CN103288468A - Preparation method for fiber reinforced carbon-silicon carbide-zirconium carbide-based composite material - Google Patents

Preparation method for fiber reinforced carbon-silicon carbide-zirconium carbide-based composite material Download PDF

Info

Publication number
CN103288468A
CN103288468A CN2013101782069A CN201310178206A CN103288468A CN 103288468 A CN103288468 A CN 103288468A CN 2013101782069 A CN2013101782069 A CN 2013101782069A CN 201310178206 A CN201310178206 A CN 201310178206A CN 103288468 A CN103288468 A CN 103288468A
Authority
CN
China
Prior art keywords
zrc
nanometer powder
carbon cloth
resol
carbide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013101782069A
Other languages
Chinese (zh)
Inventor
沙建军
代吉祥
张兆甫
张玉翠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalian University of Technology
Original Assignee
Dalian University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian University of Technology filed Critical Dalian University of Technology
Priority to CN2013101782069A priority Critical patent/CN103288468A/en
Publication of CN103288468A publication Critical patent/CN103288468A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses a preparation method for a fiber reinforced carbon-silicon carbide-zirconium carbide-based (C/C-SiC-ZrC) composite material. The preparation method comprises the following steps of: (a) evenly dispersing ZrC nanopowder in absolute ethyl alcohol; (b) mixing phenolic resin and ZrC dispersion liquid to form slurry; (c) immersing a two-dimensional carbon fiber sheet into the slurry for dipping and drying, then carrying out continuous superposition paving on the two-dimensional carbon fiber sheet, and carrying out curing and post-curing treatment to prepare a fiber-reinforced sintered body; (d) cracking the fiber-reinforced sintered body to obtain a porous C/C prefabricate; (e) placing silicon powder into a graphite crucible, burying the porous C/C prefabricate into the silicon powder, heating to 1,500-1,650 DEG C, and preserving heat for preset time so as to carry out liquid silicon permeation. The method can be used for improving the high-temperature oxidizing property and ablation property of the carbon fiber reinforced ceramic (C/C-SiC) composite material.

