CN108728681A - A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy - Google Patents
A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy Download PDFInfo
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- CN108728681A CN108728681A CN201810740862.6A CN201810740862A CN108728681A CN 108728681 A CN108728681 A CN 108728681A CN 201810740862 A CN201810740862 A CN 201810740862A CN 108728681 A CN108728681 A CN 108728681A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/04—Alloys based on a platinum group metal
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/14—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of noble metals or alloys based thereon
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Abstract
The invention discloses a kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloys.According to weight percent, the ingredient of the alloy is:Sb:1.0-1.5wt.%,Ca:0.6-1.5wt.%,Mn:1.2-1.8wt.%,Ti:2.5-3.2wt.%,C:0.4-0.6wt.%,Re:3.0-3.8wt.%,Pt:2.0-2.4wt.%,Cu:32.0-36.0wt.%, surplus are palladium.The patent provides a kind of still no palldium alloys with excellent properties rose color and luster on the market, and have greatly enriched jewellery palldium alloy type in the market.
Description
Technical field
The present invention relates to technical field of alloy, specifically, being related to a kind of palldium alloy.
Background technology
Palladium appearance is similar to platinum, and be silvery white in color metallic luster, bright and lustrous, and ductility is strong.Palladium is most rare in the world
One of noble metal, it is more rare than gold very much.The only a few countries such as Russia and South Africa are produced in the world, annual total output
Less than the 5% of gold.The appearance glittering of palladium writes pure white radiance, and purity is also very suitable for skin, will not cause skin allergy.Palladium
It is abnormal tough and tensile, manufactured jewellery not only with natural day as platinum at charming brilliance, but also stand tempering for years, for a long time such as
Newly.
Palladium possesses unique makings, palladium jewellery are in jewellery market as the rare precious metals for possessing white metal gloss
It is concerned, it may be said that palladium is increasingly becoming the new lover in market.The beauty of palladium jewellery, the romantic fashion strong derived from Greeks
Makings and classic life sentiment, to make people obtain beautiful enjoyment.It is pure, beautiful, wisdom, eternal symbol.Due to
The similitude of its property and platinum, originally people are using palladium as a kind of addition element of Platinum ornaments.Until in recent years, people are just made
Bullion is made for main element of volume.
In the case where the lasting color trend of international fashion is led, more and more urban womans become chasing after for modern colour fashion
With person, it is desirable to show distinguished individual character by changeable collocation of colour.In order to meet consumer to jewellery color diversification
Demand, colored noble metal jewelry new varieties are opened up with abundant color, domestic and international market blank will have been filled up, caused industry
Very big concern.The color of palladium race noble metal jewelry only has white at present, and relatively simple, color palladium lucuriant in design is undoubtedly met
Urban woman is to the diversified demand of jewellery color.What coloured silk palladium of new generation was walked is fashion route, and not only color has differentiation excellent
Gesture, and design and be filled with more fashionable elements, it can more show individual character, embody grade.
After sparkling gold ornament with classical graceful platinum ornaments, the soft charming rosiness ornaments of tone
The new lover for gradually becoming fashion personage deduces the another brand-new world of precious metal jewelry with its idiosyncrasy and culture.With
Traditional gold is compared with platinum, and roseate noble metal not only can make the color of colored gemstone denser, and gold is also presented
Belong to exquisiteness, the exquisiteness of material.It is also in different poses and with different expressions on style, there is pointed heart, olive, oval, pyriform, Emerald.Respectively
The ornaments of kind of different style, be it is bright dazzling, women either business wear or evening dress and suspender skirt, match therewith
All show graceful makings.
Although the sale and industrialization of palladium jewellery have been achieved for very beautiful achievement, regrettably, palladium at present
There is no high quality to have roseate palldium alloy in first jewelry alloy.Rosiness palldium alloy available on the market, is to pass through table
What the method for face ion plating obtained.Due to color and color and luster that TiCN has rose gold similar, can be plated in precious metal surface
One layer of TiCN.But color and luster and rose gold some gaps due to TiCN, usually rose also thin in the top of TiCN plating last layer
Rare gold promotes roseate perception.But the coating of these rose golds is fallen off after using some months through often there is coating, is plated
The phenomenon that layer discoloration.The serious perception for affecting palldium alloy surface and obtaining rose by the method for coating.Thus, directly develop
It is a kind of solution of bottom with roseate palldium alloy.
