CN108727876A - A kind of preparation method for the filler promoting fishing lines intensity and rotproofness - Google Patents

A kind of preparation method for the filler promoting fishing lines intensity and rotproofness Download PDF

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Publication number
CN108727876A
CN108727876A CN201810483951.7A CN201810483951A CN108727876A CN 108727876 A CN108727876 A CN 108727876A CN 201810483951 A CN201810483951 A CN 201810483951A CN 108727876 A CN108727876 A CN 108727876A
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parts
rotproofness
montmorillonite
fishing lines
preparation
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CN108727876B (en
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胡文龙
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CHAOHU XIANGYU FISHING GEAR Co Ltd
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CHAOHU XIANGYU FISHING GEAR Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40Compounds of aluminium
    • C09C1/405Compounds of aluminium containing combined silica, e.g. mica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06Treatment with inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08Treatment with low-molecular-weight non-polymer organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10Treatment with macromolecular organic compounds
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

The invention discloses a kind of preparation methods of the filler of promotion fishing lines intensity and rotproofness, include the following steps:(1)Cleaning treatment,(2)High-temperature process,(3)Modification,(4)It is dried.The present invention provides a kind of preparation methods of filler, and integrated artistic is simple, and reasonable standard is arranged in process, the characteristics such as corrosion resistant, heatproof, the intensity of fishing lines can be effectively promoted conducive to duplication and batch operation, filler stay in grade obtained, extend its service life, great application value.

