CN108840406A - Electrolysis reactor and trade effluent electrolysis pretreatment system - Google Patents
Electrolysis reactor and trade effluent electrolysis pretreatment system Download PDFInfo
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- CN108840406A CN108840406A CN201810952978.6A CN201810952978A CN108840406A CN 108840406 A CN108840406 A CN 108840406A CN 201810952978 A CN201810952978 A CN 201810952978A CN 108840406 A CN108840406 A CN 108840406A
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 67
- 239000010865 sewage Substances 0.000 claims abstract description 58
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000003814 drug Substances 0.000 claims abstract description 29
- 239000002893 slag Substances 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 17
- 238000007790 scraping Methods 0.000 claims description 13
- 239000012530 fluid Substances 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 10
- 238000007667 floating Methods 0.000 claims description 8
- 230000005611 electricity Effects 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- 125000006850 spacer group Chemical group 0.000 claims description 4
- 239000002198 insoluble material Substances 0.000 claims description 2
- 239000007769 metal material Substances 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 6
- 231100000719 pollutant Toxicity 0.000 abstract description 6
- 230000037431 insertion Effects 0.000 abstract 1
- 238000003780 insertion Methods 0.000 abstract 1
- 238000005189 flocculation Methods 0.000 description 6
- 229910001385 heavy metal Inorganic materials 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000016615 flocculation Effects 0.000 description 5
- 239000010842 industrial wastewater Substances 0.000 description 5
- 238000002161 passivation Methods 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 235000010210 aluminium Nutrition 0.000 description 4
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000005416 organic matter Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000036647 reaction Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 239000000149 chemical water pollutant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- -1 metallurgy Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/463—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/465—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electroflotation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The present invention provides a kind of electrolysis reactor and trade effluent electrolysis pretreatment system, wherein the electrolysis reactor includes：Submersible sewage pump and tank house, tank house are rectangular parallelepiped structure comprising water inlet, water outlet, muti-piece electrode plate, two pieces of conductive plates and positive and negative electrode；Submersible sewage pump is connect by water inlet with tank house；Water inlet is located at the first side of tank house, and water outlet is located at the second side of tank house；Muti-piece electrode plate is installed in tank house in arranged in parallel, parallel with third, the 4th side；Two pieces of conductive plates are respectively arranged in third, on the 4th side, connect with outermost two electrode plate；Positive and negative electrode is located at outside tank house to be separately connected with two pieces of conductive plates, in insertion third, the 4th side.Trade effluent electrolysis pretreatment system includes electrolysis reactor, bracket, reservoir, medicine system and scrapes slag system.Based on Novel electrolytic reactor, which can efficiently remove pollutant from high-concentration industrial sewage.
Description
Technical field
The present invention relates to technical field of sewage, in particular to a kind of electrolysis reactor and trade effluent electrolysis pretreatment
System.
Background technique
Shortage of water resources has become the bottleneck problem for restricting Chinese society economic development, carries forward vigorously municipal sewage treatment
Reuse is to alleviate the important means of shortage of water resources and Constructing Water-saved Society.Wherein, pollutant load is gradually in industrial wastewater
Raising, ingredient also become increasingly complex, and processing cost is high.Organic pollutant and heavy metal has been processed into environment in trade effluent
The emphasis of problem.Traditional chemical precipitation method can remove most of heavy metal in trade effluent, but to environmental pH requirement
It is higher, and generate the waste residue for largely needing to be further processed；Membrane separation technique is to contaminant removal efficiency height, but film is easily dirty
Dye, it is with high costs；Biological method is although low in cost, but early period, bacterial screening was difficult, and was not suitable for high pollution object concentration
Industrial Wastewater Treatment.Therefore, using new technique, novel process is developed, is realized efficiently controllable, low in cost, without secondary pollution
Industrial Wastewater Treatment will bring huge economic benefit and social benefit.
