CN108859561A - A kind of metal embedding craft and preparation method thereof - Google Patents

A kind of metal embedding craft and preparation method thereof Download PDF

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Publication number
CN108859561A
CN108859561A CN201810831546.XA CN201810831546A CN108859561A CN 108859561 A CN108859561 A CN 108859561A CN 201810831546 A CN201810831546 A CN 201810831546A CN 108859561 A CN108859561 A CN 108859561A
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CN
China
Prior art keywords
metal
decoration groove
parts
decoration
groove
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810831546.XA
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Chinese (zh)
Inventor
罗列诗
尹晶
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Honghe University
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Honghe University
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Filing date
Publication date
Application filed by Honghe University filed Critical Honghe University
Priority to CN201810831546.XA priority Critical patent/CN108859561A/en
Publication of CN108859561A publication Critical patent/CN108859561A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/26Inlaying with ornamental structures, e.g. niello work, tarsia work
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02Electroplating of selected surface areas
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated

Abstract

The present invention relates to damascene techniques fields, more particularly to a kind of metal embedding craft, including metallic matrix and metal insert, the metallic matrix outer surface offers decoration groove, it is equipped with the metal insert inside the decoration groove, is equipped with shaping workpiece above the decoration groove;Its production method includes the following steps:Any moulding is first made and surface has the metallic matrix of decoration groove;Outer surface and the inner surface on metallic matrix in addition to decoration groove are shielded with insulating materials;Metal surface activation agent is filled inside to decoration groove, then produces the shaping workpiece to match with decoration groove;By electro-deposition techniques by the metal ion orientated deposition of metal insert to decoration groove surface;Shaping workpiece is removed, and wrong mill is carried out to the part exceeded;The present invention solves the problems, such as the various dirts that cannot be removed effectively decoration groove inner surface;Also the problem of solving and retain bubble inside deposition layer, influencing metal embedding craft quality.

