CN103304004A - Mixed ion exchanger of flotation bed - Google Patents
Mixed ion exchanger of flotation bed Download PDFInfo
- Publication number
- CN103304004A CN103304004A CN2013101914621A CN201310191462A CN103304004A CN 103304004 A CN103304004 A CN 103304004A CN 2013101914621 A CN2013101914621 A CN 2013101914621A CN 201310191462 A CN201310191462 A CN 201310191462A CN 103304004 A CN103304004 A CN 103304004A
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- water
- tank body
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- ion exchanger
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Abstract
The invention discloses a mixed ion exchanger of a flotation bed. The mixed ion exchanger comprises a tank body, a water inlet and a water outlet, wherein the water inlet is formed in the bottom of the tank body; and the water outlet is formed in the top of the tank body. By setting the water inlet in the bottom of the tank body and the water outlet in the top of the tank body, industrial water to be treated firstly takes part in reaction with strong-acid cation-exchange resin, wherein the chemical formula is as follows: RH+NaHSiO3=RNa+H2SiO3, generated acidic water is used for improving subsequent ion exchange reaction, and qualified secondary desalted water is prepared; all resin at the upper, middle and lower parts in the tank body take part in the reaction, so that the running cycle of a mixed bed is prolonged, the cyclic water preparation amount is increased, and the outlet water quality is improved; as the industrial water enters from the bottom of the tank body, anion exchange resin and cation exchange resin are in suspension states, the surface of contact between the industrial water and the resin is increased, the exchange capability of the resin is brought into full play, the exchange effect is improved, the equipment running speed is increased, and the water yield is increased. The mixed ion exchanger is suitable for treating the industrial water.
Description
Technical field
The present invention relates to a kind of Industrial cleaning facility water treating equipment, particularly the floating bed mixed ion exchanger.
Background technology
At present, the general fixed bed yin, yang mixed ion exchanger (abbreviation mixed bed) that adopts of industry is processed service water, filling anionite-exchange resin and Zeo-karb in the described mixed bed, and mix, can regard as by countless anionite-exchange resin and Zeo-karb (abbreviation resin) to be staggered.The service water that contains the yin, yang ion enters from the top of described mixed bed, described yin, yang ion in described mixed bed by resins exchange, thereby obtain high-purity water in the bottom of described mixed bed.Behind described mixed bed operation for some time efficiency lost resin, need respectively anionite-exchange resin and Zeo-karb to be regenerated with alkali, acid regeneration liquid, make resin recover exchange capacity.But there is following problem in described mixed bed:
Because the proportion of described anionite-exchange resin is little, the ratio of Zeo-karb is great, (mixed bed internal upper part anionite-exchange resin accounts for more ratio so the easy mixing of anionite-exchange resin and Zeo-karb is inhomogeneous, the bottom Zeo-karb accounts for more ratio), thereby causing described mixed bed internal upper part is strongly basic anion exchange resin, the bottom is storng-acid cation exchange resin, like this, the yin, yang ion in the pending service water at first contacts with strong anion-exchange resin.But because pending service water mostly is greatly neutrality or slight alkalinity (mainly containing sodium ion and bicarbonate radical, silicate etc.), and HSiO
3Ion and the reaction of described strong anion-exchange resin generate the concrete reaction formula of NaOH(and are: ROH+NaHSiO
3=RHSiO
3+ NaOH), so such ion exchange reaction may be carried out hardly; Like this, described NaHSiO
3Directly enter the mixed bed middle part, with the strong-acid cation-exchange resin generation ion exchange reaction at middle part: RH+NaHSiO
3=RNa+H
2SiO
3, the H of generation
2SiO
3With strong anion-exchange resin generation ion exchange reaction: ROH+H
2SiO
3=RHSiO
3+ H
2O; But owing to the anionite-exchange resin on mixed bed top does not play one's part to the full, so must also have some NaHSiO
3And H
2SiO
3Enter into the mixed bed bottom, the strong-acid cation-exchange resin reaction of they and mixed bed bottom: RH+NaHSiO
3=RNa+H
2SiO
3, so just cause containing in the water outlet H
2SiO
3Thereby so that the water after purifying is aobvious acid, specific conductivity also raises, and so that mixed-bed effluent quality deterioration.Simultaneously, only be the resin that mixes of middle that part of mixed bed owing to what ion exchange really can occur, so the resin utilization ratio is lower, so just so that the mixed bed cycle of operation is short, water production in periodic mode descends, effluent quality worsens.
