CN108727006A - A kind of composite ceramic material and preparation method thereof - Google Patents
A kind of composite ceramic material and preparation method thereof Download PDFInfo
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- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
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- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
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Abstract
The invention belongs to technical field of ceramic material, and in particular to a kind of composite ceramic material and preparation method thereof.The present invention uses the body portion of albite, red clay, quartz sand as composite ceramic material, pass through the organic and inorganic materials such as water-bath combination polyethylene, polypropylene, polytetrafluoroethylene (PTFE), paraffin, calgon, thallic oxide, the especially addition of polytetrafluoroethylene (PTFE), red clay, paraffin and thallic oxide so that the composite ceramic material that the present invention is prepared has stronger bending strength, higher hardness and preferable fire-resistance property and lower dielectric constant.
Description
Technical field
The invention belongs to technical field of ceramic material, and in particular to a kind of based composite ceramic material and preparation method thereof.
Background technology
Ceramics are made as primary raw material by crushing to be kneaded, be molded and calcine using natural clay and various natural minerals
Material various products.People were referred to as the article fired in special kiln high temperature being fabricated to clay and made pottery in the past
Porcelain, ceramics are the general names of pottery and porcelain.The traditional concept of ceramics refers to all using Inorganic nonmetal minerals such as clays as raw material
Artificial industrial products.It includes the mixture by clay or containing clay through being kneaded, forming, calcining and manufactured various systems
Product.By most coarse earthenware its range is belonged to most fine fine pottery and porcelain.Ceramics by purposes can be divided into domestic ceramics,
The art pottery, industrial ceramics etc., wherein industrial ceramics is divided into as construction sanitary ceramic, chemical stoneware, electroceramics, special cermacis etc.,
Wherein special cermacis product is mainly used for various modern industries and advanced science technology, for example, space flight and aviation, nuclear industry, new energy
The fields such as source, defence and military, and all it is badly in need of a large amount of new material in each field, special cermacis is due to excellent heat resistance
Energy, dielectric properties, wear-resisting property, heat-proof quality, piezoelectric property, light transmission receive the extensive attention of various countries.
As ultrahigh temperature ceramic composite mainly includes refractory boride, carbide and the nitrogen of some transiting metal group metals
Compound, such as ZrB2, ZrC, HfN etc., their fusing point is at 3000 DEG C or more.In these superhigh temperature ceramics, ZrB2And HfB2Base
Ultrahigh temperature ceramic composite has higher thermal conductivity, moderate coefficient of thermal expansion and good anti-oxidant ablation property, can
It is non-ablative for a long time to be realized in 2000 DEG C or more of oxidation environment, it is that a kind of very promising non-ablative type superhigh temperature is anti-
Hot material can be applied in manned vehicle, the nose cone of endoatmosphere hypersonic aircraft, leading edge and engine combustion room
Crucial hot-end component will have tremendous contribution to promoting high-speed aircraft aeroperformance, control ability, flight efficiency etc..
As the ceramic composite of high-temperature structural material, it is mainly used for aerospace, the departments such as military project.In addition, machinery,
The fields such as chemical industry, electronic technology also widely used various ceramic composites.Composite ceramic material has high alumina matter porcelain, magnesite matter
The multiple types such as porcelain, zinc-magnesium stone matter porcelain, zircon porcelain, lithium ceramic, ferrite, cermet.Composite ceramics usually have difference
The good comprehensive performance that material is mutually learnt from other's strong points to offset one's weaknesses.Composite ceramic material has the characteristics of two or more material concurrently, can change
It is apt to the performance of single ceramic material, such as improves intensity, increases toughness and improve dielectric properties.Ceramics have high temperature resistant, high-strength
Degree and rigidity, relative weight be lighter, the excellent properties such as anticorrosive, and its deadly defect is to enbrittle, when being in stress state
It cracks, or even fracture leads to material failure, and uses organic polymer material and ceramic matrix compound, be then to improve ceramics
One effective method of toughness.Organic fiber can prevent the diffusion of crackle, to obtain the fiber-reinforced composite of excellent in toughness
Ceramic material.Composite ceramic material has excellent high temperature resistance, is mainly used as high temperature resistant agent high abrasion goods, and highest uses
Temperature depends primarily on its structure feature, and due to the excellent properties of composite ceramic material, application range is also increasingly wider, increasingly
Liked by people.
Invention content
The object of the present invention is to provide a kind of composite ceramic materials and preparation method thereof, by being prepared in composite ceramic material
Polytetrafluoroethylene (PTFE), red clay, paraffin and thallic oxide are added in the process so that composite ceramic material prepared by the present invention has
Stronger bending strength, higher hardness and preferable fire-resistance property and smaller dielectric constant.
