CN1087812A

CN1087812A - Toiletry composition for hair care

Info

Publication number: CN1087812A
Application number: CN 93118593
Authority: CN
Inventors: 松尾贵史; 足立久美子; 矢作和行
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 1992-10-09
Filing date: 1993-10-09
Publication date: 1994-06-15

Abstract

A kind ofly do not stimulate hair and skin, and have the Toiletry composition for hair care of excellent clean result, it contains:

(a) quarternary ammonium salt compound, it contains aliphatic chain and is bonded in secondary or tertiary amine base and quaternary ammonium group on the aliphatic chain, and its indefiniteness ground contains ether, ester group or the acyl group that is connected in the aliphatic chain;

(b) anion surfactant; With

(c) contain to water-soluble polymer and indefiniteness

(d) alkyl glucoside surfactant.

Description

Toiletry composition for hair care

The present invention relates to a kind of Toiletry composition for hair care, promptly a kind of hair products, it is chafe and hair not, and has excellent clean result.

Furtherly, the present invention relates to a kind of Toiletry composition for hair care, it is chafe and hair not, and has excellent foam performance, dirt-removing power and clean result.

In recent years, very big variation has taken place in the hair care behavior of consumer, comprises the increase of hair washing number of times and the number that wears one's hair long.Along with these variations, preventing to damage hair becomes and is even more important, need a kind of hair care to apply some make up, it does not stimulate hair, and can improve the slickness of hair and can use the finger cardability, apply some make up with a kind of hair care, it does not stimulate hair, and has excellent foam performance, dirt-removing power and clean result.

For reaching this requirement, the present inventor has proposed a kind of cleanser compositions, and it contains specific quarternary ammonium salt compound, and hair is had excellent clean result (seeing that European patent discloses-A2 No.0472107 Feb.26 1992).

Though above-mentioned compositions, shows excellent clean result as cleanser compositions, apply some make up with common hair care and to compare with the hair maintaining agent as the hair rinse agent, its clean result is relatively poor.Thereby, need a kind of hair care that has improved clean result to apply some make up, for example a kind of washing shampoo, particularly those are compared with the hair rinse agent, do not stimulate hair, and the hair care with excellent foam performance, dirt-removing power and clean result applies some make up.

Thereby in order to address the above problem, the present inventor has carried out extensive studies.The result, they have found a kind of skin and hair are had only low zest and the Toiletry composition for hair care of excellent clean result is arranged, it contains specific quarternary ammonium salt compound, and anion surfactant and water miscible polymer have been finished the present invention like this.

Therefore, the invention provides a kind of Toiletry composition for hair care, it contains:

(b) anion surfactant; With

(c) water-soluble polymer.

In other words, the present invention relates to a kind of hair care and apply some make up, it is characterized in that containing:

(a). the chemical compound of quaternary ammonium salt, it contains aliphatic chain or has the ether of aliphatic chain, ester or acyl compound, secondary or tertiary amine base and quaternary ammonium group;

(b). anion surfactant; With

(c). water-soluble polymer.

As the preferred water miscible cationic polymer of the water-soluble polymer of component (c).

Quarternary ammonium salt compound is so a kind of chemical compound, and it contains aliphatic chain or has the ether of aliphatic chain, ester or acyl compound, has secondary or tertiary amine base and quaternary ammonium group on the aliphatic chain.

The present invention is those chemical compounds with following general formula (1) expression as the quarternary ammonium salt compound of component (a) preferably:

Wherein:

R ¹The straight or branched alkyl or the alkenyl of expression 7 to 35 carbon;

R ², R ³And R ⁴Can be identical, also can be different, alkyl or the hydroxyalkyl or the hydrogen atom of each expression 1 to 4 carbon;

M represents-CONG-(wherein G represent hydrogen atom, the perhaps alkyl of 1 to 3 carbon or hydroxyalkyl) ,-O-or-COO-;

X represents hydrogen atom or hydroxyl;

A ^-Expression halide ion or organic anion;

M is 2 or 3 integer;

N is 0 or 1 to 5 integer, and subsidiary following restrictive condition: n is 1 o'clock, and X is hydrogen atom or hydroxyl; N is 0,2,3,4 or 5 o'clock, and X is a hydrogen atom; With

Y represents hydrogen atom, straight or branched alkyl, alkenyl or the hydroxyalkyl of 1 to 36 carbon, or the group of representing with following formula:

(R wherein ², R ³, R ⁴, X, A ^-The same with the definition of n), when the restrictive condition below subsidiary: G was the alkyl of 1 to 3 carbon or hydroxyalkyl, Y can not be the alkyl and the hydroxyalkyl of 1 to 3 carbon.

In the quarternary ammonium salt compound of superincumbent general formula (1) expression, these chemical compounds are preferred, wherein: R ¹The straight or branched alkyl or the alkenyl of expression 7 to 21 carbon; R ², R ³And R ⁴Can be identical or different, the alkyl or the hydroxyalkyl of each expression 1 to 4 carbon; Y represents hydrogen atom, the alkyl of 1 to 3 carbon or hydroxyalkyl, the perhaps group represented of following formula:

The particularly preferred quarternary ammonium salt compound as component (a) of the present invention is those chemical compounds with following general formula (2) expression:

Wherein:

R ¹The straight or branched alkyl or the alkenyl of expression 7 to 35 carbon;

G represents the alkyl or the hydroxyalkyl of hydrogen atom or 1 to 3 carbon;

X represents hydrogen atom or hydroxyl;

A ^-Expression halide ion or organic anion;

M is 2 or 3 integer;

Y ' expression hydrogen atom, the alkyl of 1 to 3 carbon or hydroxyalkyl, or the group of representing with following formula:

(R wherein ², R ³, R ⁴, X, A ^-The same with the definition of n), when the restrictive condition below subsidiary: G was the alkyl of 1 to 3 carbon or hydroxyalkyl, Y ' can not be the alkyl and the hydroxyalkyl of 1 to 3 carbon.