Electrolysis method sewage treatment is to convert electrical energy into chemical energy to keep electrode generation redox nearby in electrolytic cell anti-
It answers, thus the process for making waste water be purified.The effects of electrolytic process includes redox, electric flocculation and air bearing.This is a series of
Process can effectively decompose the organic pollutant removed in sewage, heavy metal ion, harmful anion etc..Electrolysis method processing is dirty
Water uses low-voltage dc power supply, does not expend a large amount of chemical agents, operation is simple, and convenient for management, occupied area is small.Electrolysis method sewage
Facture can efficiently remove the pollutants such as organic matter, nitrogen phosphate and sulfur, the heavy metal in sewage, and the chemical oxygen demand of sewage is effectively reduced
Measure (COD), solid suspension concentration (SS), ammonia nitrogen concentration, total phosphorus content, salinity, coloration.
Electrolysis method is widely used in field of industrial waste water treatment, in papermaking, weaving, process hides, pesticide, metallurgy, oil refining, electricity
Plating, etc. show huge advantage in the processing of industrial wastewaters and landfill leachate.But traditional electrolyte method sewage treatment industry
In, sewage flow velocity between electrode plate is slower, needs to improve electrolysis degree by extending residence time of the sewage between electrode plate.This
Kind electrolysis mode be easy to cause serious concentration polarization, reduces transmission efficiency of the electric current between electrode plate.In addition, due to water flow velocity
Slowly, easily insoluble precipitate is formed between electrode plate and lead to pole plate passivation or short circuit, increase electrolysis process energy consumption serious shadow simultaneously
Ring the practical application effect of electrolysis method.
Summary of the invention
The embodiment of the invention provides a kind of electrolysis reactors, including：Submersible sewage pump and tank house, the tank house are rectangular
Body structure, the tank house include water inlet, water outlet, muti-piece electrode plate, two pieces of conductive plates and positive and negative electrode；The submersible sewage pump
It is connect by the water inlet with the tank house；
The water inlet is located at the first side of the tank house, and the water outlet is located at second side of the tank house
Face, the first side are opposite with second side；
The muti-piece electrode plate is installed in the tank house, and the muti-piece electrode plate is tandem, is in arranged in parallel, institute
It is parallel with third side and the 4th side to state muti-piece electrode plate, the third side and the 4th side are opposite；
Two pieces of conductive plates are respectively arranged on the third side and the 4th side, in the muti-piece electrode plate most
Two electrode plates in outside are connect with two pieces of conductive plates respectively；
The positive and negative electrode is located at outside the tank house, and is respectively embedded into third side and the 4th side, and with it is described
Two pieces of conductive plates are separately connected；
The submersible sewage pump is used for：Sewage is pressed into the tank house by water inlet, sewage high speed is made to flow through the muti-piece
Electrode plate；
The tank house is used for：Electrolysis processing is carried out to sewage, processed sewage is discharged by the electricity by water outlet
Solve room.
In embodiments of the present invention, by setting submersible sewage pump in electrolysis reactor, sewage is pressed into electricity by water inlet
It solves in room, makes the excessive electrode plate of sewage high velocity stream, not will cause serious concentration polarization in this way, electric current will not be reduced in electrode
Transmission efficiency between plate.In addition, will not to form insoluble precipitate between electrode plate and cause due to increasing water velocity
Pole plate passivation or the problem of short circuit occur, and reduce electrolysis process energy consumption, will not influence the practical application effect of electrolysis method.
