CN108851291A - A kind of Anti-splashing sanitary dipped gloves and its preparation process - Google Patents
A kind of Anti-splashing sanitary dipped gloves and its preparation process Download PDFInfo
- Publication number
- CN108851291A CN108851291A CN201810758821.XA CN201810758821A CN108851291A CN 108851291 A CN108851291 A CN 108851291A CN 201810758821 A CN201810758821 A CN 201810758821A CN 108851291 A CN108851291 A CN 108851291A
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- Prior art keywords
- gloves
- dipped
- liner
- dipped gloves
- splashing sanitary
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
- C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Gloves (AREA)
Abstract
The invention discloses a kind of Anti-splashing sanitary dipped gloves and its preparation processes, belong to dipped gloves technical field, Anti-splashing sanitary dipped gloves include gloves liner, the centre of the palm side of the gloves liner is equipped with rubber shoe latex layer, the whole outside of dipped gloves is equipped with waterproof membrane, the waterproof membrane is perfluoroalkyl acrylic ethyl ester waterproof membrane, and specific preparation process includes：(1) prepared by water repellent solution：Waterproofing agent perfluor alkyl ethyl acrylate is diluted with water, is then adjusted with acid pH, obtains water repellent solution；(2) gloves liner is formed into rubber shoe latex layer in the centre of the palm side of gloves liner by impregnation mode and obtains dipped gloves, dipped gloves are immersed in above-mentioned water repellent solution；(3) above-mentioned gloves are dried.By handling dipped gloves surface, the effect of moment Anti-splashing sanitary can reach, and gloves permeability is good.
Description
Technical field
The present invention relates to dipped gloves technical fields, and in particular to a kind of Anti-splashing sanitary dipped gloves and its preparation process.
Background technique
Dipped gloves are also known as latex glove, are one of gloves, it is different from the gloves of general disposable unlined,
It is process by woven lining and latex coating, is indispensable hand protection articles, in industrial and agricultural production, medical treatment, daily life
In suffer from and be widely applied.
Common dipped gloves have preferable gas permeability, but poor waterproof properties, and waterproofing agent can assign glove surface with thin
Aqueous energy, by forming one or more layers waterproof membrane in glove surface, can not only improve the appearance of gloves, moreover it is possible to have gloves
Certain waterproof performance.Currently on the market waterproofing agent used there are problems that it is difficult to degrade, have biological accumulation toxicity, using ecology
Degradable waterproofing agent is future developing trend.
Summary of the invention
The present invention provides a kind of Anti-splashing sanitary dipped gloves and its preparation process, by handling dipped gloves surface,
It can reach the effect of moment Anti-splashing sanitary, and gloves permeability is good.
To achieve the above object, the present invention uses following technical scheme：
The centre of the palm side of a kind of Anti-splashing sanitary dipped gloves, including gloves liner, the gloves liner is equipped with rubber shoe latex layer, impregnation
The whole outside of gloves is equipped with waterproof membrane, and the waterproof membrane is perfluoroalkyl acrylic ethyl ester waterproof membrane.
Preferably, the rubber shoe latex layer is Heveatex, NBR latex, polyurethane rubber latex, any one in PVC latex.
Preferably, the gloves liner is any one in the mixed goods of pure cotton fabric, chemical & blended fabric, cotton thread and chemical fibre
Kind.
Preferably, the rubber shoe latex layer is arranged on the centre of the palm side of the gloves liner by impregnation mode.
Preferably, the outside of the dipped gloves entirety is arranged in by immersion way for the waterproof membrane.
The present invention also provides a kind of preparation processes of Anti-splashing sanitary dipped gloves, include the following steps：
(1) prepared by water repellent solution：Waterproofing agent perfluor alkyl ethyl acrylate is diluted with water, is then adjusted with acid pH,
Obtain water repellent solution；
(2) gloves liner is formed into rubber shoe latex layer in the centre of the palm side of gloves liner by impregnation mode and obtains dipped gloves,
Then dipped gloves are immersed in above-mentioned water repellent solution；
(3) above-mentioned gloves are dried.