In the quarternary ammonium salt compound of superincumbent general formula (2) expression, these chemical compounds are preferred, wherein: R ¹The straight or branched alkyl or the alkenyl of expression 7 to 21 carbon: R ², R ³And R ⁴Can be identical or different, the alkyl or the hydroxyalkyl of each expression 1 to 4 carbon.

In addition, the chemical compound of general formula (3) expression is preferably as the quarternary ammonium salt compound of component (a), and these chemical compounds can comprise the chemical compound that general formula (5) as by-product and (6) are represented:

Wherein:

R ¹The straight or branched alkyl or the alkenyl of expression 7 to 35 carbon;

R ²', R ³' and R ⁴' can be identical or different, the alkyl or the hydroxyalkyl of each expression 1 to 4 carbon; With

A ^⊙Expression halide ion or organic anion.

In the quarternary ammonium salt compound of general formula (3) expression in the above, preferred those R ¹Expression 7 to 21 carbon, particularly the straight or branched alkyl of 11 to 17 carbon or the chemical compound of alkenyl.More preferably those R ¹The group that CO-represents is lauroyl or myristoyl, and R ²', R ³' and R ⁴' all be the chemical compound of methyl.

In addition, the chemical compound of general formula (4) expression is preferably as the quarternary ammonium salt compound of component (a):

Wherein:

R ⁵And R ⁶Can be identical or different, the alkyl of each expression 1 to 4 carbon;

R ⁷The alkylidene or the alkylene group of expression 2 to 6 carbon;

R ⁸The straight or branched alkyl or the alkenyl of expression 4 to 36 carbon;

R ⁹The straight or branched alkyl or the alkenyl of expression 7 to 35 carbon;

R ¹⁰The alkyl or the hydroxyalkyl of expression hydrogen atom or 1 to 4 carbon;

Z ^-The expression halide ion, 1/2SO 2- ₄, HSO - ₄, RCOO ^-(wherein R represents the alkyl or the alkenyl of 1 to 4 carbon, can have hydrogen atom to be replaced (or R ' SO by hydroxyl in alkyl or alkenyl - ₄(the wherein alkyl of R ' expression 1 to 4 carbon), in other words, Z represents halogen atom, sulfate radical, bisulfate ion can have the hydroxy acid root of 1 to 4 carbon that hydroxyl replaces, perhaps 1 to 4C alkyl sulfate; With

A is 2 to 9 integer.

In the quarternary ammonium salt compound of general formula (4) expression in the above, preferred those chemical compounds, wherein: R ⁵And R ⁶Be methyl, R ⁷Be the alkylidene of 2 or 3 carbon, R ⁸Be hard tallow alkyl or hard palm oil alkyl, and R ⁹CO is hard tallow fatty acids acyl group or hard palm oil fatty acid acyl.

Further, the inventor has invented a kind of Toiletry composition for hair care, it contains alkane polyglycoside surfactant activating agent, specific quaternary ammonium salt, anion surfactant and water miscible polymer, it is chafe and hair not, show excellent foaming and detergency ability, and excellent clean result is arranged, finished the present invention like this.

Therefore, the present invention also provides a kind of Toiletry composition for hair care, and it contains above-mentioned component (a) and (b) and (c), and (d) alkyl glucoside surfactant.

Preferably with the chemical compound of following general formula (I) expression as component (d)-alkyl glucoside surfactant:

Wherein:

R represents the straight or branched alkyl or the alkenyl of 8 to 18 carbon, perhaps the straight or branched alkyl of 8 to 18 carbon or alkenyl phenyl;

What J represented 5 or 6 carbon goes back the raw sugar residue;

V is the average addition molal quantity of oxirane, is worth to be 0-20; With

W is an average of going back the raw sugar residue, is worth to be 1-10.

From detailed description hereinafter, can obviously find out scope and adaptability that the present invention is wider.But should not be construed as, when indicating the preferred embodiment of the invention, just the mode by illustration has provided detailed description and specific embodiment, this be because, those skilled in the art can obviously find out various changes and modifications within the spirit and scope of the present invention from this describes in detail.

Quarternary ammonium salt compound of the present invention (a) comprises aforesaid all cpds.The quarternary ammonium salt compound of general formula wherein, (3) expression is with preparing as following method:

Shown in Figure 1 as following preparation flow, fatty acid (R ¹CO ₂H) with the amino ethyl ethanolamine reaction of following molecular formula (7) expression, form the imidazolidine derivatives shown in the general formula (8).Then, this derivant is with alkali treatment with carry out quaternized with the chemical compound of general formula (9) expression.The quarternary ammonium salt compound that has synthesized general formula (3) expression like this.Consider the dissolubility of water-soluble polymer in Toiletry composition for hair care of the present invention (c), and the viscometric properties of cosmetic composition of the present invention, preferably the electrodialysis methods desalination is for example used in the chemical compound desalination of the general formula that will obtain like this (3) expression.

Preparation flow Fig. 1

The formation of＜imidazoline 〉

R wherein ¹, R ²', R ³', R ⁴' and A ^⊙Definition the same.

The quarternary ammonium salt compound with top general formula (4) expression that the present invention uses is used as the preparation of following method:

Shown in Figure 2 as following preparation flow, acidic materials shown in ester amine shown in the general formula (10) and the general formula (11) or quaternizing agent reaction.Can obtain the target compound shown in the general formula (4) like this.

Preparation flow Fig. 2

R wherein ⁵, R ⁶, R ⁷, R ⁸, R ⁹, R ¹⁰, the definition of Z and a is the same.

A kind of such quarternary ammonium salt compound, the perhaps combination of two or more such quarternary ammonium salt compounds can be used as component (a).Their content ranges in Toiletry composition for hair care of the present invention are preferably the 0.1-20% of cosmetic composition weight, more preferably 1-10%.

When cosmetic composition of the present invention contains component (d), promptly during the alkyl sugar surfactant, the content range of component in the cosmetic composition (a) is preferably the 1-20% of cosmetic composition weight, more preferably 2-10%.

The anion surfactant that is used as component (b) among the present invention comprises that following compounds (ⅰ) is to (Xii);

(ⅰ). straight or branch-alkylbenzene sulfonate, it has average carbon atom number is 10 to 16 alkyl.