The embodiment of the invention also provides a kind of trade effluent electrolysis pretreatment systems, including：Electrolysis recited above is anti-
It answers device, bracket, reservoir, scrape slag system and medicine system；
Wherein, the bracket is installed in the reservoir, and the electrolysis reactor is installed on the bracket, described to scrape
Slag system and medicine system are respectively arranged in the top of the reservoir；
The reservoir top is equipped with water inlet, and lower part is equipped with water outlet；The slag system of scraping includes Slag Scraping Device and dross
Collecting box, the medicine system include medicament pond and blender；
The reservoir is used for：Store the sewage entered；
The Slag Scraping Device scraped in slag system is used for：Separate the dross that electric floating process generates；
The dross collecting box scraped in slag system is used for：Collect the dross after the Slag Scraping Device separation；
Medicament pond in the medicine system is used for：Medical fluid is stored, and medical fluid is passed through in the reservoir；
Blender in the medicine system is used for：Medical fluid in the medicament pond is stirred.
In embodiments of the present invention, based on novel electrolysis reactor mentioned above, which can be efficiently from high concentration
Pollutant is removed in trade effluent.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with
It obtains other drawings based on these drawings.
Fig. 1 is a kind of structure chart of electrolysis reactor provided in an embodiment of the present invention；
Fig. 2 is a kind of scheme of installation (right view of Fig. 1) of muti-piece electrode plate provided in an embodiment of the present invention；
Fig. 3 is a kind of trade effluent electrolysis pretreatment system construction drawing provided in an embodiment of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that the described embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Based on this
Embodiment in invention, every other reality obtained by those of ordinary skill in the art without making creative efforts
Example is applied, shall fall within the protection scope of the present invention.
In embodiments of the present invention, a kind of electrolysis reactor 100 is provided, as shown in Figure 1, including：Submersible sewage pump 1 and electrolysis
Room 3, the tank house 3 are rectangular parallelepiped structure, and the tank house includes 5, two pieces of water inlet 2, water outlet, positive and negative electrode conductive plates
6 and muti-piece electrode plate 7；The submersible sewage pump 1 is connect by the water inlet 2 with the tank house 3；
The water inlet 2 is located at the first side of the tank house 3, and the water outlet is located at the second of the tank house 3
Side, the first side are opposite with second side；
The positive and negative electrode 5 is located at outside the tank house 3, and is respectively embedded into third side and the 4th side, and with institute
Two pieces of conductive plates 6 are stated to be separately connected；
Two pieces of conductive plates 6 are respectively arranged on the third side and the 4th side, in the muti-piece electrode plate 7
Outermost two electrode plate is connect with two pieces of conductive plates 6 respectively；
The muti-piece electrode plate 7 is installed in the tank house 3, and the muti-piece electrode plate 7 is tandem, is in parallel
Column, the muti-piece electrode plate 7 is parallel with third side and the 4th side, and the third side and the 4th side are opposite；
The submersible sewage pump 1 is used for：Sewage is pressed into the tank house 3 by water inlet 2, flows through sewage high speed described more
Electrode plate 7；
The tank house 3 is used for：Electrolysis processing is carried out to sewage, processed sewage is discharged by the electricity by water outlet
Solve room 3.
Sewage is pressed into water inlet by submersible sewage pump, and sewage high speed is made to pass through the electrode sheet separation in tank house.The high speed of sewage
Flowing reduces the concentration difference gradient that electrolytic process (comprising redox reaction, electric flocculation and electric floating process) generates, and makes to sink
Starch is not easy to be deposited on electrode plate surface, effectively prevents electrode passivation.In addition, high speed liquid flow can make the diameter for generating bubble
Smaller, bubble has bigger specific surface area, thus has stronger absorption property, is more advantageous to electric floating.The electrolysis reactor
Handle sewage method be it is circulating, sewage stopped in electrolysis reactor it is very short, by after electrolysis reactor with extraneous sewage
It re-mixes, and is constantly recycled with this process.The degree of sewage treatment can be controlled by control electrolysis time.
In embodiments of the present invention, the shape of the tank house 3 is also possible to other structures body, such as square etc..
In embodiments of the present invention, liquid stream electrolysis reactor in the prior art is typically all closed container, and this side
There are some disadvantages for formula.In order to solve these disadvantages, water outlet is set open outlet by the present invention, that is to say, that the electricity
It is no for solving the second side of room 3.The flocculate and minute bubbles that this mode can preferably maintain electrolytic process to generate are steady
It is fixed, improve electric flocculation and electric floating efficiency.