Description

A kind of preparation method for the filler promoting fishing lines intensity and rotproofness
Technical field
The invention belongs to fishing lines processing and manufacturing technologies, and in particular to a kind of fishing lines intensity and rotproofness of being promoted The preparation method of filler.
Background technology
Fishing lines is basic material common in fishing gear field, is initially mostly made of linen-cotton material, as people make it With the continuous promotion and the continuous enhancing of production technology of characteristic, existing fishing lines is mostly Plastic artificial synthetic fiber, The accounting of middle nylon fishing net line is larger.Although the usage amount of nylon fishing net line is larger, production and processing is more mature, with people Continuous promotion for product demand so that the performance requirement produced and processed to it constantly enhances.
For qualities such as the intensity, corrosion resistant, the heatproofs that improve nylon fishing net line, now many techniques by add filler ingredient come Improve, common filler has kaolin, attapulgite etc., although playing certain improvement, because filler grain is easy to Reunite, dispersibility is bad, with the compatibility of high molecular material matrix it is bad, itself have a single function the problems such as, limit filler Using effect.
Invention content
The purpose of the present invention is for existing problem, provide the filler of a kind of promotion fishing lines intensity and rotproofness Preparation method.
The present invention is achieved by the following technical solutions:
A kind of preparation method for the filler promoting fishing lines intensity and rotproofness, includes the following steps:
(1)Cleaning treatment:
5 ~ 7min of immersion treatment in tartaric acid solution first is put into montmorillonite, then takes out to be put into sodium hydroxide solution and soak Bubble 7 ~ 10min of processing, finally taking-up are spare after being rinsed one time with deionized water;
(2)High-temperature process:
By step(1)Montmorillonite after cleaning, which is put into high-temperature calcination stove, carries out calcination processing, is taken out after 1 ~ 2h spare;
(3)Modification:
A. by step(2)Montmorillonite that treated, which is put into ultraviolet irradiation instrument, carries out radiation treatment, is taken out after 25 ~ 30min It is spare;
B. will operation a treated that montmorillonite is immersed in modification solution A, ultrasonic vibration handle take out after 1 ~ 2h it is spare; The modification solution A by following parts by weight material composition:20 ~ 25 parts of polyoxylethylene abietates, 7 ~ 12 parts of metatitanic acids Ester coupling agent, 4 ~ 8 parts of magnesium thiosulfates, 300 ~ 350 parts of deionized waters;
C. will operation b treated that montmorillonite is immersed in modification solution B, ultrasonic vibration handle take out after 2 ~ 3h it is spare; The modification solution B by following parts by weight material composition:4 ~ 6 parts of nano-titanium dioxides, 3 ~ 5 parts of detergent alkylate sulphurs Sour sodium, 2 ~ 4 parts of calcium stearates, 0.5 ~ 1 part of disodium ethylene diamine tetraacetate, 90 ~ 100 parts of deionized waters;
(4)It is dried:
By step(3)Montmorillonite that treated, which is put into drying box, is dried processing, is taken out after 1.5 ~ 2.5h.
Further, step(1)Described in tartaric acid solution mesotartaric acid mass fraction be 6 ~ 9%;The hydrogen-oxygen The mass fraction for changing sodium hydroxide in sodium solution is 8 ~ 10%.
Further, step(2)Described in calcination processing when keep high-temperature calcination stove in temperature be 800 ~ 900 DEG C.
Further, step(3)Operate a described in radiation treatment when control ultraviolet irradiation instrument in power be 900 ~ 1000W, the wavelength for controlling ultraviolet light are 260 ~ 320nm.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in b is 180 ~ 200kHz.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in c is 300 ~ 400kHz.
Further, step(3)The grain diameter for operating the nano-titanium dioxide described in c is 20 ~ 70nm.
Further, step(4)Described in drying process when control drying box in temperature be 83 ~ 88 DEG C.
The present invention provides a kind of preparation methods of filler, effectively improve the use characteristic of filler, enhance fishing net The use quality of line is modified and is handled using montmorillonite as matrix composition, the cleaning treatment and high temperature first carried out Calcination processing effectively improves the specific surface area and adsorption capacity of montmorillonite, lays a good foundation for subsequent processing, with laggard Gone modification, radiation treatment first during which carried out to montmorillonite with ultraviolet light, improve montmorillonite surface group content and Structure enhances its respond, then carries out immersion modification, modification with the modification solution A of formulated Two kinds of ingredients of polyoxylethylene abietate and magnesium thiosulfate in solution A can penetrate into infiltration to the interlayer of montmorillonite, weaken Its lamella mutual hydrogen bond and polarity effect are subsequent place to which create the effect of swollen, expanding interfloor distance Reason is laid a good foundation, and the titanate coupling agent of addition can effectively improve the surface characteristic of montmorillonite, improve itself and height Compatibility between molecular chaperones and remaining ingredient has then been carried out impregnating modification again with modification solution B, at modification In reason solution B the nano-titanium dioxide ingredient that adds can the intercalated grafted interlayer to montmorillonite, improve montmorillonite particle Corrosion resistant, resistance to mild granule stability, and the specific surface area and adsorption capacity of montmorillonite are enhanced, improve what filling used Effect.