Although China's bullion industry, especially first jewelry alloy is quickly grown, and due to starting evening, starting point is low, one
Also there is a big difference compared with world level on a little sport technique segments.Industry problems do not solve for a long time, not only affect related production
The market sales volume and usage experience of product, also it is serious limit such product international scope market occupancy volume.Exploitation is simultaneously
It has been the inevitable problem of field of jewelry that industrialization, which has roseate palldium alloy, for a long time domestic many research aircrafts
Structure and enterprise have carried out multi-faceted trial, but regrettably, the progress of any substance is not yet obtained so far.
Alloy material can be innovated by the thermodynamics and kinetics means of bottom by advanced design of material technology, and
And prodigious market value is had to the problem solution and industrialization of developing and develop rose palladium.In face of the international state being growing more intense
Interior market competition, it is necessary to which paces of accelerating restructuring, this is not only the needs of China's jewellery industry survival and development, and current
The development trend of world's related field.
Invention content
The purpose of the present invention is to overcome the deficiency in the prior art, provides a kind of corrosion-resistant rub resistance jewellery material rosiness
Palldium alloy.
To achieve the goals above, the present invention adopts the following technical scheme that：
A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy.By weight percentage, the group of alloy becomes:Sb:
1.0-1.5wt.%,Ca:0.6-1.5wt.%,Mn:1.2-1.8wt.%,Ti:2.5-3.2wt.%,C:0.4-0.6wt.%,Re:
3.0-3.8wt.%,Pt:2.0-2.4wt.%,Cu:32.0-36.0wt.%, surplus are palladium.
A kind of above-mentioned corrosion-resistant rub resistance jewellery material preparation method of rosiness palldium alloy, includes the following steps：It will
As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses graphite crucible;Low discharge is used after metal molten
Argon gas protection, avoid big air-flow from making the serious scaling loss of alloying element;10 minutes are kept the temperature at 1650 degree when melting, leans on high-frequency induction
Stove electromagnetic agitation is uniform;1 minute being kept the temperature at 1650 degree after stirring evenly and being cast come out of the stove;Palldium alloy casting uses diameter 100-
The punching block of 200mm, and cooled down by the way of water cooling.The ingot casting of gained is rolled at room temperature, every time rolls lower amount and is
20-30%;It is 820 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;It is 10- that material, which is finally rolled into thickness,
The palladium plate of 15mm;In jewellery forming process, needs to carry out intermediate annealing process, eliminate the stress in process;Wherein,
It is 800 degree to homogenize temperature, and the time is 3-4 hours.
Compared with prior art, the present invention has the advantages that：
（1）Although the sale and industrialization of rose gold have been achieved for very beautiful achievement, regrettably, jewellery at present
With not having roseate product in palldium alloy.What coloured silk palladium of new generation was walked is fashion route, and not only color has differentiation
Advantage, and design and be filled with more fashionable elements, it can more show individual character, embody grade.Existing rose palladium jewellery are logical
The method for crossing overlay coating plates and has roseate TiCN coating and one layer of thin rose gold to obtain rosiness, but should
Class product corrosion resistance is special poor, is easy discoloration, and property is unstable.Thus, directly develop rosiness palldium alloy material of new generation
It is a kind of solution of bottom.The rose palladium of present patent application protection overcomes chemical instability and appearance in itself
The phenomenon that fugitive color.By introducing suitable trace element and content, the forming core and length of cenotype can be avoided in cooling procedure
Greatly, thus final products exist in the form of stable phase.
（2）The color measuring of the alloy uses the CM-700d types in D65 standard sources and Japanese Konica Minolta company
Spectrophotometric color measurement instrument measures the lightness L of alloy surface*, red green degree a*With champac coloration b*.For traditional rose gold, L*, a*
With b*Respectively 84.0,11.0 and 16.0, and these parameters of this material are respectively 83.2,11.5 and 16.1.Thus product
The aberration unobvious of visual effect and rose gold have very excellent decorative effect.The alloy is due to having carried out material composition
Innovation with structure obtains excellent appearance perception, thus is a kind of solution of bottom.
