CN108855248A - Ion-exchange reactions and regenerating unit - Google Patents

Ion-exchange reactions and regenerating unit Download PDF

Info

Publication number
CN108855248A
CN108855248A CN201810671675.7A CN201810671675A CN108855248A CN 108855248 A CN108855248 A CN 108855248A CN 201810671675 A CN201810671675 A CN 201810671675A CN 108855248 A CN108855248 A CN 108855248A
Authority
CN
China
Prior art keywords
anion
cation
exchange resin
valve
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810671675.7A
Other languages
Chinese (zh)
Inventor
苏战华
苏仲民
吕峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LIAONING LAVENDER ENVIRONMENTAL ENGINEERING Co Ltd
Original Assignee
LIAONING LAVENDER ENVIRONMENTAL ENGINEERING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LIAONING LAVENDER ENVIRONMENTAL ENGINEERING Co Ltd filed Critical LIAONING LAVENDER ENVIRONMENTAL ENGINEERING Co Ltd
Priority to CN201810671675.7A priority Critical patent/CN108855248A/en
Publication of CN108855248A publication Critical patent/CN108855248A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00Ion-exchange processes in general; Apparatus therefor
    • B01J47/02Column or bed processes
    • B01J47/04Mixed-bed processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/05Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
    • B01J49/09Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds of mixed beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/60Cleaning or rinsing ion-exchange beds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/427Treatment of water, waste water, or sewage by ion-exchange using mixed beds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/04Non-contaminated water, e.g. for industrial water supply for obtaining ultra-pure water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The present invention relates to ion-exchange reactions and regenerating units, including:Shell, anion exchanger lower clapboard, glass sand, anion exchange resin, anion water collector, anion regeneration distributor, cation exchanger upper spacer, cation exchange resin water distributor, cation exchanger lower clapboard, cation exchange resin, cationic regenerative divider, it is discharged partition, double end water cap.Ion-exchange reactions and regenerating unit of the invention solves the problems, such as that the regeneration occurred when mixed ion exchanger acid-alkali regeneration is not thorough or destruction of the regenerated liquid to resin.By the redesign constructed to equipment, the influence after the mixing of acid-alkali regeneration liquid to resin can be avoided, regeneration level is high, and cleaning thoroughly, can be widely applied to the water treatment field with ion exchange.

