CN108803534A - Ethane cracking furnace burning process monitors system - Google Patents

Ethane cracking furnace burning process monitors system Download PDF

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Publication number
CN108803534A
CN108803534A CN201810814316.2A CN201810814316A CN108803534A CN 108803534 A CN108803534 A CN 108803534A CN 201810814316 A CN201810814316 A CN 201810814316A CN 108803534 A CN108803534 A CN 108803534A
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CN
China
Prior art keywords
temperature
monitoring
module
cracking furnace
burning process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810814316.2A
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Chinese (zh)
Inventor
徐勇
王国耀
李端发
郭杰
刘强
曹明润
于文彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Gold Star M & E Technical Development Co Ltd
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Hefei Gold Star M & E Technical Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201810814316.2A priority Critical patent/CN108803534A/en
Publication of CN108803534A publication Critical patent/CN108803534A/en
Withdrawn legal-status Critical Current

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Classifications

    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05BCONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B19/00Programme-control systems
    • G05B19/02Programme-control systems electric
    • G05B19/418Total factory control, i.e. centrally controlling a plurality of machines, e.g. direct or distributed numerical control [DNC], flexible manufacturing systems [FMS], integrated manufacturing systems [IMS], computer integrated manufacturing [CIM]
    • G05B19/41865Total factory control, i.e. centrally controlling a plurality of machines, e.g. direct or distributed numerical control [DNC], flexible manufacturing systems [FMS], integrated manufacturing systems [IMS], computer integrated manufacturing [CIM] characterised by job scheduling, process planning, material flow
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/14Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
    • C10G9/18Apparatus
    • C10G9/20Tube furnaces
    • C10G9/206Tube furnaces controlling or regulating the tube furnaces
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1088Olefins
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05BCONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B2219/00Program-control systems
    • G05B2219/30Nc systems
    • G05B2219/33Director till display
    • G05B2219/33273DCS distributed, decentralised controlsystem, multiprocessor

Abstract

The present invention relates to ethane cracking furnace burning process to monitor system, it include the field visualized multispectral monitoring device of fire box temperature mounted on pyrolysis furnace radiant section, many reference amounts gas controlling device mounted on boiler tube tail portion, mounted on the coil outlet temperature monitoring device of coil outlet, the present invention can timely and accurately detect the operating mode that ethane cracking furnace is burnt, and operating mode provides basic foundation in order to control.

