CN108855037A - A kind of preparation method of alumina-silica zinc composite catalyzing material - Google Patents

A kind of preparation method of alumina-silica zinc composite catalyzing material Download PDF

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Publication number
CN108855037A
CN108855037A CN201810799502.3A CN201810799502A CN108855037A CN 108855037 A CN108855037 A CN 108855037A CN 201810799502 A CN201810799502 A CN 201810799502A CN 108855037 A CN108855037 A CN 108855037A
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zinc
hydroxide
alumina
preparation
catalyzing material
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刘青
唐丽华
陆磊
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39Photocatalytic properties

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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Abstract

The invention discloses a kind of preparation methods of alumina-silica zinc composite catalyzing material, including:(1) aluminum nitrate solution is mixed with excessive urea liquid, quickly stirs 5~10h under 50~60 DEG C of water bath conditions, wherein mixing speed is 1200~1600r/min, obtains aluminum hydroxide sol;(2) a certain amount of zinc solution is added into above-mentioned aluminum hydroxide sol, is uniformly mixed, 1.5~3h is kept the temperature under 70~80 DEG C of water bath conditions, increases bath temperature to 85~95 DEG C, keeps the temperature 4~5h, obtain aluminium hydroxide-zinc hydroxide mixed sols;(3) above-mentioned aluminium hydroxide-zinc hydroxide mixed sols is cooled to room temperature, is filtered by vacuum, is washed 3~5 times with dehydrated alcohol and deionized water respectively, it is dry, 2~3h is calcined under the conditions of 380~450 DEG C, obtains alumina-silica zinc composite catalyzing material.Alumina-silica zinc composite catalyzing material in the present invention has preferable stability, and preparation method is simple, environmentally protective.

