CN1064013A - The human body foam abluent that contains the foam enhancing polymer - Google Patents

The human body foam abluent that contains the foam enhancing polymer Download PDF

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Publication number
CN1064013A
CN1064013A CN91102025.XA CN91102025A CN1064013A CN 1064013 A CN1064013 A CN 1064013A CN 91102025 A CN91102025 A CN 91102025A CN 1064013 A CN1064013 A CN 1064013A
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surfactant
alkyl
human body
detergent
composition
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斯科特·W·赛弗特
马丽·L·巴特
劳伦斯·H·桑福德
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Procter and Gamble Co
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Procter and Gamble Co
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Organic Chemistry (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
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  • Detergent Compositions (AREA)

Abstract

A kind of human body is packed with the extruding bubbling container with washing cleansing composition, and said composition contains a small amount of preferred gentle surfactant and a small amount of foam enhancing polymer, uses water as solvent.The foam that is rich in the lactic acid sense of emitting from squeeze foamer can be used for skin effectively and clean.Product is gentle in the extreme.Thereby said composition contains the Organic substance of minute quantity has reduced environmental pollution, and final consumer is easy to prepare said composition by concentrate.

Description

The human body foam abluent that contains the foam enhancing polymer
The present invention relates to human body and clean the particularly facial abluent that cleans usefulness.
People clean health with liquid or blocks of solid compositions usually, and the active ingredient in these compositionss mainly is soap class and/or synthetic surfactant.Produce enough foams during for thin up, the consumption of surfactant is greater than cleaning actual requirement in the abluent.Excessive superficiality agent has stimulation to skin, also can cause environmental pollution.The foam abluent with after need not rinsing thereby the special product that usually cleans as skin use.For example, see United States Patent (USP) the 3rd, No. 692150 (authorize viola, on June 8th, 1976, bulletin was hereby incorporated by reference document).People to the mildness of this series products and the benefit understanding of the environment aspect of bringing after using still shallow.It is very little to produce the surfactant actual requirement of good cleaning performance to skin.Thereby most of surfactant for washing of common fancy soap has all been wasted, or stays on the box of containing fancy soap, does not perhaps dissolve fully as yet just to rinse with being had no benefit.When using the mechanical foaming device, can obtain the capacity foam with more a spot of surfactant.Yet along with the minimizing of dosage of surfactant, foam quality reduces, and may be lower than fancy soap preferably.
The present invention relates to human body liquid abluent (compositions).Said composition contains a small amount of surfactant for washing of 0.1%-about 16% according to appointment, surfactant is preferably comparatively gentle, and containing a small amount of polymer that can foam enhancing in the system of water as solvent, the container of packing described compositions can and produce foam (extruding foaming agent container) by individual's operation.The surfactant for washing content of the present composition is very low, thereby has reduced the dual adverse effect to skin and environment.Surprisingly, add after a spot of polymer increased viscosity, foam quality increases and the use ability of product is not had adverse effect.Relation between foam quality and the viscosity is so closely to make us very surprised.The very little change of viscosity just can cause the great changes of foam quality.
The human body that the present invention includes aqueous solution type is washed cleansing composition, and said composition comprises the surfactant for washing of (1) about 0.1%-about 16%, and about 1%-about 8% is better, and about 2%-about 6% is best, and surfactant for washing is preferably comparatively gentle; (2) the foam enhancing polymer of about 0.01%-about 5%, about 0.04%-about 2% is better.
The difference of the viscosity when compositions contains the foam enhancing polymer and do not contain the foam enhancing polymer is called " δ viscosity ".The viscosity of the compositions that produces by the foam enhancing polymer raise (with addition polymerization compound not time relatively) should be about 1 centipoise at least, about 2-is about, and 10 centipoises are better, about 2-is about, and 5 centipoises are better.The increase of viscosity can cause the increase of the foamy butterfat feel grade (hereinafter will be described in detail) of compositions, and it is about 0.5 that described foamy breast refers to that the increase of feel grade should be at least, and is at least about 1 better, is at least about 2 better.When in other words, the foamy butterfat feel grade ratio that does not contain the compositions of polymer contains polymer at least low 0.5.
It is about 1.5 that present composition viscosity should be at least, and about 2-about 15 is better, and about 2-about 12 is better, and about 3-is about, and 10 centipoises are best (the cloth Rockwell Bu Luoke Field LVT viscometer with band UL changer is measured down at 21 ℃).The lower limit of viscosity changes by foamy quality decision and with used surfactant system.In a word, as long as product disperses easily, upper limit viscosity can be high as much as possible; Thereby range of viscosities of the present invention comprises 20,30 even 40 centipoises.Range of viscosities is more excellent for the compositions of the formulated of about 5 centipoises of about 1-when not containing polymer.It is 5 better that the foamy butterfat feel grade (hereinafter will define) of the present composition is at least about, and is about 6 better.Some product also needs the utmost points such as foamy butterfat feel to approximate or greater than 7.
The consumption that does not contain surfactant in the prescription of extruding Efferescent compositions of polymer can higher (10-25%), and 15-20% is better, and the foamy butterfat feel grade that is produced is 6,7 or 8.
Compare with washing cleansing composition with the human body of fancy soap formula, compositions of the present invention is gentle especially, the consumption that reduces surfactant for washing make the effect of any surfactant for washing become comparatively gentle and also the foam that uses the squeeze foamer packing to make to produce more consumer accept and need not increase the consumption of rodent surfactant for washing in order to increase foam.
Just as discussed above, consider that from the position of environment the present invention has reduced the use amount of organic material, and the consumption by reducing material and do not use volatilizer to simplify the method for final consumer usefulness concentrate compositions formulated.This greatly reduces the demand of crushed foam disperser.
The present composition comprises the water of about 60%-about 99%, at least about 75% better, and contains a small amount of solvents that other are fit to.Relatively large water and more a spot of organic substance help reducing the influence to environment.
The surfactant of the present composition comprises water miscible for example alkali metal, ammonium or replaces the synthetic of ammonium, soap class, washing with Surfactant or its mixture.