Description

Ethane cracking furnace burning process monitors system
Technical field
The invention belongs to petrochemical industry, more particularly to a kind of ethane cracking furnace burning process monitoring and control method and dress It sets.
Background technology
Ethylene is important one of industrial chemicals and demand and the maximum petroleum chemicals of output, more indicates one The petroleum chemical industry development level of a country.Tube cracking furnace is then the main device for producing ethylene.Hydrocarbon is radiated in pyrolysis furnace While Duan Fasheng steam cracking reactions, coking can be formed in boiler tube inner wall.Coke thermal resistance is big, while can cause tube fluid Pressure drop increases.After pyrolysis furnace runs a period of time, radiant section furnace tube wall temperature or quenching boiler is caused to go out due to coking Mouthful temperature reach capacity or Venturi tube before and after pressure difference when reaching capacity, it is necessary to burning could normal production run.In pyrolysis furnace In radiant coil burning process, 0 in boiler tube2With vapor under the high temperature conditions with coke gasification reaction, CO is generated2And CO.It is burning During coke, the air capacity in logical people's boiler tube gradually increases, and steam vapour amount is gradually reduced, CO and C02Content is first improved and is reduced afterwards. Work as C02When volume fraction is less than 0.2%, indicate that coke has been removed totally in radiant coil, burns end.
The length of pyrolysis furnace charring time, burn efficiency directly affect the yield of ethylene, fuel consumption, the boiler tube service life and The probability that " temperature runaway " occurs generates significant impact to the production of ethylene.Article《Ethane cracking furnace burns technical progress》Middle introduction It is various to burn method, but be all that char length is fixed according to preset condition, this method is easy in slight coking excessively to burn Coke, when severe coking, are easy to burn to be not thorough again, to make next operation lytic cycle shorten.So burning can be monitored in real time Burnt situation simultaneously carries out the online device that quickly burns of feedback regulation as research hotspot to technological parameter simultaneously.Such as《It is a kind of online The method for monitoring burn off coke process》《The autocontrol method of online rapid decoking of cracking furnace》《Pyrolysis furnace is quickly burnt online The exploitation and application of technology》Etc. O by monitoring burning process middle outlet flue gas is had studied in patents and article2、CO2、CO Content and coil outlet temperature (COT) are come the method that controls intake air and vapor flow and furnace tube temperature.But this method In be limited to monitoring means and can only monitor coil outlet temperature using thermocouple, and furnace tube temperature it is uneven caused by part temperature It spends height to detect by peephole by man-hour manually hand-held temperature-measuring gun, this detection mode has very big limitation.And Patent《A kind of visualization pyrolysis furnace charring state monitoring apparatus》Then use is monitored instead of COT by visualizing infrared temperature measurement apparatus Visualization infrared temperature measurement apparatus measured temperature while monitoring furnace tube temperature variation in real time, is replaced COT by thermocouple and temperature-measuring gun Temperature carries out feedback regulation, has certain advance.But visualization infrared temperature measurement apparatus can only survey tube skin temperature, for The reaction temperature monitoring burnt inside boiler tube is not an extraordinary selection.In addition during adjusting temperature temperature it is equal Even property and furnace flame situation are also a very important influence factor, and individually visualizing infrared temperature measurement apparatus can not see The case where fire detecting flame.So this patent is proposed using the field visualized multispectral monitoring device of fire box temperature on the basis of forefathers In conjunction with coil outlet temperature (COT), burns the composite monitoring device of tail gas many reference amounts gas-monitoring and realized by DCS system real When feedback regulation, improve the above problem, and by rational closed loop control logic, make to burn control more rationally more scientific.
Invention content
The purpose of the present invention is to provide a kind of ethane cracking furnace burning process to monitor system, timely and accurately detects ethylene The operating mode of pyrolysis furnace charring, in order to control operating mode basic foundation is provided.