The technical scheme is that:
A kind of composite ceramic material, is made of following components:Albite, quartz sand, polyethylene, polypropylene, gathers red clay
Tetrafluoroethene, plasticizer, paraffin, sodium alginate, calgon, diphenylamines, thallic oxide.
Preferably, above-mentioned each component weight ratio is:Albite 25-30 parts by weight, red clay 20-25 parts by weight, quartz
Sand 25-30 parts by weight, polyethylene 2-5 parts by weight, polypropylene 2-5 parts by weight, polytetrafluoroethylene (PTFE) 2-5 parts by weight, plasticizer 0.1-
0.2 parts by weight, paraffin 1-3 parts by weight, sodium alginate 1-2 parts by weight, calgon 0.2-0.5 parts by weight, diphenylamines 0.1-
0.3 parts by weight, thallic oxide 1-3 parts by weight.
The preparation method of above-mentioned composite ceramic material, includes the following steps:
(1) it is mixed after albite, red clay and quartz sand being distinguished ball milling;
(2) by polyethylene, polypropylene, polytetrafluoroethylene (PTFE), plasticizer, paraffin, sodium alginate, calgon, diphenylamines,
Paste is stirred into after thallic oxide and water mixing;
(3) material for obtaining step (1) and step (2), which mixes, carries out ball milling;
(4) material after ball milling is subjected to water-bath;
(5) by the material injection mold after water-bath, curing agent is added and carries out curing molding;
(6) composite ceramic material is prepared in material after molding sintering.
Preferably, the weight ratio of each material is in step (2):Albite 25-30 parts by weight, red clay 20-25 weight
Part, quartz sand 25-30 parts by weight, polyethylene 2-5 parts by weight, polypropylene 2-5 parts by weight, polytetrafluoroethylene (PTFE) 2-5 parts by weight, plasticising
Agent 0.1-0.2 parts by weight, paraffin 1-3 parts by weight, sodium alginate 1-2 parts by weight, calgon 0.2-0.5 parts by weight, hexichol
Amine 0.1-0.3 parts by weight, thallic oxide 1-3 parts by weight.
Preferably, in step (3) ball milling condition be for:1200-1500rpm high speed ball millings 50-80min.Preferably, step
(4) water bath condition is in:Water-bath 10-30min under the conditions of 60-80 DEG C.Preferably, sintering temperature is 1500-2000 in step (6)
℃。
Beneficial effects of the present invention are as follows:
The present invention passes through water-bath knot using the body portion of albite, red clay, quartz sand as composite ceramic material is closed
Close polyethylene, polypropylene, polytetrafluoroethylene (PTFE), paraffin, organic and inorganic material, the especially red clay such as thallic oxide, paraffin,
The addition of polytetrafluoroethylene (PTFE) and thallic oxide so that it is strong that the composite ceramic material that the present invention is prepared has stronger bending resistance
Degree, higher hardness and preferable fire-resistance property and smaller dielectric constant.
Specific implementation mode
With reference to embodiment, technical scheme of the present invention is described in further detail, but do not constituted pair
Any restrictions of the present invention.
Embodiment 1
A kind of composite ceramic material is made of following each component:28 parts by weight of albite, 25 parts by weight of red clay, quartz
28 parts by weight of sand, 4 parts by weight of polyethylene, 5 parts by weight of polypropylene, 4 parts by weight of polytetrafluoroethylene (PTFE), 0.2 parts by weight of plasticizer, paraffin
3 parts by weight, 1 parts by weight of sodium alginate, 0.5 parts by weight of calgon, 0.3 parts by weight of diphenylamines, 1 weight of thallic oxide
Part.
The method for preparing above-mentioned composite ceramic material:
(1) it is mixed after albite, red clay and quartz sand being distinguished ball milling;
(2) by the polyethylene of aforementioned proportion, polypropylene, polytetrafluoroethylene (PTFE), plasticizer, paraffin, sodium alginate, hexa metaphosphoric acid
Paste is stirred into after sodium, diphenylamines, thallic oxide and water mixing;
(3) material obtained step (1) and step (2) mix after under 1200rpm high speeds ball milling 60min;
(4) by the material after ball milling under 65 DEG C of water temperatures water-bath 15min;
(5) by the material injection mold after water-bath, curing agent p-aminobenzene sulfonic acid is added and carries out curing molding;
(6) material after molding is sintered in 1800 DEG C of sintering furnace and composite ceramic material is prepared.
Embodiment 2
A kind of composite ceramic material is made of following each component:30 parts by weight of albite, 24 parts by weight of red clay, quartz
30 parts by weight of sand, 3 parts by weight of polyethylene, 2 parts by weight of polypropylene, 5 parts by weight of polytetrafluoroethylene (PTFE), 0.25 parts by weight of plasticizer, stone
2 parts by weight of wax, 1 parts by weight of sodium alginate, 0.45 parts by weight of calgon, 0.3 parts by weight of diphenylamines, 2 weight of thallic oxide
Measure part.
