CN108719305A - Herbicidal combinations containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide - Google Patents
Herbicidal combinations containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide Download PDFInfo
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- CN108719305A CN108719305A CN201810568543.1A CN201810568543A CN108719305A CN 108719305 A CN108719305 A CN 108719305A CN 201810568543 A CN201810568543 A CN 201810568543A CN 108719305 A CN108719305 A CN 108719305A
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- Prior art keywords
- grass amine
- fluorine ketone
- sulfonylurea herbicide
- humulone
- sulphur
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
Abstract
The invention discloses a kind of Herbicidal combinations containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide, active ingredient is made of furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide, the weight ratio of the one kind of sulfonylurea herbicide in halosulfuronmethyl, pyrazosulfuron, orthosulfamuron, bensulfuron-methyl, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide three is 0.5~50:5:0.5~50.Herbicidal combinations provided by the invention are applied to preventing and kill off for paddy field weed, are used alone with each single dose or mutually significantly improve herbicidal effect compared with binary built use, expand herbicidal spectrum, the lasting period is long, to rice safety.
Description
Technical field
It is specifically a kind of with furans sulphur humulone, fluorine ketone sulphur grass the present invention relates to composition pesticide and its application field
Amine and the Herbicidal combinations that sulfonylurea herbicide is effective active composition ternary built, are mainly used in the anti-of paddy field weed
It removes.
Background technology
Furans sulphur humulone (tefuryltrione)：Belong to benzoylcyclohexan dione herbicides, the mechanism of action is 4- hydroxyls
Base phenylpyruvic acid dual oxide enzyme inhibitor, can inhibit pigment synthesis indispensable in plant growth, by root, stem, young shoot,
Leaf is absorbed and is conducted rapidly.Furans sulphur humulone can be used for rice terrace and prevent and kill off annual and perennial broadleaf weed, and before or after buds are equal
It can be used, it is broken to annual broadleaf weeds, the awns such as firefly Lin, Herba Cyperi Glomerati such as Monochoria vaginalis, Procumbent Falsepimpernel, Monochoria korsakowii, rhizoma alismatis, auricle water amaranths
Rice Cyperus weeds and the broad leaved weeds such as the short arrowhead of resistance, angustifolia arrowhead herb, water chestnut are generated to sulfonylurea in recent years has and extremely have
Effect.In addition, having to the paddy land weeds such as the special weeds such as triquetrousc murdannia herb, ambatch, sweet wine intestines, bur beggar-ticks, big bur beggar-ticks and fake rice, Rong's grass
Extensive preventive effect.
Fluorine ketone sulphur grass amine (triafamone)：Belong to sulfonamides herbicide, can lead to via plant root and Foliage Absorption
It crosses inhibition acetolactate synthase to work (ALS inhibitor), to rice terrace grassy weed barnyard grass, broad leaved weed Eclipta prostrata, cloves
Knotweed and sedge weed difformed galingale herb etc. have good preventive effect.
Sulfonylurea herbicide is a kind of herbicide that kind is most, application range is most wide in the world, with high activity, extensively
Spectrum, low dosage, low toxicity, it is highly selective the advantages that.Sulfonylurea herbicide passes through to the acetolactate synthestase in plant
Inhibit, to hinder branched-chain amino acid biosynthesis, inhibits the division and growth of plant cell.Halosulfuronmethyl
(halosulfuron-methyl), pyrazosulfuron (pyrazosulfuron-ethyl), orthosulfamuron
(orthosulfamuron), bensulfuron-methyl (bensulfuron-methyl), promazine Sulfometuron Methyl (propyrisulfuron), piperazine
Pyrazosulfuron (metazosulfuron) is the sulfonylurea herbicide being commercialized, and is widely used in the anti-of weeds in farmland
It removes.
The use of chemical agent weeding is agriculturally to control one of the main means of weeds in field.However in recent years, due to one
The large area of a little herbicide kinds is individually used continuously, and already leads to many weeds and produces drug resistance；Simultaneously as field is miscellaneous
Mutually complexity, type are various for grass when grass occurs, single if grassy weed, sedge weed and broad leaved weed often mix generation
Herbicide kind or two-spot be used in compounding and can not effectively solve the above problems, can show defect in a certain respect.