The present composition contains that to be no more than the about 1%-of about 15%(about 8% better) the synthesis of detergent surfactant, synthesis of detergent is preferably gentle with surfactant.As United States Patent (USP) the 4th, 673, No. 525 (people such as Small, on June 16th, 1987 bulletin, this description document incorporated by reference) disclosed like that, the synthesis of detergent surfactant is gentle preferably.The synthesis of detergent of this article and gentleness defined herein with surfactant to the almost not infringement comparatively speaking of very thin cuticular barrier function.
In this compositions, synthetic detergent is preferred surfactant for washing.Preferred synthesis of detergent surfactant is anion or amphoteric ion type.Surfactant for washing still is known better to very gentle those of the effect of skin.
A lot of gentle surfactants are low foaming.The present invention is of value to the improvement of these low foaming surfactant performances.
The mixture that contains two kinds of amphoteric surfactantes is a preferred compositions of the present invention, and first kind of amphoteric surfactant is the imidazoline surfactant that is selected from formula I:
R wherein 1Be C 8-22Alkyl or alkenyl, R 2Be H or CH 2CH 2M, Z are CO 2M or CH 2CO 2M, M are H, alkali metal, ammonium or alkanol ammonium;
Second kind of amphoteric surfactant is the amino-alkane hydrochlorate that is selected from formula II, imido grpup two alkanoates of formula III and its mixture:
R 1NH（CH 2）nCO 2M（Ⅱ）
R 1N[（CH 2）mCO 2M] 2（Ⅲ）
Wherein n and m equal 1-4, R 1Identical with the definition of m and formula I.
The example that is fit to as first kind of amphoteric surfactant comprises those R 1Be C 8H 17(particularly iso-octyl), C 9H 19And C 11H 23The formula I chemical compound of alkyl.Especially preferred R wherein 1Be C 9H 19, Z is CO 2M, R 2It is the chemical compound of H; With those R 1Be C 11H 23, Z is COM, R 2Be CH 2CO 2The chemical compound of M.
Should be understood that many such commercially available amphoteric surfactantes be with anion surfactant (those sulphations C particularly 8-C 18Alcohol or C 8-C 18Manufactured and the sale of the form of the complex anion surfactant of acyl glyceride type).Thereby as a content of the present invention, compositions comprises that the equivalent proportion of first kind of amphoteric surfactant and anion surfactant is about 1.1(in order to keep electric neutrality basically) pre-composition or complex.
The synthesis of detergent surfactant of some useful preferred gentlenesses of the present invention comprises alkyl glycerol ether sulfonate (AGS); The anionic acyl sarcosinates class; Formoxyl taurine salt; Aliphatic acylglycine salt; N-acyl glutamic acid salt; The alkyl androstanediol class; Acyl group-2-ethylenehydrinsulfonic acid salt; Sulfo-succinic acid alkyl salt; α-alpha-sulfonated fatty acids, their salt and/or their ester; The alkyl acid phosphate esters; Ethoxylation alkyl acid phosphate esters; The alkyl ether sulphate class; Glucose ester and alkylation glucose ester, for example: the methyl glucoside ester; Acyl groupization and/or alkylation protein condensation substance class; The mixture of alkyl ether sulphate and alkyl amine oxide; Betaines; The Sudan's alkali (sultaine) class; With their mixture.Surfactant comprises the alkyl ether sulfate that contains the 1-12 ethyoxyl, particularly ammonium dodecyl ether sulfate and sodium.The alkyl of these surfactants and/or acyl group chain length are C 8-C 22, C wherein 10-C 18Better.
Preferred gentle synthesis of detergent comprises with surfactant: C 8-C 18MAP preferably is the form of their multichain alkanol to small part, for example, and N, N, N ', N '-four ethoxy-(ethylenediamine) (tetrol) salt; N-(C 8-C 18Fatty acyl group) glutamate; C 8-C 18Alkyl imino acetic acid salt and/or iminopropinate class; Preferred propionate compound; C 8-C 18The sweet nitronic acid salt of fatty acyl group and/or with add anion synthesis of detergent surfactant mixtures, and/or their mixture.
The example of anion synthetic detergent be the organic sulfur product salt for example:
(a) alkyl sulfate, molecular formula are R 24OSO 3M;
(b) alkylsulfonate, molecular formula are R 24OSO 3M;
(c) alkyl ether sulfate, molecular formula are R 24(OC 2H 4) xOSO 3M;
(d) alkyl monoglyceride sulfonate, molecular formula are R 24OG 1-2-OSO 3M; With
(e) alkylbenzenesulfonate, molecular formula is:
Figure 91102025X_IMG2
In the above-mentioned molecular formula, each R 24Represent about 8 straight or branched alkyl to about 24 carbon atoms; Each G represents a partial glycerol base ether; Each X represents the intermediary number of 1-10; Each M represents alkali metal, ammonium or a substituted ammonium ion.
The example of nonionic synthetic detergent is ethoxylized fatty alcohol (for example product of the oxirane that 1 mole Cortex cocois radicis aliphatic alcohol and about 3-are about 30 moles) and fatty acid amide such as coconut fatty acid single ethanol amide and more pure fraction such as dodecylic acid, tetradecanoic acid or Stearic acid diethanolamine salt.The 3rd, 962, No. 150 disclosed non-ionic surface active agents of aforesaid United States Patent (USP) can be used for the present composition.
A preferred compositions is not have the compositions of soap substantially, and PH is about 8.5 for about 4.5-, and about 6-about 8 is better.
It also is desirable using soap, for example, and as the alkali metal soap of surfactant for washing.This soap can be by the directly saponification and making of fat and oil, perhaps by the free fatty neutralization for preparing in preparation technology independently and make.Useful especially is to be derived and sodium, potassium and alkanol ammonium (as: triethanol ammonium) salt of the mixture of the fatty acid that comes by Oleum Cocois and tallow, for example, and the sodium of tallow and Cortex cocois radicis and potash soap.
