CN108754539A - Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material - Google Patents

Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material Download PDF

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Publication number
CN108754539A
CN108754539A CN201810571414.8A CN201810571414A CN108754539A CN 108754539 A CN108754539 A CN 108754539A CN 201810571414 A CN201810571414 A CN 201810571414A CN 108754539 A CN108754539 A CN 108754539A
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China
Prior art keywords
anode
particle
little particle
filler material
roasting
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Pending
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CN201810571414.8A
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Chinese (zh)
Inventor
王长山
张建全
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Inner Mongolia Hoing Carbon Co Ltd
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Inner Mongolia Hoing Carbon Co Ltd
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Priority to CN201810571414.8A priority Critical patent/CN108754539A/en
Publication of CN108754539A publication Critical patent/CN108754539A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08Cell construction, e.g. bottoms, walls, cathodes
    • C25C3/12Anodes
    • C25C3/125Anodes based on carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Using anode scrap little particle as the prebaked anode roasting technique of filler material, anode scrap little particle is broken into certain particle size, it is sieved by certain particle size, when anode green bodies shove charge, it is roasted according to prebaked anode roasting common process using anode scrap little particle as filler material, after prebake anode roasting is burnt down at coming out of the stove, the anode scrap little particle for being sticked to prebaked anode surface is cleaned out, the anode scrap little particle return system under clearing up is reused.Present invention process roasts the filler material used using anode scrap little particle as prebaked anode, not only greatly reduce the production cost of prebaked anode roasting, and anode scrap little particle will not be consumed during prebaked anode roasts, and can be reused, and have the advantages that at low cost and environmental protection and energy saving.

Description

Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material
Technical field
The present invention relates to prebaked anode roasting technique technical fields, and in particular to using aluminum electrolytic residual electrode little particle as filling out The prebaked anode roasting technique of charge.
Background technology
China is electrolyzing aluminum industry big producer, and with increasing substantially for electrolytic aluminium, the demand to anode block is also all with day Increase, and 30 ~ 40 kilograms of filler material need to be consumed by often producing one ton of prebaked anode, the main function of filler material is:Prevent anodic oxygen Change;Conduction heat makes anode carbon block thermally equivalent;The shape of fixed anode carbon block prevents its deformation;Hinder the suitable of volatile matter Profit discharge, and also to export volatile matter.It is mainly metallurgical coke to produce the filler material in roasting process currently as prebaked anode And calcined petroleum coke, the price of metallurgical coke is at 1100 yuan/ton;The price of calcined petroleum coke is therefore every at 2400 yuan/ton The filler material expense that year consumes generates a large amount of carbon dioxide pollution environment more than 500,000,000 RMB.
Pre-baked anode for aluminum consumes lower part 90%-85% or so during electrolytic aluminium factory use, and remaining 10-15% is left The right side is anode scrap, the bulky grain anode scrap after broken(Diameter is more than 8mm)It can be used as prebaked anode raw material;Prebaked anode little particle is residual Pole occurs mainly with the anode scrap outer layer before being crushed, since anode scrap outer layer is by long-time high-temperature oxydation and contact electrolyte, ash content Impurity is more(More than 2%), and intensity is low, cannot function as the use of prebaked anode raw material to prevent from influencing product quality.In this way, prebake Anode little particle anode scrap is taken as waste material and undersells, as the situation is tense for national environmental protection, prebaked anode little particle anode scrap conduct Solid waste commercial value persistently drops, future face sell do not go out even to need to spend to look for the company for having disposition qualification into Row disposition.
Invention content
The present invention provides using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material, showed with solution There is skill
Filler material existing for art is of high cost, pollution environment, resource recycling the problems such as.
The technical solution adopted by the present invention to solve the technical problems is:
Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material, steps are as follows for specific method:
(1)It is broken:Anode scrap little particle is broken into certain particle size, is sieved by certain particle size, specific grain size proportion is that grain size is more than 8 The particle of millimeter accounts for the 85% of total particle, and the particle less than 8 millimeters accounts for the 15% of total particle;
(2)Shove charge:When anode green bodies shove charge, by step(1)The obtained particle less than 8 millimeters is as filler material according to prebake sun Pole roasting common process is roasted;
(3)Scarfing cinder:After prebake anode roasting is burnt down at displaying for the first time, viscous anode scrap little particle on the anode surface is cleaned out, prebake Anode is tested and is packaged after qualification, and the anode scrap little particle return system under clearing up is reused.
Above-mentioned anode scrap little particle is that remaining anode scrap is reacted in aluminium electroloysis.
Anode scrap little particle of the above-mentioned grain size more than 8 millimeters is roasted as raw material according to prebaked anode roasting common process It burns.
Anode scrap little particle is the waste in prebaked anode aluminium electrolysis process, generally undersells or garbage disposal, anode scrap are small Particle will not be consumed during prebaked anode roasts, and can be reused.
Present invention process roasts the filler material used using anode scrap little particle as prebaked anode, not only greatly reduces pre- The production cost of anode-baking is roasted, and anode scrap little particle will not be consumed during prebaked anode roasts, and can be repeated It utilizes, has the advantages that at low cost and environmental protection and energy saving.
Specific implementation mode
Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material, steps are as follows for specific method:
(1)It is broken:Anode scrap little particle is broken into certain particle size, is sieved by certain particle size, specific grain size proportion is that grain size is more than 8 The particle of millimeter accounts for the 85% of total particle, and the particle less than 8 millimeters accounts for the 15% of total particle;
(2)Shove charge:When anode green bodies shove charge, by step(1)The obtained particle less than 8 millimeters is as filler material according to prebake sun Pole roasting common process is roasted;
(3)Scarfing cinder:After prebake anode roasting is burnt down at displaying for the first time, viscous anode scrap little particle on the anode surface is cleaned out, prebake Anode is tested and is packaged after qualification, and the anode scrap little particle return system under clearing up is reused.

