CN108795551A - A kind of antimicrobial form metalworking fluid - Google Patents

A kind of antimicrobial form metalworking fluid Download PDF

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Publication number
CN108795551A
CN108795551A CN201810560491.3A CN201810560491A CN108795551A CN 108795551 A CN108795551 A CN 108795551A CN 201810560491 A CN201810560491 A CN 201810560491A CN 108795551 A CN108795551 A CN 108795551A
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CN
China
Prior art keywords
grams
acid
dimethyl
sodium
antimicrobial form
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810560491.3A
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Chinese (zh)
Inventor
束洋
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Hubei Sanhuan Chemical New Material Ltd By Share Ltd
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Hubei Sanhuan Chemical New Material Ltd By Share Ltd
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Priority to CN201810560491.3A priority Critical patent/CN108795551A/en
Publication of CN108795551A publication Critical patent/CN108795551A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/284—Esters of aromatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of antimicrobial form metalworking fluids comprising with the following component of weight：49~66 grams of oleic acid, 21~25 grams of dimethyl chloride siloxy dimethyl-silicon ether, 20~30 grams of phosphoric acid, 5~8 grams of zinc sulfate, 2~6 grams of sodium sulfite, 14~22 grams of triethanolamine, 3~9 grams of b propanol, 300~500 grams of water, 10~20 grams of propionic acid, 12~18 grams of 3- ethoxy anilids methanesulfonic sodium.Pass through a variety of antiseptic mating reactions in above-mentioned cutting fluid, the antibacterial effect (recycling 30 days odorless) of cutting fluid can effectively be promoted, make it while the lubrication of cutting fluid, corrosion protection, corrosion inhibition can be reached, and meets the requirements of GB/T6144-2010.