" tallow " used herein speech is meant fatty acid mixt, and the carbon chain length distribution of representative fatty acids mixture is approximately 2.5%C 14, 29%C 16, 23%C 18, 2% palmitoleic acid, 41.5% oleic acid and 3% linoleic acid (first three fatty acid is a saturated acid).Other mixture with similar distribution also can use, and are for example derived by various tallows and next fatty acid.Tallow also can be made the unsaturated fatty acids acid moieties change satisfied fatty acid partially or entirely into by sclerosis (for example hydrogenation).
This paper so-called " Oleum Cocois " and " coconut fatty acid " are the mixture of fatty acid (CNFA), and the typical carbon chain length distribution of this mixture is approximately 8%C 7, 7%C 10, 48%C 12, 17%C 14, 9%C 16, 2%C 187% oleic acid and 2% linoleic acid (the first six fatty acid is a saturated acid).For example palm-kernel oil and babassu oil are also included within Oleum Cocois and the coconut fatty acid scope to have the mixture in other sources of similar carbon chain length distribution.
As mentioned above, preferred surfactant for washing is the synthetic surfactant of the disclosed gentleness of No. the 4th, 673,525, United States Patent (USP) (people such as Small, on June 16th, 1987 bulletin) of this paper document incorporated by reference.
Have been found that in squeeze foamer container (back will be described in detail) and can blistered liquid to wash that the specific polymeric material of adding in the cleansing composition can provide more acceptable foam and other performances of not damaging product.Usually, useful polymer to a certain extent or can be water-soluble or can aqueous dispersion, and the viscosity that can provide expectation increases, and the polymer that is fit to is a high molecular (weight average molecular weight is for example by light scattering determining), generally be about 2,000-3,000,000, about 5,000-2,500,000 is better, and about 7,000-1,000,000 is better.Significantly, because the effect of polymer is the viscosity that increases compositions, thereby the thickening capabilities of polymer is for 1% being dispersed in polymer in the water and viscosity being increased surpass 1 centipoise better down at 21 ℃ (70 °F), and it is better to surpass 2 centipoises.Useful polymer is cation, nonionic, both sexes and the anionic polymer that is used for cosmetic industry.Cation, non-ionic resin and composition thereof are better, and particularly those are of value to the resin of skin.The better polymerization thing also has for example ethoxy and carboxymethyl cellulose, guar gum class hydroxypropyl trimethylammonium guar gum for example of cellulose derivative.Owing to add the purpose of polymer is to increase viscosity, thereby compositions preferably do not contain a large amount of materials that can reduce viscosity, does not particularly have the material of other effects except reducing viscosity.
1 or the multinomial human body abluent that contains quaternary polyamines that discloses in the following patent:
Patent No. date inventor
US 3，761，418 9/1973 Parran，Jr.;
US 4，234，464 11/1980 Morshauser;
US 4，061，602 12/1977 Oberstar et al.;
US 4，472，297 9/1984 Bolich et al.;
US 4，491，539 1/1985 Hoskins et al.;
US 4，540，507 9/1985 Grollier;
US 4，673，525 6/1987 Small et al.;
US 4，704，224 11/1987 Saud;and
Jap.J57105 6/30/82 Pola.
All above-mentioned patent this paper documents incorporated by reference, particularly disclosed main human body abluent and polymer.
As mentioned above, the useful polymer of the present invention is any typical polymers that can increase viscosity.The preferred substituted cellulose of the present invention usually is used to wash cleansing composition and is applicable to compositions with contact skin.Good especially substituted cellulose polymer is easily water-soluble or aqueous dispersion, particularly can increase viscosity during those low consumptions and the solution that produces is transparent polymer.The example of these polymer has carboxymethyl and ethoxy cellulose polymer.
Concrete example comprises: hydroxyethyl-cellulose (for example: Natrosol 250MXR, Natrosol 250HR or the like); And cationic cellulose polymer (for example: the JR-400 of Union Carbide Corporation).
The molecular weight of other aniones of the present invention, nonionic and cationic polymeric skin regulator is 1,000-3,000,000.Useful polymer is selected from:
(I) nonionic, anion and cationic polysaccharides;
The copolymer of saccharide of (II) formula I and compatible synthon;
(III) contains the water-soluble synthetic polymer of water solublity group, as: quaternary sillicones and quaternized polycarboxylate.
The instantiation of cationic polysaccharides comprises: cationic hydroxyethyl cellulose, for example, JR-400 and LM-200 are made by Union Carbide Corporation.
The copolymer that can be used for saccharide of the present invention and synthon comprises the copolymer that contains following saccharide: glucose, galactose, mannose, arabinose, xylose, fucose, fructose, glycosamine, galactosamine, glucuronic acid, galacturonic acid and 5 or 6 yuan of cyclitols.Synthesising biological polymeric gel for example keltrol T(molecular weight is about 2,000,000) also be a kind of suitable polymer.Polymer also comprises methylol, ethoxy and the hydroxypropyl derivatives of above-mentioned sugar.
More excellent polymer also has the large volume amine polymer, U.S. Patent application 07/374 is seen in definition, No. 315, apply on June 30th, 1989 by Robert G.bartolo and Louis F.Wong, title is " the human body detergent that contains the large volume cationic polymer of abnormal smells from the patient coupling ", described application the present invention document incorporated by reference.This polymer has following general formula, and wherein skeleton is replaced by " polymer " and stable cationic functional group invariably.
(I) (polymer)-(CR ' H-CR R-NR R R), wherein R-R is H or any other substituent group, R 4, R 5And R 6The abnormal smells from the patient of the amine that forms of linking to each other with N is littler than trimethylamine, R 4, R 5And R 6In preferably have at least one to be that chain length is the alkyl of about 2-24 carbon atom, perhaps contain the alkoxyl alkyl of about 2-12 carbon atom.