Description

Ion-exchange reactions and regenerating unit
Technical field
The present invention relates to a kind of ion-exchange reactions and regenerating units.
Background technique
In boiler feedwater, in the pure water and ultrapure water apparatus applied in photovoltaic element and production of electronic components, ion is handed over Changing device is widely used.
Mixed bed ion-exchange method is exactly placed on anion and cation exchange resin in the same exchanger, before operation They are uniformly mixed, so can look at is to answer bed by the countless staggered multi-stags of yin, yang exchanger resin, institute's saliferous in water The anions and canons of class then by resins exchange, and obtain high pure water by this exchanger.In mixed bed, due to yin, yang Resin mutually mixes, so its anions and canons exchange reaction almost carries out simultaneously, in other words, the cation exchange of water and Anion exchange is repeatedly staggeredly to carry out, and exchanges generated H through H-type+Generated OH is exchanged with by OH type-All cannot Accumulate, substantially eliminate the influence of counter ion, exchange carry out ratio more thoroughly.Due to entering the primary pure water matter of mixed bed Preferably, the light load of exchanger, the exchange capacity of resin for a long time just exhaust by quilt.
Mixed bed uses internal method of reproduction, different first with the specific gravity of two kinds of resins when regeneration, with backwash right to use yin, Cation exchange resin is kept completely separate, and positive resin is deposited on down, and negative resin floats on above, and then positive resin is with hydrochloric acid (or sulfuric acid) Regeneration, negative resin are regenerated with sodium hydroxide.In hybrid resin regenerative process, the anion exchange resin and sun that will be mixed are needed Ion exchange resin separates, and anion exchange resin is since density is small on upper layer, and cation exchange resin density is greatly in lower layer.So Enter resin from the both direction up and down of resin respectively with sodium hydroxide and hydrochloric acid afterwards, then utilizes collector will again in interface Spent acid alkali mobile phone discharge after life.It is possible to will appear layering when layering unevenly, has caused a small amount of anion exchange Resin is mixed in cation exchange resin or has a small amount of cation exchange resin to be mixed in anion exchange resin.It makes Destruction is caused to resin instead when at regeneration, influences effluent quality and the cycle of operation.In cation exchange resin by Na+Type turns Change H into+When type, the volume of resin can change, and similarly regeneration be easy to cause to be not thorough.
Summary of the invention
An object of the present invention is to provide a kind of ion-exchange reactions and regenerating units.
Ion-exchange reactions and regenerating unit of the invention, including:Shell further includes in the shell:Upper water-distributing device, Top is arranged in the shell in the upper water-distributing device;Anion exchanger lower clapboard;High-purity (99.9%) quartz sand, institute Glass sand is stated to be laid on the anion exchanger lower clapboard;Anion exchange resin, the anion exchange tree Rouge is arranged on the glass sand;Anion water collector, the anion water collector are embedded in the high-purity quartz In sand;Anion regeneration distributor, the anion regeneration distributor be more spaced first hollow pipes, it is described yin from Sub- regenerative divider is arranged on the anion exchanger lower clapboard;Cation exchanger upper spacer, the cation exchange Device upper spacer is below the anion exchanger lower clapboard;Cation exchange resin water distributor, the cation exchange resin Water distributor is below the cation exchanger upper spacer;Cation exchanger lower clapboard, the cation exchanger lower clapboard Below the cation exchange resin water distributor;Cation exchange resin, the cation exchange resin are arranged in the sun On ion-exchanger lower clapboard;Cationic regenerative divider, the cation regenerative divider is more spaced second Hollow pipe, the cation regenerative divider are arranged on the cation exchanger lower clapboard;Be discharged partition, it is described water outlet every Plate is arranged below the cation exchanger lower clapboard;Double end water cap, the double end water cap will be for that will pass through resin cation The water of processing passes through the cation exchanger lower clapboard and the water outlet partition, then flows into and is arranged in below the shell Outlet valve.
Ion-exchange reactions and regenerating unit of the invention, occurs again when solving mixed ion exchanger acid-alkali regeneration It is raw to be not thorough or the problem of regenerated liquid is to the destruction of resin.By the redesign constructed to equipment, soda acid can be avoided again Influence after the mixing of raw liquid to resin, regeneration level is high, and cleaning thoroughly, can be widely applied to the water process with ion exchange Field.
In addition, ion-exchange reactions and regenerating unit that the present invention is above-mentioned, can also have following additional technical characteristic:
Further, the outer wall of first hollow pipe is the grid of 0.2mm, is highly 1.4m.
Further, the outer wall of second hollow pipe is the grid of 0.2mm, is highly 0.6m.
Further, the cation exchanger upper spacer is below the anion exchanger lower clapboard at 0.1m.
Further, the cation exchange resin water distributor is below the cation exchanger upper spacer at 0.15m.
Further, the glass sand with a thickness of 0.3m, the anion exchange resin with a thickness of 1m, institute State cation exchange resin with a thickness of 0.5m.
Further, further include on the shell:Inlet valve, the inlet valve are arranged in the case top;Backwash row Water valve after the backwash drain valve is in parallel with the inlet valve, is connect with the upper water-distributing device on top in shell;Anion Regenerated liquid drain valve, the anion regeneration liquid drain valve are arranged above the anion exchanger lower clapboard;Anion is handed over Resin outlet valve is changed, the anion exchange resin outlet valve is above the anion exchanger lower clapboard;Anion regeneration Liquid liquid feed valve, the anion regeneration liquid liquid feed valve on the anion exchanger lower clapboard and the cation exchanger every Between plate;Anion regeneration liquid flushing valve, the anion regeneration liquid flushing valve are in parallel with the anion regeneration liquid liquid feed valve; Cation exchange resin inlet valve, the cation exchange resin inlet valve are connected to the cation exchange resin water distributor, And the cation exchange resin inlet valve is connected to after the anion exchange resin outlet valve parallel connection with conversion drain valve;Sun Ion regenerated liquid liquid feed valve, the cation regenerated liquid liquid feed valve is in the cation exchanger lower clapboard and the water outlet partition Between;Cationic regenerated liquid flushing valve, the cation regenerated liquid flushing valve are in parallel with the cationic regenerated liquid liquid feed valve;With The flushing valve of the outlet valve parallel connection.