The present invention has the following advantages compared with prior art:
The present invention provides a kind of preparation methods of filler, and integrated artistic is simple, and reasonable standard is arranged in process, are conducive to replicate And batch operation, filler stay in grade obtained can effectively promote the characteristics such as corrosion resistant, heatproof, the intensity of fishing lines, extend Its service life, great application value.
Specific implementation mode
Embodiment 1
A kind of preparation method for the filler promoting fishing lines intensity and rotproofness, includes the following steps:
(1)Cleaning treatment:
Immersion treatment 5min in tartaric acid solution first is put into montmorillonite, then takes out to be put into sodium hydroxide solution and impregnate 7min is handled, finally taking-up is spare after being rinsed one time with deionized water;
(2)High-temperature process:
By step(1)Montmorillonite after cleaning, which is put into high-temperature calcination stove, carries out calcination processing, is taken out after 1h spare;
(3)Modification:
A. by step(2)Montmorillonite that treated, which is put into ultraviolet irradiation instrument, carries out radiation treatment, is taken out after 25min standby With;
B. will operation a treated that montmorillonite is immersed in modification solution A, taken out after ultrasonic vibration processing 1h spare;Institute The modification solution A stated by following parts by weight material composition:20 parts of polyoxylethylene abietates, 7 parts of titanate coupling agents, 4 parts of magnesium thiosulfates, 300 parts of deionized waters;
C. will operation b treated that montmorillonite is immersed in modification solution B, taken out after ultrasonic vibration processing 2h spare;Institute The modification solution B stated by following parts by weight material composition:4 parts of nano-titanium dioxides, 3 parts of neopelexes, 2 Part calcium stearate, 0.5 part of disodium ethylene diamine tetraacetate, 90 parts of deionized waters;
(4)It is dried:
By step(3)Montmorillonite that treated, which is put into drying box, is dried processing, is taken out after 1.5h.
Further, step(1)Described in tartaric acid solution mesotartaric acid mass fraction be 6%;The hydroxide The mass fraction of sodium hydroxide is 8% in sodium solution.
Further, step(2)Described in calcination processing when keep high-temperature calcination stove in temperature be 800 DEG C.
Further, step(3)Operation a described in radiation treatment when control ultraviolet irradiation instrument in power be 900W, the wavelength for controlling ultraviolet light are 260 ~ 320nm.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in b is 180kHz.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in c is 300kHz.
Further, step(3)The grain diameter for operating the nano-titanium dioxide described in c is 20 ~ 70nm.
Further, step(4)Described in drying process when control drying box in temperature be 83 DEG C.
Embodiment 2
A kind of preparation method for the filler promoting fishing lines intensity and rotproofness, includes the following steps:
(1)Cleaning treatment:
Immersion treatment 6min in tartaric acid solution first is put into montmorillonite, then takes out to be put into sodium hydroxide solution and impregnate 9min is handled, finally taking-up is spare after being rinsed one time with deionized water;
(2)High-temperature process:
By step(1)Montmorillonite after cleaning, which is put into high-temperature calcination stove, carries out calcination processing, is taken out after 1.5h spare;
(3)Modification:
A. by step(2)Montmorillonite that treated, which is put into ultraviolet irradiation instrument, carries out radiation treatment, is taken out after 28min standby With;
B. will operation a treated that montmorillonite is immersed in modification solution A, taken out after ultrasonic vibration processing 1.6h spare; The modification solution A by following parts by weight material composition:23 parts of polyoxylethylene abietates, 10 parts of titanate esters couplings Agent, 6 parts of magnesium thiosulfates, 330 parts of deionized waters;
C. will operation b treated that montmorillonite is immersed in modification solution B, taken out after ultrasonic vibration processing 2.5h spare; The modification solution B by following parts by weight material composition:5 parts of nano-titanium dioxides, 4 parts of dodecyl benzene sulfonic acid Sodium, 3 parts of calcium stearates, 0.8 part of disodium ethylene diamine tetraacetate, 95 parts of deionized waters;
(4)It is dried:
By step(3)Montmorillonite that treated, which is put into drying box, is dried processing, is taken out after 2h.
