CN108719220A - A kind of preparation method of corrosion-resistant bionic fish bait fish hook - Google Patents
A kind of preparation method of corrosion-resistant bionic fish bait fish hook Download PDFInfo
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- CN108719220A CN108719220A CN201810629347.0A CN201810629347A CN108719220A CN 108719220 A CN108719220 A CN 108719220A CN 201810629347 A CN201810629347 A CN 201810629347A CN 108719220 A CN108719220 A CN 108719220A
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- 241000251468 Actinopterygii Species 0.000 title claims abstract description 75
- 239000011664 nicotinic acid Substances 0.000 title claims abstract description 30
- 238000005260 corrosion Methods 0.000 title claims abstract description 23
- 230000007797 corrosion Effects 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 17
- -1 rare-earth hydroxide Chemical class 0.000 claims abstract description 17
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 238000012545 processing Methods 0.000 claims abstract description 13
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 12
- 238000011017 operating method Methods 0.000 claims abstract description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000908 ammonium hydroxide Substances 0.000 claims abstract description 6
- 239000003729 cation exchange resin Substances 0.000 claims abstract description 6
- 229940023913 cation exchange resins Drugs 0.000 claims abstract description 6
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims abstract description 6
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 6
- 238000001556 precipitation Methods 0.000 claims abstract description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 6
- NASFKTWZWDYFER-UHFFFAOYSA-N sodium;hydrate Chemical compound O.[Na] NASFKTWZWDYFER-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005341 cation exchange Methods 0.000 claims abstract description 3
- 238000005119 centrifugation Methods 0.000 claims abstract description 3
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- CFYGEIAZMVFFDE-UHFFFAOYSA-N neodymium(3+);trinitrate Chemical class [Nd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CFYGEIAZMVFFDE-UHFFFAOYSA-N 0.000 claims description 5
- 238000000643 oven drying Methods 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract description 6
- JPAOMENBKRZQDR-UHFFFAOYSA-N CC=CC.[Na] Chemical compound CC=CC.[Na] JPAOMENBKRZQDR-UHFFFAOYSA-N 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract description 4
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- 229910052779 Neodymium Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 abstract 1
- 235000019688 fish Nutrition 0.000 description 55
- 230000000694 effects Effects 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 230000003592 biomimetic effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000238424 Crustacea Species 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000270666 Testudines Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K83/00—Fish-hooks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Environmental Sciences (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Fodder In General (AREA)
Abstract
The present invention discloses a kind of preparation method of corrosion-resistant bionic fish bait fish hook, including following operating procedure：（1）Neodymium nitrate, lanthanum nitrate are added into water, then proceed to that ammonium hydroxide is added thereto, after being mixed evenly, isothermal holding, centrifugation is precipitated, and after precipitation is dried, rare-earth hydroxide is made；（2）Industrial waterglass is passed through into 732 type cation exchange resins, after cation exchanges, active silicic acid solution is obtained, then after mixing by active silicic acid solution, lithium hydroxide, rare-earth hydroxide, two molybdic acid hydrate sodium, methylpropene sodium sulfonate, fish hook coating is made；（3）By fish hook coating application on bionic fish bait fish hook surface, then it is added in baking oven, after drying and processing, finished product.A kind of preparation method of corrosion-resistant bionic fish bait fish hook provided by the invention, easy to operate, of low cost, bionic fish bait fish hook obtained, excellent anti-corrosion performance, service life are long.
Description
Technical field
The invention belongs to bionic fish bait preparing technical fields, and in particular to a kind of preparation of corrosion-resistant bionic fish bait fish hook
Method.
Background technology
The common shape of soft bionic fish bait has spiral list tail worm type, and in taper is spun, there is spiral shape in tail portion on the bait head
Tail, can with water movement, be suitable for each water layer, to most of predacious fish all have phagostimulating effect.Double tails
The bait of maggot type can imitate out the action of huge legendary turtle shrimp, some feeding habits of food calling in water in double tails of the flow action in the bait
Tend to the demersal fishes of crustacean.Soft bionic fish bait can go out different fishing Biomimetic Fishs according to different mold design
Bait is applicable to different water environments, and plays different effects for different predacious fish.Fish in bionic fish bait
Hook, in water due to regular immersion, corrosive substance is more in water, and bill is corroded, just no longer sharp, if again
For the fish for fishing mouth small, hooked-off rate obviously rises.
Invention content
In order to solve the above technical problem, the present invention provides a kind of preparation methods of corrosion-resistant bionic fish bait fish hook.
The present invention is achieved by the following technical solutions.