Further, 1.5m is arranged above the anion exchanger lower clapboard in the anion regeneration liquid drain valve Place.
Further, the anion exchange resin outlet valve is above the anion exchanger lower clapboard at 0.15m.
Additional aspect and advantage of the invention will be set forth in part in the description, and will partially become from the following description Obviously, or practice through the invention is recognized.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of ion-exchange reactions and regenerating unit of the invention;
Fig. 2 is sectional view of the Fig. 1 along A-A ' line;
Fig. 3 is sectional view of the Fig. 1 along B-B ' line;
Fig. 4 is sectional view of the Fig. 1 along C-C ' line;
In Fig. 1 it is each label be respectively:1- inlet valve, 2- backwash drain valve, the upper water-distributing device of 3-, 4- anion regeneration point Orchestration, 5- anion water collector, 6- anion exchange resin outlet valve, 7- cation exchange resin inlet valve, 8- conversion draining Valve, 9- cation exchange resin water distributor, 10- anion exchanger lower clapboard, 11- cation exchanger upper spacer, 12- yin from Sub- regenerated liquid liquid feed valve, 13- anion regeneration liquid flushing valve, 14- cation regenerative divider, under 15- cation exchanger every Plate, 16- water outlet partition, 17- cation regenerated liquid liquid feed valve, 18- cation regenerated liquid flushing valve, 19- double end water cap, 20- go out Water valve, 21- flushing valve, 22- anion regeneration liquid drain valve, 23- glass sand, 24- anion exchange resin, 25- sun Ion exchange resin, 26- shell.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, it is intended to is used to explain the present invention, and is not considered as limiting the invention.
As shown in Figs 1-4, as one embodiment of the present invention, the ion-exchange reactions and regenerating unit, packet It includes:Shell 26 further includes in the shell 26:Upper water-distributing device 3, the upper setting of water-distributing device 3 are pushed up in the shell 26 End;Anion exchanger lower clapboard 10;High-purity (99.9%) quartz sand 23, the glass sand 23 is laid in the yin On ion-exchanger lower clapboard 10 (wherein, "upper", "lower" are relative position, as shown in Figure 1);Anion exchange resin 24, institute Anion exchange resin 24 is stated to be arranged on the glass sand 23;Anion water collector 5, the anion water collector 5 are embedded in the glass sand 23;Anion regeneration distributor 4, the anion regeneration distributor 4 are more interval rows First hollow pipe of column, the anion regeneration distributor 4 are arranged on the anion exchanger lower clapboard 10;Cation is handed over Parallel operation upper spacer 11, the cation exchanger upper spacer 11 is below the anion exchanger lower clapboard 10;Cation is handed over Resin water distributor 9 is changed, the cation exchange resin water distributor 9 is below the cation exchanger upper spacer 11;Cation Exchanger lower clapboard 15, the cation exchanger lower clapboard 15 is below the cation exchange resin water distributor 9;Cation Exchanger resin 25, the cation exchange resin 25 are arranged on the cation exchanger lower clapboard 15;Cation is estranged again Orchestration 14, the cation regenerative divider 14 is more spaced second hollow pipes, the cation regenerative divider 14 are arranged on the cation exchanger lower clapboard 15;It is discharged partition 16, the water outlet partition 16 is arranged in the cation 15 lower section of exchanger lower clapboard;Double end water cap 19, the double end water cap 19 are used to wear in the water handled by resin cation 25 The cation exchanger lower clapboard 15 and the water outlet partition 16 are crossed, the water outlet being arranged in below the shell 26 is then flowed into Valve 20.
Ion-exchange reactions and regenerating unit of the invention, occurs again when solving mixed ion exchanger acid-alkali regeneration It is raw to be not thorough or the problem of regenerated liquid is to the destruction of resin.By the redesign constructed to equipment, soda acid can be avoided again Influence after the mixing of raw liquid to resin, regeneration level is high, and cleaning thoroughly, can be widely applied to the water process with ion exchange Field.
As another embodiment of the invention, the outer wall of first hollow pipe is the grid of 0.2mm, is highly 1.4m。
As another embodiment of the invention, the outer wall of second hollow pipe is the grid of 0.2mm, is highly 0.6m。
As another embodiment of the invention, the cation exchanger upper spacer 11 is in the anion exchanger At 10 lower section 0.1m of lower clapboard.
As another embodiment of the invention, the cation exchange resin water distributor 9 is in the cation exchange At 11 lower section 0.15m of device upper spacer.
As another embodiment of the invention, the glass sand 23 with a thickness of 0.3m, the anion Exchanger resin 24 with a thickness of 1m, the cation exchange resin 25 with a thickness of 0.5m.
As another embodiment of the invention, further include on the shell:Inlet valve 1, the setting of inlet valve 1 exist 26 top of shell;Backwash drain valve 2, after the backwash drain valve 2 is in parallel with the inlet valve 1, with top in shell 26 The upper water-distributing device 3 connect;Anion regeneration liquid drain valve 22, the anion regeneration liquid drain valve 22 are arranged described 10 top of anion exchanger lower clapboard;Anion exchange resin outlet valve 6, the anion exchange resin outlet valve 6 is in institute State 10 top of anion exchanger lower clapboard;Anion regeneration liquid liquid feed valve 12, the anion regeneration liquid liquid feed valve 12 is in institute It states between anion exchanger lower clapboard 10 and the cation exchanger upper spacer 11;Anion regeneration liquid flushing valve 13, institute It is in parallel with the anion regeneration liquid liquid feed valve 12 to state anion regeneration liquid flushing valve 13;Cation exchange resin inlet valve 7, institute Cation exchange resin inlet valve 7 is stated to be connected to the cation exchange resin water distributor 9, and the cation exchange resin into Water valve 7 is connected to after 6 parallel connection of anion exchange resin outlet valve with conversion drain valve 8;Cationic regenerated liquid liquid feed valve 17, The cation regenerated liquid liquid feed valve 17 is between the cation exchanger lower clapboard 15 and the water outlet partition 16;Cation Regenerated liquid flushing valve 18, the cation regenerated liquid flushing valve 18 are in parallel with the cationic regenerated liquid liquid feed valve 17;Outlet valve 20, the outlet valve 20 is arranged below the shell 26;Flushing valve 21, the flushing valve 21 are in parallel with the outlet valve 20.