(ⅱ). alkyl or alkenyl ether sulfate, it has average carbon atom number is 10 to 20 straight or branched alkyl or alkenyl, and every mole on average contain 0.5 to 8 mole, add to the oxirane on the above-mentioned sulfate, expoxy propane, epoxy butane, mixed proportion is the ethylene oxide/propylene oxide mixture of 0.1/9.9 to 9.9/0.1, or mixed proportion is the ethylene oxide/butylene oxide mixture of 0.1/9.9 to 9.9/0.1.

(ⅲ). alkyl or alkenyl sulfate, it contains average carbon atom number is 10 to 20 alkyl or alkenyl.

(ⅳ). ethylenic sulfonate on average has 10 to 20 carbon atoms in the per molecule.

(ⅴ). alkylsulfonate on average has 10 to 20 carbon atoms in the per molecule.

(ⅵ). saturated or unsaturation soap, per molecule on average have 10 to 24 carbon atoms.

(ⅶ). alkyl or alkenyl ether carboxylic acid salt, it contains average carbon atom number is 10 to 20 alkyl or alkenyl, and every mole on average contain 0.5 to 8 mole, add to the oxirane on the above-mentioned carboxylate, expoxy propane, epoxy butane, mixed proportion is the ethylene oxide/propylene oxide mixture of 0.1/9.9 to 9.9/0.1, or mixed proportion is the ethylene oxide/butylene oxide mixture of 0.1/9.9 to 9.9/0.1.

(ⅷ). have average carbon atom number and be the salt and/or the esters of the α-thia fatty acid of 10 to 20 alkyl or alkenyl.

(ⅸ). have the acyl group of 8 to 24 carbon and the N-acylamino acid surfactant of free carboxylate radical.

(ⅹ) have the alkyl of 8 to 24 carbon or the phosphate monoester or the diester surfactant of alkenyl.

(xi). have the esters of sulfosuccinic acids of higher alcohol or its b-oxide of 8 to 22 carbon atoms, or the deutero-esters of sulfosuccinic acids of higher fatty acid amides.

(xii). the deutero-ether sulfonate of high fat fatty acid amide.

The example of the counter ion of the anion residue in these anion surfactants comprises: alkali metal ion such as sodium ion and potassium ion; Alkaline-earth metal ions such as calcium ion and magnesium ion; Ammonium ion; Alkanolamine with chain triacontanol base of 1 to 32 or 3 carbon, as monoethanolamine, diethanolamine, triethanolamine and triisopropanolamine.

In these anion surfactants; preferred especially (ⅱ) alkyl ether sulfate class, (ⅲ) alkylsurfuric acid salt, (ⅵ) salt of saturated or unsaturation fatty acid; (ⅸ) acylated amino acids, (ⅹ) phosphate monoester surfactant and (xi) esters of sulfosuccinic acids.Suitable example comprises poly(ethylene oxide) lauryl ether sulfate (oxirane that on average adds 2 to 3 moles); triethanolamine base lauryl sulfate; the sodium salt of cupu oil fat acid; the amide ether sulfate of cupu oil fat acid; lauroyl-N-methylamino ethyl sulfonic acid; lauroyl-N-methyl-Beta-alanine; N-tetradecanoyl-L-disodium glutamate; poly-(embodiment example 3 to 7) oxirane lauryl sulfo-disodium succinate; lauryl phosphate; N-lauroyl-N '-carboxymethyl-N '-(2-hydroxyethyl) ethylene diamine/triethanolamine salt; N-lauroyl-N-(2-hydroxyethyl)-and N, the sodium salt of N '-two (carboxymethyl) ethylene diamine and lauroyl-Beta-alanine.

Component (b) can be used a kind of this anion surfactant, perhaps uses the combination of two or more this anion surfactants.Their content ranges in Toiletry composition for hair care of the present invention are preferably the 1-20% of cosmetic composition weight, more preferably 2-15%, especially preferably 5-15%.

When cosmetic composition of the present invention contained component (d), the content range of component (b) in cosmetic composition was preferably the 1-20% of cosmetic composition weight, more preferably 3-15%.

The water-soluble polymer that is used as component (c) among the present invention can be any natural polymer, the polymer of half synthetic and synthetic and any cationic polymer, anionic polymer, non-ionic polymers or the like.

The example of natural water-soluble copolymer comprises: vegetable polymer such as Radix Acaciae senegalis, Tragacanth, galactan, guar gum, carob, karaya, carrageenin, pectin, agar ， Fructus cydoniae oblongae (Cydonia oblonga) and glycyrrhizic acid; Microbial polymer such as synthesising biological polymeric gel, glucosan, amber oil and amylopectin and proteolysis polymer such as keratin decompose derivant.

The example of the water-soluble polymer of half synthetic comprises: starch polymer such as cationic starch, carboxymethyl starch and methyl hydroxypropyl starch; The cellulose derivative of cellulosic polymer such as cationization, methylcellulose, NC Nitroncellulose, ethyl cellulose, the methyl hydroxy propyl cellulose, hydroxy ethyl cellulose, sulfate cellulose, hydroxy propyl cellulose, sodium carboxymethyl cellulose (CMC), crystalline cellulose and cellulose powder; Alginic acid polymer such as sodium alginate, alginic acid/propylene glycol ester; The guar gum derivatives of anionization.

The example of the water-soluble polymer of synthetic comprises: diallyl quaternary ammonium salt homopolymer; Diallyl quaternary ammonium salt/acrylamide copolymer; Quaternised polyvinyl pyrrolidone derivant; Polyvinyl pyrrolidone; Vinyl pyrrolidone with as the copolymer of vinyl acetate or alkyl amido acrylate; The lower alkyl half ester of methyl vinyl ether/copolymer-maleic anhydride; Vinyl acetate with as the copolymer of .beta.-methylacrylic acid; The copolymer of acrylic acid and/or methacrylic acid and alkyl acrylate and/or alkyl methacrylate; The copolymer of acrylic acid and alkyl acrylate and N-alkyl acrylamide; The amphoteric derivatives of copolymer, copolymer for example are methacrylic acid dialkyl amido ethyl ester, propenoic acid dialkyl amino ethyl ester or diethyl ketone acrylamide with as acrylic acid, methacrylic acid, the copolymer of alkyl acrylate or alkyl methacrylate; The terpolymer of Hydroxypropyl acrylate and metering system acid butyl amino ethyl ester and acrylic acid caprylamide; Alkyl acrylamide, acrylate, the copolymer of alkyl amino alkyl acrylamide and polymethylacrylic acid glycol ester.

