CN108706545A - A kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof - Google Patents
A kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof Download PDFInfo
- Publication number
- CN108706545A CN108706545A CN201810657643.1A CN201810657643A CN108706545A CN 108706545 A CN108706545 A CN 108706545A CN 201810657643 A CN201810657643 A CN 201810657643A CN 108706545 A CN108706545 A CN 108706545A
- Authority
- CN
- China
- Prior art keywords
- parts
- sodium
- preparation
- dioxide solution
- potassium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/037—Stabilisation by additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof, including following making material number, wherein sodium stannate 4-7 parts, 3-9 parts of sodium pyrophosphate, 3.5-6 parts of vulcanized sodium, 0.75-1.5 parts of zinc sulfate, 2.5-5 parts of Cymag, 7-14 parts of potassium bichromate, 2-4 parts of potassium cyanide, 0.8-2 parts of carboxymethyl cellulose, 3-6 parts of diethanolamine, 4-8 parts of sodium metasilicate, 0.2-0.4 parts of sodium oxalate, 0.15-0.3 parts of gaultherolin, 0.3-0.5 parts of Potassium Benzoate, 0.4-0.6 parts of sodium thioglycolate, modified 15-30 parts of ether.The decomposing hydrogen dioxide solution inhibitor that the present invention makes can effectively prevent the decomposition reaction of hydrogen peroxide, the cost of material of entire inhibitor is low, and processing method is simple, is worthy to be popularized in the case of room temperature or high temperature.
Description
Technical field
The present invention relates to chemical industry pharmaceutical techniques field, especially a kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof.
Background technology
Hydrogen peroxide is also known as hydrogen peroxide (hydrogen peroxide), chemical formula H2O2.Pure hydrogen peroxide is nattier blue
Thick liquid, can arbitrary proportion it is miscible with water, be a kind of strong oxidizer, aqueous solution is commonly called as hydrogen peroxide, be colourless transparent liquid.Its
Aqueous solution is suitable for medical wound disinfection and environment disinfected and food sterilization.Water and oxygen can be slowly resolved under normal circumstances
Gas, but decomposition rate is extremely slow, and the method for accelerating its reaction speed is that catalyst --- manganese dioxide etc. is penetrated with shortwave for addition
Line irradiates.
Chemical industry is used as the original of production sodium perborate, SODIUM PERCARBONATE, Peracetic acid, sodium chlorite, thiourea peroxide etc.
Material, the oxidant of tartaric acid, vitamin etc..Medical industry be used as fungicide, disinfectant, and production thiram insecticide and
The oxidant of 40l antiseptics.Printing and dyeing industry is used as the bleaching agent of cotton fabric, the color development after reducing dye dyeing.For producing gold
De-iron and other heavy metals are removed when belonging to salt or other compounds.It is also used for electroplate liquid, inorganic impurity can be removed, improves plating piece matter
Amount.It is additionally operable to the bleaching of wool, raw silk, ivory, paper pulp, fat etc..The hydrogen peroxide of high concentration can be used as rocket-powered combustion-supporting
Agent.
Inhibitor (also known as retarder) is a kind of substance being used for blocking or reducing chemical reaction velocity, and effect is urged with negative
Agent is identical.It cannot stop polymerisation, only slow down polymerisation.So as to inhibiting or mitigating the substance of chemical reaction.Kind
There are many class, and application is very wide, however stabilized hydrogen peroxide is poor, once temperature is excessively high, is often susceptible to and resolves into water and oxygen,
Problems above just needs to be improved traditional processing method, herein it is proposed that a kind of double for above problem
Oxygen water decomposition inhibitor and preparation method thereof.
Invention content
The present invention provides a kind of hydrogen peroxide for the technical deficiency such as in terms of existing hydrogen peroxide inhibitor function
Decomposing inhibitor and preparation method thereof.