To achieve the above object, present invention employs following technical schemes:A kind of ethane cracking furnace burning process monitoring system System, it is characterised in that:Include the field visualized multispectral monitoring device of fire box temperature mounted on pyrolysis furnace radiant section, is mounted on stove The many reference amounts gas controlling device of pipe tail portion is mounted on coil outlet temperature (COT) monitoring device of coil outlet;The burner hearth The multispectral monitoring device of visual for temperature field includes that can detect the visible light monitoring modular and infrared spectrum of two-dimensional space Monitoring modular, wherein visible light monitoring modular are for observing burner hearth flame combustion case;Infrared spectroscopy monitor module is used In monitoring outer surface of furnace tube thermo parameters method, real-time tracking local temperature is excessively high and warm liter is too fast position;The boiler tube goes out Mouth temperature (COT) monitoring device is for monitoring the reaction temperature burnt in boiler tube;The many reference amounts gas controlling device is for supervising CO/CO in tail gas is burnt in survey2/O2Changes of contents.
In ethane cracking furnace burning process, DCS control systems, which can start, burns program:The field visualized mostly light of fire box temperature Spectrum monitoring device will monitor the profiling temperatures of furnace tube outer wall, and locking part automatically in real time by infrared spectroscopy monitor module The excessively high region of temperature and temperature rise too fast region and carry out real-time tracking monitoring, and stove is observed by visible light monitoring modular State is extinguished or lighted to thorax flame combustion situation, analysis flame size shape;Thermocouple sensor is supervised in real time at coil outlet It surveys coil outlet temperature (COT) judgement and burns reaction temperature whether in setting range;Meanwhile many reference amounts gas controlling device is real When monitoring burn CO, CO in tail gas2、O2Concentration variation;DCS system, which will synchronize to receive above-mentioned monitoring data and carry out analysis, to be sentenced It has no progeny and corrects technological parameter in real time by controlling air mass flow, vapor flow, temperature-adjusting device, make its both holding in boiler tube By in range, and fast speed can be kept to burn.Core of the invention is to fire outer surface of furnace tube Temperature Distribution, furnace flame The analysis and judgement that burning situation, coil outlet temperature triplicity are got up into trip temperature increase reliability and accuracy, then tie CO, CO in tail gas are burnt in conjunction2、O2Concentration variation, keep monitoring data more complete more scientific.
Description of the drawings
Fig. 1 is the system the general frame of the present invention;
Fig. 2 is the field visualized multispectral monitoring device internal frame diagram of fire box temperature in the present invention;
Fig. 3 is many reference amounts gas controlling device internal frame diagram in the present invention.
Specific implementation mode
Referring to Fig. 1, ethane cracking furnace burning process monitors system, includes the fire box temperature mounted on pyrolysis furnace radiant section H Field visualized multispectral monitoring device 50 is mounted on many reference amounts gas controlling device 40 of boiler tube tail portion, is mounted on coil outlet Coil outlet temperature (COT) monitoring device 60;The field visualized multispectral monitoring device 50 of fire box temperature includes that can visit Survey the visible light monitoring modular 513 and infrared spectroscopy monitor module 512 of two-dimensional space, wherein visible light monitoring modular 513 for observing burner hearth flame combustion case;Infrared spectroscopy monitor module 512 is for monitoring outer surface of furnace tube temperature field point Cloth, the position that real-time tracking local temperature is excessively high and warm liter is too fast;Coil outlet temperature (COT) monitoring device 60 is used for The reaction temperature burnt in monitoring boiler tube;The many reference amounts gas controlling device 40 burns CO/CO in tail gas for monitoring2/O2Contain Amount variation.
It is learnt through studying, testing, the reaction temperature of burning inside boiler tube should be in 780~890 degrees centigrades;Described Data Analysis Services device is used to the data monitored carrying out preliminary treatment and is input to DCS control systems.The DCS controls System processed, is the core of closed-loop control, data cases for judging to monitor and according to the real-time adjusting control amount of judging result; The air/water vapor flow rate and temperature-adjusting device are carried out corresponding parameter by DCS system control and are adjusted;Described is aobvious Show device, every operating parameter of real-time display instrument.
Preferably, the data signal transmission of above-mentioned detection device acquisition is to Data Analysis Services module 70;DCS is controlled Molding block 80 receives the signal of Data Analysis Services module 70 and exports control signal control air-flow control device 10, water steams Air-flow amount control device 20 and fire box temperature control device 30 adjust the air/water vapor flow rate of input pyrolysis furnace radiant section H with And fire box temperature.Data Analysis Services module 70 includes summarizing to all information of fire box temperature, coil outlet temperature, gas And analysis.
