CN108760832A - Gas sensor sensitive material and preparation method thereof - Google Patents
Gas sensor sensitive material and preparation method thereof Download PDFInfo
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- CN108760832A CN108760832A CN201810498239.4A CN201810498239A CN108760832A CN 108760832 A CN108760832 A CN 108760832A CN 201810498239 A CN201810498239 A CN 201810498239A CN 108760832 A CN108760832 A CN 108760832A
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- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
- G01N27/125—Composition of the body, e.g. the composition of its sensitive layer
- G01N27/127—Composition of the body, e.g. the composition of its sensitive layer comprising nanoparticles
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Abstract
The invention discloses a kind of gas sensor sensitive materials and preparation method thereof.Wherein, the gas sensor sensitive material contains following component：SnO288~95wt%, Sb2O32~5wt%, SiO20.2~2wt%, Al2O30.2~2wt%, PdCl20.5~4wt%.Technical solution of the present invention passes through SnO288~95wt%, Sb2O32~5wt%, SiO20.2~2wt%, Al2O30.2~2wt%, PdCl2The rational formula of 0.5~4wt% designs, and is conducive to the long-term working stability for promoting gas sensor；Pass through SnO2、Al2O3And Sb2O3Cooperation, the mechanical strength for improving sensitive membrane, thermally and chemically stability reduces the potential barrier of excitable material pellet interface, reduces the resistance for being formed by sensitive membrane, improves sensitivity.
Description
Technical field
The present invention relates to gas sensor materials, more particularly to gas sensor sensitive material and preparation method thereof.
Background technology
Core one of of the gas sensitive material as semiconductor gas sensor, to the actually detected ability of sensor
Play an important roll.When preparing semiconductor gas sensor, the formula of size of sensitive material prepares most important, directly affects
The characteristic of sensor.Currently, the formula of the sensitive material slurry of the overwhelming majority designs and prepares method and cannot meet sensor
Requirement, the sensitivity of the sensor of preparation is relatively low and long-term working stability is poor, this directly affects and limit these biographies
The practical application area of sensor.
Invention content
The main object of the present invention is to provide gas sensor sensitive material, it is intended to solve existing gas sensor sensitive material and exist
When being applied to semiconductor gas sensor, the sensitivity of prepared sensor is relatively low, the poor problem of long-term working stability.
To achieve the above object, the present invention proposes that a kind of gas sensor sensitive material, the gas sensor sensitive material contain
There is following component：SnO288~95wt%, Sb2O32~5wt%, SiO20.2~2wt%, Al2O30.2~2wt%,
PdCl20.5~4wt%.
Optionally, the gas sensor sensitive material contains following component：SnO292~94wt%, Sb2O32.5~
4wt%, SiO20.3~1wt%, Al2O30.5~1.2wt%, PdCl21~2.5wt%.
Optionally, the SnO2In powdered, and grain size is 20~80nm.
Optionally, the Sb2O3In powdered, and grain size is 20~60nm.
Optionally, the SiO2In powdered, and grain size is 20~60nm.
Optionally, the Al2O3In powdered, and grain size is 40~80nm.
Optionally, the gas sensor sensitive material also includes and the SnO2, Sb2O3, SiO2, Al2O3And PdCl2Phase
Mixed organic solvent.
Optionally, the organic solvent is ethyl alcohol-pine tar mixed alkoxide solution.
The invention also discloses a kind of preparation methods of gas sensor sensitive material, include the following steps：
By SnO2, Sb2O3, SiO2, Al2O3And PdCl2It mixes and is scattered in organic solvent, obtain gas sensor sensitivity material
Material.
Optionally, described by SnO2, Sb2O3, SiO2, Al2O3And PdCl2It mixes and is scattered in organic solvent and be specially：
By the SnO2, Sb2O3, SiO2, Al2O3And PdCl2It mixes and assisting ultrasonic is scattered in organic solvent.
Optionally, the organic solvent is ethyl alcohol-pine tar mixed alkoxide solution.
