CN108728749A - A kind of wear-resisting steel plate and preparation method thereof - Google Patents
A kind of wear-resisting steel plate and preparation method thereof Download PDFInfo
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- B22—CASTING; POWDER METALLURGY
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- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
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- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
- C22C33/06—Making ferrous alloys by melting using master alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
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- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
- B22F2009/043—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by ball milling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
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Abstract
The invention discloses a kind of wear-resisting steel plates, include following component according to mass percent meter:Carbon is 0.12~0.2%, and manganese is 0.3~0.8%, and cobalt is 0.1~0.35%, tungsten is 0.05~0.15%, neodymium is 0.01~0.04%, and nickel is 0.15~0.35%, and silicon is less than or equal to 0.3%, sulphur is less than or equal to 0.05%, boron is 0.02~0.06%, and phosphorus is less than or equal to 0.05%, and surplus is siderochrome powder and inevitable impurity, wherein, the mass ratio of the iron in the siderochrome powder and chromium is 0.8~1.2:1.The invention also discloses the preparation methods of above-mentioned steel plate, including:(1) the above proportion ingredient is pressed, it is 50~100 μm to be milled to grain diameter, obtains alloyed powder;(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, are placed in filled with melting in argon gas, the vacuum drying oven that temperature is 2000~2200 DEG C, removal of impurities, furnace cooling obtains steel billet;(3) it is 50~100 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, compression moulding, 1~2h is pre-sintered at a temperature of being initially positioned at 800~850 DEG C, it is sintered 3~5h at a temperature of 1200~1300 DEG C, keeps the temperature 1~2h, obtains wear-resisting steel plate.Steel plate in the present invention has preferable wearability.
Description
Technical field
The present invention relates to steel plate materials technical fields, more particularly to a kind of wear-resisting steel plate and preparation method thereof.
Background technology
The appearance and development of metal-based compound plank, dramatically improve and expanded traditional single metal material performance and
Use scope.Metal-based compound plank has higher than tonicity, specific stiffness and specific strength etc. than traditional single metal material;Its
Be using a kind of metal as base material, using another different physics, chemical property material as multiple material, and using complex technique by
A kind of its composite board being combined.This for China lack nickel, chromium resource country for have great significance and
Social benefit.
With the rapid development of the pillar ofs the economy industry such as metallurgy, chemical industry, as mining machinery, coal fell and transport, petrochemical industry,
The demand multiplication to wear-resistant material composite plate such as building materials and ornaments, Marine engineering, as mining machinery track, coal use coal picker
Tool, Oil and Natural Gas Transportation Pipeline and hull, structural member etc..But existing clad steel plate is due to lacking there are technique and selection
It falls into, causes wearability, corrosion resistance, intensity etc. not ideal enough.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of wear-resisting steel plate and preparation method thereof, existing skill can be solved
The problem of art.
Invention content
The purpose of the present invention is to provide a kind of wear-resisting steel plates and preparation method thereof, to overcome deficiency in the prior art.
To achieve the above object, the present invention provides the following technical solutions:
A kind of wear-resisting steel plate includes following component according to mass percent meter:Carbon be 0.12~0.2%, manganese be 0.3~
0.8%, cobalt is 0.1~0.35%, and tungsten is 0.05~0.15%, and neodymium is 0.01~0.04%, and nickel is 0.15~0.35%, and silicon is small
In or be equal to 0.3%, sulphur be less than or equal to 0.05%, boron be 0.02~0.06%, phosphorus be less than or equal to 0.05%, surplus is iron
Chromium powder and inevitable impurity, wherein the mass ratio of iron and chromium in the siderochrome powder is 0.8~1.2:1.
Preferably, include following component according to mass percent meter:Carbon is 0.14~0.18%, and manganese is 0.4~0.65%,
Cobalt be 0.2~0.25%, tungsten be 0.08~0.12%, neodymium be 0.02~0.03%, nickel be 0.2~0.3%, silicon be 0.15~
0.25%, sulphur is 0.01~0.04%, and boron is 0.03~0.05%, and phosphorus is 0.02~0.04%, and surplus is siderochrome powder and can not
The impurity avoided.