In these water-soluble polymers, be preferably especially and contain amino or the ammonium that is connected on the polymer chain, or contain the water-soluble cationic polymer of a halogenation dimethyldiallylammonium at least as construction unit.The example of this water-soluble cationic polymer comprises: the cellulose derivative of cationization, cationic starch, the guar gum derivatives of cationization, the homopolymer of diallyl quaternary ammonium salt, diallyl quaternary ammonium salt/acrylamide copolymer and quaternised polyvinyl pyrrolidone derivant.

The chemical compound of following general formula (12) expression is the example of the cellulose derivative of preferred cationization:

In formula (12), the B glucose residue unit of representing to dewater; F is an average degree of polymerization, is 50 to 20,000; Each R ¹¹The following represented substituent group of general formula (13) of expression independently of each other:

In formula (13), each R ¹²And R ¹³The alkylidene of representing 2 or 3 carbon independently of each other; G is 0 to 10 integer; H is 0 to 3 integer; I is 0 to 10 integer; R ¹⁴The alkylidene or the hydroxy alkylidene of expression 1 to 3 carbon; R ¹⁵, R ¹⁶And R ¹⁷Can be identical or different, each expression carbon number reaches 10 alkyl, aromatic radical or aralkyl, perhaps R ¹⁵, R ¹⁶And R ¹⁷Can form heterocycle by the nitrogen-atoms in formula; X θ ₁The expression anion (for example: chloride ion, bromide ion, iodide ion, 1/2SO 2- ₄, SO ₃H ^-, CH ₃SO - ₄, 1/3PO 3- ₄Or NO - ₃).

In the cellulose derivative Shangyang ionic replacement degree of cationization, i.e. meansigma methods of each dehydration glucose unit h, the preferable range that the present invention uses is 0.01 to 1, more preferably 0.02 to 0.5.G and i's and scope average out to 1 to 3.It is not enough that cation replacement degree is lower than 0.01.Can surpass 1 though cation replaces degree, consider reaction yield, be preferably it and be no more than 1.The mean molecule quantity of the cellulose derivative of cationization used herein is preferably about 100,000 to 3,000, in 000 scope.

What following general formula (14) was represented is preferred cation starch:

In formula (14), D represents the starch residue; R ¹⁸Expression alkylidene or hydroxy alkylidene; R ¹⁹, R ²⁰And R ²¹Can be identical or different, alkyl, aromatic radical or the aralkyl of each 10 of expression or carbon still less, perhaps R ¹⁹, R ²⁰And R ²¹Wherein two can form heterocycle by the nitrogen-atoms in formula; X - ₂The expression anion (as chloride ion, bromide ion, iodide ion, 1/2SO 2- ₄, SO ₃H ^-, CH ₃SO - ₄, 1/3PO 3- ₄Or NO - ₃); J is a positive integer.The heterocycle that forms comprises as pyrrole ring and imidazoline ring.

Cationic replacement degree on cationic starch, i.e. the average of the cation radical of introducing in each dehydration glucose unit, the preferable range that the present invention uses is 0.01 to 1, more preferably 0.02 to 0.5.It is not enough being lower than 0.01 cation replacement degree.Can surpass 1 though cation replaces degree, consider that reaction yield is preferably it and is no more than 1.

What following general formula (15) was represented is the guar gum derivatives of preferred cationization:

In formula (15), E represents-the guar gum residue; R ²²Expression alkylidene or hydroxy alkylidene; R ²³, R ²⁴And R ²⁵Can be identical or different, each 10 of expressions or still less alkyl, aromatic radical or the aralkyl of carbon, perhaps R ²³, R ²⁴And R ²⁵Wherein two nitrogen-atoms in formula form heterocycle; X θ ₃The expression anion (as chloride ion, bromide ion, iodide ion, 1/2SO 2- ₄, SO ₃H ^-, CH ₃SO - ₄, 1/3PO 3- ₄Or NO - ₃); K is a positive integer.The heterocycle that forms comprises as pyrrole ring and imidazoline ring.

Cation on the guar gum derivatives of cationization replaces degree, i.e. the average of the cation radical of introducing in each sucrose unit, and the preferable range that the present invention uses is 0.01 to 1, more preferably 0.02 to 0.5.For example, European patent discloses-A Nos.18717(Nov.12,1980 is open), 74264(March 16,1983 is open) and 93601(Nov.9th, 1983 is open) such cationic polymer described, it can obtain from Celanese Stein Hall, and trade mark is Jaguar.

What following general formula (16) or (17) were represented is preferred cation diallyl quaternary ammonium salt homopolymer and cation diallyl quaternary ammonium salt/acrylamide copolymer:

In superincumbent formula (16) and (17), R ²⁶And R ²⁷Can be identical or different, each represents hydrogen atom, the alkyl of 1 to 18 carbon, phenyl, aromatic radical, hydroxy alkyl, amido alkyl, cyanoalkyl, alkoxyalkyl or carboxylic alkoxyalkyl; R ²⁸, R ²⁹, R ³⁰And R ³¹Can be identical or different, each represents hydrogen atom, the low alkyl group of 1 to 3 carbon, or phenyl; X - ₄The expression anion (as chloride ion, bromide ion, iodide ion, 1/2SO 2- ₄, SO ₃H ^-, CH ₃SO - ₄, 1/3PO - ₃Or NO - ₃); P is the unitary average degree of polymerization of quaternary ammonium salt, is 1 to 50; Q is the average degree of polymerization of amine unit, is 0 to 50; R is an average degree of polymerization, is 150 to 8,000.

The diallyl quaternary ammonium salt homopolymer that the present invention uses or the molecular weight of diallyl quaternary ammonium salt/acrylamide copolymer be preferably about 30,000 to 2,000, in 000 the scope, and more preferably 100,000 to 1,000,000.

