CN108839165A - A method of reducing wood color difference before and after highland hook leaf rattan thermal softening - Google Patents

A method of reducing wood color difference before and after highland hook leaf rattan thermal softening Download PDF

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Publication number
CN108839165A
CN108839165A CN201810587918.9A CN201810587918A CN108839165A CN 108839165 A CN108839165 A CN 108839165A CN 201810587918 A CN201810587918 A CN 201810587918A CN 108839165 A CN108839165 A CN 108839165A
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China
Prior art keywords
highland
hook leaf
leaf rattan
color difference
thermal softening
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Pending
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CN201810587918.9A
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Chinese (zh)
Inventor
陈献军
陈子玉
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FUNAN COUNTY XINGGUANG ARTS & CRAFTS Co Ltd
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FUNAN COUNTY XINGGUANG ARTS & CRAFTS Co Ltd
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Priority to CN201810587918.9A priority Critical patent/CN108839165A/en
Publication of CN108839165A publication Critical patent/CN108839165A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/0207Pretreatment of wood before impregnation
    • B27K3/0214Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/003Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
    • B27K5/0055Radio-waves, e.g. microwaves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/06Softening or hardening of wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00Chemical or physical treatment of reed, straw, or similar material
    • B27K9/002Cane, bamboo

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Mechanical Engineering (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention belongs to windmill palm vine material technical field of hot working, and in particular to a method of wood color difference before and after highland hook leaf rattan thermal softening is reduced, including(1)No disease and pests harm, highland hook leaf rattan uniform in material are acquired, being dried after cleaned, truncation to moisture content is 12%, is then impregnated 6-10 days in soak;(2)By treated highland hook leaf rattan temperature be 115 DEG C under conditions of heat and soften, then under conditions of 400W power microwave heating to get.The present invention has the following advantages that compared with prior art:By being handled with soak highland hook leaf rattan in the present invention, can with inside the hook leaf rattan material of highland color development and auxochrome group be combined, rationally control thermal softening condition, color development and auxochrome group inside highland hook leaf rattan material is reduced to aoxidize under the high temperature conditions, the volatilization or hydrolysis dissolution of extract are reduced simultaneously, and then the variation of lightness during thermal softening is reduced, reduce the change of overall color difference.

