CN108752052A - A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof - Google Patents
A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof Download PDFInfo
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- CN108752052A CN108752052A CN201810416853.1A CN201810416853A CN108752052A CN 108752052 A CN108752052 A CN 108752052A CN 201810416853 A CN201810416853 A CN 201810416853A CN 108752052 A CN108752052 A CN 108752052A
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
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- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/08—Flooring or floor layers composed of a number of similar elements only of stone or stone-like material, e.g. ceramics, concrete; of glass or with a top layer of stone or stone-like material, e.g. ceramics, concrete or glass
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract
The invention discloses a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tiles and preparation method thereof, include the following steps：Step 1, place election, step 2, raw material selection, step 3, manufacture, step 4 cut out material, step 5, filling.The present invention is by being equipped with anti-scratch layer, increase the hardness of ceramic tile itself, bottom germinal layer raw material are added into water, mud is worn into the ball mill, mud dusts in the drying process, powder is pressed into type in press, then pass through drying, sintering, as bottom germinal layer, skid resistant course forms slurry, then slurry is applied to bottom germinal layer surface, melting occurs after 1000 DEG C of -1500 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer of formation first together, anti-scratch layer also forms slurry, then slurry is applied to anti-skidding layer surface, melting occurs after 1000 DEG C of -1500 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer of formation second together, using aluminium oxide and silicon carbide as the anti-scratch layer of main making material.
Description
Technical field
The present invention relates to ceramic tile manufacturing technology field, more particularly to a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and its preparation side
Method.
Background technology
So-called ceramic tile, is metal oxide and half-metal oxide with fire resisting, via grinding, mixing, compacting, glazing,
The process of sintering, the porcelain or the building of stone matter etc. or the material of decoration of a kind of acid and alkali-resistance of formation.
After ceramic tile is manufactured and is laid with, the step of people steps down on ceramic tile, and the sand of shoes bottom surface is quartz, so can be to ceramic tile
Scuffing is generated, needs to protect ceramic tile.
Therefore, it is necessary to solve the above problems to invent a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof.
Invention content
The purpose of the present invention is to provide a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof, using aluminium oxide and
Anti-scratch layer of the silicon carbide as main making material, the Mohs' hardness more than 8 increases the hardness of anti-scratch layer, to avoid sand
Stone is left a trace in ceramic tile surface, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides the following technical solutions：A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile, including bottom
Germinal layer, the bottom germinal layer top are equipped with skid resistant course, and the first viscous glutinous layer, the skid resistant course are equipped between the bottom germinal layer and skid resistant course
Top is equipped with anti-scratch layer, and the second viscous glutinous layer is equipped between the skid resistant course and anti-scratch layer.
Preferably, the bottom germinal layer is fixedly connected with skid resistant course by the first viscous glutinous layer, the skid resistant course and anti-scratch
Hinder layer to be fixedly connected by the second viscous glutinous layer.
A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof, includes the following steps：
Step 1, place election：In traffic convenience, selection is convenient, and there is the suitable workshop for firing ceramic tile, fires ceramic tile
It is divided into bottom germinal layer, anti-scratch layer and skid resistant course；
Step 2, raw material are chosen：Bottom germinal layer main material is silica flour 55wt%-60wt%, kaolin 26wt%-
31wt%, feldspar powder 4wt%-6wt%, Iron Ore Powder 0.5wt%-1wt%, matching for titanium dioxide 0.25wt%-0.35wt% compare
Example, anti-scratch layer main material is aluminium oxide 48wt%-50wt%, silicon carbide 25wt%-30wt%, silica flour 15wt%-
19wt%, carbon dust 0.5wt%-1wt%, skid resistant course main material are aluminium oxide 48wt%-50wt%, silica 25wt%-
40wt%, clay 5wt%-9wt%, fiberfill 0.5wt%-1wt%；
Step 3, manufacture：Bottom germinal layer raw material are added into water, wear into mud in the ball mill, mud sprays in the drying process
Powder, powder are pressed into type in press, then pass through drying, and sintering becomes bottom germinal layer, and skid resistant course forms slurry, then will slurry
Body is applied to bottom germinal layer surface, and melting occurs after -1500 DEG C of calcinings of 1000 DEG C of excess temperature and is sticky in that form first together viscous glutinous
Layer, anti-scratch layer also form slurry, slurry are then applied to anti-skidding layer surface, after 1000 DEG C of -1500 DEG C of calcinings of excess temperature
Melting occurs and is sticky in the viscous glutinous layer of formation second together；
Step 4 cuts out material：The ceramic tile manufactured is carried out cutting work by diamond tool, specification is cut and is square face
Brick has 152mm × 152mm, 200mm × 200mm, rectangle face brick to have 152mm × 200mm, 200mm × 300mm etc., skid resistant course
Thickness is 2mm-3mm, anti-scratch layer 2mm-3mm；
Step 5, filling：Ceramic tile is transported, is separated ceramic tile using partition board, spacing distance 1mm-2mm.