Summary of the invention
The objective of the invention is provides the floating bed that a kind of effluent quality is good, the cycle of operation is long, water production in periodic mode is high and water production rate is large mixed ion exchanger in order to overcome the deficiency of above-mentioned background technology.
In order to realize above purpose, a kind of floating bed mixed ion exchanger provided by the invention, comprise that inside is filled with the tank body of anionite-exchange resin and Zeo-karb, water-in and water outlet, described water-in is arranged on the bottom of described tank body, and described water outlet is arranged on the top of described tank body.By described water-in being arranged on the bottom of described tank body, and described water outlet is arranged on the top of described tank body, like this, pending service water reacts with the strong-acid cation-exchange resin of tank base first: RH+NaHSiO
3=RNa+H
2SiO
3, the sour water of generation has improved the ion exchange reaction of follow-up middle tank body middle part hybrid resin and top strong anion-exchange resin, makes qualified secondary de-mineralized water; The resin of tank body internal upper part, middle part and bottom all participates in reaction, has prolonged the cycle that mixed bed is moved, has improved water production in periodic mode, has improved effluent quality; Because service water enters from tank base, so anionite-exchange resin and Zeo-karb are in suspended state, has increased the contact surface of service water and resin, given full play to the exchange capacity of resin, improve the exchange effect, increased equipment operation flow velocity, improved water production rate.
In such scheme, the position of the corresponding described water outlet in described tank body top is provided with water cap mounting plate, and described upper water cap mounting plate is provided with the water cap.The upper water cap that adds has avoided water outlet to take resin out of tank body and water outlet is even; Simultaneously, described upper water cap can make regeneration alkali lye fully contact with resin.
In such scheme, the position of the corresponding described water-in of described tank body lower part is provided with lower water cap mounting plate, and described lower water cap mounting plate is provided with lower water cap.The lower water cap that adds can make pending service water fully contact with resin, and the regeneration acid solution is fully contacted with resin; Simultaneously, the lower water cap that adds can be avoided into water resin being broken up effectively.
In such scheme, the cap head of described upper water cap arranges downwards, and the cap head of described lower water cap is upwards arranged.
In such scheme, described tank body middle part is provided with water port.
The beneficial effect that technical scheme provided by the invention is brought is:
1, by described water-in being arranged on the bottom of described tank body, and described water outlet is arranged on the top of described tank body, like this, pending service water reacts with the strong-acid cation-exchange resin of tank base first: RH+NaHSiO
3=RNa+H
2SiO
3, the sour water of generation has improved the ion exchange reaction of follow-up middle tank body middle part hybrid resin and top strong anion-exchange resin, makes qualified secondary de-mineralized water; The resin of tank body internal upper part, middle part and bottom all participates in reaction, has prolonged the cycle that mixed bed is moved, has improved water production in periodic mode, has improved effluent quality; Because service water enters from tank base, so anionite-exchange resin and Zeo-karb are in suspended state, has increased the contact surface of service water and resin, given full play to the exchange capacity of resin, improve the exchange effect, increased equipment operation flow velocity, improved water production rate.
2, the upper water cap that adds has avoided water outlet to take resin out of tank body and water outlet is even; Simultaneously, described upper water cap can make regeneration alkali lye fully contact with resin.
3, the lower water cap that adds can make pending service water fully contact with resin, and the regeneration acid solution is fully contacted with resin; Simultaneously, the lower water cap that adds can be avoided into water resin being broken up effectively.