By the screening of a variety of different mixture of herbicides formulas, rational formula is filtered out, can be effectively improved to weeds
Practical control effect expands herbicide controlling spectrum, reduces dosage, reduces cost, mitigates the pollution to environment, delays herbicide resistance
It generates, extends the Pesticide use service life, be the important means of agriculturally weeds comprehensive treatment.
The present inventor is in further investigation furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide ternary built formula
In the process, surprisingly furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide carry out ternary built, certain
Compound proportion within the scope of significant collaboration is all had to a variety of grassy weeds, sedge weed and the broad leaved weed of rice terrace
Synergistic effect completes the present invention after further study.
Invention content
The purpose of the present invention is to provide a kind of component is reasonable, obvious synergy, herbicidal effect protrudes, herbicidal spectrum
Extensively, the lasting period is long, and drug cost is low, weeds can be delayed to develop immunity to drugs, and to the ternary built Herbicidal combinations of rice safety.
Another object of the present invention is to provide one kind to remove containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea
The preparation formulation of the Herbicidal combinations of careless agent.
It is still another object of the present invention to provide purposes of the above-mentioned Herbicidal combinations in preventing and kill off paddy field weed.
Technical scheme of the present invention：To achieve the above object, present invention offer is a kind of containing furans sulphur humulone and fluorine ketone sulphur
The Herbicidal combinations of careless amine and sulfonylurea herbicide, effective active composition is by furans sulphur humulone, fluorine ketone sulphur grass amine and sulphonyl
Carbamide herbicides form, and sulfonylurea herbicide is selected from halosulfuronmethyl, pyrazosulfuron, orthosulfamuron, bensulfuron-methyl, promazine
The weight ratio of one kind in Sulfometuron Methyl, piperazine pyrazosulfuron, furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide is 0.5
~50:5:0.5~50, the preferably weight ratio of furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide is 1~25:5:1~
25。
In Herbicidal combinations of the present invention, furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide are in the composition
Total weight percentage composition is 0.1%~85%, and preferably furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide are in composition
In total weight percentage composition be 1%~75%.
Herbicidal combinations of the present invention can be prepared into any application forms used in suitable agricultural production, relatively good agent
Type has aqueous suspension agent, dispersible oil-suspending agent, missible oil, water dispersible granules, wettable powder, granule etc..
Further include in pesticide other than effective active composition in various application forms prepared by Herbicidal combinations of the present invention
Allow to use and the various auxiliary elements of acceptable.
The auxiliary element includes but not limited to：It is solvent, emulsifier, wetting agent, dispersant, thickener, antifoaming agent, antifreeze
Agent, preservative, stabilizer, binder, disintegrant, solid carrier, liquid-carrier, deionized water etc..
Solvent wherein in auxiliary element includes but not limited to：Toluene, dimethylbenzene, trimethylbenzene, solvent naphtha S-150, solvent
Oily S-180, solvent naphtha S-200, ethyl alcohol, isopropanol, n-butanol, n-octyl alcohol, n-amyl alcohol, acetone, cyclohexanone, hexane, dimethyl
Formamide, N-Methyl pyrrolidone, acetonitrile, dichloromethane, ethyl acetate, methyl oleate, dibutyl phthalate, acetic acid are secondary
One or more kinds of a mixture of arbitrary proportions in butyl ester.
Emulsifier wherein in auxiliary element includes but not limited to：Calcium dodecyl benzene sulfonate, aliphatic acid polyethenoxy ether,
APES sulfosuccinate, styrylphenol polyoxyethylene ether, nonylphenol polyoxyethylene ether, castor oil are poly-
One or more in ethylene oxide ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether are arbitrarily more mixed than composition
Close object.
Wetting agent wherein in auxiliary element includes but not limited to：Lauryl sodium sulfate, neopelex, fourth
One kind in base sodium naphthalene sulfonate, sodium alkyl sulfonate, tea seed cake powder, spaonin powder, spaonin powder, condensed phosphate, sulfate, phosphate
Or more than one a mixture of arbitrary proportions.