Preferably, in the step 1, skid resistant course is laid on bottom germinal layer surface, and anti-scratch layer is laid on anti-skidding layer surface.
Preferably, in the step 3, skid resistant course is 30min-40min, anti-scratch layer with bottom germinal layer calcination time
It is 40min-45min with skid resistant course calcination time.
Preferably, in the step 4, it is 4g-5g that skid resistant course, which smears quality, and it is 4g- that anti-scratch layer, which smears quality,
5g。
Preferably, in the step 5, ceramic tile needs are processed, and frame chamfering, chamfer angle are carried out to ceramic tile
It is 45 °.
The technique effect and advantage of the present invention：
1, the present invention increases the hardness of ceramic tile itself, to avoid sandstone from being stayed in ceramic tile surface by being equipped with anti-scratch layer
Bottom germinal layer raw material are added water, wear into mud in the ball mill, mud dusts in the drying process, and powder is in press by lower trace
In be pressed into type, then pass through drying, sintering becomes bottom germinal layer, and skid resistant course forms slurry, and slurry is then applied to bottom germinal layer
Melting occurs for surface is sticky in form the first viscous glutinous layer together after -1500 DEG C of calcinings of 1000 DEG C of excess temperature, anti-scratch layer also shape
At slurry, slurry is then applied to anti-skidding layer surface, melting, which occurs, after 1000 DEG C of -1500 DEG C of calcinings of excess temperature is sticky in one
It rises and forms the second viscous glutinous layer, using aluminium oxide and silicon carbide as the anti-scratch layer of main making material, the Mohs' hardness more than 8
Increase the hardness of anti-scratch layer；
2, the present invention increases the friction coefficient of ceramic tile and sole, the friction effect of fiberfill itself by being equipped with skid resistant course
Fruit is preferable, facilitates people to get on one's shoes on ceramic tile and walks about, reduces the possibility fallen down.
Description of the drawings
Fig. 1 is the overall structure diagram of the present invention；
In figure：1 bottom germinal layer, 2 skid resistant courses, 3 first viscous glutinous layers, 4 anti-scratch layers, 5 second viscous glutinous layers.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
With reference to embodiment, the present invention is further described.
Embodiment 1
A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile, including bottom germinal layer 1,1 top of the bottom germinal layer is equipped with skid resistant course 2, described
The first viscous glutinous layer 3 is equipped between bottom germinal layer 1 and skid resistant course 2,2 top of the skid resistant course is equipped with anti-scratch layer 4, the skid resistant course 2
The second viscous glutinous layer 5 is equipped between anti-scratch layer 4.
The bottom germinal layer 1 is fixedly connected with skid resistant course 2 by the first viscous glutinous layer 3, and the skid resistant course 2 is logical with anti-scratch layer 4
It crosses the second viscous glutinous layer 5 to be fixedly connected, increases bottom germinal layer 1, skid resistant course 2 and anti-scratch using the first viscous glutinous viscous glutinous layer 5 of layer 3 and second
Overall effect between layer 4, to avoid bottom germinal layer 1, skid resistant course 2 and anti-scratch layer 4 from being mutually disengaged.