Description of drawings
Fig. 1 is structural representation of the present invention;
Fig. 2 is the side-looking structural representation of Fig. 1.
Among the figure, tank body 1, water-in 2, water outlet 3, upper water cap mounting plate 4, upper water cap 5, lower water cap mounting plate 6, lower water cap 7, water port 8, inlet pipe 9, water-in valve 9a, resin layering water inlet valve 9b, lower drain port valve 9c, acid solution inlet valve 9d, outlet pipe 10, water outlet valve 10a, top scupper valve 10b, alkali lye inlet valve 10c advances washing fluid mouth valve 10d.
Embodiment
For making the purpose, technical solutions and advantages of the present invention clearer, embodiment of the present invention is described further in detail below in conjunction with accompanying drawing.
As shown in Figure 1, a kind of floating bed mixed ion exchanger provided by the invention, comprise that inside is filled with the tank body 1 of anionite-exchange resin and Zeo-karb, water-in 2 and water outlet 3, described water-in 2 is arranged on the bottom of described tank body 1, and described water outlet 3 is arranged on the top of described tank body 1.By described water-in 2 being arranged on the bottom of described tank body 1, and described water outlet 3 is arranged on the top of described tank body 1, like this, pending service water reacts with the strong-acid cation-exchange resin of tank body 1 bottom first: RH+NaHSiO
3=RNa+H
2SiO
3, the sour water of generation has improved the ion exchange reaction of follow-up middle tank body 1 middle part hybrid resin and top strong anion-exchange resin, makes qualified secondary de-mineralized water; The resin of tank body 1 internal upper part, middle part and bottom all participates in reaction, has prolonged the cycle that mixed bed is moved, has improved water production in periodic mode, has improved effluent quality; Because service water enters from tank body 1 bottom, so anionite-exchange resin and Zeo-karb are in suspended state, has increased the contact surface of service water and resin, given full play to the exchange capacity of resin, improve the exchange effect, increased equipment operation flow velocity, improved water production rate.
The position of the corresponding described water outlet 3 in above-mentioned tank body 1 top is provided with water cap mounting plate 4, and described upper water cap mounting plate 4 is provided with water cap 5.The upper water cap 5 that adds has avoided water outlet to take resin out of tank body and water outlet is even; Simultaneously, described upper water cap 5 can make regeneration alkali lye fully contact with resin.The position of the corresponding described water-in 2 in described tank body 1 bottom is provided with lower water cap mounting plate 6, and described lower water cap mounting plate 6 is provided with lower water cap 7.The lower water cap 7 that adds can make pending service water fully contact with resin, and the regeneration acid solution is fully contacted with resin; Simultaneously, the lower water cap 7 that adds can be avoided into water resin being broken up effectively.The cap head of described upper water cap 5 arranges downwards, and the cap head of described lower water cap 7 is upwards arranged.Described tank body 1 middle part is provided with water port 8.
Working process of the present invention is as follows:
After pending service water enters tank body 1 bottom from described water-in 2, at first with the strong-acid cation-exchange resin generation ion exchange reaction of tank body 1 bottom: RH (positive resin)+NaHSiO
3=RNa+H
2SiO
3It is acid that reacted water outlet is, and improved the chemical working condition of water, is conducive to the strong anion-exchange resin generation ion exchange reaction on next step and middle part hybrid resin and top; The ion exchange reaction of middle part hybrid resin is: RH+ROH (negative resin)+NaHSiO
3=RNa+RHSiO
3+ H
2O; The generation ion exchange reaction of the strong base negative resin on top is: ROH+H
2SiO
3=RHSiO
3+ H
2O.Like this, the water that purifies from described water outlet 3 is neutrality.
Resin regeneration process of the present invention is as follows:
1, resin layering: from described water-in 2 water inlets, the control water flow velocity, utilize anionite-exchange resin with the difference in specific gravity of Zeo-karb anionite-exchange resin to be separated with Zeo-karb, top is anionite-exchange resin, the bottom is Zeo-karb, carries out resin settled and draining after layering is complete again.
