CN108841464A - A kind of preparation method of vegetable residual pesticide cleanser - Google Patents
A kind of preparation method of vegetable residual pesticide cleanser Download PDFInfo
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- CN108841464A CN108841464A CN201810478982.3A CN201810478982A CN108841464A CN 108841464 A CN108841464 A CN 108841464A CN 201810478982 A CN201810478982 A CN 201810478982A CN 108841464 A CN108841464 A CN 108841464A
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- cleanser
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/14—Silicates
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of preparation methods of vegetable residual pesticide cleanser, belong to cleanser technical field.Technical solution of the present invention uses plant ash and heavy salinized leaches material as raw material, high alkalinity environment is provided by leachate, since plant ash main component is potassium oxide, by being dispersed and under alkaline environment, under the action of metal ion, it decomposes organophosphorus pesticide effectively and forms phosphoric acid species and alcohols material, effectively decompose and remove vegetables and fruits farm chemical ingredients remained on surface；Technical solution of the present invention also uses hydrogen peroxide and silica solution to be used in combination, since hydrogen peroxide has efficient oxidation susceptibility, it can be effectively with organophosphorus pesticide oxidation reaction and degrading organic phosphor pesticides remain, simultaneously, technical solution of the present invention uses coagulant liquid as load carriers, cleanser ingredient is effectively improved in the adhesion property and adsorption effect on vegetables and fruits surface, plays higher absorption property and higher degradation effect.
Description
Technical field
The present invention relates to a kind of preparation methods of vegetable residual pesticide cleanser, belong to cleanser technical field.
Background technique
The living standard of people is improved constantly, therefore increasingly pays attention to environmental protection and food-safety problem.In these problems
In with people it is closest be exactly the exceeded problem of remains of pesticide amount in agricultural product, the exceeded problem of remains of pesticide amount is direct
Affect the health of people.Therefore many scholars of recent domestic utilize ozone degradation method, microbial degradation method, work
Property enzyme disintoxication, ultrasound involve the different method such as ultraviolet light the remains of pesticide problem in agricultural product studied.But
These methods are inconvenient to use, and cost is also relatively high.Mainly use clear water or detergent in people's daily life at present
The methods of washing by soaking vegetables, the former cannot completely remove remains of pesticide, and inherently a kind of chemicals of the latter, also can be right
Human health affects.Therefore a kind of easy to operate, nonhazardous, removal vegetable residual pesticide at low cost are studied
Method has great meaning to people's health.
Vegetable residual pesticide not only seriously affects human health, but also influences agricultural development and international trade.Many pesticides
The generation of accident, such as drops in production over a large area, and is all to have seriously affected agricultural development because unreasonable using pesticide.Due to WTO/SPS
Agreement joined the detection of the persticide residue of vegetables and become developed country's control technical barrier to trade, become
One of the means of developed country's control trade.China is the big country of an export of farm produce, and at this stage for the agriculture in vegetables
Medicine residual quantity control means be not also it is as sound as a bell, be restricted in exit procedure so causing many agricultural product, very
The limit amount that more persticide residues cannot reach international is horizontal, and very big shadow is also caused to the International Agricultural Trade in China
It rings.
The washing methods of vegetable pesticide residue has very much, has physical method, chemical method and microbial degradation by chemical property point
The fairly simple some sides of storage, originally washing, boiling water boiling, peeling etc. are commonly used in method three categories, people in daily life
Method.There are also some methods that can remove vegetable residual pesticide, such as salt and vinegar are added in water or uses detergent, furthermore
Vegetable residual pesticide can also be removed there are also some instruments.It is directed to different vegetable varieties in these methods, washing vegetables are residual
The method for staying pesticide is also different, and if decortication method is not suitable for leaf vegetables, only applicable use can be with long-term storage for storage method
Vegetables etc..