Description

The preparation method of a kind of fiber reinforcement carbon-silicon carbide-zirconium carbide based composites
Technical field
The present invention relates to the technology of preparing of fiber reinforcement multiphase ceramic based composites, particularly adopt the insoluble metal carbide matrices of composite material to be carried out the Technology of modification.
Background technology
Carbon-fiber reinforced carbon Tao Ji (C/C-SiC) matrix material is a kind of novel high-performance thermal structure material, has highly than excellent properties such as strong, Gao Bimo, corrosion-resistant, anti-thermal shocks, has very large application potential at high-technology fields such as aerospace.But complicated along with Service Environment had higher requirement to material system, and requires material system to have stronger designability.The C/C-SiC matrix material is being difficult to satisfy performance requirement anti-oxidant, anti-ablation more than 1600 ℃.In order further to improve oxidation-resistance and the ablation property of C/C-SiC matrix material, introducing ultrahigh-temperature ceramic phase (being mainly refractory carbide) in material is a kind of effective ways.This mainly has characteristics such as high-melting-point, excellent mechanical behavior under high temperature, anti-oxidant and anti-ablation owing to the ultrahigh-temperature pottery.
Zirconium carbide (ZrC) belongs to typical insoluble metal carbide, and its fusing point can generate the zone of oxidation of thickness up to 3420 ℃ under high-temperature oxidation environment, and protecting materials is further oxided and degrades, and makes material have excellent high-temperature stability.The method that at present ZrC is incorporated in the C/C-SiC matrix material mainly contains solution impregnation cracking process and zirconium alloy permeable reactive method etc.Not only preparation cycle is long and cost is high for these Technologies, is unfavorable for suitability for industrialized production.
Summary of the invention
The object of the present invention is to provide a kind of technological process simple, can realize that the dead size shaping fiber strengthens the preparation method of carbon-silicon carbide-zirconium carbide base (C/C-SiC-ZrC) matrix material.
Specific embodiments is as follows:
The preparation method of a kind of fiber reinforcement carbon-silicon carbide-zirconium carbide based composites is characterized in that, comprises the steps:
(a) a certain proportion of ZrC nanometer powder is joined in a certain amount of dehydrated alcohol, through fully behind stirring and the sonic oscillation ZrC nanometer powder evenly being disperseed in dehydrated alcohol;
(b) the ZrC dispersion liquid that resol and step (a) are obtained, makes resol be dissolved in the dehydrated alcohol and adopts ultra-sonic oscillation to make the ZrC nanometer powder evenly disperse to form slurry than mixing according to certain mass;
(c) two-dimentional carbon cloth is immersed in the slurry that step (b) obtains and fully floods, dry two-dimentional carbon cloth through dipping, in mould, this two dimension carbon cloth is folded overlay continuously then, and behind folded overlay, be cured and post curing treatment preparation fiber reinforcement biscuit body;
(d) the fiber reinforcement biscuit body that step (c) is obtained places in the pyrographite stove, is warmed up to default temperature rise rate and carries out cracking more than 900 ℃, obtains the porous C/C precast body of even dispersion ZrC particle;
(e) silica flour is positioned in the plumbago crucible, and porous C/C precast body that step (d) is obtained is embedded in the silica flour, plumbago crucible is placed in the pyrographite stove, be heated to 1500-1650 ℃ and be incubated the scheduled time and carry out the liquid silicon infiltration with default temperature rise rate, obtain fiber reinforcement carbon-silicon carbide-zirconium carbide based composites.
In step (a), preferably more than 99.0%, granularity is preferably 10-60nm to the purity of ZrC nanometer powder, when big as if powder size, need reduce granularity through high-energy ball milling.In addition, the mass ratio of ZrC nanometer powder and dehydrated alcohol is preferably 0.025-0.125:1.
In step (b), the resol kind of using is not particularly limited.ZrC nanometer powder in the ZrC dispersion liquid and the mass ratio of resol are preferably 0.02-0.1:1, by adopting ultrasonic oscillation, can obtain the resin adhesive liquid of even dispersion ZrC nanometer powder.In addition, in order to promote the dissolving of resol in dehydrated alcohol, before preferably mixing with the ZrC dispersion liquid resol is carried out fragmentation and handle, and the preferred mixed solution that heats between 30-50 ℃ is finished up to the dissolution process of resol in dehydrated alcohol.
In step (c), two-dimentional carbon cloth is T300, T700 or other product.Two-dimentional carbon cloth is fully flooded in the slurry that step (b) obtains, fully dipping is by the super-dry process, absolute ethanol volatilizes, even dispersion resin and ZrC nanometer powder in the fibrous bundle of two dimension carbon cloth, the mass ratio of its disperse quality and two-dimentional carbon cloth is preferably 1:1.4-2.6.Two-dimentional carbon cloth behind the folded overlay is preferably applied the pressure of 2-5MPa, can make the gas that discharges in the resin solidification cross-linking process be extruded eliminating like this, thereby prepare the fiber reinforcement biscuit body of tight shop layer.Condition of cure is preferably 130-150 ℃, 6-10 hour, and the after fixing condition is 180-230 ℃, 20-30 hour.In addition, the shop number of plies is not particularly limited, can requires suitably to adjust according to material thickness.
