CN108722981A - A kind of method of paraffin in quick removing dewatering box - Google Patents

A kind of method of paraffin in quick removing dewatering box Download PDF

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Publication number
CN108722981A
CN108722981A CN201810357992.1A CN201810357992A CN108722981A CN 108722981 A CN108722981 A CN 108722981A CN 201810357992 A CN201810357992 A CN 201810357992A CN 108722981 A CN108722981 A CN 108722981A
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Prior art keywords
dewatering box
paraffin
parts
mentioned steps
removal liquid
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CN201810357992.1A
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CN108722981B (en
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朱清
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BENGBU MEDICAL COLLEGE
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/266Esters or carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/28Organic compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3245Aminoacids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/34Organic compounds containing sulfur

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The method that the present invention discloses paraffin in a kind of quick removal dewatering box, including following operating procedure:(1)After mixing by in-situ polymerization nano hybridization silicone oil, methylpropene sodium sulfonate, deionized water, using supersound process, dissociation agent is made;(2)1,2-cyclohexanediaminetetraacetic acid, D-ALPHA-Hydroxypropionic acid methyl esters, chloro-carbonic acid diethylene glycol (DEG) ester are added into ethyl alcohol, after being mixed evenly, then dissociation agent is added thereto, continues after being uniformly mixed, paraffin removal liquid is made;(3)Dewatering box is put into warm water, after immersion treatment, dewatering box, the moisture on the dewatering box surface that quickly exhausted with filter paper are taken out, then paraffin removal liquid is sprayed to dewatering box surface, after 5-7min, dewatering box is placed again into warm water, after immersion treatment, take out dewatering box, after being rinsed with water again, naturally dry, paraffin removal is completed in dewatering box.Method provided by the invention, can effectively remove the paraffin adhered on dewatering box, and noresidue does not interfere with reusing for dewatering box.