Description

A method of reducing wood color difference before and after highland hook leaf rattan thermal softening
Technical field
The invention belongs to windmill palm vine material technical field of hot working, and in particular to a kind of reduction highland hook leaf rattan thermal softening front and back The method of wood color difference.
Background technique
Rattan rattan is that " rattan " is commonly called as on commodity, and density is medium, and light firm, polishing degree height, durability are strong, and It is beautiful plain, it is the excellent material of furniture and craftwork, is widely used in manufacturing the rattans men such as table, chair, tea table, sofa, bed Tool and craftwork, the theory that naturally light-duty primary colors rattan furniture embodies modern's back to nature, pursues healthy living, are known as work The title of skill artistic products is that conventional outlet is earned foreign exchange one of commodity, has very high economic value, wherein whose evaluation rattan material table of wood color One of face characteristic and the Chinese medicine index of utility value, in thermal softening and drying process, wood color variation, chromatic value variation, Oxidation occurs with chromophoric groups certain in rattan material and auxochrome group or extract volatilization is related, it is existing the study found that wherein highly Hook leaf rattan heated by microwave, which softens lightness, reduces by 40%, and decatize thermal softening reduces by 45%, and microwave heating softens overall color difference knots modification It is 24.29, decatize thermal softening totality color difference knots modification is 28.45, the increase of lightness casting, material in the drying process of highland hook leaf rattan Gradually variable is dried the influence to rattan material Surface lightness and is less than sofening treatment, that is, after drying color compared to softening process Rattan material lightness is respectively less than untreated rattan material, same dried medium, at a temperature of, complete dry rattan wood color under higher temperature conditions Difference is greater than the value of chromatism after the completion of drying under cryogenic, and microwave drying can be reduced wood color difference, but how further decrease Color difference is not studied also now.
Summary of the invention
The purpose of the present invention is being directed to existing problem, it is poor to provide a kind of reduction highland hook leaf rattan thermal softening front and back wood color Different method.
The present invention is achieved by the following technical solutions:A kind of reduction highland hook leaf rattan thermal softening front and back wood color difference Method, including the following contents:
(1)No disease and pests harm, highland hook leaf rattan uniform in material are acquired, after cleaned, truncation under conditions of temperature is 55-60 DEG C Drying to moisture content is 12%, is then impregnated 6-10 days in soak;
Every liter of soak includes the raw material of following weight:Groomwell root oil 22-28mg, carboxymethyl chitosan 6-10mg, sulfopropyl Glycine betaine 1-2mg, isooctyl mercaptopropionate 0.6-0.8mg, surplus are water;
(2)Treated highland hook leaf rattan is heated and softened 20-30 minutes under conditions of temperature is 115 DEG C, is then existed Under conditions of 400W power microwave heating 100-120 seconds to get.
As further improvement of these options, the preparation method of the Groomwell root oil is to dry after cleaning Asian puccoon to containing Water is lower than 5%, then impregnates 12-16 hours in the wild tea oil for being equivalent to 2 times of its weight, and filtering, gained filter residue is with being equivalent to The wild tea oil of 1.5 times of its weight impregnates 2-4 hours, and then thermal extraction 20 minutes, stand diacolation 12 hours after cooling, filter, and closes And twice filtrate to get.
As further improvement of these options, the temperature of the soak is 55-65 DEG C.
As further improvement of these options, water is magnetized water in the soak, by magnetizer A400p magnetization Reason, water yield 40m3/h.
As further improvement of these options, the deacetylation of the raw materials of chitosan of carboxymethyl chitosan is 87%, carboxylic The viscosity average molecular weigh of methyl chitosan is 3.15 × 105-3.31×105
As further improvement of these options, carboxymethyl chitosan is N- carboxymethyl chitosan or N, O- carboxymethyl shell One of glycan.
As further improvement of these options, the step(2)The Deflection Modulus of Elasticity of highland hook leaf rattan after the completion For step(1)Deflection Modulus of Elasticity 18-22%, illustrates to have reached preferable bating effect before impregnating in soak.
The present invention has the following advantages that compared with prior art:In the present invention by with soak to highland hook leaf rattan at Reason, can with inside the hook leaf rattan material of highland color development and auxochrome group be combined, rationally control thermal softening condition, reduce highland hook Color development and auxochrome group aoxidize under the high temperature conditions inside leaf rattan material, while reducing the volatilization or hydrolysis dissolution of extract, in turn The variation of lightness during reduction thermal softening, reduces the change of overall color difference.
Specific embodiment
Embodiment 1
A method of reducing wood color difference before and after highland hook leaf rattan thermal softening, including the following contents:
(1)No disease and pests harm, highland hook leaf rattan uniform in material are acquired, it is dry under conditions of temperature is 58 DEG C after cleaned, truncation It is dry to moisture content be 12%, then impregnated 8 days in soak;
Every liter of soak includes the raw material of following weight:Groomwell root oil 25mg, carboxymethyl chitosan 8mg, azochlorosulfonate propyl lycine 1.5mg, isooctyl mercaptopropionate 0.7mg, surplus are water;
(2)Treated highland hook leaf rattan is heated and softened 25 minutes under conditions of temperature is 115 DEG C, then in 400W Under conditions of power microwave heating 110 seconds to get.