The present invention is to solve above-mentioned phenomenon, using the technical solution of following modification, a kind of decomposing hydrogen dioxide solution inhibitor and its
Preparation method, including following making material number, wherein sodium stannate 4-7 parts, 3-9 parts of sodium pyrophosphate, 3.5-6 parts of vulcanized sodium, sulphur
Sour zinc 0.75-1.5 parts, 2.5-5 parts of Cymag, 7-14 parts of potassium bichromate, 2-4 parts of potassium cyanide, 0.8-2 parts of carboxymethyl cellulose,
3-6 parts of diethanolamine, 4-8 parts of sodium metasilicate, 0.2-0.4 parts of sodium oxalate, 0.15-0.3 parts of gaultherolin, Potassium Benzoate 0.3-
0.5 part, 0.4-0.6 parts of sodium thioglycolate, modified 15-30 parts of ether.
Further include following making material number as present invention further optimization mode, wherein 7 parts of sodium stannate, burnt phosphorus
9 parts of sour sodium, 6 parts of vulcanized sodium, 1.5 parts of zinc sulfate, 5 parts of Cymag, 14 parts of potassium bichromate, 4 parts of potassium cyanide, carboxymethyl cellulose 2
Part, 6 parts of diethanolamine, 8 parts of sodium metasilicate, 0.4 part of sodium oxalate, 0.3 part of gaultherolin, 0.5 part of Potassium Benzoate, thioacetic acid
0.6 part of sodium, modified 30 parts of ether.
Further include following making material number as present invention further optimization mode, wherein 4 parts of sodium stannate, burnt phosphorus
3 parts of sour sodium, 3.5 parts of vulcanized sodium, 0.75 part of zinc sulfate, 2.5 parts of Cymag, 7 parts of potassium bichromate, 2 parts of potassium cyanide, carboxymethyl cellulose
0.8 part of element, 3 parts of diethanolamine, 4 parts of sodium metasilicate, 0.2 part of sodium oxalate, 0.15 part of gaultherolin, 0.3 part of Potassium Benzoate, mercapto
0.4 part of guanidine-acetic acid sodium, modified 15 parts of ether.
As present invention further optimization mode, manufacturing process steps are as follows：
A. above-mentioned raw materials are weighed according to weight percent, raw material is integrally put into high-speed stirred container, by mixed solvent
Adequately it is uniformly dispersed；
B. by the inside of above-mentioned scattered liquid reactions tank body, reaction 15-20min is carried out；
C. the solution in step b is sent into vacuum tank, then constantly injection inert gas, selection use argon gas, and
And the speed of 20ml/min is kept, it constantly injects, continues 5-12min and pH adjusting agent is then put into vacuum tank after mixing
In body, the acid-base value of mixture is adjusted to 7.2；
D. after the completion of mixing, high-temperature sterilization is carried out, temperature is controlled at 110-140 DEG C, continues 5-12 minutes, high-temperature sterilization
Afterwards, then disinfection by ultraviolet light is carried out, that is, completes processing.
As present invention further optimization mode, in step a, first the rotating speed of 150-250r/min is kept to continue 5min,
Then high speed rotation is carried out, control continues 25min in 600-900r/min, and in whipping process, control temperature is at 75 DEG C.
As present invention further optimization mode, in step b, reaction temperature is at 50-200 DEG C, reaction pressure 5-
12MPa。
As present invention further optimization mode, the production method of the modified ether includes, first by diethyl ether solution
The vacuum for being sent into sealing fills, then continuous injection inert nitrogen gas, while injecting the ammonia of equivalent, then control temperature into
The continuous continuous heating of row, keeps 12 DEG C of temperature, is constantly warming up to 160 DEG C, control pressure continues 10min, finally in 3.2Mpa
Cooling and standings 5min completes to be modified.
Compared with prior art：The decomposing hydrogen dioxide solution inhibitor that the present invention makes can in the case of room temperature or high temperature
Effectively to prevent the decomposition reaction of hydrogen peroxide, the cost of material of entire inhibitor is low, and processing method is simple, is worthy to be popularized.
Specific implementation mode
Below in conjunction in the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts
Example, shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution：A kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof, including following making
Material number, wherein sodium stannate 4-7 parts, 3-9 parts of sodium pyrophosphate, 3.5-6 parts of vulcanized sodium, 0.75-1.5 parts of zinc sulfate, Cymag
2.5-5 parts, 7-14 parts of potassium bichromate, 2-4 parts of potassium cyanide, 0.8-2 parts of carboxymethyl cellulose, 3-6 parts of diethanolamine, sodium metasilicate
4-8 parts, 0.2-0.4 parts of sodium oxalate, 0.15-0.3 parts of gaultherolin, 0.3-0.5 parts of Potassium Benzoate, sodium thioglycolate 0.4-
0.6 part, modified 15-30 parts of ether.