In embodiments of the present invention, how muti-piece electrode plate to be installed in the tank house.Specifically, in the electrolysis
Corresponding on 5th side of room 3 and the 6th side to be equipped with multiple grooves, then the muti-piece electrode plate is inserted into institute respectively
In the corresponding recesses for stating multiple grooves, as shown in Figure 2.
In embodiments of the present invention, as shown in Figure 1, further including in the tank house 3：Homogenizing plate 4 is installed on the water inlet
Between mouth 2 and muti-piece electrode plate 7, it is inserted into corresponding recesses；Between homogenizing plate 4 can make the discharge of sewage uniformly pass through electrode plate 7
Gap makes all electrode plates 7 uniformly and effectively participate in cell reaction, reduces electrode reaction rate difference and degree difference.
Specifically, an entire plate can be set into the homogenizing plate, it is evenly distributed on the homogenizing plate of this monolith more
A hole makes the gross area in multiple holes close to water inlet open area, and then the discharge of sewage uniformly passes through this some holes.It is also possible to set
Setting the homogenizing plate includes muti-piece, and the block number of homogenizing plate is identical as the block number of muti-piece electrode plate；The muti-piece homogenizing plate is in flat
Row arrangement, the muti-piece homogenizing plate are parallel with third side and the 4th side.The sky that is formed between any two of muti-piece homogenizing plate in this way
Gap is corresponding with the clearance position that muti-piece electrode plate is formed between any two, and makes the gross area in gap between homogenizing plate close to water inlet
Open area can also make the discharge of sewage uniformly pass through 7 gap of electrode plate in this way.
When not including homogenizing plate in the tank house 3, the number and muti-piece of the 5th side or the groove on the 6th side
The block number of electrode plate is identical, when in the tank house 3 including homogenizing plate, the number of the 5th side or the groove on the 6th side
The block number of block number and homogenizing plate including muti-piece electrode plate.
In embodiments of the present invention, the electrode plate can be conducive to generate hydrogen with the soluble metals material such as aluminium, iron
Aluminium oxide or iron hydroxide flocculent deposit promote electric flocculation process.Therefore electrode plate is consumables, so electrode plate is replaceable
's.5 piece of -15 electrode plate can be set in tank house, these electrode plate spacings can be set to 1mm-10mm.
In embodiments of the present invention, the muti-piece electrode plate can add netted insulating spacer, purpose between any two
It is turbulence level in order to increase the flowing of the liquid between electrode plate and prevents from electrode plate from falling off deforming caused intereelectrode short-circuit.
In embodiments of the present invention, the conductive plate is insoluble material, stainless steel material can be selected, it is therefore an objective to prevent dirt
Water and the conductive plate generate chemical reaction, so that the conductive effect of the conductive plate reduces.Two pieces of conductive plates respectively with
The positive and negative electrode is connected by welding form.
In embodiments of the present invention, the DC power supply that the positive and negative electrode can alternately change with positive and negative anodes is connect.Wherein,
The DC power supply of positive and negative anodes alternately variation can use high frequency pulse positive pole, be conducive to remove polar board surface so in time and coagulate
Poly- metal oxide or insoluble product, prevents pole plate passivation.