Wherein, the preparation method of the Groomwell root oil is to dry after cleaning Asian puccoon to water content to be lower than 5%, then suitable It impregnates 14 hours, filters in 2 times of its weight of wild tea oil, gained filter residue impregnates 3 with the wild tea oil for being equivalent to 1.5 times of its weight Hour, then thermal extraction 20 minutes stand diacolation 12 hours after cooling, filter, merging twice filtrate to get.
Wherein, the temperature of the soak is 60 DEG C;Water is magnetized water in the soak, is magnetized by magnetizer A400p Processing, water yield 40m3/h.
Wherein, the deacetylation of the raw materials of chitosan of carboxymethyl chitosan is 87%, the viscosity average molecular weigh of carboxymethyl chitosan It is 3.15 × 105;Carboxymethyl chitosan is N- carboxymethyl chitosan.
Wherein, the step(2)The Deflection Modulus of Elasticity of highland hook leaf rattan is step after the completion(1)It is impregnated in soak Preceding Deflection Modulus of Elasticity 18-22% illustrates to have reached preferable bating effect.
In 2 soak of embodiment
A method of reducing wood color difference before and after highland hook leaf rattan thermal softening, including the following contents:
(1)No disease and pests harm, highland hook leaf rattan uniform in material are acquired, it is dry under conditions of temperature is 55 DEG C after cleaned, truncation It is dry to moisture content be 12%, then impregnated 10 days in soak;
Every liter of soak includes the raw material of following weight:Groomwell root oil 22mg, carboxymethyl chitosan 10mg, azochlorosulfonate propyl lycine 1mg, isooctyl mercaptopropionate 0.6mg, surplus are water;
(2)Treated highland hook leaf rattan is heated and softened 30 minutes under conditions of temperature is 115 DEG C, then in 400W Under conditions of power microwave heating 100 seconds to get.
Wherein, the preparation method of the Groomwell root oil is to dry after cleaning Asian puccoon to water content to be lower than 5%, then suitable It impregnates 12 hours, filters in 2 times of its weight of wild tea oil, gained filter residue impregnates 4 with the wild tea oil for being equivalent to 1.5 times of its weight Hour, then thermal extraction 20 minutes stand diacolation 12 hours after cooling, filter, merging twice filtrate to get.
Wherein, the temperature of the soak is 55 DEG C;Water is magnetized water in the soak, is magnetized by magnetizer A400p Processing, water yield 40m3/h.
Wherein, the deacetylation of the raw materials of chitosan of carboxymethyl chitosan is 87%, the viscosity average molecular weigh of carboxymethyl chitosan It is 3.31 × 105;Carboxymethyl chitosan is n,O-carboxymethyl chitosan.
Wherein, the step(2)The Deflection Modulus of Elasticity of highland hook leaf rattan is step after the completion(1)It is impregnated in soak Preceding Deflection Modulus of Elasticity 18-22% illustrates to have reached preferable bating effect.
Embodiment 3
A method of reducing wood color difference before and after highland hook leaf rattan thermal softening, including the following contents:
(1)No disease and pests harm, highland hook leaf rattan uniform in material are acquired, it is dry under conditions of temperature is 60 DEG C after cleaned, truncation It is dry to moisture content be 12%, then impregnated 6 days in soak;
Every liter of soak includes the raw material of following weight:Groomwell root oil 28mg, carboxymethyl chitosan 6mg, azochlorosulfonate propyl lycine 2mg, isooctyl mercaptopropionate 0.8mg, surplus are water;
(2)Treated highland hook leaf rattan is heated and softened 20 minutes under conditions of temperature is 115 DEG C, then in 400W Under conditions of power microwave heating 120 seconds to get.
Wherein, the preparation method of the Groomwell root oil is to dry after cleaning Asian puccoon to water content to be lower than 5%, then suitable It impregnates 16 hours, filters in 2 times of its weight of wild tea oil, gained filter residue impregnates 2 with the wild tea oil for being equivalent to 1.5 times of its weight Hour, then thermal extraction 20 minutes stand diacolation 12 hours after cooling, filter, merging twice filtrate to get.
Wherein, the temperature of the soak is 65 DEG C;Water is magnetized water in the soak, is magnetized by magnetizer A400p Processing, water yield 40m3/h.
Wherein, the deacetylation of the raw materials of chitosan of carboxymethyl chitosan is 87%, the viscosity average molecular weigh of carboxymethyl chitosan It is 3.15 × 105;Carboxymethyl chitosan is N- carboxymethyl chitosan.
Wherein, the step(2)The Deflection Modulus of Elasticity of highland hook leaf rattan is step after the completion(1)It is impregnated in soak Preceding Deflection Modulus of Elasticity 18-22% illustrates to have reached preferable bating effect.
Control group 1 is set, and by Groomwell root oil removes in soak in embodiment 1, remaining content is constant;Control group 2 is set, it will Carboxymethyl chitosan removes in soak in embodiment 1, remaining content is constant;Control group 3 is set, by soak in embodiment 1 Middle azochlorosulfonate propyl lycine removes, remaining content is constant;Control group 4 is set, by isooctyl mercaptopropionate in soak in embodiment 1 Remove, remaining content is constant;Control group 5 is set, by step in embodiment 1(2)Thermal softening method is micro- under the power of 540W Wave heating 3min, remaining content are constant;Control group 6 is set, by step in embodiment 1(2)Thermal softening method is the temperature at 121 DEG C Degree is lower to heat and soften 60min, remaining content is constant;Control group 7 is set, test specimen in embodiment 1 is impregnated 14 days to full in water After water under the power of 540W microwave heating 3min;Control group 8 is set, test specimen in embodiment 1 is impregnated 14 days to full in water After water 121 DEG C at a temperature of heat and soften 60min;
Using CIE in 1976(L*a*b*)Standard colorimetric characterization system characterizes rattan material color, mainly calculates in this experiment Lightness L*Reduced rate simultaneously calculates color difference △ E*;Obtain following result:
Table 1
Group Lightness L*Reduced rate(%) △E*
Embodiment 1 22 11.34
Embodiment 2 20 10.86
Embodiment 3 22 11.29
Control group 1 31 17.56
Control group 2 34 18.92
Control group 3 27 13.75
Control group 4 24 12.16
Control group 5 37 20.58
Control group 6 40 23.34
Control group 7 40 24.29
Control group 8 45 28.45
Can be seen that method in the present invention by data in table 1 can reduce the change of lightness and color difference, can be improved highland hook The use value of leaf rattan material.

