CN108840969A - 一种水性油墨树脂 - Google Patents

一种水性油墨树脂 Download PDF

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Publication number
CN108840969A
CN108840969A CN201810586333.5A CN201810586333A CN108840969A CN 108840969 A CN108840969 A CN 108840969A CN 201810586333 A CN201810586333 A CN 201810586333A CN 108840969 A CN108840969 A CN 108840969A
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Prior art keywords
mass parts
parts
water
mass
methyl
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CN201810586333.5A
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茅天宇
钟文军
陈杰
王译珩
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CHANGSHU GUOHE NEW MATERIALS Co Ltd
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CHANGSHU GUOHE NEW MATERIALS Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

本发明公开了一种水性油墨树脂，包括各组分按质量份计，包括丙烯酸甲酯25~45份、丙烯酸丁酯25~35份、六亚甲基二异氰酸酯10~12份、1,9‑壬二醇二(甲基)丙烯酸酯17~20质量份、N‑甲氧基甲基(甲基)丙烯酰胺15~25质量份、二苯基‑2,4,6‑三甲基苯甲酰7~11质量份、己二酸二酰肼2~3质量份、甲基丙烯酸丁酯5~7质量份、异丁基乙烯醚7~8质量份、谷氨酸二乙酸四钠1~3质量份、水100~120质量份。本发明一种水性油墨树脂有良好成膜性和流动性。

Description

一种水性油墨树脂
技术领域
本发明涉及一种水性油墨树脂。
背景技术
现有的水性油墨树脂存在着流动性和成膜性不能同时达到良好的问题，当流动性提高后会影响成膜性，故此，本申请为在流动性和成膜性之间找到平衡点，研发出一种兼具良好流动性和成膜性的水性油墨树脂。
发明内容
本发明的目的在于一种水性油墨树脂，旨在解决上述问题。
为了实现上述目的，本发明的技术方案是设计一种水性油墨树脂，各组分按质量份计，包括丙烯酸甲酯25~45份、丙烯酸丁酯25~35份、六亚甲基二异氰酸酯10~12份、1,9-壬二醇二(甲基)丙烯酸酯17~20质量份、N-甲氧基甲基(甲基)丙烯酰胺15~25质量份、二苯基-2,4,6-三甲基苯甲酰7~11质量份、己二酸二酰肼2~3质量份、甲基丙烯酸丁酯5~7质量份、异丁基乙烯醚7~8质量份、谷氨酸二乙酸四钠1~3质量份、水100~120质量份。
本发明的优点和有益效果在于：本发明一种水性油墨树脂有良好成膜性和流动性。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例：
一种水性油墨树脂，各组分按质量份计，包括丙烯酸甲酯25份、丙烯酸丁酯25份、六亚甲基二异氰酸酯10份、1,9-壬二醇二(甲基)丙烯酸酯17质量份、N-甲氧基甲基(甲基)丙烯酰胺15质量份、二苯基-2,4,6-三甲基苯甲酰7质量份、己二酸二酰肼2质量份、甲基丙烯酸丁酯5质量份、异丁基乙烯醚7质量份、谷氨酸二乙酸四钠1质量份、水100质量份。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (1)

1.一种水性油墨树脂，其特征在于：各组分按质量份计，包括丙烯酸甲酯25~45份、丙烯酸丁酯25~35份、六亚甲基二异氰酸酯10~12份、1,9-壬二醇二(甲基)丙烯酸酯17~20质量份、N-甲氧基甲基(甲基)丙烯酰胺15~25质量份、二苯基-2,4,6-三甲基苯甲酰7~11质量份、己二酸二酰肼2~3质量份、甲基丙烯酸丁酯5~7质量份、异丁基乙烯醚7~8质量份、谷氨酸二乙酸四钠1~3质量份、水100~120质量份。
CN201810586333.5A 2018-06-08 2018-06-08 一种水性油墨树脂 Pending CN108840969A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1896113A (zh) * 2006-06-15 2007-01-17 南开大学 印刷用含氟丙烯酸酯自交联乳液及制备方法
CN102040726A (zh) * 2010-10-15 2011-05-04 成都市新津托展油墨有限公司 一种高性能油墨树脂的制备方法
CN106752346A (zh) * 2015-11-25 2017-05-31 重庆伟恒包装有限公司 应用于水性油墨的树脂溶液
CN108084350A (zh) * 2018-01-02 2018-05-29 上海保立佳新材料有限公司 一种水性油墨用聚丙烯酸酯乳液

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1896113A (zh) * 2006-06-15 2007-01-17 南开大学 印刷用含氟丙烯酸酯自交联乳液及制备方法
CN102040726A (zh) * 2010-10-15 2011-05-04 成都市新津托展油墨有限公司 一种高性能油墨树脂的制备方法
CN106752346A (zh) * 2015-11-25 2017-05-31 重庆伟恒包装有限公司 应用于水性油墨的树脂溶液
CN108084350A (zh) * 2018-01-02 2018-05-29 上海保立佳新材料有限公司 一种水性油墨用聚丙烯酸酯乳液

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