Claims (3)

1. using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material, it is characterized in that specific method step is such as Under:
(1)It is broken:Anode scrap little particle is broken into certain particle size, is sieved by certain particle size, specific grain size proportion is that grain size is more than 8 The particle of millimeter accounts for the 85% of total particle, and the particle less than 8 millimeters accounts for the 15% of total particle;
(2)Shove charge:When anode green bodies shove charge, by step(1)The obtained particle less than 8 millimeters is as filler material according to prebake sun Pole roasting common process is roasted;
(3)Scarfing cinder:After prebake anode roasting is burnt down at displaying for the first time, viscous anode scrap little particle on the anode surface is cleaned out, prebake Anode is tested and is packaged after qualification, and the anode scrap little particle return system under clearing up is reused.
2. it is according to claim 1 using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material, It is characterized in that:The anode scrap little particle is that remaining anode scrap is reacted in aluminium electroloysis.
3. it is according to claim 1 using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material, It is characterized in that:Anode scrap little particle of the grain size more than 8 millimeters is carried out as raw material according to prebaked anode roasting common process Roasting.
CN201810571414.8A 2018-06-06 2018-06-06 Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material Pending CN108754539A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810571414.8A CN108754539A (en) 2018-06-06 2018-06-06 Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810571414.8A CN108754539A (en) 2018-06-06 2018-06-06 Using aluminum electrolytic residual electrode little particle as the prebaked anode roasting technique of filler material

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CN108754539A true CN108754539A (en) 2018-11-06

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111717907A (en) * 2020-06-19 2020-09-29 内蒙古霍煤通顺碳素有限责任公司 Pre-baked anode carbon blank filler and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104694967A (en) * 2015-03-29 2015-06-10 索通发展股份有限公司 Prebaked anode baking technology by utilizing smelting slags as filler
CN105347825A (en) * 2015-11-19 2016-02-24 湖南祯晟炭素实业有限公司 Preparation method of high-strength low-electrical resistance normal-temperature cold ramming paste
CN106222700A (en) * 2016-08-22 2016-12-14 中国铝业股份有限公司 A kind of method utilizing anode scrap to prepare aluminum carbon anode

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104694967A (en) * 2015-03-29 2015-06-10 索通发展股份有限公司 Prebaked anode baking technology by utilizing smelting slags as filler
CN105347825A (en) * 2015-11-19 2016-02-24 湖南祯晟炭素实业有限公司 Preparation method of high-strength low-electrical resistance normal-temperature cold ramming paste
CN106222700A (en) * 2016-08-22 2016-12-14 中国铝业股份有限公司 A kind of method utilizing anode scrap to prepare aluminum carbon anode

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李龙钦,: ""残极灰综合利用探讨"", 《2015河南有色金属学术年会论文集》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111717907A (en) * 2020-06-19 2020-09-29 内蒙古霍煤通顺碳素有限责任公司 Pre-baked anode carbon blank filler and preparation process thereof

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Application publication date: 20181106

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