Embodiment 2
A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof, includes the following steps：
Step 1, place election：In traffic convenience, selection is convenient, and there is the suitable workshop for firing ceramic tile, fires ceramic tile
It is divided into bottom germinal layer 1, anti-scratch layer 4 and skid resistant course 2, skid resistant course 2 is laid on 1 surface of bottom germinal layer, and anti-scratch layer 4 is laid on 2 table of skid resistant course
Face；
Step 2, raw material are chosen：Germinal layer 1 main material in bottom is silica flour 55wt%, kaolin 26wt%, feldspar powder
The ratio of 4wt%, Iron Ore Powder 0.5wt%, titanium dioxide 0.25wt%, 4 main material of anti-scratch layer be aluminium oxide 48wt%,
Silicon carbide 25wt%, silica flour 15wt%, carbon dust 0.5wt%, 2 main material of skid resistant course are aluminium oxide 48wt%, silica
25wt%, clay 5wt%, fiberfill 0.5wt%；
Step 3, manufacture：Germinal layer 1 raw material in bottom are added into water, wear into mud in the ball mill, mud sprays in the drying process
Powder, powder are pressed into type in press, then pass through drying, and sintering becomes bottom germinal layer 1, and skid resistant course 2 forms slurry, then will
Slurry is applied to 1 surface of bottom germinal layer, and melting occurs after 1000 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer 3 of formation first together,
Skid resistant course 2 is 30min with 1 calcination time of bottom germinal layer, and anti-scratch layer 4 also forms slurry, slurry is then applied to 2 table of skid resistant course
Melting occurs after 1000 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer 5 of formation second together for face, and anti-scratch layer 4 is forged with skid resistant course 2
The burning time is 40min；
Step 4 cuts out material：The ceramic tile manufactured is carried out cutting work by diamond tool, specification is cut and is square face
Brick has 152mm × 152mm, 200mm × 200mm, rectangle face brick to have 152mm × 200mm, 200mm × 300mm etc., skid resistant course 2
Thickness is 2mm, and anti-scratch layer 42mm, it is 4g that skid resistant course 2, which smears quality, and it is 4g that anti-scratch layer 4, which smears quality,；
Step 5, filling：Ceramic tile is transported, is separated ceramic tile using partition board, spacing distance 1mm, ceramic tile needs
It is processed, frame chamfering is carried out to ceramic tile, chamfer angle is 45 °.
Embodiment 3
A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof, includes the following steps：
Step 1, place election：In traffic convenience, selection is convenient, and there is the suitable workshop for firing ceramic tile, fires ceramic tile
It is divided into bottom germinal layer 1, anti-scratch layer 4 and skid resistant course 2, skid resistant course 2 is laid on 1 surface of bottom germinal layer, and anti-scratch layer 4 is laid on 2 table of skid resistant course
Face；
Step 2, raw material are chosen：Germinal layer 1 main material in bottom is silica flour 60wt%, kaolin 31wt%, feldspar powder
The ratio of 6wt%, Iron Ore Powder 1wt%, titanium dioxide 0.35wt%, 4 main material of anti-scratch layer are aluminium oxide 50wt%, carbon
SiClx 30wt%, silica flour 19wt%, carbon dust 1wt%, 2 main material of skid resistant course are aluminium oxide 50wt%, silica
40wt%, clay 9wt%, fiberfill 1wt%；
Step 3, manufacture：Germinal layer 1 raw material in bottom are added into water, wear into mud in the ball mill, mud sprays in the drying process
Powder, powder are pressed into type in press, then pass through drying, and sintering becomes bottom germinal layer 1, and skid resistant course 2 forms slurry, then will
Slurry is applied to 1 surface of bottom germinal layer, and melting occurs after 1500 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer 3 of formation first together,
Skid resistant course 2 is 40min with 1 calcination time of bottom germinal layer, and anti-scratch layer 4 also forms slurry, slurry is then applied to 2 table of skid resistant course
Melting occurs after 1500 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer 5 of formation second together for face, and anti-scratch layer 4 is forged with skid resistant course 2
The burning time is 45min；
Step 4 cuts out material：The ceramic tile manufactured is carried out cutting work by diamond tool, specification is cut and is square face
Brick has 152mm × 152mm, 200mm × 200mm, rectangle face brick to have 152mm × 200mm, 200mm × 300mm etc., skid resistant course 2
Thickness is 3mm, and anti-scratch layer 43mm, it is 5g that skid resistant course 2, which smears quality, and it is 5g that anti-scratch layer 4, which smears quality,；
Step 5, filling：Ceramic tile is transported, is separated ceramic tile using partition board, spacing distance 2mm, ceramic tile needs
It is processed, frame chamfering is carried out to ceramic tile, chamfer angle is 45 °.