Further include following making material number, wherein 7 parts of sodium stannate, 9 parts of sodium pyrophosphate, 6 parts of vulcanized sodium, zinc sulfate 1.5
Part, 5 parts of Cymag, 14 parts of potassium bichromate, 4 parts of potassium cyanide, 2 parts of carboxymethyl cellulose, 6 parts of diethanolamine, 8 parts of sodium metasilicate,
0.4 part of sodium oxalate, 0.3 part of gaultherolin, 0.5 part of Potassium Benzoate, 0.6 part of sodium thioglycolate, modified 30 parts of ether.
Further include following making material number, wherein 4 parts of sodium stannate, 3 parts of sodium pyrophosphate, 3.5 parts of vulcanized sodium, zinc sulfate
0.75 part, 2.5 parts of Cymag, 7 parts of potassium bichromate, 2 parts of potassium cyanide, 0.8 part of carboxymethyl cellulose, 3 parts of diethanolamine, metasilicic acid
4 parts of sodium, 0.2 part of sodium oxalate, 0.15 part of gaultherolin, 0.3 part of Potassium Benzoate, 0.4 part of sodium thioglycolate, modified ether 15
Part.
Manufacturing process steps are as follows：
A. above-mentioned raw materials are weighed according to weight percent, raw material is integrally put into high-speed stirred container, by mixed solvent
Adequately it is uniformly dispersed；
B. by the inside of above-mentioned scattered liquid reactions tank body, reaction 15-20min is carried out；
C. the solution in step b is sent into vacuum tank, then constantly injection inert gas, selection use argon gas, and
And the speed of 20ml/min is kept, it constantly injects, continues 5-12min and pH adjusting agent is then put into vacuum tank after mixing
In body, the acid-base value of mixture is adjusted to 7.2；
D. after the completion of mixing, high-temperature sterilization is carried out, temperature is controlled at 110-140 DEG C, continues 5-12 minutes, high-temperature sterilization
Afterwards, then disinfection by ultraviolet light is carried out, that is, completes processing.
In step a, first the rotating speed of 150-250r/min is kept to continue 5min, then carry out high speed rotation, controlled in 600-
900r/min continues 25min, and in whipping process, control temperature is at 75 DEG C.
In step b, reaction temperature is at 50-200 DEG C, reaction pressure 5-12MPa.
The production method of the modified ether includes diethyl ether solution being sent into the vacuum filling of sealing first, then constantly
Inert nitrogen gas is injected, while injecting the ammonia of equivalent, temperature is then controlled and carries out continuous continuous heating, keep 12 DEG C of temperature
Degree is constantly warming up to 160 DEG C, and control pressure continues 10min, final cooling and standings 5min in 3.2Mpa, that is, completes to be modified.
Decomposing hydrogen dioxide solution inhibitor parameter table of the present invention is as follows：Table 1
Traditional decomposing hydrogen dioxide solution inhibitor parameter table is as follows：Table 2
。
It to sum up states, the inhibition that the present invention is will become apparent from by Tables 1 and 2 is more preferable, the dioxygen moisture that the present invention makes
Solution inhibitor can effectively prevent the decomposition reaction of hydrogen peroxide, the raw material of entire inhibitor in the case of room temperature or high temperature
It is at low cost, and processing method is simple, is worthy to be popularized.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention, for this field skill
For art personnel, it is clear that invention is not limited to the details of the above exemplary embodiments, and without departing substantially from the present invention spirit or
In the case of essential characteristic, the present invention can be realized in other specific forms.Therefore, in all respects, should all incite somebody to action
Embodiment regards exemplary as, and is non-limiting, the scope of the present invention by appended claims rather than on state
Bright restriction, it is intended that including all changes that come within the meaning and range of equivalency of the claims in the present invention
It is interior.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (7)
1. a kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof, it is characterised in that：Including following making material number, wherein tin
Sour sodium 4-7 parts, 3-9 parts of sodium pyrophosphate, 3.5-6 parts of vulcanized sodium, 0.75-1.5 parts of zinc sulfate, 2.5-5 parts of Cymag, potassium bichromate
7-14 parts, 2-4 parts of potassium cyanide, 0.8-2 parts of carboxymethyl cellulose, 3-6 parts of diethanolamine, 4-8 parts of sodium metasilicate, sodium oxalate 0.2-
0.4 part, 0.15-0.3 parts of gaultherolin, 0.3-0.5 parts of Potassium Benzoate, 0.4-0.6 parts of sodium thioglycolate, modified ether 15-
30 parts.