The method for preparing above-mentioned composite ceramic material:
(1) it is mixed after albite, red clay and quartz sand being distinguished ball milling;
(2) by the polyethylene of aforementioned proportion, polypropylene, polytetrafluoroethylene (PTFE), plasticizer, paraffin, sodium alginate, hexa metaphosphoric acid
Paste is stirred into after sodium, diphenylamines, thallic oxide and water mixing;
(3) material obtained step (1) and step (2) mix after under 1400rpm high speeds ball milling 50min;
(4) by the material after ball milling under 70 DEG C of water temperatures water-bath 20min;
(5) by the material injection mold after water-bath, curing agent p-aminobenzene sulfonic acid is added and carries out curing molding;
(6) material after molding is sintered in 1600 DEG C of sintering furnace and composite ceramic material is prepared.
Embodiment 3
A kind of composite ceramic material is made of following each component:30 parts by weight of albite, 21 parts by weight of red clay, quartz
30 parts by weight of sand, 5 parts by weight of polyethylene, 5 parts by weight of polypropylene, 4 parts by weight of polytetrafluoroethylene (PTFE), 0.3 parts by weight of plasticizer, paraffin
2 parts by weight, 1 parts by weight of sodium alginate, 0.45 parts by weight of calgon, 0.25 parts by weight of diphenylamines, 1 weight of thallic oxide
Part.
The method for preparing above-mentioned composite ceramic material:
(1) it is mixed after albite, red clay and quartz sand being distinguished ball milling;
(2) by the polyethylene of aforementioned proportion, polypropylene, polytetrafluoroethylene (PTFE), plasticizer, paraffin, sodium alginate, hexa metaphosphoric acid
Paste is stirred into after sodium, diphenylamines, thallic oxide and water mixing;
(3) material obtained step (1) and step (2) mix after under 1500rpm high speeds ball milling 80min;
(4) by the material after ball milling under 80 DEG C of water temperatures water-bath 30min;
(5) by the material injection mold after water-bath, curing agent p-aminobenzene sulfonic acid is added and carries out curing molding;
(6) material after molding is sintered in 2000 DEG C of sintering furnace and composite ceramic material is prepared.
Embodiment 4
A kind of composite ceramic material is made of following each component:29 parts by weight of albite, 23 parts by weight of red clay, quartz
30 parts by weight of sand, 5 parts by weight of polyethylene, 5 parts by weight of polypropylene, 3 parts by weight of polytetrafluoroethylene (PTFE), 0.3 parts by weight of plasticizer, paraffin
2 parts by weight, 1 parts by weight of sodium alginate, 0.45 parts by weight of calgon, 0.25 parts by weight of diphenylamines, 1 weight of thallic oxide
Part.
The method for preparing above-mentioned composite ceramic material:
(1) it is mixed after albite, red clay and quartz sand being distinguished ball milling;
(2) by the polyethylene of aforementioned proportion, polypropylene, polytetrafluoroethylene (PTFE), plasticizer, paraffin, sodium alginate, hexa metaphosphoric acid
Paste is stirred into after sodium, diphenylamines, thallic oxide and water mixing;
(3) material obtained step (1) and step (2) mix after under 1500rpm high speeds ball milling 80min;
(4) by the material after ball milling under 80 DEG C of water temperatures water-bath 30min;
(5) by the material injection mold after water-bath, curing agent p-aminobenzene sulfonic acid is added and carries out curing molding;
(6) material after molding is sintered in 2000 DEG C of sintering furnace and composite ceramic material is prepared.
Comparative example 1
Difference lies in be not added polytetrafluoroethylene (PTFE), red clay and paraffin as composite ceramic to this comparative example with embodiment 1
The constituent of ceramic material.
Comparative example 2
This comparative example the difference from example 2 is that, polytetrafluoroethylene (PTFE), red clay and thallic oxide conduct is not added
The constituent of composite ceramic material.
Performance test
High-temperature heat-resistance temperature, bending strength and the hardness of each embodiment and comparative example are compared, comparing result see the table below
1, it can be seen that polytetrafluoroethylene (PTFE), red clay, paraffin and thallic oxide is not added in comparative example 1 and comparative example 2, prepare
High-temperature heat-resistance temperature/the hardness and bending strength of obtained composite ceramic material are poorer than embodiment, and its dielectric constant compares
Embodiment is high.