Technical solution of the present invention passes through SnO288~95wt%, Sb2O32~5wt%, SiO20.2~2wt%, Al2O3
0.2~2wt%, PdCl2The rational formula of 0.5~4wt% designs, and is conducive to the long-term working stability for promoting gas sensor；
Pass through SnO2、Al2O3And Sb2O3Cooperation, the mechanical strength for improving sensitive membrane, thermally and chemically stability reduce sensitive material
The potential barrier of grain interface, reduces the resistance for being formed by sensitive membrane, improves sensitivity.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with
The structure shown according to these attached drawings obtains other attached drawings.
Fig. 1 is the sensitivity of gas sensor and 1 sample of comparative example to 100ppm alcohol gas prepared by Examples 1 to 5
With temperature change curve graph；
Fig. 2 is the long-term working stability curve of 1 sample of gas sensor and comparative example prepared by Examples 1 to 5；
Fig. 3 is the long-term working stability curve of 2 gas sensor of comparative example；
The scanning electron microscope (SEM) photograph of sensitive membrane after 2 gas sensor of Fig. 4 embodiments continuously works on power 2 months；
The scanning electron microscope (SEM) photograph of sensitive membrane after 5 gas sensor of Fig. 5 embodiments continuously works on power 2 months；
The scanning electron microscope (SEM) photograph of sensitive membrane after 2 gas sensor of Fig. 6 comparative examples continuously works on power 2 months.
The embodiments will be further described with reference to the accompanying drawings for the realization, the function and the advantages of the object of the present invention.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation describes, it is clear that described embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art obtained without creative efforts it is all its
His embodiment, shall fall within the protection scope of the present invention.
It is to be appreciated that the directional instruction (such as up, down, left, right, before and after ...) of institute is only used in the embodiment of the present invention
In explaining relative position relation, motion conditions etc. under a certain particular pose (as shown in the picture) between each component, if should
When particular pose changes, then directionality instruction also correspondingly changes correspondingly.
In addition, the description for being such as related to " first ", " second " in the present invention is used for description purposes only, and should not be understood as
It indicates or implies its relative importance or implicitly indicate the quantity of indicated technical characteristic.Define as a result, " first ",
The feature of " second " can explicitly or implicitly include at least one of the features.In addition, the technical side between each embodiment
Case can be combined with each other, but must can be implemented as basis with those of ordinary skill in the art, when the combination of technical solution
Conflicting or cannot achieve when occur will be understood that the combination of this technical solution is not present, also not the present invention claims guarantor
Within the scope of shield.
The present invention proposes that a kind of gas sensor sensitive material, the gas sensor sensitive material contain following component：SnO2
88~95wt%, Sb2O32~5wt%, SiO20.2~2wt%, Al2O30.2~2wt%, PdCl20.5~4wt%.
With SnO2Nano particle is sensitive material, and large specific surface area, gap structure is abundant, and surface and internal activity are high,
In air, surface energy largely adsorbs oxygen molecule, and under certain heating temperature, the oxygen of chemisorption will be with O- or O2-
Formation exist, due to the absorption of these negative oxygen ions, sensitive material surface forms certain electronics dissipation layer, leads to SnO2Grain
High potential barrier is generated between son, and sensitive material sheet resistance is caused to increase.When sensitive material encounters reducibility gas (such as H2、CO、CH4
Deng) after, reducibility gas reacts with the negative oxygen ion for being adsorbed on sensitive material surface, and the electronics that oxygen captures is released back into
Sensitive material surface, to make the reduction of sensitive material resistance.Therefore, when being prepared into sensing element by above-mentioned sensitive material, lead to
The conductance variation of detection sensing element is crossed to realize the detection to gas.
Due to SnO2For nano particle under long-term hot environment, crystal grain will appear growth, and air-sensitive performance will appear drift,
Long-term working stability is poor, in order to improve SnO2The long-term working stability of base sensitive membrane needs formula incorporated in the present invention.Its
In, Binder Phase is introduced, main function is to connect, tense in the sintering process of gas sensor, fixing sensitive material particle so that
The sensitive membrane of formation is strongly adhered to together with matrix, the advantageous long-term working stability for promoting gas sensor.Wherein, SiO2
Play the basic framework effect of Binder Phase；Al2O3Fluxing agent is can be used as, improves the mechanical strength of sensitive membrane, thermally and chemically stablize
Property；Sb2O3The potential barrier for reducing excitable material pellet interface, reduces the resistance of sensitive membrane, advantageous to improve material sensitivity.Meanwhile
It is anti-for being catalyzed air-sensitive using doped catalyst (Pd) in order to effectively improve selectivity and sensitivity of the sensitive material to gas
It answers.