The example of preferred large volume polymer is the cationic guar gum with following array structure, and wherein " guar gum " represents the guar gum skeleton:
Figure 91102025X_IMG3
The example of a large volume amine hydroxyethyl-cellulose (HEC) polymer is:
Figure 91102025X_IMG4
Selected in the following formula " X " can provide the substitution value of about 0.5-about 4 typical, can provide the substitution value of about 1-about 2.5 better.There is not the abnormal smells from the patient problem in this " large volume amine " group and helps regulating skin.
It is better that the present composition contains the polymer of about 0.01%-about 5%, and it is better to contain about 0.04%-about 2%.United States Patent (USP) the 4th, 758, No. 282 (people such as Slober, bulletin this paper on July 19th, 1988 document incorporated by reference) discloseder preferred cationic guar gums (galactomannan class).07/456, No. 065 (J.R.Knochel and P.E.Vest, December in 1989 application on the 21st) disclosed cationic guar gum of U.S. Patent application is the polymer that is fit to, particularly when cation group is replaced by the large volume amine groups.
For isonomic chemical compound (for example, three replace amine), the volatility of amine depends on that increasing decrease in molecular weight decomposes.In other factors, volatility depends on the boiling point of clean amine.Abnormal smells from the patient also depends on evaporable amount when reaching nose strongly.There is good influence in " large volume " gum base group to volatility in addition, thereby the abnormal smells from the patient of amine is little.Replace for pure hydrocarbon, alkyl chain long more (or the long-chain substitution value is big more) abnormal smells from the patient is more little.Thereby the boiling point of preferred large volume is higher than room temperature, at least be 30 ℃ better, greater than about 80 ℃ better.
Preferred non-ionic polymers does not almost have the activity of surfactant for washing.Disclosed non-ionic surface active agent-the polymer of embodiment that No. the 3rd, 962,150, aforesaid United States Patent (USP) can be used as suds booster, and consumption is to make the increase of composition viscosity be at least about 1 centipoise.The non-ionic polymers that is fit to comprises poly alkylene glycol, and ethylene glycol polymer class for example comprises the polymer when having other groups for example alkyl or acyl group existing.For example Polyethylene Glycol (20-500) distearate (or equivalent) can rise to desired value with viscosity.
Some addition polymers comprise the copolymer of polyvinylpyrrolidone and vinylpyrrolidone, and for example those contain vinyl acetate, dimethylaminoethyl methacrylate and the quaternary conversion product identical with Methylsulfate and the polymer and the copolymer of vinyl alcohol and vinyl acetate.One this acrylate copolymer comprises the copolymer of polyacrylic acid, polyacrylamide, acrylate and methacrylic acid and the copolymer of methyl vinyl ether and maleic anhydride.
As the disclosed embodiment of following patent (this paper document incorporated by reference), the squeeze foamer packing is well-known.United States Patent (USP): the 3rd, 709, No. 437 Wright, on January 9th, 1973 was announced; The 3rd, 937, No. 364, Wright, on February 10th, 1976 was announced; The 4th, 022, No. 351, Wright, on May 10th, 1977 was announced; The 4th, 147, No. 306, Bennett, on April 3rd, 1979 was announced; The 4th, 184, No. 615, Wright, on January 22nd, 1980 was announced; The 4th, 598, No. 862, Rice, on July 8th, 1986 was announced; The 4th, 615, No. 467, Grogan etc., on October 7th, 1986 was announced; With French Patent (FRP) 2,604,622, Verhulst, on April 8th, 1988 is open.
Said vesse packing is not used any volatilizer thereby all is safe to consumer and environment, and they almost can make all surface activator compositions produce foam.Though do not need to add the foam adjuvant that only adds for stable foam, this material is useful.Because foam must interrupt to guarantee the container operate as normal, the effect of foam adjuvant even opposite in some compositions.Compositions is placed container reservoir (plastics squeeze bottle).With the hands squeeze receptacle compositions is pressed to bubbler head (perhaps using other the foamy method of generation), compositions is mixed with air herein, makes more uniformity of foam through a homogenize mechanism then.Discharge then uniformity, the normal pressure aerated foam.
The minimum pressure of starting squeeze receptacle is about 1 pound/square inch (gauge pressure), and typical pressure is about 2-about 7 pounds/square inch (gauge pressures).Minimum pressure is relevant with the channel size of dispenser, the viscosity of compositions etc.
Usually, foam density should be between the about 0.25g/cc of about 0.002-, and about 0.01-is about, and 0.12g/cc is better, and about 0.02-is about, and 0.07g/cc is better.Foam density and butterfat feel grade are inversely proportional to, so the low person of foam density is good.
The present composition can contain inessential component, for example in human body normally used those components in the abluent.The present composition can comprise antibacterial commonly used, and it is about 4% that consumption is about 0.1%-, and about 0.2%-about 1% is better.The typical antibacterial that the present invention is suitable for is 3,4-two-and 3,4 ', 5-three bromo-salicylamides; 4,4 '-two chloro-3-(trifluoromethyls)-carbanilide; 3,4,4 '-Amolden MCM 400; Phenyl phenol or propanol; Chloro hexene diacid salt; Six amidine salt; Chlorophenol DP 300; Salicylic acid; Parachlorometaxylenol; Octopirox; Mixture with these materials.The present composition can also comprise that nonionic emollient commonly used transfers additive as dermatomere, and consumption is for being no more than 20%, and about 1%-about 15% is better.These materials comprise, for example, mineral oil, aliphatic Isosorbide Dinitrate (are seen United States Patent (USP) the 3rd, 988, No. 255, Seiden, on October 26th, 1976 was announced, this paper document incorporated by reference), the derivant of lanoline and lanoline, esters is isopropyl myristate and triglyceride Oleum Cocois for example for example.
The present composition can add for example volume of foam and the quality (creaminess) of coconut fatty acid to improve its generation of free fatty.
Can also add spice commonly used, dyestuff, antiseptic and pigment in the present composition, consumption is no more than about 1.5%.The spice consumption is good during for about 0.1%-1%, and dyestuff and amount of pigment are that about 0.001%-was good in about 0.5% o'clock.