In step (d), default temperature rise rate is generally 1-3 ℃/minute, and the cracking time was generally 30-60 minute.Under the Pintsch process condition, resol generation polycondensation in the fiber reinforcement biscuit body, thereby the volumetric shrinkage that 50%-60% occurs, owing to contain fortifying fibre in the biscuit body, resin matrix tension stress occurs owing to being subjected to the different resistance of fiber both direction in contraction process, this makes and produces tiny crack in the matrix.Simultaneously, resin also can produce a large amount of gases in cracking process, along with the rising of cracking temperature, gas yield accumulates and forms air pressure gradually in base cavity, air pressure progressively raises and finally causes pore to break, and produces micropore, forms the C/C precast body of porous/crackle.In order there to be more cracking carbon to generate in the precast body, the preferred higher resin system of carbon residue rate, the present invention selects resol for use.In addition, cracking environmental optimization nitrogen environment, this is because two-dimentional carbon cloth can not cause the fibre strength degradation under nitrogen environment, can keep the wild phase fibre shape.
In step (e), the mass ratio of C/C precast body and silica flour is preferably 0.4-0.5:1, by adopting this mass ratio, can make matrix carbon and liquid silicon that fully reaction takes place, and does not have too much liquid silicon infiltration simultaneously and forms the residual silicon phase.Silicon particle size is generally the 10-40 order.In addition, default temperature rise rate is generally 3-5 ℃/minute, and the insulation Preset Time was generally 30-60 minute.
The beneficial effect of the invention is:
(1) can prepare comparatively fine and close C/C-SiC-ZrC matrix material by the present invention, and this C/C-SiC-ZrC matrix material effectively improves its oxidation-resistance and ablation resistance with respect to the C/C-SiC matrix material, therefore had excellent high-temperature stability.
(2) because the present invention directly is incorporated into ZrC ultrahigh-temperature ceramic phase in the C/C-SiC matrix material, make that whole prepared cycle shortening and operating process are simple, be conducive to suitability for industrialized production more.
(3) the matrix modification method that adopts among the present invention is conducive to carbon-fiber reinforced carbon pottery based composites is carried out heterogeneous matrix component optimization, to satisfy the different requirements under the complicated Service Environment.
Embodiment
Describe the present invention in detail below in conjunction with embodiment; but the following examples only are preferred implementation of the present invention; protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to replacement or change according to technical scheme of the present invention and inventive concept thereof, all should be encompassed within protection scope of the present invention.
Material therefor is the commercially available material among the following embodiment.
Embodiment 1
In the present embodiment, ZrC nanometer powder and resol mass ratio are 0.02:1, and selected two-dimentional carbon cloth is two-dimentional T300 carbon cloth.Its implementation method is carried out according to following step:
1. be that 0.1 milligram analytical balance takes by weighing 2 gram ZrC nanometer powder (purity 99.0% in precision, median size 50nm), take by weighing 80 gram dehydrated alcohols at general utility balance, both mix, stir, being placed on vibrates in the ultrasonic bath is uniformly dispersed the ZrC nanometer powder.
2. after solid phenolic resin being carried out fragmentation (the bulk resin is suitably broken), taking by weighing 100 gram resins joins in the dispersion liquid of step 1 preparation, mixed solution is placed on is heated to resin in 50 ℃ of baking ovens and dissolves fully, adopt ultra-sonic oscillation to make the ZrC nanometer powder evenly disperse to form slurry then.
3. (size: 100 * 70 * 60mm) in the slurry that step 2 obtains fully behind the dipping with the two-dimentional T300 carbon cloth of about 25 grams after the cuttings, in air, dry, take by weighing cloth after drying at general utility balance, quality is about 43g, (from molding jig, size: continuous shop layer is to 20 layers in 100 * 70 * 60mm) at mould then.Shop layer is finished the back mould and is added 2MPa pressure, is positioned over that 130 ℃ of heating were cured in 10 hours in the baking oven, puts into retort furnace again and continues to heat with 180 ℃ and finished after fixing in 20 hours.
4. the material that step 3 is obtained is placed in the pyrographite stove, vacuumize and inflated with nitrogen after, be warmed up to 1200 ℃ and be incubated 60 minutes with 2 ℃/minute speed, insulation finishes the back powered-down, naturally cooling returns to room temperature, obtains about 27 gram porous C/C-ZrC precast bodies.
