CN104522026B - Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen - Google Patents

Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen Download PDF

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Publication number
CN104522026B
CN104522026B CN201410823081.5A CN201410823081A CN104522026B CN 104522026 B CN104522026 B CN 104522026B CN 201410823081 A CN201410823081 A CN 201410823081A CN 104522026 B CN104522026 B CN 104522026B
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oxyfluorfen
sulfometuron methyl
promazine sulfometuron
herbicidal combinations
combinations containing
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CN104522026A (en
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王礼文
陈佛祥
张志伟
朱刚
吴泽伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Abstract

The invention discloses a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen, it includes active ingredient promazine Sulfometuron Methyl and Oxyfluorfen, and remaining is insecticides adjuvant, and the ratio of weight and number of promazine Sulfometuron Methyl and Oxyfluorfen is 10:1~1:10, the mass percent of promazine Sulfometuron Methyl and Oxyfluorfen weight summation in the composition is 1%~80%.According to using needs, the present invention can be prepared into one kind in suspending agent, oil-suspending agent, water dispersible granules, wettable powder, for preventing and kill off rice terrace annual grassy weeds.The rice terrace annual grassy weeds positive effect of preventing and kill off of said composition is better than each single dose, reduces dosage, delays herbicide resistance.

Description

Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen
Technical field
It is with promazine Sulfometuron Methyl the present invention relates to a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen It is active ingredient with Oxyfluorfen, for preventing and kill off paddy field weed, especially with Paspalum distichum (Paspalum Paspaloides), rhizoma alismatis (Alisma plantago-aquatica), short arrowhead (Sagittaria pygmaea) are advantage The rice terrace annual grassy weeds of weeds.
Background technology
Promazine Sulfometuron Methyl (Propyrisulfuron), it is a kind of selective broad-spectrum herbicide, to resistance to sulfonylurea herbicide The weeds of agent have preferable preventive effect, effective to above the average age for marriage barnyard grass, nutgrass flatsedge, broadleaved herb, can foliar spray, get rid of and apply.
Oxyfluorfen (Oxyfluorfen), it is contact killing type herbicide.Its activity of weeding is played in the case where there is light. Mainly entered by plumule, mesocotyl in plant, it is less through root absorption, and there is denier to be transported up by root Into leaf portion, for before cotton, round onions, peanut, soybean, beet, fruit tree and vegetable fields bud, applied after bud and prevent and kill off barnyard grass, field Cyanines, downy brome, green bristlegrass, datura, quackgrass, artemisiifolia, thorn chrysanthemum sth. made by twisting, piemarker, charlock unifacial leaf and broad leaved weed.
The present inventor has made intensive studies to promazine Sulfometuron Methyl, Oxyfluorfen mixture, finds promazine Sulfometuron Methyl, second Oxygen AKH7088 mixture has Synergistic response to rice terrace annual grassy weeds, especially to Paspalum distichum (Paspalum Paspaloides, PASPA), rhizoma alismatis (Alisma plantago-aquatica, ALIPL), short arrowhead (Sagittaria Pygmaea, SAGPY) there is the response of significant Synergistic, after further study, complete the present invention.
It is an object of the invention to solve developed immunity to drugs in the prior art to farmland weed problem and actual prevention effect It is poor, there is provided a kind of efficient, low toxicity, quick-acting are good and the lasting period is grown, and are advantageous to the Herbicidal combination of the farmland weed comprehensive regulation Thing.
It is another object of the present invention to be used to the Herbicidal combinations prevent and kill off paddy field weed, especially with Paspalum distichum (Paspalum paspaloides), lady's-grass (Digitaria sanguinalis), bent grass (Agrostis Matsumurae it is) the rice terrace annual grassy weeds of dominant weed.
Technical scheme:To achieve the above object, the invention provides a kind of containing promazine Sulfometuron Methyl and Oxyfluorfen Herbicidal combinations, it includes the weight of active ingredient promazine Sulfometuron Methyl and Oxyfluorfen, promazine Sulfometuron Methyl and Oxyfluorfen Portion rate is 10:1~1:10, the percentage by weight of promazine Sulfometuron Methyl and Oxyfluorfen weight summation in the composition be 1~ 80%, remaining is agriculturally acceptable insecticides adjuvant.
Herbicidal combinations those skilled in the art of the present invention can be auxiliary from suitable pesticidal preparations according to known methods Co-ingredients, the formulation that suspending agent, oil-suspending agent, water dispersible granules, wettable powder etc. are agriculturally commonly used is made.
The auxiliary agent used in Herbicidal combinations provided by the invention includes solvent, emulsifying agent, wetting agent, stabilizer, scattered Agent, safener, thickener, pH adjusting agent, defoamer, antifreezing agent, deionized water, filler etc., all it is normal in Pesticide formulation Various auxiliary agents, specific composition and dosage are determined according to recipe requirements by simple experiment.
The production technology of the various application forms of Herbicidal combinations provided by the invention belongs to existing known technology, herein not Repeat again.
The frequency of administration and amount of application of the present composition change with crops, weeds, weather condition and have small quantitative change Change, the purpose effectively prevented and treated can be reached by using appropriate dosage.
Herbicidal combinations provided by the invention have the advantages that:
1st, Herbicidal combinations provided by the invention, obvious synergistic effect, composition are shown in certain ratio range Prevention effect be significantly improved than single dose, reduce the dosage of agricultural chemicals, reduce times for spraying, reduce medication Cost, reduce adverse effect of the agricultural chemicals to ecological environment.
2nd, Herbicidal combinations provided by the invention, the combination of two kinds of active ingredient expand herbicidal spectrum, and a drug is Can solve weed problem, compensate for single dose use when the defects of and limitation.