2, resin regeneration: the regeneration acid solution enters from the water-in 2 of tank body 1 bottom, and the Zeo-karb of tank body 1 bottom is regenerated, and then discharges from the water port 8 at tank body 1 middle part; Regeneration alkali lye enters from the water outlet 3 at tank body 1 top, and the anionite-exchange resin on tank body 1 top is regenerated, and then discharges from the water port 8 at tank body 1 middle part; Regenerate complete after, replace tank body 1 interior residual spent acid, alkali lye with de-mineralized water.
3, mixed with resin: the water-in 2 to tank body 1 bottom passes into pressurized air, and mixed with resin is evenly got final product.
For the operation flow velocity be 110 ~ 130m
3The high flow rate interchanger of/h adopts external regeneration, adds respectively resin input aperture and resin delivery port in top and the bottom of tank body 1 accordingly.
In actual production process, can add inlet pipe 9 at described water-in 2 places, and add water-in valve 9a, resin layering water inlet valve 9b, lower drain port valve 9c, acid solution inlet valve 9d and entrance pressure contracting air scoop valve (acid solution inlet valve 9d and entrance pressure contracting air scoop valve are communicated with by threeway) at described inlet pipe 9; Also can go out to add outlet pipe 10 at described water outlet 3, and add water outlet valve 10a, top scupper valve 10b, alkali lye inlet valve 10c and advance washing fluid mouth valve 10d at described outlet pipe 10.Switch by controlling above-mentioned each valve is to realize the normal operation of this interchanger.
The present invention is by being arranged on described water-in 2 bottom of described tank body 1, and described water outlet 3 is arranged on the top of described tank body 1, and like this, pending service water reacts with the strong-acid cation-exchange resin of tank body 1 bottom first: RH+NaHSiO
3=RNa+H
2SiO
3, the sour water of generation has improved the ion exchange reaction of follow-up middle tank body 1 middle part hybrid resin and top strong anion-exchange resin, makes qualified secondary de-mineralized water; The resin of tank body 1 internal upper part, middle part and bottom all participates in reaction, has prolonged the cycle that mixed bed is moved, has improved water production in periodic mode, has improved effluent quality; Because service water enters from tank body 1 bottom, so anionite-exchange resin and Zeo-karb are in suspended state, has increased the contact surface of service water and resin, given full play to the exchange capacity of resin, improve the exchange effect, increased equipment operation flow velocity, improved water production rate.Be applicable to Treatment of Industrial Water.The upper water cap 5 that adds has avoided water outlet to take resin out of tank body and water outlet is even; Simultaneously, described upper water cap 5 can make regeneration alkali lye fully contact with resin.The lower water cap 7 that adds can make pending service water fully contact with resin, and the regeneration acid solution is fully contacted with resin; Simultaneously, the lower water cap 7 that adds can be avoided into water resin being broken up effectively.
The above only is preferred embodiment of the present invention, and is in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. floating bed mixed ion exchanger, comprise that inside is filled with the tank body of anionite-exchange resin and Zeo-karb, water-in and water outlet, it is characterized in that, described water-in is arranged on the bottom of described tank body, and described water outlet is arranged on the top of described tank body.
2. floating bed mixed ion exchanger according to claim 1 is characterized in that, the position of the corresponding described water outlet in described tank body top is provided with water cap mounting plate, and described upper water cap mounting plate is provided with the water cap.
3. floating bed mixed ion exchanger according to claim 1 and 2 is characterized in that, the position of the corresponding described water-in of described tank body lower part is provided with lower water cap mounting plate, and described lower water cap mounting plate is provided with lower water cap.
4. floating bed mixed ion exchanger according to claim 3 is characterized in that, the cap head of described upper water cap arranges downwards, and the cap head of described lower water cap is upwards arranged.
