CN108795182A - A kind of Interior decorative paints capable of purifying air and preparation method thereof - Google Patents

A kind of Interior decorative paints capable of purifying air and preparation method thereof Download PDF

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Publication number
CN108795182A
CN108795182A CN201810722190.6A CN201810722190A CN108795182A CN 108795182 A CN108795182 A CN 108795182A CN 201810722190 A CN201810722190 A CN 201810722190A CN 108795182 A CN108795182 A CN 108795182A
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parts
interior decorative
purifying air
decorative paints
pretreatment
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俞克波
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Hefei Still Decoration Engineering Co Ltd
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Hefei Still Decoration Engineering Co Ltd
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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    • C08B37/00Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0024Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
    • C08B37/00272-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
    • C08B37/003Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
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    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
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    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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Abstract

The invention discloses a kind of Interior decorative paints capable of purifying air, include the raw material of following parts by weight:32-38 parts of aqueous acrylic emulsion, 18-22 parts of linseed oil fatty acid, 18-22 parts of catalysis material of pretreatment volcano float stone doping, 6-10 parts of modification biological charcoal, 5-9 parts of dimethylbenzene, 2-6 parts of bamboo charcoal, 3-5 parts of nano phase ag_2 o, 3-5 parts of tourmaline powder, 1-3 parts of turpentine oil, 3-6 parts of rosin, 18-24 parts of deionized water.The object of the present invention is to provide a kind of Interior decorative paints capable of purifying air, the paint is good except aldehyde, bactericidal effect, has higher use value and good application prospect.

Description

A kind of Interior decorative paints capable of purifying air and preparation method thereof
Technical field
The present invention relates to interior paint technical fields, and in particular to a kind of Interior decorative paints and its system capable of purifying air Preparation Method.
Background technology
Paint be thickness oil colour, it is inflammable in the case of not dry, it is not soluble in water, be slightly soluble in fat, dissolve in alcohol, aldehyde, ether, Benzene, alkane are soluble in gasoline, kerosene, diesel oil, no matter paint kind or form, are all by film forming matter, subsidiary film forming matter With three kinds of base substance compositions of auxiliary film forming matter, subsidiary film forming matter:Including various pigment, extender pigment, rust resisting pigment, face Material provides color and covering power for paint film, improves the protective value and decorative effect of paint, oil can be improved in the pigment of good weatherability The service life of paint, extender pigment can increase the thickness of paint film, and using itself sheet, the performance of acicular texture passes through face The accumulation of material is folded multiple, forms the paint film of fish scale-shaped, improves the service life of paint film, improves water proofing property and rust-proof effect;Antirust face Material prevents body surface by air, chemicals attack, metal surface is become rusty by itself physics and chemical anti-rust action Erosion.
Existing Chinese patent literature(Publication number:CN105400244B)Disclose a kind of waterborne inorganic einc-rich primer and preparation Method, wherein waterborne inorganic einc-rich primer, including first component and second component;The first component includes the raw material group of following parts by weight At:60~95 parts of high mode aqueous inorganic zinc-rich coating resins, 1~20 part of water-compatible amino resin, 0.1~1 part of antifoaming agent;The second Component includes the raw material composition of following parts by weight:40~90 parts of zinc powder, 10~60 parts of filler, 0.5~10 part of anti-settling agent, wherein filling out Material is nano-calcination-kaolinite can greatly increase the anticorrosive property of paint film, while by nanometer by adding nano-calcination-kaolinite Calcined kaolin participates in the fine and close paint film to be formed, and road paints under energy direct spraying, not will produce bubble and pin hole, which adopts Raw material is mainly high mode aqueous inorganic zinc-rich coating resins, water-compatible amino resin, and raw material does not have purification air effect.