The field visualized multispectral monitoring device 50 of fire box temperature includes optical signal receiving unit 51 and image data point Analyse unit 52 two parts, wherein optical signal receiving unit 51 include light-dividing device 511, it is infrared spectroscopy monitor module 512, visible Light spectrum monitoring module 513.
The main field visualized multispectral monitoring device 50 of fire box temperature includes optical signal reception system and image data Two parts of analysis system, wherein optical signal reception system include light-dividing device 511, infrared spectroscopy monitor module 512, visible light Spectrum monitoring module 513 etc., analysis of image data system for analyzing tube skin temperature and furnace flame situation in real time, in time The locking position that tube skin local temperature is excessively high or local temperature rise is too fast.The coil outlet temperature COT monitoring devices:With In burning reaction temperature in monitoring boiler tube, its multispectral monitoring device field visualized with fire box temperature 50 is combined can be to boiler tube Internal and external temperature situation carries out comprehensive descision, not only can guarantee in boiler tube and has burnt reaction in desirable temperature range, but also can in real time comprehensively Grasp outer surface of furnace tube profiling temperatures, especially local temperature abnormal conditions.
The many reference amounts gas controlling device 40 includes O2Laser 421, CO lasers 422, CO2Laser 423 and correspondence Laser drive 41, the coupled collimating module of laser 43 that laser provides exposes to high-temperature-resistant gas pond 44, boiler tube Through air-exhausting filtering device 46, the optical signal that photoelectric conversion device 47 acquires, which is converted to electric signal and is delivered to locking phase, to be put for gas in 45 Digital sampling and processing 49 is connected to after big device 48 again, the output of digital sampling and processing 49 displays signal to industry control display 491 displays.Digital sampling and processing 49 is mainly responsible for the calculating of gas concentration.
In said program, many reference amounts gas controlling device 40 includes three and is directed to O respectively2、CO、CO2It is tunable swash Light device, that is, O2Laser 421, CO lasers 422, CO2Laser 423, the present apparatus can monitor and differentiate O in real time2、CO、CO2Three The concentration information of kind gas.
Signal generating module 492 provides trigger signal to digital sampling and processing 49, lock-in amplifier 48 and laser Drive module 41.
Signal generating module 492 sends modulated signal to laser drive module 41, and laser drive module 41 will be according to The signal is modulated laser, and subsequent three lasers will send out the laser of different wave length for three kinds of gases, using High-temperature-resistant gas pond 44 is inputted after coupling collimating module 43.
Detecting system provided by the invention is that the control of system is the underlying parameter that DCS control systems provide, the DCS controls System processed is that the brain of whole system is used for feedback regulation air vapor flow and fire box temperature, still, if primary adjust Saving may well can make boiler tube " temperature runaway " phenomenon locally occur makes scorching process parameter it is ensured that under the premise of safety Optimum state is kept in real time.
Beneficial effects of the present invention are also embodied in following aspect:
1. the monitoring of pair ethane cracking furnace burning process is more comprehensively accurate:Monitoring outer surface of furnace tube temperature, boiler tube in real time The reaction temperature inside burnt, boiler tube burn CO/CO in tail gas2/O2Four changes of contents, furnace flame combustion state aspects.It can be with Excessively high to boiler tube local temperature or warm liter is too fast, flame adds burning waste of energy after boiler tube, coke burn off, burn be not thorough, stove Reaction temperature is burnt in pipe carries out comprehensive prevention not in optimized scope, the problems such as char length is long etc..
2. invention introduces the closed-loop control thought based on DCS control systems, using " it repeatedly adjusts, changes by a small margin, Gradually approach optimal value " control strategy, it is ensured that adjustment process is safer.
3. many reference amounts gas controlling device has used three tunable laser for corresponding to gas with various respectively in the present invention, Each gas concentration percentage is accurately obtained while three kinds of gas can be differentiated completely.
Fig. 3 is used only to calculate gas concentration, has handled industrial PC display density that later first can be at the scene, then That the Data Analysis Services module for uploading to Fig. 1 simultaneously summarizes.
Namely Fig. 3 is calculated just for gas concentration, and Fig. 1 is total, including fire box temperature, coil outlet temperature, gas All information summarize and analyze.