What following formula (18) was represented is preferred quaternised polyvinyl pyrrolidone derivant:

In formula (18), R ³²The alkyl of expression hydrogen atom or 1 to 3 carbon; R ³³, R ³⁴And R ³⁵Can be identical or different, each represents hydrogen atom, the alkyl of 1 to 4 carbon, hydroxy alkyl, amido alkyl, cyanoalkyl, alkoxyalkyl or carboxylic alkoxyalkyl; Y ₁Represent oxygen atom or expression NH base in amido link; X - ₃The expression anion (as chloride ion, bromide ion, iodide ion, 1/2SO 2- ₄, SO ₃H ^-, R ¹SO - ₄(R wherein ¹The alkyl of expression 1 to 4 carbon), 1/3PO 3- ₄Or NO - ₃); U is 1 to 10 integer; S adds t average out to 20 to 8,000.

The mean molecule quantity of the quaternised polyvinyl pyrrolidone derivant that the present invention uses is preferably 10,000 to 2,000, in 000 the scope, and more preferably 50,000 to 1,500,000.

Perhaps these water-soluble polymers is wherein a kind of, and perhaps the compositions of wherein two or more can be used as component C.In the Toiletry composition for hair care of the present invention, the content of these water-soluble polymers is preferably the 0.01-2% of cosmetic composition weight, more preferably 0.1-0.8%.

When cosmetic composition of the present invention contained component (d), in the cosmetic composition, the content range of component C was preferably the 0.01-3% of cosmetic composition weight, more preferably 0.3-1.5%.

Toiletry composition for hair care of the present invention can contain alkyl glucoside surfactant (d).

Among the present invention, the example that is used as the alkyl glucoside surfactant of component (d) comprises the chemical compound that logical formula I is represented:

R-（OCH ₂CH ₂） _V-（J） _W（Ⅰ）

Wherein:

What J represented 5 or 6 carbon goes back the raw sugar residue;

V is the average addition molal quantity of oxirane, is worth to be 0-20;

W is an average of going back the raw sugar residue, is worth to be 1-10.

In above-mentioned logical formula I, R represents the straight or branched alkyl of 8 to 18 carbon, the straight or branched alkenyl of 8 to 18 carbon, perhaps alkyl or alkenyl phenyl, alkyl wherein or alkenyl are the straight or branched bases of 8 to 18 carbon, are preferably the straight or branched alkyl (as nonyl, decyl, lauryl and myristyl) of 9 to 14 carbon.The sugar moieties of hydrophilic radical (J in the formula I) is made of the raw sugar of going back as 5 or 6 carbon of elementary cell.Also the preference of raw sugar comprises glucose, galactose and fructose.The degree of polymerization S of sugar, i.e. W average out in the formula I 1 to 10.

Above preferred alkyl glucoside surfactant shown in the logical formula I contain 80% or more below shown in the logical formula II, promptly average degree of polymerization S is 1 to 4 chemical compound.

Wherein:

What J represented 5 or 6 carbon goes back the raw sugar residue;

X is 0 or positive integer; With

Y is 1 to 4 integer.

In addition, consider the alkyl glucoside surfactant Effect on Performance of carbon number mutual-through type (I) expression in degree of polymerization S and the R base, preferred those wherein R 8 to 11 carbon atoms are arranged, degree of polymerization S scope is 1 to 1.4 alkyl polyglucoside, with those wherein R 12 to 14 carbon atoms are arranged, degree of polymerization scope is 1.5 to 4.0 alkyl polyglucoside, further, because the foaming capacity of alkyl glucoside surfactant is step-down with the increase of its degree of polymerization S, consider their foaming capacity, preferred especially those wherein R 8 to 11 carbon atoms are arranged, degree of polymerization S is the alkyl polyglucoside that 1 to 1.4 logical formula I is represented.The average degree of polymerization W of sucrose can measure according to ' H-NMR method.

The example of above-mentioned alkyl glucoside surfactant comprises: β-alkyl polyglucoside such as octyl glucoside, nonyl glucoside, decyl glucoside, decyl maltoside, poly(ethylene oxide) (2E.O.) Lauryl.beta.-maltoside, Lauryl.beta.-maltoside and tridecyl maltoside, they are all according to known method, prepare as the Koening-Knorr method, and those are from going back alkyl polyglucoside and the higher alcohol or the polyethylene oxide alkyl ethers alcohol (seeing United States Patent(USP) Nos. 3839318 and 3598865) of raw sugar such as glucose, galactose, maltose preparation.

The alkyl glucoside surfactant that Toiletry composition for hair care of the present invention preferably contains the 1-60% of cosmetic composition weight is used as component (d), is preferably 2-30% especially.

Remove above-mentioned quarternary ammonium salt compound as component (a), anion surfactant as component (b), contain beyond the alkyl glucoside surfactant as component (d) as the water-soluble polymer of component (c) and indefiniteness ground, if necessary, only otherwise damage effect of the present invention, Toiletry composition for hair care of the present invention contains at cosmetics to indefiniteness in addition, emollient, normally used various components in medicine or the food, for example, medicative component, comprise dandruff removing agent such as yellow ferrum thioketone zinc (Zpt), antibacterial and vitamin; The storage agent is as the para Toluic Acid; Wetting agent, as propylene glycol, glycerol, diethylene glycol monoethyl ether, sorbitol, panthenol and glycine betaine; Painted thing such as dyestuff and pigment; Regulator such as PFPE; Pearling agent such as glycol ether; The chitosan derivant is as the hydroxypropyl chitosan; Various spice mixts; And those are in ENCYCLOPEDIA OF CONDITIONING RINSE INGREDIENTS(MICELLE PRESS, 1987) the middle component of describing.

Toiletry composition for hair care of the present invention has excellent moist performance in application and rinse cycle, make the molding of hair nature, can make scalp combing glossily, and hair and skin are had only slight and low stimulation.Thereby it is highly suitable for shampoo or hair rinse agent.