Summary of the invention
The technical problems to be solved by the invention：For the problem that existing cleanser absorption property is poor, one kind is provided
The preparation method of vegetable residual pesticide cleanser.
In order to solve the above technical problems, the technical solution adopted by the present invention is that：
A kind of preparation method of vegetable residual pesticide cleanser, specific preparation step are：
（1）It takes heavy salinized ground soil and grinds, pulverized particles of being sieved to obtain take plant ash and in mass ratio 1：1, by vegetation
Ash is stirred and regrinds with pulverized particles, is sieved and collects sieving powder；
（2）In mass ratio 1：10, sieving powder and deionized water are stirred and heating water bath, standing, centrifugation are collected respectively
Supernatant liquor and lower sediment must leach modification liquid and sediment respectively, and sediment vacuum freeze drying is obtained dried object；
（3）It takes triangle pearl freshwater mussel clam shell and is crushed to obtain clam shell particle, in mass ratio 1：1, dried object and clam shell particle are stirred mixed
After be placed in grinding distribution in mortar, collect disperse materials and be placed in crucible, preheating, heating heating, heat preservation calcining stands
It is cooled to room temperature, is ground up, sieved, obtain calcined powder；
（4）In mass ratio 1：10, calcined powder is added in deionized water, 1~2h is stirred and stands, filters and collects
Filter cake, after dry, standing is cooled to room temperature, and obtains calcining modified materials；
（5）According to parts by weight, 45~50 parts of leaching modification liquids, 15~20 parts of silica solution, 15~20 parts of peroxidating are weighed respectively
Hydrogen solution and 10~15 parts of calcining modified materials are placed in a beaker, and are stirred to obtain coagulant liquid, and it is residual can be prepared into the vegetables
Stay pesticide cleanser.
Step（3）The calcined temperature is 100~110 DEG C.
Step（3）The heating, which is heated to be, is warming up to 950~1000 DEG C by 8 DEG C/min.
Step（5）The silica solution is the silica solution that Baume degrees is 15.
The present invention is compared with other methods, and advantageous effects are：
（1）Technical solution of the present invention use plant ash and it is heavy salinized leach material as raw material, provided by leachate high-alkali
Property environment, due to plant ash main component be potassium oxide, by being dispersed and under alkaline environment, the effect through metal ion
Under, it decomposes organophosphorus pesticide effectively and forms phosphoric acid species and alcohols material, effectively decompose and remove vegetables and fruits remained on surface
Farm chemical ingredients；
（2）Technical solution of the present invention also uses hydrogen peroxide and silica solution to be used in combination, since hydrogen peroxide has efficient oxygen
Change performance, can effectively with organophosphorus pesticide oxidation reaction and degrading organic phosphor pesticides remain, meanwhile, technical solution of the present invention uses
Coagulant liquid effectively improves cleanser ingredient in the adhesion property and adsorption effect on vegetables and fruits surface, plays as load carriers
Higher absorption property and higher degradation effect.
Specific embodiment
It takes heavy salinized ground soil and grinds, cross 200 meshes and obtain pulverized particles, take plant ash and in mass ratio 1：1,
Plant ash and pulverized particles are stirred and are regrind 2~3h, cross 500 meshes and collects sieving powder, in mass ratio 1：
10, sieving powder and deionized water are stirred and are placed in 25~30min of heating water bath at 25~30 DEG C, stands 10~12h,
Be centrifugated at 2500~3000r/min again and collect supernatant liquor and lower sediment respectively, must leach respectively modification liquid with
Sediment vacuum freeze drying is obtained dried object by sediment；It takes triangle pearl freshwater mussel clam shell and cleans and dry, be crushed to obtain clam shell
Grain, then in mass ratio 1：1, it is placed in grinding distribution in mortar after dried object and the stirring of clam shell particle are mixed, collects disperse materials simultaneously
It is placed in crucible, crucible is placed in 25~30min of pre-burning in 100~110 DEG C of Muffle furnaces, obtain pre-burning object and heat up by 8 DEG C/min
To 950~1000 DEG C, heat preservation 2~3h of calcining, standing is cooled to room temperature, and ground 200 mesh obtains calcined powder, in mass ratio
1：10, calcined powder is added in deionized water, 1~2h is stirred and stands, filters and collects filter cake, filter cake is placed in
It dries at 100~110 DEG C to constant weight, standing is cooled to room temperature, and obtains calcining modified materials；According to parts by weight, 45 are weighed respectively
~50 parts are leached modification liquid, the silica solution that 15~20 parts of Baume degrees are 15,15~20 parts of 30% hydrogenperoxide steam generators of mass fraction
It is placed in a beaker with 10~15 parts of calcining modified materials, then is stirred to obtain coagulant liquid at 45~55 DEG C, can be prepared into described
Vegetable residual pesticide cleanser.