Dispersant wherein in auxiliary element includes but not limited to：APES formaldehyde condensation product, naphthalene sulfonic acids
Salt formaldehyde condensation products, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, lignosulfonates, polycarboxylate, alkylphenol-polyethenoxy
Ether sulfate, alkyl benzene sulfonate calcium salt, aliphatic ester sulfate, alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, polyoxy
One or more kinds of a mixture of arbitrary proportions in ethylene polyoxypropylene base ether block copolymers.
Thickener wherein in auxiliary element includes but not limited to：Polyvinyl acetate, xanthans, gelatin, Arabic tree
One or more in glue, aluminium-magnesium silicate, phenolic resin, hydroxymethyl cellulose, sodium alginate are arbitrarily than the mixing of composition
Object.
Antifoaming agent wherein in auxiliary element includes but not limited to：Silicone oil, silicone compound, C10-20Saturated fat acids
Compound, C8-10One or more kinds of a mixture of arbitrary proportions in aliphatic alcohols, hexanol, butanol, octanol.
Antifreezing agent wherein in auxiliary element includes but not limited to：In ethylene glycol, propylene glycol, glycerine, urea, sodium chloride
One or more kinds of a mixture of arbitrary proportions.
Preservative wherein in auxiliary element includes but not limited to：Formaldehyde, benzoic acid, sodium benzoate, potassium sorbate, different thiophene
One or more kinds of a mixture of arbitrary proportions in oxazoline ketone.
Stabilizer wherein in auxiliary element includes but not limited to：Epoxidized soybean oil, triphenyl phosphite, epoxy chloropropionate
One or more kinds of a mixture of arbitrary proportions in alkane, sodium citrate, resorcinol.
Binder wherein in auxiliary element includes but not limited to：Sucrose, polyvinyl alcohol, polyethylene glycol, carboxymethyl cellulose
Plain sodium, calcium carboxymethylcellulose, carboxy-propyl cellulose, dextrin, amylodextrin, polyvinylpyrrolidone, sticky kaolin, stone
One or more kinds of a mixture of arbitrary proportions in wax, rosin.
Disintegrant wherein in auxiliary element includes but not limited to：Sodium carboxymethyl starch, low-substituted hydroxypropyl cellulose, friendship
Join sodium carboxymethylcellulose, crospovidone, chitosan, sodium alginate sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urine
One or more kinds of a mixture of arbitrary proportions in element, ammonium sulfate, bentonite.
Solid carrier wherein in auxiliary element includes but not limited to：It is precipitated calcium carbonate, clay, kaolin, diatomite, swollen
Moisten the one or more in soil, white carbon, clay, attapulgite, talcum powder, quartz sand, sepiolite arbitrarily than composition
Mixture.
Liquid-carrier wherein in auxiliary element includes but not limited to：Exquisite soybean oil, corn oil, rapeseed oil, turpentine oil,
One or more kinds of a mixture of arbitrary proportions in methyl oleate, coconut oil, palm oil, peanut oil, sunflower oil.
Deionized water wherein in auxiliary element is industrialization deionized water.
The production technology of the various application forms of Herbicidal combinations belongs to existing known technology, and details are not described herein.
Compared with the prior art, the advantages of the present invention are as follows：
1, furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide ternary built have significant synergistic work
With compared with the exclusive use of each single dose or mutually binary built expands weeding using the control effect significantly improved to weeds
Spectrum.
2, furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide ternary built, the mechanism of action is different, effect
Site increases, and can delay the generation of herbicide resistance, extends the Pesticide use service life.
3, furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide ternary built, reduce the effective usage amount of pesticide,
It reduces use cost, alleviate the pollution to environment.
Specific implementation mode
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention cannot be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of that invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
The content of each substance is weight percentage in following all embodiments.