Claims (5)

1. a kind of ethane cracking furnace burning process monitors system, it is characterised in that:Stove including being mounted on pyrolysis furnace radiant section (H) The field visualized multispectral monitoring device (50) of bore temperature is mounted on many reference amounts gas controlling device (40) of boiler tube tail portion, installation In coil outlet temperature (COT) monitoring device (60) of coil outlet;The field visualized multispectral monitoring device of fire box temperature (50) include the visible light monitoring modular (513) and infrared spectroscopy monitor module (512) that can detect two-dimensional space, wherein Visible light monitoring modular (513) is for observing burner hearth flame combustion case;Infrared spectroscopy monitor module (512) is for supervising Outer surface of furnace tube thermo parameters method is surveyed, the position that real-time tracking local temperature is excessively high and warm liter is too fast;The coil outlet temperature Degree (COT) monitoring device (60) is for monitoring the reaction temperature burnt in boiler tube;The many reference amounts gas controlling device (40) is used CO/CO in tail gas is burnt in monitoring2/O2Changes of contents.
2. ethane cracking furnace burning process according to claim 1 monitors system, it is characterised in that:Above-mentioned detection device is adopted The data signal transmission of collection is to Data Analysis Services module (70);DCS control module (80) receives Data Analysis Services module (70) signal simultaneously exports control signal control air-flow control device (10), vapor flow control device (20) and burner hearth Temperature control equipment (30) adjusts the air/water vapor flow rate and fire box temperature of input pyrolysis furnace radiant section (H).
3. monitoring system according to the ethane cracking furnace burning process described in claim 1, it is characterised in that:The fire box temperature Field visualized multispectral monitoring device (50) includes (52) two portions of optical signal receiving unit (51) and analysis of image data unit Point, wherein optical signal receiving unit (51) includes light-dividing device (511), infrared spectroscopy monitor module (512), visible light prison Survey module (513).
4. monitoring system according to the ethane cracking furnace burning process described in claim 1, it is characterised in that:The many reference amounts gas Body monitoring device (40) includes O2Laser (421), CO lasers (422), CO2Laser (423) and the driving of corresponding laser Device (41), the coupled collimating module of laser (43) that laser provides expose to high-temperature-resistant gas pond (44), and boiler tube (45) is interior Gas through air-exhausting filtering device (46), the optical signal of photoelectric conversion device (47) acquisition, which is converted to electric signal and is delivered to locking phase, to be put It is connected to digital sampling and processing (49) again after big device (48).
5. monitoring system according to the ethane cracking furnace burning process described in claim 1, it is characterised in that:Signal generating module (492) trigger signal is provided to digital sampling and processing (49), lock-in amplifier (48) and laser drive module (41).
CN201810814316.2A 2018-07-23 2018-07-23 Ethane cracking furnace burning process monitors system Withdrawn CN108803534A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN110343541A (en) * 2019-06-18 2019-10-18 广东石油化工学院 A kind of cracking furnace pipe intelligence coking monitoring side cloud collaborative platform and its working method
CN110804746A (en) * 2019-12-16 2020-02-18 百色百矿集团产业技术研究院有限公司 Temperature on-line detection system and temperature detection method for electrolytic cell shell
CN112394682A (en) * 2020-11-24 2021-02-23 河南中中中环保设备有限公司 Thermal cracking steam boiler linkage control system
CN115505415A (en) * 2022-08-25 2022-12-23 江苏博颂能源科技有限公司 Catalytic cracking pilot scale is multidirectional closed detecting element for device

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CN102658214A (en) * 2012-05-14 2012-09-12 神华集团有限责任公司 Catalyst regenerating equipment for preparing methanol into olefin and method for regenerating catalyst by using same
CN105467939A (en) * 2014-09-04 2016-04-06 中国石油化工股份有限公司 Optimization method for production and operation of ethylene cracking furnace
CN106970542A (en) * 2017-03-27 2017-07-21 合肥瑞石测控工程技术有限公司 One kind visualization pyrolysis furnace charring state monitoring apparatus
CN208421626U (en) * 2018-07-23 2019-01-22 合肥金星机电科技发展有限公司 Ethane cracking furnace burning process monitors system

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CN1388340A (en) * 2001-05-25 2003-01-01 王满家 Method and system for measuring combustion radiation energy and temperature field of boiler and controlling combustion
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Publication number Priority date Publication date Assignee Title
CN110343541A (en) * 2019-06-18 2019-10-18 广东石油化工学院 A kind of cracking furnace pipe intelligence coking monitoring side cloud collaborative platform and its working method
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CN112394682A (en) * 2020-11-24 2021-02-23 河南中中中环保设备有限公司 Thermal cracking steam boiler linkage control system
CN115505415A (en) * 2022-08-25 2022-12-23 江苏博颂能源科技有限公司 Catalytic cracking pilot scale is multidirectional closed detecting element for device
CN115505415B (en) * 2022-08-25 2023-09-22 江苏博颂能源科技有限公司 Multidirectional closed detection unit for catalytic cracking pilot plant

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