Example 1
It takes heavy salinized ground soil and grinds, cross 200 meshes and obtain pulverized particles, take plant ash and in mass ratio 1：1, it will be careless
Wood ash and pulverized particles are stirred and regrind 2h, cross 500 meshes and collect sieving powder, in mass ratio 1：10, incited somebody to action
Sieve powder and deionized water, which are stirred, is placed in heating water bath 25min at 25 DEG C, stands 10h, then be centrifuged at 2500r/min
It separates and collects supernatant liquor and lower sediment respectively, modification liquid and sediment must be leached respectively, sediment vacuum refrigeration is done
It is dry to obtain dried object；It takes triangle pearl freshwater mussel clam shell and cleans and dry, be crushed to obtain clam shell particle, then in mass ratio 1：1, by dried object with
It is placed in grinding distribution in mortar after the stirring of clam shell particle is mixed, disperse materials is collected and is placed in crucible, crucible is placed in 100 DEG C of horses
Not pre-burning 25min in furnace obtains pre-burning object and is warming up to 950 DEG C by 8 DEG C/min, and heat preservation calcining 2h, standing is cooled to room temperature, grinds
200 meshes are crossed, calcined powder, in mass ratio 1 are obtained：10, calcined powder is added in deionized water, is stirred and stands
1h filters and collects filter cake, and filter cake is placed at 100 DEG C and is dried to constant weight, standing is cooled to room temperature, and obtains calcining modified materials；
According to parts by weight, 45 parts are weighed respectively leaches modification liquid, the silica solution that 15 parts of Baume degrees are 15,15 parts of 30% mistakes of mass fraction
Hydrogen peroxide solution and 10 parts of calcining modified materials are placed in a beaker, then coagulant liquid is stirred to obtain at 45 DEG C, can be prepared into institute
The vegetable residual pesticide cleanser stated.
Example 2
It takes heavy salinized ground soil and grinds, cross 200 meshes and obtain pulverized particles, take plant ash and in mass ratio 1：1, it will be careless
Wood ash and pulverized particles are stirred and regrind 2h, cross 500 meshes and collect sieving powder, in mass ratio 1：10, incited somebody to action
Sieve powder and deionized water, which are stirred, is placed in heating water bath 28min at 28 DEG C, stands 11h, then be centrifuged at 2800r/min
It separates and collects supernatant liquor and lower sediment respectively, modification liquid and sediment must be leached respectively, sediment vacuum refrigeration is done
It is dry to obtain dried object；It takes triangle pearl freshwater mussel clam shell and cleans and dry, be crushed to obtain clam shell particle, then in mass ratio 1：1, by dried object with
It is placed in grinding distribution in mortar after the stirring of clam shell particle is mixed, disperse materials is collected and is placed in crucible, crucible is placed in 105 DEG C of horses
Not pre-burning 28min in furnace obtains pre-burning object and is warming up to 980 DEG C by 8 DEG C/min, and heat preservation calcining 2h, standing is cooled to room temperature, grinds
200 meshes are crossed, calcined powder, in mass ratio 1 are obtained：10, calcined powder is added in deionized water, is stirred and stands
1h filters and collects filter cake, and filter cake is placed at 105 DEG C and is dried to constant weight, standing is cooled to room temperature, and obtains calcining modified materials；
According to parts by weight, 48 parts are weighed respectively leaches modification liquid, the silica solution that 18 parts of Baume degrees are 15,18 parts of 30% mistakes of mass fraction
Hydrogen peroxide solution and 13 parts of calcining modified materials are placed in a beaker, then coagulant liquid is stirred to obtain at 50 DEG C, can be prepared into institute
The vegetable residual pesticide cleanser stated.