Embodiment 1：33% furans sulphur humulone fluorine ketone sulphur grass amine halosulfuronmethyl aqueous suspension agent
Furans sulphur humulone 15%, fluorine ketone sulphur grass amine 3%, halosulfuronmethyl 15%, alkyl phenol polyoxyethylene ether formaldehyde condensation
Object 12%, sodium alginate 3%, potassium sorbate 0.5%, silicone compound 0.1%, ethylene glycol 2.5%, deionized water complements to
100%.Above-mentioned material is mixed in proportion, be uniformly dispersed through high speed shear, in sand mill be sanded after, you can be made 33% furans
Sulphur humulone fluorine ketone sulphur grass amine halosulfuronmethyl aqueous suspension agent.
Halosulfuronmethyl is substituted for pyrazosulfuron, orthosulfamuron, bensulfuron-methyl, promazine Sulfometuron Methyl, piperazine pyrazosulfuron
In a kind of can form new aqueous suspension agent example of formulations.
Embodiment 2：The 30.5% dispersible oil-suspending agent of furans sulphur humulone fluorine ketone sulphur metazachlor Sulfometuron Methyl
Furans sulphur humulone 25%, fluorine ketone sulphur grass amine 5%, pyrazosulfuron 0.5%, aliphatic ester sulfate 15%, castor oil
Polyoxyethylene ether 10%, aluminium-magnesium silicate 2%, turpentine oil complements to 100%.Above-mentioned material is mixed in proportion, through high speed shear
Be uniformly dispersed, in sand mill be sanded after, you can be made 30.5% furans sulphur humulone fluorine ketone sulphur metazachlor Sulfometuron Methyl it is dispersible
Oil-suspending agent.
Pyrazosulfuron is substituted for halosulfuronmethyl, orthosulfamuron, bensulfuron-methyl, promazine Sulfometuron Methyl, piperazine pyrazosulfuron
In a kind of can form new dispersible oil-suspending agent example of formulations.
Embodiment 3：61% furans sulphur humulone fluorine ketone sulphur grass amine orthosulfamuron water dispersible granules
Furans sulphur humulone 1%, fluorine ketone sulphur grass amine 10%, orthosulfamuron 50%, polycarboxylate 13%, spaonin powder 8%,
Sodium chloride 6%, kaolin complements to 100%.Above-mentioned material is mixed in proportion, kneading granulation uniformly mixed through air-flow crushing,
After dry screening, you can 61% furans sulphur humulone fluorine ketone sulphur grass amine orthosulfamuron water dispersible granules are made.
Orthosulfamuron is substituted for halosulfuronmethyl, pyrazosulfuron, bensulfuron-methyl, promazine Sulfometuron Methyl, piperazine pyrazosulfuron
In a kind of can form new water dispersible granules example of formulations.
Embodiment 4：72% furans sulphur humulone fluorine ketone sulphur grass amine bensulfuron-methyl wettable powder
Furans sulphur humulone 45%, fluorine ketone sulphur grass amine 4.5%, bensulfuron-methyl 22.5%, tea seed cake powder 8%, fatty alcohol polyoxy second
Alkene ether 7%, white carbon 5%, kaolin complements to 100%.Above-mentioned material is mixed in proportion, again through air-flow powder after mechanical crushing
It is broken after mixing, you can be made 72% furans sulphur humulone fluorine ketone sulphur grass amine bensulfuron-methyl wettable powder.
Bensulfuron-methyl is substituted for halosulfuronmethyl, pyrazosulfuron, orthosulfamuron, promazine Sulfometuron Methyl, piperazine pyrazosulfuron
In a kind of can form new wettable powder formulation embodiment.
Embodiment 5：21% furans sulphur humulone fluorine ketone sulphur grass amine promazine Sulfometuron Methyl missible oil
Furans sulphur humulone 10%, fluorine ketone sulphur grass amine 1%, promazine Sulfometuron Methyl 10%, styrylphenol polyoxyethylene ether
15%, N-Methyl pyrrolidone 15%, ethyl alcohol 5%, dimethylbenzene complements to 100%.Above-mentioned material is mixed in proportion, through dissolving
After stirring evenly, you can 21% furans sulphur humulone fluorine ketone sulphur grass amine promazine Sulfometuron Methyl missible oil is made.
Promazine Sulfometuron Methyl is substituted for halosulfuronmethyl, pyrazosulfuron, orthosulfamuron, bensulfuron-methyl, piperazine pyrazosulfuron
In a kind of can form new cream preparation embodiment.