（3）The fining agent that intermetallic compound is used as crystal grain is formed by a small amount of alloying element of addition in the alloy, with
So that making crystal grain as the nucleating center of new crystal grain in recrystallization process of the alloy after solidification or then cold working
It is refined, hardness and strength increase, and thermal stability improves.The wear-resisting property of rose palladium is carried out using vibro-grinding test method(s)
Test.Sample is put into and is pre-loaded with 2L milled ceramic particles, the UB-SL vibrations of 400 mL water and 12 mL surfactants are ground
In grinding machine, sample is taken out after vibro-grinding 2-48 h at 50 Hz, is cleaned by ultrasonic 10min, then rinsed and dried with clear water.Knot
Fruit shows sample after the experiment of 2h vibro-grindings, and there is no apparent wear phenomenons on rose palladium surface, it is seen that present patent application
The rose palladium of protection has excellent crocking resistance.In actual use, the rose palladium jewellery prepared using the alloy are made
Apparent surface scratch and recess are not will produce in 10 years.
（4）The jewelry piece of the material preparation, the corrosion rate under marine environment are 2.4 × 1-6Mm/.Thus in ocean
Under weather, which can use safely 10 years or more occurs without apparent corrosion phenomenon.In comparison, it uses at present
The rosiness jewellery of TiCN and rose gold plate are plated on palldium alloy surface, generation is changed colour and fallen off after using 6 months
Phenomenon.The rose palldium alloy of present patent application protection, due to optimizing in alloy and the ingredient and content of phase, and in rose palladium table
Face forms one layer of fine and close protective film and that the alloy is had is excellent corrosion-resistant, and antioxidation is seen, thus is extended
The usage time of the alloy.After daily wearing, apparent corrosion phenomenon or table do not occur the alloy for roseate surface
Face cut occurs, and the ability with good artificial perspiration resistance's corrosion.It is contemplated that the implementation and industrialization of the material will
Obtain excellent economic benefit and social benefit.
Specific implementation mode
Embodiment 1
A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy.By weight percentage, the group of alloy becomes: Sb:
1.0wt.%,Ca:0.6wt.%,Mn:1.2wt.%,Ti:2.5wt.%,C:0.4wt.%,Re:3.0wt.%,Pt:2.0wt.%,Cu:
32.0wt.%, surplus are palladium.A kind of preparation method of above-mentioned corrosion-resistant rub resistance jewellery material rosiness palldium alloy, including such as
Lower step：As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses graphite crucible;It is adopted after metal molten
It is protected with the argon gas of low discharge, big air-flow is avoided to make the serious scaling loss of alloying element;10 minutes are kept the temperature at 1650 degree when melting, is leaned on
Efco-Northrup furnace electromagnetic agitation is uniform;1 minute being kept the temperature at 1650 degree after stirring evenly and being cast come out of the stove;Palldium alloy casting is using straight
The punching block of diameter 100-200mm, and cooled down by the way of water cooling.The ingot casting of gained is rolled at room temperature, every time is rolled
Lower amount is 20-30%;It is 820 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;Material is finally rolled into thickness
For the palladium plate of 10-15mm;In jewellery forming process, needs to carry out intermediate annealing process, eliminate the stress in process;Its
In, homogenization temperature is 800 degree, and the time is 3-4 hours.