2. a kind of decomposing hydrogen dioxide solution inhibitor according to claim 1 and preparation method thereof, which is characterized in that further include with
Lower making material number, wherein 7 parts of sodium stannate, 9 parts of sodium pyrophosphate, 6 parts of vulcanized sodium, 1.5 parts of zinc sulfate, 5 parts of Cymag, weight chromium
14 parts of sour potassium, 4 parts of potassium cyanide, 2 parts of carboxymethyl cellulose, 6 parts of diethanolamine, 8 parts of sodium metasilicate, 0.4 part of sodium oxalate, salicylic acid
0.3 part of methyl esters, 0.5 part of Potassium Benzoate, 0.6 part of sodium thioglycolate, modified 30 parts of ether.
3. a kind of decomposing hydrogen dioxide solution inhibitor according to claim 1 and preparation method thereof, which is characterized in that further include with
Lower making material number, wherein 4 parts of sodium stannate, 3 parts of sodium pyrophosphate, 3.5 parts of vulcanized sodium, 0.75 part of zinc sulfate, Cymag 2.5
Part, 7 parts of potassium bichromate, 2 parts of potassium cyanide, 0.8 part of carboxymethyl cellulose, 3 parts of diethanolamine, 4 parts of sodium metasilicate, sodium oxalate 0.2
Part, 0.15 part of gaultherolin, 0.3 part of Potassium Benzoate, 0.4 part of sodium thioglycolate, modified 15 parts of ether.
4. a kind of decomposing hydrogen dioxide solution inhibitor according to claim 1 and preparation method thereof, which is characterized in that manufacture craft
Steps are as follows：
A. above-mentioned raw materials are weighed according to weight percent, raw material is integrally put into high-speed stirred container, mixed solvent is carried out
Adequately it is uniformly dispersed；
B. by the inside of above-mentioned scattered liquid reactions tank body, reaction 15-20min is carried out；
C. the solution in step b is sent into vacuum tank, then constantly injection inert gas, selection are protected using argon gas
The speed of 20ml/min is held, is constantly injected, continues 5-12min and pH adjusting agent is then put into vacuum tank after mixing
In, the acid-base value of mixture is adjusted to 7.2；
D. after the completion of mixing, high-temperature sterilization is carried out, temperature is controlled at 110-140 DEG C, continues 5-12 minutes, after high-temperature sterilization, then
Disinfection by ultraviolet light is carried out, that is, completes processing.
5. a kind of decomposing hydrogen dioxide solution inhibitor according to claim 4 and preparation method thereof, which is characterized in that in step a,
First the rotating speed of 150-250r/min is kept to continue 5min, then carry out high speed rotation, control continues in 600-900r/min
25min, in whipping process, control temperature is at 75 DEG C.
6. a kind of decomposing hydrogen dioxide solution inhibitor according to claim 4 and preparation method thereof, which is characterized in that in step b,
Reaction temperature is at 50-200 DEG C, reaction pressure 5-12MPa.