As shown in figure 3, the embodiment of the invention also provides a kind of trade effluent electrolysis pretreatment systems, including：Institute above
The electrolysis reactor 100 stated, reservoir 200 (shape is the square or cuboid not covered), scrapes slag system 300 at bracket 101
With medicine system 400；
Wherein, the bracket 101 is installed in the reservoir 200, and the electrolysis reactor 100 is installed on the bracket
It is described to scrape slag system 300 and medicine system 400 is respectively arranged in the top (the right and left) of the reservoir 200 on 101；
200 (the one of side) top of reservoir is equipped with water inlet 201, (can be opposite flank) lower part
Equipped with water outlet 202；The slag system 300 of scraping includes Slag Scraping Device 301 and dross collecting box 302 (after Slag Scraping Device 301
Face, on the one side of water outlet 202), the medicine system 400 includes that medicament pond 401 and blender 402 (are put into medicament
In pond 401)；
The reservoir 200 is used for：Store the sewage entered；
The Slag Scraping Device 301 scraped in slag system 300 is used for：Separate the dross that electric floating process generates；
The dross collecting box 302 scraped in slag system 300 is used for：Collect the dross after the Slag Scraping Device separation；
Medicament pond 401 in the medicine system 400 is used for：Medical fluid is stored, and medical fluid is passed through in the reservoir；
Blender 402 in the medicine system 400 is used for：Medical fluid in the medicament pond is stirred.
It can also include a control valve in the outlet in the medicament pond 401 of the medicine system 400, be passed through for controlling
To the flow of the medical fluid in the reservoir.
It is described to scrape slag system 300 and the medicine system 400 is all made of existing use.
Embodiment 1：The assembly of electrolysis reactor
As shown in Figure 1, being inserted into 11 pieces of interchangeable aluminums or irony electrode plate, electrode in the tank house of electrolysis reactor
Plate spacing is 4mm, and netted insulating spacer is added between electrode plate, and conductive plate selects stainless steel material, and electrode connects positive and negative anodes alternating
The high frequency pulse positive pole (50V, 5000 times/second) of variation.
Embodiment 2：Electrolysis reactor is for aluminium processing waste emulsified mixture processing
Certain aluminium processing enterprise waste emulsified mixture is handled using the electrolysis reactor of above-mentioned configuration.Electrolysis reactor is placed in 1 ton
In sewage, after electrolysis starts, sewage surface generates a large amount of black blisters, shows that wherein insoluble impurities is by air bearing, with reaction
Progress, dross color gradually becomes shallower as, and eventually becomes white, at this time the pollutants such as electrolytic process main oxidation organic matter, ammonia nitrogen.
After electrolysis 1 hour, water quality is in as clear as crystal.Water outlet COD is reduced to 3000mg/L by 10000mg/L, and removal rate is greater than 70%, ammonia nitrogen
Removal rate is greater than 90%, SS removal rate and is greater than 95%, and heavy metal removing rate is greater than 99%.
Embodiment 3：Electrolysis reactor is for the processing of steel pipe rolling waste emulsified mixture
Certain steel pipe rolling enterprise waste emulsified mixture is handled using the electrolysis reactor of above-mentioned configuration.Electrolysis reactor is placed in 2
In ton sewage, after electrolysis starts, there are a large amount of bubbles to generate, bubble color is deeper, insoluble impurities by air bearing, with reaction into
Row, dross color gradually become shallower as, and eventually become white, and organic matter is carbon dioxide and water by direct oxidation.Electrolysis 100 minutes,
Water quality is in as clear as crystal.Water outlet COD is reduced to 1000mg/L by 6000mg/L, and removal rate is greater than 73%.