Preferably, after being diluted with water in the step (1), the mass fraction of perfluoroalkyl acrylic ethyl ester in water is 6-
8%.
It preferably, is 5.5-6.0 with vinegar acid for adjusting pH in the step (1).
Preferably, soaking time > 30min in the step (2).
Preferably, in the step (3), gloves are dried in an oven, and drying is divided into two parts, first part's drying temperature
130 DEG C -140 DEG C, drying time 5min-8min, 95 DEG C -105 DEG C of second part drying temperature, drying time 65min-80min.
Wherein, the performance indicator of perfluor alkyl ethyl acrylate：Milky white liquid, density at 100 DEG C of boiling point, 20 DEG C
1.05-1.10g/cm3, soluble easily in water, pH is 4-7 (1% aqueous solution) at 20 DEG C.
Advantageous effects of the invention are：
Using waterproofing agent perfluoroalkyl acrylic ethyl ester, film forming is sprawled in glove surface, stable polymer is formed, can hinder
The entrance of water blocking, reaches waterproof effect；Waterproofing agent perfluoroalkyl acrylic ethyl ester is six waterproofing agent of carbon, and strand is relatively short,
Harmful substance PFOS and PFOA will not be generated in production application, the decomposition time limit is short, does not influence on environment；Equipped in gloves
Gallbladder is directly contacted with hand skin, also guarantees gas permeability while reaching waterproof effect, has good comfort.
Specific embodiment
The present invention is further explained in the light of specific embodiments.
Embodiment 1
The centre of the palm side of a kind of Anti-splashing sanitary dipped gloves, including gloves liner, the gloves liner is equipped with rubber shoe latex layer, impregnation
The whole outside of gloves is equipped with waterproof membrane, and the waterproof membrane is perfluoroalkyl acrylic ethyl ester waterproof membrane.
The rubber shoe latex layer is natural emulsion.The gloves liner is polyamide fibre yarn fabric.The rubber shoe latex layer passes through impregnation side
The centre of the palm part of the gloves liner is arranged in formula.The entirety of the dipped gloves is arranged in by immersion way for the waterproof membrane
Outside.
The preparation process of above-mentioned Anti-splashing sanitary dipped gloves, specifically includes following steps：
(1) prepared by water repellent solution：Waterproofing agent perfluor alkyl ethyl acrylate is diluted with water, makes perfluoroalkyl acrylic
The mass fraction of ethyl ester in water is 6%, is then 5.5 with vinegar acid for adjusting pH, obtains water repellent solution；
(2) gloves liner is formed into rubber shoe latex layer in the centre of the palm side of gloves liner by impregnation mode and obtains dipped gloves,
Dipped gloves are immersed in above-mentioned water repellent solution, soaking time 35min；
(3) above-mentioned gloves to be dried in an oven, drying is divided into two parts, and 130 DEG C of first part's drying temperature, drying time
5min, 95 DEG C of second part drying temperature, drying time 65min.
Comparative example 1：
This comparative example is the comparative example of embodiment 1, which includes gloves liner, and the centre of the palm side of gloves liner is set
Have rubber shoe latex layer, the whole outside of the dipped gloves is not provided with waterproof membrane, i.e., only by gloves liner by impregnation mode in gloves
The centre of the palm side of gallbladder forms rubber shoe latex layer, without impregnating the processing of water repellent solution.
The waterproof performance of dipped gloves obtained in above-described embodiment 1 and comparative example 1 is detected, water is sprayed onto leaching
Rubber gloves are observed, and the dipped gloves in comparative example 1, water penetrates into inside gloves quickly, and the dipped gloves in embodiment 1, water exist
Glove surface forms droplet and flows down, and does not penetrate into inside gloves, plays the effect of moment Anti-splashing sanitary.
Embodiment 2
The centre of the palm side of a kind of Anti-splashing sanitary dipped gloves, including gloves liner, the gloves liner is equipped with rubber shoe latex layer, impregnation
The whole outside of gloves is equipped with waterproof membrane, and the waterproof membrane is perfluoroalkyl acrylic ethyl ester waterproof membrane.