Description

A kind of preparation method of alumina-silica zinc composite catalyzing material
Technical field
The present invention relates to field of material technology, more particularly to a kind of preparation of alumina-silica zinc composite catalyzing material Method.
Background technique
The preparation process of alumina support is simple, and specific surface area is high, and mechanical strength is good, and aperture is suitable for being current using most One of extensive catalyst carrier, but the co-acting force of the active metal and carrier on pure alumina surface is larger, is easily formed Inactive species, such as nickel aluminate are not easy to form the II type activity phase of high activity.Therefore the preparation in relation to alumina support And modified preparation containing aluminium composite oxide is always the direction of scientific worker's research.
Nano zine oxide is a kind of self-activating semiconductor material, and forbidden bandwidth at room temperature is 3.27eV, swashs electron beam The ability of tiing up is 60meV.This allows for nano zine oxide can stablize the ability of transmitting from ultraviolet light to visible light.Photocatalysis width It is higher than optically catalytic TiO 2 width, in addition, zinc oxide has very high conductive, heating conduction and very high chemical stabilization again Property, these have broad application prospects nano zine oxide in fields such as photocatalysis, photoelectric conversions.It is existing nano oxidized Research of the zinc photochemical catalyst for environmental contaminants degradation has got more and more people's extensive concerning, and in some basic research and application Research aspect obtains many significant achievements.But for photocatalyst of zinc oxide there is also deficiency, being mainly manifested in it is a kind of broadband Gap semiconductor material, and Carrier recombination rate is high, quantum efficiency is low, and it is unstable under some extreme conditions, vulnerable to environmental factor And cause efficiency lower.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of preparation method of alumina-silica zinc composite catalyzing material, It is able to solve problems of the prior art.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation methods of alumina-silica zinc composite catalyzing material, existing to overcome There is the deficiency in technology.
To achieve the above object, the present invention provides the following technical solutions:
A kind of preparation method of alumina-silica zinc composite catalyzing material, including:
(1) aluminum nitrate solution is mixed with excessive urea liquid, quickly stir 5 under 50~60 DEG C of water bath conditions~ 10h, wherein mixing speed is 1200~1600r/min, obtains aluminum hydroxide sol;
(2) a certain amount of zinc solution is added into above-mentioned aluminum hydroxide sol, is uniformly mixed, in 70~80 DEG C of water 1.5~3h is kept the temperature under the conditions of bath, is increased bath temperature to 85~95 DEG C, is kept the temperature 4~5h, it is mixed to obtain aluminium hydroxide-zinc hydroxide Close colloidal sol;
(3) above-mentioned aluminium hydroxide-zinc hydroxide mixed sols is cooled to room temperature, is filtered by vacuum, uses dehydrated alcohol respectively It is washed 3~5 times with deionized water, it is dry, 2~3h is calcined under the conditions of 380~450 DEG C, obtains that alumina-silica zinc is compound to urge Change material.
Preferably, in step (1), the ratio between amount of the aluminum nitrate solution and the urea liquid substance is 1:10~15.
Preferably, the ratio between amount of the aluminum nitrate solution and the urea liquid substance is 1:10~12.
Preferably, in step (2), aluminium hydroxide and zinc hydroxide in the aluminium hydroxide-zinc hydroxide mixed sols The ratio between the amount of substance be 1:1~10.
Preferably, the amount of the substance of the aluminium hydroxide in the aluminium hydroxide-zinc hydroxide mixed sols and zinc hydroxide The ratio between be 1:1~5.
Preferably, in step (2), the zinc salt is zinc nitrate hexahydrate.
Compared with the prior art, the advantages of the present invention are as follows:Alumina-silica zinc composite catalyzing material tool in the present invention There is preferable stability, preparation method is simple, environmentally protective.
Specific embodiment
The present invention is described further by the following example:According to following embodiments, the present invention may be better understood. However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of preparation method of alumina-silica zinc composite catalyzing material, including:
(1) aluminum nitrate solution is mixed with excessive urea liquid, quickly stir 5 under 50~60 DEG C of water bath conditions~ 10h, wherein mixing speed is 1200~1600r/min, obtains aluminum hydroxide sol;
(2) a certain amount of zinc solution is added into above-mentioned aluminum hydroxide sol, is uniformly mixed, in 70~80 DEG C of water 1.5~3h is kept the temperature under the conditions of bath, is increased bath temperature to 85~95 DEG C, is kept the temperature 4~5h, it is mixed to obtain aluminium hydroxide-zinc hydroxide Close colloidal sol;
(3) above-mentioned aluminium hydroxide-zinc hydroxide mixed sols is cooled to room temperature, is filtered by vacuum, uses dehydrated alcohol respectively It is washed 3~5 times with deionized water, it is dry, 2~3h is calcined under the conditions of 380~450 DEG C, obtains that alumina-silica zinc is compound to urge Change material.
In step (1), the ratio between amount of the aluminum nitrate solution and the urea liquid substance is 1:10~15, it is preferred that The ratio between amount of the aluminum nitrate solution and the urea liquid substance is 1:10~12, it is further preferred that the aluminum nitrate is molten The ratio between amount of liquid and the urea liquid substance is 1:11.
In step (2), the substance of aluminium hydroxide and zinc hydroxide in the aluminium hydroxide-zinc hydroxide mixed sols The ratio between amount is 1:1~10, it is preferred that aluminium hydroxide and zinc hydroxide in the aluminium hydroxide-zinc hydroxide mixed sols The ratio between amount of substance is 1:1~5, it is further preferred that aluminium hydroxide in the aluminium hydroxide-zinc hydroxide mixed sols and The ratio between amount of substance of zinc hydroxide is 1:3;The zinc salt is zinc nitrate hexahydrate.
Following preparation sides that alumina-silica zinc composite catalyzing material in the present invention is illustrated with specifically embodiment Method.
Embodiment 1
It (1) is 1 by the ratio between amount of substance:11 aluminum nitrate solution is mixed with excessive urea liquid, in 55 DEG C of water-bath items 8h is quickly stirred under part, wherein mixing speed 1500r/min obtains aluminum hydroxide sol;
(2) a certain amount of zinc nitrate hexahydrate solution is added into above-mentioned aluminum hydroxide sol, is uniformly mixed, in 75 2.5h is kept the temperature under DEG C water bath condition, bath temperature is increased to 90 DEG C, keeps the temperature 4.5h, and it is molten to obtain aluminium hydroxide-zinc hydroxide mixing Glue, wherein the ratio between amount of substance of aluminium hydroxide and zinc hydroxide in the aluminium hydroxide-zinc hydroxide mixed sols is 1: 3;
(3) above-mentioned aluminium hydroxide-zinc hydroxide mixed sols is cooled to room temperature, is filtered by vacuum, uses dehydrated alcohol respectively It is washed 3~5 times with deionized water, it is dry, 2.5h is calcined under the conditions of 420 DEG C, obtains alumina-silica zinc composite catalyzing material Material.
Alumina-silica zinc composite catalyzing material made from method in the present invention, zinc oxide nano-particle can be uniform Ground is dispersed in the surface of aluminium oxide, has preferable stability, and the preparation method is simple, environmentally protective, has and preferably answers Use prospect.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that include a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (6)