Example 3
It takes heavy salinized ground soil and grinds, cross 200 meshes and obtain pulverized particles, take plant ash and in mass ratio 1：1, it will be careless
Wood ash and pulverized particles are stirred and regrind 3h, cross 500 meshes and collect sieving powder, in mass ratio 1：10, incited somebody to action
Sieve powder and deionized water, which are stirred, is placed in heating water bath 30min at 30 DEG C, stands 12h, then be centrifuged at 3000r/min
It separates and collects supernatant liquor and lower sediment respectively, modification liquid and sediment must be leached respectively, sediment vacuum refrigeration is done
It is dry to obtain dried object；It takes triangle pearl freshwater mussel clam shell and cleans and dry, be crushed to obtain clam shell particle, then in mass ratio 1：1, by dried object with
It is placed in grinding distribution in mortar after the stirring of clam shell particle is mixed, disperse materials is collected and is placed in crucible, crucible is placed in 110 DEG C of horses
Not pre-burning 30min in furnace obtains pre-burning object and is warming up to 1000 DEG C by 8 DEG C/min, and heat preservation calcining 3h, standing is cooled to room temperature, grinds
Honed 200 mesh, obtains calcined powder, in mass ratio 1：10, calcined powder is added in deionized water, is stirred and stands
2h filters and collects filter cake, and filter cake is placed at 110 DEG C and is dried to constant weight, standing is cooled to room temperature, and obtains calcining modified materials；
According to parts by weight, 50 parts are weighed respectively leaches modification liquid, the silica solution that 20 parts of Baume degrees are 15,20 parts of 30% mistakes of mass fraction
Hydrogen peroxide solution and 15 parts of calcining modified materials are placed in a beaker, then coagulant liquid is stirred to obtain at 55 DEG C, can be prepared into institute
The vegetable residual pesticide cleanser stated.
Reference examples：The vegetable residual pesticide cleanser of Shanghai company production.
The vegetable residual pesticide cleanser of example and reference examples is detected, specific detection is as follows：
Removal effect measurement：Experiment investigates the effect of detergent removal pesticide using pesticides removal rate as index.According to formula meter
Calculate pesticides removal rate.It is put into the experimental group vegetables of naturally dry in beaker, with cleanser, is washed, washs 5min,
1% NaOH solution 10mL is added in 25mL color-comparison tube in the accurate appropriate solution 10ml taken out in cleaning solution, vibrates water
1min is solved, sulfuric acid solution 0.3mL, the 0.1% liquor potassic permanganate 0.1mL of 3.75mol/L are then sequentially added, is mixed, with steaming
Distilled water is diluted to scale, and after placing 5min, using reagent blank as reference, spectrophotometer detection is carried out at 400nm.
Specific testing result such as table 1.
1 performance characterization contrast table of table
| Detection project | Example 1 | Example 2 | Example 3 | Reference examples |
| Remove pesticide concentration mg/kg | 1.529 | 1.527 | 1.521 | 1.118 |
| Removal rate % | 76.47 | 76.36 | 76.21 | 55.9 |
As shown in Table 1, cleanser removal rate prepared by the present invention is up to 76.47%, has good washing effect.