In the cosmetic composition of the present invention, those compositionss that contain component (d) are specially adapted to shampoo, because this compositions produces like lactous foam, show excellent foam performance, the enough fingers of energy combing glossily in hair washing and rinse cycle, make the molding of hair nature, can smooth combing, and skin and hair had only slight and low stimulation.

According to following embodiment, now will describe the present invention in further detail, but these examples should not thought and limit the scope of the invention.

Embodiment 1

The various hair cares that prepared composition as shown in table 1 apply some make up, with according to its performance of following standard evaluation.Table 1 shows the result.

＜evaluation criterion 〉

The feel of hair in use:

◎: soft, smooth, be suitable for pointing combing especially.

Zero: smooth, be suitable for pointing combing.

△: rough, be difficult to point combing.

*: very puckery and entanglement.

Finger carding property when rinsing:

◎: do not have puckery sense fully, very suitable finger combing.

Zero: slight puckery sense, the combing of suitable finger.

△: some puckery senses are arranged, be difficult to point combing.

*: puckery especially, the finger carding property is very poor.

Towel and the viscosity that dries up the back hair:

Zero: sticking but do not have oil.

△: have some sticking.

*: sticking.

The soft property of hair after the towel:

◎: very soft and high resilience.

Zero: soft.

△: some is poor for soft property.

*: hard.

Hair style after drying up:

◎: very Liu Chang molding.

Zero: natural molding.

△: some is poor for hair style.

*: hair style is poor, and the hair of perk is arranged.

Carding property after drying up:

Zero: be highly susceptible to combing.

△: some is difficult to combing.

*: send out the tip and tangle, cardability is poor.

Zest to skin:

Zero: do not have or few stimulation.

△: slight stimulation.

*: moderate or serious zest.

Annotate:

＊1：

* 2: cationic polymer 1

mfd.Union????????Carbide????????Corp????????Polymer????????JR-400

(Poise C-80M).

* 3: cationic polymer 2

mfd.by????????Merck????????&????????Co.，Inc.，Merquat????????100

(polychlorostyrene N, N '-dimethyl-3,5-methylenepiperidines).

Embodiment 2

Preparation has the hair rinse agent compositions of following composition.These hair rinse agent compositionss are in use and rinse cycle, and hair is very smooth and soft, and it is good to dry up the back hair style.

Chlorination (tetradecanoyl-N-ethoxy) amino-ethyl-

2-Hydroxyproyl Trimethyl ammonium 6%(weight)

Poly(ethylene oxide) (3) lauryl sulfo-disodium succinate 4

Poly-(chlorination N, N-dimethyl-3,5-methylenepiperidines) ^{* 1}0.5

Hexadecanol 0.3

Polydimethylsiloxane ^{* 2}0.3

Polydimethylsiloxane ^{* 3}0.3

Sodium benzoate 0.5

Spice 0.4

Painted thing 0.0001

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100。

＊2：（CH ₃） ₃SiO〔（CH ₃） ₂SiO〕 _nSi（CH ₃） ₃

n＝9000。

＊3：mfd.by????????Shin-Etsu????????Chemical????????Co.，Ltd.，Silicone????????KF-96。

Embodiment 3

The hair rinse agent compositions for preparing following composition.This hair rinse agent compositions is in use and rinse cycle, and hair is very smooth and soft, and it is good to dry up the back hair style.

Chlorination (tetradecanoyl-N-ethoxy) amino-ethyl

-2-Hydroxyproyl Trimethyl ammonium 5%(weight)

N-tetradecanoyl-L-disodium glutamate 5

Octadecyl trimethyl ammonium chloride 0.5

Poly-(chlorination N, N-dimethyl-3, the 5-methylenepiperidines drone) ^{* 1}0.3

The cellulose of cationization ^{* 2}0.3

Propylene glycol 3

Polyether-modified siloxanes ^{* 3}0.5

Polydimethylsiloxane ^{* 4}0.3

Polydimethylsiloxane ^{* 5}0.3

Sodium benzoate 0.5

Spice 0.4

Painted thing 0.0001

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

＊2：mfd.by????????Union????????Carbide????????Corp.，Polymer????????JR-400.

＊3：mfd.by????????Shin-Etsu????????Chemical????Co.，Ltd.，Silicone????????KF-6005.

＊4：（CH ₃） ₃SiO[（CH ₃） ₂SiO] _nSi（CH ₃） ₃n＝9000.

＊5：mfd.by????????Shin-Etsu????????Chemical????????Co.，Ltd.，Silicone????????KF-96。

Embodiment 4

Preparation has the hair rinse agent compositions of following composition.This hair rinse agent compositions is in use and rinse cycle, and hair is very smooth and soft, and after drying up, hair style is good.

The quarternary ammonium salt compound 4.5%(weight of following molecular formula (19) expression)

N-tetradecanoyl-N-disodium glutamate 5.5

Cationic polymer ^{* 1}0.5

Ordinary salt 1.0

Liquid paraffin 0.2

Sodium benzoate 0.3

The spice trace

Painted thing trace

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 5

The quarternary ammonium salt compound 5.0%(weight of following molecular formula (20) expression)

Poly(ethylene oxide) (3) lauryl sulfo-disodium succinate 5.5

Cationic polymer ^{* 1}0.5

Ordinary salt 1.0

Hexadecanol 0.3

Sodium benzoate 0.3

The spice trace

Painted thing trace

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 6

The quarternary ammonium salt compound 4.5%(weight of following molecular formula (21) expression)

(COR: hard tallow fatty acids acyl group)

(R ¹: hard tallow alkyl)

N-tetradecanoyl-L-disodium glutamate 5.5

Cationic polymer ^{* 1}0.5

Ordinary salt 1.0

Liquid paraffin 0.2

Sodium benzoate 0.3

The spice trace

Painted thing trace

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 7

The quarternary ammonium salt compound 5.0%(weight of following molecular formula (22) expression)

(COR: hard tallow fatty acids acyl group)

(R ': hard tallow alkyl)

Poly(ethylene oxide) (3) lauryl sulfo-disodium succinate 5.5

Cationic polymer ^{* 1}0.5

Ordinary salt 1.0

Hexadecanol 0.3

Sodium benzoate 0.3

The spice trace

Painted thing trace

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 8

Preparation has the hair rinse agent compositions of following composition.This hair rinse agent compositions is in use and rinse cycle, and hair is non-logical smooth and soft, and after drying up, hair style is good.