Embodiment 4
A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof, includes the following steps：
Step 1, place election：In traffic convenience, selection is convenient, and there is the suitable workshop for firing ceramic tile, fires ceramic tile
It is divided into bottom germinal layer 1, anti-scratch layer 4 and skid resistant course 2, skid resistant course 2 is laid on 1 surface of bottom germinal layer, and anti-scratch layer 4 is laid on 2 table of skid resistant course
Face；
Step 2, raw material are chosen：Germinal layer 1 main material in bottom is silica flour 57wt%, kaolin 29wt%, feldspar powder
The ratio of 5wt%, Iron Ore Powder 0.75wt%, titanium dioxide 0.3wt%, 4 main material of anti-scratch layer be aluminium oxide 49wt%,
Silicon carbide 28wt%, silica flour 17wt%, carbon dust 0.75wt%, 2 main material of skid resistant course are aluminium oxide 49wt%, silica
33wt%, clay 7wt%, fiberfill 0.75wt%；
Step 3, manufacture：Germinal layer 1 raw material in bottom are added into water, wear into mud in the ball mill, mud sprays in the drying process
Powder, powder are pressed into type in press, then pass through drying, and sintering becomes bottom germinal layer 1, and skid resistant course 2 forms slurry, then will
Slurry is applied to 1 surface of bottom germinal layer, and melting occurs after 1250 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer 3 of formation first together,
Skid resistant course 2 is 35min with 1 calcination time of bottom germinal layer, and anti-scratch layer 4 also forms slurry, slurry is then applied to 2 table of skid resistant course
Melting occurs after 1250 DEG C of calcinings of excess temperature and is sticky in the viscous glutinous layer 5 of formation second together for face, and anti-scratch layer 4 is forged with skid resistant course 2
The burning time is 43min；
Step 4 cuts out material：The ceramic tile manufactured is carried out cutting work by diamond tool, specification is cut and is square face
Brick has 152mm × 152mm, 200mm × 200mm, rectangle face brick to have 152mm × 200mm, 200mm × 300mm etc., skid resistant course 2
Thickness is 2.5mm, and anti-scratch layer 42.5mm, it is 4.5g that skid resistant course 2, which smears quality, and it is 4.5g that anti-scratch layer 4, which smears quality,；
Step 5, filling：Ceramic tile is transported, is separated ceramic tile using partition board, spacing distance 1.5mm, ceramic tile needs
It is processed, frame chamfering is carried out to ceramic tile, chamfer angle is 45 °.
Table is obtained according to embodiment 2-4 data：
According to passing through above table：Germinal layer 1 raw material in bottom are added into water, wear into mud in the ball mill, mud is dry
It dusts during dry, powder is pressed into type in press, then passes through drying, and sintering becomes bottom germinal layer 1, and skid resistant course 2 forms slurry
Then slurry is applied to 1 surface of bottom germinal layer by body, melting, which occurs, after 1000 DEG C of -1500 DEG C of calcinings of excess temperature is sticky in together
The first viscous glutinous layer 3 is formed, anti-scratch layer 4 also forms slurry, slurry is then applied to 2 surface of skid resistant course, through excess temperature 1000
It melting occurs after DEG C of -1500 DEG C calcinings is sticky in form the second viscous glutinous layer 5 together, using aluminium oxide and silicon carbide as mainly making
Make the anti-scratch layer 4 of material, the Mohs' hardness more than 8 increases the hardness of anti-scratch layer 4, then successively to smearing phase homogenous quantities
The ceramic tile of skid resistant course 2 and anti-scratch layer 4 is detected, under different calcination temperatures, the firmness change of anti-scratch layer 4, so that it is right
Different degrees of ceramic tile is selected, and eliminates hardness lower tile product, and by the making of skid resistant course 2 increase shoes with
Static friction between ceramic tile avoids falling down.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (7)
1. a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile, including bottom germinal layer (1), it is characterised in that：It is equipped at the top of the bottom germinal layer (1)
Skid resistant course (2) is equipped with the first viscous glutinous layer (3), is equipped at the top of the skid resistant course (2) between the bottom germinal layer (1) and skid resistant course (2)
Anti-scratch layer (4) is equipped with the second viscous glutinous layer (5) between the skid resistant course (2) and anti-scratch layer (4).