Embodiment 6：8% furans sulphur humulone fluorine ketone sulphur grass amine piperazine pyrazosulfuron granule
Furans sulphur humulone 2.5%, fluorine ketone sulphur grass amine 0.5%, piperazine pyrazosulfuron 5%, alkyl benzene sulfonate calcium salt 12%, 12
Sodium alkyl sulfate 8%, calcium carboxymethylcellulose 5%, sepiolite complements to 100%.Above-mentioned material is mixed in proportion, uses ultra micro
Air-flow crushing is uniformly mixed, and then adds water to pelletize in granulating disc, after the survey of dry sieve sorting, you can 8% furans sulphur is made
Humulone fluorine ketone sulphur grass amine piperazine pyrazosulfuron granule.
Piperazine pyrazosulfuron is substituted for halosulfuronmethyl, pyrazosulfuron, orthosulfamuron, bensulfuron-methyl, promazine Sulfometuron Methyl
In a kind of can form new granular preparation embodiment.
Embodiment 7：Indoor biological determination of activity embodiment
Test method：With reference to《Farm-chemical indoor determination test rule herbicide NY/T1155.5-2006》, using pouring
Method.It is 0.01m in area2The built-in quantitative soil of basin alms bowl to the 3/4 of basin alms bowl at, then from the top of basin alms bowl pour, keep soil complete
It is complete to moisten to saturation state.It will uniformly sowing be big according to seed in basin alms bowl soil surface for 15~20, target weeds seed of examination
It is placed in greenhouse and cultivates after the fine earth of 0.5~2cm of tegillum.After for 24 hours, irrigation liquid 10ml is quantitatively poured per basin alms bowl, often handles 4 weights
It is multiple, and the processing without medicament is set as control, examination material, which is placed in greenhouse, after processing cultivates, the growth feelings of routine observation target weeds
Condition manages basin alms bowl and remains 1~2cm water layers everywhere during experiment.Target damage symptoms and growth inhibition situation are estimated after 21d,
And claim aerial part fresh weight, and claim aerial part fresh weight, calculate fresh weight preventive effect (%).
Evaluation to the mixed synergistic effect for applying middle display of three kinds of herbicidal active components is based in " Calculating
Synergistic and Antagonistic Responses of Herbicide combinations”(Weeds 15/1
(1967), S.R.Colby) described in Colby ' s methods determine, as follows：
In formula：
A be when using the reactive compound A that dosage is mg/ha or a concentration of mppm, survival rate to target weeds or
Fresh weight survival rate (%)；
B be when using the reactive compound B that dosage is ng/ha or a concentration of nppm, survival rate to target weeds or
Fresh weight survival rate (%)；
C be when using the reactive compound C that dosage is hg/ha or a concentration of hppm, survival rate to target weeds or
Fresh weight survival rate (%)；
N is the herbicidal active component kind number of mixture；
E0It is to work as to use dosage for m, it is right when the reactive compound A, B and C of n, hg/ha or a concentration of m, n, hppm are mixed
The theoretical value of target weeds survival rate or fresh weight survival rate (%)；
It is m that E, which is when using dosage, when the reactive compound A, B and C of n, hg/ha or a concentration of m, n, hppm are mixed, to target
Mark weeds survival rate or the observation of fresh weight survival rate (%)；
If the target weeds survival rate or fresh weight survival rate of actual observation are less than theoretical target weeds survival rate or fresh weight
Survival rate has the effect of unexpected then the composition shows to act synergistically.
1, the Toxicity Determination of furans sulphur humulone, fluorine ketone sulphur grass amine and halosulfuronmethyl ternary built to barnyard grass
The The Toxicity Determination result of 1 furans sulphur humulone of table, fluorine ketone sulphur grass amine and halosulfuronmethyl ternary built to barnyard grass
Furans sulphur humulone, fluorine ketone sulphur grass amine and halosulfuronmethyl exist it can be seen from the The Toxicity Determination result of table 1
0.5~50:5:When being compounded in the range of 0.5~50 (by weight), the observation of fresh weight survival rate is significantly less than theoretical value, says
It is bright that significant synergistic function is shown to barnyard grass.