The quarternary ammonium salt compound 6%(weight of following molecular formula (23) expression)

Poly(ethylene oxide) (3) lauryl sulfo-disodium succinate 3

Ordinary salt 1

Carboxymethyl cellulose ^{* 1}0.5

Polyether-modified siloxanes ^{* 2}0.5

Sodium benzoate 0.3

The spice trace

Painted thing trace

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Daicel????????Chemical????????Industries，Ltd.（product????????No.1310）.

＊2：mfd.by????????Shin-Etsu????????Chemical????????Co.，Ltd.，Silicone????????KF-6005.

Embodiment 9

Prepare the invention product 11 to 13 of composition as shown in table 2 and the various shampoos of comparative product 3 to 9, with their performance of standard evaluation according to description among following standard and the embodiment 1.

Measure foam performance with stirring stirring method.Performances such as the feel of hair are that five people panels of expert measure by following method: the 1g shampoo is used for 20g(15Cm) healthy Japanese women's hair, foam and used water rinse in 1 minute later on.Then, toweling off dried back reuse hair dryer dries up.

＜evaluation criterion 〉

Foaming capacity:

◎: show good foaming capacity.

Zero: the foaming capacity that shows.

△: the foaming but not enough.

*: foaming seldom.

The feel of hair in the hair washing process:

◎: soft, smooth, be suitable for pointing very much combing.

Zero: smooth, be suitable for pointing combing.

△: rough, be difficult to point combing.

*: puckery and entanglement.

Annotate:

* 1: the alkyl glucoside surfactant that logical formula I is represented, its restrictive condition is: R represents the alkyl of 9 to 11 carbon, and J represents glucose, V be 0 and W be 1.3.

* 3: cationic polymer 1

Mfd.by Union Carbide Corp., the cellulose of Polymer JR-400(cationization).

* 4: cationic polymer 2

mfd.by????????Merck????????&????????Co，.Inc.，Merquat????????100

(poly-(and chlorination N, N-dimethyl-3, the 5-methylenepiperidines drone)).

Embodiment 10

Preparation has the shampoo of following composition.When washing hair with this shampoo, in washing and rinse cycle, the finger combing is smooth, dry up the soft and natural molding of back hair, and combing is smooth.

The alkyl polyglucoside surface activity that logical formula I is represented

Agent, its restrictive condition is: R represents 9 to 11

The alkyl of carbon, J represents glucose, V is 0 He

W is 1.3.12%(weight)

Chlorination (tetradecanoyl-N-ethoxy) amino-ethyl-2-

Hydroxyproyl Trimethyl ammonium 5

N-tetradecanoyl-L-disodium glutamate 5

The cellulose of cationization ^{* 1}0.3

Poly-(chlorination N, N-dimethyl-3,5-methylenepiperidines) ^{* 2}0.3

Sodium benzoate 0.5

Spice is an amount of

Painted thing is an amount of

The PH regulator is an amount of

The aequum of purifying waste water

PH：6.5

Annotate:

＊1：mfd.by????????Union????????Carbide????????Corp.，Polymer????????JR-40

＊2：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 11

The alkyl polyglucoside surface activity that logical formula I is represented

Agent, its restrictive condition is: R represents 9 to 11

The alkyl of carbon, J represents glucose, V is 0 He

W is 1.3.12%(weight)

The quarternary ammonium salt compound 4.5 of following molecular formula (19) expression

Poly(ethylene oxide) (3) lauryl sulfo-succinum

Acid disodium 5.5

Cationic polymer ^{* 1}0.5

Hexadecanol 1.0

Ordinary salt 0.3

Sodium benzoate 0.3

Spice is an amount of

Painted thing is an amount of

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 12

The alkyl polyglucoside surface activity that logical formula I is represented

Agent, its restrictive condition is: R represents 9 to 11

The alkyl of carbon, J represents glucose, V is 0 He

W is 1.3 13%(weight)

The quarternary ammonium salt compound of following molecular formula (20) expression: 4.5

Poly(ethylene oxide) (3) sodium lauryl sulfate 5.5

Cationic polymer ^{* 1}0.5

White oil 0.2

Ordinary salt 0.3

Sodium benzoate 0.3

Spice is an amount of

Painted thing is an amount of

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 13

The alkyl polyglucoside surface activity that logical formula I is represented

Agent, its restrictive condition is: R represents 9 to 11

The alkyl of carbon, J represents glucose, V is 0 He

W is 1.3.12%(weight)

The quarternary ammonium salt compound 4.5 of following molecular formula (21) expression

(COR: hard tallow fatty acids acyl group)

(R ': hard tallow alkyl)

Poly(ethylene oxide) (3) lauryl sulfo-disodium succinate 5.5

Cationic polymer ^{* 1}0.5

Hexadecanol 1.0

Ordinary salt 0.3

Sodium benzoate 0.3

Spice is an amount of

Painted thing is an amount of

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 14

The alkyl polyglucoside surface activity that logical formula I is represented

Agent, its restrictive condition is: R represents 9 to 11

The alkyl of carbon, J represents glucose, V is 0 He

W is 1.3.13%(weight)

The quarternary ammonium salt compound 4.5 of following molecular formula (22) expression

(COR: hard tallow fatty acids acyl group)

(R ': hard tallow alkyl)

Poly(ethylene oxide) (3) sodium lauryl sulfate 5.5

Cationic polymer ^{* 1}0.5

White oil 0.2

Ordinary salt 0.3

Sodium benzoate 0.3

Spice is an amount of

Painted thing is an amount of

The aequum of purifying waste water

Annotate:

＊1：mfd.by????????Merck????????Co.，&????????Inc.，Merquat????????100.