7. a kind of decomposing hydrogen dioxide solution inhibitor according to claim 1 and preparation method thereof, which is characterized in that the modification
The production method of ether includes that diethyl ether solution is sent into the vacuum filling of sealing first, then constantly injects inert nitrogen gas,
The ammonia of equivalent is injected simultaneously, is then controlled temperature and is carried out continuous continuous heating, keeps 12 DEG C of temperature, be constantly warming up to 160
DEG C, control pressure continues 10min, final cooling and standings 5min in 3.2Mpa, that is, completes to be modified.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810657643.1A CN108706545A (en) | 2018-06-20 | 2018-06-20 | A kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810657643.1A CN108706545A (en) | 2018-06-20 | 2018-06-20 | A kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108706545A true CN108706545A (en) | 2018-10-26 |
Family
ID=63872000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810657643.1A Pending CN108706545A (en) | 2018-06-20 | 2018-06-20 | A kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108706545A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050226800A1 (en) * | 2004-04-08 | 2005-10-13 | Xue Wang | Stabilization of alkaline hydrogen peroxide |
| CN102295274A (en) * | 2011-06-16 | 2011-12-28 | 天津运盛化学品有限公司 | Hydrogen peroxide stabilizing agent |
| CN103896217A (en) * | 2012-12-29 | 2014-07-02 | 新煤化工设计院（上海）有限公司 | Stabilizer of hydrogen peroxide |
| CN106660792A (en) * | 2014-06-30 | 2017-05-10 | 阿肯马法国公司 | Hydrogen peroxide purification process and hyrodgen peroxide solution |
| CN107055482A (en) * | 2016-12-30 | 2017-08-18 | 上海哈勃化学技术有限公司 | A kind of stabilizer of hydrogen peroxide and preparation method thereof |
-
2018
- 2018-06-20 CN CN201810657643.1A patent/CN108706545A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050226800A1 (en) * | 2004-04-08 | 2005-10-13 | Xue Wang | Stabilization of alkaline hydrogen peroxide |
| CN102295274A (en) * | 2011-06-16 | 2011-12-28 | 天津运盛化学品有限公司 | Hydrogen peroxide stabilizing agent |
| CN103896217A (en) * | 2012-12-29 | 2014-07-02 | 新煤化工设计院（上海）有限公司 | Stabilizer of hydrogen peroxide |
| CN106660792A (en) * | 2014-06-30 | 2017-05-10 | 阿肯马法国公司 | Hydrogen peroxide purification process and hyrodgen peroxide solution |
| CN107055482A (en) * | 2016-12-30 | 2017-08-18 | 上海哈勃化学技术有限公司 | A kind of stabilizer of hydrogen peroxide and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 周连江: "《无机盐工业手册（下册）》", 30 June 1996 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102626104B (en) | Stabilized chlorine dioxide disinfection solution and preparation method thereof | |
| CN108793401A (en) | A kind of formula and preparation method thereof of denitrification compounded carbons | |
| CN110040688B (en) | Preparation method of stable chlorine dioxide solution | |
| CN100391343C (en) | Monophyletic solid disinfectant of chlorine dioxide and preparation method thereof | |
| CN102268814B (en) | Auxiliary agent composition used in low temperature one-bath scouring and bleaching process for cotton textile and application thereof | |
| CN108996629A (en) | Potassium Monopersulfate compound effervescent tablet and preparation method thereof for the improvement of water quality substrate | |
| CN113207906B (en) | Slow-release long-acting oxone disinfectant and preparation method thereof | |
| US3804944A (en) | Sodium dithionite solution stablization | |
| CN108706545A (en) | A kind of decomposing hydrogen dioxide solution inhibitor and preparation method thereof | |
| CN102839533A (en) | Short-process pre-treatment scouring agent for textile and preparation method thereof | |
| CN110558318A (en) | Stable chlorine dioxide effervescent agent and preparation method thereof | |
| US4100098A (en) | Stabilized solutions of sodium dithionite | |
| CN107127353A (en) | A kind of nano silver colloidal sol and preparation method thereof | |
| CN106398908B (en) | A method of adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake | |
| CA2384471A1 (en) | Oxidised white liquor in an oxygen delignification process | |
| CN104153185B (en) | Chloroperoxidase catalysis oxidation hair decolorising agent and the method decolourized and application | |
| CN103351316B (en) | Method for removing iron ions from sodium thiomethoxide solution | |
| CN101648836A (en) | Water replenishing nutrient of edible mushroom | |
| CN114342929B (en) | Oxidant stabilizing solution and preparation method thereof | |
| CN109535444A (en) | The bleaching process of hydroxyethyl cellulose | |
| CN103334291B (en) | Method for bleaching cotton fabric by chlorine dioxide | |
| CN213446231U (en) | Nitrosyl sulfuric acid's synthesizer | |
| CN102515205A (en) | Process for removing sulfides from brine | |
| KR930003659B1 (en) | Process for manufacturing stable chlorine dioxide acqueous solution | |
| CN102452857A (en) | Peroxy calcium-magnesium plant growth solution |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181026 |