Description

A kind of metal embedding craft and preparation method thereof
Technical field
The present invention relates to damascene techniques fields, and in particular to a kind of metal embedding craft and preparation method thereof.
Background technique
With damascene techniques craft articles, there is long history in China.It is the most typically exactly the embedding silver of tradition Technique.The embedding silver of tradition includes:Design rough sketch, by hand cross original text, flatten filamentary silver, by hand inlay, picture modification etc. processes.Briefly It says, exactly flattens thin filamentary silver, be embedded on wood materials by hand, produce the various pictures of filamentary silver composition.In order to eliminate metal Gap between matrix and insertion metal compounds interface makes metallic matrix in conjunction with insertion metal in close, and people attempt with various Bonding agent goes to tamp gap, but all bonding agents can all influence over time metallic matrix and insertion gold with time aging The bond quality of category, therefore be mostly used electro-deposition techniques now and metal is embedded in craftwork.
But still there are many problems for existing electro-deposition techniques, firstly, cannot be removed effectively decoration groove inner surface Various dirts, the metal after leading to electro-deposition easily fall off phenomenon;Secondly, decoration groove inner surface is rough, cause electricity heavy Bubble is retained inside lamination, influences the quality of metal embedding craft.
Summary of the invention
The technical issues of solution
For disadvantages mentioned above present in the prior art, the present invention provides a kind of metal embedding craft and its production sides Method, the various dirts for solving decoration groove inner surface cannot be removed effectively, and what the metal after leading to electro-deposition was fallen off asks Topic;Also it is rough to solve decoration groove inner surface, causes to retain bubble inside deposition layer, influences metal embedding craft product The problem of matter.
Technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of metal embedding craft, including metallic matrix and metal insert, the metallic matrix outer surface offer Decoration groove, the decoration groove inside are equipped with the metal insert, are equipped with shaping workpiece above the decoration groove.
Further, the depth and width of the decoration groove can arbitrarily be set.
Further, the metal material of the metal insert be can with electro-deposition method carry out wet process smelt it is any Metal and alloy.
Further, production method includes the following steps:
A, casting is first passed through, machining, etching, the method for carving processing is carved any moulding and surface is made with decoration groove Metallic matrix;
B, outer surface and the inner surface on metallic matrix in addition to decoration groove are shielded with insulating materials;
C, to filling metal surface activation agent inside decoration groove, decoration groove is cleaned after handling a period of time, Then the shaping workpiece to match with decoration groove is produced;
D, shaping workpiece is installed on above decoration groove, is determined the metal ion of metal insert by electro-deposition techniques To decoration groove surface is deposited to, make decoration groove with the joint face of metal insert in conjunction with lattice and in a manner of mechanical bond It combines together;
E, until metal insert is completely filled with decoration groove or deposition layer has been higher than decoration groove, work will be formed Part is removed, and carries out wrong mill to the part exceeded and metal embedding craft can be obtained.
Further, metal surface activation agent is made of following raw material in the step c:Absolute alcohol 5~7 It is part, 6~9 parts of hydrochloric acid, 5~8 parts of citric acid, 10~14 parts of fatty alcohol polyoxyethylene ether, 7~10 parts of sodium stearyl sulfate, hard 10~12 parts of resin acid sodium, 1~3 part of amino acid dehydrogenase, 2~4 parts of gelatin and 45~50 parts of deionized water.
Further, the processing time that metal surface activation agent is filled in the step c is 20~30min.
Beneficial effect
Using technical solution provided by the invention, compared with known publicly-owned technology, have as follows
Beneficial effect:
1, in the present invention, metal surface activation agent, metal surface activation are filled inside the forward direction decoration groove of electro-deposition Agent, which can effectively permeate, to be dispersed to inside decoration groove, and effectively removes the various dirts of decoration groove inner surface, treated line It is smooth to adorn grooved inner surface, is also advantageous for electro-deposition techniques for the metal ion orientated deposition of metal insert to decoration groove table Face will not retain bubble inside deposition layer, be conducive to the quality for improving craftwork.
2, in the present invention, shaping workpiece is installed on above decoration groove, can prevent deposition layer from overflowing decoration groove pollution Metal base surface.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below Needed for having in technical description;Attached drawing to be used is briefly described.It should be evident that the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
Fig. 1 is the structural schematic diagram of metal embedding craft of the present invention.
Label in figure respectively represents:1- metallic matrix;2- metal insert;3- decoration groove;4- shaping workpiece.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described.Obviously, described embodiment is A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art Every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
The present invention will be further described with reference to the examples below.
As shown in Figure 1, a kind of metal embedding craft and preparation method thereof of the present embodiment, including metallic matrix 1 and gold Belong to insert 2,1 outer surface of metallic matrix offers decoration groove 3, is equipped with metal insert 2, decorative pattern ditch inside decoration groove 3 Shaping workpiece 4 is equipped with above slot 3;The depth and width of decoration groove 3 can arbitrarily be set;The metal material of metal insert 2 It is that can carry out any metal and alloy that wet process smelts with electro-deposition method.
Embodiment 1:
A kind of metal embedding craft, production method include the following steps:
A, casting is first passed through, machining, etching, the method for carving processing is carved any moulding and surface is made with decoration groove 3 metallic matrix 1;
B, outer surface and the inner surface on metallic matrix 1 in addition to decoration groove 3 are shielded with insulating materials;
C, to filling metal surface activation agent inside decoration groove 3, decoration groove 3 is carried out clearly after handling a period of time It washes, then produces the shaping workpiece 4 to match with decoration groove 3;
D, shaping workpiece 4 is installed on the top of decoration groove 3, by electro-deposition techniques by the metal of metal insert 2 from Sub- orientated deposition to 3 surface of decoration groove, make decoration groove 3 and the joint face of metal insert 2 with lattice in conjunction with and mechanical tie The mode of conjunction combines together;
E, it until metal insert 2 is completely filled with decoration groove 3 or deposition layer has been higher than decoration groove 3, will form Workpiece 4 is removed, and carries out wrong mill to the part exceeded and 1 metal embedding craft of embodiment can be obtained.