Description

A kind of method of paraffin in quick removing dewatering box
Technical field
The invention belongs to medical detecting Instrument cleaning technique fields, and in particular to paraffin in a kind of quick removing dewatering box Method.
Background technology
Paraffin tissue sections technology is important technology indispensable in life science, teaching, diagnosis, in paraffin group During knitting microsection manufacture, especially pathological diagnosis and teaching, scientific experiment paraffin tissue sections manufacturing process in, dehydration Box is one of the important equipment that can be recycled, and various tissue specimens need to be contained in respectively after number, materials each de- In water box, main purpose is to distinguish the similar tissue in Different Individual source, while ensureing the various tissues chosen from losing. Fixation, dehydration, transparent, waxdip of each batch tissue etc. carry out in dewatering box, after organization embedding, with organize into The solid paraffin for entering to stick on the dewatering box of wax cylinder volume, due to being recycled in next batch histotomy manufacturing process Dewatering box on the solid paraffin that sticks in tissue dewatering, clearing process, to be used for dimethylbenzene of transparency of organization etc. organic Solvent dissolves, and the dimethylbenzene for having dissolved paraffin can be severely impacted on the transparent effect of purity and tissue, and then influences To the making result of histotomy.Therefore, after organization embedding, it is necessary to at the solid paraffin that sticks on dewatering box Reason, is removed.If the paraffin being set on dewatering box is not processed or is handled it is bad, can under the influence of batch tissue cut To the normal use of dewatering box when piece makes.Some paraffin tissue sections production units use disposable dewatering box, although exempting The worry of the solidification paraffin sticked on dewatering box is removed, but causes a large amount of paraffin waste, and paraffin can be caused to ring The pollution in border.
Invention content
In order to solve the above technical problem, the present invention provides a kind of methods of paraffin in quick removing dewatering box.
The present invention is achieved by the following technical solutions.
A kind of method of paraffin in quick removing dewatering box, including following operating procedure:
(1)By weight, it is according to mass ratio by in-situ polymerization nano hybridization silicone oil, methylpropene sodium sulfonate, deionized water 10-15:1:After mixing, using 28-32min is ultrasonically treated, dissociation agent is made in 20 ratio;
(2)By weight, by 14-19 parts of 1,2-cyclohexanediaminetetraacetic acid, 3-6 parts of D-ALPHA-Hydroxypropionic acid methyl esters, 16-20 parts of chloro-carbonic acids two Glycol ester is added into 75-85 parts of ethyl alcohol, after being mixed evenly, then 8-10 parts of steps is added thereto(1)Solution obtained From agent, continue after being uniformly mixed, paraffin removal liquid is made;
(3)Dewatering box is put into 40-50 DEG C of warm water, after immersion treatment 3-5min, dewatering box is taken out, is quickly exhausted with filter paper Then the moisture on dewatering box surface sprays paraffin removal liquid to dewatering box surface, after 5-7min, dewatering box is placed again into 40- In 50 DEG C of warm water, after immersion treatment 10-12min, dewatering box is taken out, after being rinsed with water again, naturally dry, stone in dewatering box Wax, which is removed, to be completed.
Specifically, above-mentioned steps(1)In, the purity of in-situ polymerization nano hybridization silicone oil is 99.9%.
Specifically, above-mentioned steps(1)In, the frequency size of supersound process is 28-30kHz.
Specifically, above-mentioned steps(2)In, the mass fraction of ethyl alcohol is 90-95%.
Specifically, above-mentioned steps(3), the fountain height of paraffin removal liquid is 350-400ml/m2
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows:
The method of paraffin, easy to operate in a kind of quick removing dewatering box provided by the invention, environmentally protective, can effectively remove The paraffin adhered on dewatering box, noresidue do not interfere with reusing for dewatering box, in the application, paraffin removal liquid in sprinkling Afterwards, it can be completed the cleaning to dewatering box using 40-50 DEG C of warm water, energy conservation and environmental protection, meanwhile, the ingredient in paraffin removal liquid can It is scatter with the paraffin that will be disengaged from out so that paraffin will not condense into solid in sewer, avoid blocking sewer.Its In, step(1)In dissociation agent obtained, may make the active force between paraffin molecule drastically to decline, can effectively avoid paraffin There is a phenomenon where block in sewer;1,2- 1,2-diaminocyclohexane tetraacetic acids, D-ALPHA-Hydroxypropionic acid methyl esters, chloro-carbonic acid diethylene glycol (DEG) ester synergistic effect Afterwards, permeability of the dissociation agent inside solid paraffin can be effectively promoted, and then greatly improves the elimination effect of paraffin, and And to the paraffin at the dead angle position in dewatering box, equally there is good elimination effect, noresidue not to interfere with dewatering box It reuses.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following embodiment carries out the present invention It is further described.It should be appreciated that specific embodiment party example described herein is only used to explain the present invention, it is not used to limit The fixed present invention.