5. the silica flour (purity 〉=98%) that 60 grams, 40 mesh sieves sieve is got is positioned in the plumbago crucible, and porous C/C-ZrC precast body that step 4 is obtained is embedded in the silica flour, crucible is placed the pyrographite stove, be heated to 1650 ℃ and be incubated 60 minutes and carry out the liquid silicon infiltration with 5 ℃/minute temperature rise rates, insulation finishes the back powered-down, naturally cooling returns to room temperature, obtains the C/C-SiC-ZrC matrix material.
Embodiment 2
The present embodiment mass ratio of ZrC nanometer powder and resol as different from Example 1 is 0.05:1(ZrC nanometer powder 5 grams), other are identical with embodiment 1.
Embodiment 3
The present embodiment mass ratio of ZrC nanometer powder and resol as different from Example 1 is 0.08:1(ZrC nanometer powder 8 grams), other are identical with embodiment 1.
Embodiment 4
The present embodiment mass ratio of ZrC nanometer powder and resol as different from Example 1 is 0.1:1(ZrC nanometer powder 10 grams), other are identical with embodiment 1.
Embodiment 5
Present embodiment selected two-dimentional carbon cloth as different from Example 1 is two-dimentional T700 carbon cloth, and other are identical with embodiment 1.
Embodiment 6
The present embodiment mass ratio of ZrC nanometer powder and resol as different from Example 1 is 0.05:1(ZrC nanometer powder 5 grams), selected two-dimentional carbon cloth is two-dimentional T700 carbon cloth, other are identical with embodiment 1.
Embodiment 7
The present embodiment mass ratio of ZrC nanometer powder and resol as different from Example 1 is 0.08:1(ZrC nanometer powder 8 grams), selected two-dimentional carbon cloth is two-dimentional T700 carbon cloth, other are identical with embodiment 1.
Embodiment 8
The present embodiment mass ratio of ZrC nanometer powder and resol as different from Example 1 is 0.1:1(ZrC nanometer powder 10 grams), selected two-dimentional carbon cloth is two-dimentional T700 carbon cloth, other are identical with embodiment 1.
At first, adopt sem observation sample microscopic appearance.Used sample and observed result are as follows: gained C/C-SiC-ZrC matrix material and the sample section after the cutting carried out polished finish among (1) cutting embodiment 1-8, observe the sample section after the polishing, and find that the matrix material that obtains is comparatively fine and close.(2) gained C/C-SiC-ZrC matrix material among the embodiment 1-8 is carried out three-point bending mechanical property test (implementing according to the ASTMC1341-06 testing standard), find that the material fracture is non-brittle rupture, fracture surface of sample has tangible fiber bridging and fiber to extract, and fiber has played good toughening effect.(3) surface topography of sample is observed in (implementing according to the ASTM E458-2008 testing standard) back of ablating of gained C/C-SiC-ZrC matrix material among the embodiment 1-8, discovery has glassy oxides to generate, and this is the SiO that matrix (SiC, ZrC) high temperature oxidation generates 2And ZrO 2, its formation has protected material inside to be further oxided well, has improved the anti-oxidant and ablation resistance of material.
Among the cutting embodiment 1-8 gained C/C-SiC-ZrC matrix material and the specimen surface after the cutting carried out polished finish after, carry out Mechanics Performance Testing.Table 1 has been listed Mechanics Performance Testing result (flexural strength is implemented according to ASTM C1341-06 testing standard, and fracture toughness property is implemented according to ASTM C1421-10 testing standard).
Table 1
As can be seen from Table 1, the flexural strength of T700 fiber reinforcement C/C-SiC-ZrC matrix material and fracture toughness property all are higher than T300 fiber reinforcement C/C-SiC-ZrC matrix material.This is that T700 tensile strength of fiber (4.9GPa) is higher than due to the T300 tensile strength of fiber (3.5GPa) simultaneously because the C/C-SiC-ZrC matrix material of T700 fiber production contains higher fiber volume fraction.In addition, the present invention finds, the ZrC nanometer powder of interpolation different mass mark has tangible influence to the mechanical property of final C/C-SiC-ZrC matrix material, when the content of ZrC nanometer powder in resin is that the mass ratio of 5%(ZrC nanometer powder and resol is 0.05:1) time, it is optimum that the flexural strength of matrix material and fracture toughness property all reach, and add too much ZrC nanometer powder slurry viscosity is increased, easily form thicker ZrC nano powder reunion layer at the carbon cloth interlayer, thereby cause the arch formation of micro mist, cause mechanical property to reduce.
Simultaneously, among the cutting embodiment 1-8 gained C/C-SiC-ZrC matrix material and the specimen surface after the cutting carried out polished finish after, investigate its antioxidant property (natural air atmosphere in the tube furnace, oxidizing temperature is selected 500,700,900,1200,1400,1500 degrees centigrade, oxidization time was respectively 2,5 hours), discovery is under the high temperature atmosphere well-oxygenated environment, and the mass loss of the C/C-SiC-ZrC matrix material of the present invention's preparation is lower than the C/C-SiC matrix material.This is because under well-oxygenated environment, the oxidation of SiC and ZrC causes SiO 2And ZrO 2Formation, these oxidation productss are overlying on material surface and stop oxygen further to the material internal diffusion, thereby improve the material resistance of oxidation.