Chinese patent literature(Publication number:CN104327571B)Disclose a kind of wrinkle paint, it is characterised in that including with The component of lower mass percent:60-65% acrylic resins, 20-25% amine resins, 8-10% acrylic acid, 3-4% enclosed type sulphur Acid, 2-3% ammonium hydroxide and the anti-settling waxes of 1-2%, though the raw material environmental protection of the invention, except formaldehyde, bactericidal effect are poor.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of Interior decorative paints capable of purifying air, should Paint is good except aldehyde, bactericidal effect, has higher use value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that:
The present invention provides a kind of Interior decorative paints capable of purifying air, include the raw material of following parts by weight:
32-38 parts of aqueous acrylic emulsion, 18-22 parts of linseed oil fatty acid, pretreatment volcano float stone doping catalysis material 18- 22 parts, 6-10 parts of modification biological charcoal, 5-9 parts of dimethylbenzene, 2-6 parts of bamboo charcoal, 3-5 parts of nano phase ag_2 o, 3-5 parts of tourmaline powder, pine 1-3 parts of fuel-economizing, 3-6 parts of rosin, 18-24 parts of deionized water.
Preferably, the Interior decorative paints capable of purifying air include the raw material of following parts by weight:
34-38 parts of aqueous acrylic emulsion, 20-22 parts of linseed oil fatty acid, pretreatment volcano float stone doping catalysis material 19- 22 parts, 8-10 parts of modification biological charcoal, 6-9 parts of dimethylbenzene, 3-6 parts of bamboo charcoal, 4-5 parts of nano phase ag_2 o, 4-5 parts of tourmaline powder, pine 2-3 parts of fuel-economizing, 4-6 parts of rosin, 20-24 parts of deionized water.
Preferably, the Interior decorative paints capable of purifying air include the raw material of following parts by weight:
35 parts of aqueous acrylic emulsion, 20 parts of catalysis material of pretreatment volcano float stone doping, is modified 20 parts of linseed oil fatty acid 8 parts of charcoal, 4 parts of bamboo charcoal, 4 parts of nano phase ag_2 o, 4 parts of tourmaline powder, 2 parts of turpentine oil, 4.5 parts of rosin, is gone 7 parts of dimethylbenzene 21 parts of ionized water.
Preferably, pretreatment volcano float stone doping catalysis material is pretreatment volcano float stone, nano-photo catalytic material Material is according to weight ratio 5:1 is mixed.
Preferably, pretreatment volcano float stone is added to the water for volcano float stone and carries out ultrasonic disperse, disperses 6- 10min, it is 10-20% ferric chloride solutions that mass fraction, which is then added, is stirred 12-16min to get pretreatment volcano float stone.
Preferably, the nano-photocatalyst material is nano titanic oxide sol, cross-linked chitosan according to weight ratio 3:The mixture of 2 compositions.
Preferably, it is matrix that the cross-linked chitosan preparation method, which is chitosan acetic acid solution, and polyethoxy fatty alcohol is Dispersant, glutaraldehyde as cross linker are crosslinked by lotion and are made.
Preferably, the modification biological charcoal preparation method is that charcoal reacts 1-2h in nitration mixture, is then re-fed into microwave Expansion 35-45min is carried out in stove, expansion temperature is 225-235 DEG C.
Preferably, the nitration mixture is the concentrated sulfuric acid, concentrated nitric acid according to weight ratio 3:The mixture of 2 compositions.
The present invention also provides a kind of methods preparing Interior decorative paints capable of purifying air, include the following steps:
Step 1 weighs each component raw material as required;
Step 2 sequentially adds aqueous acrylic emulsion, linseed oil fatty acid, dimethylbenzene, turpentine oil, rosin, deionized water In homogenizer, rotating speed 210-220r/min stirs 35-45min, and mixture A is made;
Step 3, by mixture A, modification biological charcoal, pretreatment volcano float stone doping catalysis material, bamboo charcoal, nano phase ag_2 o, Tourmaline powder sequentially adds in high-speed mixer, be sufficiently stirred so that all material be uniformly mixed, mixing speed 750-850r/ Min, mixing time 1-2 hours to get the present invention Interior decorative paints capable of purifying air.
Compared with prior art, the present invention has following advantageous effect:
(1)Using aqueous acrylic emulsion, linseed oil fatty acid, dimethylbenzene, turpentine oil etc. as paint base, addition changes the present invention Property charcoal, pretreatment volcano float stone doping catalysis material, bamboo charcoal, nano phase ag_2 o, tourmaline powder be formaldehyde absorbing, sterilization Play respective action, formaldehyde absorbing, sterilization and other effects then can be improved in mutual associated between each raw material.