Description

A kind of antimicrobial form metalworking fluid
Technical field
The present invention relates to a kind of cutting fluids, and in particular to a kind of antimicrobial form metalworking fluid.
Background technology
Metalworking fluid has considerable effect in metal cutting, Grinding Process.It is in mechanical processing Using extremely wide.The more check weighings of research and development of existing cutting fluid but have ignored one and critically important ask in the improvement to above-mentioned function Topic, i.e. cutting fluid go bad smelly problem.Existing cutting fluid is easy to grow bacterium, will send out evil in a short period of time It is smelly, the health of people is caused greatly to damage.
Invention content
To solve the above problems, this invention address that provide a kind of antimicrobial form metalworking fluid, it is set to have preferable anti- Bacterium effect.
The invention discloses a kind of antimicrobial form metalworking fluids comprising with the following component of weight：Oleic acid 49 ~66 grams, 21~25 grams of dimethyl chloride siloxy dimethyl-silicon ether, 20~30 grams of phosphoric acid, 5~8 grams of zinc sulfate, sodium sulfite 2~ 6 grams, 14~22 grams of triethanolamine, 3~9 grams of b propanol, 300~500 grams of water, 10~20 grams of propionic acid, 3- ethoxy anilid first 12~18 grams of sodium sulfonate.
Preferably, the antimicrobial form metalworking fluid includes the following component with weight：66 grams of oleic acid, two 23 grams of methyl chloride siloxy dimethyl-silicon ether, 20 grams of phosphoric acid, 5 grams of zinc sulfate, 4 grams of sodium sulfite, 18 grams of triethanolamine, second third 3 grams of alcohol, 500 grams of water, 10 grams of propionic acid, 14 grams of 3- ethoxy anilids methanesulfonic sodium, 5 grams of ethyl p-hydroxybenzoate.
Preferably, the antimicrobial form metalworking fluid includes the following component with weight：56 grams of oleic acid, two 21 grams of methyl chloride siloxy dimethyl-silicon ether, 30 grams of phosphoric acid, 8 grams of zinc sulfate, 2 grams of sodium sulfite, 14 grams of triethanolamine, second third 9 grams of alcohol, 400 grams of water, 20 grams of propionic acid, 12 grams of 3- ethoxy anilids methanesulfonic sodium, 20 grams of ethyl p-hydroxybenzoate.
Preferably, the antimicrobial form metalworking fluid includes the following component with weight：49 grams of oleic acid, two 25 grams of methyl chloride siloxy dimethyl-silicon ether, 25 grams of phosphoric acid, 6 grams of zinc sulfate, 6 grams of sodium sulfite, 22 grams of triethanolamine, second third 6 grams of alcohol, 300 grams of water, 15 grams of propionic acid, 18 grams of 3- ethoxy anilids methanesulfonic sodium, 10 grams of ethyl p-hydroxybenzoate.
By a variety of antiseptic mating reactions in above-mentioned cutting fluid, the antibacterial effect of cutting fluid can be effectively promoted (recycle 30 days odorless) makes it while can reach the lubrication of cutting fluid, corrosion protection, corrosion inhibition, and meet GB/ The requirements of T6144-2010.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following specific examples, to the present invention It is described in further detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Embodiment 1：
The metalworking fluid of the present embodiment comprising：66 grams of oleic acid, 23 grams of dimethyl chloride siloxy dimethyl-silicon ether, phosphorus 20 grams of acid, 5 grams of zinc sulfate, 4 grams of sodium sulfite, 18 grams of triethanolamine, 3 grams of b propanol, 500 grams of water, 10 grams of propionic acid, 3- ethoxies 14 grams of anilid methanesulfonic sodium, 5 grams of ethyl p-hydroxybenzoate.
Embodiment 2：
The metalworking fluid of the present embodiment comprising：56 grams of oleic acid, 21 grams of dimethyl chloride siloxy dimethyl-silicon ether, phosphorus 30 grams of acid, 8 grams of zinc sulfate, 2 grams of sodium sulfite, 14 grams of triethanolamine, 9 grams of b propanol, 400 grams of water, 20 grams of propionic acid, 3- ethoxies 12 grams of anilid methanesulfonic sodium, 20 grams of ethyl p-hydroxybenzoate.
Embodiment 3：
The metalworking fluid of the present embodiment comprising：49 grams of oleic acid, 25 grams of dimethyl chloride siloxy dimethyl-silicon ether, phosphorus 25 grams of acid, 6 grams of zinc sulfate, 6 grams of sodium sulfite, 22 grams of triethanolamine, 6 grams of b propanol, 300 grams of water, 15 grams of propionic acid, 3- ethoxies 18 grams of anilid methanesulfonic sodium, 10 grams of ethyl p-hydroxybenzoate.
The beneficial effects of the invention are as follows：By a variety of antiseptic mating reactions in above-mentioned cutting fluid, can effectively carry The antibacterial effect (recycle 30 days odorless) for rising cutting fluid makes it while can reach the lubrication of cutting fluid, corrosion protection, inhibition Effect, and meet the requirements of GB/T6144-2010.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those skilled in the art, It, can also be to making several modifications and improvements without departing from the spirit of the invention, these modification and improvement should all be received Enter protection scope of the present invention.

Claims (4)