As another embodiment of the invention, the setting of anion regeneration liquid drain valve 22 is handed in the anion At 10 top 1.5m of parallel operation lower clapboard.
As another embodiment of the invention, the anion exchange resin outlet valve 6 is in the anion exchange At 10 top 0.15m of device lower clapboard.
Wherein, on the hollow pipe of anion regeneration distributor 4 and anion exchanger lower clapboard 10 and cation exchanger The gap connection of partition 11.The gap and anion regeneration of anion exchanger lower clapboard 10 and cation exchanger upper spacer 11 13 connection of liquid liquid feed valve 12 and the flushing valve of anion regeneration liquid.Anion water collector 5 and anion exchange resin outlet valve 6 It is logical.Cation exchange resin water distributor 9 and 7 connection of cation exchange resin inlet valve.
Cationic regenerative divider 14 is connect with cation exchanger lower clapboard 15, cationic regenerative divider 14 and sun from The gap connection of sub- exchanger lower clapboard 15 and water outlet partition 16.The gap of cation exchanger lower clapboard 15 and water outlet partition 16 With cationic regenerated liquid liquid feed valve 17 and cationic 18 connection of regenerated liquid flushing valve.
Double end water cap 19 through cation exchanger lower clapboard 15 and water outlet partition 16,19 central space of double end water cap not with The void contacts of cation exchanger lower clapboard 15 and water outlet partition 16.
At work, water is evenly dispersed to shell 26 by upper water-distributing device 3 after inlet valve 1 by untreated water It is interior.Gone out after being collected by anion water collector 5 by anion exchange resin by the processed water of anion exchange resin 24 Water valve 6 enters cation exchange tree after 9 water distribution uniformity of cation exchange resin inlet valve 7 and cation exchange resin water distributor Rouge 25.Deionized water is obtained by double end water cap 19 after cation exchange resin 25, finally by outlet valve 20 will go from Sub- water transfers out.
After ion-exchange reactions and regenerating unit complete water processed cycle, needs to carry out backwash to ion-exchanger, regenerate, just It washes.
Ion-exchange reactions and regenerating unit backwash process are:(1) backwash is carried out to cation exchange resin 25, water passes through To 25 reverse cleaning of cation exchange resin, backwash water passes through cation exchange resin inlet valve for outlet valve 20 and double end water cap 19 7 discharge with conversion drain valve 8.(2) backwash is carried out to anion exchange resin 24, water passes through cation exchange resin inlet valve 7 With anion exchange resin outlet valve 6, anion water collector 5 carries out backwash to anion exchange resin 24, and backwash water passes through anti- Drain valve 2 is washed to emit.
Ion-exchange reactions and regenerating unit regeneration process are:(1) when anion exchange resin 24 regenerates, sodium hydroxide is logical It crosses anion regeneration liquid liquid feed valve 12 to enter between anion exchanger lower clapboard 10 and cation exchanger upper spacer 11, so Anion exchange resin 24 is regenerated by anion regeneration distributor 4 afterwards.Due to regenerated liquid by surrounding and lower section to tree Rouge is regenerated, favorable regeneration effect.Regenerated liquid after regeneration is emitted by anion regeneration liquid drain valve 22.(2) sun from When sub-exchange resin 25 regenerates, hydrochloric acid passes through cationic regenerated liquid liquid feed valve 17 and enters cation exchanger lower clapboard 15 and go out Between water partition 16, then cation exchange resin 25 is regenerated by cationic regenerative divider 14.Due to regenerated liquid Resin is regenerated by surrounding and lower section, favorable regeneration effect.Regenerated liquid after regeneration passes through cation exchange resin inlet valve 7 It is discharged with conversion drain valve 8.
Ion-exchange reactions and the positive wash journey of regenerating unit are:(1) with untreated water pair after ion exchange resin regeneration Anion exchange resin 24 is rinsed, and flushing water anionic reactive device outlet valve 6 and turns from anion regeneration liquid flushing valve 12 The water valve 8 that changes gear discharge.(2) cation exchange resin 25 is rinsed, water passes through anionic reactive device outlet valve 6, cation Reactor inlet valve 7, cation exchange resin water distributor 9 enter cationic water quality, and flushing water passes through cationic regenerated liquid and rinses Valve 18 and flushing valve 21 are discharged.
To sum up, ion-exchange reactions of the invention and regenerating unit, hair when solving mixed ion exchanger acid-alkali regeneration The problem of raw regeneration is not thorough or regenerated liquid is to the destruction of resin.By the redesign constructed to equipment, can be avoided To the influence of resin after the mixing of acid-alkali regeneration liquid, regeneration level is high, and cleaning thoroughly, can be widely applied to ion exchange Water treatment field.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not It must be directed to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be in office It can be combined in any suitable manner in one or more embodiment or examples.In addition, without conflicting with each other, the skill of this field Art personnel can tie the feature of different embodiments or examples described in this specification and different embodiments or examples It closes and combines.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example Property, it is not considered as limiting the invention, those skilled in the art within the scope of the invention can be to above-mentioned Embodiment is changed, modifies, replacement and variant.