Further, the gas sensor sensitive material contains following component：SnO292~94wt%, Sb2O32.5~
4wt%, SiO20.3~1wt%, Al2O30.5~1.2wt%, PdCl21~2.5wt%.By advanced optimizing proportioning,
Promote long-term working stability and the sensitivity of prepared gas sensor.
Further, the SnO2In powdered, and grain size is 20~80nm.
Further, the Sb2O3In powdered, and grain size is 20~60nm.
Further, the SiO2In powdered, and grain size is 20~60nm.
Further, the Al2O3In powdered, and grain size is 40~80nm.
The grain size of sensitive material directly affects the gas-sensitive property of material, and grain size is smaller, and specific surface area is bigger, and active site is got over
It is more, it is stronger to the detectability of VOC gas.SnO2As main sensitive material, when grain size is less than 100nm, SnO2Nano material is to gas
The detectable limit of body is lower and sensitivity is higher, the SnO synthesized in the application2The grain size of nano particle is 20~80nm.It is making
When standby slurry and sensitive membrane, in order to reduce other components (such as Sb as far as possible2O3, SiO2, Al2O3) to SnO2Nano grain surface
Covering, keep SnO as far as possible2The contact area of nano particle and detection gas ensures response sensitivity, so Sb2O3,
SiO2, Al2O3Equal particles are as appropriate as possible, and grain size is close to SnO2The size of nano particle.
Those skilled in the art are known, PdCl2As catalyst precursor, will be given birth in follow-up formula of size processing procedure
At nanoscale simple substance Pd or PdO, catalytic action is played, therefore to presoma PdCl2It does not need to limit its grain size.
Grain size described above is statistical data, is a value range, is such as tested using laser diffraction analyzer.
Further, the gas sensor sensitive material also includes and the SnO2, Sb2O3, SiO2, Al2O3And PdCl2
The organic solvent mixed.Organic solvent is equivalent to carrier, controls the rheological behavior of slurry, prepared by gas sensor sensitive material
At the form of slurry, in order to make gas sensor.The dosage of organic solvent can depend on the gas sensor type subsequently prepared
It is different and different.When the dosage of organic solvent is more, slurry more dilutes, and when the dosage of organic solvent is few, slurry is more dense
It is thick.To those skilled in the art, the dosage of organic solvent can depend on actual conditions and adjust.
Further, the organic solvent is ethyl alcohol-pine tar mixed alkoxide solution.
The invention also provides a kind of preparation methods of gas sensor sensitive material, include the following steps：By SnO2,
Sb2O3, SiO2, Al2O3And PdCl2It mixes and is scattered in organic solvent, obtain gas sensor sensitive material.
Further, described by SnO in order to remarkably promote the evenly dispersed of each component2, Sb2O3, SiO2, Al2O3With
PdCl2It mixes and is scattered in organic solvent and be specially：By the SnO2, Sb2O3, SiO2, Al2O3And PdCl2It mixes and assists surpassing
Sound is scattered in organic solvent.
Further, the organic solvent is ethyl alcohol-pine tar mixed alkoxide solution.
The consistency of ethyl alcohol is relatively low, but readily volatilized, causes the coating processes for preparing gas sensor more difficult, and quickly wave
Hair is easy to cause the sensitive membrane to be formed and crack occurs, influences the performance of gas sensor；The consistency of terpinol is higher, it is not easy to wave
Hair, the drying of sensitive membrane is slower, influences element making.Therefore, point of the ethyl alcohol-pine tar mixed alkoxide solution as formula of size is prepared
Dissipate solvent, be conducive to improve coating processes, sensitive membrane stability and final gas sensor performance.
Below with reference to specific embodiment, present invention is described, it should be noted that these embodiments are only to describe
Property, without limiting the invention in any way.
The preparation process of heater-type sintering-type gas sensor is as follows：
Step 1：By with a pair of of gold electrode and four Pt leads ceramic tube and the welding of Ni-Cr alloy heater strip
On six leg bases；
Step 2：Gas sensor sensitive material is coated on ceramic pipe surface, and 4h is sintered in 700 DEG C, heater-type is obtained and burns
Junction type gas sensor.