Claims (9)

1. the preparation method of fiber reinforcement carbon-silicon carbide-zirconium carbide based composites is characterized in that, comprises the steps:
(a) a certain proportion of ZrC nanometer powder is joined in a certain amount of dehydrated alcohol, through fully behind stirring and the sonic oscillation ZrC nanometer powder evenly being disperseed in dehydrated alcohol;
(b) the ZrC dispersion liquid that resol and step (a) are obtained, makes resol be dissolved in the dehydrated alcohol and adopts ultra-sonic oscillation to make the ZrC nanometer powder evenly disperse to form slurry than mixing according to certain mass;
(c) two-dimentional carbon cloth is immersed in the slurry that step (b) obtains and fully floods, dry two-dimentional carbon cloth through dipping, in mould, this two dimension carbon cloth is folded overlay continuously then, and behind folded overlay, be cured and post curing treatment preparation fiber reinforcement biscuit body;
(d) the fiber reinforcement biscuit body that step (c) is obtained places in the pyrographite stove, is warmed up to default temperature rise rate and carries out cracking more than 900 ℃, obtains the porous C/C precast body of even dispersion ZrC particle;
(e) silica flour is positioned in the plumbago crucible, and porous C/C precast body that step (d) is obtained is embedded in the silica flour, plumbago crucible is placed in the pyrographite stove, be heated to 1500-1650 ℃ and be incubated the scheduled time and carry out the liquid silicon infiltration with default temperature rise rate, obtain fiber reinforcement carbon-silicon carbide-zirconium carbide based composites.
2. method according to claim 1 is characterized in that, in step (a), the purity of described ZrC nanometer powder is more than 99.0%, and granularity is 10-60nm, and the mass ratio of ZrC nanometer powder and dehydrated alcohol is 0.025-0.125:1.
3. method according to claim 1 is characterized in that, in step (b), the ZrC nanometer powder in the ZrC dispersion liquid and the mass ratio of resol are 0.02-0.1:1.
4. method according to claim 1 is characterized in that, in step (b), before mixing with the ZrC dispersion liquid resol is carried out fragmentation and handle, and the heating mixed solution is finished up to the dissolution process of resol in dehydrated alcohol between 30-50 ℃.
5. method according to claim 1, it is characterized in that, in step (c), fully dipping is by the super-dry process, absolute ethanol volatilizes, even dispersion resin and ZrC nanometer powder in the fibrous bundle of two dimension carbon cloth, the mass ratio of its disperse quality and two-dimentional carbon cloth is 1:1.4-2.6.
6. method according to claim 1 is characterized in that, in step (c), the two-dimentional carbon cloth behind the folded overlay is applied the pressure of 2-5MPa, and condition of cure is 130-150 ℃, 6-10 hour, and the after fixing condition is 180-230 ℃, 20-30 hour.
7. method according to claim 1 is characterized in that, in step (d), default temperature rise rate is 1-3 ℃/minute, and the cracking environment is nitrogen environment.
8. method according to claim 1 is characterized in that, in step (e), the mass ratio of porous C/C precast body and silica flour is 0.4-0.5:1, and silicon particle size is the 10-40 order.
9. according to any described method of claim 1-8, it is characterized in that in step (e), default temperature rise rate is 3-5 ℃/minute, the insulation Preset Time is 30-60 minute.
CN2013101782069A 2013-05-14 2013-05-14 Preparation method for fiber reinforced carbon-silicon carbide-zirconium carbide-based composite material Pending CN103288468A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013101782069A CN103288468A (en) 2013-05-14 2013-05-14 Preparation method for fiber reinforced carbon-silicon carbide-zirconium carbide-based composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013101782069A CN103288468A (en) 2013-05-14 2013-05-14 Preparation method for fiber reinforced carbon-silicon carbide-zirconium carbide-based composite material