Claims (9)

1. a kind of ion-exchange reactions and regenerating unit, which is characterized in that including:Shell further includes in the shell:
Top is arranged in the shell in upper water-distributing device, the upper water-distributing device;
Anion exchanger lower clapboard;
Quartz sand, the quartz sand are laid on the anion exchanger lower clapboard;
Anion exchange resin, the anion exchange resin are arranged on the glass sand;
Anion water collector, the anion water collector are embedded in the glass sand;
Anion regeneration distributor, the anion regeneration distributor be more spaced first hollow pipes, it is described yin from Sub- regenerative divider is arranged on the anion exchanger lower clapboard;
Cation exchanger upper spacer, the cation exchanger upper spacer is below the anion exchanger lower clapboard;
Cation exchange resin water distributor, the cation exchange resin water distributor is under the cation exchanger upper spacer Side;
Cation exchanger lower clapboard, the cation exchanger lower clapboard is below the cation exchange resin water distributor;
Cation exchange resin, the cation exchange resin are arranged on the cation exchanger lower clapboard;
Cationic regenerative divider, it is described cation regenerative divider be more spaced second hollow pipes, it is described sun from Sub- regenerative divider is arranged on the cation exchanger lower clapboard;
It is discharged partition, the water outlet partition is arranged below the cation exchanger lower clapboard;
Double end water cap, the double end water cap for will by resin cation processing water pass through the cation exchanger under every Then plate and the water outlet partition flow into the outlet valve being arranged in below the shell.
2. ion-exchange reactions according to claim 1 and regenerating unit, which is characterized in that outside first hollow pipe Wall is the grid of 0.2mm, is highly 1.4m.
3. ion-exchange reactions according to claim 1 and regenerating unit, which is characterized in that outside second hollow pipe Wall is the grid of 0.2mm, is highly 0.6m.
4. ion-exchange reactions according to claim 1 and regenerating unit, which is characterized in that on the cation exchanger Partition is below the anion exchanger lower clapboard at 0.1m.
5. ion-exchange reactions according to claim 1 and regenerating unit, which is characterized in that the cation exchange resin Water distributor is below the cation exchanger upper spacer at 0.15m.
6. ion-exchange reactions according to claim 1 and regenerating unit, which is characterized in that the glass sand With a thickness of 0.3m, the anion exchange resin with a thickness of 1m, the cation exchange resin with a thickness of 0.5m.
7. ion-exchange reactions according to claim 1 and regenerating unit, which is characterized in that further include on the shell:
Inlet valve, the inlet valve are arranged in the case top;
Backwash drain valve, the upper water-distributing device after the backwash drain valve is in parallel with the inlet valve, with top in shell Connection;
Anion regeneration liquid drain valve, the anion regeneration liquid drain valve are arranged on the anion exchanger lower clapboard Side;
Anion exchange resin outlet valve, the anion exchange resin outlet valve is on the anion exchanger lower clapboard Side;
Anion regeneration liquid liquid feed valve, the anion regeneration liquid liquid feed valve is in the anion exchanger lower clapboard and the sun Between ion-exchanger upper spacer;
Anion regeneration liquid flushing valve, the anion regeneration liquid flushing valve are in parallel with the anion regeneration liquid liquid feed valve;
Cation exchange resin inlet valve, the cation exchange resin inlet valve and the cation exchange resin water distributor connect It is logical, and the cation exchange resin inlet valve it is in parallel with the anion exchange resin outlet valve after with convert drain valve company It is logical;
Cationic regenerated liquid liquid feed valve, it is described cation regenerated liquid liquid feed valve the cation exchanger lower clapboard and it is described go out Between water partition;
Cationic regenerated liquid flushing valve, the cation regenerated liquid flushing valve are in parallel with the cationic regenerated liquid liquid feed valve;
The flushing valve in parallel with the outlet valve.
8. ion-exchange reactions according to claim 7 and regenerating unit, which is characterized in that the anion regeneration liquid row Valve setting is put above the anion exchanger lower clapboard at 1.5m.
9. ion-exchange reactions according to claim 7 and regenerating unit, which is characterized in that the anion exchange resin Outlet valve is above the anion exchanger lower clapboard at 0.15m.
CN201810671675.7A 2018-06-26 2018-06-26 Ion-exchange reactions and regenerating unit Pending CN108855248A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810671675.7A CN108855248A (en) 2018-06-26 2018-06-26 Ion-exchange reactions and regenerating unit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810671675.7A CN108855248A (en) 2018-06-26 2018-06-26 Ion-exchange reactions and regenerating unit