Preferably, the mass ratio of the iron in the siderochrome powder and chromium is 1.1:1.
Preferably, the thickness specification of the steel plate is 20~60mm.
The present invention also provides a kind of preparation methods of wear-resisting steel plate, include the following steps:
(1) dispensing is carried out according to following mass percent:Carbon is 0.12~0.2%, and manganese is 0.3~0.8%, cobalt 0.1
~0.35%, tungsten is 0.05~0.15%, and neodymium is 0.01~0.04%, and nickel is 0.15~0.35%, and silicon is less than or equal to
0.3%, sulphur is less than or equal to 0.05%, and boron is 0.02~0.06%, and phosphorus is less than or equal to 0.05%, and surplus is siderochrome powder, ball
It is milled to the powder that grain diameter is 50~100 μm, obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, it is 2000~2200 DEG C to be placed in filled with argon gas, temperature
Vacuum drying oven in melting, removal of impurities, furnace cooling obtains steel billet;
(3) it is 50~100 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, and compression moulding is initially positioned at
It is pre-sintered 1~2h at a temperature of 800~850 DEG C, 3~5h is sintered at a temperature of 1200~1300 DEG C, keeps the temperature 1~2h, obtains
To wear-resisting steel plate.
Compared with the prior art, the advantages of the present invention are as follows:Light plate of the present invention is high with intensity, plasticity is good, toughness
The preferable advantage with quenching degree performance, but also there is preferable wear-resisting property.
Specific implementation mode
The present invention is described further by the following example:According to following embodiments, the present invention may be better understood.
However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used
In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of wear-resisting steel plate, includes following component according to mass percent meter:Carbon is 0.12~0.2%,
Manganese be 0.3~0.8%, cobalt be 0.1~0.35%, tungsten be 0.05~0.15%, neodymium be 0.01~0.04%, nickel be 0.15~
0.35%, silicon is less than or equal to 0.3%, and sulphur is less than or equal to 0.05%, and boron is 0.02~0.06%, and phosphorus is less than or equal to
0.05%, surplus be siderochrome powder and inevitable impurity, wherein the mass ratio of iron and chromium in the siderochrome powder be 0.8~
1.2:1。
Invention additionally discloses a kind of preparation methods of wear-resisting steel plate, include the following steps:
(1) dispensing is carried out according to following mass percent:Carbon is 0.12~0.2%, and manganese is 0.3~0.8%, cobalt 0.1
~0.35%, tungsten is 0.05~0.15%, and neodymium is 0.01~0.04%, and nickel is 0.15~0.35%, and silicon is less than or equal to
0.3%, sulphur is less than or equal to 0.05%, and boron is 0.02~0.06%, and phosphorus is less than or equal to 0.05%, and surplus is siderochrome powder, ball
It is milled to the powder that grain diameter is 50~100 μm, obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, it is 2000~2200 DEG C to be placed in filled with argon gas, temperature
Vacuum drying oven in melting, removal of impurities, furnace cooling obtains steel billet;
(3) it is 50~100 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, and compression moulding is initially positioned at
It is pre-sintered 1~2h at a temperature of 800~850 DEG C, 3~5h is sintered at a temperature of 1200~1300 DEG C, keeps the temperature 1~2h, obtains
To wear-resisting steel plate.
It is following to be illustrated with specifically embodiment, to prepare the wear-resisting steel plate in the present invention.
Embodiment 1
Include following component according to mass percent meter:Carbon is 0.12%, manganese 0.3%, cobalt 0.1%, and tungsten is
0.05%, neodymium 0.01%, nickel 0.15%, boron 0.02%, surplus is siderochrome powder.
A kind of preparation method of wear-resisting steel plate, includes the following steps:
(1) dispensing is carried out according to following mass percent:Carbon is 0.12%, manganese 0.3%, cobalt 0.1%, and tungsten is
0.05%, neodymium 0.01%, nickel 0.15%, boron 0.02%, surplus is siderochrome powder, is milled to the powder that grain diameter is 50 μm
End obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, are placed in filled with argon gas, the vacuum that temperature is 2000 DEG C
Melting in stove, removal of impurities, furnace cooling obtain steel billet;
(3) it is 50 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, and compression moulding is initially positioned at 800 DEG C
At a temperature of be pre-sintered 1h, 3h is sintered at a temperature of 1200 DEG C, 1h is kept the temperature, obtains wear-resisting steel plate.