Further, step(1)Described in tartaric acid solution mesotartaric acid mass fraction be 8%;The hydroxide The mass fraction of sodium hydroxide is 9% in sodium solution.
Further, step(2)Described in calcination processing when keep high-temperature calcination stove in temperature be 860 DEG C.
Further, step(3)Operation a described in radiation treatment when control ultraviolet irradiation instrument in power be 970W, the wavelength for controlling ultraviolet light are 260 ~ 320nm.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in b is 190kHz.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in c is 360kHz.
Further, step(3)The grain diameter for operating the nano-titanium dioxide described in c is 20 ~ 70nm.
Further, step(4)Described in drying process when control drying box in temperature be 85 DEG C.
Embodiment 3
A kind of preparation method for the filler promoting fishing lines intensity and rotproofness, includes the following steps:
(1)Cleaning treatment:
Immersion treatment 7min in tartaric acid solution first is put into montmorillonite, then takes out to be put into sodium hydroxide solution and impregnate 10min is handled, finally taking-up is spare after being rinsed one time with deionized water;
(2)High-temperature process:
By step(1)Montmorillonite after cleaning, which is put into high-temperature calcination stove, carries out calcination processing, is taken out after 2h spare;
(3)Modification:
A. by step(2)Montmorillonite that treated, which is put into ultraviolet irradiation instrument, carries out radiation treatment, is taken out after 30min standby With;
B. will operation a treated that montmorillonite is immersed in modification solution A, taken out after ultrasonic vibration processing 2h spare;Institute The modification solution A stated by following parts by weight material composition:25 parts of polyoxylethylene abietates, 12 parts of titanate esters couplings Agent, 8 parts of magnesium thiosulfates, 350 parts of deionized waters;
C. will operation b treated that montmorillonite is immersed in modification solution B, taken out after ultrasonic vibration processing 3h spare;Institute The modification solution B stated by following parts by weight material composition:6 parts of nano-titanium dioxides, 5 parts of neopelexes, 4 Part calcium stearate, 1 part of disodium ethylene diamine tetraacetate, 100 parts of deionized waters;
(4)It is dried:
By step(3)Montmorillonite that treated, which is put into drying box, is dried processing, is taken out after 2.5h.
Further, step(1)Described in tartaric acid solution mesotartaric acid mass fraction be 9%;The hydroxide The mass fraction of sodium hydroxide is 10% in sodium solution.
Further, step(2)Described in calcination processing when keep high-temperature calcination stove in temperature be 900 DEG C.
Further, step(3)Operation a described in radiation treatment when control ultraviolet irradiation instrument in power be 1000W, the wavelength for controlling ultraviolet light are 260 ~ 320nm.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in b is 200kHz.
Further, step(3)The supersonic frequency for operating the ultrasonic vibration processing described in c is 400kHz.
Further, step(3)The grain diameter for operating the nano-titanium dioxide described in c is 20 ~ 70nm.
Further, step(4)Described in drying process when control drying box in temperature be 88 DEG C.
Comparative example 1
This comparative example 1 compared with Example 2, eliminates step(3)Operation b processing in modification, side in addition to this Method step all same.
Comparative example 2
This comparative example 2 compared with Example 2, eliminates step(3)Operation c processing in modification, side in addition to this Method step all same.
Comparative example 3
This comparative example 3 compared with Example 2, eliminates step(3)The whole operation of modification, method step in addition to this Rapid all same.
Control group
Existing commercially available montmorillonite filler.
In order to compare effect of the present invention, by above-described embodiment 2, comparative example 1, comparative example 2, comparative example 3, Control group corresponds to filler ingredient obtained in the manufacture of nylon fishing net line, the weight percent of addition to be 7%, after the completion To nylon fishing net line made from each group(Filament diameter specification is 0.20 ± 0.01mm)It is tested for the property, specific correction data As shown in table 1 below:
Table 1
Note:Fracture strength described in upper table 1 is measured by Britain INSTRON-4466 type strength testers, and when test controls Temperature condition is 20 ± 2 DEG C, and relative humidity control is 65 ± 5%, and the speed for controlling stretching is 330mm/min, and the length of monofilament is 600mm;The knot strength retention is that the nylon fishing net line after each group alignment processing is put in temperature as 35 DEG C, relative humidity After exposure under 85% natural conditions 12 months, tests it and tie the conservation rate of strength, to react the anti-aging characteristic of its corrosion resistant.
Filler produced by the present invention can effectively promote the intensity of fishing lines, the anti-aging product of corrosion resistant it can be seen from upper table 1 Matter, hence it is evident that improve the use characteristic of fishing lines, there is good application value.

