CN108794177A - A kind of tea garden soil modifying agent and its application - Google Patents
A kind of tea garden soil modifying agent and its application Download PDFInfo
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- CN108794177A CN108794177A CN201810729215.5A CN201810729215A CN108794177A CN 108794177 A CN108794177 A CN 108794177A CN 201810729215 A CN201810729215 A CN 201810729215A CN 108794177 A CN108794177 A CN 108794177A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of tea garden soil modifying agents comprising each component of following parts by weight:12~25 parts of charcoal, 4~10 parts of egg shell, 1.5~3.7 parts of humic acid, 0.2~2.3 part of hydroxycarboxylic acid compound.The main component of the soil conditioner of the present invention is charcoal, and charcoal itself is in alkalinity, it has larger porosity and specific surface area, also containing there are many mineral elements;Egg shell can provide albumen and calcium element, consume the acid in soil, moreover it is possible to provide good nutrition for soil;In humic acid and hydroxycarboxylic acid compound contain hydroxyl and carboxyl functional group, applied in acid soil, in soil hydrogen ion and aluminium ion have stronger exchange capacity and suction-operated;Biomass and egg shell are porous structure, can load humic acid and hydroxycarboxylic acid compound, and these types of substance enhances the improved effect to acid soil according to proportioning compounding application.The invention also discloses the applications of the tea garden soil modifying agent.
Description
Technical field
The present invention relates to soil improvements and ecological restoration technical field, and in particular to a kind of tea garden soil acidification modifying agent and
It is applied.
Background technology
Tea tree is typically to get well sour crop, but the factors such as the metabolism of tea tree own growth, acquisition of tealeaves can accelerate soil again
Acidification, in addition a large amount of applications of nitrogenous fertilizer are also the key factor of aggravation tea garden soil acidification.Make although tea tree is typical happiness acid
Object, but its suitable growing environment is between soil pH section 4.5~6.0, the growth of tea plant when pH value is less than 4.0 or higher than 6.0
It will be suppressed.In addition, highly acid tea garden soil will increase the content of Aluminum in Tea, and excess of the aluminium in human body accumulates quilt
Think related with senile dementia with chronic neurological disorders.It is suitable to its it is therefore desirable to regulate and control to highly acid tea garden soil acidity
The yield and quality of tealeaves is improved in section.
At present liming be improvement acid soil more effectively and common method, but a large amount of or chronic administration lime
Soil hardening can not only be caused, and the addition of a large amount of calcium constituents can cause the antagonism to magnesium, potassium element, so as to cause soil
Calcium, potassium, three kinds of elements of magnesium dysequilibrium and lead to the underproduction.It is also possible to cause magnesium and aluminium in the excessive liming of acid soil
The co-precipitation of hydrated oxide reduces the Mg in the soil liquid2+Activity and plant availability.In addition, lime category mineral resources,
Long-term exploitation certainly will damage ecology.Especially for Tea Garden Ecosystem, it be easy to cause office in the actual production process
Portion excessively applies, and exceeds the proper limits in righting a wrong, in addition excess amount of Ca2+Absorption can reduce amino acid in tealeaves, water-soluble apparent extract, seriously affect
Tea leaf quality.
In consideration of it, can have a good improved effect to acidification or acid soil it is necessary to provide a kind of, chronic administration is not yet
The tea garden soil modifying agent that tea garden soil can be impacted.
Invention content
The purpose of the present invention is to provide a kind of good to tea garden soil acidification improved effect and chronic administration will not be to tea
The modifying agent that Orchard Soil impacts.
To reach above-mentioned technical purpose, technical scheme of the present invention provides a kind of tea garden soil modifying agent comprising as follows
The each component of parts by weight:12~25 parts of charcoal, 4~10 parts of egg shell, 1.5~3.7 parts of humic acid, hydroxycarboxylic acid chemical combination
0.2~2.3 part of object.
Compared with prior art, beneficial effects of the present invention include:In tea garden soil modifying agent in the technical program
Main component is charcoal, and charcoal itself is in alkalinity, and it not only has larger porosity and specific surface area, also contains tea
Set the mineral elements such as K, Na, Ca, Mg, the Si needed;Egg shell can not only provide albumen and calcium element for soil, consume in soil
Acid, moreover it is possible to provide good nutrition for soil;Contain more hydroxyl and carboxyl official in humic acid and hydroxycarboxylic acid compound
Can group, applied in acid soil, can in soil hydrogen ion and aluminium ion have stronger exchange capacity and suction-operated,
Meanwhile other in soil can also be complexed to the harmful heavy metal ion of crop in humus acid;Biomass and egg shell are porous
Structure, can load humic acid and hydroxycarboxylic acid compound, and these types of substance can increase according to certain proportioning compounding application
Improved effect of the strong modifying agent to acid soil.Meanwhile charcoal, egg shell, humic acid and hydroxyl carboxylic in the technical program
Acid compound is safe from harm to soil and tea tree, is suitble to chronic administration.