Publications (1)

Publication Number Publication Date
CN108855248A true CN108855248A (en) 2018-11-23

Family

ID=64294890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810671675.7A Pending CN108855248A (en) 2018-06-26 2018-06-26 Ion-exchange reactions and regenerating unit

Country Status (1)

Country Link
CN (1) CN108855248A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111362357A (en) * 2019-04-25 2020-07-03 依科沃特系统有限公司 Water treatment tank with distribution plate assembly and assembly method
CN111549829A (en) * 2020-05-22 2020-08-18 南昌大学 Bentonite waterproof blanket for enhancing anionic pollution barrier capability and manufacturing method thereof
CN113058662A (en) * 2021-03-22 2021-07-02 江西蓝星星火有机硅有限公司 Resin regeneration method and mixed bed regeneration system used by same
CN117326637A (en) * 2023-08-31 2024-01-02 惠州金茂源环保科技有限公司 Ion exchange resin tank and regeneration treatment method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101450331A (en) * 2008-12-17 2009-06-10 牛继星 Ion exchange resin regeneration technique capable of saving acid and alkali
CN102730796A (en) * 2011-03-29 2012-10-17 栗田工业株式会社 Ion exchange device
CN203411366U (en) * 2013-06-14 2014-01-29 成都之和环保科技有限公司 Novel mixed ion exchanger
CN104743639A (en) * 2015-04-15 2015-07-01 西安净源水处理科技有限公司 High-efficiency sodium ion exchanger
CN204675862U (en) * 2015-05-05 2015-09-30 江苏金凯树脂化工有限公司 Reverse-flow mixed-bed resin regenerating unit
CN206289009U (en) * 2016-12-19 2017-06-30 马鞍山中创环保科技有限公司 A kind of mixed bed formula ion-exchange fibre sewage treatment equipment