1. a kind of preparation method of alumina-silica zinc composite catalyzing material, which is characterized in that including:
(1) aluminum nitrate solution is mixed with excessive urea liquid, quickly stirs 5~10h under 50~60 DEG C of water bath conditions, In, mixing speed is 1200~1600r/min, obtains aluminum hydroxide sol;
(2) a certain amount of zinc solution is added into above-mentioned aluminum hydroxide sol, is uniformly mixed, in 70~80 DEG C of water-bath items 1.5~3h is kept the temperature under part, bath temperature is increased to 85~95 DEG C, keeps the temperature 4~5h, and it is molten to obtain aluminium hydroxide-zinc hydroxide mixing Glue;
(3) above-mentioned aluminium hydroxide-zinc hydroxide mixed sols is cooled to room temperature, is filtered by vacuum, respectively with dehydrated alcohol and going It is ion water washing 3~5 times, dry, 2~3h is calcined under the conditions of 380~450 DEG C, obtains alumina-silica zinc composite catalyzing material Material.
2. the preparation method of alumina-silica zinc composite catalyzing material according to claim 1, which is characterized in that step (1) in, the ratio between amount of the aluminum nitrate solution and the urea liquid substance is 1:10~15.
3. the preparation method of alumina-silica zinc composite catalyzing material according to claim 2, which is characterized in that described The ratio between amount of aluminum nitrate solution and the urea liquid substance is 1:10~12.
4. the preparation method of alumina-silica zinc composite catalyzing material according to claim 1, which is characterized in that step (2) in, the ratio between amount of substance of aluminium hydroxide and zinc hydroxide in the aluminium hydroxide-zinc hydroxide mixed sols is 1:1 ~10.
5. the preparation method of alumina-silica zinc composite catalyzing material according to claim 4, which is characterized in that described The ratio between amount of substance of aluminium hydroxide and zinc hydroxide in aluminium hydroxide-zinc hydroxide mixed sols is 1:1~5.
6. the preparation method of alumina-silica zinc composite catalyzing material according to claim 1, which is characterized in that step (2) in, the zinc salt is zinc nitrate hexahydrate.
CN201810799502.3A 2018-07-19 2018-07-19 A kind of preparation method of alumina-silica zinc composite catalyzing material Withdrawn CN108855037A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108855043A (en) * 2018-07-19 2018-11-23 刘青 A kind of preparation method of alumina fibre-bismuth oxide composite catalyst
CN115467047A (en) * 2022-09-09 2022-12-13 南通大学 Preparation method of efficient antibacterial photocatalytic continuous alumina fiber

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CN101927158A (en) * 2010-07-12 2010-12-29 中国日用化学工业研究院 Preparation method of nano ZnO/gamma-Al2O3 composite photocatalyst
CN102451768A (en) * 2010-10-15 2012-05-16 中国石油化工股份有限公司 Method for preparing zirconia-alumina composite oxide xerogel
CN102616829A (en) * 2012-04-17 2012-08-01 吉林大学 Production method for aluminum-doped zinc oxide nanometer material
CN103395826A (en) * 2013-08-06 2013-11-20 大连交通大学 Preparation method of aluminum doped zinc oxide nano powder

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CN101927158A (en) * 2010-07-12 2010-12-29 中国日用化学工业研究院 Preparation method of nano ZnO/gamma-Al2O3 composite photocatalyst
CN102451768A (en) * 2010-10-15 2012-05-16 中国石油化工股份有限公司 Method for preparing zirconia-alumina composite oxide xerogel
CN102616829A (en) * 2012-04-17 2012-08-01 吉林大学 Production method for aluminum-doped zinc oxide nanometer material
CN103395826A (en) * 2013-08-06 2013-11-20 大连交通大学 Preparation method of aluminum doped zinc oxide nano powder

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108855043A (en) * 2018-07-19 2018-11-23 刘青 A kind of preparation method of alumina fibre-bismuth oxide composite catalyst
CN115467047A (en) * 2022-09-09 2022-12-13 南通大学 Preparation method of efficient antibacterial photocatalytic continuous alumina fiber
CN115467047B (en) * 2022-09-09 2023-10-03 南通大学 Preparation method of high-efficiency antibacterial photocatalytic continuous alumina fiber

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Application publication date: 20181123