3rd, Herbicidal combinations provided by the invention, two kinds of active ingredient mechanism of action are different, can overcome long-term list One uses the shortcomings that easily producing resistance, extends the service life of medicament, and the comprehensive regulation to Weed Resistance has important meaning Justice.
4th, Herbicidal combinations provided by the invention, drug effect play rapidly, and lasting period length, use cost is low, easy to use, Time saving and energy saving, its popularization and application has huge economic benefit and social benefit.
Embodiment
In order that the objects, technical solutions and advantages of the present invention are more concise, present invention specific examples below Illustrate, but the present invention is only limitted to absolutely not these examples.As described below is only the preferable embodiment of the present invention, is used only for The description present invention, it is impossible to be interpreted as limiting the scope of the present invention.It is it should be pointed out that all in the spiritual and former of the present invention All any modification, equivalent and improvement done within then etc., should be included in the scope of the protection.
Assays Example 1:Promazine Sulfometuron Methyl, Oxyfluorfen and its compounding are to Paspalum distichum (Paspalum Paspaloides, PASPA), rhizoma alismatis (Alisma plantago-aquatica, ALIPL), short arrowhead (Sagittaria Pygmaea, SAGPY) interior virulence determination test
Herbicide associated form (NY/T 1155.7-2006) is evaluated according to Gowing methods, its formula is as follows:
In formula:
X be promazine Sulfometuron Methyl with certain dosage when alone to the fresh weight inhibition of target weeds;
Y be Oxyfluorfen with certain dosage when alone to the fresh weight inhibition of target weeds;
E0For two kinds of promazine Sulfometuron Methyl, Oxyfluorfen pharmacy mix when to the theoretical value of target weeds fresh weight inhibition Or desired value;
It is the reality of control to target weeds fresh weight inhibition when E is two kinds of promazine Sulfometuron Methyl, Oxyfluorfen pharmacy mix Measured value or observation.
Evaluation criterion:As E ﹣ E0During > 10%, synergistic function is expressed as;As ﹣ 10%≤E ﹣ E0When≤10%, performance To cooperate with summation action;As E ﹣ E0During < ﹣ 10%, joint action of antagonism is shown as.
After table 1, medicine 15 days promazine Sulfometuron Methyls, Oxyfluorfen and its compounding to 3 leaf phase PASPA, ALIPL in greenhouse, SAGPY control data
Herbicide associated form is evaluated according to Gowing methods, the data of table 1 are shown, promazine Sulfometuron Methyl, Oxyfluorfen binary Combination is to Paspalum distichum(Paspalum paspaloides, PASPA), rhizoma alismatis(Alisma plantago-aquatica, ALIPL), short arrowhead(Sagittaria pygmaea, SAGPY)Synergistic effect is notable, and E- E0 values are all higher than 20%.
Example of formulations 1:40% promazine Sulfometuron Methyl Oxyfluorfen water dispersible granules.
Above-mentioned material is added in cone-type mixer together and is well mixed, is crushed by airslide disintegrating mill, the thing after crushing Material is mixed through cone-type mixer again, and mixed fineness of materials 98% is added in kneader and is kneaded into by 600 mesh standard sieves Plasticity material, this material is finally put into extruder grain in Squeezinggranulator, be made after drying, screening after granulation 40% promazine Sulfometuron Methyl Oxyfluorfen water dispersible granules.
Example of formulations 2:30% promazine Sulfometuron Methyl Oxyfluorfen wettable powder).
Above-mentioned material is added in cone-type mixer together and is well mixed, is crushed by airslide disintegrating mill, the thing after crushing Material mixes through cone-type mixer again, and mixed fineness of materials 98% produces the phonetic sulphur of 30% promazine by 600 mesh standard sieves Grand Oxyfluorfen wettable powder.
Example of formulations 3:35% promazine Sulfometuron Methyl Oxyfluorfen suspending agent.
Above-mentioned formula is crushed in advance in proportion, adds in sand mill and grinds, system is allocated after high shear mixing Obtain the promazine Sulfometuron Methyl Oxyfluorfen suspending agent of corresponding percentage by weight.
Example of formulations 4:25% promazine Sulfometuron Methyl Oxyfluorfen oil-suspending agent.
Above-mentioned material (except organobentonite) is added in reactor mixer together, stirred 2 hours, opens kettle Bottom pan feeding valve, material is injected in multistage sand mill and ground, and the fineness of materials 98% after grinding after 1-5um by discharging, material It is put into again with together with the organobentonite dissolved in advance in high-shear emulsifying kettle, is that can be made into flowing to property well after emulsification 25% promazine Sulfometuron Methyl Oxyfluorfen oil-suspending agent.
Assays Example 2:Promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition prevent and kill off transplant field rice 1 year Raw weeds field control effectiveness test.
Test site is located at Liaoning Province Panjin City Panshan County peace town transplant field rice annual grassy weeds and includes but not only limit In Paspalum distichum (Paspalum paspaloides, PASPA), barnyard grass (Echinochloa crusgalli, ECHCR), short kind Aunt (Sagittaria pygmaea, SAGPY), rhizoma alismatis (Alisma plantago-aquatica, ALIPL).
Table 2, promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition are to peaceful town transplanted rice field annual grassy weeds field Between test of pesticide effectiveness result
Assays Example 3:Promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition prevent and kill off rice seedling throwing Tian Yinian Raw weeds field control effectiveness test.
Test site is located at Zhong Kai areas of Huizhou City Chen Jiang towns, and rice seedling throwing field annual grassy weeds includes but are not limited to Lee Family name's standing grain (Leersia hexandra, LEEHE), Paspalum distichum (Paspalum paspaloides, PASPA), moleplant seed (Leptochloa chinensis, LEPCH), Herba Cyperi Glomerati (Juncellus serotinus, JUNSE).
Table 3, promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition are to Chen Jiang towns seedling throwing field annual grassy weeds field medicine Imitate result of the test
As can be seen from the test results:The Herbicidal combinations of the present invention can effectively prevent and kill off rice terrace annual grassy weeds, expand Herbicide controlling spectrum, synergistic effect are notable.Each medicament is showed no generation poisoning during experiment, to rice safety.