A kind of preparation method of corrosion-resistant bionic fish bait fish hook, including following operating procedure：
（1）By weight, 11-15 parts of neodymium nitrates, 19-24 parts of lanthanum nitrates are added into 66-70 parts of water, are then proceeded to it
The middle ammonium hydroxide that 40-45 parts of mass fractions are added and are 27% after being mixed evenly, heats the mixture to 105-110 DEG C, heat preservation
After processing 3-4 hours, centrifugation is precipitated, and after precipitation is dried, rare-earth hydroxide is made；
（2）After industrial waterglass addition distilled water is diluted to the concentration of 7-9%, by 732 type cation exchange resins, pass through
After cation exchanges, active silicic acid solution is obtained, then by weight, by 44-50 parts of active silicic acid solution, 8-12 parts of hydrogen-oxygens
Change lithium, 6-12 parts of rare-earth hydroxides, two molybdic acid hydrate sodium of 0.1-0.3 parts, 0.4-0.8 parts of methylpropene sodium sulfonates to be uniformly mixed
Afterwards, fish hook coating is made；
（3）By fish hook coating application on bionic fish bait fish hook surface, then it is added in baking oven, after drying and processing, finished product.
Specifically, above-mentioned steps（1）In, the temperature for precipitating drying is 105-110 DEG C, time 2-3 hour of drying and processing.
Specifically, above-mentioned steps（3）In, the temperature of baking oven drying is 85-90 DEG C.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows：
A kind of preparation method of corrosion-resistant bionic fish bait fish hook provided by the invention, it is easy to operate, it is of low cost, it is obtained imitative
Raw bait fish hook, excellent anti-corrosion performance, service life are long.Wherein, rare-earth hydroxide produced by the present invention, can be effective
Promote the water resistance that film layer is formed after the drying of fish hook coating, so it is effective extend bionic fish bait fish hook it is corrosion-resistant when
Effect, while rare-earth hydroxide also effectively extends film layer to the resistance of acid-base material, greatly extends Biomimetic Fish
The service life of bait fish hook.
Specific implementation mode
Following embodiment cannot be used for limiting the scope of the invention for illustrating the present invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of preparation method of corrosion-resistant bionic fish bait fish hook, including following operating procedure：
（1）By weight, 11 parts of neodymium nitrates, 19 parts of lanthanum nitrates are added into 66 parts of water, then proceed to that 40 are added thereto
The ammonium hydroxide that part mass fraction is 27%, after being mixed evenly, heats the mixture to 105 DEG C, and isothermal holding is after 3 hours, from
The heart is precipitated, and after precipitation is dried, rare-earth hydroxide is made；
（2）After industrial waterglass addition distilled water is diluted to 7% concentration, by 732 type cation exchange resins, by sun
After ion exchange, obtain active silicic acid solution, then by weight, by 44 parts of active silicic acid solution, 8 parts of lithium hydroxides, 6 parts
After mixing, fish hook coating is made in rare-earth hydroxide, 0.1 part of two molybdic acid hydrate sodium, 0.4 part of methylpropene sodium sulfonate；
（3）By fish hook coating application on bionic fish bait fish hook surface, then it is added in baking oven, after drying and processing, finished product.
Specifically, above-mentioned steps（1）In, the temperature for precipitating drying is 105 DEG C, the time 2 h of drying and processing.
Specifically, above-mentioned steps（3）In, the temperature of baking oven drying is 85 DEG C.
Embodiment 2
A kind of preparation method of corrosion-resistant bionic fish bait fish hook, including following operating procedure：
（1）By weight, 13 parts of neodymium nitrates, 21 parts of lanthanum nitrates are added into 68 parts of water, then proceed to that 43 are added thereto
The ammonium hydroxide that part mass fraction is 27%, after being mixed evenly, heats the mixture to 108 DEG C, and isothermal holding is after 3.5 hours, from
The heart is precipitated, and after precipitation is dried, rare-earth hydroxide is made；
（2）After industrial waterglass addition distilled water is diluted to 8% concentration, by 732 type cation exchange resins, by sun
After ion exchange, active silicic acid solution is obtained, then by weight, by 48 parts of active silicic acid solution, 10 parts of lithium hydroxides, 10
After mixing, fish hook coating is made in part rare-earth hydroxide, 0.2 part of two molybdic acid hydrate sodium, 0.6 part of methylpropene sodium sulfonate；
（3）By fish hook coating application on bionic fish bait fish hook surface, then it is added in baking oven, after drying and processing, finished product.
Specifically, above-mentioned steps（1）In, the temperature for precipitating drying is 108 DEG C, the 2.5 hours time of drying and processing.
Specifically, above-mentioned steps（3）In, the temperature of baking oven drying is 88 DEG C.