The performance indicator of 1 composite ceramic material of table
It is found by above-mentioned test, base of the present invention using conjunction albite, red clay, quartz sand as composite ceramic material
Body portion, by organic and inorganic materials such as water-bath combination polyethylene, polypropylene, polytetrafluoroethylene (PTFE), paraffin, thallic oxides,
The especially addition of red clay, paraffin, polytetrafluoroethylene (PTFE) and thallic oxide so that the composite ceramics material that the present invention is prepared
Material has stronger bending strength, higher hardness and preferable fire-resistance property and smaller dielectric constant.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, it is other it is any without departing from the spirit and principles of the present invention made by changes, modifications, substitutions, combinations, simplifications,
Equivalent substitute mode is should be, is included within the scope of the present invention.
Claims (7)
1. a kind of composite ceramic material, which is characterized in that be made of following components:Albite, red clay, quartz sand, polyethylene,
Polypropylene, polytetrafluoroethylene (PTFE), plasticizer, paraffin, sodium alginate, calgon, diphenylamines, thallic oxide.
2. a kind of composite ceramic material according to claim 1, which is characterized in that each component weight ratio is:Sodium
Feldspar 25-30 parts by weight, red clay 20-25 parts by weight, quartz sand 25-30 parts by weight, polyethylene 2-5 parts by weight, polypropylene 2-5
Parts by weight, polytetrafluoroethylene (PTFE) 2-5 parts by weight, plasticizer 0.1-0.2 parts by weight, paraffin 1-3 parts by weight, sodium alginate 1-2 weight
Part, calgon 0.2-0.5 parts by weight, diphenylamines 0.1-0.3 parts by weight, thallic oxide 1-3 parts by weight.
3. the preparation method of composite ceramic material as claimed in claim 1 or 2, which is characterized in that include the following steps:
(1) it is mixed after albite, red clay and quartz sand being distinguished ball milling;
(2) by polyethylene, polypropylene, polytetrafluoroethylene (PTFE), plasticizer, paraffin, sodium alginate, calgon, diphenylamines, three oxygen
Paste is stirred into after changing two thalliums and water mixing;
(3) material for obtaining step (1) and step (2), which mixes, carries out ball milling;
(4) material after ball milling is subjected to water-bath;
(5) by the material injection mold after water-bath, curing agent is added and carries out curing molding;
(6) composite ceramic material is prepared in material after molding sintering.
4. a kind of preparation method of composite ceramic material according to claim 3, which is characterized in that each object in step (2)
The weight ratio of material is:Albite 25-30 parts by weight, red clay 20-25 parts by weight, quartz sand 25-30 parts by weight, polyethylene 2-
5 parts by weight, polypropylene 2-5 parts by weight, polytetrafluoroethylene (PTFE) 2-5 parts by weight, plasticizer 0.1-0.2 parts by weight, paraffin 1-3 weight
Part, sodium alginate 1-2 parts by weight, calgon 0.2-0.5 parts by weight, diphenylamines 0.1-0.3 parts by weight, thallic oxide 1-
3 parts by weight.
5. a kind of preparation method of composite ceramic material according to claim 3, which is characterized in that ball milling in step (3)
Condition be for:1200-1500rpm high speed ball millings 50-80min.
6. a kind of preparation method of composite ceramic material according to claim 3, which is characterized in that water-bath in step (4)
Condition is:Water-bath 10-30min under the conditions of 60-80 DEG C.
7. a kind of preparation method of composite ceramic material according to claim 3, which is characterized in that sintering in step (6)
Temperature is 1500-2000 DEG C.
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CN106187260A (en) * | 2016-07-07 | 2016-12-07 | 安徽省德邦瓷业有限公司 | A kind of antivibration wear resistant ceramic material |
CN106565231A (en) * | 2016-10-20 | 2017-04-19 | 郑州丽福爱生物技术有限公司 | High-strength composite ceramic and preparation method thereof |
CN107651977A (en) * | 2017-10-25 | 2018-02-02 | 佛山市瑞生通科技有限公司 | A kind of composite ceramic material and preparation method thereof |
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2018
- 2018-07-07 CN CN201810740316.2A patent/CN108727006A/en active Pending
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2006307295A (en) * | 2005-04-28 | 2006-11-09 | National Institute Of Advanced Industrial & Technology | Clay composition for porous metal or porous ceramic, and method for producing porous metal or porous ceramic using it |
CN103771829A (en) * | 2014-01-04 | 2014-05-07 | 安徽省含山瓷业股份有限公司 | High-plasticity toughened daily use ceramic product |
CN104761239A (en) * | 2015-03-31 | 2015-07-08 | 马健 | Firing technique of blue and white porcelain |
CN106187260A (en) * | 2016-07-07 | 2016-12-07 | 安徽省德邦瓷业有限公司 | A kind of antivibration wear resistant ceramic material |
CN106565231A (en) * | 2016-10-20 | 2017-04-19 | 郑州丽福爱生物技术有限公司 | High-strength composite ceramic and preparation method thereof |
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