Claims (3)

  1. A kind of 1. Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen, it is characterised in that:Active ingredient is that promazine is phonetic Sulphur is grand and Oxyfluorfen, and the ratio of weight and number of promazine Sulfometuron Methyl and Oxyfluorfen is 10:1~1:10, promazine Sulfometuron Methyl and The percentage by weight of Oxyfluorfen weight summation in the composition is 1~80%.
  2. 2. a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen according to claim 1, its feature exist In:The formulation of the Herbicidal combinations is one kind in suspending agent, oil-suspending agent, water dispersible granules, wettable powder.
  3. 3. a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen described in claim 1 are preventing and kill off rice terrace one Application in year raw weeds Paspalum distichum, rhizoma alismatis, short arrowhead.
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Families Citing this family (5)

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Publication number Priority date Publication date Assignee Title
CN104824000A (en) * 2015-05-13 2015-08-12 广东中迅农科股份有限公司 Weeding composition containing propyrisulfuron, mefenacet and oxyfluorfen
CN105052970A (en) * 2015-07-29 2015-11-18 北京燕化永乐生物科技股份有限公司 Herbicidal composition
CN105724405B (en) * 2016-03-14 2018-07-17 南京华洲药业有限公司 A kind of Herbicidal combinations and its application containing trifloxysulfuron and Oxyfluorfen
CN108235992A (en) * 2016-12-27 2018-07-03 江苏龙灯化学有限公司 A kind of Herbicidal combinations and its application
CN116746586A (en) * 2023-07-03 2023-09-15 黑龙江省农业科学院植物保护研究所 Ternary compound weeding composition and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005126415A (en) * 2003-09-30 2005-05-19 Sumitomo Chemical Takeda Agro Co Ltd Herbicidal composition
JP2007314519A (en) * 2006-04-28 2007-12-06 Sumitomo Chemical Co Ltd Herbicidal composition
US8138122B2 (en) * 2006-04-28 2012-03-20 Sumitomo Chemical Company, Limited Herbicidal composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005126415A (en) * 2003-09-30 2005-05-19 Sumitomo Chemical Takeda Agro Co Ltd Herbicidal composition
JP2007314519A (en) * 2006-04-28 2007-12-06 Sumitomo Chemical Co Ltd Herbicidal composition
US8138122B2 (en) * 2006-04-28 2012-03-20 Sumitomo Chemical Company, Limited Herbicidal composition

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