Preferred compositions of the present invention also contains and is no more than about 20% wetting agent, preferably is selected from glycerol and free fatty or its mixture.The compositions that contains about 15% lubricant of about 1%-is better.
The referenced patent of this paper discloses other inessential components.
Foamy butterfat feel grade test is used for measuring foamy quality or the newborn ester feel that the squeeze foamer packing produces.Foamy newborn ester feel tier definition is comprehensively measured for foamy stability in hands (main body is direct in other words) and lubricity.Be divided into 9 grades approximately with respect to product standard (setting is arranged) foam.
I grade size
1-9 " foamy newborn ester feel grade " is used for characterizing newborn ester feel, and 1 is minimum newborn ester sense, and 9 is maximum newborn ester sense.Lactic acid feel value is defined as:
Foam breast ester
The feel classification standard
1.0 blistered liquid hand soaps (hereinafter will define)
5.0 the foam solution that commercially available squeeze foamer packing produces
7.0 blistered washing one's hands used fancy soap
II. demarcate: the compositions of standard and the foam of its generation
Before demarcation, wash one's hands with the liquid hand soaps in advance.
A. liquid hand soaps
Form the % effective content
Potash soap (50 oleic acid/50 dodecylic acids) 26
Free fatty (50 oleic acid/50 dodecylic acids) 1.8
Potassium acetate 4
Glycerol 2
Opacifier 0.4
EDTA 0.1
Water balance
Foamy butterfat feel grade=1.0
Step
1. hands is soaked
2. scattering 1g liquid hand soaps on hand.
3. add water (0.5cc) and rubbing two handss are made circular motion 5 times.
4. rotate both hands up hill and dale 20 times, foam is scraped the quantifier top.
5. judge foamy stability and lubricity by compressing and the foam of rubbing in enumerator top and hands.Measuring foam butterfat feel grade is 1.
B. foam solution/bubbler is packed
Component % effective content
Myristoyl sodium glutamate 5.0
Dodecanoyl diglycollic amide 5.0
Coconut monoethanolamide CAB 0.75
Dodecanoyl sodium sarcosinate 0.75
Butterfat feel grade=5.5
Commercially available squeeze foamer packing
Bottle is made by Uster, Switzerland Kunstoff company limited, comprising:
1.150ml circular polyethylene from high pressure process/low-pressure polyethylene bottle
2. the push-and-pull of standard, switch spreading head
3. " white " mixing chamber
4. diameter is the long pipe that soaks of 11.5mm of 2.0mm
Step
1. the 40-50ml foam solution of packing in the spreading bottle.
2. hands is soaked
3. squeeze foamer packing produces foam and at quantifier top spreading 1.5g foam.
4. judge foamy stability and lubricity by compressing and the foam of rubbing in enumerator top and hands, measuring foam breast ester feel grade is 5.5.
C. fancy soap
Component (approximately) %(effective content)
Coco group hydroxyethyl sulfonate 50
Soda soap (80% tallow/20% Cortex cocois radicis) 12
Stearic acid 18.5
Coconut fatty acid 3
Sodium n-alkylbenzenesulfonate 1.1
Hydroxyethyl sulfonate 0.6
Na 2SO 40.5
Water becomes balance-dividing with other
Breast ester feel grade=7.0
Step:
1. before test, fancy soap placed 95 water pretreatment 2 minutes.
2. with 95 (about 35 ℃) water hands is soaked.
3. rotate the soap bars 6 times in the hands fully.
4. add water (0.5cc) and rubbing both hands and make circular motion 5 times.
5. rotate both hands fully 20 times, foam is scraped on the quantifier.
6. judge foamy stability by compressing and the foam of rubbing in enumerator top and hands, measuring foam breast ester feel grade is 7.
III. measure the step of foam grade
1. hands is soaked.
2. about 1.5g foam is spread on the quantifier.
3. judge foamy stability and lubricity by compressing and the foam of rubbing in enumerator top and hands.9 grades of reference standard determine that foam is which waits the utmost point.
The foam of all products of the present invention breast ester feel grade should be 5 at least, high better (measures by this method).Foamy newborn ester feel grade be 6 o'clock better.Also do not see compositions in the prior art greater than 6.Best foam breast ester feel grade is 7.Usually only a large amount of could be when using surface activity greater than 7, if in the squeeze foamer compositions, do not use polymer then can not be greater than 7.
Measure the testing regulations of low-viscosity (mobile) liquid
Equipment needed thereby;
Cloth Rockwell Bu Luoke Field LVT viscometer; With
Cloth Rockwell Bu Luoke Field UL adaptor
Measuring method:
1. level placed in viscometer;
2. with 70 (about 21 ℃) water flushing sample rooms and axle, dry then.
3. fasten axle;
4. the assurance sample test is carried out at 70 °F;
5. in test chamber, slowly add the 16ml sample and guarantee not form bubble (UL of other models is by answering device may need the 18.5ml sample);
6. test chamber being moved to axle goes up and is tied on the viscometer;
7. start viscometer and make axle rotation, maximum permissible revolution (is 60rpm for the sample less than 10 centipoises);
8. allow the stable reading time to be about 30 seconds, when reading reading, depress clutch then and fall motor;
9. the reading of step 8 should be proofreaied and correct, and multiply by the rotating speed factor (seeing below) of axle then;
10. with 70 water cleaning down chambers and axle, test next sample then;
11. check the accuracy of viscometer in case of necessity with standard sample.
Correction factor:
60rpm viscosity centipoise=(axle reading-0.4) x0.1
30rpm viscosity centipoise=axle reading x0.2
The description that more detailed data is published referring to the Bu Luoke Field.
The following example only explains usefulness.
Usually, the preparation method of employing is exactly the preparation method that those liquid commonly used are washed cleansing composition.The squeeze foamer packing is used kunstoff Supermatic packing, perhaps its slight modified model.The comparing result of report uses the packing of same kind.