Specific implementation mode
Present embodiments provide a kind of tea garden soil modifying agent comprising each component of following parts by weight:Charcoal 12
~25 parts, 4~10 parts of egg shell, 1.5~3.7 parts of humic acid, 0.2~2.3 part of hydroxycarboxylic acid compound.
Charcoal:Be biomass material (such as:Sawdust, agricultural crop straw, grass or other Wastes of Crops) it is lacking completely
Oxygen or in the environment of the anoxic of part, pass through high temperature pyrolysis generate a kind of concrete dynamic modulus, high-specific surface area rich carbon product.Biology
There is the alkaline matter of certain content in charcoal, so in alkalinity;Meanwhile not only carbon content is high in charcoal, nitrogen, phosphorus, calcium, potassium and
The content of magnesium is also relatively abundanter, and these nutrient elements are also supplied with the nutrient needed for plant growth.
Egg shell:Calcium carbonate and protein are rich in egg shell, wherein also contain various trace elements, such as:Zinc, copper,
The elements such as manganese, iron, selenium, and the structure of eggshell is porous, and eggshell is added into soil, can not only maintain moisture, moreover it is possible to for flower
Grass provides nutrient.
Humic acid:Also known as humic acid, a kind of natural organic polymer compounds are the chief components of humus.It is rotten
Plant matter is the main organic principle in soil, peat, coal, many highland streams, rotten plant nutrition lake, seawater, dead by organic-biological
It is generated through biodegradation after dying.A humic acid not instead of single acid, one complicated to contain the functions such as carboxyl, phenolic hydroxyl group
The mixture of group.Humic acid cation exchange capacity is very big, is applied on acid soil, can in soil Na, Ca, Mg, Fe,
Al, Cl etc. have very strong exchange capacity and suction-operated, reduce the chloride in the soil liquid, sulfate concentration, reduce salt
Divide the harm to crop, the buffer capacity of soil can be enhanced.
Hydroxycarboxylic acid compound:Hydroxycarboxylic acid compound is tartaric acid, citric acid or tartaric acid and citric acid
Mixture.Hydroxycarboxylic acid compound contains hydroxyl and carboxyl simultaneously, is applied in acid soil, can be to the hydrogen ion in soil
There is stronger exchange capacity and suction-operated with aluminium ion.
The present embodiment additionally provides the preparation method of the tea garden soil modifying agent comprising following steps:
(1) following parts by weight are pressed to stock up:12~25 parts of charcoal, 4~10 parts of egg shell, 1.5~3.7 parts of humic acid,
0.2~2.3 part of hydroxycarboxylic acid compound;
(2) charcoal and egg shell are broken into the little particle that grain size is 5~20mm, respectively by humic acid and hydroxycarboxylic acid
Property compound grind, then cross 2mm sieve, select grain size≤2mm humic acid and hydroxycarboxylic acid compound;
It selects the grain size of humic acid and hydroxycarboxylic acid compound to be less than the grain size of charcoal, is to allow charcoal can be with
More humic acids and hydroxycarboxylic acid compound are loaded, their effect is given full play to;Select the biology of 5~20mm of aperture
Charcoal is that can preferably act on soil to increase the contact area of charcoal and soil, if aperture is too small, can increase sieve
The difficulty and cost divided;In order to ensure that egg shell can provide calcium ion and protein, but in order to avoid tea tree absorbed
More calcium ions selects the egg shell of 5~20mm of aperture.
(3) charcoal, egg shell, humic acid and the hydroxycarboxylic acid compound after crushing or grinding in step (2) are stirred
It mixes and is uniformly mixed to get to tea garden soil modifying agent.
The application method of the soil conditioner:The modifying agent is applied with base manure, be may be used and is spread fertilizer over the fields or the side of ditch spread
Formula is applied fertilizer;It should avoid being used in mixed way with acidic fertilizier in application;The dosage of the soil conditioner is 150~200kg/ mus.