5. floating bed mixed ion exchanger according to claim 3 is characterized in that, described tank body middle part is provided with water port.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101914621A CN103304004A (en) | 2013-05-22 | 2013-05-22 | Mixed ion exchanger of flotation bed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101914621A CN103304004A (en) | 2013-05-22 | 2013-05-22 | Mixed ion exchanger of flotation bed |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103304004A true CN103304004A (en) | 2013-09-18 |
Family
ID=49129770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013101914621A Pending CN103304004A (en) | 2013-05-22 | 2013-05-22 | Mixed ion exchanger of flotation bed |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103304004A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103910411A (en) * | 2014-04-14 | 2014-07-09 | 周明 | Solid bed, double bed and method for producing industrial demineralized water by taking solid bed and double bed as terminal demineralization equipment |
| CN104310531A (en) * | 2014-11-28 | 2015-01-28 | 何新华 | Elastic full-type fixed bed up-flow regeneration ion exchanger |
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| JP2001179249A (en) * | 1999-12-22 | 2001-07-03 | Japan Organo Co Ltd | Condensed water desalting apparatus |
| CN201037120Y (en) * | 2007-04-13 | 2008-03-19 | 中国大唐集团科技工程有限公司 | Condensation water refined processing high-speed mixing bed |
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| CN202038896U (en) * | 2010-12-22 | 2011-11-16 | 南京中电联环保工程有限公司 | DN3400 high-flow-rate spherical mixed bed for nuclear power plant condensate polishing |
| CN102730796A (en) * | 2011-03-29 | 2012-10-17 | 栗田工业株式会社 | Ion exchange device |
| CN202766339U (en) * | 2012-08-17 | 2013-03-06 | 山东兆光色谱分离技术有限公司 | Mixed bed ion exchanger |
| CN203373182U (en) * | 2013-05-22 | 2014-01-01 | 陈龙 | Floating bed mixed ion exchanger |
-
2013
- 2013-05-22 CN CN2013101914621A patent/CN103304004A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001179249A (en) * | 1999-12-22 | 2001-07-03 | Japan Organo Co Ltd | Condensed water desalting apparatus |
| CN201037120Y (en) * | 2007-04-13 | 2008-03-19 | 中国大唐集团科技工程有限公司 | Condensation water refined processing high-speed mixing bed |
| CN201165477Y (en) * | 2008-01-17 | 2008-12-17 | 张文波 | Mixed bed |
| CN201161191Y (en) * | 2008-01-24 | 2008-12-10 | 杭州美亚水处理科技有限公司 | Acid-alkali regenerative agent conserving mix bed regenerating unit |
| CN102115228A (en) * | 2009-12-31 | 2011-07-06 | 张文波 | Regeneration systems for softeners and mixed beds |
| CN202030566U (en) * | 2010-09-03 | 2011-11-09 | 浙江弗莱德环境科技有限公司 | Mixed bed ion exchanger |
| CN202038896U (en) * | 2010-12-22 | 2011-11-16 | 南京中电联环保工程有限公司 | DN3400 high-flow-rate spherical mixed bed for nuclear power plant condensate polishing |
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| CN203373182U (en) * | 2013-05-22 | 2014-01-01 | 陈龙 | Floating bed mixed ion exchanger |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103910411A (en) * | 2014-04-14 | 2014-07-09 | 周明 | Solid bed, double bed and method for producing industrial demineralized water by taking solid bed and double bed as terminal demineralization equipment |
| CN103910411B (en) * | 2014-04-14 | 2015-11-04 | 周明 | Real bed, multiple bed and the industrial de-mineralized water production method as terminal demineralization plant thereof |
| CN104310531A (en) * | 2014-11-28 | 2015-01-28 | 何新华 | Elastic full-type fixed bed up-flow regeneration ion exchanger |
| CN104310531B (en) * | 2014-11-28 | 2016-08-24 | 何新华 | Elastic full room fixed bed countercurrent regenerating ion exchanger |
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Application publication date: 20130918 |