(2)Charcoal is bio-organic materials high temperature pyrolysis product under anaerobic environment, is commonly used for heavy metal absorbent, and Modification biological charcoal is improved surface area by the present invention by enhancing its surface-active, then by expansion, then can effectively improve suction The impurity such as attached formaldehyde, harmful substance.
(3)Volcano float stone have good weatherability, corrosion resistance is good, have it is wear-resistant, after iron chloride is handled, carry High porosity, nano-photocatalyst material are the compound of nano titanic oxide sol, cross-linked chitosan composition, promote pretreatment fire Dispersion of the mountain float stone in paint then improves formaldehyde adsorption effect, pre-processes volcano float stone dopen Nano photocatalysis material in addition Material activity is strong, plays synergistic effect with sterilization materials such as nano silvers on dispersion base, then enhances antibacterial effect.
(4)3 purifying formaldehyde rate of the embodiment of the present invention is relative to comparative example 4, and purifying rate improves 45.9%, golden yellow grape Coccus sterilizing rate improves 47.7%, is obtained from comparative example 1-3, pretreatment volcano float stone doping catalysis material, modification biological Charcoal can PARA FORMALDEHYDE PRILLS(91,95) purifies, synergistic effect is played in staphylococcus aureus sterilization.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to In the scope of protection of the invention.
Embodiment 1.
A kind of Interior decorative paints capable of purifying air of the present embodiment, include the raw material of following parts by weight:
32 parts of aqueous acrylic emulsion, 18 parts of catalysis material of pretreatment volcano float stone doping, is modified 18 parts of linseed oil fatty acid 6 parts of charcoal, 5 parts of dimethylbenzene, 2 parts of bamboo charcoal, 3 parts of nano phase ag_2 o, 3 parts of tourmaline powder, 1 part of turpentine oil, 3 parts of rosin, go from 18 parts of sub- water.
The pretreatment volcano float stone doping catalysis material of the present embodiment is pretreatment volcano float stone, nano-photocatalyst material According to weight ratio 5:1 is mixed.
The pretreatment volcano float stone of the present embodiment is added to the water for volcano float stone and carries out ultrasonic disperse, disperses 6-10min, It is 10% ferric chloride solution that mass fraction, which is then added, is stirred 12min to get pretreatment volcano float stone.
The nano-photocatalyst material of the present embodiment is nano titanic oxide sol, cross-linked chitosan according to weight ratio 3:2 groups At mixture.
The cross-linked chitosan preparation method of the present embodiment is that chitosan acetic acid solution is matrix, and polyethoxy fatty alcohol is point Powder, glutaraldehyde as cross linker are crosslinked by lotion and are made.
The modification biological charcoal preparation method of the present embodiment is that charcoal reacts 1h in nitration mixture, is then re-fed into micro-wave oven Expansion 35min is carried out, expansion temperature is 225 DEG C.
The nitration mixture of the present embodiment is the concentrated sulfuric acid, concentrated nitric acid according to weight ratio 3:The mixture of 2 compositions.
A kind of method preparing Interior decorative paints capable of purifying air of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Step 2 sequentially adds aqueous acrylic emulsion, linseed oil fatty acid, dimethylbenzene, turpentine oil, rosin, deionized water In homogenizer, rotating speed 210r/min stirs 35min, and mixture A is made;
Step 3, by mixture A, modification biological charcoal, pretreatment volcano float stone doping catalysis material, bamboo charcoal, nano phase ag_2 o, Tourmaline powder sequentially adds in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 750r/min is stirred 1 hour time is mixed to get the Interior decorative paints capable of purifying air of the present invention.
Embodiment 2.