The phenomenon that alloy overcomes chemical instability and is easy to fade in itself.It is suitable micro by introducing
Element and content can avoid the forming core of cenotype and grow up in cooling procedure, thus final products are deposited in the form of stable phase
?.The visual effect of the product and the aberration unobvious of rose gold have very excellent decorative effect.The rose palladium has excellent
Good crocking resistance.In actual use, the rose palladium jewellery prepared using the alloy not will produce bright in using 10 years
Aobvious surface scratch and recess.Since surface tension reduces, and prevent the knot that porous oxide layer is formed in process of setting
Fruit, this will make cast(ing) surface obtain brighter surface.Due to optimizing in alloy and the ingredient and content of phase, and in rose
Rare palladium surface forms one layer of fine and close protective film and that the alloy is had is excellent corrosion-resistant, and antioxidation is seen, thus
Extend the usage time of the alloy.After daily wearing, apparent corrosion phenomenon does not occur the alloy for roseate surface
Or surface scratch occurs, and the ability with good artificial perspiration resistance's corrosion.
Embodiment 2
A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy.By weight percentage, the group of alloy becomes: Sb:
1.5wt.%,Ca:1.5wt.%,Mn:1.8wt.%,Ti:3.2wt.%,C:0.6wt.%,Re:3.8wt.%,Pt:2.4wt.%,Cu:
36.0wt.%, surplus are palladium.A kind of preparation method of above-mentioned corrosion-resistant rub resistance jewellery material rosiness palldium alloy, including such as
Lower step：As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses graphite crucible;It is adopted after metal molten
It is protected with the argon gas of low discharge, big air-flow is avoided to make the serious scaling loss of alloying element;10 minutes are kept the temperature at 1650 degree when melting, is leaned on
Efco-Northrup furnace electromagnetic agitation is uniform;1 minute being kept the temperature at 1650 degree after stirring evenly and being cast come out of the stove;Palldium alloy casting is using straight
The punching block of diameter 100-200mm, and cooled down by the way of water cooling.The ingot casting of gained is rolled at room temperature, every time is rolled
Lower amount is 20-30%;It is 820 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;Material is finally rolled into thickness
For the palladium plate of 10-15mm;In jewellery forming process, needs to carry out intermediate annealing process, eliminate the stress in process;Its
In, homogenization temperature is 800 degree, and the time is 3-4 hours.
The phenomenon that alloy overcomes chemical instability and is easy to fade in itself.It is suitable micro by introducing
Element and content can avoid the forming core of cenotype and grow up in cooling procedure, thus final products are deposited in the form of stable phase
?.The visual effect of the product and the aberration unobvious of rose gold have very excellent decorative effect.The rose palladium has excellent
Good crocking resistance.In actual use, the rose palladium jewellery prepared using the alloy not will produce bright in using 10 years
Aobvious surface scratch and recess.Since surface tension reduces, and prevent the knot that porous oxide layer is formed in process of setting
Fruit, this will make cast(ing) surface obtain brighter surface.Due to optimizing in alloy and the ingredient and content of phase, and in rose
Rare palladium surface forms one layer of fine and close protective film and that the alloy is had is excellent corrosion-resistant, and antioxidation is seen, thus
Extend the usage time of the alloy.After daily wearing, apparent corrosion phenomenon does not occur the alloy for roseate surface
Or surface scratch occurs, and the ability with good artificial perspiration resistance's corrosion.
Embodiment 3
A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy.By weight percentage, the group of alloy becomes: Sb:
1.2wt.%,Ca:0.8wt.%,Mn:1.5wt.%,Ti:2.8wt.%,C:0.5wt.%,Re:3.2wt.%,Pt:2.2wt.%,Cu:
35.0wt.%, surplus are palladium.A kind of preparation method of above-mentioned corrosion-resistant rub resistance jewellery material rosiness palldium alloy, including such as
Lower step：As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses graphite crucible;It is adopted after metal molten
It is protected with the argon gas of low discharge, big air-flow is avoided to make the serious scaling loss of alloying element;10 minutes are kept the temperature at 1650 degree when melting, is leaned on
Efco-Northrup furnace electromagnetic agitation is uniform;1 minute being kept the temperature at 1650 degree after stirring evenly and being cast come out of the stove;Palldium alloy casting is using straight
The punching block of diameter 100-200mm, and cooled down by the way of water cooling.The ingot casting of gained is rolled at room temperature, every time is rolled
Lower amount is 20-30%;It is 820 degree per intermediate anneal temperature after rolling twice, keeps the temperature 0.5 hour;Material is finally rolled into thickness
For the palladium plate of 10-15mm;In jewellery forming process, needs to carry out intermediate annealing process, eliminate the stress in process;Its
In, homogenization temperature is 800 degree, and the time is 3-4 hours.