Embodiment 1
A kind of method of paraffin in quick removing dewatering box, including following operating procedure:
(1)By weight, it is according to mass ratio by in-situ polymerization nano hybridization silicone oil, methylpropene sodium sulfonate, deionized water 10:1:After mixing, using 28min is ultrasonically treated, dissociation agent is made in 20 ratio;
(2)By weight, 14 parts of 1,2-cyclohexanediaminetetraacetic acid, 3 parts of D-ALPHA-Hydroxypropionic acid methyl esters, 16 parts of chloro-carbonic acid diethylene glycol (DEG) esters are added Enter into 75 parts of ethyl alcohol, after being mixed evenly, then 8 parts of steps is added thereto(1)It is mixed to continue stirring for dissociation agent obtained After closing uniformly, paraffin removal liquid is made;
(3)Dewatering box is put into 40 DEG C of warm water, after immersion treatment 3min, takes out dewatering box, quickly exhausted dehydration with filter paper Then the moisture on box surface sprays paraffin removal liquid to dewatering box surface, after 5min, dewatering box is placed again into 40 DEG C of warm water In, after immersion treatment 10min, dewatering box is taken out, after being rinsed with water again, naturally dry, paraffin removal is completed in dewatering box.
Specifically, above-mentioned steps(1)In, the purity of in-situ polymerization nano hybridization silicone oil is 99.9%.
Specifically, above-mentioned steps(1)In, the frequency size of supersound process is 28kHz.
Specifically, above-mentioned steps(2)In, the mass fraction of ethyl alcohol is 90%.
Specifically, above-mentioned steps(3), the fountain height of paraffin removal liquid is 350ml/m2
Embodiment 2
A kind of method of paraffin in quick removing dewatering box, including following operating procedure:
(1)By weight, it is according to mass ratio by in-situ polymerization nano hybridization silicone oil, methylpropene sodium sulfonate, deionized water 13:1:After mixing, using 30min is ultrasonically treated, dissociation agent is made in 20 ratio;
(2)By weight, 17 parts of 1,2-cyclohexanediaminetetraacetic acid, 5 parts of D-ALPHA-Hydroxypropionic acid methyl esters, 18 parts of chloro-carbonic acid diethylene glycol (DEG) esters are added Enter into 80 parts of ethyl alcohol, after being mixed evenly, then 9 parts of steps is added thereto(1)It is mixed to continue stirring for dissociation agent obtained After closing uniformly, paraffin removal liquid is made;
(3)Dewatering box is put into 45 DEG C of warm water, after immersion treatment 4min, takes out dewatering box, quickly exhausted dehydration with filter paper Then the moisture on box surface sprays paraffin removal liquid to dewatering box surface, after 6min, dewatering box is placed again into 45 DEG C of warm water In, after immersion treatment 11min, dewatering box is taken out, after being rinsed with water again, naturally dry, paraffin removal is completed in dewatering box.
Specifically, above-mentioned steps(1)In, the purity of in-situ polymerization nano hybridization silicone oil is 99.9%.
Specifically, above-mentioned steps(1)In, the frequency size of supersound process is 29kHz.
Specifically, above-mentioned steps(2)In, the mass fraction of ethyl alcohol is 93%.
Specifically, above-mentioned steps(3), the fountain height of paraffin removal liquid is 380ml/m2
Embodiment 3
A kind of method of paraffin in quick removing dewatering box, including following operating procedure:
(1)By weight, it is according to mass ratio by in-situ polymerization nano hybridization silicone oil, methylpropene sodium sulfonate, deionized water 15:1:After mixing, using 32min is ultrasonically treated, dissociation agent is made in 20 ratio;
(2)By weight, 19 parts of 1,2-cyclohexanediaminetetraacetic acid, 6 parts of D-ALPHA-Hydroxypropionic acid methyl esters, 20 parts of chloro-carbonic acid diethylene glycol (DEG) esters are added Enter into 85 parts of ethyl alcohol, after being mixed evenly, then 10 parts of steps is added thereto(1)Dissociation agent obtained, continues to stir After mixing, paraffin removal liquid is made;
(3)Dewatering box is put into 50 DEG C of warm water, after immersion treatment 5min, takes out dewatering box, quickly exhausted dehydration with filter paper Then the moisture on box surface sprays paraffin removal liquid to dewatering box surface, after 7min, dewatering box is placed again into 50 DEG C of warm water In, after immersion treatment 12min, dewatering box is taken out, after being rinsed with water again, naturally dry, paraffin removal is completed in dewatering box.
Specifically, above-mentioned steps(1)In, the purity of in-situ polymerization nano hybridization silicone oil is 99.9%.
Specifically, above-mentioned steps(1)In, the frequency size of supersound process is 30kHz.
Specifically, above-mentioned steps(2)In, the mass fraction of ethyl alcohol is 95%.
Specifically, above-mentioned steps(3), the fountain height of paraffin removal liquid is 400ml/m2
Comparative example 1
Step(2)In, do not add step(1)Dissociation agent obtained, remaining operating procedure are identical with embodiment 1.
Same a batch, the identical dewatering box of paraffin pollution level are cleaned with the method for each embodiment and comparative example respectively Experiment, test result are as shown in table 1:
1 dewatering box paraffin removal effect of table
It should be understood that the application of the present invention is not limited to the above, for those of ordinary skills, Ke Yigen It is improved or converted according to above description, all these modifications and variations should all belong to the protection model of appended claims of the present invention It encloses.