2. a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile according to claim 1, it is characterised in that：The bottom germinal layer (1) with
Skid resistant course (2) is fixedly connected by the first viscous glutinous layer (3), and the skid resistant course (2) passes through the second viscous glutinous layer with anti-scratch layer (4)
(5) it is fixedly connected.
3. a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof, which is characterized in that include the following steps：
Step 1, place election：In traffic convenience, selection is convenient, and there is the suitable workshop for firing ceramic tile, fires ceramic tile and is divided into
Bottom germinal layer (1), anti-scratch layer (4) and skid resistant course (2)；
Step 2, raw material are chosen：Bottom germinal layer (1) main material is silica flour 55wt%-60wt%, kaolin 26wt%-
31wt%, feldspar powder 4wt%-6wt%, Iron Ore Powder 0.5wt%-1wt%, matching for titanium dioxide 0.25wt%-0.35wt% compare
Example, anti-scratch layer (4) main material is aluminium oxide 48wt%-50wt%, silicon carbide 25wt%-30wt%, silica flour 15wt%-
19wt%, carbon dust 0.5wt%-1wt%, skid resistant course (2) main material is aluminium oxide 48wt%-50wt%, silica
25wt%-40wt%, clay 5wt%-9wt%, fiberfill 0.5wt%-1wt%；
Step 3, manufacture：Bottom germinal layer (1) raw material are added into water, wear into mud in the ball mill, mud sprays in the drying process
Powder, powder are pressed into type in press, then pass through drying, and sintering becomes bottom germinal layer (1), and skid resistant course (2) forms slurry, so
Slurry is applied to bottom germinal layer (1) surface afterwards, occurs to melt to be sticky in be formed together after 1000 DEG C of -1500 DEG C of calcinings of excess temperature
First viscous glutinous layer (3), anti-scratch layer (4) also form slurry, slurry are then applied to skid resistant course (2) surface, through excess temperature
Melting occurs after 1000 DEG C of -1500 DEG C of calcinings and is sticky in the viscous glutinous layer (5) of formation second together；
Step 4 cuts out material：The ceramic tile manufactured is carried out cutting work by diamond tool, cutting specification and being square face brick has
152mm × 152mm, 200mm × 200mm, rectangle face brick have 152mm × 200mm, 200mm × 300mm etc., skid resistant course (2) thick
Degree is 2mm-3mm, anti-scratch layer (4) 2mm-3mm；
Step 5, filling：Ceramic tile is transported, is separated ceramic tile using partition board, spacing distance 1mm-2mm.
4. a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile according to claim 1 and preparation method thereof, it is characterised in that：It is described
In step 1, skid resistant course (2) is laid on bottom germinal layer (1) surface, and anti-scratch layer (4) is laid on skid resistant course (2) surface.
5. a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile according to claim 1 and preparation method thereof, it is characterised in that：It is described
In step 3, skid resistant course (2) is 30min-40min with bottom germinal layer (1) calcination time, and anti-scratch layer (4) is calcined with skid resistant course (2)
Time is 40min-45min.
6. a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile according to claim 1 and preparation method thereof, it is characterised in that：It is described
In step 4, it is 4g-5g that skid resistant course (2), which smears quality, and it is 4g-5g that anti-scratch layer (4), which smears quality,.
7. a kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile according to claim 1 and preparation method thereof, it is characterised in that：It is described
In step 5, ceramic tile needs are processed, and carry out frame chamfering to ceramic tile, chamfer angle is 45 °.
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| CN201810416853.1A CN108752052A (en) | 2018-05-03 | 2018-05-03 | A kind of Environment-friendlyscratch-resistant scratch-resistant inner-wall ceramic tile and preparation method thereof |
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