Claims (4)
1. a kind of preparation method of vegetable residual pesticide cleanser, it is characterised in that specifically preparation step is：
（1）It takes heavy salinized ground soil and grinds, pulverized particles of being sieved to obtain take plant ash and in mass ratio 1：1, by vegetation
Ash is stirred and regrinds with pulverized particles, is sieved and collects sieving powder；
（2）In mass ratio 1：10, sieving powder and deionized water are stirred and heating water bath, standing, centrifugation are collected respectively
Supernatant liquor and lower sediment must leach modification liquid and sediment respectively, and sediment vacuum freeze drying is obtained dried object；
（3）It takes triangle pearl freshwater mussel clam shell and is crushed to obtain clam shell particle, in mass ratio 1：1, dried object and clam shell particle are stirred mixed
After be placed in grinding distribution in mortar, collect disperse materials and be placed in crucible, preheating, heating heating, heat preservation calcining stands
It is cooled to room temperature, is ground up, sieved, obtain calcined powder；
（4）In mass ratio 1：10, calcined powder is added in deionized water, 1~2h is stirred and stands, filters and collects
Filter cake, after dry, standing is cooled to room temperature, and obtains calcining modified materials；
（5）According to parts by weight, 45~50 parts of leaching modification liquids, 15~20 parts of silica solution, 15~20 parts of peroxidating are weighed respectively
Hydrogen solution and 10~15 parts of calcining modified materials are placed in a beaker, and are stirred to obtain coagulant liquid, and it is residual can be prepared into the vegetables
Stay pesticide cleanser.
2. a kind of preparation method of vegetable residual pesticide cleanser according to claim 1, it is characterised in that：Step（3）
The calcined temperature is 100~110 DEG C.
3. a kind of preparation method of vegetable residual pesticide cleanser according to claim 1, it is characterised in that：Step（3）
The heating, which is heated to be, is warming up to 950~1000 DEG C by 8 DEG C/min.
4. a kind of preparation method of vegetable residual pesticide cleanser according to claim 1, it is characterised in that：Step（5）
The silica solution is the silica solution that Baume degrees is 15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810478982.3A CN108841464A (en) | 2018-05-18 | 2018-05-18 | A kind of preparation method of vegetable residual pesticide cleanser |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810478982.3A CN108841464A (en) | 2018-05-18 | 2018-05-18 | A kind of preparation method of vegetable residual pesticide cleanser |
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| CN108841464A true CN108841464A (en) | 2018-11-20 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5867796A (en) * | 1981-10-18 | 1983-04-22 | 竹嶋 亮 | Liquid detergent |
| CN1990850A (en) * | 2005-12-26 | 2007-07-04 | 谈嘉俊 | Pesticide remover |
| CN102198059A (en) * | 2011-04-29 | 2011-09-28 | 安徽师范大学 | Novel cleaning material |
| CN104164677A (en) * | 2014-07-31 | 2014-11-26 | 青岛华承天机械制造有限公司 | High-efficiency cleaning agent |
-
2018
- 2018-05-18 CN CN201810478982.3A patent/CN108841464A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5867796A (en) * | 1981-10-18 | 1983-04-22 | 竹嶋 亮 | Liquid detergent |
| CN1990850A (en) * | 2005-12-26 | 2007-07-04 | 谈嘉俊 | Pesticide remover |
| CN102198059A (en) * | 2011-04-29 | 2011-09-28 | 安徽师范大学 | Novel cleaning material |
| CN104164677A (en) * | 2014-07-31 | 2014-11-26 | 青岛华承天机械制造有限公司 | High-efficiency cleaning agent |
Non-Patent Citations (2)
| Title |
|---|
| 乔永祥等: "新鲜蔬菜清洗技术研究进展", 《包装工程》 * |
| 韩霁昌等: "《陕西卤泊滩盐碱地综合治理的和谐生态模式研究与实践》", 31 March 2009 * |
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Application publication date: 20181120 |