In conclusion electrolysis reactor proposed by the present invention has the advantages that：
1, it is acted on using redox, electric flocculation effect and the electric floating in electrolytic process, it can be efficiently from highly concentrated
Spend in trade effluent and remove organic matter, nitrogen phosphate and sulfur, the pollutants such as heavy metal, be effectively reduced sewage COD (COD),
Solid suspension concentration (SS), ammonia nitrogen concentration, total phosphorus content, salinity, coloration；
2, it using semi-enclosed structure, ensure that the stability of the flocculate and minute bubbles that generate in electrolytic process, improve
Electric flocculation and electric floating efficiency；
3, sewage flow velocity between electrode plate is high, can effectively promote cell reaction efficiency, slow down electrode passivation phenomenon；
4, electrode plate spacing is small, and flow stream velocity is uniform between plate, and the utilization rate for greatly improving electric energy is high, reduces sewage treatment
The energy consumption of journey can handle the trade effluent of high concentration；
5, have simple structure, low cost, occupied area small, portable, electrode replacement is convenient, and long service life etc. is excellent
Point.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the embodiment of the present invention can have various modifications and variations.All within the spirits and principles of the present invention, made
Any modification, equivalent substitution, improvement and etc. should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of electrolysis reactor, which is characterized in that including：Submersible sewage pump and tank house, the tank house are rectangular parallelepiped structure, institute
Stating tank house includes water inlet, water outlet, muti-piece electrode plate, two pieces of conductive plates and positive and negative electrode；The submersible sewage pump passes through described
Water inlet is connect with the tank house；
The water inlet is located at the first side of the tank house, and the water outlet is located at the second side of the tank house, institute
It is opposite with second side to state first side；
The muti-piece electrode plate is installed in the tank house, and the muti-piece electrode plate is tandem, described more in arranged in parallel
Electrode plate is parallel with third side and the 4th side, and the third side and the 4th side are opposite；
Two pieces of conductive plates are respectively arranged on the third side and the 4th side, the outermost in the muti-piece electrode plate
Two electrode plates connect respectively with two pieces of conductive plates；
The positive and negative electrode is located at outside the tank house, and is respectively embedded into third side and the 4th side, and with described two pieces
Conductive plate is separately connected；
The submersible sewage pump is used for：Sewage is pressed into the tank house by water inlet, sewage high speed is made to flow through the muti-piece electrode
Plate；
The tank house is used for：Electrolysis processing is carried out to sewage, processed sewage is discharged by water outlet.
2. electrolysis reactor as described in claim 1, which is characterized in that the water outlet is open outlet.
3. electrolysis reactor as described in claim 1, which is characterized in that on the 5th side of the tank house and the 6th side
Equipped with multiple grooves, the muti-piece electrode plate is inserted into respectively in the corresponding recesses of the multiple groove.
4. electrolysis reactor as claimed in claim 3, which is characterized in that further include in the tank house：Homogenizing plate is installed on
Between the water inlet and muti-piece electrode plate, it is inserted into the corresponding recesses of the multiple groove；
The homogenizing plate is used for：The discharge of sewage is set uniformly to pass through muti-piece electrode sheet separation.
5. electrolysis reactor as claimed in claim 4, which is characterized in that the homogenizing plate is one block of plate, on the homogenizing plate
It is evenly distributed with multiple holes.
6. electrolysis reactor as claimed in claim 4, which is characterized in that the homogenizing plate includes muti-piece, the homogenizing plate
Block number is identical as the block number of muti-piece electrode plate；The muti-piece homogenizing plate is in arranged in parallel, the muti-piece homogenizing plate and third side
It is parallel with the 4th side.
7. electrolysis reactor as described in claim 1, which is characterized in that the conductive plate is insoluble material, the electrode
Plate is soluble metal material.
8. electrolysis reactor as described in claim 1, which is characterized in that the muti-piece electrode plate is added with net between any two
Shape insulating spacer；
The netted insulating spacer is used for：Increase the turbulence level of the liquid flowing between electrode plate and prevents electrode plate from falling off deformation
Caused intereelectrode short-circuit.
9. electrolysis reactor as described in claim 1, which is characterized in that the positive and negative electrode replaces the straight of variation with positive and negative anodes
The connection of galvanic electricity source.