Claims (8)

1. a kind of preparation method for the filler promoting fishing lines intensity and rotproofness, which is characterized in that include the following steps:
(1)Cleaning treatment:
5 ~ 7min of immersion treatment in tartaric acid solution first is put into montmorillonite, then takes out to be put into sodium hydroxide solution and soak Bubble 7 ~ 10min of processing, finally taking-up are spare after being rinsed one time with deionized water;
(2)High-temperature process:
By step(1)Montmorillonite after cleaning, which is put into high-temperature calcination stove, carries out calcination processing, is taken out after 1 ~ 2h spare;
(3)Modification:
A. by step(2)Montmorillonite that treated, which is put into ultraviolet irradiation instrument, carries out radiation treatment, is taken out after 25 ~ 30min It is spare;
B. will operation a treated that montmorillonite is immersed in modification solution A, ultrasonic vibration handle take out after 1 ~ 2h it is spare; The modification solution A by following parts by weight material composition:20 ~ 25 parts of polyoxylethylene abietates, 7 ~ 12 parts of metatitanic acids Ester coupling agent, 4 ~ 8 parts of magnesium thiosulfates, 300 ~ 350 parts of deionized waters;
C. will operation b treated that montmorillonite is immersed in modification solution B, ultrasonic vibration handle take out after 2 ~ 3h it is spare; The modification solution B by following parts by weight material composition:4 ~ 6 parts of nano-titanium dioxides, 3 ~ 5 parts of detergent alkylate sulphurs Sour sodium, 2 ~ 4 parts of calcium stearates, 0.5 ~ 1 part of disodium ethylene diamine tetraacetate, 90 ~ 100 parts of deionized waters;
(4)It is dried:
By step(3)Montmorillonite that treated, which is put into drying box, is dried processing, is taken out after 1.5 ~ 2.5h.
2. a kind of preparation method of filler promoting fishing lines intensity and rotproofness according to claim 1, feature exist In step(1)Described in tartaric acid solution mesotartaric acid mass fraction be 6 ~ 9%;Hydrogen-oxygen in the sodium hydroxide solution The mass fraction for changing sodium is 8 ~ 10%.
3. a kind of preparation method of filler promoting fishing lines intensity and rotproofness according to claim 1, feature exist In step(2)Described in calcination processing when keep high-temperature calcination stove in temperature be 800 ~ 900 DEG C.
4. a kind of preparation method of filler promoting fishing lines intensity and rotproofness according to claim 1, feature exist In step(3)Power when operating the radiation treatment described in a in control ultraviolet irradiation instrument is 900 ~ 1000W, and control is ultraviolet The wavelength of line is 260 ~ 320nm.
5. a kind of preparation method of filler promoting fishing lines intensity and rotproofness according to claim 1, feature exist In step(3)The supersonic frequency for operating the ultrasonic vibration processing described in b is 180 ~ 200kHz.
6. a kind of preparation method of filler promoting fishing lines intensity and rotproofness according to claim 1, feature exist In step(3)The supersonic frequency for operating the ultrasonic vibration processing described in c is 300 ~ 400kHz.
7. a kind of preparation method of filler promoting fishing lines intensity and rotproofness according to claim 1, feature exist In step(3)The grain diameter for operating the nano-titanium dioxide described in c is 20 ~ 70nm.
8. a kind of preparation method of filler promoting fishing lines intensity and rotproofness according to claim 1, feature exist In step(4)Described in drying process when control drying box in temperature be 83 ~ 88 DEG C.
CN201810483951.7A 2018-05-19 2018-05-19 Preparation method of filler for improving strength and corrosion resistance of fishing net thread Active CN108727876B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112048100A (en) * 2020-09-09 2020-12-08 巢湖市方太渔具有限责任公司 Preparation method of fishing net thread quality enhancer
CN112064170A (en) * 2020-09-04 2020-12-11 黎扬斌 Antibacterial warm-keeping fabric and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN102485805A (en) * 2010-12-02 2012-06-06 广东高科达科技实业有限公司 Method for preparing modified nano montmorillonite
RU2626414C1 (en) * 2016-10-26 2017-07-27 Федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный технический университет" (ВолгГТУ) Method for obtaining of organomodified montmorillonite with polyfluoroalkyl groups
CN107287680A (en) * 2017-07-17 2017-10-24 巢湖市渔郎渔具有限公司 A kind of fishing net with good tensile strength

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102485805A (en) * 2010-12-02 2012-06-06 广东高科达科技实业有限公司 Method for preparing modified nano montmorillonite
RU2626414C1 (en) * 2016-10-26 2017-07-27 Федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный технический университет" (ВолгГТУ) Method for obtaining of organomodified montmorillonite with polyfluoroalkyl groups
CN107287680A (en) * 2017-07-17 2017-10-24 巢湖市渔郎渔具有限公司 A kind of fishing net with good tensile strength

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112064170A (en) * 2020-09-04 2020-12-11 黎扬斌 Antibacterial warm-keeping fabric and preparation method thereof
CN112048100A (en) * 2020-09-09 2020-12-08 巢湖市方太渔具有限责任公司 Preparation method of fishing net thread quality enhancer

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