Claims (5)

1. a kind of method of paraffin in quick removing dewatering box, which is characterized in that including following operating procedure:
(1)By weight, it is according to mass ratio by in-situ polymerization nano hybridization silicone oil, methylpropene sodium sulfonate, deionized water 10-15:1:After mixing, using 28-32min is ultrasonically treated, dissociation agent is made in 20 ratio;
(2)By weight, by 14-19 parts of 1,2-cyclohexanediaminetetraacetic acid, 3-6 parts of D-ALPHA-Hydroxypropionic acid methyl esters, 16-20 parts of chloro-carbonic acids two Glycol ester is added into 75-85 parts of ethyl alcohol, after being mixed evenly, then 8-10 parts of steps is added thereto(1)Solution obtained From agent, continue after being uniformly mixed, paraffin removal liquid is made;
(3)Dewatering box is put into 40-50 DEG C of warm water, after immersion treatment 3-5min, dewatering box is taken out, is quickly exhausted with filter paper Then the moisture on dewatering box surface sprays paraffin removal liquid to dewatering box surface, after 5-7min, dewatering box is placed again into 40- In 50 DEG C of warm water, after immersion treatment 10-12min, dewatering box is taken out, after being rinsed with water again, naturally dry, stone in dewatering box Wax, which is removed, to be completed.
2. the method for paraffin in a kind of quick removing dewatering box according to claim 1, which is characterized in that above-mentioned steps (1)In, the purity of in-situ polymerization nano hybridization silicone oil is 99.9%.
3. the method for paraffin in a kind of quick removing dewatering box according to claim 1, which is characterized in that above-mentioned steps (1)In, the frequency size of supersound process is 28-30kHz.
4. the method for paraffin in a kind of quick removing dewatering box according to claim 1, which is characterized in that above-mentioned steps (2)In, the mass fraction of ethyl alcohol is 90-95%.
5. the method for paraffin in a kind of quick removing dewatering box according to claim 1, which is characterized in that above-mentioned steps (3), the fountain height of paraffin removal liquid is 350-400ml/m2
CN201810357992.1A 2018-04-20 2018-04-20 Method for quickly removing paraffin in dehydration box Active CN108722981B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4089703A (en) * 1976-12-23 1978-05-16 White Chemical Company, Inc. Hot detergent process
JP2003313595A (en) * 2002-04-25 2003-11-06 Shinko Pantec Co Ltd Method for decontaminating organic halogen contaminant and decontamination system for the same
CN103614083A (en) * 2013-12-03 2014-03-05 沈阳化工大学 Automobile cleaning water wax and preparation method thereof
CN103980939A (en) * 2014-05-13 2014-08-13 山西兰花科技创业股份有限公司 Method of rapidly eliminating "wax precipitation" in alcoholization and alkylation systems
CN105419756A (en) * 2015-10-28 2016-03-23 中国石油化工股份有限公司 Wax removal and inhibition composition, water-soluble wax removal and inhibition agent and preparation method thereof
CN107144456A (en) * 2017-06-20 2017-09-08 广西壮族自治区肿瘤防治研究所 A kind of hydrogel support of paraffin pathological section tissue and lipid remove processing method
CN107429205A (en) * 2015-03-06 2017-12-01 弗洛泰克化学有限责任公司 Composition and method for clean surface and other application

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4089703A (en) * 1976-12-23 1978-05-16 White Chemical Company, Inc. Hot detergent process
JP2003313595A (en) * 2002-04-25 2003-11-06 Shinko Pantec Co Ltd Method for decontaminating organic halogen contaminant and decontamination system for the same
CN103614083A (en) * 2013-12-03 2014-03-05 沈阳化工大学 Automobile cleaning water wax and preparation method thereof
CN103980939A (en) * 2014-05-13 2014-08-13 山西兰花科技创业股份有限公司 Method of rapidly eliminating "wax precipitation" in alcoholization and alkylation systems
CN107429205A (en) * 2015-03-06 2017-12-01 弗洛泰克化学有限责任公司 Composition and method for clean surface and other application
CN105419756A (en) * 2015-10-28 2016-03-23 中国石油化工股份有限公司 Wax removal and inhibition composition, water-soluble wax removal and inhibition agent and preparation method thereof
CN107144456A (en) * 2017-06-20 2017-09-08 广西壮族自治区肿瘤防治研究所 A kind of hydrogel support of paraffin pathological section tissue and lipid remove processing method

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Effective date of registration: 20211221

Address after: Bengbu Medical College, 2600 Donghai Avenue, Longzihu District, Bengbu City, Anhui Province 233030

Patentee after: BENGBU MEDICAL College

Address before: 233000 Affiliated Hospital of Bengbu Medical College, Longzihu District, Bengbu City, Anhui Province

Patentee before: Zhu Qing