Embodiment 3
A kind of preparation method of corrosion-resistant bionic fish bait fish hook, including following operating procedure：
（1）By weight, 15 parts of neodymium nitrates, 24 parts of lanthanum nitrates are added into 70 parts of water, then proceed to that 45 are added thereto
The ammonium hydroxide that part mass fraction is 27%, after being mixed evenly, heats the mixture to 110 DEG C, and isothermal holding is after 4 hours, from
The heart is precipitated, and after precipitation is dried, rare-earth hydroxide is made；
（2）After industrial waterglass addition distilled water is diluted to 9% concentration, by 732 type cation exchange resins, by sun
After ion exchange, active silicic acid solution is obtained, then by weight, by 50 parts of active silicic acid solution, 12 parts of lithium hydroxides, 12
After mixing, fish hook coating is made in part rare-earth hydroxide, 0.3 part of two molybdic acid hydrate sodium, 0.8 part of methylpropene sodium sulfonate；
（3）By fish hook coating application on bionic fish bait fish hook surface, then it is added in baking oven, after drying and processing, finished product.
Specifically, above-mentioned steps（1）In, the temperature for precipitating drying is 110 DEG C, the 3 hours time of drying and processing.
Specifically, above-mentioned steps（3）In, the temperature of baking oven drying is 90 DEG C.
Comparative example 1
Step（2）In do not add rare-earth hydroxide, remaining operating procedure is identical with embodiment 1.
Corrosion-resistant bionic fish bait fish hook is made with the method for each embodiment and comparative example respectively, it is corrosion-resistant then to test its
Performance, test result are as shown in table 1：
The corrosion resistance of 1 corrosion-resistant bionic fish bait fish hook of table is able to verify that
Percentage in above table is mass fraction, and as shown in Table 1, corrosion-resistant bionic fish bait made from the present embodiment uses fish
Hook, excellent anti-corrosion performance greatly extend the service life of bionic fish bait.
Certainly, above description is not limitation of the present invention, and the present invention is also not limited to the example above, the art
Those of ordinary skill, the present invention essential scope in, variation, change, addition or the replacement made, should all belong to the present invention
Protection domain.
Claims (3)
1. a kind of preparation method of corrosion-resistant bionic fish bait fish hook, which is characterized in that including following operating procedure：
（1）By weight, 11-15 parts of neodymium nitrates, 19-24 parts of lanthanum nitrates are added into 66-70 parts of water, are then proceeded to it
The middle ammonium hydroxide that 40-45 parts of mass fractions are added and are 27% after being mixed evenly, heats the mixture to 105-110 DEG C, heat preservation
After processing 3-4 hours, centrifugation is precipitated, and after precipitation is dried, rare-earth hydroxide is made；
（2）After industrial waterglass addition distilled water is diluted to the concentration of 7-9%, by 732 type cation exchange resins, pass through
After cation exchanges, active silicic acid solution is obtained, then by weight, by 44-50 parts of active silicic acid solution, 8-12 parts of hydrogen-oxygens
Change lithium, 6-12 parts of rare-earth hydroxides, two molybdic acid hydrate sodium of 0.1-0.3 parts, 0.4-0.8 parts of methylpropene sodium sulfonates to be uniformly mixed
Afterwards, fish hook coating is made；
（3）By fish hook coating application on bionic fish bait fish hook surface, then it is added in baking oven, after drying and processing, finished product.
2. a kind of preparation method of corrosion-resistant bionic fish bait fish hook according to claim 1, which is characterized in that above-mentioned step
Suddenly（1）In, the temperature for precipitating drying is 105-110 DEG C, time 2-3 hour of drying and processing.
3. a kind of preparation method of corrosion-resistant bionic fish bait fish hook according to claim 1, which is characterized in that above-mentioned step
Suddenly（3）In, the temperature of baking oven drying is 85-90 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810629347.0A CN108719220A (en) | 2018-06-19 | 2018-06-19 | A kind of preparation method of corrosion-resistant bionic fish bait fish hook |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810629347.0A CN108719220A (en) | 2018-06-19 | 2018-06-19 | A kind of preparation method of corrosion-resistant bionic fish bait fish hook |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108719220A true CN108719220A (en) | 2018-11-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810629347.0A Pending CN108719220A (en) | 2018-06-19 | 2018-06-19 | A kind of preparation method of corrosion-resistant bionic fish bait fish hook |
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|---|---|---|---|---|
| CN102833999A (en) * | 2010-04-12 | 2012-12-19 | 伽玛卡兹股份有限公司 | Fishhook and method for manufacturing same |
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| CN103205198A (en) * | 2013-04-18 | 2013-07-17 | 陕西驭腾实业有限公司 | Anti-corrosion coating for low-temperature flue gas heat exchange device of boiler and preparation method thereof |
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2018
- 2018-06-19 CN CN201810629347.0A patent/CN108719220A/en active Pending
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