Following embodiment prepares corresponding heater-type sintering-type gas sensor according to above-mentioned preparation process.
Embodiment 1
A kind of preparation method of gas sensor sensitive material, includes the following steps：
Weigh SnO288wt%, Sb2O35wt%, SiO22wt%, Al2O32wt%, PdCl23wt%, by each component
Mix and assisting ultrasonic in volume ratio be 2:In the mixed solution of 1 ethyl alcohol-terpinol, gas sensor sensitive material is obtained.
Wherein, the SnO2In powdered, and grain size is 20~80nm.
The Sb2O3In powdered, and grain size is 20~60nm.
The SiO2In powdered, and grain size is and grain size is 20~60nm.
The Al2O3In powdered, and grain size is and grain size is 40~80nm.
Using the gas sensor sensitive material of acquisition heater-type sintering-type gas sensor (tool is prepared by coating, being sintered
Body step referring to aforementioned heater-type sintering-type gas sensor preparation process).
Embodiment 2
A kind of preparation method of gas sensor sensitive material, includes the following steps：
Weigh SnO292wt%, Sb2O34.5wt%, SiO20.5wt%, Al2O31wt%, PdCl22wt%, will be each
Component mixing and assisting ultrasonic in volume ratio be 2:In the mixed solution of 1 ethyl alcohol-terpinol, gas sensor sensitivity material is obtained
Material.
Wherein, the SnO2In powdered, and grain size is 20~80nm.
The Sb2O3In powdered, and grain size is 20~60nm.
The SiO2In powdered, and grain size is and grain size is 20~60nm.
The Al2O3In powdered, and grain size is and grain size is 40~80nm.
Using the gas sensor sensitive material of acquisition heater-type sintering-type gas sensor (tool is prepared by coating, being sintered
Body step referring to aforementioned heater-type sintering-type gas sensor preparation process).
Embodiment 3
A kind of preparation method of gas sensor sensitive material, includes the following steps：
Weigh SnO293.5wt%, Sb2O33.5wt%, SiO20.7wt%, Al2O30.7wt%,
PdCl21.6wt%, by each component mix and assisting ultrasonic in volume ratio be 2:In the mixed solution of 1 ethyl alcohol-terpinol, obtain
Obtain gas sensor sensitive material.
Wherein, the SnO2In powdered, and grain size is 20~80nm.
The Sb2O3In powdered, and grain size is 20~60nm.
The SiO2In powdered, and grain size is and grain size is 20~60nm.
The Al2O3In powdered, and grain size is and grain size is 40~80nm.
Using the gas sensor sensitive material of acquisition heater-type sintering-type gas sensor (tool is prepared by coating, being sintered
Body step referring to aforementioned heater-type sintering-type gas sensor preparation process).
Embodiment 4
A kind of preparation method of gas sensor sensitive material, includes the following steps：
Weigh SnO295wt%, Sb2O32wt%, SiO21.5wt%, Al2O31wt%, PdCl20.5wt%, will be each
Component mixing and assisting ultrasonic in volume ratio be 2:In the mixed solution of 1 ethyl alcohol-terpinol, gas sensor sensitivity material is obtained
Material.
Wherein, the SnO2In powdered, and grain size is 20~80nm.
The Sb2O3In powdered, and grain size is 20~60nm.
The SiO2In powdered, and grain size is and grain size is 20~60nm.
The Al2O3In powdered, and grain size is and grain size is 40~80nm.
Using the gas sensor sensitive material of acquisition heater-type sintering-type gas sensor (tool is prepared by coating, being sintered
Body step referring to aforementioned heater-type sintering-type gas sensor preparation process).
Embodiment 5
A kind of preparation method of gas sensor sensitive material, includes the following steps：
Weigh SnO294wt%, Sb2O31.6wt%, SiO20.2wt%, Al2O30.2wt%, PdCl24wt%, will
Each component mixing and assisting ultrasonic in volume ratio be 2:In the mixed solution of 1 ethyl alcohol-terpinol, gas sensor sensitivity material is obtained
Material.
Wherein, the SnO2In powdered, and grain size is 20~80nm.
The Sb2O3In powdered, and grain size is 20~60nm.