10. a kind of trade effluent electrolysis pretreatment system, which is characterized in that including：The described in any item electricity of claim 1 to 9
Solution reactor, reservoir, scrapes slag system and medicine system at bracket；
Wherein, the bracket is installed in the reservoir, and the electrolysis reactor is installed on the bracket, described to scrape slag system
System and medicine system are respectively arranged in the top of the reservoir；
The reservoir top is equipped with water inlet, and lower part is equipped with water outlet；The slag system of scraping includes that Slag Scraping Device and dross are collected
Case, the medicine system include medicament pond and blender；
The reservoir is used for：Store the sewage entered；
The Slag Scraping Device scraped in slag system is used for：Separate the dross that electric floating process generates；
The dross collecting box scraped in slag system is used for：Collect the dross after the Slag Scraping Device separation；
Medicament pond in the medicine system is used for：Medical fluid is stored, and medical fluid is passed through in the reservoir；
Blender in the medicine system is used for：Medical fluid in the medicament pond is stirred.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810952978.6A CN108840406A (en) | 2018-08-21 | 2018-08-21 | Electrolysis reactor and trade effluent electrolysis pretreatment system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810952978.6A CN108840406A (en) | 2018-08-21 | 2018-08-21 | Electrolysis reactor and trade effluent electrolysis pretreatment system |
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| Publication Number | Publication Date |
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| CN108840406A true CN108840406A (en) | 2018-11-20 |
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ID=64188374
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810952978.6A Withdrawn CN108840406A (en) | 2018-08-21 | 2018-08-21 | Electrolysis reactor and trade effluent electrolysis pretreatment system |
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| CN (1) | CN108840406A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110158116A (en) * | 2019-05-31 | 2019-08-23 | 凯莱英医药集团（天津）股份有限公司 | Electrolysis unit and electrolysis system |
| CN111115764A (en) * | 2020-01-14 | 2020-05-08 | 赵宫鼎 | Electrode plate assembly for sewage treatment, treatment device with same and use method |
| CN112194290A (en) * | 2020-06-30 | 2021-01-08 | 广州中科建禹环保有限公司 | Physicochemical treatment system and method for cosmetic production waste liquid |
| CN114920335A (en) * | 2022-06-08 | 2022-08-19 | 重庆普优尔科技有限公司 | Electrolysis unit and multistage electrolysis device |
| CN115557578A (en) * | 2022-09-28 | 2023-01-03 | 中核四0四有限公司 | Device and method for treating organic phase in uranium-containing nitric acid waste liquid through electro-flotation-electro-flocculation |
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| US6350354B1 (en) * | 1999-09-03 | 2002-02-26 | Koch-Glitsch, Inc. | Modular solvent extraction plant |
| CN2496853Y (en) * | 2001-09-13 | 2002-06-26 | 韩庆生 | Sewage treatment apapratus |
| CN2663403Y (en) * | 2003-12-05 | 2004-12-15 | 舒煦 | Tandem type electrolyzer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US6350354B1 (en) * | 1999-09-03 | 2002-02-26 | Koch-Glitsch, Inc. | Modular solvent extraction plant |
| CN2496853Y (en) * | 2001-09-13 | 2002-06-26 | 韩庆生 | Sewage treatment apapratus |
| CN2663403Y (en) * | 2003-12-05 | 2004-12-15 | 舒煦 | Tandem type electrolyzer |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110158116A (en) * | 2019-05-31 | 2019-08-23 | 凯莱英医药集团（天津）股份有限公司 | Electrolysis unit and electrolysis system |
| CN111115764A (en) * | 2020-01-14 | 2020-05-08 | 赵宫鼎 | Electrode plate assembly for sewage treatment, treatment device with same and use method |
| CN112194290A (en) * | 2020-06-30 | 2021-01-08 | 广州中科建禹环保有限公司 | Physicochemical treatment system and method for cosmetic production waste liquid |
| CN114920335A (en) * | 2022-06-08 | 2022-08-19 | 重庆普优尔科技有限公司 | Electrolysis unit and multistage electrolysis device |
| CN115557578A (en) * | 2022-09-28 | 2023-01-03 | 中核四0四有限公司 | Device and method for treating organic phase in uranium-containing nitric acid waste liquid through electro-flotation-electro-flocculation |
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Application publication date: 20181120 |