The rubber shoe latex layer is NBR latex.The gloves liner is polyamide fibre yarn fabric.The rubber shoe latex layer passes through impregnation side
The centre of the palm part of the gloves liner is arranged in formula.The entirety of the dipped gloves is arranged in by immersion way for the waterproof membrane
Outside.
The preparation process of above-mentioned Anti-splashing sanitary dipped gloves, specifically includes following steps：
(1) prepared by water repellent solution：Waterproofing agent perfluor alkyl ethyl acrylate is diluted with water, makes perfluoroalkyl acrylic
The mass fraction of ethyl ester in water is 8%, is then 6.0 with vinegar acid for adjusting pH, obtains water repellent solution；
(2) gloves liner is formed into rubber shoe latex layer in the centre of the palm side of gloves liner by impregnation mode and obtains dipped gloves,
Dipped gloves are immersed in above-mentioned water repellent solution, soaking time 35min；
(3) above-mentioned gloves to be dried in an oven, baking oven is divided into two parts, and 130 DEG C of first part's drying temperature, drying time
5min, 95 DEG C of second part drying temperature, drying time 65min.
Comparative example 2：
This comparative example is the comparative example of embodiment 2, which includes gloves liner, and the centre of the palm side of gloves liner is set
Have rubber shoe latex layer, the whole outside of the dipped gloves is not provided with waterproof membrane, i.e., only by gloves liner by impregnation mode in gloves
The centre of the palm side of gallbladder forms rubber shoe latex layer, without impregnating the processing of water repellent solution.
The waterproof performance of dipped gloves obtained in above-described embodiment 2 and comparative example 2 is detected, water is sprayed onto leaching
Rubber gloves are observed, and the dipped gloves in comparative example 2, water penetrates into inside gloves quickly, and the dipped gloves in embodiment 2, water exist
Glove surface forms droplet and flows down, and does not penetrate into inside gloves, plays the effect of moment Anti-splashing sanitary.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in skill of the invention
On the basis of art scheme, the various modifications or variations that can be made by those skilled in the art with little creative work still exists
In protection scope of the present invention.
Claims (9)
1. a kind of Anti-splashing sanitary dipped gloves, which is characterized in that including gloves liner, the centre of the palm side of the gloves liner is equipped with leaching
Glue-line, the whole outside of dipped gloves are equipped with waterproof membrane, and the waterproof membrane is perfluoroalkyl acrylic ethyl ester waterproof membrane.
2. a kind of Anti-splashing sanitary dipped gloves according to claim 1, which is characterized in that the rubber shoe latex layer be Heveatex,
NBR latex, polyurethane rubber latex, any one in PVC latex.
3. a kind of Anti-splashing sanitary dipped gloves according to claim 1, which is characterized in that the rubber shoe latex layer passes through impregnation mode
It is arranged on the centre of the palm side of the gloves liner.
4. a kind of Anti-splashing sanitary dipped gloves according to claim 1, which is characterized in that the waterproof membrane passes through immersion way
The outside of the dipped gloves entirety is set.
5. a kind of described in any item preparation processes of Anti-splashing sanitary dipped gloves of claim 1-4, which is characterized in that including following
Step：
(1) prepared by water repellent solution：Waterproofing agent perfluor alkyl ethyl acrylate is diluted with water, is then adjusted with acid pH, obtains
Water repellent solution；
(2) gloves liner is formed into rubber shoe latex layer in the centre of the palm side of gloves liner by impregnation mode and obtains dipped gloves, will soaked
Rubber gloves are immersed in above-mentioned water repellent solution；
(3) above-mentioned gloves are dried.
6. a kind of preparation process of Anti-splashing sanitary dipped gloves according to claim 5, which is characterized in that the step (1)
In be diluted with water after, the mass fraction of perfluoroalkyl acrylic ethyl ester in water be 6-8%.
7. a kind of preparation process of Anti-splashing sanitary dipped gloves according to claim 5, which is characterized in that the step (1)
Middle with vinegar acid for adjusting pH is 5.5-6.0.
8. a kind of preparation process of Anti-splashing sanitary dipped gloves according to claim 5, which is characterized in that the step (2)
Middle soaking time > 30min.