1. a kind of antimicrobial form metalworking fluid, which is characterized in that include the following component with weight：Oleic acid 49~66 Gram, 21~25 grams of dimethyl chloride siloxy dimethyl-silicon ether, 20~30 grams of phosphoric acid, 5~8 grams of zinc sulfate, 2~6 grams of sodium sulfite, 14~22 grams of triethanolamine, 3~9 grams of b propanol, 300~500 grams of water, 10~20 grams of propionic acid, 3- ethoxy anilid methanesulfonic acids 12~18 grams of sodium.
2. antimicrobial form metalworking fluid as described in claim 1, which is characterized in that include with following group of weight Point：66 grams of oleic acid, 23 grams of dimethyl chloride siloxy dimethyl-silicon ether, 20 grams of phosphoric acid, 5 grams of zinc sulfate, 4 grams of sodium sulfite, three second 18 grams of hydramine, 3 grams of b propanol, 500 grams of water, 10 grams of propionic acid, 14 grams of 3- ethoxy anilids methanesulfonic sodium, P-hydroxybenzoic acid second 5 grams of fat.
3. antimicrobial form metalworking fluid as described in claim 1, which is characterized in that include with following group of weight Point：56 grams of oleic acid, 21 grams of dimethyl chloride siloxy dimethyl-silicon ether, 30 grams of phosphoric acid, 8 grams of zinc sulfate, 2 grams of sodium sulfite, three second 14 grams of hydramine, 9 grams of b propanol, 400 grams of water, 20 grams of propionic acid, 12 grams of 3- ethoxy anilids methanesulfonic sodium, P-hydroxybenzoic acid second 20 grams of fat.
4. antimicrobial form metalworking fluid as described in claim 1, which is characterized in that include with following group of weight Point：49 grams of oleic acid, 25 grams of dimethyl chloride siloxy dimethyl-silicon ether, 25 grams of phosphoric acid, 6 grams of zinc sulfate, 6 grams of sodium sulfite, three second 22 grams of hydramine, 6 grams of b propanol, 300 grams of water, 15 grams of propionic acid, 18 grams of 3- ethoxy anilids methanesulfonic sodium, P-hydroxybenzoic acid second 10 grams of fat.
CN201810560491.3A 2018-05-25 2018-05-25 A kind of antimicrobial form metalworking fluid Pending CN108795551A (en)

Priority Applications (1)

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CN201810560491.3A CN108795551A (en) 2018-05-25 2018-05-25 A kind of antimicrobial form metalworking fluid

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Application Number Priority Date Filing Date Title
CN201810560491.3A CN108795551A (en) 2018-05-25 2018-05-25 A kind of antimicrobial form metalworking fluid

Publications (1)

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CN108795551A true CN108795551A (en) 2018-11-13

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007186537A (en) * 2006-01-11 2007-07-26 Yasuo Fukutani Cutting fluid
CN101613634A (en) * 2009-07-28 2009-12-30 武汉玻尔科技有限公司 A kind of high-property water-based emulsion cutting fluid composite
CN101955843A (en) * 2010-09-28 2011-01-26 上海宏泽化工有限公司 Emulsified cutting fluid complexing agent
CN103695130A (en) * 2013-12-20 2014-04-02 海安县吉程机械有限公司 Environment-friendly antirust lubricant
CN105296126A (en) * 2015-12-02 2016-02-03 苏州捷德瑞精密机械有限公司 Environment-friendly water-based antirust cutting fluid and preparation method thereof
CN105985848A (en) * 2015-02-27 2016-10-05 全椒县兴盛化工厂 Environment-friendly waterborne cutting fluid
CN106047464A (en) * 2016-06-29 2016-10-26 无锡伊佩克科技有限公司 Preparation method of water-based micro-emulsification cutting fluid
CN106350164A (en) * 2016-08-18 2017-01-25 深圳市前海龙达新能源有限公司 Antibacterial cutting oil and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007186537A (en) * 2006-01-11 2007-07-26 Yasuo Fukutani Cutting fluid
CN101613634A (en) * 2009-07-28 2009-12-30 武汉玻尔科技有限公司 A kind of high-property water-based emulsion cutting fluid composite
CN101955843A (en) * 2010-09-28 2011-01-26 上海宏泽化工有限公司 Emulsified cutting fluid complexing agent
CN103695130A (en) * 2013-12-20 2014-04-02 海安县吉程机械有限公司 Environment-friendly antirust lubricant
CN105985848A (en) * 2015-02-27 2016-10-05 全椒县兴盛化工厂 Environment-friendly waterborne cutting fluid
CN105296126A (en) * 2015-12-02 2016-02-03 苏州捷德瑞精密机械有限公司 Environment-friendly water-based antirust cutting fluid and preparation method thereof
CN106047464A (en) * 2016-06-29 2016-10-26 无锡伊佩克科技有限公司 Preparation method of water-based micro-emulsification cutting fluid
CN106350164A (en) * 2016-08-18 2017-01-25 深圳市前海龙达新能源有限公司 Antibacterial cutting oil and preparation method thereof

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Application publication date: 20181113

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