The SiO2In powdered, and grain size is and grain size is 20~60nm.
The Al2O3In powdered, and grain size is and grain size is 40~80nm.
Using the gas sensor sensitive material of acquisition heater-type sintering-type gas sensor (tool is prepared by coating, being sintered
Body step referring to aforementioned heater-type sintering-type gas sensor preparation process).
Comparative example 1
The heater-type sintering-type gas sensor MQ-3B of Zhengzhou Wei Sheng Science and Technology Ltd.s production.
Comparative example 2
This comparative example is similar to Example 1, and difference lies in gas sensor sensitive material is only by SnO2Ultrasonic disperse is in second
It is prepared in the mixed solution of alcohol-terpinol.
Analysis test
Gas-sensitive property test is carried out using the WS-30A air-sensitive testers of Zhengzhou Wei Sheng Science and Technology Ltd.s production.First to
The sample room of tester is passed through zero level air, until the resistance of gas sensor is constant；Then, it is passed through tested gas to sample room
Body (e.g., ethyl alcohol etc.), this experiment is using 100ppm ethyl alcohol as test object, at this point, it is 5V to measure voltage.Recording voltage becomes at any time
The adsorption curve of change, curve to be adsorbed reach balance, stop injection gas, and test terminates.It can be calculated from adsorption curve
The sensitivity of gas sensor.
Since national standard does not have clear stipulaties for the ingredient of TVOC gases, it is contemplated that basic condition in the industry (ethyl alcohol
Gas is demarcated), therefore this experiment is test gas with alcohol gas.
The resistance of the gas sensor of 1 each embodiment and comparative example 2 of table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 2 | |
| Resistance (M Ω) | 9.6 | 7.2 | 3.3 | 11.5 | 12.4 | 76 |
As shown in Figure 1, the heater-type sintering-type gas sensor best effort being prepared in embodiment 1 to embodiment 5
Temperature is 280 DEG C, hence it is evident that is less than 360 DEG C of comparative example 1, therefore can significantly reduce energy consumption.It is prepared in embodiment 1 to embodiment 5
Obtained heater-type sintering-type gas sensor sensitivity is respectively 10.8,12.5,14.3,13.5,15.6 to be above comparative example 1
10.5.By Fig. 1 to Fig. 6 it is found that the spirit for the heater-type sintering-type gas sensor being prepared in embodiment 1 to embodiment 5
Sensitivity and long-term working stability are suitable with comparative example 1, hence it is evident that are better than comparative example 2.
The long-term working stability of gas sensor and the mechanical performance of sensitive membrane it is closely related, pass through 2 He of comparison diagram
Fig. 3 by being formulated it is found that designed, and the drift of the gas sensor sensitivity of the present embodiment significantly improves, i.e. job stability
It is significantly improved, wherein the SiO in formula2And Al2O3Itself could act as fluxing agent and Binder Phase, be conducive to improve institute's shape
At sensitive membrane mechanical strength, so that sensitive membrane is not easy to burst apart under long-term work environment and is fallen off.
As shown in figures 4-6, it is formulated prepared sensitive membrane through the invention in the case where 2 months persistently work on power, sensitive membrane
Still comparatively dense and smooth (embodiment 2 and 5), the sensitive membrane without inventive formulation is quick in the case where 2 months persistently work on power
Feel film and apparent crack (comparative example 2) occur, this is also further illustrated the present invention with the mechanical performance that can improve sensitive membrane.
Sb2O3Middle Sb adulterates Sn2+ lattices, favorably improves conductance.
As shown in table 1, the comparative example 2 of our surface compositions is free of, sensitive film resistance is 76M Ω, contains inventive formulation
The sensitive film resistance of Examples 1 to 5 is 9.6,7.2,3.3,11.5,12.4M Ω respectively, hence it is evident that is less than comparative example 2, this also illustrates
Inventive formulation can improve the electrical property of sensitive membrane.
The foregoing is merely the preferred embodiment of the present invention, are not intended to limit the scope of the invention, every at this
Under the inventive concept of invention, using equivalent structure transformation made by description of the invention and accompanying drawing content, or directly/use indirectly
In the scope of patent protection that other related technical areas are included in the present invention.