Embodiment 2
Include following component according to mass percent meter:Carbon is 0.14%, manganese 0.4%, cobalt 0.2%, and tungsten is
0.08%, neodymium 0.02%, nickel 0.2%, silicon 0.15%, sulphur 0.01%, boron 0.03%, phosphorus 0.02%, surplus
For siderochrome powder.
A kind of preparation method of wear-resisting steel plate, includes the following steps:
(1) dispensing is carried out according to following mass percent:Carbon is 0.14%, manganese 0.4%, cobalt 0.2%, and tungsten is
0.08%, neodymium 0.02%, nickel 0.2%, silicon 0.15%, sulphur 0.01%, boron 0.03%, phosphorus 0.02%, surplus
For siderochrome powder, it is milled to the powder that grain diameter is 80 μm, obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, are placed in filled with argon gas, the vacuum that temperature is 2100 DEG C
Melting in stove, removal of impurities, furnace cooling obtain steel billet;
(3) it is 80 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, and compression moulding is initially positioned at 830 DEG C
At a temperature of be pre-sintered 1.5h, 4h is sintered at a temperature of 1250 DEG C, 1.5h is kept the temperature, obtains wear-resisting steel plate.
Embodiment 3
Include following component according to mass percent meter:Carbon is 0.16%, manganese 0.5%, cobalt 0.22%, and tungsten is
0.1%, neodymium 0.025%, nickel 0.25%, silicon 0.2%, sulphur 0.25%, boron 0.04%, phosphorus 0.03%, surplus
For siderochrome powder.
A kind of preparation method of wear-resisting steel plate, includes the following steps:
(1) dispensing is carried out according to following mass percent:Carbon is 0.16%, manganese 0.5%, cobalt 0.22%, and tungsten is
0.1%, neodymium 0.025%, nickel 0.25%, silicon 0.2%, sulphur 0.25%, boron 0.04%, phosphorus 0.03%, surplus
For siderochrome powder, it is milled to the powder that grain diameter is 80 μm, obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, are placed in filled with argon gas, the vacuum that temperature is 2100 DEG C
Melting in stove, removal of impurities, furnace cooling obtain steel billet;
(3) it is 80 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, and compression moulding is initially positioned at 830 DEG C
At a temperature of be pre-sintered 1.5h, 4h is sintered at a temperature of 1250 DEG C, 1.5h is kept the temperature, obtains wear-resisting steel plate.
Embodiment 4
Include following component according to mass percent meter:Carbon is 0.18%, manganese 0.65%, cobalt 0.25%, and tungsten is
0.12%, neodymium 0.03%, nickel 0.3%, silicon 0.25%, sulphur 0.04%, boron 0.05%, phosphorus 0.04%, surplus
For siderochrome powder.
A kind of preparation method of wear-resisting steel plate, includes the following steps:
(1) dispensing is carried out according to following mass percent:Carbon is 0.18%, manganese 0.65%, cobalt 0.25%, and tungsten is
0.12%, neodymium 0.03%, nickel 0.3%, silicon 0.25%, sulphur 0.04%, boron 0.05%, phosphorus 0.04%, surplus
For siderochrome powder, it is milled to the powder that grain diameter is 80 μm, obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, are placed in filled with argon gas, the vacuum that temperature is 2100 DEG C
Melting in stove, removal of impurities, furnace cooling obtain steel billet;
(3) it is 80 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, and compression moulding is initially positioned at 830 DEG C
At a temperature of be pre-sintered 1.5h, 4h is sintered at a temperature of 1250 DEG C, 1.5h is kept the temperature, obtains wear-resisting steel plate.
Embodiment 5
Include following component according to mass percent meter:Carbon is 0.2%, manganese 0.8%, cobalt 0.35%, and tungsten is
0.15%, neodymium 0.04%, nickel 0.35%, silicon 0.3%, sulphur 0.05%, boron 0.06%, phosphorus 0.05%, surplus
For siderochrome powder.