Embodiment 1
Prescription 1
Component % effective content
Myristoyl sodium glutamate 5.0
Dodecane amide diethanolamine 5.0
Coconut monoethanolamide CAB 0.75
Dodecanoyl sodium sarcosinate 0.75
Dowicil 200 0.2
Spice 0.05
Water 88.25
Viscosity: 2.4
Foamy newborn ester feel grade: 5.5
Foam density: 0.05
PH value: about 6.7
Prescription 1 is the good foam compositions that does not contain polymer, and viscosity is 2.4, and foamy butterfat feel grade is 5.5.Prescription 2 is the preferred compositions that contain polymer, and viscosity is 7.1, and foamy butterfat feel grade is 6.4.Prescription 3 is another preferred compositions that contain polymer, and viscosity is 5.3, and foamy butterfat feel grade is 7.5.
Prescription 2
Component % effective content
Single Cortex cocois radicis alkylphosphonic
（Quadrol Salt） 2.5
Coconut monoethanolamide propyl group diformamide oxide
（Standamox CAW） 0.5
Cortex cocois radicis potassium (hydrogenant animal proteinum)
（Lamepon S，32%） 0.03
1,3 butylene glycol 2.5
Glycerol 2.0
Aloe 0.5
Methyl metagin 0.5
Propyl group metagin 0.2
Synthesising biological polymeric gel (keltol T) * 0.05
Spice 0.05
FD＆C＃2 0.0017
Water balance
Viscosity: 7.1
Foamy butterfat feel grade: 6.4
Foam density: 0.07
* Keltol T is a kind of polysaccharide, by kelco, and San Diego, Calif makes, and molecular weight is about 2,000, and 000.
Prescription 3
Component % effective content
Cortex cocois radicis Anfu carboxyl glycinate/sodium lauryl sulphate
(Mirarol 2MCA type, 39.5%) 2.8
N-dodecyl-imino group propanoic acid
（Deriphat 160C，28%） 2.8
Glycerol 5.0
Hydroxyethyl-cellulose (HEC) glue
（Natrosol 250HR）＊ 0.09
Euxyl K400 0.2
Spice 0.1
Water balance
Molecular weight: about 1,000,000
Viscosity: 5.3
Foamy butterfat feel grade: 7.5
Foamy density: 0.04
PH value: 7.8
Prescription 4
Component % effective content
Myristoyl sodium glutamate 1.09
Dodecane amide diglycollic amide 1.09
Coconut monoethanolamide CAB 0.16
Dodecanoyl sodium sarcosinate 0.16
HEC glue (Natrosol 250MXR) 0.16
Dowicil 200 0.2
Spice 0.05
Water balance
Viscosity: 4.5
PH：7.2
Prescription 5
Component percentages (weight)
Cortex cocois radicis Anfu carboxyl glycinate/0.56(effective content)
Sodium lauryl sulphate (Miranol 2MCA type, 39,5%)
Deriphat 160c 1.69(effective content)
Hydroxyethyl-cellulose (1% solution) 10.05
Glycerol 15.00
Ammonium chloride 1.00
Euxyl K400 0.20
Spice 0.10
Citric acid (10% solution) is regulated PH and is equaled 7
Water balance
Embodiment 2
In embodiment 2, prescription A does not contain polymer, and viscosity is 1.5, and foamy butterfat feel grade is 5.2.Prescription B, C and D have all added polymer, viscosity and the foamy butterfat of minute quantity
The feel grade all has increase, and prescription E contains 32 times effective surfactant for washing, but identical with the viscosity of prescription B, C and D.
Prescription (% effective content)
Component A B C D E
Coco group sodium glutamate 7.3 7.3 7.3 7.3 22.6
HEC glue (Natrosol 250MXR) *-0.14---
PEG 150 distearate * *--1.85--
JR400 resin (season amyloid) * * *---0.27-
Water balance balance balance balance balance
* molecular weight: about 720,000
* molecular weight: about 7,000
* * molecular weight: about 400,000
Viscosity: 1.5 5.0 5.0 5.0 5.0
Foamy butterfat feel grade: 5.2 6.5 6.3 6.8 7.0
Prescription (% effective content)
Component F G
Myristoyl sodium glutamate 5.0 5.0
Dodecanoyl diglycollic amide 5.0 5.0
Coconut monoethanolamide CAB 0.75 0.75
Dodecanoyl sodium sarcosinate 0.75 0.75
PEG 150 distearates-1.0
Dowicil 200 0.2 0.2
Spice 0.05 0.05
Water balance balance
Viscosity 2.4 5.0
Foamy butterfat feel class 4 .8 6.5
Embodiment 3
Implementing in 3 prescription 1 and 2; 3 and 4; 5 and 6; 7 and 8; 9 and 10; 11 and 12; 13 and 14 is the Comparative Examples that contain polymer and do not contain polymer, and the balance term of 1-22 is a water.
Prescription (% effective content)
Component 1234
Coco group sodium glutamate 5.0 5.0 11.5 11.5
HEC glue (Natrosol 250MXR)-0.165-0.120
Viscosity 1.3 5.1 2.0 5.1
Foamy butterfat feel class 4 .6 7.4 5.8 6.7
Foamy density 0.09 0.05 0.07 0.06
Prescription (% effective content)
Component 5678
Myristoyl sodium glutamate 2.17 2.17 5.0 5.0
Dodecanoyl diglycollic amide 2.17 2.17 5.0 5.0
Coconut monoethanolamide CAB 0.33 0.33 0.75 0.75
Dodecanoyl sodium sarcosinate 0.33 0.33 0.75 0.75
The % effective content 5.0 5.0 11.5 11.5 of gross weight
HEC glue (Natrosol 250MXR)-0.150-0.100
Viscosity 1.5 5.0 2.4 5.2
Foamy butterfat feel class 4 .8 6.3 5.3 6.3
Foamy density 0.07 0.07 N/A 0.07
Prescription (% effective content)
Component 9 10 11 12
MAP (Miranol
L-100) (Quadrol salt) 5.0 5.0 11.5 11.5
HEC glue (Natrosol 250MXR)-0.150-0.113
Viscosity 1.3 5.2 1.8 5.0
Foamy butterfat feel class 5 .5 6.5 5.5 7.3
Foamy density 0.06 0.08 N/A N/A
The N/A=non-availability
The N/A=non-availability.