Embodiment 15

The alkyl polyglucoside surface activity that logical formula I is represented

Agent, its restrictive condition is: R represents 9 to 11

The alkyl of carbon, J represents glucose, V is 0 He

W is 1.3.12%(weight)

The quarternary ammonium salt compound 6 of following molecular formula (23) expression

N-tetradecanoyl-L-disodium glutamate 3

Carboxymethyl cellulose ^{* 1}0.5

Polyether-modified siloxanes ^{* 2}0.5

Sodium benzoate 0.3

Spice is an amount of

Painted thing is an amount of

The aequum of purifying waste water

Annotate:

* 1:mfd.by Daicel Chemical Industries, Ltd.(product NO.1310).

* 2:mfd.by Shin-Etsu Chemical Co., Ltd., silazane KF-6005.

Described the present invention above, clearly, can change equally and a lot of methods.These variations are not considered to leave the spirit and scope of the invention, are that conspicuous all these variations all are intended to be included within the scope of appended claims to those skilled in the art.

Claims

1, a kind of Toiletry composition for hair care, it contains:

(b) anion surfactant; With

(c) water-soluble polymer.

2, the Toiletry composition for hair care of claim 1, wherein said quarternary ammonium salt compound as component (a) are the chemical compounds that following general formula (1) is represented:

Wherein:

R ¹The straight or branched alkyl or the alkenyl of expression 7 to 35 carbon;

R ², R ³And R ⁴Can be identical, also can be different, the alkyl or the hydroxyalkyl of 1 to 4 carbon of each expression, or hydrogen atom;

M represents-CONG-(wherein G represent hydrogen atom, or the alkyl of 1 to 3 carbon or hydroxyalkyl) ,-O-or-COO-;

X represents hydrogen atom or hydroxyl;

A ^-Expression halide ion or organic anion;

M is 2 or 3 integer;

N is 0 or 1 to 5 integer, and subsidiary following restrictive condition: n is 1 o'clock, and X is hydrogen atom or hydroxyl; N is 0,2,3,4 or 5 o'clock, and X is a hydrogen atom;

(R wherein ², R ³, R ⁴, X, A ^-The same with the definition of n)

When the restrictive condition below subsidiary: G was the alkyl of 1 to 3 carbon or hydroxyalkyl, Y can not be the alkyl and the hydroxyalkyl of 1 to 3 carbon.

3, the Toiletry composition for hair care of claim 2, wherein the chemical compound with general formula (1) expression is such chemical compound, wherein R ¹The straight or branched alkyl or the alkenyl of expression 7 to 21 carbon; R ², R ³And R ⁴Can be identical or different, the alkyl or the hydroxyalkyl of each expression 1 to 4 carbon; Y represents hydrogen atom, 1 to 3 carbon alkyl or hydroxyalkyl, the perhaps group represented of following formula:

4, the Toiletry composition for hair care of claim 1, wherein said quarternary ammonium salt compound as component (a) are the chemical compounds of following general formula (2) expression:

Wherein:

R ¹The straight or branched alkyl or the alkenyl of expression 7 to 35 carbon;

R ², R ³And R ⁴Can be identical, also can be different, the alkyl or the hydroxyalkyl of each expression 1 to 4 carbon, or hydrogen atom;

G represents the alkyl or the hydroxyalkyl of hydrogen atom or 1 to 3 carbon;

X represents hydrogen atom or hydroxyl;

A ^-Expression halide ion or organic anion;

M is 2 or 3 integer;

5, the Toiletry composition for hair care of claim 4, wherein the chemical compound with general formula (2) expression is such chemical compound, wherein R ¹The straight or branched alkyl or the alkenyl of expression 7 to 21 carbon; R ², R ³And R ⁴Can be identical or different, the alkyl or the hydroxyalkyl of each expression 1 to 4 carbon.

6, the Toiletry composition for hair care of claim 1, wherein said quarternary ammonium salt compound as component (a) are the chemical compounds with following general formula (3) expression:

Wherein:

R ¹The straight or branched alkyl or the alkenyl of expression 7 to 35 carbon;

A ^⊙Expression halide ion or organic anion.

7, the Toiletry composition for hair care of claim 6, wherein the chemical compound with general formula (3) expression is such chemical compound, wherein R ¹The straight or branched alkyl or the alkenyl of expression 7 to 21 carbon.

8, the Toiletry composition for hair care of claim 1, wherein said quarternary ammonium salt compound as component (a) are the chemical compounds of following general formula (4) expression:

Wherein:

R ⁷The alkylidene or the alkylene group of expression 2 to 6 carbon;

Z-represents halide ion, 1/2SO 2- ₄, HSO - ₄, RCOO ^-(wherein R represents the alkyl or the alkenyl of 1 to 4 carbon, can have hydrogen atom to be replaced by hydroxyl in alkyl or alkenyl) or R ' SO - ₄(the wherein alkyl of R ' expression 1 to 4 carbon); With

A is 2 to 9 integer.

9, the Toiletry composition for hair care of claim 8, wherein the chemical compound with general formula (4) expression is such chemical compound: R wherein ⁵And R ⁶Be methyl, R ⁷Be the alkylidene of 2 or 3 carbon, R ⁸Be hard tallow alkyl or hard palm oil alkyl, and R ⁹CO is a kind of hard tallow fatty acids acyl group or hard palm oil fatty acid acyl.

10, the Toiletry composition for hair care of claim 1, wherein said water-soluble polymer as component (c) is a water-soluble cationic polymer.

11, the Toiletry composition for hair care of claim 1, it contains the component (a) of the 0.1-20% of cosmetic composition weight, the component (c) of the component of 1-20% (b) and 0.01-2%.

12, the Toiletry composition for hair care of claim 1, it contains (d)-alkyl glucoside surfactant in addition.

13, the Toiletry composition for hair care of claim 12, wherein said alkyl glucoside surfactant as component (d) is represented with following logical formula I:

Wherein:

What J represented 5 or 6 carbon goes back the raw sugar residue;

V is the average addition molal quantity of oxirane, is worth to be 0-20;

W is an average of going back the raw sugar residue, is worth to be 1-10.

14, the Toiletry composition for hair care of claim 12, it contains the component (a) of the 1-20% of cosmetic composition weight, the component of 1-20% (b), the component (d) of the component of 0.01-3% (c) and 1-60%.