Metal surface activation agent is made of following raw material in the step c:5 parts of absolute alcohol, 6 parts of hydrochloric acid, lemon It is 5 parts of acid, 104 parts of fatty alcohol polyoxyethylene ether, 8 parts of sodium stearyl sulfate, 10 parts of odium stearate, 1 part of amino acid dehydrogenase, bright 2 parts and 45 parts of deionized water of glue.
Embodiment 2:
A kind of metal embedding craft, production method include the following steps:
A, casting is first passed through, machining, etching, the method for carving processing is carved any moulding and surface is made with decoration groove 3 metallic matrix 1;
B, outer surface and the inner surface on metallic matrix 1 in addition to decoration groove 3 are shielded with insulating materials;
C, to filling metal surface activation agent inside decoration groove 3, decoration groove 3 is carried out clearly after handling a period of time It washes, then produces the shaping workpiece 4 to match with decoration groove 3;
D, shaping workpiece 4 is installed on the top of decoration groove 3, by electro-deposition techniques by the metal of metal insert 2 from Sub- orientated deposition to 3 surface of decoration groove, make decoration groove 3 and the joint face of metal insert 2 with lattice in conjunction with and mechanical tie The mode of conjunction combines together;
E, it until metal insert 2 is completely filled with decoration groove 3 or deposition layer has been higher than decoration groove 3, will form Workpiece 4 is removed, and carries out wrong mill to the part exceeded and 2 metal embedding craft of embodiment can be obtained.
Metal surface activation agent is made of following raw material in the step c:6 parts of absolute alcohol, 6 parts of hydrochloric acid, lemon It is 7 parts of acid, 11 parts of fatty alcohol polyoxyethylene ether, 8 parts of sodium stearyl sulfate, 11 parts of odium stearate, 2 parts of amino acid dehydrogenase, bright 2 parts and 46 parts of deionized water of glue.
Embodiment 3:
A kind of metal embedding craft, production method include the following steps:
A, casting is first passed through, machining, etching, the method for carving processing is carved any moulding and surface is made with decoration groove 3 metallic matrix 1;
B, outer surface and the inner surface on metallic matrix 1 in addition to decoration groove 3 are shielded with insulating materials;
C, to filling metal surface activation agent inside decoration groove 3, decoration groove 3 is carried out clearly after handling a period of time It washes, then produces the shaping workpiece 4 to match with decoration groove 3;
D, shaping workpiece 4 is installed on the top of decoration groove 3, by electro-deposition techniques by the metal of metal insert 2 from Sub- orientated deposition to 3 surface of decoration groove, make decoration groove 3 and the joint face of metal insert 2 with lattice in conjunction with and mechanical tie The mode of conjunction combines together;
E, it until metal insert 2 is completely filled with decoration groove 3 or deposition layer has been higher than decoration groove 3, will form Workpiece 4 is removed, and carries out wrong mill to the part exceeded and 3 metal embedding craft of embodiment can be obtained.
Metal surface activation agent is made of following raw material in the step c:6 parts of absolute alcohol, 8 parts of hydrochloric acid, lemon It is 7 parts of acid, 12 parts of fatty alcohol polyoxyethylene ether, 9 parts of sodium stearyl sulfate, 12 parts of odium stearate, 2 parts of amino acid dehydrogenase, bright 3 parts and 47 parts of deionized water of glue.
Embodiment 4:
A kind of metal embedding craft, production method include the following steps:
A, casting is first passed through, machining, etching, the method for carving processing is carved any moulding and surface is made with decoration groove 3 metallic matrix 1;
B, outer surface and the inner surface on metallic matrix 1 in addition to decoration groove 3 are shielded with insulating materials;
C, to filling metal surface activation agent inside decoration groove 3, decoration groove 3 is carried out clearly after handling a period of time It washes, then produces the shaping workpiece 4 to match with decoration groove 3;
D, shaping workpiece 4 is installed on the top of decoration groove 3, by electro-deposition techniques by the metal of metal insert 2 from Sub- orientated deposition to 3 surface of decoration groove, make decoration groove 3 and the joint face of metal insert 2 with lattice in conjunction with and mechanical tie The mode of conjunction combines together;
E, it until metal insert 2 is completely filled with decoration groove 3 or deposition layer has been higher than decoration groove 3, will form Workpiece 4 is removed, and carries out wrong mill to the part exceeded and 4 metal embedding craft of embodiment can be obtained.
Metal surface activation agent is made of following raw material in the step c:7 parts of absolute alcohol, 8 parts of hydrochloric acid, lemon It is 7 parts of acid, 13 parts of fatty alcohol polyoxyethylene ether, 9 parts of sodium stearyl sulfate, 11 parts of odium stearate, 3 parts of amino acid dehydrogenase, bright 4 parts and 47 parts of deionized water of glue.
Embodiment 5:
A kind of metal embedding craft, production method include the following steps:
A, casting is first passed through, machining, etching, the method for carving processing is carved any moulding and surface is made with decoration groove 3 metallic matrix 1;
B, outer surface and the inner surface on metallic matrix 1 in addition to decoration groove 3 are shielded with insulating materials;
C, to filling metal surface activation agent inside decoration groove 3, decoration groove 3 is carried out clearly after handling a period of time It washes, then produces the shaping workpiece 4 to match with decoration groove 3;
D, shaping workpiece 4 is installed on the top of decoration groove 3, by electro-deposition techniques by the metal of metal insert 2 from Sub- orientated deposition to 3 surface of decoration groove, make decoration groove 3 and the joint face of metal insert 2 with lattice in conjunction with and mechanical tie The mode of conjunction combines together;
E, it until metal insert 2 is completely filled with decoration groove 3 or deposition layer has been higher than decoration groove 3, will form Workpiece 4 is removed, and carries out wrong mill to the part exceeded and 5 metal embedding craft of embodiment can be obtained.
Metal surface activation agent is made of following raw material in the step c:7 parts of absolute alcohol, 9 parts of hydrochloric acid, lemon It is 8 parts of acid, 13 parts of fatty alcohol polyoxyethylene ether, 10 parts of sodium stearyl sulfate, 12 parts of odium stearate, 3 parts of amino acid dehydrogenase, bright 3 parts and 50 parts of deionized water of glue.
The metal embedding craft that Examples 1 to 5 produces is detected, obtain metal surface activation agent removes dirt Effect it is obvious, decoration groove inner surface is smooth, be beneficial to subsequent electro-deposition operation, not bubbles inside metal insert, Metal embedding craft it is best in quality.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments Invention is explained in detail, those skilled in the art should understand that:It still can be to aforementioned each implementation Technical solution documented by example is modified or equivalent replacement of some of the technical features;And these modification or Replacement, can't be such that the essence of corresponding technical solution departs from the spirit and scope of the technical scheme of various embodiments of the present invention.