The present inventor further carries out experiment and finds, changes halosulfuronmethyl into pyrazosulfuron, orthosulfamuron, benzyl phonetic sulphur
One kind in grand, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, 0.5~50:5:When being compounded in the range of 0.5~50 (by weight), together
Sample shows synergistic function to barnyard grass.
2, the Toxicity Determination of furans sulphur humulone, fluorine ketone sulphur grass amine and pyrazosulfuron ternary built to lady's-grass
The The Toxicity Determination result of 2 furans sulphur humulone of table, fluorine ketone sulphur grass amine and pyrazosulfuron ternary built to lady's-grass
Furans sulphur humulone, fluorine ketone sulphur grass amine and pyrazosulfuron are 0.5 it can be seen from the The Toxicity Determination result of table 2
~50:5:When being compounded in the range of 0.5~50 (by weight), the observation of fresh weight survival rate is significantly less than theoretical value, explanation
Significant synergistic function is shown to lady's-grass.
The present inventor further carries out experiment and finds, changes pyrazosulfuron into halosulfuronmethyl, orthosulfamuron, benzyl phonetic sulphur
One kind in grand, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, 0.5~50:5:When being compounded in the range of 0.5~50 (by weight), together
Sample shows synergistic function to lady's-grass.
3, the Toxicity Determination of furans sulphur humulone, fluorine ketone sulphur grass amine and orthosulfamuron ternary built to firefly Lin
The The Toxicity Determination result of 3 furans sulphur humulone of table, fluorine ketone sulphur grass amine and orthosulfamuron ternary built to firefly Lin
Furans sulphur humulone, fluorine ketone sulphur grass amine and orthosulfamuron exist it can be seen from the The Toxicity Determination result of table 3
0.5~50:5:When being compounded in the range of 0.5~50 (by weight), the observation of fresh weight survival rate is significantly less than theoretical value, says
It is bright that significant synergistic function is shown to firefly Lin.
The present inventor further carries out experiment and finds, changes orthosulfamuron into halosulfuronmethyl, pyrazosulfuron, benzyl phonetic sulphur
One kind in grand, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, 0.5~50:5:When being compounded in the range of 0.5~50 (by weight), together
Sample shows synergistic function to firefly Lin.
4, the Toxicity Determination of furans sulphur humulone, fluorine ketone sulphur grass amine and bensulfuron-methyl ternary built to difformed galingale herb
The Toxicity Determination knot of 4 furans sulphur humulone of table, fluorine ketone sulphur grass amine and bensulfuron-methyl ternary built to difformed galingale herb
Fruit
Furans sulphur humulone, fluorine ketone sulphur grass amine and bensulfuron-methyl are 0.5 it can be seen from the The Toxicity Determination result of table 4
~50:5:When being compounded in the range of 0.5~50 (by weight), the observation of fresh weight survival rate is significantly less than theoretical value, explanation
Significant synergistic function is shown to difformed galingale herb.
The present inventor further carries out experiment and finds, changes bensulfuron-methyl into halosulfuronmethyl, pyrazosulfuron, phonetic aniline sulphur
One kind in grand, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, 0.5~50:5:When being compounded in the range of 0.5~50 (by weight), together
Sample shows synergistic function to difformed galingale herb.
5, the Toxicity Determination of furans sulphur humulone, fluorine ketone sulphur grass amine and promazine Sulfometuron Methyl ternary built to Monochoria vaginalis
The The Toxicity Determination result of 5 furans sulphur humulone of table, fluorine ketone sulphur grass amine and promazine Sulfometuron Methyl ternary built to Monochoria vaginalis
Furans sulphur humulone, fluorine ketone sulphur grass amine and promazine Sulfometuron Methyl exist it can be seen from the The Toxicity Determination result of table 5
0.5~50:5:When being compounded in the range of 0.5~50 (by weight), the observation of fresh weight survival rate is significantly less than theoretical value, says
It is bright that significant synergistic function is shown to Monochoria vaginalis.
The present inventor further carries out experiment and finds, changes promazine Sulfometuron Methyl into halosulfuronmethyl, pyrazosulfuron, phonetic aniline
Sulphur is grand, one kind in bensulfuron-methyl, piperazine pyrazosulfuron, 0.5~50:5:When being compounded in the range of 0.5~50 (by weight), together
Sample shows synergistic function to Monochoria vaginalis.