Tea garden soil modifying agent provided by the invention and its application are given furtherly below in conjunction with specific embodiment
It is bright.The embodiments described below is exemplary, and is only used for explaining the present invention, and is not considered as limiting the invention.
Embodiment 1:
Present embodiments provide a kind of tea garden soil modifying agent comprising each component of following parts by weight:Charcoal 12
Part, 4 parts of egg shell, 1.5 parts of humic acid, 0.2 part of hydroxycarboxylic acid compound, wherein hydroxycarboxylic acid compound are tartaric acid.
The preparation method of the modifying agent is as follows:
(1) following parts by weight are pressed to stock up:12 parts of charcoal, 4 parts of egg shell, 1.5 parts of humic acid, 0.2 part of tartaric acid;
(2) charcoal and egg shell are broken into the little particle that grain size is 5~20mm, respectively grind humic acid and tartaric acid
It is milled broken, then crosses the sieve of 2mm, it is spare;
(3) charcoal, egg shell, humic acid and the tartaric acid after crushing or grinding in step (2) are uniformly mixed,
Obtain soil conditioner 1.
Embodiment 2:
Present embodiments provide a kind of tea garden soil modifying agent comprising each component of following parts by weight:Charcoal 15
Part, 5 parts of egg shell, 2 parts of humic acid, 1 part of hydroxycarboxylic acid compound, wherein hydroxycarboxylic acid compound are citric acid;This reality
The preparation method is the same as that of Example 1 for the tea garden soil modifying agent for applying in example, and soil conditioner 2 is made.
Embodiment 3:
Present embodiments provide a kind of tea garden soil modifying agent comprising each component of following parts by weight:Charcoal 18
Part, 6 parts of egg shell, 2.5 parts of humic acid, 1.3 parts of hydroxycarboxylic acid compound, wherein hydroxycarboxylic acid compound be citric acid and
The weight ratio of the mixture of tartaric acid, citric acid and tartaric acid is 1:1;The preparation side of tea garden soil modifying agent in the present embodiment
Soil conditioner 3 is made with embodiment 1 in method.
Embodiment 4:
Present embodiments provide a kind of tea garden soil modifying agent comprising each component of following parts by weight:Charcoal 20
Part, 8 parts of egg shell, 3 parts of humic acid, 2 parts of hydroxycarboxylic acid compound, wherein hydroxycarboxylic acid compound are citric acid, lemon
The weight ratio of acid and tartaric acid is 2:1;The preparation method is the same as that of Example 1 for tea garden soil modifying agent in the present embodiment, and soil is made
Earth modifying agent 4.
Embodiment 5:
Present embodiments provide a kind of tea garden soil modifying agent comprising each component of following parts by weight:Charcoal 25
Part, 10 parts of egg shell, 3.7 parts of humic acid, 2.3 parts of hydroxycarboxylic acid compound, wherein hydroxycarboxylic acid compound are citric acid,
The weight ratio of citric acid and tartaric acid is 3:1;The preparation method is the same as that of Example 1 for tea garden soil modifying agent in the present embodiment, system
Obtain soil conditioner 5.
The compliance test result of tea garden soil modifying agent:
It is that 5 mu of tea place planting site is improved to 1 piece of area, which is divided into 5 parts, 1 mu every part, after decile
The soil conditioner 1 of 150kg, the soil conditioner 2 of 180kg, the soil conditioner 3 of 180kg, 180kg are applied successively in 5 mu of ground
The soil conditioner 5 of soil conditioner 4,200kg.Soil conditioner 1~5 is applied with base manure, and above-mentioned various soil are changed
Good dose is spread fertilizer over the fields between two row tea trees.Behind 15 days after modifying agent application, soil pH value, heavy metal ion content are measured respectively
Reduced rate, test result are shown in Table 1.
The effect of 1 different soils modifying agent of table
As can be seen from Table 1, apply soil conditioner after, the pH value of tea garden soil is obviously improved, and heavy metal from
The content of son has apparent reduction, and as can be seen from Table 1, the effect of soil conditioner 3 is optimal in all soil conditioners,
The effect of soil conditioner 2 and soil conditioner 4 is better than the effect of soil conditioner 1 and soil conditioner 5.
The specific implementation mode of present invention described above, is not intended to limit the scope of the present invention..Any basis
The various other corresponding changes and deformation that the technical concept of the present invention is made, should be included in the guarantor of the claims in the present invention
It protects in range.