A kind of Interior decorative paints capable of purifying air of the present embodiment, include the raw material of following parts by weight:
38 parts of aqueous acrylic emulsion, 22 parts of catalysis material of pretreatment volcano float stone doping, is modified 22 parts of linseed oil fatty acid 10 parts of charcoal, 9 parts of dimethylbenzene, 6 parts of bamboo charcoal, 5 parts of nano phase ag_2 o, 5 parts of tourmaline powder, 3 parts of turpentine oil, 6 parts of rosin, go from 24 parts of sub- water.
The pretreatment volcano float stone doping catalysis material of the present embodiment is pretreatment volcano float stone, nano-photocatalyst material According to weight ratio 5:1 is mixed.
The pretreatment volcano float stone of the present embodiment is added to the water for volcano float stone and carries out ultrasonic disperse, disperses 10min, with It is 20% ferric chloride solution that mass fraction is added afterwards, is stirred 16min to get pretreatment volcano float stone.
The nano-photocatalyst material of the present embodiment is nano titanic oxide sol, cross-linked chitosan according to weight ratio 3:2 groups At mixture.
The cross-linked chitosan preparation method of the present embodiment is that chitosan acetic acid solution is matrix, and polyethoxy fatty alcohol is point Powder, glutaraldehyde as cross linker are crosslinked by lotion and are made.
The modification biological charcoal preparation method of the present embodiment is that charcoal reacts 2h in nitration mixture, is then re-fed into micro-wave oven Expansion 45min is carried out, expansion temperature is 235 DEG C.
The nitration mixture of the present embodiment is the concentrated sulfuric acid, concentrated nitric acid according to weight ratio 3:The mixture of 2 compositions.
A kind of method preparing Interior decorative paints capable of purifying air of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Step 2 sequentially adds aqueous acrylic emulsion, linseed oil fatty acid, dimethylbenzene, turpentine oil, rosin, deionized water In homogenizer, rotating speed 220r/min stirs 45min, and mixture A is made;
Step 3, by mixture A, modification biological charcoal, pretreatment volcano float stone doping catalysis material, bamboo charcoal, nano phase ag_2 o, Tourmaline powder sequentially adds in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 850r/min is stirred Time 2 h is mixed to get the Interior decorative paints capable of purifying air of the present invention.
Embodiment 3.
A kind of Interior decorative paints capable of purifying air of the present embodiment, include the raw material of following parts by weight:
35 parts of aqueous acrylic emulsion, 20 parts of catalysis material of pretreatment volcano float stone doping, is modified 20 parts of linseed oil fatty acid 8 parts of charcoal, 4 parts of bamboo charcoal, 4 parts of nano phase ag_2 o, 4 parts of tourmaline powder, 2 parts of turpentine oil, 4.5 parts of rosin, is gone 7 parts of dimethylbenzene 21 parts of ionized water.
The pretreatment volcano float stone doping catalysis material of the present embodiment is pretreatment volcano float stone, nano-photocatalyst material According to weight ratio 5:1 is mixed.
The pretreatment volcano float stone of the present embodiment is added to the water for volcano float stone and carries out ultrasonic disperse, divides 8min, then Addition mass fraction is 15% ferric chloride solution, is stirred 14min to get pretreatment volcano float stone.
The nano-photocatalyst material of the present embodiment is nano titanic oxide sol, cross-linked chitosan according to weight ratio 3:2 groups At mixture.
The cross-linked chitosan preparation method of the present embodiment is that chitosan acetic acid solution is matrix, and polyethoxy fatty alcohol is point Powder, glutaraldehyde as cross linker are crosslinked by lotion and are made.
The modification biological charcoal preparation method of the present embodiment is that charcoal reacts 1.5h in nitration mixture, is then re-fed into micro-wave oven In carry out expansion 40min, expansion temperature is 230 DEG C.
The nitration mixture of the present embodiment is the concentrated sulfuric acid, concentrated nitric acid according to weight ratio 3:The mixture of 2 compositions.
A kind of method preparing Interior decorative paints capable of purifying air of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Step 2 sequentially adds aqueous acrylic emulsion, linseed oil fatty acid, dimethylbenzene, turpentine oil, rosin, deionized water In homogenizer, rotating speed 215r/min stirs 40min, and mixture A is made;
Step 3, by mixture A, modification biological charcoal, pretreatment volcano float stone doping catalysis material, bamboo charcoal, nano phase ag_2 o, Tourmaline powder sequentially adds in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 800r/min is stirred 1.5 hours time is mixed to get the Interior decorative paints capable of purifying air of the present invention.