Publications (1)

Publication Number Publication Date
CN103288468A true CN103288468A (en) 2013-09-11

Family

ID=49090073

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2013101782069A Pending CN103288468A (en) 2013-05-14 2013-05-14 Preparation method for fiber reinforced carbon-silicon carbide-zirconium carbide-based composite material

Country Status (1)

Country Link
CN (1) CN103288468A (en)

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103627889A (en) * 2013-12-16 2014-03-12 浙江金牛工贸有限公司 Preparation technology of efficient and stop loss noble metal product
CN103964882A (en) * 2014-04-29 2014-08-06 中国科学院上海硅酸盐研究所 Preparation method for fiber-reinforced superhigh temperature ceramic matrix composite
CN104311090A (en) * 2014-08-27 2015-01-28 航天材料及工艺研究所 Method for preparing Cf/ZrC-SiC superhigh-temperature ceramic composite material through hot-pressing sintering/precursor cracking process
CN105418106A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion niobium boride and silicon carbide-carbon fiber friction material
CN105418121A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion titanium boride and boron carbide-carbon fiber friction material
CN105418118A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparation method of resin dispersion zirconium carbide boron carbide-carbon fiber friction material
CN105418108A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method for ethanol-dispersed titanium boride boron carbide and carbon fiber friction material
CN105418104A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion hafnium carbide and silicon carbide-carbon fiber friction material
CN105418109A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method for ethanol-dispersed tantalum carbide boron carbide and carbon fiber friction material
CN105418123A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion tungsten carbide and boron carbide-carbon fiber friction material
CN105439603A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method of resin dispersed niobium carbide silicon carbide-carbon fiber friction material
CN105439596A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method for ethanol dispersed vanadium boride boron carbide-carbon fiber friction material
CN105439591A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method of synthetic fat dispersed tantalum carbide and silicon carbide-carbon fiber friction material
CN105439589A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method of ultrasonic-dispersion niobium and carbide silicon carbide-carbon fiber friction material
CN105439595A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method for ethanol dispersed tungsten carbide boron carbide-carbon fiber friction material
CN105481441A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparation method for resin dispersed hafnium boride silicon carbide-carbon fiber friction material
CN105481437A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparing method for ethanol-dispersed vanadium carbide silicon carbide and carbon fiber friction material
CN105481439A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparation method for resin dispersed niobium boride boron carbide-carbon fiber friction material
CN105481438A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparation method for resin dispersed hafnium boride boron carbide-carbon fiber friction material
CN105481421A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparing method for synthetic fat dispersed zirconium boride silicon carbide-carbon fiber friction material
CN105481432A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparing method for ethanol-dispersed zirconium carbide silicon carbide and carbon fiber friction material
CN105622148A (en) * 2016-01-11 2016-06-01 山东理工大学 Method for preparing resin-dispersed zirconium carbide, silicon carbide and carbon fiber friction material
CN105622136A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparing method for synthetic fat dispersed vanadium boride silicon carbide-carbon fiber friction material
CN105622141A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparation method of ethanol dispersed titanium carbide silicon carbide-carbon fiber friction material
CN105622143A (en) * 2016-01-11 2016-06-01 山东理工大学 Method for preparing resin-dispersed tantalum boride, boron carbide-carbon fiber friction material
CN105622140A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparation method of ethanol dispersed hafnium carbide silicon carbide-carbon fiber friction material
CN105622144A (en) * 2016-01-11 2016-06-01 山东理工大学 Method for preparing resin-dispersed zirconium boride, boron carbide-carbon fiber friction material
CN105622149A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparation method for resin-dispersed tantalum carbide based silicon carbide-carbon fiber friction material
CN106882975A (en) * 2015-12-16 2017-06-23 航天特种材料及工艺技术研究所 A kind of preparation method of C/C composites
CN107382321A (en) * 2017-09-25 2017-11-24 常熟理工学院 A kind of ultra-fine Zirconium carbide powder and preparation method thereof
CN107500769A (en) * 2017-08-22 2017-12-22 巩义市泛锐熠辉复合材料有限公司 A kind of C/TiB2The surface treatment method of composite
CN108178650A (en) * 2018-01-22 2018-06-19 哈尔滨工业大学 A kind of method for preparing graphene network toughening ZrC-SiC superhigh temperature ceramic materials
CN108395266A (en) * 2018-03-28 2018-08-14 中国航发北京航空材料研究院 A kind of preparation method of fiber reinforcement multiphase ceramic matrix composite
CN109293383A (en) * 2018-10-31 2019-02-01 航天特种材料及工艺技术研究所 A kind of fiber reinforcement carbon/carbon-silicon carbide ceramics base composite material and preparation method thereof
CN111099911A (en) * 2020-01-02 2020-05-05 航天特种材料及工艺技术研究所 Carbon fiber reinforced carbon-silicon carbide-zirconium carbide composite material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640847A (en) * 2004-01-09 2005-07-20 谭毅 Simple carbon/carborundum composite material manufacturing method
CN101838146A (en) * 2010-02-09 2010-09-22 西安工程大学 Preparation method of hemp fabric construction morph-genetic ceramic composite material
CN102537155A (en) * 2011-12-29 2012-07-04 中国科学院过程工程研究所 C/C-SiC-ZrC-ZrB2 complex-phase ceramic-based frictional braking material and preparation method thereof
CN102976756A (en) * 2012-04-19 2013-03-20 安徽众星新材料有限公司 Continuous carbon fiber reinforced C-SiC binary base composite material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640847A (en) * 2004-01-09 2005-07-20 谭毅 Simple carbon/carborundum composite material manufacturing method
CN101838146A (en) * 2010-02-09 2010-09-22 西安工程大学 Preparation method of hemp fabric construction morph-genetic ceramic composite material
CN102537155A (en) * 2011-12-29 2012-07-04 中国科学院过程工程研究所 C/C-SiC-ZrC-ZrB2 complex-phase ceramic-based frictional braking material and preparation method thereof
CN102976756A (en) * 2012-04-19 2013-03-20 安徽众星新材料有限公司 Continuous carbon fiber reinforced C-SiC binary base composite material and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
李秀倩等: "ZrC/SiC多组元改性C/C复合材料的弯曲性能研究", 《第17届全国复合材料学术会议论文》 *
梁赤勇等: "Cf/SiC复合材料表面熔盐反应法锆金属化研究", 《航空材料学报》 *
蒋进明等: "先驱体浸渍裂解结合反应熔渗法制备C_f/ZrC-SiC复合材料", 《第十七届全国高技术陶瓷学术年会摘要集》 *