Claims (6)

1. a kind of metal embedding craft, including metallic matrix and metal insert, which is characterized in that the metallic matrix appearance Face offers decoration groove, and the metal insert is equipped with inside the decoration groove, is equipped with molding above the decoration groove Workpiece.
2. a kind of metal embedding craft according to claim 1, which is characterized in that the depth and width of the decoration groove Degree can arbitrarily be set.
3. a kind of metal embedding craft according to claim 1, which is characterized in that the metal material of the metal insert Material is can to carry out any metal and alloy that wet process smelts with electro-deposition method.
4. a kind of metal embedding craft according to claim 1, which is characterized in that its production method includes following step Suddenly:
A, it first passes through casting, machining, etching, carve the gold that any moulding is made in the method for carving processing and surface has decoration groove Belong to matrix;
B, outer surface and the inner surface on metallic matrix in addition to decoration groove are shielded with insulating materials;
C, to filling metal surface activation agent inside decoration groove, decoration groove is cleaned after handling a period of time, then Produce the shaping workpiece to match with decoration groove;
D, shaping workpiece is installed on above decoration groove, the metal ion of metal insert is oriented by electro-deposition techniques and is sunk Product arrive decoration groove surface, melt decoration groove in conjunction with lattice and in a manner of mechanical bond with the joint face of metal insert for One;
E, until metal insert is completely filled with decoration groove or deposition layer has been higher than decoration groove, shaping workpiece is taken Under, and wrong mill is carried out to the part exceeded, metal embedding craft can be obtained.
5. a kind of production method of metal embedding craft according to claim 4, which is characterized in that in the step c Metal surface activation agent is made of following raw material:5~7 parts of absolute alcohol, 6~9 parts of hydrochloric acid, 5~8 parts of citric acid, fat 10~14 parts of alcohol polyoxyethylene ether, 7~10 parts of sodium stearyl sulfate, 10~12 parts of odium stearate, amino acid dehydrogenase 1~3 Part, 2~4 parts of gelatin and 45~50 parts of deionized water.
6. a kind of metal embedding craft according to claim 4 and preparation method thereof, which is characterized in that the step c The processing time of middle filling metal surface activation agent is 20~30min.
CN201810831546.XA 2018-07-26 2018-07-26 A kind of metal embedding craft and preparation method thereof Pending CN108859561A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810831546.XA CN108859561A (en) 2018-07-26 2018-07-26 A kind of metal embedding craft and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810831546.XA CN108859561A (en) 2018-07-26 2018-07-26 A kind of metal embedding craft and preparation method thereof

Publications (1)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101523522A (en) * 2005-11-09 2009-09-02 谢清雄 An electroplating method in the manufacture of the surface mount precision metal resistor
JP2011096705A (en) * 2009-10-27 2011-05-12 Fujitsu Ltd Method of manufacturing substrate, and substrate
CN103660754A (en) * 2012-09-03 2014-03-26 蒋荣昌 Metal embedding craft and making method thereof
CN104047040A (en) * 2014-06-23 2014-09-17 梧州恒声电子科技有限公司 Electroplating activating agent and preparation method thereof
CN106868515A (en) * 2017-01-23 2017-06-20 麻城天安化工股份有限公司 A kind of metal surface activation agent and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101523522A (en) * 2005-11-09 2009-09-02 谢清雄 An electroplating method in the manufacture of the surface mount precision metal resistor
JP2011096705A (en) * 2009-10-27 2011-05-12 Fujitsu Ltd Method of manufacturing substrate, and substrate
CN103660754A (en) * 2012-09-03 2014-03-26 蒋荣昌 Metal embedding craft and making method thereof
CN104047040A (en) * 2014-06-23 2014-09-17 梧州恒声电子科技有限公司 Electroplating activating agent and preparation method thereof
CN106868515A (en) * 2017-01-23 2017-06-20 麻城天安化工股份有限公司 A kind of metal surface activation agent and preparation method thereof

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Application publication date: 20181123

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