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101450331A (en) * 2008-12-17 2009-06-10 牛继星 Ion exchange resin regeneration technique capable of saving acid and alkali
CN102730796A (en) * 2011-03-29 2012-10-17 栗田工业株式会社 Ion exchange device
CN203411366U (en) * 2013-06-14 2014-01-29 成都之和环保科技有限公司 Novel mixed ion exchanger
CN104743639A (en) * 2015-04-15 2015-07-01 西安净源水处理科技有限公司 High-efficiency sodium ion exchanger
CN204675862U (en) * 2015-05-05 2015-09-30 江苏金凯树脂化工有限公司 Reverse-flow mixed-bed resin regenerating unit
CN206289009U (en) * 2016-12-19 2017-06-30 马鞍山中创环保科技有限公司 A kind of mixed bed formula ion-exchange fibre sewage treatment equipment

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
化学工程手册编委会: "《化学工程手册》", 30 June 1985, 化学工业出版社 *
机械工业部第二设计研究院编: "《电镀废水治理涉及手册》", 31 October 1987, 浙江科学技术出版社 *
陈志和等: "《电厂化学设备及系统》", 31 March 2006, 中国电力出版社 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111362357A (en) * 2019-04-25 2020-07-03 依科沃特系统有限公司 Water treatment tank with distribution plate assembly and assembly method
CN111362357B (en) * 2019-04-25 2023-12-29 依科沃特系统有限公司 Water treatment tank with distribution plate assembly and assembly method
CN111549829A (en) * 2020-05-22 2020-08-18 南昌大学 Bentonite waterproof blanket for enhancing anionic pollution barrier capability and manufacturing method thereof
CN113058662A (en) * 2021-03-22 2021-07-02 江西蓝星星火有机硅有限公司 Resin regeneration method and mixed bed regeneration system used by same
CN117326637A (en) * 2023-08-31 2024-01-02 惠州金茂源环保科技有限公司 Ion exchange resin tank and regeneration treatment method thereof
CN117326637B (en) * 2023-08-31 2024-04-26 惠州金茂源环保科技有限公司 Ion exchange resin tank and regeneration treatment method thereof

Similar Documents

Publication Publication Date Title
CN108855248A (en) Ion-exchange reactions and regenerating unit
CN205419857U (en) Cloudy cation exchange system
US3385787A (en) Condensate purification process
JP5720364B2 (en) Ion exchanger
JP4869881B2 (en) Ion exchange apparatus and ion exchange method
WO2007040266A1 (en) Process and equipment for demineralizing condensate
US5955510A (en) Process for the regeneration of ion exchange resins in a fixed double-bed type apparatus
CN104743639B (en) High-efficiency sodium ion exchanger
JPH10137751A (en) Ion exchange method and ion exchange column used for ion exchange method
US3583908A (en) Condensate purification process
CN101264954B (en) Multi-standard type ion-exchanger
CN100506711C (en) Double-tower type two-stage desalting device
CN103304004A (en) Mixed ion exchanger of flotation bed
JP5999400B1 (en) Ion exchange apparatus and method of using the same
CN208302795U (en) A kind of flat bed as ion-exchange unit
CN203959882U (en) A kind of ion-exchanger
CN113044919A (en) Fine treatment process and device for condensed water in power plant
CN203373182U (en) Floating bed mixed ion exchanger
JP2006159013A (en) Method and apparatus for regeneration by chemical-passing of ion exchange resin
CN211896442U (en) Pure water equipment for cleaning miniature quartz crystal resonator
RU2447026C2 (en) Method and apparatus for post-treatment of water during fine demineralisation
CN217627934U (en) Integrated continuous ion exchange desalination system
CN204324956U (en) The water softening system of series connection
CN214780916U (en) Fine treatment device for condensate water in power plant
CN214765522U (en) Ion exchange resin regenerating unit

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181123

RJ01 Rejection of invention patent application after publication