Claims (8)
1. a kind of tea garden soil modifying agent, which is characterized in that it includes each component of following parts by weight:Charcoal 12~25
Part, 4~10 parts of egg shell, 1.5~3.7 parts of humic acid, 0.2~2.3 part of hydroxycarboxylic acid compound.
2. tea garden soil modifying agent according to claim 1, which is characterized in that the tea garden soil modifying agent includes as follows
The each component of parts by weight:15~20 parts of charcoal, 5~8 parts of egg shell, 2~3 parts of humic acid, hydroxycarboxylic acid compound 1~
2 parts.
3. tea garden soil modifying agent according to claim 1, which is characterized in that the tea garden soil modifying agent includes as follows
The each component of parts by weight:18 parts of charcoal, 6 parts of egg shell, 2.5 parts of humic acid, 1.3 parts of hydroxycarboxylic acid compound.
4. tea garden soil modifying agent according to claim 1, which is characterized in that the hydroxycarboxylic acid compound is winestone
Acid and/or citric acid.
5. tea garden soil modifying agent according to claim 1, which is characterized in that the grain size of the charcoal is 5~20mm,
The grain size of egg shell is 5~20mm.
6. tea garden soil modifying agent according to claim 1, which is characterized in that humic acid and hydroxycarboxylic acid compound
Grain size≤2mm.
7. a kind of application of tea garden soil modifying agent, which is characterized in that using claim 1~6 any one of them tea place soil
Earth modifying agent.
8. the application of tea garden soil modifying agent according to claim 7, which is characterized in that the dosage of the soil conditioner
It is 150~200kg/ mus.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110093164A (en) * | 2019-04-26 | 2019-08-06 | 福建省农业科学院农业生态研究所 | A kind of tea place acidic soil conditioner and its preparation method and application |
CN111440615A (en) * | 2020-04-02 | 2020-07-24 | 南京林业大学 | Preparation of waste source calcium salt-biomass charcoal composite material and application thereof in soil |
CN112840935A (en) * | 2020-12-31 | 2021-05-28 | 九江学院 | Method for improving tea garden soil health by using biomass charcoal |
CN113912456A (en) * | 2021-10-15 | 2022-01-11 | 中国热带农业科学院海口实验站 | Tea garden soil conditioner, preparation method thereof and tea garden soil improvement method |
CN115806825A (en) * | 2023-02-03 | 2023-03-17 | 中国建设基础设施有限公司 | Soil conditioner for increasing yield and improving quality of astragalus membranaceus, and preparation method and application thereof |
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CN106831237A (en) * | 2017-02-03 | 2017-06-13 | 安徽帝元现代农业投资发展有限公司 | A kind of clayed soil modifying agent containing straw biomass charcoal |
CN107162821A (en) * | 2017-07-19 | 2017-09-15 | 合肥浦邦农业科技有限公司 | A kind of saline-alkali land soil conditioner and preparation method thereof |
CN108046955A (en) * | 2017-12-13 | 2018-05-18 | 江西省农业科学院土壤肥料与资源环境研究所 | A kind of heavy metal cadmium soil remediation modifying agent and preparation method thereof |
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CN103739411A (en) * | 2014-01-17 | 2014-04-23 | 合肥市东方美捷分子材料技术有限公司 | Preparation method of functional organic fertilizer for soil restoration |
CN106190157A (en) * | 2016-07-22 | 2016-12-07 | 福建省烟草公司南平市公司 | A kind of acid tobacco-planting soil conditioner and using method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110093164A (en) * | 2019-04-26 | 2019-08-06 | 福建省农业科学院农业生态研究所 | A kind of tea place acidic soil conditioner and its preparation method and application |
CN111440615A (en) * | 2020-04-02 | 2020-07-24 | 南京林业大学 | Preparation of waste source calcium salt-biomass charcoal composite material and application thereof in soil |
CN112840935A (en) * | 2020-12-31 | 2021-05-28 | 九江学院 | Method for improving tea garden soil health by using biomass charcoal |
CN113912456A (en) * | 2021-10-15 | 2022-01-11 | 中国热带农业科学院海口实验站 | Tea garden soil conditioner, preparation method thereof and tea garden soil improvement method |
CN115806825A (en) * | 2023-02-03 | 2023-03-17 | 中国建设基础设施有限公司 | Soil conditioner for increasing yield and improving quality of astragalus membranaceus, and preparation method and application thereof |
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