Cited By (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103627889A (en) * 2013-12-16 2014-03-12 浙江金牛工贸有限公司 Preparation technology of efficient and stop loss noble metal product
CN103964882A (en) * 2014-04-29 2014-08-06 中国科学院上海硅酸盐研究所 Preparation method for fiber-reinforced superhigh temperature ceramic matrix composite
CN104311090A (en) * 2014-08-27 2015-01-28 航天材料及工艺研究所 Method for preparing Cf/ZrC-SiC superhigh-temperature ceramic composite material through hot-pressing sintering/precursor cracking process
CN106882975B (en) * 2015-12-16 2020-06-16 航天特种材料及工艺技术研究所 Preparation method of C/C composite material
CN106882975A (en) * 2015-12-16 2017-06-23 航天特种材料及工艺技术研究所 A kind of preparation method of C/C composites
CN105418108A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method for ethanol-dispersed titanium boride boron carbide and carbon fiber friction material
CN105418118A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparation method of resin dispersion zirconium carbide boron carbide-carbon fiber friction material
CN105418104A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion hafnium carbide and silicon carbide-carbon fiber friction material
CN105418109A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method for ethanol-dispersed tantalum carbide boron carbide and carbon fiber friction material
CN105418123A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion tungsten carbide and boron carbide-carbon fiber friction material
CN105439603A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method of resin dispersed niobium carbide silicon carbide-carbon fiber friction material
CN105439596A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method for ethanol dispersed vanadium boride boron carbide-carbon fiber friction material
CN105439591A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method of synthetic fat dispersed tantalum carbide and silicon carbide-carbon fiber friction material
CN105439589A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method of ultrasonic-dispersion niobium and carbide silicon carbide-carbon fiber friction material
CN105439595A (en) * 2016-01-11 2016-03-30 山东理工大学 Preparation method for ethanol dispersed tungsten carbide boron carbide-carbon fiber friction material
CN105481441A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparation method for resin dispersed hafnium boride silicon carbide-carbon fiber friction material
CN105481437A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparing method for ethanol-dispersed vanadium carbide silicon carbide and carbon fiber friction material
CN105481439A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparation method for resin dispersed niobium boride boron carbide-carbon fiber friction material
CN105481438A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparation method for resin dispersed hafnium boride boron carbide-carbon fiber friction material
CN105481421A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparing method for synthetic fat dispersed zirconium boride silicon carbide-carbon fiber friction material
CN105481432A (en) * 2016-01-11 2016-04-13 山东理工大学 Preparing method for ethanol-dispersed zirconium carbide silicon carbide and carbon fiber friction material
CN105622148A (en) * 2016-01-11 2016-06-01 山东理工大学 Method for preparing resin-dispersed zirconium carbide, silicon carbide and carbon fiber friction material
CN105622136A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparing method for synthetic fat dispersed vanadium boride silicon carbide-carbon fiber friction material
CN105622141A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparation method of ethanol dispersed titanium carbide silicon carbide-carbon fiber friction material
CN105622143A (en) * 2016-01-11 2016-06-01 山东理工大学 Method for preparing resin-dispersed tantalum boride, boron carbide-carbon fiber friction material
CN105622140A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparation method of ethanol dispersed hafnium carbide silicon carbide-carbon fiber friction material
CN105439603B (en) * 2016-01-11 2018-06-26 山东理工大学 The preparation method of resin dispersion niobium carbide silicon carbide―carbon fiber friction material
CN105622149A (en) * 2016-01-11 2016-06-01 山东理工大学 Preparation method for resin-dispersed tantalum carbide based silicon carbide-carbon fiber friction material
CN105418121A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion titanium boride and boron carbide-carbon fiber friction material
CN105622148B (en) * 2016-01-11 2017-11-21 山东理工大学 The preparation method of resin dispersion zirconium carbide carborundum carbon fiber friction material
CN105622149B (en) * 2016-01-11 2017-11-21 山东理工大学 The preparation method of resin dispersion ramet carborundum carbon fiber friction material
CN105418106A (en) * 2016-01-11 2016-03-23 山东理工大学 Preparing method of synthetic-fat dispersion niobium boride and silicon carbide-carbon fiber friction material
CN105622136B (en) * 2016-01-11 2017-12-19 山东理工大学 Close the preparation method that fat disperses vanadium boride carborundum carbon fiber friction material
CN105439591B (en) * 2016-01-11 2018-06-26 山东理工大学 Close the preparation method of fat dispersion ramet silicon carbide―carbon fiber friction material
CN105622141B (en) * 2016-01-11 2018-02-02 山东理工大学 Ethanol disperses the preparation method of titanium carbide carborundum carbon fiber friction material
CN105622140B (en) * 2016-01-11 2018-03-23 山东理工大学 Ethanol disperses the preparation method of hafnium carbide carborundum carbon fiber friction material