Comparative example 1.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with pretreatment volcano float stone doping light Catalysis material.
Comparative example 2.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with modification biological charcoal.
Comparative example 3.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with pretreatment volcano float stone doping light Catalysis material, modification biological charcoal.
Comparative example 4.
Chinese patent literature(Publication number:CN105400244B)It discloses real in a kind of waterborne inorganic einc-rich primer and preparation method Apply the raw material and method of example 1.
Embodiment 3 and comparative example 1-4 the performance test results are as follows
Purifying formaldehyde rate(%) Staphylococcus aureus sterilizing rate(%)
Embodiment 3 67.2 99.4
Comparative example 1 55.4 97.6
Comparative example 2 61.7 98.8
Comparative example 3 45.1 93.2
Comparative example 4 21.3 51.7
3 purifying formaldehyde rate of the embodiment of the present invention is relative to comparative example 4, and purifying rate improves 45.9%, staphylococcus aureus sterilization Rate improves 47.7%, is obtained from comparative example 1-3, and pretreatment volcano float stone doping catalysis material, modification biological charcoal can be right Synergistic effect is played in purifying formaldehyde, staphylococcus aureus sterilization.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (10)

1. a kind of Interior decorative paints capable of purifying air, which is characterized in that include the raw material of following parts by weight:
32-38 parts of aqueous acrylic emulsion, 18-22 parts of linseed oil fatty acid, pretreatment volcano float stone doping catalysis material 18- 22 parts, 6-10 parts of modification biological charcoal, 5-9 parts of dimethylbenzene, 2-6 parts of bamboo charcoal, 3-5 parts of nano phase ag_2 o, 3-5 parts of tourmaline powder, pine 1-3 parts of fuel-economizing, 3-6 parts of rosin, 18-24 parts of deionized water.
2. a kind of Interior decorative paints capable of purifying air according to claim 1, which is characterized in that described to purify sky The Interior decorative paints of gas include the raw material of following parts by weight:
34-38 parts of aqueous acrylic emulsion, 20-22 parts of linseed oil fatty acid, pretreatment volcano float stone doping catalysis material 19- 22 parts, 8-10 parts of modification biological charcoal, 6-9 parts of dimethylbenzene, 3-6 parts of bamboo charcoal, 4-5 parts of nano phase ag_2 o, 4-5 parts of tourmaline powder, pine 2-3 parts of fuel-economizing, 4-6 parts of rosin, 20-24 parts of deionized water.
3. a kind of Interior decorative paints capable of purifying air according to claim 2, which is characterized in that described to purify sky The Interior decorative paints of gas include the raw material of following parts by weight:
35 parts of aqueous acrylic emulsion, 20 parts of catalysis material of pretreatment volcano float stone doping, is modified 20 parts of linseed oil fatty acid 8 parts of charcoal, 4 parts of bamboo charcoal, 4 parts of nano phase ag_2 o, 4 parts of tourmaline powder, 2 parts of turpentine oil, 4.5 parts of rosin, is gone 7 parts of dimethylbenzene 21 parts of ionized water.
4. a kind of Interior decorative paints capable of purifying air according to claim 1, which is characterized in that the pretreatment fire Mountain float stone doping catalysis material is pretreatment volcano float stone, nano-photocatalyst material according to weight ratio 5:1 is mixed.
5. a kind of Interior decorative paints capable of purifying air according to claim 4, which is characterized in that the pretreatment fire Mountain float stone is added to the water for volcano float stone and carries out ultrasonic disperse, disperses 6-10min, and mass fraction is then added as 10-20% chlorine Change ferrous solution, is stirred 12-16min to get pretreatment volcano float stone.
6. a kind of Interior decorative paints capable of purifying air according to claim 4, which is characterized in that the nanometer Catalysis material is nano titanic oxide sol, cross-linked chitosan according to weight ratio 3:The mixture of 2 compositions.
