil-base mud and containing oil rock
Bits and the unclassified stores in the pretreating scheme of formulation carry out mixing quenched mixing in tempering system, the unclassified stores includes
Emulsion, organic solvent, bronsted lowry acids and bases bronsted lowry, for changing calorific value, pH value, moisture, the ash content, member of oil-base mud and oil patch sample
Plain ingredient and viscosity, until oil-base mud and oil patch meet cement kiln and enter kiln index;
S3, the discharging product formed in S2 through hybrid modulation treatment process is put into thermal desorption system, and carries out thermal desorption processing,
Calorific value is reduced, the additional diesel oil generated of thermal desorption processing send shale gas drilling platforms to be recycled, for configuring oil base drilling fluid;
S4, the thermal desorption product formed in S3 through thermal desorption treatment process feeding cement kiln synergic processing system is carried out at collaboration
It sets.
6. according to claim 5 utilize method, it is characterised in that:The quenched process of mixing in the S2 mainly include by
Oil-base mud, oil patch and unclassified stores are sent into blender and are sieved after blender stirs using vibrating screen, sieve
Mixture afterwards enters magnetic separator together, by separating in oil-base mud and oil patch containing magnetic metal impurity, oil-base mud
And oil patch reaches after cement kiln enters kiln index, by dewaterer dehydration, enter back into temporary storing bin it is temporary after by discharging
Machine forms discharging product.
7. according to claim 6 utilize method, it is characterised in that:It is described to contain magnetic metal by what magnetic separator was isolated
Impurity is cleaned with asphalt felt, and the used asphalt felt recycling is used for thermal desorption treatment process.
8. according to claim 5 utilize method, it is characterised in that:Thermal desorption processing in the S3 mainly includes following
Step:S31, by S2 treated discharging product by feeder equipment feeding thermal desorption furnace in thermal desorption chamber;
S32, oil-base mud and oil patch are intracavitary in thermal desorption, are heated indirectly under anaerobic condition, and temperature is gradually increasing, and is added
After hot 5h, temperature rises to 120 DEG C, and the vapor in oil-base mud and oil patch is evaporated;
S33, in the intracavitary oil-base mud of thermal desorption and oil patch under anaerobic condition continuous heating, heat 16h after, temperature
360 DEG C are risen to, the oils in oil-base mud and oil patch is evaporated;
S34, the water being successively evaporated and oil are drawn into parsing gas condenser, are cooled down indirectly using water, and then water and oil are logical
Oil water separator is crossed, the oil isolated is sent to diesel oil tank by pipeline and stored, and isolated water is back to greasy filth by cesspool
Discharging product mix in pond and S2, fixed gas is by HCL, the water in alkaline process spray column removal fixed gas after condenser system
Solidifying lower vapor, then it is delivered to combustion chamber processing;
S35, after the oils in oil-base mud and oil patch evaporates, temperature can from 260 DEG C fall after rise to 310 DEG C, then
The indoor combustion of natural gas of burning is closed, when the indoor oil-base mud of thermal desorption and oil patch naturally cool to 180 DEG C, rain
Water in water collecting pit spray water dust suppression cooling 15min by water injecting pump into thermal desorption room;
S36, when the indoor oil-base mud of thermal desorption and oil patch temperature are lower than 100 DEG C, thermal desorption room is opened, using scraping blade
Residue is scraped into chain transfer hopper, residue is delivered in residue pool by chain transfer hopper;
S37, thermal desorption product is carried out dehydrating and formed to residue in residue pool, and the diesel oil that thermal desorption goes out send shale pneumatic drill
Well platform loop uses configuration oil base drilling fluid.
9. according to claim 5 utilize method, it is characterised in that:Cement kiln synergic processing in the S4, it is main to wrap
Include following step:
S41, the thermal desorption product for needing to carry out cement kiln synergic processing are first placed into storage silo and temporarily put;
Product in S42, storage silo is admitted to screw discharging machine by the broken arch balladeur train of storage silo lower part, using screw feeder
Machine is sent to hydraulic sludge pump, and then under the action of sludge pump, product is admitted to the tail kiln cigarette of dry method clinker production cement kiln
Room is finally fed in the rotary kiln of cement kiln and burns together with cement slurry.
10. according to claim 5 utilize method, it is characterised in that:The ignition temperature of the cement kiln is 1600 DEG C.
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Effective date of registration: 20191111 Address after: 100000 Beijing, Chaoyangmen, North Street, No. 22, No. Applicant after: CHINA PETROLEUM & CHEMICAL Corp. Applicant after: SINOPEC EAST CHINA OIL & GAS COMPANY Address before: 400060 5 coral 11-4, coral road, Nan'an District, Chongqing, 11-4 Applicant before: Wang Yuhai |
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