The phenomenon that alloy overcomes chemical instability and is easy to fade in itself.It is suitable micro by introducing
Element and content can avoid the forming core of cenotype and grow up in cooling procedure, thus final products are deposited in the form of stable phase
?.The visual effect of the product and the aberration unobvious of rose gold have very excellent decorative effect.The rose palladium has excellent
Good crocking resistance.In actual use, the rose palladium jewellery prepared using the alloy not will produce bright in using 10 years
Aobvious surface scratch and recess.Since surface tension reduces, and prevent the knot that porous oxide layer is formed in process of setting
Fruit, this will make cast(ing) surface obtain brighter surface.Due to optimizing in alloy and the ingredient and content of phase, and in rose
Rare palladium surface forms one layer of fine and close protective film and that the alloy is had is excellent corrosion-resistant, and antioxidation is seen, thus
Extend the usage time of the alloy.After daily wearing, apparent corrosion phenomenon does not occur the alloy for roseate surface
Or surface scratch occurs, and the ability with good artificial perspiration resistance's corrosion.
Claims (3)
1. a kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy；According to weight percent, the ingredient of the alloy is:
Sb:1.0-1.5wt.%,Ca:0.6-1.5wt.%,Mn:1.2-1.8wt.%,Ti:2.5-3.2wt.%,C:0.4-0.6wt.%,Re:
3.0-3.8wt.%,Pt:2.0-2.4wt.%,Cu:32.0-36.0wt.%, surplus are palladium.
2. a kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy described in claim 1, it is characterised in that including as follows
Smelting step：As above the raw material matched is added in the electric induction furnace of argon gas protection, and uses graphite crucible;After metal molten
It is protected using the argon gas of low discharge, big air-flow is avoided to make the serious scaling loss of alloying element;10 minutes are kept the temperature at 1650 degree when melting,
It is uniform by Efco-Northrup furnace electromagnetic agitation;1 minute being kept the temperature at 1650 degree after stirring evenly and being cast come out of the stove;Palldium alloy casting uses
The punching block of diameter 100-200mm, and cooled down by the way of water cooling.
3. according to a kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy described in claim 1, it is characterised in that comprising such as
It is lower to use step：The ingot casting of gained is rolled at room temperature, it is 20-30% that every time, which rolls lower amount,;Per intermediate after rolling twice
Annealing temperature is 820 degree, keeps the temperature 0.5 hour;Material is finally rolled into the palladium plate that thickness is 10-15mm;It was molded in jewellery
Cheng Zhong needs to carry out intermediate annealing process, eliminates the stress in process;Wherein, homogenization temperature is 800 degree, and the time is
3-4 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810740862.6A CN108728681A (en) | 2018-07-08 | 2018-07-08 | A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810740862.6A CN108728681A (en) | 2018-07-08 | 2018-07-08 | A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy |
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| Publication Number | Publication Date |
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| CN108728681A true CN108728681A (en) | 2018-11-02 |
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ID=63925911
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810740862.6A Withdrawn CN108728681A (en) | 2018-07-08 | 2018-07-08 | A kind of corrosion-resistant rub resistance jewellery material rosiness palldium alloy |
Country Status (1)
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| CN (1) | CN108728681A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112063879A (en) * | 2020-08-28 | 2020-12-11 | 昆明贵研新材料科技有限公司 | High-conductivity high-elasticity palladium-based alloy, heat treatment process and application |
-
2018
- 2018-07-08 CN CN201810740862.6A patent/CN108728681A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112063879A (en) * | 2020-08-28 | 2020-12-11 | 昆明贵研新材料科技有限公司 | High-conductivity high-elasticity palladium-based alloy, heat treatment process and application |
| CN112063879B (en) * | 2020-08-28 | 2022-02-18 | 昆明贵研新材料科技有限公司 | High-conductivity high-elasticity palladium-based alloy, heat treatment process and application |
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Application publication date: 20181102 |