7. a kind of Interior decorative paints capable of purifying air according to claim 6, which is characterized in that the crosslinking shell is poly- Sugared preparation method is that chitosan acetic acid solution is matrix, and polyethoxy fatty alcohol is dispersant, glutaraldehyde as cross linker, by breast Liquid crosslinking is made.
8. a kind of Interior decorative paints capable of purifying air according to claim 1, which is characterized in that the modification biological Charcoal preparation method is that charcoal reacts 1-2h in nitration mixture, is then re-fed into micro-wave oven and carries out expansion 35-45min, expansion temperature Degree is 225-235 DEG C.
9. a kind of Interior decorative paints capable of purifying air according to claim 8, which is characterized in that described mixed
Acid is the concentrated sulfuric acid, concentrated nitric acid according to weight ratio 3:The mixture of 2 compositions.
10. a kind of method preparing Interior decorative paints capable of purifying air as claimed in claim 1 or 2, which is characterized in that Include the following steps:
Step 1 weighs each component raw material as required;
Step 2 sequentially adds aqueous acrylic emulsion, linseed oil fatty acid, dimethylbenzene, turpentine oil, rosin, deionized water In homogenizer, rotating speed 210-220r/min stirs 35-45min, and mixture A is made;
Step 3, by mixture A, modification biological charcoal, pretreatment volcano float stone doping catalysis material, bamboo charcoal, nano phase ag_2 o, Tourmaline powder sequentially adds in high-speed mixer, be sufficiently stirred so that all material be uniformly mixed, mixing speed 750-850r/ Min, mixing time 1-2 hours to get the present invention Interior decorative paints capable of purifying air.
CN201810722190.6A 2018-07-04 2018-07-04 A kind of Interior decorative paints capable of purifying air and preparation method thereof Withdrawn CN108795182A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112680009A (en) * 2020-12-29 2021-04-20 广东花王涂料有限公司 Antibacterial wood varnish and preparation method and application thereof
CN116200078A (en) * 2022-12-20 2023-06-02 攀钢集团攀枝花钢铁研究院有限公司 Water-resistant antibacterial paint for fishing light complementary zinc-aluminum-magnesium coating photovoltaic bracket and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530788A (en) * 2014-12-30 2015-04-22 青岛佳尚创意文化有限公司 Paint
CN106280785A (en) * 2016-08-01 2017-01-04 太仓顺如成建筑材料有限公司 The antibacterial interior wall coating of a kind of insulation
CN107828294A (en) * 2017-10-25 2018-03-23 广东巴得劳建材科技有限公司 A kind of ecological wall finiss for discharging anion, purifying air and preparation method thereof
CN108159467A (en) * 2018-03-19 2018-06-15 王阳 The ore and natural plant composition and preparation method of pure and fresh removal harmful substance

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530788A (en) * 2014-12-30 2015-04-22 青岛佳尚创意文化有限公司 Paint
CN106280785A (en) * 2016-08-01 2017-01-04 太仓顺如成建筑材料有限公司 The antibacterial interior wall coating of a kind of insulation
CN107828294A (en) * 2017-10-25 2018-03-23 广东巴得劳建材科技有限公司 A kind of ecological wall finiss for discharging anion, purifying air and preparation method thereof
CN108159467A (en) * 2018-03-19 2018-06-15 王阳 The ore and natural plant composition and preparation method of pure and fresh removal harmful substance

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112680009A (en) * 2020-12-29 2021-04-20 广东花王涂料有限公司 Antibacterial wood varnish and preparation method and application thereof
CN116200078A (en) * 2022-12-20 2023-06-02 攀钢集团攀枝花钢铁研究院有限公司 Water-resistant antibacterial paint for fishing light complementary zinc-aluminum-magnesium coating photovoltaic bracket and preparation method and application thereof
CN116200078B (en) * 2022-12-20 2024-05-03 攀钢集团攀枝花钢铁研究院有限公司 Water-resistant antibacterial paint for fishing light complementary zinc-aluminum-magnesium coating photovoltaic bracket and preparation method and application thereof

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Application publication date: 20181113