CN105439596B (en) * 2016-01-11 2018-05-22 山东理工大学 Ethyl alcohol disperses the preparation method of vanadium boride boron carbide-carbon fiber friction material
CN105622144B (en) * 2016-01-11 2018-05-22 山东理工大学 The preparation method of resin dispersion zirconium boride boron carbide-carbon fiber friction material
CN105481441B (en) * 2016-01-11 2018-05-25 山东理工大学 The preparation method of resin dispersion hafnium boride silicon carbide―carbon fiber friction material
CN105622144A (en) * 2016-01-11 2016-06-01 山东理工大学 Method for preparing resin-dispersed zirconium boride, boron carbide-carbon fiber friction material
CN105439595B (en) * 2016-01-11 2018-06-19 山东理工大学 The preparation method of ethyl alcohol dispersion tungsten carbide carbonization boron-carbon fiber friction material
CN107500769B (en) * 2017-08-22 2020-06-12 巩义市泛锐熠辉复合材料有限公司 C/TiB2Surface treatment method of composite material
CN107500769A (en) * 2017-08-22 2017-12-22 巩义市泛锐熠辉复合材料有限公司 A kind of C/TiB2The surface treatment method of composite
CN107382321B (en) * 2017-09-25 2019-12-20 常熟理工学院 Superfine zirconium carbide powder and preparation method thereof
CN107382321A (en) * 2017-09-25 2017-11-24 常熟理工学院 A kind of ultra-fine Zirconium carbide powder and preparation method thereof
CN108178650B (en) * 2018-01-22 2021-06-01 哈尔滨工业大学 Method for preparing graphene network toughened ZrC-SiC ultrahigh-temperature ceramic material
CN108178650A (en) * 2018-01-22 2018-06-19 哈尔滨工业大学 A kind of method for preparing graphene network toughening ZrC-SiC superhigh temperature ceramic materials
CN108395266A (en) * 2018-03-28 2018-08-14 中国航发北京航空材料研究院 A kind of preparation method of fiber reinforcement multiphase ceramic matrix composite
CN109293383B (en) * 2018-10-31 2021-06-25 航天特种材料及工艺技术研究所 Fiber-reinforced carbon-silicon carbide ceramic matrix composite and preparation method thereof
CN109293383A (en) * 2018-10-31 2019-02-01 航天特种材料及工艺技术研究所 A kind of fiber reinforcement carbon/carbon-silicon carbide ceramics base composite material and preparation method thereof
CN111099911A (en) * 2020-01-02 2020-05-05 航天特种材料及工艺技术研究所 Carbon fiber reinforced carbon-silicon carbide-zirconium carbide composite material and preparation method thereof
CN111099911B (en) * 2020-01-02 2020-11-13 航天特种材料及工艺技术研究所 Carbon fiber reinforced carbon-silicon carbide-zirconium carbide composite material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN103288468A (en) Preparation method for fiber reinforced carbon-silicon carbide-zirconium carbide-based composite material
CN104311090B (en) A kind of hot pressed sintering/presoma cracking process prepares the method for Cf/ZrC-SiC ultrahigh temperature ceramic composite
CN102976756B (en) Continuous carbon fiber reinforced C-SiC binary base composite material and preparation method thereof
CN103332943B (en) Microstructure design and the Properties Control method of carbon pottery based composites is prepared based on liquid silicon infiltration method
CN102515870A (en) Preparation method of C/SiC-ZrB2-ZrC ultrahigh-temperature ceramic-based composite material
CN101456737B (en) Boron carbide base composite ceramic and preparation method thereof
CN107673763A (en) The method for preparing ceramic structures by fused glass pellet 3D printing using thermoplasticity ceramic forerunner
CN105367106B (en) Fibre reinforced carbonization zirconium composite material and preparation method thereof
CN106882974B (en) Preparation method of C/HfC-SiC composite material with high HfC content
CN109354823B (en) Preparation method of heat-insulation ceramizable phenolic resin-based gradient composite material
CN107021771B (en) Calcium oxide-based ceramic casting mold manufacturing method based on 3D printing technology
Lu et al. Manufacturing properties of turbine blades of carbon fiber-reinforced SiC composite based on stereolithography
Hu et al. Mechanical and dielectric properties of SiCf/SiC composites fabricated by PIP combined with CIP process
CN104591768A (en) Ceramic matrix composite material employing silicon alkyne-modified SiBCN as precursor and preparation method of ceramic matrix composite material
CN106633652A (en) Preparation method of bicontinuous-phase alumina/epoxy resin composite material
CN106278278A (en) A kind of by modifying the method that presoma regulates and controls carborundum thermal conductivity
CN107556011A (en) SiCf/ SiC ceramic matrix composite material and preparation method thereof
CN104926346B (en) A kind of alumina fibre fabric containing interface phase strengthens silicon carbide ceramics and preparation method thereof
CN105859318B (en) Staple fiber-SiC nano fiber enhancing carborundum porous ceramics material and preparation method thereof
CN102603344B (en) Preparing process of silicon carbide whisker toughened zirconium diboride ceramic
CN105481412B (en) C/ZrC composites based on liquid phase melt impregnation and preparation method thereof
CN106187263A (en) The manufacture method of C/C SiC ceramic matrix composite material parts and C/C SiC ceramic matrix composite material parts
CN109370148A (en) A kind of high-densit high temperature suitable for RFI moulding process can porcelain phenolic resin infiltration film and preparation method thereof
CN110078529A (en) A kind of silicon carbide whisker reinforced aluminum matrix composites and preparation method thereof
Meng et al. Continuous regulation from fully dense to high porosity within polymer-derived SiCN ceramics

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20130911