Claims (7)

1. a kind of method for reducing highland hook leaf rattan thermal softening front and back wood color difference, which is characterized in that including the following contents:
(1)No disease and pests harm, highland hook leaf rattan uniform in material are acquired, after cleaned, truncation under conditions of temperature is 55-60 DEG C Drying to moisture content is 12%, is then impregnated 6-10 days in soak;
Every liter of soak includes the raw material of following weight:Groomwell root oil 22-28mg, carboxymethyl chitosan 6-10mg, sulfopropyl Glycine betaine 1-2mg, isooctyl mercaptopropionate 0.6-0.8mg, surplus are water;
(2)Treated highland hook leaf rattan is heated and softened 20-30 minutes under conditions of temperature is 115 DEG C, is then existed Under conditions of 400W power microwave heating 100-120 seconds to get.
2. a kind of method for reducing highland hook leaf rattan thermal softening front and back wood color difference as described in claim 1, which is characterized in that institute The preparation method for stating Groomwell root oil is to be dried after cleaning Asian puccoon to water content lower than 5%, then in the open country for being equivalent to 2 times of its weight It impregnates 12-16 hours, filters in tea oil, gained filter residue use is equivalent to the immersion of wild tea oil 2-4 hours of 1.5 times of its weight, then Thermal extraction 20 minutes, stands diacolation 12 hours after cooling, filters, merging twice filtrate to get.
3. a kind of method for reducing highland hook leaf rattan thermal softening front and back wood color difference as described in claim 1, which is characterized in that institute The temperature for stating soak is 55-65 DEG C.
4. a kind of method for reducing highland hook leaf rattan thermal softening front and back wood color difference as described in claim 1, which is characterized in that institute Stating water in soak is magnetized water, by magnetizer A400p magnetization treatment, water yield 40m3/h.
5. a kind of method for reducing highland hook leaf rattan thermal softening front and back wood color difference as described in claim 1, which is characterized in that carboxylic The deacetylation of the raw materials of chitosan of methyl chitosan is 87%, and the viscosity average molecular weigh of carboxymethyl chitosan is 3.15 × 105- 3.31×105
6. a kind of method for reducing highland hook leaf rattan thermal softening front and back wood color difference as described in claim 1, which is characterized in that carboxylic Methyl chitosan is one of N- carboxymethyl chitosan or n,O-carboxymethyl chitosan.
7. a kind of method for reducing highland hook leaf rattan thermal softening front and back wood color difference as described in claim 1, which is characterized in that institute State step(2)The Deflection Modulus of Elasticity of highland hook leaf rattan is step after the completion(1)Deflection Modulus of Elasticity before being impregnated in soak 18-22%。
CN201810587918.9A 2018-06-08 2018-06-08 A method of reducing wood color difference before and after highland hook leaf rattan thermal softening Pending CN108839165A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101804651A (en) * 2010-04-06 2010-08-18 浙江升华云峰新材股份有限公司 Method for improving utilization rate of precious timber
CN105415470A (en) * 2015-11-30 2016-03-23 国家林业局竹子研究开发中心 Method for accurately regulating and controlling bamboo wood color
CN105754768A (en) * 2016-02-24 2016-07-13 福建春辉生物工程有限公司 Natural camellia saponin-containing baby care handmade soap and preparation method thereof
CN106553250A (en) * 2015-09-21 2017-04-05 浙江省林业科学研究院 A kind of mould proof anti-complexion changed agent of bamboo material surface
CN107283577A (en) * 2017-07-28 2017-10-24 阜南县中信柳木工艺品有限公司 It is a kind of to improve the anti-mildew processing method of mao bamboon bamboo wood
CN107908887A (en) * 2017-11-22 2018-04-13 西南林业大学 The model building method of timber bating effect after a kind of microwave combined sofening treatment of hydro-thermal

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101804651A (en) * 2010-04-06 2010-08-18 浙江升华云峰新材股份有限公司 Method for improving utilization rate of precious timber
CN106553250A (en) * 2015-09-21 2017-04-05 浙江省林业科学研究院 A kind of mould proof anti-complexion changed agent of bamboo material surface
CN105415470A (en) * 2015-11-30 2016-03-23 国家林业局竹子研究开发中心 Method for accurately regulating and controlling bamboo wood color
CN105754768A (en) * 2016-02-24 2016-07-13 福建春辉生物工程有限公司 Natural camellia saponin-containing baby care handmade soap and preparation method thereof
CN107283577A (en) * 2017-07-28 2017-10-24 阜南县中信柳木工艺品有限公司 It is a kind of to improve the anti-mildew processing method of mao bamboon bamboo wood
CN107908887A (en) * 2017-11-22 2018-04-13 西南林业大学 The model building method of timber bating effect after a kind of microwave combined sofening treatment of hydro-thermal

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Application publication date: 20181120