Prescription (% effective content)
Component 13 14 15 16
Cortex cocois radicis potassium (hydrogenant animal protein)
（Lamepon S，32%） 2.26 2.26 5.19 5.19
Cortex cocois radicis Anfu carboxyl glycine salt/
Sodium lauryl sulphate
(Miranol 2MCA type, 48%) 1.03 1.03 2.36 2.36
Palm-kernel oil fatty acid sarcosinate 0.85 0.85 1.96 1.96
N-dodecyl-imines propanoic acid
（Deriphat 160C，28%） 0.86 0.86 1.98 1.98
The % effective content 5.0 5.0 11.5 11.5 of gross weight
HEC glue (Natrosol 250MXR)-0.150-0.135
Viscosity 1.3 5.2 1.7 5.0
Foamy butterfat feel class 4 .8 6.8 5.0 7.0
Foamy density 0.08 0.08 0.07 0.05
Embodiment 4
In embodiment 4, prescription 1,4,7,10,13 and 16 does not contain polymer.
Prescription (% effective content)
Component 12345
Coco group sodium glutamate 1.0 1.0 1.0 3.0 3.0
HEC glue (Natrosol 250MXR)-0.18 0.255-0.170
Water balance balance balance balance balance
Viscosity 1.1 5.2 8.5 1.2 5.0
Foamy butterfat feel grade 3.1 6.1 7.0 5.1 6.8
Foamy density 0.05 0.04 0.06 0.04 0.04
Prescription (% effective content)
Component 6789
Coco group sodium glutamate 3.0 5.0 5.0 5.0
HEC glue (Natrosol 250MXR) 0.255-0.165 0.230
The water balance balance balance balance
Viscosity 8.6 1.3 5.1 8.5
Foamy butterfat feel grade 7.4 4.6 7.4 6.9
Foamy density 0.03 0.04 0.035 0.03
Attention: prescription 1-6 contains the water of about 97%-about 99%, and the foamy newborn ester feel grade of prescription 2,3,5 and 6 is respectively 6.1,7.0,6.8 and 7.4.
Prescription (% effective content)
Component 10 11 12 13 14
N-dodecyl imines propanoic acid
（Deriphat 160C，28%） 0.5 0.5 0.5 1.5 1.5
Cortex cocois radicis Anfu carboxyl glycinate/
Sodium lauryl sulphate
(Miranol 2MCA type, 39%) 0.41 0.41 0.41 1.23 1.23
Total surfactant 0.91 0.91 0.91 2.73 2.73
HEC glue (Natrosol 250MXR)-0.185 0.260-0.175
Water balance balance balance balance balance
Viscosity 1.1 4.9 8.2 1.2 4.8
Foamy butterfat feel grade 3.8 6.8 6.6 4.1 7.2
Foamy density 0.05 0.045 0.04 0.05 0.025
Prescription (% effective content)
Component 15 16 17 18
N-dodecyl imines propanoic acid
（Deriphat 160C，28%） 1.5 2.5 2.5 2.5
Cortex cocois radicis Anfu carboxyl glycinate/
Sodium lauryl sulphate
(Miranol 2MCA type, 39%) 1.23 2.06 2.06 2.06
Total surfactant 2.73 4.56 4.56 4.56
HEC glue (Natrosol 250MXR) 0.250-0.165 0.242
The water balance balance balance balance
Viscosity 8.3 1.3 4.9 8.6
Foamy butterfat feel grade 7.8 4.0 6.4 7.6
Foamy density 0.035 0.05 0.03 0.03
Embodiment 5
Test recipe [%(weight) effective content]
Component A B C
Coco group sodium glutamate 22.00--
Cortex cocois radicis Anfu carboxyl glycinate/-5.16-
Sodium lauryl sulphate
(Miranol 2MCA type, 48%)
Palm-kernel oil fatty acid sarcosinate-4.28-
（Medialan KF 40%）
N-dodecyl-imines propanoic acid-4.32-
（Deriphat 160c，28%）
Cortex cocois radicis potassium (hydrogenant animal protein)-11.39-
（Lamepon S，32%）
Sodium lauryl sulphate--1.77
Total % effective content (weight) 22.00 25.15 17.7
Viscosity 4.9 5.1 5.0
Foamy butterfat feel class 6 .6 7.5 6.0
Can clearly be seen that by above-mentioned Comparative Examples the present composition compares with the same compositions of addition polymerization compound not, foamy butterfat feel grade increases.

Claims (21)

1, a kind of human body is used the squeeze foamer container package with washing cleansing composition, it is characterized in that: described compositions contains the surfactant of 0.1%-16% (weight); The water of 60%-99%; And the Tackified polymeric of 0.01%-5% (weight); Wherein, surfactant be selected from synthesis of detergent with Surfactant, soap, and composition thereof, make the viscosity increase of compositions be at least the polymer of 1 centipoise after described Tackified polymeric representative adds.
2, according to the human body of claim 1 with washing cleansing composition, wherein said surfactant mainly is the synthesis of detergent surfactant, described water content is at least 75%.
3, according to the human body of claim 2 with washing cleansing composition, wherein said compositions contains the synthesis of detergent surfactant of 1%-8%, and surfactant is selected from: alkylsurfuric acid salt, alkyl glyceryl ether sulfonate class, anionic acyl sarcosinates class, methyl-acyl taurine salt class, acyl glycine salt, N-acyl glutamic acid salt, alkyl androstanediol class, acyl group-2-hydroxyl sulfoacid salt, salts of alkyl sulfosuccinates salt, α-alpha-sulfonated fatty Barbiturates; α-sulfonation methyl ester salt, alkyl phosphoric acid esters, ethoxylated alkyl phosphate ester, methyl glucoside ester, acyl group/protein condensation substance class, betaines, the Sudan's alkali (Sultaines), the alkyl ether sulfate that contains 1-12 ethyoxyl or alkyl ether sulfate and trialkylamine hopcalite and their mixture, wherein said synthesis of detergent contains 8-22 carbon atom with the alkyl chain in the surfactant.