9. a kind of preparation process of Anti-splashing sanitary dipped gloves according to claim 5, which is characterized in that the step (3)
In, gloves are dried in an oven, and drying is divided into two parts, and 130 DEG C -140 DEG C of first part's drying temperature, drying time 5min-
8min, 95 DEG C -105 DEG C of second part drying temperature, drying time 65min-80min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810758821.XA CN108851291A (en) | 2018-07-11 | 2018-07-11 | A kind of Anti-splashing sanitary dipped gloves and its preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810758821.XA CN108851291A (en) | 2018-07-11 | 2018-07-11 | A kind of Anti-splashing sanitary dipped gloves and its preparation process |
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| Publication Number | Publication Date |
|---|---|
| CN108851291A true CN108851291A (en) | 2018-11-23 |
Family
ID=64301173
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| CN201810758821.XA Pending CN108851291A (en) | 2018-07-11 | 2018-07-11 | A kind of Anti-splashing sanitary dipped gloves and its preparation process |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143137A (en) * | 2020-09-29 | 2020-12-29 | 江苏顶洁医疗器械有限公司 | Environment-friendly degradable PVC gloves and production process thereof |
Citations (8)
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|---|---|---|---|---|
| CN2414637Y (en) * | 2000-03-23 | 2001-01-17 | 金启先 | Protection gloves |
| CN101945592A (en) * | 2008-02-15 | 2011-01-12 | 株式会社东和公司 | Glove and process for producing the same |
| CN101956330A (en) * | 2010-08-12 | 2011-01-26 | 吴江市恒润织造厂 | Method for preparing waterproof and moisture-permeable composite cloth |
| CN102797166A (en) * | 2012-09-05 | 2012-11-28 | 上海华峰超纤材料股份有限公司 | Water-repellent oil-repellent superfine fiber synthetic leather and preparation method thereof |
| CN103524346A (en) * | 2013-10-22 | 2014-01-22 | 太仓中化环保化工有限公司 | Method for synthesizing perfluoroalkylethyl acrylate |
| CN203538436U (en) * | 2013-06-21 | 2014-04-16 | 上海世目防护用品有限公司 | Total latex-immersed protective gloves with needle loop napped liner |
| CN104233807A (en) * | 2014-09-17 | 2014-12-24 | 王东生 | Low-temperature water-based waterproof agent and production technology thereof |
| CN106175018A (en) * | 2016-07-08 | 2016-12-07 | 华南理工大学 | A kind of degradable disponsable hair care towel and preparation method thereof |
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2018
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Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2414637Y (en) * | 2000-03-23 | 2001-01-17 | 金启先 | Protection gloves |
| CN101945592A (en) * | 2008-02-15 | 2011-01-12 | 株式会社东和公司 | Glove and process for producing the same |
| CN101956330A (en) * | 2010-08-12 | 2011-01-26 | 吴江市恒润织造厂 | Method for preparing waterproof and moisture-permeable composite cloth |
| CN102797166A (en) * | 2012-09-05 | 2012-11-28 | 上海华峰超纤材料股份有限公司 | Water-repellent oil-repellent superfine fiber synthetic leather and preparation method thereof |
| CN203538436U (en) * | 2013-06-21 | 2014-04-16 | 上海世目防护用品有限公司 | Total latex-immersed protective gloves with needle loop napped liner |
| CN103524346A (en) * | 2013-10-22 | 2014-01-22 | 太仓中化环保化工有限公司 | Method for synthesizing perfluoroalkylethyl acrylate |
| CN104233807A (en) * | 2014-09-17 | 2014-12-24 | 王东生 | Low-temperature water-based waterproof agent and production technology thereof |
| CN106175018A (en) * | 2016-07-08 | 2016-12-07 | 华南理工大学 | A kind of degradable disponsable hair care towel and preparation method thereof |
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| 刘建平: "《染整助剂》", 30 June 2009, 东华大学出版社 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143137A (en) * | 2020-09-29 | 2020-12-29 | 江苏顶洁医疗器械有限公司 | Environment-friendly degradable PVC gloves and production process thereof |
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Application publication date: 20181123 |