6, the Toxicity Determination of furans sulphur humulone, fluorine ketone sulphur grass amine and piperazine pyrazosulfuron ternary built to short arrowhead
The Toxicity Determination knot of 6 furans sulphur humulone of table, fluorine ketone sulphur grass amine and piperazine pyrazosulfuron ternary built to short arrowhead
Fruit
Furans sulphur humulone, fluorine ketone sulphur grass amine and piperazine pyrazosulfuron exist it can be seen from the The Toxicity Determination result of table 6
0.5~50:5:When being compounded in the range of 0.5~50 (by weight), the observation of fresh weight survival rate is significantly less than theoretical value, says
It is bright that significant synergistic function is shown to short arrowhead.
The present inventor further carries out experiment and finds, changes piperazine pyrazosulfuron into halosulfuronmethyl, pyrazosulfuron, phonetic aniline
Sulphur is grand, one kind in bensulfuron-methyl, promazine Sulfometuron Methyl, 0.5~50:5:When being compounded in the range of 0.5~50 (by weight), together
Sample shows synergistic function to short arrowhead.
Embodiment 8：Crop field drug effect verification
Experimental field more rice terrace progress occurs for selection weeds, often handles and sets 3 repetitions, and 30d observations are each after medicine after medicine
A situation arises and calculates preventive effect for treatment region weeds.
7 each chemicals treatment of table prevents and kill off the field control effectiveness test result of paddy field weed
30d each example composition preparations provided by the invention are right after medicine it can be seen from the field test results of table 7
The weeds such as barnyard grass, lady's-grass, difformed galingale herb, firefly Lin, Monochoria vaginalis, the short arrowhead of rice terrace have good control effect, average anti-
Effect is not found during pilot survey using after each example composition preparation provided by the invention up to 85% or more
Poisoning is generated to rice.
In conclusion one kind provided by the invention contains furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide
Herbicidal combinations, obvious synergy, compared to each single dose be used alone or mutually binary built use expand weeding
Spectrum, improves preventive effect, can effectively prevent and kill off a variety of weeds such as rice terrace grassy weed, sedge weed and broad leaved weed, holding effect
Phase is long, to rice safety, is worth promoting and applying in agricultural production.
Claims (6)
1. a kind of Herbicidal combinations containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide, feature exist
In：Active ingredient is made of furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide, furans sulphur humulone, fluorine ketone sulphur grass amine
Weight ratio with three kinds of active ingredient of sulfonylurea herbicide is 0.5~50:5:0.5~50, furans sulphur humulone, fluorine ketone sulphur grass amine
It is 5%~95% with the weight percent of the weight summation of three kinds of active ingredients of sulfonylurea herbicide in the composition.
2. a kind of removing containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide according to claim 1
Careless composition, it is characterised in that：The sulfonylurea herbicide is selected from halosulfuronmethyl, pyrazosulfuron, orthosulfamuron, benzyl
One kind in Sulfometuron Methyl, promazine Sulfometuron Methyl, piperazine pyrazosulfuron.
3. a kind of removing containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide according to claim 1
Careless composition, it is characterised in that：The weight ratio of three kinds of furans sulphur humulone, fluorine ketone sulphur grass amine and sulfonylurea herbicide active ingredient
For weight ratio be 1~25:5:1~25.
4. a kind of removing containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide according to claim 1
Careless composition, it is characterised in that：The Herbicidal combinations also contain pesticidal preparations auxiliary element, make so that suitable agricultural is made
Application forms.
5. a kind of removing containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide according to claim 1
Careless composition, it is characterised in that：The dosage form of the Herbicidal combinations is aqueous suspension agent, dispersible oil-suspending agent, missible oil, water-dispersed
One kind in granula, wettable powder, granule.
6. a kind of weeding group containing furans sulphur humulone and fluorine ketone sulphur grass amine and sulfonylurea herbicide described in claim 1
Close purposes of the object in preventing and kill off paddy field weed.
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