Claims (10)
1. a kind of gas sensor sensitive material, which is characterized in that the gas sensor sensitive material contains following component：SnO2 88
~95wt%, Sb2O32~5wt%, SiO20.2~2wt%, Al2O30.2~2wt%, PdCl20.5~4wt%.
2. gas sensor sensitive material as described in claim 1, which is characterized in that the gas sensor sensitive material contain as
Lower component：SnO292~94wt%, Sb2O32.5~4wt%, SiO20.3~1wt%, Al2O30.5~1.2wt%,
PdCl21~2.5wt%.
3. gas sensor sensitive material as claimed in claim 1 or 2, which is characterized in that the SnO2In powdered, and grain size
For 20~80nm.
4. gas sensor sensitive material as claimed in claim 1 or 2, which is characterized in that the Sb2O3In powdered, and grain size
For 20~60nm.
5. gas sensor sensitive material as claimed in claim 1 or 2, which is characterized in that the SiO2In powdered, and grain size
For 20~60nm.
6. gas sensor sensitive material as claimed in claim 1 or 2, which is characterized in that the Al2O3In powdered, and grain size
For 40~80nm.
7. gas sensor sensitive material as claimed in claim 1 or 2, which is characterized in that the gas sensor sensitive material is also
Include and the SnO2, Sb2O3, SiO2, Al2O3And PdCl2The organic solvent mixed.
8. gas sensor sensitive material as claimed in claim 7, which is characterized in that the organic solvent is ethyl alcohol-terpinol
Mixed solution.
9. a kind of preparation method of gas sensor sensitive material, which is characterized in that include the following steps：
By SnO2, Sb2O3, SiO2, Al2O3And PdCl2It mixes and is scattered in organic solvent, obtain gas sensor sensitive material.
10. the preparation method of gas sensor sensitive material as claimed in claim 9, which is characterized in that described by SnO2,
Sb2O3, SiO2, Al2O3And PdCl2It mixes and is scattered in organic solvent and be specially：By the SnO2, Sb2O3, SiO2, Al2O3With
PdCl2It mixes and assisting ultrasonic is scattered in organic solvent；
And/or the organic solvent is ethyl alcohol-pine tar mixed alkoxide solution.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57182155A (en) * | 1981-05-01 | 1982-11-09 | Asahi Glass Co Ltd | Gas detecting element |
| CN1165797A (en) * | 1996-05-22 | 1997-11-26 | 四川联合大学(四川大学) | Gas sensitive alumina-based material and gas sensitive component |
| JP2004333289A (en) * | 2003-05-07 | 2004-11-25 | Ngk Spark Plug Co Ltd | Gas sensor |
| CN102041474A (en) * | 2010-12-20 | 2011-05-04 | 昆明理工大学 | Preparation method for nano precious metal particle modified tin dioxide gas sensitive material |
| CN102692437A (en) * | 2012-06-12 | 2012-09-26 | 惠州市富济电子材料有限公司 | Gas sensitive material, carbon monoxide gas sensitive element adopting gas sensitive material and preparation method of carbon monoxide gas sensitive element |
-
2018
- 2018-05-22 CN CN201810498239.4A patent/CN108760832A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57182155A (en) * | 1981-05-01 | 1982-11-09 | Asahi Glass Co Ltd | Gas detecting element |
| CN1165797A (en) * | 1996-05-22 | 1997-11-26 | 四川联合大学(四川大学) | Gas sensitive alumina-based material and gas sensitive component |
| JP2004333289A (en) * | 2003-05-07 | 2004-11-25 | Ngk Spark Plug Co Ltd | Gas sensor |
| CN102041474A (en) * | 2010-12-20 | 2011-05-04 | 昆明理工大学 | Preparation method for nano precious metal particle modified tin dioxide gas sensitive material |
| CN102692437A (en) * | 2012-06-12 | 2012-09-26 | 惠州市富济电子材料有限公司 | Gas sensitive material, carbon monoxide gas sensitive element adopting gas sensitive material and preparation method of carbon monoxide gas sensitive element |
Non-Patent Citations (2)
| Title |
|---|
| M. SAHA 等: "Effect of alumina addition on methane sensitivity of tin dioxide thick films", 《SENSORS AND ACTUATORS B》 * |
| 新华书店北京发行所: "《化工词典》", 31 August 1969, 燃料化学工业出版社 * |
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