A kind of preparation method of wear-resisting steel plate, includes the following steps:
(1) dispensing is carried out according to following mass percent:Carbon is 0.2%, manganese 0.8%, cobalt 0.35%, and tungsten is
0.15%, neodymium 0.04%, nickel 0.35%, silicon 0.3%, sulphur 0.05%, boron 0.06%, phosphorus 0.05%, surplus
For siderochrome powder, it is milled to the powder that grain diameter is 100 μm, obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, are placed in filled with argon gas, the vacuum that temperature is 2200 DEG C
Melting in stove, removal of impurities, furnace cooling obtain steel billet;
(3) it is 100 μm that granularity is milled to after being crushed above-mentioned steel billet, is packed into mold, and compression moulding is initially positioned at 850 DEG C
At a temperature of be pre-sintered 2h, 5h is sintered at a temperature of 1300 DEG C, 2h is kept the temperature, obtains wear-resisting steel plate.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive
Property include so that including a series of elements process, method, article or equipment not only include those elements, but also
Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic
Element.
Claims (5)
1. a kind of wear-resisting steel plate, which is characterized in that according to mass percent meter include following component:Carbon is 0.12~0.2%, manganese
Be 0.3~0.8%, cobalt be 0.1~0.35%, tungsten be 0.05~0.15%, neodymium be 0.01~0.04%, nickel be 0.15~
0.35%, silicon is less than or equal to 0.3%, and sulphur is less than or equal to 0.05%, and boron is 0.02~0.06%, and phosphorus is less than or equal to
0.05%, surplus be siderochrome powder and inevitable impurity, wherein the mass ratio of iron and chromium in the siderochrome powder be 0.8~
1.2:1。
2. wear-resisting steel plate according to claim 1, which is characterized in that according to mass percent meter include following component:Carbon
Be 0.14~0.18%, manganese be 0.4~0.65%, cobalt be 0.2~0.25%, tungsten be 0.08~0.12%, neodymium be 0.02~
0.03%, nickel is 0.2~0.3%, and silicon is 0.15~0.25%, and sulphur is 0.01~0.04%, and boron is 0.03~0.05%, and phosphorus is
0.02~0.04%, surplus is siderochrome powder and inevitable impurity.
3. wear-resisting steel plate according to claim 1, which is characterized in that the mass ratio of iron and chromium in the siderochrome powder is
1.1:1。
4. wear-resisting steel plate according to claim 1, which is characterized in that the thickness specification of the steel plate is 20~60mm.
5. a kind of preparation method of wear-resisting steel plate, which is characterized in that include the following steps:
(1) dispensing is carried out according to following mass percent:Carbon be 0.12~0.2%, manganese be 0.3~0.8%, cobalt be 0.1~
0.35%, tungsten is 0.05~0.15%, and neodymium is 0.01~0.04%, and nickel is 0.15~0.35%, and silicon is less than or equal to 0.3%,
Sulphur is less than or equal to 0.05%, and boron is 0.02~0.06%, and phosphorus is less than or equal to 0.05%, and surplus is siderochrome powder, is milled to
The powder that grain grain size is 50~100 μm, obtains alloyed powder;
(2) above-mentioned alloyed powder and mixing of molten steel are uniformly packed into mold, it is 2000~2200 DEG C true to be placed in filled with argon gas, temperature
Melting in empty stove, removal of impurities, furnace cooling obtain steel billet;
(3) by above-mentioned steel billet it is broken after to be milled to granularity be 50~100 μm, be packed into mold, compression moulding, be initially positioned at 800~
It is pre-sintered 1~2h at a temperature of 850 DEG C, 3~5h is sintered at a temperature of 1200~1300 DEG C, keeps the temperature 1~2h, obtains wear-resisting
Steel plate.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113106323A (en) * | 2021-04-24 | 2021-07-13 | 江阴市富仁重工机械有限公司 | Regeneration process of steel wheel surface wear-resistant layer of vibratory roller |
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CN1156187A (en) * | 1995-11-27 | 1997-08-06 | 扬州市永进泵阀厂 | Novel anti-corrosion wear-resistance stainless steel and its producing process |
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