4, according to the human body of claim 3 with washing cleansing composition, wherein said synthesis of detergent is selected from surfactant: C 8-C 18Single alkyl phosphonic acid salt, N-(C 8-C 18Acyl group) glutamate, Glu, C 8-C 18Acyl glycinate, C 8-C 18Alkyl imino acetate and/or imido grpup propionate, and composition thereof.
5, according to the human body of claim 2 with washing cleansing composition, said composition contains the water of the described synthesis of detergent of 1%-8% with surfactant and 80%-98%; What wherein said compositions added viscosity behind the described polymer increases to the 2-10 centipoise.
6, according to the human body of claim 2 with washing cleansing composition, wherein said polymer volume is a 0.04%-2%(weight).
7, according to the human body of claim 2 with washing cleansing composition, wherein said PH is 4.5-8.5.
8, according to the human body of claim 1 with washing cleansing composition, the molecular weight of wherein said polymer is 2,000-3,000,000 and be selected from:
(I) anion, nonionic and cationic polysaccharide;
The copolymer of (II) described sugar (I) and synthon;
(III) water-soluble with synthetic polymer aqueous dispersion; With
(IV) their mixture.
9, human body according to Claim 8 is with washing cleansing composition, and wherein said polymer volume is 0.04%-2%.Viscosity lifts away from the 2-10 centipoise.
10, according to the human body of claim 9 with washing cleansing composition, wherein said surfactant for washing be selected from soap, synthesis of detergent with Surfactant, and composition thereof.
11, according to the human body of claim 10 with washing cleansing composition, wherein said compositions contains the synthesis of detergent surfactant of 1%-8%, and surfactant is selected from: alkyl glyceryl ether sulfonate, anionic acyl sarcosinates, methyl-acyl taurine salt, acyl glycinate, N-acyl glutamate, alkyl androstanediol, acyl group-2-hydroxy sulfonate, salts of alkyl sulfosuccinates salt, α-alpha-sulfonated fatty hydrochlorate; α-sulfonation methyl ester salt, alkylphosphonate, ethoxylation alkylphosphonate, methyl glucoside ester, acyl group/protein condensation substance class, betanin, the Sudan's alkali (Sultaines), the alkyl ether sulfate that contains 1-12 ethyoxyl or alkyl ether sulfate and trialkylamine hopcalite, and composition thereof, wherein said synthesis of detergent contains 8-22 carbon atom with the alkyl chain in the surfactant.
12, according to the human body of claim 10 with washing cleansing composition, wherein said synthesis of detergent is selected from surfactant: C 8-C 18Single alkyl phosphonic acid salt, N-(C 8-C 18Acyl group) glutamate, Glu, C 8-C 18Acyl glycinate, C 8-C 18Alkyl imino acetate and/or imido grpup propionate, and composition thereof.
13, according to the human body of claim 1 with washing cleansing composition, the foamy lactic acid feel grade of wherein said compositions is at least 5.
14, according to the human body of claim 1 with washing cleansing composition, the foamy newborn ester feel grade of wherein said compositions is at least 6.
15, according to the human body of claim 1 with washing cleansing composition, the foamy newborn ester feel grade of wherein said compositions is at least 6-8.
16, a kind of human body cleaning compositions is used the squeeze foamer container package, and the contained surfactant of described compositions is selected from: synthesis of detergent with surfactant, soap, and composition thereof; The water of 60%-99%; The foamy newborn ester feel grade of wherein said compositions is 6-8.
17, according to the human body of claim 16 with washing cleansing composition, wherein said surfactant mainly is the synthesis of detergent surfactant, described water content is at least 75%.
18, according to the human body of claim 17 with washing cleansing composition, wherein said compositions contains the synthesis of detergent surfactant of 10%-25%, and surfactant is selected from: alkyl sulfate, alkyl glyceryl ether sulfonate, anionic acyl sarcosinates, methyl-acyl taurine salt, acyl glycinate, N-acyl glutamate, alkyl androstanediol, acyl group-2-hydroxy sulfonate, salts of alkyl sulfosuccinates salt, α-alpha-sulfonated fatty hydrochlorate; α-sulfonation methyl ester salt, alkylphosphonate, ethoxylation alkylphosphonate, methyl glucoside ester, acyl group/protein condensation substance, betanin, the Sudan's alkali (Sultaines), the alkyl ether sulfate that contains 1-12 ethyoxyl or alkyl ether sulfate and trialkylamine hopcalite, and composition thereof, wherein said synthesis of detergent contains 8-22 carbon atom with the alkyl chain in the surfactant.
19, according to the human body of claim 18 with washing cleansing composition, wherein said synthesis of detergent is selected from surfactant: C 8-C 18Single alkyl phosphonic acid salt, N-(C 8-C 18Acyl group) glutamate, Glu, C 8-C 18Acyl glycinate, C 8-C 18Alkyl imino acetate and/or imido grpup propionate, and composition thereof.
20, according to the human body of claim 16 with washing cleansing composition, said composition contains the water of the described synthesis of detergent of 15%-20% with surfactant and 80%-98%.
21, according to the human body of claim 16 with washing cleansing composition, said composition contains the water of the described synthesis of detergent of 10%-15% with surfactant and 80%-98%.
CN91102025.XA 1990-03-27 1991-03-27 The human body foam abluent that contains the foam enhancing polymer Pending CN1064013A (en)

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JPH05506259A (en) 1993-09-16
WO1991014759A1 (en) 1991-10-03
PT97097A (en) 1991-12-31
CA2078443A1 (en) 1991-09-28
AU7457191A (en) 1991-10-21
MY106392A (en) 1995-05-30
EP0521893A1 (en) 1993-01-13
EP0521893A4 (en) 1992-11-24

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